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Air interaction around outdoor air-cooled condensers 被引量:1
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作者 王树刚 张腾飞 张剑 《Journal of Southeast University(English Edition)》 EI CAS 2010年第2期222-226,共5页
In order to increase cooling or heating efficiency,a porous computational fluid dynamics(CFD)model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is est... In order to increase cooling or heating efficiency,a porous computational fluid dynamics(CFD)model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is established to validate the accuracy of CFD simulation in terms of velocity and temperature distributions.The comparison between the measurement and the simulation shows a good agreement.By evaluating the condensers' sucked air temperature with CFD for three units installed in a row,it is found that the minimum separation distance among neighboring units is 0.2 m;a vertical wall should be apart from the unit line by at least 0.8 m;and large different operating pressures among units do not impact the flow rate and the heat transfer of the other units meaningfully. 展开更多
关键词 air-cooled condensers flow interaction heat transfer optimization computational fluid dynamics(CFD) MEASUREMENT
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Evaporative Condensers in Comfortable Air Conditioning System
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作者 YIN Ying-de1,ZHU Dong-sheng1,DU Gui-mei2,LI Yuan-xi1,SUN He-jing1,LIU Qing-ming1(1.Key Lab of Enhancement Heat Transfer and Energy Conservation,the Ministry of Education,South China University of Technology,Guangzhou,Guangdong 510641,China 2.College of Civil Engineering,Hunan University,Changsha,Hunan 410082,China) 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2009年第S1期136-140,共5页
The operating theory of an evaporative condenser was expatiated.The difference between an evaporative condensing refrigeration system and a general refrigeration system was analyzed.Compared with the air-cooled and th... The operating theory of an evaporative condenser was expatiated.The difference between an evaporative condensing refrigeration system and a general refrigeration system was analyzed.Compared with the air-cooled and the water-cooled,the virtues of energy-conservation and water-conservation of evaporative condensers were analyzed.Some questions existing in the application of evaporative condensers were pointed out,the corresponding solving methods were analyzed accordingly,and the development trend of evaporative condensing technique in mechanical refrigeration system field and the applied foreground of evaporative condensers in comfortable air conditioning were prospected. 展开更多
关键词 EVAPORATIVE condensers EVAPORATIVE condensing REFRIGERATION SYSTEM general REFRIGERATION SYSTEM comfortable AIR CONDITIONING SYSTEM
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Experimental Investigation on the Effection of Flow Regulator in a Multiple Evaporators/Condensers Loop Heat Pipe with Plastic Porous Structure
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作者 Xinyu Chang H. Nagano 《Journal of Power and Energy Engineering》 2014年第9期49-56,共8页
Multiple loop heat pipes which have two evaporators and two condensers in one loop are a kind of active heat transfer device. Since they have two evaporators and two condensers, the operating mode also becomes multipl... Multiple loop heat pipes which have two evaporators and two condensers in one loop are a kind of active heat transfer device. Since they have two evaporators and two condensers, the operating mode also becomes multiple. This work discusses the cases that multiple loop heat pipes were operated with one condenser at high temperature and the other at low temperature. To avoid the high temperature returning liquid and keep the multiple loop heat pipes work properly, the flow regulator which was made of polyethylene was designed, fabricated and applied in this test. The effect of flow regulator was confirmed and analyzed. In the test that large temperature difference existed between two sinks, it can be found according to the result that the flow regulator worked effectively and prevented the high temperature vapor to enter the inlet of common liquid line, which can keep the evaporators and returning liquid to operate at low temperature. With the increment of heat loads and the temperature difference between two sinks, the pressure difference between two condensers became larger and larger. When the pressure difference was larger than the flow regulator’s capillary force, the flow regulator could not work properly because the high temperature vapor began to flow through the flow regulator. According to the test data, the flow regulator can work properly within the sinks’ temperature 0&deg;C/60&deg;C and the two evaporators’ heat load 30/30 W. 展开更多
关键词 Flow REGULATOR Loop HEAT Pipe MULTIPLE Evaporators and condensers Two-Phase HEAT Transfer
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Operating Characteristics of Multiple Evaporators and Multiple Condensers Loop Heat Pipe with Polytetrafluoroethylene Wicks
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作者 Sho Okutani Hosei Nagano +2 位作者 Shun Okazaki Hiroyuki Ogawa Hiroki Nagai 《Journal of Electronics Cooling and Thermal Control》 2014年第1期22-32,共11页
This paper presents fabrication and testing of a multiple-evaporator and multiple-condenser loop heat pipe (MLHP) with polytetrafluoroethylene (PTFE) porous media as wicks. The MLHP has two evaporators and two condens... This paper presents fabrication and testing of a multiple-evaporator and multiple-condenser loop heat pipe (MLHP) with polytetrafluoroethylene (PTFE) porous media as wicks. The MLHP has two evaporators and two condensers in a loop heat pipe in order to adapt to various changes of thermal condition in spacecraft. The PTFE porous media was used as the primary wicks to reduce heat leak from evaporators to compensation chambers. The tests were conducted under an atmospheric condition. In the tests that heat loads are applied to both evaporators, the MLHP was stably operated as with a LHP with a single evaporator and a single condenser. The relation between the sink temperature and the thermal resistance was experimentally evaluated. In the test with the heat load to one evaporator, the heat transfer from the heated evaporator to the unheated evaporator was confirmed. In the heat load switching test, in which the heat load is switched from one evaporator to another evaporator repeatedly, the MLHP could be stably operated. The loop operation with the large temperature difference between the heat sinks was also tested. From this result, the stable operation of the MLHP in the various conditions was demonstrated. It was also found that a flow regulator which prevents the uncondensed vapor from the condensers is required at the inlet of the common liquid line when one condenser has higher temperature and cannot condense the vapor in it. 展开更多
关键词 LOOP HEAT PIPE MULTIPLE Evaporators MULTIPLE condensers Thermal Control TWO-PHASE HEAT Transfer
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Effect of Temperature Differentials on Condensers of Split-Type Air Conditioners in Apartment Buildings
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作者 Ahmad Alotaibi Ahmad A1-Mulla Rajeev Alasseri 《Journal of Energy and Power Engineering》 2013年第2期272-276,共5页
Analyzing the effects of heat rejection from condensers of split-type air-conditioning units at lower-floors of MLABs (multi-level apartment buildings), using field measurements to monitor environmental conditions a... Analyzing the effects of heat rejection from condensers of split-type air-conditioning units at lower-floors of MLABs (multi-level apartment buildings), using field measurements to monitor environmental conditions and condenser operation, revealed increases in the inlet air temperature at the condensers at the upper floors, which in turn increased the power and energy requirements for these units and decreased their cooling capacities. Results indicated that a decrease of up to 16,000 tons in cooling capacity and an increase of up to 67.2 MW in the national peak load demand might be reached for a 4 ℃ temperature differential for Kuwait conditions. It is recommended that the condensers be placed in the wind pathway to minimize the impact of heat rejection and stack effect and to optimize the operation of split-type air-conditioning units, and that other factors regarding installation setup and location are investigated. 展开更多
关键词 Split-type air-conditioning peak load temperature differentials power rating cooling capacity condensers.
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Experimental Study of Condensation Heat Transfer on Tube Bundles in Large Power Plant Condensers 被引量:1
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作者 Koichi Inoue Issaku Fujita +2 位作者 Kotaro Machii Satoshi Hiraoka Manabu Ishihara 《Journal of Energy and Power Engineering》 2014年第5期920-928,共9页
In order to clarify the effect of condensate inundation on steam condensation in a large tube bundle, condensation heat transfer and the condensate flow pattern in the tube bundle have been experimentally investigated... In order to clarify the effect of condensate inundation on steam condensation in a large tube bundle, condensation heat transfer and the condensate flow pattern in the tube bundle have been experimentally investigated. Test tube bundle consists of 36 cooling tubes, 12 condensate supply tubes and 24 un-cooled dummy tubes. Cooling test tubes are made of copper and have an outer diameter of 19.1 mm and condensing length of 150 mm, Steam flows horizontally through the test tube bundle at gap velocities 15-27 m/s at pressures of 8.8 kPa. In this study, experimental data about condensate flow pattern and condensation heat transfer in a tube bundle were collected for the optimization of tube arrangement in large power plant condensers. 展开更多
关键词 CONDENSATION INUNDATION CONDENSER tube bundle tube arrangement power station.
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A STUDY ON HEAT TRANSFER IN INCLINED REFLUX CONDENSERS
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作者 李修伦 刘杰 +1 位作者 谷俊杰 黄鸿鼎 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1992年第1期39-48,共10页
The condensation heat transfer in the inclined reflux condensers is investigated at various inclinations. A condensation heat transfer model is set up. The calculated values of the model agree well with the experiment... The condensation heat transfer in the inclined reflux condensers is investigated at various inclinations. A condensation heat transfer model is set up. The calculated values of the model agree well with the experimental data. Both the experimental data and the theoretical calculations show that the condensation heat transfer coefficient in the inclined reflux condensers varies with the inclinations and will be maximum when the inclination angle is about 10°. 展开更多
关键词 heat transfer REFLUX CONDENSER INCLINATION CONDENSATION
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A STUDY ON FLOODING VELOCITIES IN INCLINED REFLUX CONDENSERS
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作者 李修伦 刘杰 +1 位作者 谷俊杰 黄鸿鼎 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1992年第1期49-58,共10页
This paper deals with the flooding velocities of the reflux condensers with various inclinations.The flooding phenomena and two-phase flow patterns in such condensers have been observed. A physical and a mathematical ... This paper deals with the flooding velocities of the reflux condensers with various inclinations.The flooding phenomena and two-phase flow patterns in such condensers have been observed. A physical and a mathematical models for calculating flooding velocities are developed, which agree well with the experimental data. The flooding velocity in an inclined reflux condenser varies with the inclination and may reach the maximum value when the inclination is between 30° and 50°. 展开更多
关键词 FLOODING velocity REFLUX CONDENSER INCLINATION
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Calculation of the Choked Back Pressure for Steam Turbines with Air Cooled Condensers
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作者 Haisheng Yang Shuping Chang Ruitao Wu 《Energy and Power Engineering》 2013年第4期1474-1477,共4页
The choked back pressure characteristic of the steam turbine unit with air cooled condenser is very different with the unit with wet cooling technology, and the understanding of the choked back pressure performance ch... The choked back pressure characteristic of the steam turbine unit with air cooled condenser is very different with the unit with wet cooling technology, and the understanding of the choked back pressure performance change with operation load is important to guide the economic operation of the unit. One simplified Variable Operation Condition Analysis Method was put forward for calculation of the unit output-turbine back pressure characteristics. Based on this method, the choked back pressure for each operation load can be determined. An example was given for a super-critical, regenerative single-shaft, 2-casing with 2-exhaust steam turbine generation unit with air cooled condenser. The calculation result was provided and compared with the result of the unit with wet cooling technology. 展开更多
关键词 Air Cooled CONDENSER STEAM TURBINE Choked BACK Pressure CHARACTERISTIC CALCULATION
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Measures against the adverse impact of natural wind on air-cooled condensers in power plant 被引量:22
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作者 YANG LiJun,DU XiaoZe & YANG YongPing Key Laboratory of Condition Monitoring and Control for Power Plant Equipment of Ministry of Education of China,North China Electric Power University,Beijing 102206,China 《Science China(Technological Sciences)》 SCIE EI CAS 2010年第5期1320-1327,共8页
The natural wind plays disadvantageous roles in the operation of air-cooled steam condensers in power plant.It is of use to take various measures against the adverse effect of wind for the performance improvement of a... The natural wind plays disadvantageous roles in the operation of air-cooled steam condensers in power plant.It is of use to take various measures against the adverse effect of wind for the performance improvement of air-cooled condensers.Based on representative 2×600 MW direct air-cooled power plant,three ways that can arrange and optimize the flow field of cooling air thus enhance the heat transfer of air-cooled condensers were proposed.The physical and mathematical models of air-cooled condensers with various flow leading measures were presented and the flow and temperature fields of cooling air were obtained by CFD simulation.The back pressures of turbine were calculated for different measures on the basis of the heat transfer model of air-cooled condensers.The results show that the performance of air-cooled condensers is improved thus the back pressure of turbine is lowered to some extent by taking measures against the adverse impact of natural wind. 展开更多
关键词 air-cooled CONDENSER WIND SPEED and direction flow and HEAT TRANSFER BACK pressure power plant
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Allocation of synchronous condensers for restoration of system short-circuit power 被引量:7
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作者 Emanuel MARRAZI Guangya YANG Peter WEINREICH-JENSEN 《Journal of Modern Power Systems and Clean Energy》 SCIE EI 2018年第1期17-26,共10页
Modern power systems,employing an increasing number of converter-based renewable energy sources(RES)and decreasing the usage of conventional power plants,are leading to lower levels of short-circuit power and rotation... Modern power systems,employing an increasing number of converter-based renewable energy sources(RES)and decreasing the usage of conventional power plants,are leading to lower levels of short-circuit power and rotational inertia.A solution to this is the employment of synchronous condensers in the grid,in order to provide sufficient short-circuit power.This results in the increase of the short-circuit ratio(SCR)at transmission system busbars serving as points of interconnection(POI)to renewable generation.Evaluation of the required capacity and grid-location of the synchronous condensers,is inherently a mixed integer nonlinear optimization problem,which could not be done on manual basis considering each type of machine and all bus-bars.This study therefore proposes a method of optimal allocation of synchronous condensers in a hypothetic future scenario of a transmission system fed by renewable generation.Total cost of synchronous condenser installations in the system is minimized and the SCRs at the POIs of central renewable power plants are strengthened.The method has potential for application on larger grids,aiding grid-integration of RES. 展开更多
关键词 SHORT-CIRCUIT POWER SHORT-CIRCUIT ratio SYNCHRONOUS CONDENSER
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Study of the wind-pressure distribution of flat-roof parabolic condensers based on wind-tunnel tests
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作者 Qiong Zou Xuan Zeng +1 位作者 Chao Wang Yijun Shen 《Clean Energy》 EI 2022年第6期893-906,共14页
The structure of parabolic condensers makes them susceptible to wind load because of their thin and large windward mirrors.In this paper,the wind pressure on a model of a condenser mirror(1:35)on multistorey flat roof... The structure of parabolic condensers makes them susceptible to wind load because of their thin and large windward mirrors.In this paper,the wind pressure on a model of a condenser mirror(1:35)on multistorey flat roofs is analysed via pressure measurement in a wind tunnel.The mean wind-pressure distribution law of flat-roof condenser mirrors(including the change law with working conditions and the maximum distribution characteristics)and the distribution law of fluctuating and extreme wind pressure are obtained.Furthermore,by comparison with the ground-based condenser distribution law,similarities and differences between the two are obtained.Research results show that the wind-pressure distribution law of flat-roof parabolic condenser mirrors is the same as those on the ground,but the mean wind-pressure coefficient(absolute value)is generally~30%smaller.Furthermore,the maximum effect is generally located at the windward mirror edge and the mirror is more susceptible to wind pressure in wind directions of 30°and 135°-150°.The results of this study can provide a theoretical reference for wind-resistant structure design and multistorey flat-roof condenser-related research. 展开更多
关键词 parabolic condenser flat roof of multistorey building wind-tunnel tests mean wind pressure fluctuating wind pressure extreme wind pressure concentrated solar energy
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Novel interface engineering of LDH-based materials on Mg alloy for efficient photocatalytic systems considering the geometrical linearity of condensed phosphates 被引量:3
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作者 Mosab Kaseem Ananda Repycha Safira Arash Fattah-alhosseini 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期267-280,共14页
This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'g... This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic properties.Herein,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and orientation.Consequently,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye molecules.Furthermore,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@LDH.Specifically,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min duration.The highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for MO.This underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications. 展开更多
关键词 Plasma electrolysis Layered Double Hydroxide Condensed phosphates Adsorption capacity Photocatalytic efficiency
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Facile synthesis of hierarchical NaX zeolite from natural kaolinite for efficient Knoevenagel condensation 被引量:2
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作者 Wen Xiao Peng Dong +6 位作者 Chan Wang Jingdong Xu Tiesen Li Haibo Zhu Tinghai Wang Renwei Xu Yuanyuan Yue 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期75-84,共10页
Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficien... Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficiency.Herein,we explore an economic and environmentally friendly method for synthesizing hierarchical NaX zeolite that exhibits improved catalytic performance in the Knoevenagel condensation reaction for producing the useful fine chemical 2-cyano-3-phenylacrylate.The synthesis was achieved via a low-temperature activation of kaolinite and subsequent in-situ transformation strategy without any template or seed.Systematic characterizations reveal that the synthesized NaX zeolite has both intercrystalline and intra-crystalline mesopores,smaller crystal size,and larger external specific surface area compared to commercial NaX zeolite.Detailed mechanism investigations show that the inter-crystalline mesopores are generated by stacking smaller crystals formed from in-situ crystallization of the depolymerized kaolinite,and the intra-crystalline mesopores are inherited from the pores in the depolymerized kaolinite.This synthesis strategy provides an energy-saving and effective way to construct hierarchical zeolites,which may gain wide applications in fine chemical manufacturing. 展开更多
关键词 Hierarchical NaX zeolite Template-free synthesis Natural kaolinite Knoevenagel condensation
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Phase separation and transcriptional regulation in cancer development 被引量:1
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作者 Yan Gu Ke Wei Jun Wang 《Journal of Biomedical Research》 CAS CSCD 2024年第4期307-321,共15页
Liquid-liquid phase separation,a novel biochemical phenomenon,has been increasingly studied for its medical applications.It underlies the formation of membrane-less organelles and is involved in many cellular and biol... Liquid-liquid phase separation,a novel biochemical phenomenon,has been increasingly studied for its medical applications.It underlies the formation of membrane-less organelles and is involved in many cellular and biological processes.During transcriptional regulation,dynamic condensates are formed through interactions between transcriptional elements,such as transcription factors,coactivators,and mediators.Cancer is a disease characterized by uncontrolled cell proliferation,but the precise mechanisms underlying tumorigenesis often remain to be elucidated.Emerging evidence has linked abnormal transcriptional condensates to several diseases,especially cancer,implying that phase separation plays an important role in tumorigenesis.Condensates formed by phase separation may have an effect on gene transcription in tumors.In the present review,we focus on the correlation between phase separation and transcriptional regulation,as well as how this phenomenon contributes to cancer development. 展开更多
关键词 phase separation transcription regulation CANCER super-enhancer CONDENSATES
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Biochemistry and transcriptome analysis reveal condensed tannins alleviate liver injury induced by regulating cholesterol metabolism pathway 被引量:1
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作者 Xiangxin Li Yijing Pu +4 位作者 Bangdi Liu Xiaoming Fang Wenjun Peng Weibo Jiang Wenli Tian 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期909-919,共11页
Free cholesterol has been considered to be a critical risk factor of nonalcoholic fatty liver disease(NAFLD).It remains unknown whether dietary intake of condensed tannins(CTs)have distinguishable effects to alleviate... Free cholesterol has been considered to be a critical risk factor of nonalcoholic fatty liver disease(NAFLD).It remains unknown whether dietary intake of condensed tannins(CTs)have distinguishable effects to alleviate liver damage caused by a high cholesterol diet.Male C57BL/6 mice were fed a high cholesterol diet for 6 weeks,and given CTs treatment at a dosage of 200 mg/(kg·day)at the same time.The results indicated that compared with mice fed a normal diet,a high cholesterol diet group resulted in significant weight loss,dysregulation of lipid metabolism in blood and liver,and oxidative stress in the liver,but CTs treatment dramatically reversed these negative effects.Hematoxylin and eosin(H&E)staining and frozen section observation manifested that CTs treatment could effectively reduce the deposition of liver cholesterol and tissue necrosis caused by high cholesterol intake.CTs alleviated liver injury mainly by regulating the expression of related genes in cholesterol metabolism pathway and AMPK phosphorylation.Our results confirmed that CTs have remarkable cholesterol lowering and anti-liver injury effects in vivo. 展开更多
关键词 Condensed tannins High cholesterol Liver injury ANTIOXIDANTS Transcriptomic analysis
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Syntheses,crystal structures,and catalytic properties of three zinc(Ⅱ),cobalt(Ⅱ)and nickel(Ⅱ)coordination polymers constructed from 5⁃(4⁃carboxyphenoxy)nicotinic acid 被引量:1
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作者 LING Weizhong CHEN Xiangyun +2 位作者 LIU Wenjing HUANG Yingkai LI Yu 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1803-1810,共8页
Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been construc... Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been constructed hydrothermally using H_(2)cpna(5-(4-carboxyphenoxy)nicotinic acid),dpea(1,2-di(4-pyridyl)ethane),dpey(1,2-di(4-pyridyl)ethylene),and zinc,cobalt,and nickel chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system,space group P1.Compounds 1-3 show 2D layer structures.The catalytic activities in the Knoevenagel condensation reaction of these compounds were investigated.Compounds 1 and 2 exhibit effective catalytic activities in the Knoevenagel condensa-tion reaction at room temperature.For this reaction,various parameters were optimized,followed by the investiga-tion of the substrate scope.CCDC:2335676,1;2335677,2;2335678,3. 展开更多
关键词 coordination polymer dicarboxylic acid catalytic property Knoevenagel condensation reaction
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Fabrication and characterization of multi-scale coated boron powders with improved combustion performance:A brief review 被引量:1
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作者 Rui Liu Danfeng Yang +2 位作者 Kunyu Xiong Ying-Lei Wang Qi-Long Yan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期27-40,共14页
Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,whic... Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,which include coatings of boron by using fluoride compounds,energetic composites,metal fuels,and metal oxides.Coating techniques include recrystallization,dual-solvent,phase transfer,electrospinning,etc.As one of the effective coating agents,the fluorine compounds can react with the oxide shell of boron powder.In comparison,the energetic composites can effectively improve the flame temperature of boron powder and enhance the evaporation efficiency of oxide film as a condensed product.Metals and metal oxides would react with boron powder to form metal borides with a lower ignition point,which could reduce its ignition temperature. 展开更多
关键词 Boron powder coating Structure and morphology Condensed phase thermal reaction Ignition and combustion
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Phase behavior of gas condensate in porous media using real-time computed tomography scanning
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作者 Wen-Long Jing Lei Zhang +5 位作者 Ai-Fen Li Jun-Jie Zhong Hai Sun Yong-Fei Yang Yu-Long Cheng Jun Yao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1032-1043,共12页
The phase behavior of gas condensate in reservoir formations differs from that in pressure-volume-temperature(PVT)cells because it is influenced by porous media in the reservoir formations.Sandstone was used as a samp... The phase behavior of gas condensate in reservoir formations differs from that in pressure-volume-temperature(PVT)cells because it is influenced by porous media in the reservoir formations.Sandstone was used as a sample to investigate the influence of porous media on the phase behavior of the gas condensate.The pore structure was first analyzed using computed tomography(CT)scanning,digital core technology,and a pore network model.The sandstone core sample was then saturated with gas condensate for the pressure depletion experiment.After each pressure-depletion state was stable,realtime CT scanning was performed on the sample.The scanning results of the sample were reconstructed into three-dimensional grayscale images,and the gas condensate and condensate liquid were segmented based on gray value discrepancy to dynamically characterize the phase behavior of the gas condensate in porous media.Pore network models of the condensate liquid ganglia under different pressures were built to calculate the characteristic parameters,including the average radius,coordination number,and tortuosity,and to analyze the changing mechanism caused by the phase behavior change of the gas condensate.Four types of condensate liquid(clustered,branched,membranous,and droplet ganglia)were then classified by shape factor and Euler number to investigate their morphological changes dynamically and elaborately.The results show that the dew point pressure of the gas condensate in porous media is 12.7 MPa,which is 0.7 MPa higher than 12.0 MPa in PVT cells.The average radius,volume,and coordination number of the condensate liquid ganglia increased when the system pressure was between the dew point pressure(12.7 MPa)and the pressure for the maximum liquid dropout,Pmax(10.0 MPa),and decreased when it was below Pmax.The volume proportion of clustered ganglia was the highest,followed by branched,membranous,and droplet ganglia.This study provides crucial experimental evidence for the phase behavior changing process of gas condensate in porous media during the depletion production of gas condensate reservoirs. 展开更多
关键词 Gas condensate Pressure depletion Real-time micro-computed tomography scanning Distribution of condensate liquid
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Reaction pathways and selectivity in the chemo-catalytic conversion of cellulose and its derivatives to ethylene glycol:A review
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作者 Yao Li Yuchun Zhang +2 位作者 Zhiyu Li Huiyan Zhang Peng Fu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期310-331,共22页
Biomass-to-ethylene glycol is an effective means to achieve high-value utilisation of cellulose but is hindered by low conversion efficiency and poor catalyst activity and stability.Glucose and cellobiose are derivati... Biomass-to-ethylene glycol is an effective means to achieve high-value utilisation of cellulose but is hindered by low conversion efficiency and poor catalyst activity and stability.Glucose and cellobiose are derivatives of cellulose conversion to ethylene glycol,and it is found that studying the reaction process of both can help to understand the reaction mechanism of cellulose.It is desirable to develop a reusable,highly active catalyst to convert cellulose into ethylene glycol.This ideal catalyst might have one or more active sites described the conversion steps above.Here,we discuss the catalyst development of celluloseto-ethylene glycol,including tungsten,tin,lanthanide,and other transition metal catalysts,and special attention is given to the reaction mechanism and kinetics for preparing ethylene glycol from cellulose,and the economic advantages of biomass-to-ethylene glycol are briefly introduced.The insights given in this review will facilitate further development of efficient catalysts,for addressing the global energy crisis and climate change related to the use of fossil fuels. 展开更多
关键词 Ethylene glycol CELLULOSE Catalyst Retro-aldol condensation HYDROLYSIS Kinetics
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