Study on Dynamics of Calorific Value, Biomass and Energy in Calamagrostis epigejos Population in Songnen Grassland

There were two peaks of seasonal changes of the calorific value in shoot and leaves of Calamagrostis epigejos in middle June and in the early August respectively. The calorific value in stem presented a single peak curve which appeared in the early August. The calorific values in inflorescence and dead standing showed a fluctuation and the peak value of inflorescence was in the early September and that of dead standing was in middle June. The seasonal changes of energy standing crop on the above-ground part synchronized with that of the biomass, which presented a single peak curve. The energy allocated to each organ in different seasons was in the order as leaves > stem > inflorescence in middle June, leaves > stem > dead standing > inflorescence in early July, leaves > stem > inflorescence > dead standing in middle July, and leaves > stem > dead standing > inflorescence from August to September. The vertical allocation of energy in the parts of above-ground was that the energy value gradually increased from the surface to the 20 cm high level and the maximum value at the 10 - 20 cin high level which made up 26.91% of energy on the above-ground partion, and then it was decreased. In the under-ground portion, the energy value progressively decreased with depth and the maximum value was at 0 - 10 cm depth layer which made up 69.01% of energy of the under-ground portion.

Calorific values and ash contents of different parts of Masson pine trees in southern China

Calorific value of plants is an important parameter for evalu- ating and indexing material cycles and energy conversion in forest eco- systems. Based on mensuration data of 150 sample sets, we analyzed the calorific value （CV） and ash content （AC） of different parts of Masson pine （Pinus massoniana） trees in southern China using hypothesis testing and regression analysis. CV and AC of different tree parts were almost significantly different （P〈0.05）. In descending order, ash-free calorific value （AFCV） ranked as foliage 〉 branch 〉 stem bark 〉 root 〉 stem wood, and AC ranked as foliage 〉 stem bark 〉 root 〉 branch 〉 stem wood. CV and AC of stem wood from the top, middle and lower sections of trees differed significantly. CV increased from the top to the lower sections of the tnmk while AC decreased. Mean gross calorific value （GCV） and AFCV of aboveground parts were significantly higher than those of belowground parts （roots）. The mean GCV, AFCV and AC of a whole tree of Masson pine were 21.54 kJ/g, 21.74 kJ/g and 0.90%, re- spectively. CV and AC of different tree parts were, to some extent, cor- related with tree diameter, height and origin.

A novel model for cost performance evaluation of pulverized coal injected into blast furnace based on effective calorific value

The combustion process of pulverized coal injected into blast furnace involves a lot of physical and chemical reactions. Based on the combustion behaviors of pulverized coal, the conception of coal effective calorific value representing the actual thermal energy provided for blast furnace was proposed. A cost performance evaluation model of coal injection was built up for the optimal selection of various kinds of coal based on effective calorific value. The model contains two indicators: coal effective calorific value which has eight sub-indicators and coal injection cost which includes four sub-indicators. In addition, the calculation principle and application of cost performance evaluation model in a Chinese large-scale iron and steel company were comprehensively introduced. The evaluation results finally confirm that this novel model is of great significance to the optimal selection of blast furnace pulverized coal.

Accuracy improvement of quantitative analysis of calorific value of coal by combining support vector machine and partial least square methods in laser-induced breakdown spectroscopy

Laser-induced breakdown spectroscopy(LIBS) is a potential technology for online coal property analysis,but successful quantitative measurement of calorific value using LIBS suffers from relatively low accuracy caused by the matrix effect.To solve this problem,the support vector machine(SVM) and the partial least square(PLS) were combined to increase the measurement accuracy of calorific value in this study.The combination model utilized SVM to classify coal samples into two groups according to their volatile matter contents to reduce the matrix effect,and then applied PLS to establish calibration models for each sample group respectively.The proposed model was applied to the measurement of calorific values of 53 coal samples,showing that the proposed model could greatly increase accuracy of the measurement of calorific values.Compared with the traditional PLS method,the coefficient of determination(R2) was improved from 0.93 to 0.97,the root-mean-square error of prediction was reduced from 1.68 MJ kg-1 to1.08 MJ kg-1,and the average relative error was decreased from 6.7% to 3.93%,showing an overall improvement.

Effect of tree-age on calorific value and other fuel properties of Eucalyptus hybrid

For determining the effect of tree-age on the fuel properties of Eucalyptus hybrid, the variability in basic density, calorific value, proximate and ultimate parameters of 2-6 years old trees and mature trees （20- year-old）, grown under short rotation forestry regime, were measured and analyzed. Results show that there was no significant variation in the basic density of wood for 2-6 year-old Eucalyptus hybrid, with average value of 0.55-0.58 g.cm-3; the calorific value of mature trees was higher than that of lower age trees, but the ash content was much higher in lower age trees compared to mature trees. No particular trend was observed for volatile matter content and the fixed carbon content with tree-age. In conclusion, the fuel properties of mature tree were marginally better than trees of lower age.

Numerical simulation of UCG process with the aim of increasing calorific value of syngas

The determination of operational parameters in the underground coal gasification(UCG)process should be considered in two aspects:first,the total coal in each UCG panel must be gasified and second,the calorific value of the produced gas should be acceptable.The main aim of this study is to present a model that meets these aspects and increasing the calorific value of syngas during this process.In order to achieve those aims,eight different increasing scenarios were devised for total gasification of coal per panel.These scenarios included:increasing oxygen injection rate(scenario 1),the amount of steam injection(scenario 2),operation time(scenario 3),cavity pressure(scenario 4),increase operation time and cavity pressure simultaneously(scenario 5),increase steam injection speed and oxygen injection rate simultaneously(scenario 6),increase in cavity pressure,operating time,steam injection rate and oxygen injection rate simultaneously(scenario 7)and also simultaneous increase in the operating time and steam injection rate(scenario 8).The results showed that for producing syngas with a higher calorific value,the following parameters had the most positive effects respectively:operation time,cavity pressure,steam injection rate and oxygen injection rate.Finally,the model validation was performed for the Centralia LBK-1 UCG pilot and the results showed that this model is very close to reality.

An Experimental Determination of Gross Calorific Value of Different Agroforestry Species and Bio-Based Industry Residues

Solid biomass fuels are useful and cost effective renewable energy source. The energy content of biomass is determined by its calorific value. The objective of this study was to determine experimentally the gross calorific value (GCV) of different agroforestry species and bio-based industry residues that could be used by: a) companies specialized in processing raw biomass solid biofuel production, b) small-scale consumers (households, medium-sized residential buildings, etc.). The fuel samples used were from agricultural residues and wastes (rice husks, apricot kernels, olive pits, sunflower husks, cotton stems, etc.), energy crops and wetland herbs (cardoon, switchgrass, common reed, narrow-leaf cattail), and forest residues (populus, fagus, pinus). The GCV of the bio-mass samples was experimentally determined based on CEN/TS 14918:2005, and an oxygen bomb calorimeter was used (Model C5000 Adiabatic Calorimeter, IKA?-Werke, Staufen, Germany). The GCV of different agroforestry species and residues ranges from 14.3 - 25.4 MJ?kg–1. The highest GCV was obtained by seeds and kernels due to higher unit mass and higher lipid content. Pinus sylvestris with moisture content 24.59% obtained the lowest GCV (13.973 MJ?kg–1).

An Evaluation of the Calorific Values of the Branches and Stems of 11 Tropical Trees

This work investigated and quantified the calorific values of the main branches and trunks of eleven (11) tropical trees in correlation with their chemical composition in order to assess their suitability for use as credible sources of wood fuel. The determination of the carbon, hydrogen, nitrogen, oxygen and sulphur (CHNOS) content of the samples was done using an organic elemental analyser, while an oxygen bomb calorimeter was used to experimentally determine their corresponding gross heat values. The experimental gross heat values for the branches examined ranged from 18,703.37 kJ/kg in Lophira lanceolata to 21,350.35 kJ/kg in Afzelia africana while that of the trunks ranged from 19,747.74 kJ/kg in Tectonia grandis to 22,408.68 kJ/kg in Prosopis africana. These values were within and about the expected ranges observed for tropical trees and may be considered adequate for wood fuel. The general trend in both branches and trunks was that the higher the carbon content, the higher the gross heat value of sample. The absence of sulphur in almost all the samples except, Prosopis africana, (0.055%) was indicative of the fact that the negative environmental impact with respect to harmful emissions of oxides of sulphur is practically non-existent with respect to these species. In the light of the aforementioned variables, the main branches of Afzelia africana (21,350.35 kJ/kg), Nauclea diderrichii (21,157.30 kJ/kg) and Tectonia grandis (20,257.13 kJ/kg) could be used as credible sources of firewood and charcoal production. With respect to the trunks, the timbers in order of preference would ideally be Prosopis africana (22,408.68 kJ/kg), Nauclea diderichii (21,436.42 kJ/kg) and Brachstigia eurychoma (20,924.7 kJ/kg).

Effect of Extractive Removal on the Calorific Value of Brazilian Woods Residues

In wood processing, the production of residues is an unavoidable aspect to be considered. The use of wood residues is gaining importance due to the large amount generated and improper disposal, which can seriously harm environment. Burning of wood residues to energy generation is an increasingly usual practice. However, wood residues hold chemical substances that could be recovered before burning. These substances are the wood extractives, which may have many uses as natural dyes for fabrics, foods and cosmetics, as well as potential medicines. Thus, it is of great interest to study the effect of extractive removal on the calorific value of wood residues. In this work, the calorific value of three Brazilian wood species commonly used in sawmills （hymenaeacourbaril, jatoba; cedrelingacatenaeformis, cedroarana; tabebuiasp, ipe） and residues of urban trees pruning （caesalpiniaechinata, Brazil wood） were evaluated before and after extraction in hot water. In woods studied, the calorific value showed three patterns of behavior after removal of extractives soluble in hot water. For Brazil wood, the removal of extractives caused no significant change in calorific value. For cedroarana and jatoba, extractive removal led to a decrease in wood calorific value of 161.3 kcal.kg1 and 40. l kcal.kg^-1, respectively, which indicates that the extractives from these species have a positive energy potential. Finally, for ipe, the removal of extractives resulted in an increase in calorific value of wood （67.6 kcal.kg^-1）, which might encourage the recovery of extractives from wood residues before burning for energy generation.

Urban Plant Biomass Residues from the Neotropics and Their Potential for Thermal Energy Generation

The material associated with tree pruning in a city in the Colombian neotropics was characterized in order to determine its energy potential.The species studied for their relevance in the territory were Prosopis juliflora,Licania tomentosa,Terminalia catappa,Azadirachta indica,Pithecellobium dulce,Ficus benjamina and Leucaena leucocephala.Moisture content,bulk density,hygroscopic response,elemental chemical analysis,proximal analysis,calorific value,ease of ignition and combustion,thermogravimetric and heat flow analysis,steam generation capacity,and qualitative analysis of gases(mass spectrometry)were determined.The results that were obtained show high initial moisture contents that vary between 37%and 67%and a variable density(when dry)between 0.21 and 0.41 g/cm3.Chemically,it was shown that all residues have lower carbon and sulfur content compared to a reference mineral coal.However,the residues of some species have higher nitrogen contents compared to the same coal.All biomasses are characterized by their high content of volatile fractions and by having a lower content of inorganic matter compared to carbon.The lower calorific values of these residues are between 14170 and 16928 kJ/kg,which are not negligible compared to other biomasses.This characteristic would be related to the high presence of hemicellulose in the residues.Flue gas monitoring revealed that there are different airflow needs in order to ensure complete combustion.Steam generation tests showed that the calorific value should not be the most relevant criterion to establish the potential use of the waste,since leucaena leucocephala,despite having the highest calorific value,was the material with the lowest performance in steam generation.

Fuel properties and combustion characteristics of some promising bamboo species in India

We investigated the fuel characteristics of five important bamboo species viz., Dendrocalamus strictus, D. brandisii, D. stocksii, Bambusa bambos and B. balcooa. The selected species cover more than 85% of the total growing stock of bamboo in India. Basic density varied from 0.48 to 0.78 g.cm-3 among the bamboo species studied. Ash content, volatile matter content and fixed carbon content ranged between 1.4%-3.0%, 77.2%-80.8% and 17.6%-21.1%, respectively. Variation in calorific value （18.7-19.6 MJ-kg-l） was marginal. Fuel value index var- ied widely （586-2120） among bamboo species. The highest calorific value （19.6 MJ.kg＂l） and fuel value index （2120） were found in B. bal- cooa. Ash elemental analysis revealed that silica and potassium are the major ash forming minerals in bamboo biomass. Silica content ranged from 8.7% to 49.0%, while potassium ranged from 20.6% to 69.8%. We studied combustion characteristics under oxidizing atmosphere. Burning profiles of the samples were derived by applying the derivative thermo- gravimetric technique which is discussed in detail. The five bamboo species were different in their combustion behaviour, mainly due to differences in physical and chemical properties. We compare fuel prop- erties, ash elemental analysis and combustion characteristics of bamboo biomass with wood biomass of Eucalyptus hybrid （Eucalyptus tereticor- his × Eucalyptus camaldulensis）.

Demineralization mechanism and influence of parameters on high ash Indian coal by chemical leaching of acid and alkali solution

The current research was investigated the mechanism of coal demineralization and the effect of leaching parameters on high ash coal and study the characterization of pre and post-treated coal. The two high ash Indian coal selected from Mahanadi Coalfield Limited, Odisha, pulverized to 375, 230 and 180 gm particle size were undergone simultaneous acid and alkali treatment at a different concentration, temperature and time. The percent demineralization was increased with decrease the size of the particle and rises with leaching parameters. The investigation suggested 180 μm particle size offers efficient demineralization for both coals at 30% NaOH and 30% H2SO4 concentration. The alkali leaching leads to obtaining the demineralization 46% and 42% whereas acid treatment resulted in 34% and 32% of the original coal samples. The extent of demineralization was improved the calorific value of coal. Besides, the degree of demineralization was proved from the FTIR, XRF and FESEM-EDX analysis results. FTIR analysis result showed that the peak intensity of mineral band decreased by the leaching effect and the degree of demineralization was significantly obtained to large extent by the X-ray Fluorescence spectrometer; which elucidates major minerals removed from coal by the leaching effect of acid and alkali solution.

The use of the white poplar(Populus alba L.)biomass as fuel

We determined the calorific value of white poplar（Populus alba L.） woody biomass to use it as firewood. The value of 19.133 MJ kg-1obtained experimentally shows that the white poplar can be quite successfully used as firewood. Being of a lower quality in comparison with usual beech firewood, the white poplar has similar calorific value. The white poplar has a calorific density of 30.7 % lower than that of current firewood. That is why the price of this firewood from white poplar is lower accordingly. Also, the prognosis of calorific value on the basis of the main chemical elements, being very close to the experimental value（＋2.6 %）, indicates an appropriate value can be achieved to be used for investigation with the chemical element analysis.

An overview of Turkish lignite qualities by logistic analysis

As an indispensable energy source, lignite is almost exclusively used in power generation m TurKey, To assess me quality level of Turkish lignite, a multivariate statistical analysis was conducted. The relationship among the lignite quality parameters has been investigated using a response method that is the logistic regression method. The analysis determines the effect of multiple predictor variables such as moisture, ash and sulphur presented simultaneously to predict membership of the two calorific value categories. By this way, a reliable binary response regression structure was constructed considering all the lignite fields in Turkey. Both the experiments on identifying the influential measurements and the measure of goodness of fit indicated that the overall model has a big capability to exhibit the relationship among the parameters of the Turkish lignite.

Heating Process of Thermosetting Insulation Materials for Buildings

Polyurethane （PU） and phenolic （PF） foams used for building isolation were analyzed by thermal gravity/differential thermal analysis to determine their pyrolysis behavior, including the decomposition point and the maximum reaction rate point. Besides, the shape deformations of PU and PF foams were observed, and their oxygen index and the calorific value in combustion were also studied. The results showed that the pyrolysis of both PU and PF can be divided into three stages from room temperature to 1 000 ℃ in the atmospheric air, with total mass loss of 94.345% for PF and 88.191% for PU, respectively. The oxygen index of PU and PF decreased with increasing the temperature and the duration of the heat treatment. With the temperature increasing, the calorific values of both materials were reduced remarkably. These results of the PU and PF could provide basic data of the thermal stability and fire safety design in the application of thermosetting insulation materials.

Fundamental Study on the Production of ＂Hyper Wood Pellet＂——Effect of Torrefaction Condition on Grinding and Pelletizing Properties

In order to upgrade the conventional wood pellet, Japanese softwood and hardwood chips were torrefied at around 200-350℃, and pelletized. The characteristics of the torrefied material/pellets such as their calorific value, grinding energy, pelletizing energy and elemental composition, were also evaluated in this study. The calorific value rose with increasing torrefaction temperature and exceeded 25 MJ/kg （an increase of nearly 40% compared to the untreated state） for torrefaction at around 350℃. The grinding energy greatly decreased with increasing torrefaction temperature, and the reduction was larger for Japanese oak hardwood chips. The pelletization energy for the torrefied material tended to be slightly smaller than in the untreated case. People named such torrefied pellet as ＂hyper wood pellet＂.

Incinerability Index of Municipal Solid Waste and Its Correlation with Carbon Monoxide and Nitrogen Oxides Emissions

The main objective of this study was to establish optimal incineration conditions through the analysis of pollutant formation mechanisms involved in the combustion process of a retort incinerator. Calorific values of several types of municipal solid wastes were determined and related to specific incinerability indexes. The incinerability testing concerning this study was conducted on residues with an incinerability index （II） of 123. The samples were tested under different conditions： with and without chamber preheating, varying the percentage of inlet air （25, 50 and 75% of the system capacity）, measuring the temperatures of the primary and secondary chambers, and gauging the CO and NO stack emissions with an electrochemical cell. With comparative purposes in mind, samples with indexes ofI = 112, I = 123, I = 130 and I = 132 were also tested to assess the influence of the II on pollutant emissions.

Bamboo Biomass for Bioenergy Production in Mauritius

Bamboo, globally renowned as being one of the fastest-growing plants in the world with versatile applications, has gained increasing attention during the past decades. It is being used by millions of people around the globe as a biomass resource for energy production, as timber for furniture making, in the food industry and many more. So far, on the Island of Mauritius, little to no consideration has been given to this fascinating plant. This paper presents the physical and chemical properties of two species of bamboo—Bambusia vulgaris and Bambusia bambos, compared to sugarcane bagasse for bio-energy production. Ten samples of each species were tested for gross calorific value (GCV), moisture, ash and chloride content. The results show that both species have a very good potential for energy recovery with a GCV of 16.77 MJ/kg for Bambusia vulgaris and 17.44 MJ/kg for Bambusia bambos, and are valuable sources of biomass with an average energetic yield of 717.8 GJ/ha/yr and 1587.1 GJ/ha/yr respectively. In comparison, the GCV for sugarcane bagasse was found to be 18.33 MJ/kg with an energetic yield of 824.9 GJ/ha/yr. Simultaneously, a research survey on community acceptance and perception of the Mauritian citizens towards the utilisation of bamboo biomass as an alternative to fossil fuels for bio-energy production was conducted via semi-structured questionnaires. The questionnaires were administered to a total of 54 respondents. 3 women and 3 men were randomly interviewed in each of the 9 districts of the island. The results show that the participants are very much aware of the many issues related to the exploitation of fossil fuels and support the use and implementation of renewable sources of energy for bio-energy production. Eighty percent of the participants supported the implementation of bamboo biomass in the overall energy generation mix in a bold move to lessen their ecological footprint.

Physicomechanical Properties of Rice Husk Pellets for Domestic Combustion in Myanmar

Myanmar produces 26.21 million tons of rice annually that results in 5.24 million tons of remaining rice husk of which only around 30%is used for electricity and heat production in the country.Myanmar needs more energy consumption to develop the agricultural economy and biomass energy in the future of the country.The proximate and ultimate analysis of rice husk and produced rice husk pellets were determined as well as analyzing the physicochemical and mechanical properties.The rice husk pellets without doing size reduction were manufactured in a ring die pellet mill.Loose and pellet-formed rice husk were compared based on the ISO 17225-6 standard for the characterization of herbaceous biomass.Pelletizing increased the bulk density of rice husk by a factor of 4.5.The net calorific value of Myanmar rice husk pellets was 3.67 kW h/kg with a moisture content of 7.48%and the large amount of ash forming constituents.The result showed that the diameter,length,and durability of the produced pellets complied with ISO 17225-6 standard.However,the net calorific value and bulk density could only be partially fulfilled according to the ISO standard depending on the process parameters.

Energetic Study on Jordanian Olive Cake and Woody Biomass Materials

In this work, the potential for energy production in Jordan was explored using four distinct types of biomass samples (olive cakes, woods). The proximate analysis, oil content, and higher heating value were all determined experimentally and compared to other biomass previously published in the literature. The findings appear to be similar to other biomass materials utilized as solid biofuel feed-stock materials. Olive cake and wood samples have lower calorific values than anthracite coal, ranging from 25% to 40% lower. According to the results of this study, olive cake samples had the highest oil extractive content (14.5 wt%), followed by pine and beech woody samples with 8.9 wt% and 3.1 wt%, respectively. The calorific values of the biomass samples tested ranged from 18 to 22 MJ/kg, making them suitable for use as fuel. Moreover, the high volatile matter content (78% to 93%) was appropriate for chemical energy conversion by gasification or combustion process. Jordan can create roughly 8000 tons of pomace oil per year from the waste solid olive cake, based on existing results. Furthermore, the olive cake’s energy potential in Jordan is estimated to be 38 MW based on the higher heating value of the tested samples and the annual quantity of this resource. In the meantime, due to limited annual production, Jordanian firewood has the modest energy potential (2.4 MW).