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Design and Engineering of Urban Interchange Ramp Bridge Structure
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作者 Yuxiao Zhang Maode Yang 《Journal of Architectural Research and Development》 2024年第2期62-67,共6页
This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural de... This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural design ideas of this urban interchange ramp bridge,which can be used as a reference for future construction of the same bridge. 展开更多
关键词 Interchange ramp bridge structure design Pier structure Foundation structure bridge deck structure
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Technical Analysis of Safety Monitoring and Evaluation of Existing Bridge Structures
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作者 Jiang Feng Qing Yang 《Journal of World Architecture》 2024年第2期17-24,共8页
Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.I... Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.Its goal is to equip relevant organizations and professionals with a deep understanding of the principles and practical applications of these technologies.By doing so,it seeks to facilitate the effective implementation of safety monitoring and assessment practices in bridge management.Ultimately,the aim is to foster the constructive development of road and bridge construction and operational management at a broader level. 展开更多
关键词 bridge structure Safety monitoring Defect diagnosis Theoretical modeling method
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Vector-intensity measure based seismic vulnerability analysis of bridge structures 被引量:8
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作者 Li Zhongxian Li Yang Li Ning 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2014年第4期695-705,共11页
This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measure... This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measures of seismic event. Accounting for the uncertainties of the bridge model, ten single-bent overpass bridge structures are taken as samples statistically using Latin hypercube sampling approach. 200 earthquake records are chosen randomly for the uncertainties of ground motions according to the site condition of the bridges. The uncertainties of structural capacity and seismic demand are evaluated with the ratios of demand to capacity in different damage state. By comparing the relative importance of different intensity measures, Sa(T1) and Sa(T2) are chosen as viM. Then, the vector-valued fragility functions of different bridge components are developed. Finally, the system-level vulnerability of the bridge based on viM is studied with Duunett- Sobel class correlation matrix which can consider the correlation effects of different bridge components. The study indicates that an increment IMs from a scalar IM to viM results in a significant reduction in the dispersion of fragility functions and in the uncertainties in evaluating earthquake risk. The feasibility and validity of the proposed vulnerability analysis method is validated and the bridge is more vulnerable than any components. 展开更多
关键词 bridge structure seismic vulnerability analysis vector-valued intensity measure components' correlation system vulnerability
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Finite Element Model Updating of Bridge Structures Based on Sensitivity Analysis and Optimization Algorithm 被引量:6
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作者 HUANG Minshui ZHU Hongping 《Wuhan University Journal of Natural Sciences》 CAS 2008年第1期87-92,共6页
The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structur... The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structural health condition monitoring. In this paper, a three-dimensional finite-element model is established for a highway bridge over a railway on No.312 National Highway and the ambient test is carried out in site, the dynamic characteristics of the bridge are studied using the finite-element analysis and ambient vibration measurements. Comparison between the theoretical and experimental results shows that the frequency differences of the modes range between 0.44% and 8.77%. If the measurement is more reliable, the finite element model updating is necessary. Thus, a set of design variables is selected based on sensitivity analysis, then the finite element model of the bridge is updated based on optimization algorithm. The results of model updating show that the proposed updating method in this paper is more simple and effective, the updated finite element model can reflect the dynamic characteristics of the bridge better, the analytical results can provide the theoretical basis for damage identification and health condition monitoring of the bridge. 展开更多
关键词 sensitivity analysis optimization algorithm model updating bridge structure
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Research on the Multidimensional Constraint Stability of Bridge Structure Modeling based on Optimization Model
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作者 Cheng kang 《International Journal of Technology Management》 2016年第9期35-37,共3页
In this paper, we conduct research on the multidimensional constraint stability of bridge structure modeling based on the optimization model. The current internal and the external research results to the truss web str... In this paper, we conduct research on the multidimensional constraint stability of bridge structure modeling based on the optimization model. The current internal and the external research results to the truss web structure, the high internode the aspect ratio and the stiffness of the middle truss brace of the truss web, deffection of composite beams of the impact of stress is a very important problem in the design of the bridge. Structural health monitoring is the use of the field of the non-destructive sensing technology, including the structural response, including structural system characteristics analysis, to achieve the purpose of monitoring structural damage or degradation. Under this basis, this paper proposes the new idea on the modelling and simulates the performance. 展开更多
关键词 MULTIDIMENSIONAL Constraint Stability bridge structure Optimization Model.
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Deformation monitoring of long-span railway bridges based on SBAS-InSAR technology
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作者 Lv Zhou Xinyi Li +4 位作者 Yuanjin Pan Jun Ma Cheng Wang Anping Shi Yukai Chen 《Geodesy and Geodynamics》 EI CSCD 2024年第2期122-132,共11页
The deformation monitoring of long-span railway bridges is significant to ensure the safety of human life and property.The interferometric synthetic aperture radar(In SAR)technology has the advantage of high accuracy ... The deformation monitoring of long-span railway bridges is significant to ensure the safety of human life and property.The interferometric synthetic aperture radar(In SAR)technology has the advantage of high accuracy in bridge deformation monitoring.This study monitored the deformation of the Ganjiang Super Bridge based on the small baseline subsets(SBAS)In SAR technology and Sentinel-1A data.We analyzed the deformation results combined with bridge structure,temperature,and riverbed sediment scouring.The results are as follows:(1)The Ganjiang Super Bridge area is stable overall,with deformation rates ranging from-15.6 mm/yr to 10.7 mm/yr(2)The settlement of the Ganjiang Super Bridge deck gradually increases from the bridge tower toward the main span,which conforms to the typical deformation pattern of a cable-stayed bridge.(3)The sediment scouring from the riverbed cause the serious settlement on the bridge’s east side compared with that on the west side.(4)The bridge deformation negatively correlates with temperature,with a faster settlement at a higher temperature and a slow rebound trend at a lower temperature.The study findings can provide scientific data support for the health monitoring of long-span railway bridges. 展开更多
关键词 SBAS-InSAR Long-span railway bridge Deformation monitoring bridge structure Time series deformation
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Structure Bearing Capacity Testing and Evaluation of Existing Bridges
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作者 Huigeng Liu Zonglin Zhou 《Journal of World Architecture》 2023年第1期30-34,共5页
The bearing capacity testing and evaluation of the existing bridge engineering structure is not only the key to clarify its structural quality and safety performance,but it also can lay a solid foundation for subseque... The bearing capacity testing and evaluation of the existing bridge engineering structure is not only the key to clarify its structural quality and safety performance,but it also can lay a solid foundation for subsequent repairs and maintenance work.To ensure the bearing capacity,durability and reliability of existing bridges,this paper analyzes the importance and methods of testing and evaluation of structural bearing capacity of a bridge.This analysis aims to provide scientific reference for the quality assessment and subsequent repair and maintenance of existing bridge engineering structures. 展开更多
关键词 Existing bridge bridge structure Bearing capacity detection Bearing capacity evaluation
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Analysis of Bridge-Bearing Capacity Detection and Evaluation Technology
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作者 Wei Fu Bo Liu 《Journal of World Architecture》 2024年第2期129-133,共5页
A bridge project is taken as an example to analyze the application of bearing capacity detection and evaluation.This article provides a basic overview of the project,the application of bearing capacity detection techn... A bridge project is taken as an example to analyze the application of bearing capacity detection and evaluation.This article provides a basic overview of the project,the application of bearing capacity detection technology,and the bearing capacity assessment analysis.It is hoped that this analysis can provide a scientific reference for the load-bearing capacity detection and evaluation work in bridge engineering projects,thereby achieving a scientific assessment of the overall load-bearing capacity of the bridge engineering structure. 展开更多
关键词 bridge engineering structure Bearing capacity Calculation model Detection points Quantitative standards
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Review and Prospect of Research on Structural Health Monitoring Technology for Bridges
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作者 Guoyi Liu 《Journal of Architectural Research and Development》 2024年第3期156-161,共6页
As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its a... As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its application play an important role in ensuring the safety and extending the service life of bridges.This paper carries out in-depth research and analysis on the related technology of bridge structural health monitoring.Firstly,the existing monitoring technologies at home and abroad are sorted out,and the advantages and problems of various methods are compared and analyzed,including nondestructive testing,stress measurement,vibration characteristic identification,and other commonly used monitoring technologies.Secondly,the key technologies and equipment in the bridge health monitoring system,such as sensor technology,data acquisition,and processing technology,are introduced in detail.Finally,the development trend in the field of bridge health monitoring is prospected from both theoretical research and technical application.In the future,with the development of emerging technologies such as big data,cloud computing,and the Internet of Things,it is expected that bridge health monitoring with intelligent and systematic features will be more widely applied to provide a stronger guarantee for the safe and efficient operation of bridges. 展开更多
关键词 bridge structural health monitoring Safe operation Monitoring technology
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An Analysis of the Dynamic Behavior of Damaged Reinforced Concrete Bridges under Moving Vehicle Loads by Using the Moving Mesh Technique
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作者 Fabrizio Greco Paolo Lonetti +1 位作者 Arturo Pascuzzo Giulia Sansone 《Structural Durability & Health Monitoring》 EI 2023年第6期457-483,共27页
This work proposes a numerical investigation on the effects of damage on the structural response of Reinforced Concrete(RC)bridge structures commonly adopted in highway and railway networks.An effective three-dimensio... This work proposes a numerical investigation on the effects of damage on the structural response of Reinforced Concrete(RC)bridge structures commonly adopted in highway and railway networks.An effective three-dimensional FE-based numerical model is developed to analyze the bridge’s structural response under several damage scenarios,including the effects of moving vehicle loads.In particular,the longitudinal and transversal beams are modeled through solid finite elements,while horizontal slabs are made of shell elements.Damage phenomena are also incorporated in the numerical model according to a smeared approach consistent with Continuum Damage Mechanics(CDM).In such a context,the proposed method utilizes an advanced and efficient computational strategy for reproducing Vehicle-Bridge Interaction(VBI)effects based on a moving mesh technique consistent with the Arbitrary Lagrangian-Eulerian(ALE)formulation.The proposed model adopts a moving mesh interface for tracing the positions of the contact points between the vehicle’s wheels and the bridge slabs.Such modeling strategy avoids using extremely refined discretization for structural members,thus drastically reducing computational efforts.Vibrational analyses in terms of damage scenarios are presented to verify how the presence of damage affects the natural frequencies of the structural system.In addition,a comprehensive investigation regarding the response of the bridge under moving vehicles is developed,also providing results in terms of Dynamic Amplification Factor(DAFs)for typical design bridge variables. 展开更多
关键词 bridge structures moving mesh technique vehicle-bridge interaction dynamics damage mechanics dynamic amplification factors
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Survival Analysis Using Cox Proportional Hazards Regression for Pile Bridge Piles Under Wet Service Conditions
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作者 Naiyi Li Kuang-Yuan Hou +1 位作者 Yunchao Ye Chung C.Fu 《Journal of Architectural Environment & Structural Engineering Research》 2023年第2期45-58,共14页
This paper studies the deterioration of bridge substructures utilizing the Long-Term Bridge Performance(LTBP)Program InfoBridge^(TM)and develops a survival model using Cox proportional hazards regression.The survival ... This paper studies the deterioration of bridge substructures utilizing the Long-Term Bridge Performance(LTBP)Program InfoBridge^(TM)and develops a survival model using Cox proportional hazards regression.The survival anal­ysis is based on the National Bridge Inventory(NBI)dataset.The study calculates the survival rate of reinforced and prestressed concrete piles on bridges under marine conditions over a 29-year span(from 1992 to 2020).The state of Maryland is the primary focus of this study,with data from three neighboring regions,the District of Columbia,Vir­ginia,and Delaware to expand the sample size.The data obtained from the National Bridge Inventory are condensed and filtered to acquire the most relevant information for model development.The Cox proportional hazards regres­sion is applied to the condensed NBI data with six parameters:Age,ADT,ADTT,number of spans,span length,and structural length.Two survival models are generated for the bridge substructures:Reinforced and prestressed concrete piles in Maryland and reinforced and prestressed concrete piles in wet service conditions in the District of Columbia,Maryland,Delaware,and Virginia.Results from the Cox proportional hazards regression are used to construct Markov chains to demonstrate the sequence of the deterioration of bridge substructures.The Markov chains can be used as a tool to assist in the prediction and decision-making for repair,rehabilitation,and replacement of bridge piles.Based on the numerical model,the Pile Assessment Matrix Program(PAM)is developed to facilitate the assessment and main­tenance of current bridge structures.The program integrates the NBI database with the inspection and research reports from various states’department of transportation,to serve as a tool for condition state simulation based on mainte­nance or rehabilitation strategies. 展开更多
关键词 Survival analysis of bridge structures Cox proportional hazards regression bridge rehabilitation and maintenance bridge substructure protection National bridge inventory Simulation of bridge substructure condition state
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Integrity Design Strategy in Steel Structure Bridge Design 被引量:1
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作者 Meng Wan 《Journal of World Architecture》 2021年第4期21-24,共4页
Nowadays,the scope of bridge construction projects in China is becoming wider,which promotes China's economic development to a large extent and also improves China's transportation system.Meanwhile,people also... Nowadays,the scope of bridge construction projects in China is becoming wider,which promotes China's economic development to a large extent and also improves China's transportation system.Meanwhile,people also put forward new requirements for the quality of steel structure bridges.However,in actual design,due to the influence of many fectors,some problems are inevitable,which will affect the integrity of the design.Therefore,the designer needs to fully grasp the possible design problems,and then take efiective measures to improve the integrity of the design scheme,so as to ensure the quality of the steel structure bridge and improves the safety of the steel structure bridge from the fundamentals.This paper mainly focuses on steel structure bridges,analyzed the current status of steel structure bridge types and their selection,and proposes the integrity design strategy of steel structure bridges. 展开更多
关键词 Steel structure bridge INTEGRITY DESIGN
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Identification of Connection Flexibility Effects Based on Load Testing of a Steel-Concrete Bridge
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作者 Czeslaw Machelski Robert Toczkiewicz 《Journal of Civil Engineering and Architecture》 2012年第11期1504-1513,共10页
In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, doe... In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position, which can be used for verification of steel-concrete interaction in real bridge structures rather than in specimens is proposed. The range of the index value changes, obtained during load testing of a typical steel-concrete composite beam bridge, is presented. The investigation was carried out on a motorway viaduct, consisting of two parallel structures. During the testing values of strains in girders under static and quasi-static loads were measured. The readings from the gauges were used to determine the index, characterizing composite action of the girders. Results of bridge testing under movable load, changing position along the bridge span is presented and obtained in-situ influence functions of strains and index values are commented in the paper. 展开更多
关键词 Abstract: In the case of composite girders an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs used commonly in bridge structures does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position which can be used for verification of steel-concrete interaction in real bridge structures rather Composite bridge partial interaction
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Seismic fragility analysis of bridges by relevance vector machine based demand prediction model
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作者 Swarup Ghosh Subrata Chakraborty 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2022年第1期253-268,共16页
A relevance vector machine(RVM)based demand prediction model is explored for efficient seismic fragility analysis(SFA)of a bridge structure.The proposed RVM model integrates both record-to-record variations of ground ... A relevance vector machine(RVM)based demand prediction model is explored for efficient seismic fragility analysis(SFA)of a bridge structure.The proposed RVM model integrates both record-to-record variations of ground motions and uncertainties of parameters characterizing the bridge model.For efficient fragility computation,ground motion intensity is included as an added dimension to the demand prediction model.To incorporate different sources of uncertainty,random realizations of different structural parameters are generated using Latin hypercube sampling technique.Mean fragility,along with its dispersions,is estimated based on the log-normal fragility model for different critical components of a bridge.The effectiveness of the proposed RVM model-based SFA of a bridge structure is elucidated numerically by comparing it with fragility results obtained by the commonly used SFA approaches,while considering the most accurate direct Monte Carlo simulation-based fragility estimates as the benchmark.The proposed RVM model provides a more accurate estimate of fragility than conventional approaches,with significantly less computational effort.In addition,the proposed model provides a measure of uncertainty in fragility estimates by constructing confidence intervals for the fragility curves. 展开更多
关键词 bridge structure seismic fragility analysis seismic demand model relevance vector machine
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Dynamic Response of Structure under Blast Load
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作者 Daniel Makovicka Jr. Daniel Makovicka 《Journal of Civil Engineering and Architecture》 2016年第4期421-429,共9页
The paper follows from the theory of explosion and interaction of an impact wave formed by the explosion and a structure. Firstly, the paper determines the parameters of the blast wave excited by a small charge explos... The paper follows from the theory of explosion and interaction of an impact wave formed by the explosion and a structure. Firstly, the paper determines the parameters of the blast wave excited by a small charge explosion. The empirical formulas on the basis of our own experimental results are shown and used for the structure analysis. Evaluations of structures loaded by an explosion based on dynamic response in rotations round the central line of plate or beam systems during the dynamic load of this type is discussed in the paper and comparison of own limit values and published ones is presented. Blast loads typically produce very high strain rates in the range of 102 to 10-4 s-1. The effect of strain rate for concrete material is discussed. The formulas for increased compressive strength of concrete and steel reinforcement are presented. The ductility of structural members is influenced by the corresponding values under high strain rate of reinforcement, Damage to the structure is assessed accordingly firstly by the angle of rotation of the middle axis/surface, and secondly by the limit internal forces of the selected structure. The extreme nature of blast resistance makes it necessary to accept that structural members have some degree of inelastic response in most cases. This enables the application of structure dissipation using the ductility factor and increased of concrete strength. The limits are correlated with qualitative damage expectations. The methodology of dynamic response assessment and its application to the simple bridge structure is discussed. 展开更多
关键词 Explosion blast wave dynamic load RESPONSE ASSUMPTION bridge structure.
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Synthesis, Characterization and Application of A Novel Carbon Bridged Half-metallocene Chromium Catalyst for Methyl Methacrylate Polymerization 被引量:1
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作者 程正载 GONG Kai +5 位作者 WANG Yang ZHOU Xue ZHANG Weixing LI Yin SUN Junquan LI Wenbing 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第6期1294-1301,共8页
A new carbon bridged cyclopentadienyl chromium complex of the type [(C5H4)C(CH3)2 CH2(C5H4N)]CrCl2 was prepared by treatment of CrCl3·(THF)3 in THF solution with the lithium salt of ligand containing cycl... A new carbon bridged cyclopentadienyl chromium complex of the type [(C5H4)C(CH3)2 CH2(C5H4N)]CrCl2 was prepared by treatment of CrCl3·(THF)3 in THF solution with the lithium salt of ligand containing cyclopentadienyl and pyridyl groups. The chromium complex was characterized by 1H NMR and elemental analysis(EA), and the crystal structure was determined by X-ray diffraction analysis. Activated by Al(i-Bu)3, the chromium complex displayed a very high activity for methyl methacrylate(MMA) polymerization. After 24 hours,more than 95.5% MMA was converted to polymethyl methacrylate(PMMA) with a viscosity average molecular weight(Wη) of 416000 g·mol-1 at 60 ℃ for MMA/ Al(i-Bu)3 /chromium catalyst molar ratio of up to 2000:20:1. Effects of temperature, molar ratios of MMA/catalyst and catalyst/cocatalyst on the polymerization have been studied. The high conversion of MMA and high molecular weight of PMMA with narrow molecular weight distribution is caused by the unique stable active site formed by the new chromium complex and aluminum cocatalyst. 展开更多
关键词 metallocene catalyst carbon bridged half-metallocene chromium crystal structure MMA polymerization PMMA
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The regulation of coordination structure between cobalt and nitrogen on graphene for efficient bifunctional electrocatalysis in Zn-air batteries
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作者 Xinxin Shu Maomao Yang +2 位作者 Miaomiao Liu Wei Pan Jintao Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第5期213-221,共9页
Electrocatalysts with atomically dispersed metal moieties are of importance in enhancing electrocatalysis for a specific reaction including oxygen reduction. However, it is still challenging to modulate the coordinati... Electrocatalysts with atomically dispersed metal moieties are of importance in enhancing electrocatalysis for a specific reaction including oxygen reduction. However, it is still challenging to modulate the coordination structure of metal atoms with heteroatoms on carbon supports. Herein, an innovative and facile bridging strategy to regulate the coordination structure of cobalt with nitrogen atoms on reduced graphene oxide(r GO) sheets was developed by the interfacial complexation of amino-rich folic acid with cobalt ions on graphene oxide sheets and the subsequent thermal treatment. Typically, the actual coordination interaction between cobalt and nitrogen species was revealed by using X-ray absorption spectroscopy(XAS), exhibiting the Co-N_(4) coordination structure well-dispersed on reduced graphene oxide.Such unique structure enables the efficient oxygen reduction and evolution reactions via the favorable adsorption and desorption of intermediates. With the enhanced bifunctional electrocatalytic activities,the fabricated Zn-air battery exhibited the excellent performance with large power density of 319.8 mW cm^(-2) and good long-term stability(over 300 h). This work establishes the synthesis strategy for bridging metal atom with heteroatom on graphene sheets to enhance the bifunctional electrocatalysis toward Zn-air batteries. 展开更多
关键词 Oxygen reduction reaction Synergistic effect Bifunctional electrocatalysis Bridging structure
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Bridge Engineering-Oriented Parametric Model
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作者 周凌远 李乔 《Journal of Southwest Jiaotong University(English Edition)》 2004年第1期61-64,共4页
A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a... A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a software system. This model provides both convenience and flexibility for users in structural modeling process. The object-oriented method is applied in the model implementation. A bridge analysis preprocessor is developed on the basis of this model. It provides an effective way for bridge modeling. 展开更多
关键词 engineering-oriented modeling Parametric CAD bridge structural analysis preprocess Structural modeling Finite element method Structural analysis
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Crystal and Molecular Structure of (μ-FcCO ) (μ-t-BuS )Fe_2(CO)_6
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作者 Liu Jin-Ting(College of Chemistry, Shandong University, Jinan, 250100) 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1995年第4期309-313,共5页
The title complex (μ-FcCO) (μ-t-BuS)Fe_2(CO)_6(Fc=ferrocenoyl)crystallizes in the orthorhombic space group Pbca with a=11.910 (2), b=13. 303(3),c=29. 037(1) A,V=4601(4) A3, M_r= 581. 98, Z= 8, D_x=1.68g/cm3, μ=19. ... The title complex (μ-FcCO) (μ-t-BuS)Fe_2(CO)_6(Fc=ferrocenoyl)crystallizes in the orthorhombic space group Pbca with a=11.910 (2), b=13. 303(3),c=29. 037(1) A,V=4601(4) A3, M_r= 581. 98, Z= 8, D_x=1.68g/cm3, μ=19. 93 cm-1, and F(000)=2352. Refinement by fullmatrix least-squares techniqueshas resulted in residuals of R=0.055 and R_w=0.049, based on 1877 unique reflections. The molecular structure reveals a short distance between metallic centers [Fe(1)-Fe(2)=2.5394 A], indicating the existence of a metalmetal bond. Fe(1) and Fe(2) atoms are bridged by the tbutylthio ligand and the acyl of ferrocenoyl. Fe (1) issurrounded by Fe(2), S, C and three carbonyl carbon atoms to form a distorted octahedron, while Fe (2) is surrounded by Fe(1), S, O and other three carbonyl carbonatoms to form another distorted octahedron. The cyclopentadienyl rings are nearly eclipsed and the π-electron system of the bridged acyl is conjugated with the aromatic cyclopentadenyl ring in the ferrocenoyl moiety. 展开更多
关键词 crystal structure bridging ferrocenoyl iron-sulfur complex
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A STUDY ON THE STRUCTURAL EFFECT OF DOUBLE BRIDGES CONJUGATED SYSTEMS I.CARBONYL-IMINO SYSTEM
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作者 Gui Ying LI cui chen Dai Ming Qian Jiang(M.C.chiang)Institute of chemistry,Academia sinica,Beijing 100080 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第3期197-200,共4页
The struetural effect of the conjugative system(C)with carbonyl-imino bridges has been studied.The results show that:In the conjugated system(C),there is no electronic absorption peak attributable to the whole system,... The struetural effect of the conjugative system(C)with carbonyl-imino bridges has been studied.The results show that:In the conjugated system(C),there is no electronic absorption peak attributable to the whole system,but there are three π-π* bands each nt which displays chacactecistics of its own independently.These indicate that the two bridges-carbonyl-and-imino-can block the tlanSmlSSion of the conjngative polarization of the whole system,so as to form three segments,this is verified by means of chemical synthesis and degradation. 展开更多
关键词 CHO A STUDY ON THE STRUCTURAL EFFECT OF DOUBLE bridgeS CONJUGATED SYSTEMS I.CARBONYL-IMINO SYSTEM CI
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