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A Novel Three-stage Tectonic Model for Mississippi Valleytype Zn-Pb Deposits in Orogenic Fold-and-Thrust Belts
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作者 SONG Yucai 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第4期843-849,共7页
Mississippi Valley-type(MVT) Zn-Pb deposits predominantly form within both orogenic forelands and fold-andthrust belts, yet the mineralization process within the latter tectonic setting remains inadequately understood... Mississippi Valley-type(MVT) Zn-Pb deposits predominantly form within both orogenic forelands and fold-andthrust belts, yet the mineralization process within the latter tectonic setting remains inadequately understood. This study, through a comprehensive review of MVT deposits across global fold-and-thrust belts, introduces a novel model elucidating the mineralization process in the context of tectonic belt evolution. It is demonstrated that during the stage Ⅰ, regional compression is introduced by early stages of plate convergence, causing the folding and thrusting and creating structural or lithological traps such as evaporite diapirs and unconformity-related carbonate dissolution-collapse structures. Thereafter, in stage Ⅱ, hydrocarbons begin to migrate and accumulate within these traps, where reduced sulfur is generated through thermochemical or bacterial sulfate reduction concurrent with or preceding Zn-Pb mineralization. In the subsequent stage Ⅲ, as plate convergence persists, the regional stress transitions from compression to transpression or extension. Under these conditions, steeply-dipping extensional faults are generated, facilitating the ascent of metalliferous brines into early-formed structural or lithological traps. Precipitation of Zn and Pb sulfides occurs through the mixing of Zn-Pb-transporting fluids with pre-existing reduced sulfur or by interaction with hydrocarbons. 展开更多
关键词 Mississippi Valley-type zn-pb deposits fold-and-thrust belts tectonic model structural or lithological traps extensional faults
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伊朗Angouran Zn-Pb-Ag矿床特征与成因 被引量:4
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作者 庄亮亮 宋玉财 +1 位作者 刘英超 韩朝辉 《地质学报》 EI CAS CSCD 北大核心 2015年第9期1607-1617,共11页
Angouran Zn-Pb-Ag矿床是伊朗目前正在开采的最大的铅锌矿床。它位于Zagros造山带内的Sanandaj-Sirjan变质带的西北部,赋存于新元古界—寒武系大理岩和片岩建造内。矿体上部呈筒状出现在大理岩中,向下逐渐过渡为似层状、层状,出现在大... Angouran Zn-Pb-Ag矿床是伊朗目前正在开采的最大的铅锌矿床。它位于Zagros造山带内的Sanandaj-Sirjan变质带的西北部,赋存于新元古界—寒武系大理岩和片岩建造内。矿体上部呈筒状出现在大理岩中,向下逐渐过渡为似层状、层状,出现在大理岩与云母片岩的接触带上。由上至下,出现碳酸盐型矿体、硫化物-碳酸盐混合矿体、硫化物矿体,由角砾状和块状矿石组成。硫化物主要为闪锌矿,分早期富Fe和晚期贫Fe两种,次为方铅矿。碳酸盐矿物主要是菱锌矿和方解石,前者包括早期内生成因的和晚期为次生成因的两种类型。硫化物阶段成矿期流体具有低温、高盐度的特征,为Na+-Ca2+-Cl--SO2+4卤水体系,来自蒸发的盆地卤水。C-O、S和Pb同位素特征反映出成矿流体与大理岩围岩发生了强烈的相互作用,沉淀的碳酸盐矿物一定程度继承了围岩的C-O同位素特征,硫化物中的硫主要来源于硫酸盐的热化学还原作用,金属为壳源成因。Angouran矿床缺乏岩体、后生矿化、(主要)碳酸盐岩赋矿、角砾岩容矿、成矿流体为盆地卤水来源等特征与密西西比河谷型(MVT)矿床相似,而与火山成因块状硫化物(VMS)、沉积喷流型(SEDEX)、侵入体有关的热液矿床的特征差别明显,反映该矿床的硫化物成矿可能是一个MVT矿床。硫化物成矿后叠加了与火山作用有关的内生菱锌矿矿化,最后在表生作用下形成了次生的菱锌矿矿化。 展开更多
关键词 地质特征 MVT 闪锌矿 菱锌矿 Angouran zn-pb-Ag矿床 伊朗
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Zn-Pb合金液相分离机制的研究 被引量:1
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作者 赵忠民 贾均 +1 位作者 郭景杰 赵九洲 《铸造》 CAS CSCD 北大核心 1999年第7期1-3,共3页
根据ZnPb合金液相分离过程,建立了两相熔体中弥散相液滴粗化模型,并进行了模拟计算。通过对比试验。
关键词 zn-pb合金 液相分离 扩散长大 Ostwald凝并
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大兴安岭南段白音查干Sn-Ag-Zn-Pb矿床电气石矿物学特征及对岩浆-热液演化过程的启示 被引量:3
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作者 李真真 秦克章 +4 位作者 裴斌 赵俊兴 施睿哲 赵泽龙 韩日 《岩石学报》 SCIE EI CAS CSCD 北大核心 2020年第12期3797-3812,共16页
内蒙古西乌旗白音查干矿床是大兴安岭南段锡矿带内最典型、规模最大的Sn-Ag-Zn-Pb矿床。电气石在成矿岩体花岗斑岩和围岩地层中均广泛发育,依据其产状可分为四类:Ⅰ团斑状电气石;Ⅱ热液角砾岩胶结物中电气石;Ⅲ热液脉状电气石;Ⅳ弥散状... 内蒙古西乌旗白音查干矿床是大兴安岭南段锡矿带内最典型、规模最大的Sn-Ag-Zn-Pb矿床。电气石在成矿岩体花岗斑岩和围岩地层中均广泛发育,依据其产状可分为四类:Ⅰ团斑状电气石;Ⅱ热液角砾岩胶结物中电气石;Ⅲ热液脉状电气石;Ⅳ弥散状电气石。在详细的岩相学基础上,利用电子探针点分析和面扫描分析对不同产状和结构的电气石进行了详细的成分分析。结果显示,花岗斑岩体深部的团斑状电气石(Ⅰa类)以自形、环带发育为特征,至少可见三期生长环带:核部电气石(Ⅰa-1)极高的Fe/(Fe+Mg)和Al值暗示其岩浆成因;边部电气石(Ⅰa-3)较富Mg,且与热液矿物共生,是从早期热液流体中沉淀形成的;幔部电气石(Ⅰa-2)的结构和成分显示其形成可能与不混溶的富B-Fe-Na的熔体或流体有关。因此,电气石从核部到边部的生长记录了从晚期岩浆到早期热液阶段的演变过程。花岗斑岩体中上部的团斑状电气石(Ⅰb类)环带不发育,其与热液矿物共生的组合及成分暗示其形成更倾向于与热液过程相关,可能是岩浆顶部聚集的早期流体释放之后被固结岩浆"圈闭"的残余流体结晶的产物。随后,大规模释放的富B流体形成了大量以电气石为主要胶结物的热液角砾岩(Ⅱ类)、成矿前电气石-石英阶段脉系(Ⅲa类)及伴随围岩蚀变而形成的弥散状电气石(Ⅳ类)。对Ⅱ类和Ⅲa类电气石内存在的生长环带分析显示,成矿前可能存在多个脉冲期次且成分有差异的流体的叠加作用。同时,电气石从早期到晚期向富Mg方向的演化,及成分明显受围岩地层影响的现象,暗示岩浆热液流体与围岩地层发生的水岩反应可能在金属成矿过程中起了重要作用。此外,本研究显示,不同产状电气石的结构和成分信息能够有效记录矿床内岩浆-热液转变及热液演化过程的众多细节信息,为深入理解成矿过程提供了依据。 展开更多
关键词 白音查干 Sn-Ag-zn-pb矿床 电气石 生长环带 岩浆-热液演化
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大兴安岭北段岔路口斑岩Mo-热液脉状Zn-Pb成矿系统硫化物微量元素的分布、起源及其勘探指示 被引量:11
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作者 金露英 秦克章 +3 位作者 李光明 李真真 宋国学 孟昭君 《岩石学报》 SCIE EI CAS CSCD 北大核心 2015年第8期2417-2434,共18页
岔路口斑岩Mo-Zn-Pb矿床位于大兴安岭北段,是近年来新发现的超大型斑岩-热液脉状Mo-Zn-Pb成矿系统,脉状Zn-Pb矿化直接叠置在斑岩Mo矿化顶部。本文挑选岔路口斑岩型矿化及热液脉型矿化的黄铁矿、闪锌矿、方铅矿,通过EMPA、ICP-MS等多种... 岔路口斑岩Mo-Zn-Pb矿床位于大兴安岭北段,是近年来新发现的超大型斑岩-热液脉状Mo-Zn-Pb成矿系统,脉状Zn-Pb矿化直接叠置在斑岩Mo矿化顶部。本文挑选岔路口斑岩型矿化及热液脉型矿化的黄铁矿、闪锌矿、方铅矿,通过EMPA、ICP-MS等多种方法分析硫化物的主微量元素组成,发现岔路口各阶段硫化物均富集Mo元素,相比于斑岩型矿化各阶段中的黄铁矿,Zn、Pb、Mn、Cd、Ga、Ag、Bi等元素在铅锌矿阶段内相对富集;相比于过渡阶段,铅锌阶段闪锌矿中Mo、Co元素及方铅矿中的Bi、Cd和Ag元素含量下降。微量元素在不同阶段内的变化可能是流体降温和天水混合的结果。黄铁矿的稀土总量与成矿岩体最接近,且与成矿岩体和围岩有相似的稀土配分模式,并有较明显的Eu负异常;黄铁矿宽广的Y/Ho比值(25.0~39.0)与成矿岩体的Y/Ho比值范围(27.4~38.7)最接近,同时包括了围岩相对较窄的Y/Ho比值(25.7~31.3),这表明成矿物质主要与成矿岩体同源,可能加入了一定量的围岩物质,岔路口硫化物富Mo的特征受控于深部斑岩Mo矿化岩浆-热液系统。对比东秦岭-大别W-Mo-Pb-Zn矿集区的远源热液脉状Pb-Zn矿床,岔路口浅部近源脉状矿化中的黄铁矿具有更高含量Mo/Ag-Bi/Sb比值和Mo/Pb-Sn/Sb比值,因此浅部硫化物的高Mo含量以及黄铁矿中相关元素比值的高值,可为脉状Zn-Pb矿化附近隐伏斑岩钼矿化的勘探提供新线索。此外,与其他热液脉状和斑岩型矿床相比,岔路口矿床硫化物更富集中高温元素;且综合分析多类矿床的硫化物的微量元素后,本文还初步查明不同矿床类型硫化物富集的微量元素,这一尝试可为矿床成因的判断提供新的思路。 展开更多
关键词 黄铁矿 闪锌矿 微量元素 矿床成因 物质来源 找矿勘探 岔路口斑岩钼-脉状锌铅成矿系统 大兴安岭北段
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干旱区绿洲土壤Cd-Zn与Cd-Zn-Pb复合污染对芹菜生长吸收特征影响的比较 被引量:5
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作者 颜斌 南忠仁 +3 位作者 赵转军 胡亚虎 王兆炜 杨一鸣 《兰州大学学报(自然科学版)》 CAS CSCD 北大核心 2013年第3期327-331,共5页
通过盆栽试验对干旱区绿洲土壤Cd-Zn和Cd-Zn-Pb复合胁迫下芹菜对Cd,Zn的吸收积累和迁移规律进行了研究.结果表明:在Cd-Zn和Cd-Zn-Pb复合胁迫下,芹菜根系干重呈减小趋势,而茎叶干重则先增加后减小.Pb对芹菜的生长为先促进后抑制,对芹菜... 通过盆栽试验对干旱区绿洲土壤Cd-Zn和Cd-Zn-Pb复合胁迫下芹菜对Cd,Zn的吸收积累和迁移规律进行了研究.结果表明:在Cd-Zn和Cd-Zn-Pb复合胁迫下,芹菜根系干重呈减小趋势,而茎叶干重则先增加后减小.Pb对芹菜的生长为先促进后抑制,对芹菜根系和茎叶吸收Cd,Zn具有一定的促进作用,促进了Cd,Zn从土壤到芹菜根系和茎叶的富集,对Cd,Zn从芹菜根系到茎叶具有一定的阻碍作用. 展开更多
关键词 绿洲土壤 CD ZN Pb 复合污染 吸收特征
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基于大数据分析的铜坑锡铟多金属矿床Sn-Zn-Pb矿化规律及其地质意义 被引量:3
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作者 燕永锋 贾福聚 +3 位作者 杨光树 秦德先 陈爱兵 杨鸿飞 《岩石学报》 SCIE EI CAS CSCD 北大核心 2019年第11期3398-3406,共9页
广西大厂矿田不但锡、锌、铅、锑等主要金属储量规模巨大,铟、锗、镉等稀散金属的经济价值也非常可观。本文系统收集整理了铜坑矿床资源勘查、开发过程中形成的1642个工程的编录资料,建立了三维空间数据库,对具有空间属性的Sn、Zn、Pb... 广西大厂矿田不但锡、锌、铅、锑等主要金属储量规模巨大,铟、锗、镉等稀散金属的经济价值也非常可观。本文系统收集整理了铜坑矿床资源勘查、开发过程中形成的1642个工程的编录资料,建立了三维空间数据库,对具有空间属性的Sn、Zn、Pb化学实验数据进行了统计分析。分析结果显示,相对92号矿体和细脉带矿体,91号矿体Sn、Zn品位高、富磁黄铁矿、主量金属相关性差,推测该矿体存在富含Sn、Zn的高温成矿流体叠加。岩浆期后热液型矿床随着远离含矿热液源头Zn/Pb值呈降低趋势,喷流沉积矿床随着距离喷口由近及远、沉积矿层由下往上,Zn/Pb值呈逐步增加趋势。铜坑矿床Zn/Pb空间分布规律是喷流沉积、岩浆热液叠加改造特征的复合,表明该矿床可能为喷流沉积-叠加改造复合成因。东岩墙(花岗斑岩脉)东西两侧随距离变远,Zn/Pb值呈近似对称性降低,推测东岩墙是成矿热液运移的通道。 展开更多
关键词 大数据 矿化规律 Zn/Pb 矿床成因 大厂矿田
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Rb-Sr isotopic dating of sphalerite from the giant Huize Zn-Pb ore field, Yunnan Province, Southwestern China 被引量:30
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作者 LI Wenbo 《Chinese Journal Of Geochemistry》 EI CAS 2009年第1期70-75,共6页
The giant Huize Zn-Pb ore field in Yunnan Province, southwestern China, comprises the Qilinchang and Kuangshanchang deposits. The deposits are large in scale (more than 5 Mt of Zn and Pb) and high in grade (average gr... The giant Huize Zn-Pb ore field in Yunnan Province, southwestern China, comprises the Qilinchang and Kuangshanchang deposits. The deposits are large in scale (more than 5 Mt of Zn and Pb) and high in grade (average grade of total Zn and Pb is 30%). Reported in this paper are the results of Rb-Sr isotopic dating of sphalerite from this ore field. Two precise ages (223.5±3.9 Ma and 226±6.4 Ma) have been obtained from two isochrons. These two ages are close to the reported ages of native copper mineralizations related to the Emeishan flood basalts in this region, which are 226 Ma to 228 Ma. Previous studies showed that the magnitude of uplift resultant from the Emeishan flood basalts is greater than 1000 m, indicating that the Kuangshanchang and Qilinchang deposits were formed during the same geological event and originated by fluid migration during uplifting resultant from the Emeishan flood basalts. 展开更多
关键词 zn-pb 油气成藏过程 同位素 测年方法
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REE Geochemistry of Sulfides from the Huize Zn-Pb Ore Field, Yunnan Province: Implication for the Sources of Ore-forming Metals 被引量:15
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作者 LI Wenbo HUANG Zhilong QI Liang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2007年第3期442-449,共8页
REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples (including pyrite, galena and sphalerite) are very low, with ... REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples (including pyrite, galena and sphalerite) are very low, with the ~REE ranging from 1.6×10^-9 to 166.8×10^-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. The JEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata. 展开更多
关键词 Huize zn-pb ore field REE geochemistry SULFIDE fluid ore-forming metal
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Fluid Inclusions of Calcite and Sources of Ore-forming Fluids in the Huize Zn-Pb-(Ag-Ge) District, Yunnan, China 被引量:25
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作者 HANRunsheng LILTCongqiang +5 位作者 HUANGZhilong MADeyun LIYuan HUBin MAGengsheng LEILi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第2期583-591,共9页
The Huize Zn-Pb- (Ag-Ge) district is a typical representative of the well-known medium-to large-sized carbonate-hosted Zn-Pb- (Ag-Ge) deposits, occurring in the Sichuan-Yunnan-Guizhou Pb-Zn Ore-forming Zone. Generally... The Huize Zn-Pb- (Ag-Ge) district is a typical representative of the well-known medium-to large-sized carbonate-hosted Zn-Pb- (Ag-Ge) deposits, occurring in the Sichuan-Yunnan-Guizhou Pb-Zn Ore-forming Zone. Generally, fluid inclusions within calcite, one of the major gangue minerals, are dominated by two kinds of small (1-10 um) inclusions including pure-liquid and liquid. The inclusions exist in concentrated groups along the crystal planes of the calcite. The ore-forming fluids containing Pb and Zn, which belong to the Na+-K+-Ca2+-Cl--F--SO42- type, are characterized by temperatures of 164-221℃, medium salinity in 5-10.8 wt% NaCl, and medium pressure at 410×105 to 661×105 Pa. The contents of Na+-K+ and C1--F-, and ratios of Na+/K+-Cl-/F- in fluid inclusions present good linearity. The ratios of Na+/K+ (4.66-6.71) and Cl-/F- (18.21-31.04) in the fluid inclusions of calcite are relatively high, while those of Na+/K+ (0.29-5.69) and Cl-/F- (5.00-26.0) in the inclusions of sphalerite and pyrite are relatively low. The ratio of Na+/K+ increases in accord with those of Cl-/F-, which indicates that ore-forming fluid of deep source participates in the mineralization. The waters of fluid inclusions have δD values from -43.5‰ to -55.4‰ of calcite. The δ18OV-SMOW values of the ore-forming fluids, calculated values, range from 17.09‰ to 18.56‰ of calcite and 17.80‰ to 23.14‰ for dolomite. δ13CV-PDB values range from -1.94‰ to -3.31‰ for calcite and -3.35‰ to 0.85‰ for the ore-bearing dolomite. These data better demonstrate that the ore-forming fluids were mainly derived from metamorphic water and magmatic hot fluid, in relation to the metamorphism of the Kunyang Group in the basement and magmatic hydrothermalism. The deposit itself might have resulted from ascending cycles of ore-forming fluid, enriched in Pb and Zn. The Huize Zn-Pb- (Ag-Ge) deposits related to carbonate-hosted Zn-Pb sulphides. 展开更多
关键词 Fluid geochemistry fluid inclusion hydrogen oxygen and carbon isotopes Huize zn-pb-(Ag-Ge) district YUNNAN China
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Trace Elements in Sphalerite from the Dadongla Zn-Pb Deposit, Western Hunan-Eastern Guizhou Zn-Pb Metallogenic Belt, South China 被引量:5
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作者 HU Yusi YE Lin +3 位作者 WEI Chen LI Zhenli HUANG Zhilong WANG Haoyu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第6期2152-2164,共13页
The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb dep... The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb deposits in the region and has estimated resources more than 12 million metric tons(Mt)with an average grade of 4.11 wt%Zn+Pb.Its orebodies are hosted in the lower Cambrian Aoxi Formation dolomite,occurring as bedded,para-bedded in shape,and in conformity with the wall rock.The ore mineral assemblage is simple,dominated by sphalerite with minor pyrite and galena,and the gangue minerals are composed of dolomite,calcite with minor bitumen and barite.In view of the lack of geological and geochemical researches,the genesis of Zn-Pb ore is still unclear.Laser ablation-inductively coupled plasma mass spectrometry(LA-ICPMS)spot and mapping analyses were used to obtain sphalerite trace element chemistry in the Dadongla Zn-Pb deposit in Guizhou,China,aiming to constrain its ore genesis.The results show that sphalerite is characterized by the enrichment of Cd,Fe,Ge and Hg,corresponding with that of typical MVT deposits.Four zones were identified in the sphalerite crystal from Dadongla from the center to margin according to the color bands.in which the zone in the center,representing the early ore-stage sphalerite,is characterized by enrichment of Cd relatively,while the zone forming at late ore-stage is enriched in Ge and Hg relatively.The finding was controlled by differential leached metals content in ore-forming fluid from its source rock.Notably,critical element Ge trends to be enriched at the late ore-stage and follows a substitution of 2 Zn^2+(?)Ge^4++□(vacancy).Moreover,the calculated ore-forming temperature ranges from 79.9℃to 177.6℃by the empirical formula,which is similar to that of typical Mississippi Valley-type(MVT)deposits.Compared with the features of trace elements in sphalerite from different types of deposits,together with the geology,the Dadongla deposit belongs to an MVT Zn-Pb deposit. 展开更多
关键词 trace elements SPHALERITE LA-ICPMS MVT deposit Western Hunan-Eastern Guizhou zn-pb metallogenic belt
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基于Itrax岩芯扫描仪的岩石磁化率与Zn-Pb矿化关系研究
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作者 李煜 左仁广 白音 《矿物学报》 CAS CSCD 北大核心 2013年第S2期793-793,共1页
研究磁化率与元素含量的关系一直是环境评价和资源勘查的研究热点。近年来国内外学者做了很多研究,如Spiteri等(2005)研究了德国东部Lausitz地区表层土壤与重金属分布的关系,表明磁化率可作为土壤重金属污染的替代指标;王磊等(2009)研... 研究磁化率与元素含量的关系一直是环境评价和资源勘查的研究热点。近年来国内外学者做了很多研究,如Spiteri等(2005)研究了德国东部Lausitz地区表层土壤与重金属分布的关系,表明磁化率可作为土壤重金属污染的替代指标;王磊等(2009)研究智利某地区不同岩石磁化率的特征,探讨了岩石磁化率对寻找铁氧化物铜金型矿床的指示作用;曹烨等(2007) 展开更多
关键词 岩石磁化率 Itrax zn-pb 蚀变岩 重金属分布 指示作用 铜金 替代指标 金顶铅锌矿 德国东部
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The multistage genesis of the giant Dongshengmiao Zn-Pb-Cu deposit in western Inner Mongolia,China:Syngenetic stratabound mineralization and metamorphic remobilization 被引量:3
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作者 Richen Zhong Wenbo Li 《Geoscience Frontiers》 SCIE CAS CSCD 2016年第3期529-542,共14页
The genesis of the giant Dongshengmiao in the northern margin of the North China Block has been debated since its discovery in the 1950 s,because it shows geological and geochemical characteristics with both syngeneti... The genesis of the giant Dongshengmiao in the northern margin of the North China Block has been debated since its discovery in the 1950 s,because it shows geological and geochemical characteristics with both syngenetic and epigenetic signatures.It has geological settings and sulfur and lead isotopic compositions that are similar with typical SEDEX(sedimentary exhalative) deposit,while the Zn-Pb-Cu mineralization was controlled by shear deformation and metamorphism,showing similarities with orogenic-type deposits.In this contribution,both the syngenetic and epigenetic features of the Dongshengmiao are envisaged,and accounted for in the context of a genetic model with two metallogenic periods.Massive pyrite at the Dongshengmiao was mostly recrystallized during metamorphism,but finegrained texture was locally preserved,indicating its syngenetic origin.On the contrary,all the Zn-Pb-Cu ores observed in this study show characteristics of epigenetic hydrothermal mineralization that controlled by metamorphism and accompanying shear deformation.The sulfur and lead isotopic compositions of sphalerite and galena indicate that they were in situ remobilized from a syngenetic stratabound source,and the oxygen and hydrogen isotopic ratios of ore-fluid indicate that the large-scale remobilization was assisted by metamorphic fluid.The thermodynamic modeling indicates that the orefluid during remobilization has a great potential of transporting Cu.This may account for the abnormally enriched Cu in the remobilized SEDEX deposit.The metamorphic fluid might strip Cu from the fluid source during devolatilization,and overprint it on the Zn-Pb orebodies during remobilization.A secondary flowthrough modeling reveals that Zn- and Cu-sulfides would be preferentially redistributed in Fe-rich carbonates during remobilization,as a result of fluid-rock interaction.Conclusively,a multistage genetic model is proposed.During the development of the Proterozoic rift,stratabound Zn-Pb mineralization took place in a SEDEX ore-forming system.The syngenetic sulfides subsequently underwent a large-scale fluidassisted remobilization during the early Cretaceous metamorphism and thrusting,forming the shear zone-controlled epigenetic orebodies.During the remobilization process,Cu was scavenged from the source of metamorphic fluid,and deposited accompanying remobilized Zn-Pb sulfides.Shear structures and Fe-rich carbonates are ideal sites for redistribution and re-deposition of remobilized sulfide. 展开更多
关键词 SEDEX zn-pb-Cu Metamorphism REMOBILIZATION Orogenic-type deposit
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Kinetics of Evaporation of Zn and Pb from Carbon-bearing Pellets Made of Dust Containing Zn-Pb-Fe Oxides 被引量:2
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作者 Weiqing Chen, Dongyan Wang, Rongzhang Zhou, Zongcai Lin (Metallurgy School, University of Science and Technology Beijing, Beijing 100083, China) 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2000年第3期178-183,共6页
The influence of reduction temperature, size of coal powder and the carbon content on the evaporation rates of Zn and Pb in pellets made of ZnO-PbO-FeO bearing dust has been investigated between 1100-1300℃. The evapo... The influence of reduction temperature, size of coal powder and the carbon content on the evaporation rates of Zn and Pb in pellets made of ZnO-PbO-FeO bearing dust has been investigated between 1100-1300℃. The evaporation rate of Zn and Pb obtained from the experiments has been analyzed with kinetic models. The results show that the control step for evaporation of Zn is reduction reaction of ZnO by CO at the interface,and that the evaporation rate of Pb is controlled by the volatilization of reduction products, i.e. liquid lead. The overall apparent activation energies of Zn and Pb evaporation from the pellet are 79.42kJ/mol and 88.74kJ/mol respectively. 展开更多
关键词 zn-pb-bearing dust carbon-containing pellet evaporation kinetics
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Metallogenic Regularities and Deposit Type of Rich(Ge-Ag)-Zn-Pb Deposits in the Sichuan-Yunnan-Guizhou Triangle(SYGT)Area,China 被引量:1
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作者 HAN RunSheng WANG Feng +2 位作者 ZHANG Yan ZHOU Gaoming HE Jiaojiao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期208-209,共2页
1 Introduction The well-known1 Sichuan-Yunnan-Guizhou Triangle(SYGT)area of poly-metallic Zn-Pb deposits,southwest China is located at the south-western margin of the Yangtze Block in the transition area of the Tethys... 1 Introduction The well-known1 Sichuan-Yunnan-Guizhou Triangle(SYGT)area of poly-metallic Zn-Pb deposits,southwest China is located at the south-western margin of the Yangtze Block in the transition area of the Tethys Belt and the Circum-Pacific Metallogenic Belt,and is composed of the Northeastern Yunnan,Northwestern 展开更多
关键词 SYGT Pb zn-pb Deposits in the Sichuan-Yunnan-Guizhou Triangle AG
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Relationship Between Organic Matters and Zn-Pb Mineralization in the Giant Jinding Zn-Pb Deposit,SW China
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作者 Yongbao Gao,Chunji Xue,Jiangwei Zhang 1.Xi’an Center,China Geological Survey,Xi’an 710054,China. 2.State Key Laboratory of Geological Processes and Mineral Resources,Faculty of Earth Sciences and Resources, China University of Geosciences(Beijing),Beijing 100083,China 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期163-163,共1页
The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and he... The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and heavy-oil,hydrocarbon gas, bitumen of different occurrences and maturation,have been observed in recent underground and open pit mining.Oil-gas traces and oil-and methane-in- 展开更多
关键词 organic matter FORMER oil-gas reservoir hydrogen sulfide JINDING zn-pb deposit SW China
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Metallogenic Processes:Evidencesfrom Zoning Patterns of Mineralization and alteration and fluid inclusion geochemistryin the Lehong Zn-Pb Deposit in Northeastern Yunnan, China
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作者 ZHAO dong HAN Runshen +4 位作者 REN Tao WANG Jiasheng ZHANG Xiao-pei WU Yongtao CUI Junhao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期251-252,共2页
1 Introduction The large clusters of Zn-Pb deposits in northeastern Yunnan,located in the southwestern margin of the Yangtze Block,are an important part of the Sichuan-YunnanGuizhou Pb-Zn Poly-metallic Metallogenic Tr... 1 Introduction The large clusters of Zn-Pb deposits in northeastern Yunnan,located in the southwestern margin of the Yangtze Block,are an important part of the Sichuan-YunnanGuizhou Pb-Zn Poly-metallic Metallogenic Triangle Area 展开更多
关键词 In Pb Metallogenic Processes:Evidencesfrom Zoning Patterns of Mineralization and alteration and fluid inclusion geochemistryin the Lehong zn-pb Deposit in Northeastern Yunnan China Zn
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Ore-controlling Regularities of Thrust-fold structures and features of Tectono-geochemical Anomalies at the Xiaozhuqing Exploration Area in the Huize Zn-Pb District
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作者 Gong Hongsheng Han Runsheng +2 位作者 Li Ziteng Ren Tao Wang Jiasheng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期202-203,共2页
1 Introduction The huize Zn-Pb ore district in Yunnan province is locatedinthecentralsouthernofthe Sichuan—Yunnan—GuizhouPb-ZnPoly-metallic Mineralization Area in the southwestern margin of the Yangtze Block,and is ... 1 Introduction The huize Zn-Pb ore district in Yunnan province is locatedinthecentralsouthernofthe Sichuan—Yunnan—GuizhouPb-ZnPoly-metallic Mineralization Area in the southwestern margin of the Yangtze Block,and is strictly controlled by fault structures.It has developed to one of the famous production bases of lead&zinc and germanium in China. 展开更多
关键词 PB Ore-controlling Regularities of Thrust-fold structures and features of Tectono-geochemical Anomalies at the Xiaozhuqing Exploration Area in the Huize zn-pb District Zn
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Co-Cu-Zn-Pb-Ni-Cl-H_2O体系的热力学分析 被引量:1
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作者 郭万根 石玉臣 +3 位作者 王含渊 张吉贵 黄蕴成 许新启 《有色金属(冶炼部分)》 CAS 北大核心 2011年第9期5-8,32,共5页
根据配位化学热力学平衡原理,通过热力学平衡计算绘制出了298.15 K时钴电解液体系中5种金属离子(Co2+、Cu2+、Zn2+、Pb2+、Ni2+)及其配离子的c-lg c[Cl]T图和c-pH图。热力学计算显示,pH为2.5时钴电解液中铅、锌主要以配合阴离子形式存在... 根据配位化学热力学平衡原理,通过热力学平衡计算绘制出了298.15 K时钴电解液体系中5种金属离子(Co2+、Cu2+、Zn2+、Pb2+、Ni2+)及其配离子的c-lg c[Cl]T图和c-pH图。热力学计算显示,pH为2.5时钴电解液中铅、锌主要以配合阴离子形式存在,钴、铜、镍主要以阳离子形式存在,可以采用阴离子树脂交换法将微量铅、锌与钴、铜、镍有效分离。对所绘的热力学平衡图分析表明,高浓度氯离子有利于与金属形成配合离子,提高铅锌的配合阴离子含量,有利于阴离子树脂交换除铅、锌。 展开更多
关键词 钴电解液 Co-Cu-Ni-Pb-Zn-Cl-H2O系 热力学分析
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豫西熊耳山蒿坪沟Ag-Au-Pb-Zn多金属矿床闪锌矿矿物学和微量元素组成特征及其成矿启示 被引量:1
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作者 刘金波 张德贤 +2 位作者 胡子奇 陈绍炜 谢小雨 《现代地质》 CAS CSCD 北大核心 2024年第1期198-213,共16页
蒿坪沟银金铅锌多金属矿床是豫西熊耳山地区重要的铅锌多金属矿床之一,矿体主要赋存在蚀变破碎带和断裂带内,成矿与区内岩浆活动关系密切。目前该矿床的研究集中于同位素地球化学、成矿时代和成矿物质来源等方面,但从矿物角度示踪成矿... 蒿坪沟银金铅锌多金属矿床是豫西熊耳山地区重要的铅锌多金属矿床之一,矿体主要赋存在蚀变破碎带和断裂带内,成矿与区内岩浆活动关系密切。目前该矿床的研究集中于同位素地球化学、成矿时代和成矿物质来源等方面,但从矿物角度示踪成矿过程的报道较少。本文以矿石中不同世代闪锌矿为研究对象,开展电子探针和LA-ICP-MS原位主微量元素分析,查明不同世代闪锌矿的矿物学和微量元素组成特征,以反演矿床成矿物理化学条件进而约束矿床成因类型。结果表明,该矿床中闪锌矿主要存在两个世代:第一世代闪锌矿(Sp1)呈黑褐色或浅褐色,常与黄铁矿和黄铜矿共生,相对富集Fe、Mn、Cd、Cu和In;第二世代闪锌矿(Sp2)呈黄褐色或暗褐色,与大量方铅矿共生,裂隙被它形黄铁矿和碳酸盐充填,相对富集Co、Ge、Sn和Pb。闪锌矿中主要富集的元素为Fe、Co和In,其中Fe、Mn、Cd、Co和In等元素基本是以类质同象的形式赋存在闪锌矿的矿物晶格中,而Ag、Sb、Cu和Pb可能是以子矿物或显微包裹体的形式赋存。此外,Zn/Cd、Zn/Fe和Ga/In比值以及Fe温度计指示闪锌矿形成于中低温(沉淀时流体温度为229~259℃)和低硫逸度(lgƒ(S_(2))=-12.0~-10.1)的环境下,由成矿阶段II(Sp1到成矿阶段Ⅲ(Sp2其成矿温度可能发生了显著变化,结合面扫描分析结果,指示闪锌矿从核部到边缘温度逐渐降低。通过与国内外典型铅锌矿床闪锌矿微量元素特征对比,结合本矿床闪锌矿中低的Ga/In和Ge/In比值及Ge含量的特征,指示蒿坪沟银金铅锌多金属矿床成矿过程有岩浆活动的参与。综合认为蒿坪沟银金铅锌多金属矿床可能属于岩浆期后热液蚀变岩型和脉型矿床。 展开更多
关键词 蒿坪沟银金铅锌多金属矿床 闪锌矿微量元素 LA-ICP-MS 面扫描 矿床成因
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