We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surf...We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.展开更多
The Submerged Floating Tunnel(SFT)relies on a tensioned mooring system for precise positioning.The sudden breakage of a single cable can trigger an immediate alteration in the constraint conditions of the tube,inducin...The Submerged Floating Tunnel(SFT)relies on a tensioned mooring system for precise positioning.The sudden breakage of a single cable can trigger an immediate alteration in the constraint conditions of the tube,inducing a transient heave response within the structure along with a transient increase in cable tension experienced by adjacent cables.In more severe cases,this may even lead to a progressive failure culminating in the global destruction of the SFT.This study used ANSYS/AQWA to establish a numerical model of the entire length SFT for the hydrodynamic response analysis,and conducted a coupled calculation of the dynamic responses of the SFT-mooring line model based on Orca Flex to study the global dynamic responses of the SFT at the moment of cable breakage and the redistribution of cable internal forces.The most unfavorable position for SFT cable breakage was identified,the influence mechanism of cable breakage at different positions on the global dynamic response was revealed,and the progressive chain failure pattern caused by localized cable breakage are also clarified.展开更多
Manganese cobaltite(MnCo_(2)_(4))is a promising electrode material because of its attractive redox chemistry and excellent charge storage capability.Our previous work demonstrated that the octahedrally-coordinated Mn ...Manganese cobaltite(MnCo_(2)_(4))is a promising electrode material because of its attractive redox chemistry and excellent charge storage capability.Our previous work demonstrated that the octahedrally-coordinated Mn are prone to react with the hydroxyl ions in alkaline electrolyte upon electrochemical cycling and separates on the surface of spinel to reconstruct into d-MnO_(2) nanosheets irreversibly,thus results in a change of the reaction mechanism with Kþion intercalation.However,the low capacity has greatly limited its practical application.Herein,we found that the tetrahedrally-coordinated Co_(2) þions were leached when MnCo_(2)_(4) was equilibrated in 1 mol L^(-1) HCl solution,leading to the formation of layered CoOOH on MnCo_(2)_(4) surface which is originated from the covalency competition induced selective breakage of the CoT–O bond in CoT–O–CoO and subsequent rearrangement of free Co_(6) octahedra.The as-formed CoOOH is stable upon cycling in alkaline electrolyte,exhibits conversion reaction mechanism with facile proton diffusion and is free of massive structural evolution,thus enables utilization of the bulk electrode material and realizes enhanced specific capacity as well as facilitated charge transfer and ion diffusion.In general,our work not only offers a feasible approach to deliberate modification of MnCo_(2)_(4)'s surface structure,but also provides an in-depth understanding of its charge storage mechanism,which enables rational design of the spinel oxides with promising charge storage properties.展开更多
The breakage of brittle particulate materials into smaller particles under compressive or impact loads can be modelled as an instantiation of the population balance integro-differential equation.In this paper,the emer...The breakage of brittle particulate materials into smaller particles under compressive or impact loads can be modelled as an instantiation of the population balance integro-differential equation.In this paper,the emerging computational science paradigm of physics-informed neural networks is studied for the first time for solving both linear and nonlinear variants of the governing dynamics.Unlike conventional methods,the proposed neural network provides rapid simulations of arbitrarily high resolution in particle size,predicting values on arbitrarily fine grids without the need for model retraining.The network is assigned a simple multi-head architecture tailored to uphold monotonicity of the modelled cumulative distribution function over particle sizes.The method is theoretically analyzed and validated against analytical results before being applied to real-world data of a batch grinding mill.The agreement between laboratory data and numerical simulation encourages the use of physics-informed neural nets for optimal planning and control of industrial comminution processes.展开更多
The paper proposes a three-scale binary medium-based constitutive model on the basis of the meso structures and micro components to describe the elasto-plastic mechanical behavior of mudstone samples.Based on the brea...The paper proposes a three-scale binary medium-based constitutive model on the basis of the meso structures and micro components to describe the elasto-plastic mechanical behavior of mudstone samples.Based on the breakage mechanism of geomaterials,mudstone samples are considered as two different materials(bonded and frictional elements)at mesoscales.From micro to meso scales,given the similar but different mineralogy composition and porosity of the bonded and frictional elements at microscale,as well as their separate mechanical characteristics,different homogenization methods are adopted to obtain their respective meso mechanical properties.At the mesoscale,in view of the unique meso structures and the continuous material transformation,the extended self-consistent scheme(SCS)is improved to be adaptable to elasto-plastic composites with varying meso components.With the consideration of the evolution form of the breakage ratio under the external loading being given based on the assumed strength distribution of the meso bonded elements,the mechanical relations between meso and macro scales are established.Finally,on the basis of the mean-field method and combined with the critical mechanical connections between different scales,the micro-meso-macro constitutive model for mudstone samples are proposed.The model validation shows that,with a few model parameters,the proposed model can well reflect the stress and deformation features of mudstone samples with complex micro-components.展开更多
The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical propertie...The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical properties of the Ya’an mudstone samples under triaxial compression conditions were studied,based on an established constitutive model under the framework of breakage mechanics to simulate the mechanical properties of mudstone.Firstly,triaxial compression tests and SEM tests at the confining pressures of 0.5 MPa,1.0 MPa,and 2.0 MPa were carried out on the mudstone samples,and it was found that the mudstone sample undergoes strain softening and dilatancy followed by the volumetric compaction.Then,based on analysis on the breakage mechanism of the above test results,we idealized the mudstone sample as a binary medium material consisting of the bonded elements and frictional elements,of which the bonded elements are composed of solid matrix and pores,and the frictional elements are composed of broken aggregates.During the loading process,the cementation between clay minerals and non-clay minerals in the mudstone sample is first destroyed,leading to the formation of micro-cracks within the particle aggregate,that is,the bonded elements are gradually damaged during the loading process and gradually turned into the frictional elements,and the two jointly bear the external load.The bonded elements are composed of mudstone matrix and pores,which have the cementitious characteristics of mudstone,and the frictional elements are composed of the broken aggregate with the frictional characteristics of the broken particles.Based on the homogenization theory,the constitutive model for the mudstone is established,and the determining method for model parameters is also given.Finally,the results of the triaxial compression tests of the mudstone samples are predicted by the constitutive model proposed here,which can reflect the main mechanical properties of the mudstone samples.展开更多
In this study,more than 1500 particles of lightweight expanded clay aggregate(LECA)are individually loaded up to breakage,following different patterns of contact(from 2 to 7)using a purpose-built apparatus.Consequentl...In this study,more than 1500 particles of lightweight expanded clay aggregate(LECA)are individually loaded up to breakage,following different patterns of contact(from 2 to 7)using a purpose-built apparatus.Consequently,a statistical model for predicting the number of fragments into which a grain breaks as a function of the number of contacts and their diameter is proposed.The number of fragments is found to follow a statistical binomial-type distribution function that depends on the number of contacts.In addition,a model based on Bayesian networks,capable of assessing the number of fragments and their size(measured as normalized weight)as a function of the number of contacts,is implemented.The proposed method is applicable when performing discrete element method(DEM)simulations on granular media in which grain breakage plays a relevant role.展开更多
Particle breakage continuously changes the grading of granular materials and has a significant effect on their mechanical behaviors.Revealing the evolution pattern of particle breakage is valuable for development and ...Particle breakage continuously changes the grading of granular materials and has a significant effect on their mechanical behaviors.Revealing the evolution pattern of particle breakage is valuable for development and validation of constitutive models for crushable materials.A series of parallel triaxial compression tests along the same loading paths but stopped at different axial strains were conducted on two coral sands with different particle sizes under drained and undrained conditions.The tested specimens were carefully sieved to investigate the intermediate accumulation of particle breakage during the loading process.The test results showed that under both drained and undrained conditions,particle breakage increases continuously with increasing axial strain but exhibits different accumulating patterns,and higher confining pressures lead to greater particle breakage.Based on the test results,the correlations between particle breakage and the stress state as well as the input energy were examined.The results demonstrated that either the stress state or input energy alone is inadequate for describing the intermediate process of particle breakage evolution.Then,based on experimental observation,a path-dependent model was proposed for particle breakage evolution,which was formulated in an incremental form and reasonably considers the effects of the past breakage history and current stress state on the breakage rate.The path-dependent model successfully reproduced the development of particle breakage during undrained triaxial compression using the parameters calibrated from the drained tests,preliminarily demonstrating its effectiveness for different stress paths.展开更多
Understanding the mechanisms of the breakage of ore particles is important to predict the particle size distribution in size reduction operations.This paper aims to show the presence of common breakage modes in impact...Understanding the mechanisms of the breakage of ore particles is important to predict the particle size distribution in size reduction operations.This paper aims to show the presence of common breakage modes in impact breakage and ball milling of the cement clinker and chromite samples.For that purpose,narrow size fractions of the two samples were broken in a drop-weight tester or ball mill by changing the degree of applied energy.Then the resultant size distributions were evaluated to seek evidence for the common breakage modes.The results showed that increasing the breakage energy will produce a systematic change in the shapes of the size distributions,suggesting a sequential set of breakage modes.The breakage is initially due to tensile stresses at low breakage energies and compressive stresses at high breakage energies.Further studies should be done to assess if these breakage modes occur at sizereduction of different ores.展开更多
Laboratory tests were carried out to study the breakage kinetics of diasporic bauxite and determine its breakage distribution function. Non-first order breakage with different deceleration rates for different size int...Laboratory tests were carried out to study the breakage kinetics of diasporic bauxite and determine its breakage distribution function. Non-first order breakage with different deceleration rates for different size intervals is found, which is most probably caused by the heterogeneity of the ore. Piecewise linearization method is proposed to describe the non-first order breakage according to its characteristics. In the method, grinding time is divided into several intervals and breakage is assumed to be first order in each interval. So, the breakage rates are calculated by taking the product of the last interval as feed and then established as a function of particle size and grinding time. Based on the predetermined breakage rate function, the breakage distribution of the ore is back-calculated from the experimental data using the population balance model (PBM). Finally, the obtained breakage parameters are validated and the simulated data are in good agreement with the experimental data. The obtained breakage distribution and the method for breakage rate description are both significant for modeling the full scale ball milling process of bauxite.展开更多
This paper presents particle breakage and the mobilized drained shear strengths of sand with the purpose of clarifying the influence of particle breakage on the mobilized shear strengths of sand. Several drained triax...This paper presents particle breakage and the mobilized drained shear strengths of sand with the purpose of clarifying the influence of particle breakage on the mobilized shear strengths of sand. Several drained triaxial tests were carried out on Silica sand No.5 under 3 MPa confining pressure to produce the pre-crushed sands in simulating the high- pressure shear process on soil to result in particle breakage, and then the pre-crushed sands were re- sheared in series of drained triaxial tests to investigate the mobilized strengths of the pre-crushed sands in detecting the influence of particle breakage. It was found that, by deteriorating strain-stress behavior, particle breakage resulted in change of stress-dilataney behavior in translation and rotation of the relation of the dilatancy factor and the effective principal stress ratio. For a given initial void ratio, particle breakage resulted in impairment of dilatancy behavior of soil to be more contractive in deterioration of the mobilized friction angle and the mobilized dilatancy angle and reduction of void ratio. However, particle breakage resulted in increase of the mobilized basic friction angle especially before failure. In addition, the influence of particle breakage on the mobilized strengths was revealed to be influenced by the shear stress-strain state.展开更多
Based on the research on rock burst phenomenon induced by the breakage of thick and hard roof around roadways and working faces in coal mines, a criterion of rock burst induced by roof breakage (RBRB) was proposed a...Based on the research on rock burst phenomenon induced by the breakage of thick and hard roof around roadways and working faces in coal mines, a criterion of rock burst induced by roof breakage (RBRB) was proposed and the model was built. Through the model, a method calculating the varied stresses induced by roof breakage in support objects and coal body was proposed and a unified formula was derived for the calculation of stress increment on support objects and coal body under different breaking forms of roof. Whilst the formula for calculating dynamic load was derived by introducing dynamic index Kd. The formula was verified in Huating Mine by stress measurement. According to the formula for stress increment calculating, the sensitivities of dynamic load parameters were further studied. The results show that the thickness and breaking depth of roof, width of support objeet are the sensitive factors. Based on the discussion of the model, six associated effective methods for rock burst prevention are obtained.展开更多
Coal and gas outburst is a dynamic phenomenon in underground mining engineering that is often accompanied by the throwing and breakage of large amounts of coal.To study the crushing effect and its evolution during out...Coal and gas outburst is a dynamic phenomenon in underground mining engineering that is often accompanied by the throwing and breakage of large amounts of coal.To study the crushing effect and its evolution during outbursts,coal samples with different initial particle sizes were evaluated using a coal and gas outburst testing device.Three basic particle sizes,5–10 mesh,10–40 mesh,and 40–80 mesh,as well as some mixed particle size coal samples were used in tests.The coal particles were pre-compacted at a pressure of 4 MPa before the tests.The vertical ground stress(4 MPa)and the horizontal ground stress(2.4 MPa)were initially simulated by the hydraulic system and maintained throughout.During the tests,the samples were first placed in a vacuum for 3 h,and the coal was filled with gas(CH4)for an adsorption time of approximately 5 h.Finally,the gas valve was shut off and the coal and gas outburst was induced by quickly opening the outburst hole.The coal particles that were thrown out by the outburst test device were collected and screened based on the particle size.The results show the following.(1)Smaller particle sizes have a worse crushing effect than larger sizes.Furthermore,the well-graded coal particles are weakly broken during the outburst process.(2)As the number of repeated tests increases,the relative breakage index grows;however,the increment of growth decreases after each test,showing that further fragmentation becomes increasingly difficult.展开更多
Alternariol caused DNA single-strand breakage. Conversion of the closed circular double-stranded supercoiled DNA (pBR 322) to the nicked circular form and linear form was used to investigate the effect of extracts of ...Alternariol caused DNA single-strand breakage. Conversion of the closed circular double-stranded supercoiled DNA (pBR 322) to the nicked circular form and linear form was used to investigate the effect of extracts of some Chinese medical herbs on DNA nicking induced by alternariol. Some substances in the extracts of Rhizoma polygonati (RP) and Fructus lycii (FL) were shown to protect DNA from the attack by alternariol.Some substance in the RP may bind to plasmid DNA, and this binding reduces the electrophoretic mobility of DNA. These results indicate that substances from FL and RP may be used as DNA protectors. It is possible that they play an important role in preventing cancer.展开更多
Breakage of particles will have greatly influence on mechanical behavior of granular material(GM)under external loads,such as ballast,rockfill and sand.The discrete element method(DEM)is one of the most popular method...Breakage of particles will have greatly influence on mechanical behavior of granular material(GM)under external loads,such as ballast,rockfill and sand.The discrete element method(DEM)is one of the most popular methods for simulating GM as each particle is represented on its own.To study breakage mechanism of particle breakage,a cohesive contact mode is developed based on the GPU accelerated DEM code-Blaze-DEM.A database of the 3D geometry model of rock blocks is established based on the 3D scanning method.And an agglomerate describing the rock block with a series of non-overlapping spherical particles is used to build the DEM numerical model of a railway ballast sample,which is used to the DEM oedometric test to study the particles’breakage characteristics of the sample under external load.Furthermore,to obtain the meso-mechanical parameters used in DEM,a black-analysis method is used based on the laboratory tests of the rock sample.Based on the DEM numerical tests,the particle breakage process and mechanisms of the railway ballast are studied.All results show that the developed code can better used for large scale simulation of the particle breakage analysis of granular material.展开更多
This paper presents a laboratory experimental study on particle breakage of sand subjected to friction and collision,by a number of drum tests on granular materials(silica sand No.3 and ceramic balls)to investigate th...This paper presents a laboratory experimental study on particle breakage of sand subjected to friction and collision,by a number of drum tests on granular materials(silica sand No.3 and ceramic balls)to investigate the characteristics of particle breakage and its effect on the characteristics of grain size distribution of sand.Particle breakage increased in up convexity with increasing duration of drum tests,but increased linearly with increasing number of balls.Particle breakage showed an increase,followed by a decrease while increasing the amount of sand.There may be existence of a characteristic amount of sand causing a maximum particle breakage.Friction tests caused much less particle breakage than collision tests did.Friction and collision resulted in different mechanisms of particle breakage,mainly by abrasion for friction and by splitting for collision.The fines content increased with increasing relative breakage.Particle breakage in the friction tests(abrasion)resulted in a sharper increase but with a smaller total amount of fines content in comparison with that in the collision tests(splitting).For the collision tests,the fines content showed a decrease followed by an increase as the amount of sand increased,whereas it increased in up convexity with increasing number of balls.The characteristic grain sizes D_(10) and D_(30) decreased in down convexity with increasing relative breakage,which could be described by a natural exponential function.However,the characteristic grain sizes D50 and D60 decreased linearly while increasing the relative breakage.In addition,the coefficients of uniformity and curvature of sand showed an increase followed by a decrease while increasing the relative breakage.展开更多
This work focuses on drop breakage for liquid-liquid system with an adoption of numerical simulation by using computational fluid dynamics and population balance model (PBM) coupled with two-fluid model (TFM). Two dif...This work focuses on drop breakage for liquid-liquid system with an adoption of numerical simulation by using computational fluid dynamics and population balance model (PBM) coupled with two-fluid model (TFM). Two different breakage kernels based on identical breakage mechanism but different descriptions of breaking time are take n into account in this work. Eight cases corresp on ding to distinct configurations of agitator are carried out to validate numerical predictions, namely agitators with different porosity and hole diameters, respectively implemented in Cases 1 to 5 and Cases 6 to 8. The results are compared with experimental data for testing the applicability of both kernels. Simulations are implemented, in this work, with an approach of class method for the solution of population balance model by the special-purpose computational fluid dynamics solver Fluent 16.1 based on finite volume method, and the grids used for meshing the solution domain are accomplished in a commercial software Gambit 2.4.6. The effects of configurations of agitator corresponding to different parameters mentioned above on final Sauter mean diameter are equally concentrated in this work. Analysis of both kernels and comparisons with experimental results reveal that, the second kernel has more decent agreement with experiments, and the results of investigations on effects of agitator configurations show that the in fluences of these parameters on Sauter mean diameter are marginal, but appropriate porosity and hole diameter are actually able to decrease Sauter mean diameter. These outcomes allow us to draw general conclusions and help investigate performances of liquid-liquid system.展开更多
Particle breakage is commonly observed in granular materials when subjected to external loads. It was found that particle breakage would occur during both sample preparation and loading stages. However,main attention ...Particle breakage is commonly observed in granular materials when subjected to external loads. It was found that particle breakage would occur during both sample preparation and loading stages. However,main attention was usually paid to the particle breakage behaviour of samples during loading stage. This study attempts to explore the breakage behaviour of granular materials during sample preparation.Triaxial samples of rockfill aggregates are prepared by layered compaction method to achieve different relative densities. Extents of particle breakage based on the gradings before and after test are presented and analysed. It is found that particle breakage during sample preparation cannot be ignored. Gradings after test are observed to shift away from the initial grading. Aggregates with larger size that appear to break are more than the smaller-sized ones. Irrespective of the initial gradings, an increase in the extent of particle breakage with the increasing relative density is observed during sample preparation.展开更多
Particle breakage is a common occurrence in granular systems when the external stress exceeds the individual particle strength.A large number of experimental evidences suggested that particle breakage may significantl...Particle breakage is a common occurrence in granular systems when the external stress exceeds the individual particle strength.A large number of experimental evidences suggested that particle breakage may significantly influence the soil behavior.In the case of pile foundations,the subsoil below the pile tip experiences considerable high stress and consequently prone to break.Due to the lack of sufficient understanding on particle breakage mechanism,there is currently no consentaneous theoretical background for particle breakage analysis during the pile penetration process.This study aims to clarify the location of particle breakage and its evolving characteristics with the aid of acoustic emission(AE)source location method.The spatial distribution of AE hypocenters is interpreted to be associated with the mechanism of particle breakage.Results showed that the AE sources were not uniformly distributed,but concentrated within certain zones below the pile tip.This AE concentration zone was pushed downward with the advancing pile tip,and its distance from the real time pile tip position decreased after certain depth of pile penetration.The location of particle breakage interpreted from AE source location was verified with posttest excavations and the insights on the particle breakage evolution zone were further discussed.展开更多
A liquid-liquid cyclone reactor(LLCR)was designed to achieve mixing-reaction-separation integration during isobutane alkylation catalyzed by ionic liquids.However,studies of the droplets deformation and breakage in th...A liquid-liquid cyclone reactor(LLCR)was designed to achieve mixing-reaction-separation integration during isobutane alkylation catalyzed by ionic liquids.However,studies of the droplets deformation and breakage in the kind of reactors are lacking.In this work,the research studied the velocity distribution,pressure field,and turbulent field to investigate the flow pattern and the main energy loss location in the LLCR through the computational fluid dynamics(CFD)method.The simulation results were verified by experiemnts to prove the correctness of the model.Then the deformation and breakage process of droplets,and the influencing factors of droplets breakage were studied by remodeling which was based on the tangential velocity distribution result of the three dimensional model.The three dimensional simulation results clearly showed that the pressure of the LLCR was mainly concentrated in the cone section and fluid turbulent motion was the most intense near the lateral wall.The reconstruct the results of the two dimensional model clearly showed that the deformation and breakage location of droplets were mainly occurred in the velocity boundary layer,while it was difficult to break in the mainstream region.In addition,low surface tension and high Weber number had a positive effect on droplet breakage.展开更多
基金Supported by Innovation and Technology Fund (No.ITP/045/19AP)Commercial Research&Development (CRD) Funding Supported by Hong Kong Productivity Council (No.10008787)。
文摘We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.
基金financially supported by the National Key Research and Development Program of China(Grant No.2022YFB2602800)Science and Technology Projects of Liaoning Province(Grant No.2023011352-JH1/110)。
文摘The Submerged Floating Tunnel(SFT)relies on a tensioned mooring system for precise positioning.The sudden breakage of a single cable can trigger an immediate alteration in the constraint conditions of the tube,inducing a transient heave response within the structure along with a transient increase in cable tension experienced by adjacent cables.In more severe cases,this may even lead to a progressive failure culminating in the global destruction of the SFT.This study used ANSYS/AQWA to establish a numerical model of the entire length SFT for the hydrodynamic response analysis,and conducted a coupled calculation of the dynamic responses of the SFT-mooring line model based on Orca Flex to study the global dynamic responses of the SFT at the moment of cable breakage and the redistribution of cable internal forces.The most unfavorable position for SFT cable breakage was identified,the influence mechanism of cable breakage at different positions on the global dynamic response was revealed,and the progressive chain failure pattern caused by localized cable breakage are also clarified.
基金supported by the National Key Research and Development Program of China(2022YFE0206300)the National Natural Science Foundation of China(22209047,U21A2081,22075074)+2 种基金Natural Science Foundation of Hunan Province(2020JJ5035)Hunan Provincial Department of Education Outstanding Youth Project(23B0037)Macao Science and Technology Development Fund(Macao SAR,FDCT-0096/2020/A2).
文摘Manganese cobaltite(MnCo_(2)_(4))is a promising electrode material because of its attractive redox chemistry and excellent charge storage capability.Our previous work demonstrated that the octahedrally-coordinated Mn are prone to react with the hydroxyl ions in alkaline electrolyte upon electrochemical cycling and separates on the surface of spinel to reconstruct into d-MnO_(2) nanosheets irreversibly,thus results in a change of the reaction mechanism with Kþion intercalation.However,the low capacity has greatly limited its practical application.Herein,we found that the tetrahedrally-coordinated Co_(2) þions were leached when MnCo_(2)_(4) was equilibrated in 1 mol L^(-1) HCl solution,leading to the formation of layered CoOOH on MnCo_(2)_(4) surface which is originated from the covalency competition induced selective breakage of the CoT–O bond in CoT–O–CoO and subsequent rearrangement of free Co_(6) octahedra.The as-formed CoOOH is stable upon cycling in alkaline electrolyte,exhibits conversion reaction mechanism with facile proton diffusion and is free of massive structural evolution,thus enables utilization of the bulk electrode material and realizes enhanced specific capacity as well as facilitated charge transfer and ion diffusion.In general,our work not only offers a feasible approach to deliberate modification of MnCo_(2)_(4)'s surface structure,but also provides an in-depth understanding of its charge storage mechanism,which enables rational design of the spinel oxides with promising charge storage properties.
基金supported in part by the Ramanujan Fellowship from the Science and Engineering Research Board,Government of India(Grant No.RJF/2022/000115)。
文摘The breakage of brittle particulate materials into smaller particles under compressive or impact loads can be modelled as an instantiation of the population balance integro-differential equation.In this paper,the emerging computational science paradigm of physics-informed neural networks is studied for the first time for solving both linear and nonlinear variants of the governing dynamics.Unlike conventional methods,the proposed neural network provides rapid simulations of arbitrarily high resolution in particle size,predicting values on arbitrarily fine grids without the need for model retraining.The network is assigned a simple multi-head architecture tailored to uphold monotonicity of the modelled cumulative distribution function over particle sizes.The method is theoretically analyzed and validated against analytical results before being applied to real-world data of a batch grinding mill.The agreement between laboratory data and numerical simulation encourages the use of physics-informed neural nets for optimal planning and control of industrial comminution processes.
基金the funding of Highway Planning,Survey and Design Research Institute,Sichuan Provincial Transport Department(No.2020-WX-15)the National Natural Science Foundation of China(NSFC)(No.U22A20596).
文摘The paper proposes a three-scale binary medium-based constitutive model on the basis of the meso structures and micro components to describe the elasto-plastic mechanical behavior of mudstone samples.Based on the breakage mechanism of geomaterials,mudstone samples are considered as two different materials(bonded and frictional elements)at mesoscales.From micro to meso scales,given the similar but different mineralogy composition and porosity of the bonded and frictional elements at microscale,as well as their separate mechanical characteristics,different homogenization methods are adopted to obtain their respective meso mechanical properties.At the mesoscale,in view of the unique meso structures and the continuous material transformation,the extended self-consistent scheme(SCS)is improved to be adaptable to elasto-plastic composites with varying meso components.With the consideration of the evolution form of the breakage ratio under the external loading being given based on the assumed strength distribution of the meso bonded elements,the mechanical relations between meso and macro scales are established.Finally,on the basis of the mean-field method and combined with the critical mechanical connections between different scales,the micro-meso-macro constitutive model for mudstone samples are proposed.The model validation shows that,with a few model parameters,the proposed model can well reflect the stress and deformation features of mudstone samples with complex micro-components.
基金supported by Highway Planning,Survey and Design Research Institute,Sichuan Provincial Transport Department(Grant No.2020WX-15)the funding of National Natural Science Foundation of China(NSFC)(Grant No.U22A20596)。
文摘The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical properties of the Ya’an mudstone samples under triaxial compression conditions were studied,based on an established constitutive model under the framework of breakage mechanics to simulate the mechanical properties of mudstone.Firstly,triaxial compression tests and SEM tests at the confining pressures of 0.5 MPa,1.0 MPa,and 2.0 MPa were carried out on the mudstone samples,and it was found that the mudstone sample undergoes strain softening and dilatancy followed by the volumetric compaction.Then,based on analysis on the breakage mechanism of the above test results,we idealized the mudstone sample as a binary medium material consisting of the bonded elements and frictional elements,of which the bonded elements are composed of solid matrix and pores,and the frictional elements are composed of broken aggregates.During the loading process,the cementation between clay minerals and non-clay minerals in the mudstone sample is first destroyed,leading to the formation of micro-cracks within the particle aggregate,that is,the bonded elements are gradually damaged during the loading process and gradually turned into the frictional elements,and the two jointly bear the external load.The bonded elements are composed of mudstone matrix and pores,which have the cementitious characteristics of mudstone,and the frictional elements are composed of the broken aggregate with the frictional characteristics of the broken particles.Based on the homogenization theory,the constitutive model for the mudstone is established,and the determining method for model parameters is also given.Finally,the results of the triaxial compression tests of the mudstone samples are predicted by the constitutive model proposed here,which can reflect the main mechanical properties of the mudstone samples.
文摘In this study,more than 1500 particles of lightweight expanded clay aggregate(LECA)are individually loaded up to breakage,following different patterns of contact(from 2 to 7)using a purpose-built apparatus.Consequently,a statistical model for predicting the number of fragments into which a grain breaks as a function of the number of contacts and their diameter is proposed.The number of fragments is found to follow a statistical binomial-type distribution function that depends on the number of contacts.In addition,a model based on Bayesian networks,capable of assessing the number of fragments and their size(measured as normalized weight)as a function of the number of contacts,is implemented.The proposed method is applicable when performing discrete element method(DEM)simulations on granular media in which grain breakage plays a relevant role.
基金This research was supported by the National Natural Science Foundation of China(Grant Nos.51679016 and 52079012).
文摘Particle breakage continuously changes the grading of granular materials and has a significant effect on their mechanical behaviors.Revealing the evolution pattern of particle breakage is valuable for development and validation of constitutive models for crushable materials.A series of parallel triaxial compression tests along the same loading paths but stopped at different axial strains were conducted on two coral sands with different particle sizes under drained and undrained conditions.The tested specimens were carefully sieved to investigate the intermediate accumulation of particle breakage during the loading process.The test results showed that under both drained and undrained conditions,particle breakage increases continuously with increasing axial strain but exhibits different accumulating patterns,and higher confining pressures lead to greater particle breakage.Based on the test results,the correlations between particle breakage and the stress state as well as the input energy were examined.The results demonstrated that either the stress state or input energy alone is inadequate for describing the intermediate process of particle breakage evolution.Then,based on experimental observation,a path-dependent model was proposed for particle breakage evolution,which was formulated in an incremental form and reasonably considers the effects of the past breakage history and current stress state on the breakage rate.The path-dependent model successfully reproduced the development of particle breakage during undrained triaxial compression using the parameters calibrated from the drained tests,preliminarily demonstrating its effectiveness for different stress paths.
文摘Understanding the mechanisms of the breakage of ore particles is important to predict the particle size distribution in size reduction operations.This paper aims to show the presence of common breakage modes in impact breakage and ball milling of the cement clinker and chromite samples.For that purpose,narrow size fractions of the two samples were broken in a drop-weight tester or ball mill by changing the degree of applied energy.Then the resultant size distributions were evaluated to seek evidence for the common breakage modes.The results showed that increasing the breakage energy will produce a systematic change in the shapes of the size distributions,suggesting a sequential set of breakage modes.The breakage is initially due to tensile stresses at low breakage energies and compressive stresses at high breakage energies.Further studies should be done to assess if these breakage modes occur at sizereduction of different ores.
基金Supported by the Fundamental Research Funds for the Central Universities (2012QNZT069)the Postdoctoral Science Foundation of China (2012M521413)+1 种基金the National Science Fund for Distinguished Young Scholars of China (61025015)the National Natural Science Foundation of China (61273187, 61273159)
文摘Laboratory tests were carried out to study the breakage kinetics of diasporic bauxite and determine its breakage distribution function. Non-first order breakage with different deceleration rates for different size intervals is found, which is most probably caused by the heterogeneity of the ore. Piecewise linearization method is proposed to describe the non-first order breakage according to its characteristics. In the method, grinding time is divided into several intervals and breakage is assumed to be first order in each interval. So, the breakage rates are calculated by taking the product of the last interval as feed and then established as a function of particle size and grinding time. Based on the predetermined breakage rate function, the breakage distribution of the ore is back-calculated from the experimental data using the population balance model (PBM). Finally, the obtained breakage parameters are validated and the simulated data are in good agreement with the experimental data. The obtained breakage distribution and the method for breakage rate description are both significant for modeling the full scale ball milling process of bauxite.
基金The financial assistance by China Scholarship Council (Grant No. 2011671035)the National Basic Research Program of China (973 Program) (Grant No. 2013CB733201)+3 种基金Key Program of Chinese Academy of Sciences (Grant No. KZZDEW-05-01)One-Hundred Talents Program of Chinese Academy of Sciences (SU Li-jun)CAS "Light of West China" Program (Grant No. Y6R2250250)Youth Fund of Institute of Mountain Hazards and Environment, Chinese Academy of Sciences (Grant No. Y6K2110110)
文摘This paper presents particle breakage and the mobilized drained shear strengths of sand with the purpose of clarifying the influence of particle breakage on the mobilized shear strengths of sand. Several drained triaxial tests were carried out on Silica sand No.5 under 3 MPa confining pressure to produce the pre-crushed sands in simulating the high- pressure shear process on soil to result in particle breakage, and then the pre-crushed sands were re- sheared in series of drained triaxial tests to investigate the mobilized strengths of the pre-crushed sands in detecting the influence of particle breakage. It was found that, by deteriorating strain-stress behavior, particle breakage resulted in change of stress-dilataney behavior in translation and rotation of the relation of the dilatancy factor and the effective principal stress ratio. For a given initial void ratio, particle breakage resulted in impairment of dilatancy behavior of soil to be more contractive in deterioration of the mobilized friction angle and the mobilized dilatancy angle and reduction of void ratio. However, particle breakage resulted in increase of the mobilized basic friction angle especially before failure. In addition, the influence of particle breakage on the mobilized strengths was revealed to be influenced by the shear stress-strain state.
基金Project(2010CB226805) supported by the National Basic Research Program of ChinaProjects(30370412,30670558) supported by the National Natural Science Foundation of ChinaProject(SKLCRSM10X05) supported by the Self-research Program of the Key Laboratory of Coal Resources and Safe Mining,China
文摘Based on the research on rock burst phenomenon induced by the breakage of thick and hard roof around roadways and working faces in coal mines, a criterion of rock burst induced by roof breakage (RBRB) was proposed and the model was built. Through the model, a method calculating the varied stresses induced by roof breakage in support objects and coal body was proposed and a unified formula was derived for the calculation of stress increment on support objects and coal body under different breaking forms of roof. Whilst the formula for calculating dynamic load was derived by introducing dynamic index Kd. The formula was verified in Huating Mine by stress measurement. According to the formula for stress increment calculating, the sensitivities of dynamic load parameters were further studied. The results show that the thickness and breaking depth of roof, width of support objeet are the sensitive factors. Based on the discussion of the model, six associated effective methods for rock burst prevention are obtained.
基金This research was financially supported by the National Natural Science Foundation of China(No.51434003)the Project of the Ministry of Emergency Management of the People's Republic of China(sichuan-0011-2018AQ)the Department of Science and Technology of Sichuan Province(19YYJC2854).
文摘Coal and gas outburst is a dynamic phenomenon in underground mining engineering that is often accompanied by the throwing and breakage of large amounts of coal.To study the crushing effect and its evolution during outbursts,coal samples with different initial particle sizes were evaluated using a coal and gas outburst testing device.Three basic particle sizes,5–10 mesh,10–40 mesh,and 40–80 mesh,as well as some mixed particle size coal samples were used in tests.The coal particles were pre-compacted at a pressure of 4 MPa before the tests.The vertical ground stress(4 MPa)and the horizontal ground stress(2.4 MPa)were initially simulated by the hydraulic system and maintained throughout.During the tests,the samples were first placed in a vacuum for 3 h,and the coal was filled with gas(CH4)for an adsorption time of approximately 5 h.Finally,the gas valve was shut off and the coal and gas outburst was induced by quickly opening the outburst hole.The coal particles that were thrown out by the outburst test device were collected and screened based on the particle size.The results show the following.(1)Smaller particle sizes have a worse crushing effect than larger sizes.Furthermore,the well-graded coal particles are weakly broken during the outburst process.(2)As the number of repeated tests increases,the relative breakage index grows;however,the increment of growth decreases after each test,showing that further fragmentation becomes increasingly difficult.
文摘Alternariol caused DNA single-strand breakage. Conversion of the closed circular double-stranded supercoiled DNA (pBR 322) to the nicked circular form and linear form was used to investigate the effect of extracts of some Chinese medical herbs on DNA nicking induced by alternariol. Some substances in the extracts of Rhizoma polygonati (RP) and Fructus lycii (FL) were shown to protect DNA from the attack by alternariol.Some substance in the RP may bind to plasmid DNA, and this binding reduces the electrophoretic mobility of DNA. These results indicate that substances from FL and RP may be used as DNA protectors. It is possible that they play an important role in preventing cancer.
基金project of “Natural Science Foundation of China, China (Nos. 5187914, 51679123, 51479095)”
文摘Breakage of particles will have greatly influence on mechanical behavior of granular material(GM)under external loads,such as ballast,rockfill and sand.The discrete element method(DEM)is one of the most popular methods for simulating GM as each particle is represented on its own.To study breakage mechanism of particle breakage,a cohesive contact mode is developed based on the GPU accelerated DEM code-Blaze-DEM.A database of the 3D geometry model of rock blocks is established based on the 3D scanning method.And an agglomerate describing the rock block with a series of non-overlapping spherical particles is used to build the DEM numerical model of a railway ballast sample,which is used to the DEM oedometric test to study the particles’breakage characteristics of the sample under external load.Furthermore,to obtain the meso-mechanical parameters used in DEM,a black-analysis method is used based on the laboratory tests of the rock sample.Based on the DEM numerical tests,the particle breakage process and mechanisms of the railway ballast are studied.All results show that the developed code can better used for large scale simulation of the particle breakage analysis of granular material.
基金This work was supported by the National Natural Science Foundation of China(Grant No.41807268)the“Belt&Road”International Cooperation Team for the“Light of West”Program of Chinese Academy of Sciences(Lijun Su),China,the Youth Innovation Promotion Association of Chinese Academy of Sciences,China(Grant No.2018408)China Postdoctoral Science Foundation(Grant No.2019T120864).
文摘This paper presents a laboratory experimental study on particle breakage of sand subjected to friction and collision,by a number of drum tests on granular materials(silica sand No.3 and ceramic balls)to investigate the characteristics of particle breakage and its effect on the characteristics of grain size distribution of sand.Particle breakage increased in up convexity with increasing duration of drum tests,but increased linearly with increasing number of balls.Particle breakage showed an increase,followed by a decrease while increasing the amount of sand.There may be existence of a characteristic amount of sand causing a maximum particle breakage.Friction tests caused much less particle breakage than collision tests did.Friction and collision resulted in different mechanisms of particle breakage,mainly by abrasion for friction and by splitting for collision.The fines content increased with increasing relative breakage.Particle breakage in the friction tests(abrasion)resulted in a sharper increase but with a smaller total amount of fines content in comparison with that in the collision tests(splitting).For the collision tests,the fines content showed a decrease followed by an increase as the amount of sand increased,whereas it increased in up convexity with increasing number of balls.The characteristic grain sizes D_(10) and D_(30) decreased in down convexity with increasing relative breakage,which could be described by a natural exponential function.However,the characteristic grain sizes D50 and D60 decreased linearly while increasing the relative breakage.In addition,the coefficients of uniformity and curvature of sand showed an increase followed by a decrease while increasing the relative breakage.
基金Supported by the National Natural Science Foundation of China(21776180,21306116)
文摘This work focuses on drop breakage for liquid-liquid system with an adoption of numerical simulation by using computational fluid dynamics and population balance model (PBM) coupled with two-fluid model (TFM). Two different breakage kernels based on identical breakage mechanism but different descriptions of breaking time are take n into account in this work. Eight cases corresp on ding to distinct configurations of agitator are carried out to validate numerical predictions, namely agitators with different porosity and hole diameters, respectively implemented in Cases 1 to 5 and Cases 6 to 8. The results are compared with experimental data for testing the applicability of both kernels. Simulations are implemented, in this work, with an approach of class method for the solution of population balance model by the special-purpose computational fluid dynamics solver Fluent 16.1 based on finite volume method, and the grids used for meshing the solution domain are accomplished in a commercial software Gambit 2.4.6. The effects of configurations of agitator corresponding to different parameters mentioned above on final Sauter mean diameter are equally concentrated in this work. Analysis of both kernels and comparisons with experimental results reveal that, the second kernel has more decent agreement with experiments, and the results of investigations on effects of agitator configurations show that the in fluences of these parameters on Sauter mean diameter are marginal, but appropriate porosity and hole diameter are actually able to decrease Sauter mean diameter. These outcomes allow us to draw general conclusions and help investigate performances of liquid-liquid system.
基金supports provided by the Fundamental Research Funds for the Central Universities (Grant No. 2017B05214)
文摘Particle breakage is commonly observed in granular materials when subjected to external loads. It was found that particle breakage would occur during both sample preparation and loading stages. However,main attention was usually paid to the particle breakage behaviour of samples during loading stage. This study attempts to explore the breakage behaviour of granular materials during sample preparation.Triaxial samples of rockfill aggregates are prepared by layered compaction method to achieve different relative densities. Extents of particle breakage based on the gradings before and after test are presented and analysed. It is found that particle breakage during sample preparation cannot be ignored. Gradings after test are observed to shift away from the initial grading. Aggregates with larger size that appear to break are more than the smaller-sized ones. Irrespective of the initial gradings, an increase in the extent of particle breakage with the increasing relative density is observed during sample preparation.
基金sponsored by the Shanghai Sailing Program (Grant No. 18YF1424000)Shanghai Education Commission (Peak Discipline Construction Program, Grant Nos. 0200121005/052 & 2019010206)
文摘Particle breakage is a common occurrence in granular systems when the external stress exceeds the individual particle strength.A large number of experimental evidences suggested that particle breakage may significantly influence the soil behavior.In the case of pile foundations,the subsoil below the pile tip experiences considerable high stress and consequently prone to break.Due to the lack of sufficient understanding on particle breakage mechanism,there is currently no consentaneous theoretical background for particle breakage analysis during the pile penetration process.This study aims to clarify the location of particle breakage and its evolving characteristics with the aid of acoustic emission(AE)source location method.The spatial distribution of AE hypocenters is interpreted to be associated with the mechanism of particle breakage.Results showed that the AE sources were not uniformly distributed,but concentrated within certain zones below the pile tip.This AE concentration zone was pushed downward with the advancing pile tip,and its distance from the real time pile tip position decreased after certain depth of pile penetration.The location of particle breakage interpreted from AE source location was verified with posttest excavations and the insights on the particle breakage evolution zone were further discussed.
基金financial support of the Natural Science Foundation of China(21890763)National Science and Technology Innovation Leading Talents Project of National Ten Thousand People Plan。
文摘A liquid-liquid cyclone reactor(LLCR)was designed to achieve mixing-reaction-separation integration during isobutane alkylation catalyzed by ionic liquids.However,studies of the droplets deformation and breakage in the kind of reactors are lacking.In this work,the research studied the velocity distribution,pressure field,and turbulent field to investigate the flow pattern and the main energy loss location in the LLCR through the computational fluid dynamics(CFD)method.The simulation results were verified by experiemnts to prove the correctness of the model.Then the deformation and breakage process of droplets,and the influencing factors of droplets breakage were studied by remodeling which was based on the tangential velocity distribution result of the three dimensional model.The three dimensional simulation results clearly showed that the pressure of the LLCR was mainly concentrated in the cone section and fluid turbulent motion was the most intense near the lateral wall.The reconstruct the results of the two dimensional model clearly showed that the deformation and breakage location of droplets were mainly occurred in the velocity boundary layer,while it was difficult to break in the mainstream region.In addition,low surface tension and high Weber number had a positive effect on droplet breakage.