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Floquet topological phase transition in two-dimensional quadratic band crossing system
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作者 Guo-Bao Zhu Hui-Min Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第6期521-525,共5页
We investigate the Hall effects of quadratic band crossing(QBC) fermions in a square optical lattice with spin–orbit coupling and orbital Zeeman term. We find that the orbital Zeeman term and shaking play critical ro... We investigate the Hall effects of quadratic band crossing(QBC) fermions in a square optical lattice with spin–orbit coupling and orbital Zeeman term. We find that the orbital Zeeman term and shaking play critical roles in the systems,which can drive a topological transition from spin Hall phases to anomalous Hall phase with nonvanishing(spin) Chern numbers. Due to the interplay among the orbital Zeeman term, spin–orbit coupling, and the shaking, the phase diagram of the system exhibits rich phases, which are characterized by Chern number. 展开更多
关键词 SHAKING quadratic band crossing ORBITAL
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Evolution of polarization singularities accompanied by avoided crossing in plasmonic system
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作者 彭一啸 宋前举 +3 位作者 胡鹏 崔大健 向红 韩德专 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第1期305-310,共6页
The evolution of polarization singularities supported in a one-dimensional periodic plasmonic system is studied.The lateral inversion symmetry of the system,which breaks the in-plane inversion symmetry and up-down mir... The evolution of polarization singularities supported in a one-dimensional periodic plasmonic system is studied.The lateral inversion symmetry of the system,which breaks the in-plane inversion symmetry and up-down mirror symmetry simultaneously,yields abundant polarization states.A complete evolution process with geometry for the polarization states is traced.In the evolution,circularly polarized points(C points)can stem from 3 different processes.In addition to the previously reported processes occurring in an isolated band,a new type of C point appearing in two bands simultaneously due to the avoided band crossing,is observed.Unlike the dielectric system with a similar structure which only supports at-Γbound states in the continuum(BICs),accidental BICs off theΓpoint are realized in this plasmonic system.This work provides a new scheme of polarization manipulation for the plasmonic systems. 展开更多
关键词 polarization singularities topological charge avoided crossing inversion symmetry
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Floquet spectrum and universal dynamics of a periodically driven two-atom system
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作者 谢文柱 周正强 +2 位作者 李轩 崔思淼 孙明远 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期436-443,共8页
We investigate the Floquet spectrum and excitation properties of a two-ultracold-atom system with periodically driven interaction in a three-dimensional harmonic trap.The interaction between the atoms is changed by va... We investigate the Floquet spectrum and excitation properties of a two-ultracold-atom system with periodically driven interaction in a three-dimensional harmonic trap.The interaction between the atoms is changed by varying the s-wave scattering length in two ways,the cosine and the square-wave modulations.It is found that as the driving frequency increases,the Floquet spectrum exhibits two main features for both modulations,the accumulating and the spreading of the quasienergy levels,which further lead to different dynamical behaviors.The accumulation is associated with collective excitations and the persistent growth of the energy,while the spread indicates that the energy is bounded at all times.The initial scattering length,the driving frequency and amplitude can all significantly change the Floquet spectrum as well as the dynamics.However,the corresponding relation between them is valid universally.Finally,we propose a mechanism for selectively exciting the system to one specific state by using the avoided crossing of two quasienergy levels,which could guide preparation of a desired state in experiments. 展开更多
关键词 Floquet spectrum universal dynamics two-atom system avoided crossing
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A Simplified Method for the Stress Analysis of Underground Transfer Structures Crossing Multiple Subway Tunnels
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作者 Shen Yan Dajiang Geng +2 位作者 Ning Dai Mingjian Long Zhicheng Bai 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第6期2893-2915,共23页
According to the design specifications,the construction of extended piles involves traversing the tunnel’s upper region and extending to the underlying rock layer.To address this challenge,a subterranean transfer str... According to the design specifications,the construction of extended piles involves traversing the tunnel’s upper region and extending to the underlying rock layer.To address this challenge,a subterranean transfer structure spanning multiple subway tunnels was proposed.Deliberating on the function of piles in the transfer structure as springs with axial and bending stiffness,and taking into account the force balance and deformation coordination conditions of beams and plates within the transfer structure,we established a simplified mechanical model that incorporates soil stratification by combining it with the Winkler elastic foundation beam model.The resolved established simplifiedmechanicalmodel employed finite difference technology and the Newton-Simpsonmethod,elucidating the mechanical mechanism of the transfer structure.The research findings suggest that the load carried by the upper structural columns can be transferred to the pile foundation beneath the beams through the transfer structure,subsequently reaching the deep soil layer and ensuring minimal impact on adjacent tunnels.The established simplified analysis method can be used for stress analysis of the transfer structure,concurrently considering soil stratification,pile foundation behavior,and plate action.The pile length,pile section size,and beam section size within the transfer structure should account for the characteristics of the upper load,ensuring an even distribution of the beam bending moment. 展开更多
关键词 crossing tunnels transfer structure force mechanism simplify analysis layered soil mass
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Systematic study of the synthesis of heavy and superheavy nuclei in 48Ca-induced fusion-evaporation reactions
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作者 Shi-Hao Zhu Tian-Liang Zhao Xiao-Jun Bao 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第7期157-172,共16页
We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applic... We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applicability of the model.To produce new proton-rich Fl and Lv isotopes through hot fusion reactions in the superheavy element region with Z≥104,we utilized the reactions ^(48)Ca+^(236,238,239) Pu and ^(48)Ca+^(242,243,244,250) Cm.However,owing to the detection limit of available equipment(0.1 pb),only 283Fl and 287−289Lv,which have the maximum evaporation residue cross section values of 0.149,0.130,9.522,and 0.309 pb,respectively,can be produced.Furthermore,to produce neutron-deficient isotopes of actinides near the proton drip line with Z=93−100,we attempted to generate the new isotopes(224−227Pu,228−232,237Cm)using the reactions ^(48)Ca+180,182,183 W and ^(48)Ca+^(184,186,187,192) Os.The maximum evaporation residue cross section values are 0.07,0.06,0.26,and 0.30 nb for the former set of reactions,and 1.96 pb,5.73 pb,12.16 pb,19.39 pb,54.79 pb,and 6.45 nb for the latter,respectively.These results are expected to provide new information for the future synthesis of unknown neutron-deficient isotopes. 展开更多
关键词 Dinuclear system(DNS)model Evaporation residue cross section Neutron-deficient isotopes
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Magnetic Field Curves and Magnetic Equipotential Surfaces around Crossing Electrical Wires Replacing Classical Magnetic Field Lines
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作者 Geoffroy Auvert 《Open Journal of Applied Sciences》 2024年第8期1996-2008,共13页
This article is based on a recent model specifically defining magnetic field values around electrical wires. With this model, calculations of field around parallel wires were obtained. Now, this model is extended with... This article is based on a recent model specifically defining magnetic field values around electrical wires. With this model, calculations of field around parallel wires were obtained. Now, this model is extended with the new concept of magnetic equipotential surface to magnetic field curves around crossing wires. Cases of single, double, and triple wires are described. Subsequent article will be conducted for more general scenarios where wires are neither infinite nor parallel. 展开更多
关键词 Magnetic Field Value Magnetic Field Vector Magnetic Field Line Magnetic Field Curve Equipotential Surface crossing Electrical Wires Magnetic Cross Product
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Inuence of Electron Donating Ability on Reverse Intersystem Crossing Rate for One Kind of Thermally Activated Delayed Fluorescence Molecules
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作者 Ming-lang Wang Jian-zhong Fan Li-li Lin 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第3期291-299,367,共10页
First-principles calculations are applied for investigating influence of electron donating ability of donor groups in eight thermally activated delayed fluorescence(TADF) molecules on their geometrical structures an... First-principles calculations are applied for investigating influence of electron donating ability of donor groups in eight thermally activated delayed fluorescence(TADF) molecules on their geometrical structures and transition properties as well as reverse intersystem crossing(RISC) processes. Results show that the diphenylamine substitution in the donor part can slightly change the bond angle but decrease bond length between donor and acceptor unit except for the lowest triplet state(Ti) of carbazole-xanthone molecule. As the electron donating ability of donor groups is increased, the overlap between the highest occupied molecular orbital(HOMO) and the lowest unoccupied molecular orbital(LUMO) is decreased. As the diphenylamine groups are added in donor part, the delocalization of HOMO is enlarged,which brings a decreased energy gap(△ES1-T1) between the lowest singlet excited state(S1)and T1 state. Furthermore, with the calculated spin-orbit coupling coefficient(HSO), one finds that the larger value of ■ is, the faster the RISC is. The results show that all investigated molecules are promising candidates as TADF molecules. Overall, a wise molecular design strategy for TADF molecules,in which a small △ES1-T1 can be achieved by enlarging the delocalization of frontier molecular orbitals with large separation between HOMO and LUMO, is proposed. 展开更多
关键词 Thermally ACTIVATED DELAYED fluorescence Donating ABILITY REVERSE intersystem crossing SPIN-ORBIT coupling
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New insight into the ultra-long lifetime of excitons in organic-inorganic perovskite: Reverse intersystem crossing
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作者 Guanghao Meng Yantao Shi +4 位作者 Xiangyuan Wang Wei Wang Shufeng Wang Min Ji Ce Hao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2018年第5期1496-1500,共5页
Recently, an effective exciton diffusion length L exceeding 100μm has been reported for organic- inorganic halide perovskites owing to both the high mobility and ultra-long lifetime of the excitons; however, the orig... Recently, an effective exciton diffusion length L exceeding 100μm has been reported for organic- inorganic halide perovskites owing to both the high mobility and ultra-long lifetime of the excitons; however, the origin of ultra-long L is still unclear in nature. In some photoelectric materials, reverse intersystem crossing (RISC) from the triplet to the singlet state can enhance the quantum yield of pho- toluminescence greatly. In this study, our theoretical investigation indicated that the energy difference △E_st between the singlet state and the triplet state of CH_3NH_3Pbl_3 was less than 0.1 eV, which represents one crucial prerequisite for the occurrence of RISC. Meanwhile, the experimental results showed that the photoluminescence lifetime increased with the increasing temperature, a typical feature of RISC. Based on this study, we put forward the hypothesis that the ultra-long lifetime of excitons in organic-inorganic halide perovskite might be caused by the RISC process. This may provide a new insight into the important photophysical properties of such novel photovoltaic materials. 展开更多
关键词 Inorganic-organic halide perovskite PHOTOPHYSICS Photoluminescence Reverse intersystem crossing Ultra-long lifetime
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Regular-Singular Crossings on Nonlinear Systems with Turning Point
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作者 Zhang Hanlin (Beijing Polytechnic University) Zhang Heping (Beijing Electric Power College) 《Advances in Manufacturing》 SCIE CAS 1998年第3期21-23,共3页
We consider in this paper the boundary value problems of nonlinear systems the form εY″=F(t,Y,Y′,ε), -1<t<1, Y(-1,ε)=A(ε), Y(1,ε)=B(ε). Supoosing some or all of the components of F , that is, ... We consider in this paper the boundary value problems of nonlinear systems the form εY″=F(t,Y,Y′,ε), -1<t<1, Y(-1,ε)=A(ε), Y(1,ε)=B(ε). Supoosing some or all of the components of F , that is, f i satisfy 2 f y′ 2 i t =0 =0, we say that F possesses a generalized turning point at t =0. Our goal is to give sufficient conditions for the existence of solution of the problems and to study the asymptotic behavior of the solution when F possesses a generalized turning point at t =0. We mainly discuss regular singular crossings. 展开更多
关键词 turning point regular singular crossing differential inequality
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Safety Assessment of Closed-Loop Level Crossing Control Systems by Means of STAMP(Systems-Theoretic Accident Model and Processes)
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作者 Tetsuya TAKATA Akira ASANO Hideo NAKAMURA 《Journal of Traffic and Transportation Engineering》 2018年第5期241-254,共14页
There have been a large number of accidents at level crossings of railways and this has been considered to be a significant issue to be solved for the realization of safe and stable railway transport.A conventional le... There have been a large number of accidents at level crossings of railways and this has been considered to be a significant issue to be solved for the realization of safe and stable railway transport.A conventional level crossing control system is characterized by the use of two types of electronic train detectors;one detects a train approaching to a level crossing section and the other then detects the train having left the level crossing.By contrast,closed-loop level crossing control systems in which level crossing control equipment and train-borne equipment communicate with each other have been advocated and are expected to serve as an effective solution to the abovementioned issue.This paper describes the following three types of closed-loop level crossing control systems:decentralized level crossing control system,fully-centralized comprehensive level crossing control system and fully-centralized individual level crossing control system.This paper then assesses the safety of these systems in comparison to the conventional level crossing control system.For the purpose of the assessment of their safety,a new accident analysis model called STAMP(systems theoretic accident model and processes)that is suitable for software intensive systems is used to clarify the advantage of the proposed three types of level crossing control systems in terms of safety. 展开更多
关键词 Level crossing CONTROL railway signaling closed loop CONTROL method safety assessment STAMP
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LEO支架构建crossing Y形支架辅助栓塞治疗颅内动脉分叉部宽颈动脉瘤的安全性和有效性分析
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作者 王开杉 陈渝杰 +3 位作者 唐俊 朱刚 胡荣 缪洪平 《陆军军医大学学报》 CAS CSCD 北大核心 2023年第21期2252-2259,共8页
目的探讨使用LEO支架构建crossing Y形支架辅助栓塞治疗颅内动脉分叉部宽颈动脉瘤的安全性和有效性。方法收集2018-2022年陆军军医大学第一附属医院神经外科收治的336例颅内动脉分叉部宽颈动脉瘤患者的临床资料及随访影像,其中55例患者... 目的探讨使用LEO支架构建crossing Y形支架辅助栓塞治疗颅内动脉分叉部宽颈动脉瘤的安全性和有效性。方法收集2018-2022年陆军军医大学第一附属医院神经外科收治的336例颅内动脉分叉部宽颈动脉瘤患者的临床资料及随访影像,其中55例患者采用LEO支架构建crossing Y形支架辅助栓塞治疗。观察使用LEO支架构建crossing Y形支架辅助栓塞治疗动脉瘤的成功率、手术相关并发症、围手术期缺血和出血并发症的发生率。采用改良Rankin评分(modified Rankin scale,mRS)量表评价患者出院及临床随访时的神经功能恢复情况,使用术后即刻及随访脑血管造影Raymond分级评估栓塞效果、术后随访CTA及MRA评估有无复发。结果55例颅内动脉分叉部宽颈动脉瘤患者均成功栓塞,未见支架打开不良、支架打折等不良事件;术中支架内血栓形成1例(1.82%),迟发性缺血2例(3.64%),未见围手术期出血事件。术后即刻造影致密栓塞(RaymondⅠ级)50例(90.91%),瘤颈残留(RaymondⅡ级)3例(5.45%),RaymondⅢ级2例(3.64%)。40例患者于术后6~24个月获得影像随访,造影RaymondⅠ级38例(95%),RaymondⅡ级2例(5%);9例患者行CTA或MRA复查未见复发;术后随访动脉瘤栓塞效果较术后即刻好转。出院时mRS评分0~1分50例,2分1例,3分1例,4分2例,5分1例。获得4~24个月临床随访预后,mRS评分0~1分50例,2分2例,3分1例,4分1例,6分1例;出院时mRS评分较差患者临床随访mRS评分好转。结论使用LEO支架构建crossing Y形支架辅助栓塞治疗颅内动脉分叉部宽颈动脉瘤成功率及安全性高,复发率低,围手术期缺血事件发生率低,近期疗效可,远期疗效待进一步观察。 展开更多
关键词 血管内治疗 分叉部宽颈动脉瘤 crossing Y形支架 弹簧圈栓塞 LEO支架
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The asymptotic relation between the first crossing point and the last exit time of Gaussian order statistics sequences
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作者 NING Zi-jun TAN Zhong-quan 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2023年第4期545-561,共17页
In this paper,we study the asymptotic relation between the first crossing point and the last exit time for Gaussian order statistics which are generated by stationary weakly and strongly dependent Gaussian sequences.I... In this paper,we study the asymptotic relation between the first crossing point and the last exit time for Gaussian order statistics which are generated by stationary weakly and strongly dependent Gaussian sequences.It is shown that the first crossing point and the last exit time are asymptotically independent and dependent for weakly and strongly dependent cases,respectively.The asymptotic relations between the first crossing point and the last exit time for stationary weakly and strongly dependent Gaussian sequences are also obtained. 展开更多
关键词 rst crossing point last exit time stationary Gaussian sequences Gaussian order statistic se-quences
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Towards system genetics analysis of head and neck squamous cell carcinoma using the mouse model,cellular platform,and clinical human data
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作者 Osayd Zohud Iqbal M.Lone +1 位作者 Aysar Nashef Fuad A.Iraqi 《Animal Models and Experimental Medicine》 CAS CSCD 2023年第6期537-558,共22页
Head and neck squamous cell cancer(HNSCC)is a leading global malignancy.Every year,More than 830000 people are diagnosed with HNSCC globally,with more than 430000 fatalities.HNSCC is a deadly diverse malignancy with m... Head and neck squamous cell cancer(HNSCC)is a leading global malignancy.Every year,More than 830000 people are diagnosed with HNSCC globally,with more than 430000 fatalities.HNSCC is a deadly diverse malignancy with many tumor locations and biological characteristics.It originates from the squamous epithelium of the oral cavity,oropharynx,nasopharynx,larynx,and hypopharynx.The most frequently impacted regions are the tongue and larynx.Previous investigations have demonstrated the critical role of host genetic susceptibility in the progression of HNSCC.Despite the advances in our knowledge,the improved survival rate of HNSCC patients over the last 40 years has been limited.Failure to identify the molecular origins of development of HNSCC and the genetic basis of the disease and its biological heterogeneity impedes the development of new therapeutic methods.These results indicate a need to identify more genetic factors underlying this complex disease,which can be better used in early detection and prevention strategies.The lack of reliable animal models to investigate the underlying molecular processes is one of the most significant barriers to understanding HNSCC tumors.In this report,we explore and discuss potential research prospects utilizing the Collaborative Cross mouse model and crossing it to mice carrying single or double knockout genes(e.g.Smad 4 and P53 genes)to identify genetic factors affecting the development of this complex disease using genome-wide association studies,epigenetics,micro RNA,long noncoding RNA,lnc RNA,histone modifications,methylation,phosphorylation,and proteomics. 展开更多
关键词 animal models Collaborative Cross mice GENOMICS head and neck squamous cell cancinoma host genetic susceptibility
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Design and Simulation of an Audio Signal Alerting and Automatic Control System
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作者 Winfred Adjardjah John Awuah Addor +1 位作者 Wisdom Opare Isaac Mensah Ayipeh 《Communications and Network》 2023年第4期98-119,共22页
A large part of our daily lives is spent with audio information. Massive obstacles are frequently presented by the colossal amounts of acoustic information and the incredibly quick processing times. This results in th... A large part of our daily lives is spent with audio information. Massive obstacles are frequently presented by the colossal amounts of acoustic information and the incredibly quick processing times. This results in the need for applications and methodologies that are capable of automatically analyzing these contents. These technologies can be applied in automatic contentanalysis and emergency response systems. Breaks in manual communication usually occur in emergencies leading to accidents and equipment damage. The audio signal does a good job by sending a signal underground, which warrants action from an emergency management team at the surface. This paper, therefore, seeks to design and simulate an audio signal alerting and automatic control system using Unity Pro XL to substitute manual communication of emergencies and manual control of equipment. Sound data were trained using the neural network technique of machine learning. The metrics used are Fast Fourier transform magnitude, zero crossing rate, root mean square, and percentage error. Sounds were detected with an error of approximately 17%;thus, the system can detect sounds with an accuracy of 83%. With more data training, the system can detect sounds with minimal or no error. The paper, therefore, has critical policy implications about communication, safety, and health for underground mine. 展开更多
关键词 Emergency Response Emergency Management Team Audio Signal Alerting Automatic Control system Uni Pro XL Manual Communication Fast Fourier Transform Magnitude Zero crossing Rate Root Means Square
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Frequency Domain Fatigue Evaluation on SCR Girth-Weld Based on Structural Stress 被引量:2
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作者 ZHANG Long ZHAO Tian-feng 《China Ocean Engineering》 SCIE EI CSCD 2024年第2期255-270,共16页
The Steel Catenary Riser(SCR)is a vital component for transporting oil and gas from the seabed to the floating platform.The harsh environmental conditions and complex platform motion make the SCR’s girth-weld prone t... The Steel Catenary Riser(SCR)is a vital component for transporting oil and gas from the seabed to the floating platform.The harsh environmental conditions and complex platform motion make the SCR’s girth-weld prone to fatigue failure.The structural stress fatigue theory and Master S-N curve method provide accurate predictions for the fatigue damage on the welded joints,which demonstrate significant potential and compatibility in multi-axial and random fatigue evaluation.Here,we propose a new frequency fatigue model subjected to welded joints of SCR under multiaxial stress,which fully integrates the mesh-insensitive structural stress and frequency domain random process and transforms the conventional welding fatigue technique of SCR into a spectrum analysis technique utilizing structural stress.Besides,a full-scale FE model of SCR with welds is established to obtain the modal structural stress of the girth weld and the frequency response function(FRF)of modal coordinate,and a biaxial fatigue evaluation about the girth weld of the SCR can be achieved by taking the effects of multi-load correlation and pipe-soil interaction into account.The research results indicate that the frequency-domain fatigue results are aligned with the time-domain results,meeting the fatigue evaluation requirements of the SCR. 展开更多
关键词 SCR girth weld random vibration self(cross)power spectrum structural stress method biaxial fatigue damage
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Rational construction of heterointerfaces in biomass sugarcane-derived carbon for superior electromagnetic wave absorption 被引量:1
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作者 Shijie Zhang Di Lan +7 位作者 Jiajun Zheng Ailing Feng Yaxing Pei Shichang Cai Suxuan Du Xingliang Chen Guanglei Wu Zirui Jia 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第12期2749-2759,共11页
The pervasive adoption of 5th generation mobile communication technology propels electromagnetic wave(EW)absorbents to achieve high-level performance.The heterointerface construction is crucial to the improvement of a... The pervasive adoption of 5th generation mobile communication technology propels electromagnetic wave(EW)absorbents to achieve high-level performance.The heterointerface construction is crucial to the improvement of absorption ability.Herein,a series of ultralight composites with rational heterointerfaces(Co/ZnO@N-doped C/layer-stacked C,MSC)is fabricated by calcination with ration-al construction of sugarcane and CoZn-zeolitic imidazolate framework(ZIF).The components and structures of as-prepared composites were investigated,and their electromagnetic parameters could be adjusted by the content of CoZn-ZIFs.All composites possess excellent EW absorption performance,especially MSC-3.The optimal minimum reflection loss and effective absorption band of MSC-3 can reach−42 dB and 7.28 GHz at the thickness of only 1.6 mm with 20wt%filler loading.This excellent performance is attributed to the syner-gistic effect of dielectric loss stemming from the multiple heterointerfaces and magnetic loss induced by magnetic single Co.The sugar-cane-derived layer-stacked carbon has formed consecutive conductive networks and has further dissipated the electromagnetic energy through multiple reflection and conduction losses.Moreover,the simulated radar cross section(RCS)technology manifests that MSC-3 possesses outstanding EW attenuation capacity under realistic far-field conditions.This study provides a strategy for building efficient ab-sorbents based on biomass. 展开更多
关键词 sugarcane-derived carbon heterointerfaces bimetallic metal-organic frameworks EW absorption radar cross section
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Efficient and Fast X-Ray Luminescence in Organic Phosphors Through High-Level Triplet-Singlet Reverse Intersystem Crossing 被引量:1
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作者 Yang Zhang Minghong Chen +9 位作者 Xiaoze Wang Miao Lin Hongyu Wang Weihong Li Fuhai Chen Qing Liao Hongming Chen Qiushui Chen Meijin Lin Huanghao Yang 《CCS Chemistry》 CSCD 2024年第2期334-341,共8页
Organic scintillators that efficiently generate bright triplet excitons are of critical importance for highperformance X-ray-excited luminescence in radiation detection.However,the nature of triplet-singlet spinforbid... Organic scintillators that efficiently generate bright triplet excitons are of critical importance for highperformance X-ray-excited luminescence in radiation detection.However,the nature of triplet-singlet spinforbidden transitions in these materials often result in long-lived phosphorescence,which is undesirable for ultrafast X-ray detection and imaging.Here we demonstrate that the effect of hybridized local and charge-transfer(HLCT)excited states enables organic scintillators to exhibit highly efficient and fast radioluminescence(RL)in response to X-ray irradiation.Our experimental and theoretical investigation shows that the oxidized 1,8-naphthalimide-phenothiazine dyad(OMNI-PTZ 2)with HLCT-excited states has an enhanced overlap integral of the highest occupied molecular orbital(HOMO)and lowest unoccupied molecular orbital(LUMO)on MNIπ-orbitals,and moderate donor–acceptor electron interactions.As a result,the RL of these crystals exhibits a 61-fold increase and its monoexponential decay lifetime is three orders of magnitude faster compared to its corresponding thermally activated delayed fluorescence(TADF)molecule MNI-PTZ 1.We further demonstrate the practical utility of the OMNI-PTZ 2(G)in high-performance X-ray detection and imaging,achieving an X-ray dose sensitivity of 97 nGy s−1 and an exceptional spatial resolution of 20 lp/mm.Our study provides a promising molecular design principle for utilizing triplet excitons to develop high-efficiency and fast X-ray scintillators for the development of next-generation flexible and stretchable X-ray imaging detectors. 展开更多
关键词 organic scintillators X-ray imaging hybridized local and charge transfer excited state triplet-singlet reverse intersystem crossing high exciton utilization
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Possibilities for the synthesis of superheavy element Z=121 in fusion reactions 被引量:1
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作者 Ming-Hao Zhang Yu-Hai Zhang +3 位作者 Ying Zou Xiu-Xiu Yang Gen Zhang Feng-Shou Zhang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第6期90-100,共11页
Based on the dinuclear system model,the calculated evaporation residue cross sections matched well with the current experimental results.The synthesis of superheavy elements Z=121 was systematically studied through co... Based on the dinuclear system model,the calculated evaporation residue cross sections matched well with the current experimental results.The synthesis of superheavy elements Z=121 was systematically studied through combinations of stable projectiles with Z=21-30 and targets with half-lives exceeding 50 d.The influence of mass asymmetry and isotopic dependence on the projectile and target nuclei was investigated in detail.The reactions^(254)Es(^(46)Ti,3n)^(297)121 and^(252)Es(^(46)Ti,3n)^(295)121 were found to be experimentally feasible for synthesizing superheavy element Z=121,with maximal evaporation residue cross sections of 6.619 and 4.123 fb at 219.9 and 223.9 MeV,respectively. 展开更多
关键词 Superheavy nuclei Dinuclear system model Fusion reaction Evaporation residue cross section
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Corneal collagen cross-linking in patients with keratoconus from the Dresden protocol to customized solutions:theoretical basis 被引量:1
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作者 Ciro Caruso Luca D’Andrea +4 位作者 Mario Troisi Michele Rinaldi Raffaele Piscopo Salvatore Troisi Ciro Costagliola 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2024年第5期951-962,共12页
Keratoconus is an ectatic condition characterized by gradual corneal thinning,corneal protrusion,progressive irregular astigmatism,corneal fibrosis,and visual impairment.The therapeutic options regarding improvement o... Keratoconus is an ectatic condition characterized by gradual corneal thinning,corneal protrusion,progressive irregular astigmatism,corneal fibrosis,and visual impairment.The therapeutic options regarding improvement of visual function include glasses or soft contact lenses correction for initial stages,gas-permeable rigid contact lenses,scleral lenses,implantation of intrastromal corneal ring or corneal transplants for most advanced stages.In keratoconus cases showing disease progression corneal collagen crosslinking(CXL)has been proven to be an effective,minimally invasive and safe procedure.CXL consists of a photochemical reaction of corneal collagen by riboflavin stimulation with ultraviolet A radiation,resulting in stromal crosslinks formation.The aim of this review is to carry out an examination of CXL methods based on theoretical basis and mathematical models,from the original Dresden protocol to the most recent developments in the technique,reporting the changes proposed in the last 15y and examining the advantages and disadvantages of the various treatment protocols.Finally,the limits of non-standardized methods and the perspectives offered by a customization of the treatment are highlighted. 展开更多
关键词 corneal collagen cross linking KERATOCONUS custom fast protocol Dresden protocol lambert-beer law Bunsen-roscoe law
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Cross section determination of^(27)Al(n,2n)^(26)Al reaction induced by 14-MeV neutrons uniting with D-T neutron activation and AMS techniques 被引量:1
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作者 Xian-Lin Yang Chang-Lin Lan +6 位作者 Yu-Ting Wei Yi Zhang Gong Jiang Bo Xie Yu Liu Hong-Tao Shen Xiao-Jun Sun 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第6期78-89,共12页
Aluminum is the primary structural material in nuclear engineering,and its cross section induced by 14-MeV neutrons is of great significance.To address the issue of insufficient accuracy for the^(27)Al(n,2n)^(26)Al re... Aluminum is the primary structural material in nuclear engineering,and its cross section induced by 14-MeV neutrons is of great significance.To address the issue of insufficient accuracy for the^(27)Al(n,2n)^(26)Al reaction cross section,the activation method and accelerator mass spectrometry(AMS)technique were used to determine the^(27)Al(n,2n)^(26)Al cross section,which could be used as a D-T plasma ion temperature monitor in fusion reactors.At the China Academy of Engineering Physics,neutron activation was performed using a K-400 neutron generator produced by the T(d,n)4He reaction.The^(26)Al∕^(27)Al isotope ratios were measured using the newly installed GYIG 1 MV AMS at the Institute of Geochemistry,Chinese Academy of Sciences.The neutron flux was monitored by measuring the activity of 92mNb produced by the 93Nb(n,2n)92mNb reaction.The measured results were compared with available data in the experimental nuclear reaction database,and the measured values showed a reasonable degree of consistency with partially available literature data.The newly acquired cross-sectional data at 12 neutron energy points through systematic measurements clarified the divergence,which has two different growth trends from the existing experimental values.The obtained results are also compared with the corresponding evaluated database,and the newly calculated excitation functions with TALYS−1.95 and EMPIRE−3.2 codes,the agreement with CENDL−3.2,TENDL-2021 and EMPIRE−3.2 results are generally acceptable.A substantial improvement in the knowledge of the^(27)Al(n,2n)^(26)Al reaction excitation function was obtained in the present work,which will lay the foundation for the diagnosis of the fusion ion temperature,testing of the nuclear physics model,evaluation of nuclear data,etc. 展开更多
关键词 14-MeV neutron ^(27)Al(n 2n)^(26)Al Cross section AMS
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