期刊文献+
共找到3,424篇文章
< 1 2 172 >
每页显示 20 50 100
On-Resistance Degradations Under Different Stress Conditions in High Voltage pLEDMOS Transistors and an Improved Method 被引量:3
1
作者 孙伟锋 吴虹 +2 位作者 时龙兴 易扬波 李海松 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第2期214-218,共5页
The on-resistance degradations of the p-type lateral extended drain MOS transistor (pLEDMOS) with thick gate oxide under different hot carrier stress conditions are different, which has been experimentally investiga... The on-resistance degradations of the p-type lateral extended drain MOS transistor (pLEDMOS) with thick gate oxide under different hot carrier stress conditions are different, which has been experimentally investigated. This difference results from the interface trap generation and the hot electron injection, and trapping into the thick gate oxide and field oxide of the pLEDMOS transistor. An improved method to reduce the on-resistance degradations is also presented, which uses the field oxide as the gate oxide instead of the thick gate oxide. The effects are analyzed with a MEDICI simulator. 展开更多
关键词 pLEDMOS on-resistance degradation hot electron injection and trapping thick gate oxide
下载PDF
Microplastic degradations in simulated UV light,natural light and natural water body:A comparison investigation 被引量:1
2
作者 Bocheng Chen Beibei He +1 位作者 Hao Wu An Liu 《Emerging Contaminants》 CSCD 2024年第3期68-76,共9页
Microplastics(MPs)degradation due to light radiation,weathering,water erosion and biodegradation might change MPs physical and chemical characteristics and thereby change MPs behaviors in natural environments.This stu... Microplastics(MPs)degradation due to light radiation,weathering,water erosion and biodegradation might change MPs physical and chemical characteristics and thereby change MPs behaviors in natural environments.This study conducted a comparison investigation on polyvinyl chloride(PVC),polyethylene(PE)and polyamide(PA)degradation in three different environmental conditions,namely simulated UV light,natural light and natural water body.The results showed that degradation of MPs in natural environments is more complex than the case in a controlled experimental condition(such as simulated UV light).In the conditions of natural light and natural water body,MPs are more easily covered by sediments/microorganisms.Particularly in the natural water body,biofilm development is an important factor for MPs degradation and this is dependent on where MPs are located.PVC in the water surface adsorbed more prokaryotes and eukaryotes than those in the water bottom while PE and PA showed the opposite.The research outcomes also show that a complex interaction between MPs and heavy metals in different environments.In simulated UV light,heavy metals tended to leach from MPs while in the natural light and natural water body,heavy metal concentrations of MPs had a higher variability caused by continuous leaching-adsorption behaviors.Those outcomes were expected to contribute to an in-depth understanding of MP degradations and their environmental behaviors. 展开更多
关键词 Polyvinyl chloride POLYETHYLENE POLYAMIDE DEGRADATION Microplastics
原文传递
Therapeutic targeting of cellular prion protein: toward the development of dual mechanism anti-prion compounds
3
作者 Antonio Masone Chiara Zucchelli +2 位作者 Enrico Caruso Giovanna Musco Roberto Chiesa 《Neural Regeneration Research》 SCIE CAS 2025年第4期1009-1014,共6页
PrPSc,a misfolded,aggregation-prone isoform of the cellular prion protein(PrPC),is the infectious prion agent responsible for fatal neurodegenerative diseases of humans and other mammals.PrPSccan adopt different patho... PrPSc,a misfolded,aggregation-prone isoform of the cellular prion protein(PrPC),is the infectious prion agent responsible for fatal neurodegenerative diseases of humans and other mammals.PrPSccan adopt different pathogenic conformations(prion strains),which can be resistant to potential drugs,or acquire drug resistance,posing challenges for the development of effective therapies.Since PrPCis the obligate precursor of any prion strain and serves as the mediator of prion neurotoxicity,it represents an attractive therapeutic target fo r prion diseases.In this minireview,we briefly outline the approaches to target PrPCand discuss our recent identification of Zn(Ⅱ)-Bn PyP,a PrPC-targeting porphyrin with an unprecedented bimodal mechanism of action.We argue that in-depth understanding of the molecular mechanism by which Zn(Ⅱ)-Bn PyP targets PrPCmay lead toward the development of a new class of dual mechanism anti-prion compounds. 展开更多
关键词 anti-prion drug anti-PrPC antibody antisense oligonucleotide NEURODEGENERATION pharmacological chaperone porphyrin prion disease PrPC degrader PrPC shedding zinc finger repressor
下载PDF
Age-related driving mechanisms of retinal diseases and neuroprotection by transcription factor EB-targeted therapy
4
作者 Samuel Abokyi Dennis Yan-yin Tse 《Neural Regeneration Research》 SCIE CAS 2025年第2期366-377,共12页
Retinal aging has been recognized as a significant risk factor for various retinal disorders,including diabetic retinopathy,age-related macular degeneration,and glaucoma,following a growing understanding of the molecu... Retinal aging has been recognized as a significant risk factor for various retinal disorders,including diabetic retinopathy,age-related macular degeneration,and glaucoma,following a growing understanding of the molecular underpinnings of their development.This comprehensive review explores the mechanisms of retinal aging and investigates potential neuroprotective approaches,focusing on the activation of transcription factor EB.Recent meta-analyses have demonstrated promising outcomes of transcription factor EB-targeted strategies,such as exercise,calorie restriction,rapamycin,and metformin,in patients and animal models of these common retinal diseases.The review critically assesses the role of transcription factor EB in retinal biology during aging,its neuroprotective effects,and its therapeutic potential for retinal disorders.The impact of transcription factor EB on retinal aging is cell-specific,influencing metabolic reprogramming and energy homeostasis in retinal neurons through the regulation of mitochondrial quality control and nutrient-sensing pathways.In vascular endothelial cells,transcription factor EB controls important processes,including endothelial cell proliferation,endothelial tube formation,and nitric oxide levels,thereby influencing the inner blood-retinal barrier,angiogenesis,and retinal microvasculature.Additionally,transcription factor EB affects vascular smooth muscle cells,inhibiting vascular calcification and atherogenesis.In retinal pigment epithelial cells,transcription factor EB modulates functions such as autophagy,lysosomal dynamics,and clearance of the aging pigment lipofuscin,thereby promoting photoreceptor survival and regulating vascular endothelial growth factor A expression involved in neovascularization.These cell-specific functions of transcription factor EB significantly impact retinal aging mechanisms encompassing proteostasis,neuronal synapse plasticity,energy metabolism,microvasculature,and inflammation,ultimately offering protection against retinal aging and diseases.The review emphasizes transcription factor EB as a potential therapeutic target for retinal diseases.Therefore,it is imperative to obtain well-controlled direct experimental evidence to confirm the efficacy of transcription factor EB modulation in retinal diseases while minimizing its risk of adverse effects. 展开更多
关键词 age-related macular degeneration anti-aging interventions autophagy calorie restriction diabetic retinopathy exercise glaucoma NEUROMODULATION PHAGOCYTOSIS photoreceptor outer segment degradation retinal aging transcription factor EB
下载PDF
Regulation and function of endoplasmic reticulum autophagy in neurodegenerative diseases
5
作者 Xiu-Yun Zhao De-En Xu +3 位作者 Ming-Lei Wu Ji-Chuan Liu Zi-Ling Shi Quan-Hong Ma 《Neural Regeneration Research》 SCIE CAS 2025年第1期6-20,共15页
The endoplasmic reticulum,a key cellular organelle,regulates a wide variety of cellular activities.Endoplasmic reticulum autophagy,one of the quality control systems of the endoplasmic reticulum,plays a pivotal role i... The endoplasmic reticulum,a key cellular organelle,regulates a wide variety of cellular activities.Endoplasmic reticulum autophagy,one of the quality control systems of the endoplasmic reticulum,plays a pivotal role in maintaining endoplasmic reticulum homeostasis by controlling endoplasmic reticulum turnover,remodeling,and proteostasis.In this review,we briefly describe the endoplasmic reticulum quality control system,and subsequently focus on the role of endoplasmic reticulum autophagy,emphasizing the spatial and temporal mechanisms underlying the regulation of endoplasmic reticulum autophagy according to cellular requirements.We also summarize the evidence relating to how defective or abnormal endoplasmic reticulum autophagy contributes to the pathogenesis of neurodegenerative diseases.In summary,this review highlights the mechanisms associated with the regulation of endoplasmic reticulum autophagy and how they influence the pathophysiology of degenerative nerve disorders.This review would help researchers to understand the roles and regulatory mechanisms of endoplasmic reticulum-phagy in neurodegenerative disorders. 展开更多
关键词 AUTOPHAGY endoplasmic reticulum endoplasmic reticulum autophagy endoplasmic reticulum quality control system endoplasmic reticulum receptors endoplasmic reticulum-associated degradation NEURODEGENERATION neurodegenerative disease selective autophagy unfolded protein response
下载PDF
Photocatalytic degradations of JWS-type kinetics 被引量:1
6
作者 C.L.Wang 《Journal of Advanced Dielectrics》 CAS 2021年第6期68-73,共6页
Photocatalytic degradation kinetics of Jurlewicz-Weron-Stanislavsky(JWS)type has been identified.Experimental data are taken from previous published works,and fitted with the JWS relaxation function as well as that of... Photocatalytic degradation kinetics of Jurlewicz-Weron-Stanislavsky(JWS)type has been identified.Experimental data are taken from previous published works,and fitted with the JWS relaxation function as well as that of the Havriliak-Negami(HN)model.All experimental data can fit with either model fairly good.From the fitting parameters,the Jonscher indices are calculated and Jonscher diagram is plotted for the chemical kinetics of photocatalytic degradations.This work suggests that material parameters of photocatalysts can be well defined in the sense of fractional calculus. 展开更多
关键词 Photocatalytic degradation JWS relaxation Jonscher index fractional calculus
原文传递
One-step synthesis of three-dimensional mesoporous Co_(3)O_(4)@Al_(2)O_(3)nanocomposites with deep eutectic solvent:An efficient and stable peroxymonosulfate activator for organic pollutant degradations
7
作者 Yuchen Wang Kai Rong +4 位作者 Jiale Wei Shanlei Chang Dengbin Yu Youxing Fang Shaojun Dong 《Nano Research》 SCIE EI CSCD 2023年第8期11430-11443,共14页
The effective,stable,and secure catalysts are essential for sulfate radical(SO_(4)·−)-based advanced oxidation processes(SR-AOPs)to the degradation of organic contaminants in water.Heterogeneous supported cobalt-... The effective,stable,and secure catalysts are essential for sulfate radical(SO_(4)·−)-based advanced oxidation processes(SR-AOPs)to the degradation of organic contaminants in water.Heterogeneous supported cobalt-based catalysts are commonly used to activate peroxymonosulfate(PMS)to achieve the degradation.In this work,we synthesized Co_(3)O_(4)@Al_(2)O_(3)three-dimensional(3D)mesoporous nanocomposite(denoted as Co_(3)O_(4)@Al_(2)O_(33)DPNC)in just one step by calcining cheap and green deep eutectic solvent(DES)solution containing Co salt.Co_(3)O_(4)@Al_(2)O_(33)DPNC with the high specific surface area(93.246 m^(2)/g),uniform pore distribution(3.829 nm)and rich porosity(0.255 cm^(3)/g)were attained in a beautiful hierarchical structure which exhibited the open 3D propeller-like microstructure,two-dimensional lamellar substructure with rich folds,as well as the decoration of highly dispersed Co_(3)O_(4)nanoparticles on mesoporous amorphous Al_(2)O_(3).The excellent chemical and thermal stability of Al_(2)O_(3)ensures the high stability of the catalyst,and the formation of the complex hierarchical structure makes the active Co_(3)O_(4)be homogenously dispersed for effective catalysis.The catalyst demonstrated outstanding performance for catalytic degradations of organic pollutants(acetaminophen,oxytetracycline,5-sulfosalicylic acid,orange G and Rhodamine B)by generated SO_(4)·−,·OH and^(1)O_(2).With a very low cobalt content(equal to 28.2 mg/L of Co),the catalyst exhibited very high stability and excellent reusability in the recycling usages,while the leaching of the cobalt element(<0.145 mg/L)was also at a low level.Our catalyst achieved effective degradations of acetaminophen in cycles without losing its stable hierarchical nanostructure. 展开更多
关键词 PEROXYMONOSULFATE organic pollutant degradation deep eutectic solvent Co_(3)O_(4)@Al_(2)O_(3)nanocomposite hierarchical nanostructure
原文传递
Inhibition of protein degradation increases the Bt protein concentration in Bt cotton 被引量:2
8
作者 Yuting Liu Hanjia Li +6 位作者 Yuan Chen Tambel Leila.I.M Zhenyu Liu Shujuan Wu Siqi Sun Xiang Zhang Dehua Chen 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第6期1897-1909,共13页
Bacillus thuringiensis(Bt)cotton production is challenged by two main problems,i.e.,the low concentration of Bt protein at the boll setting stage and the lowest insect resistance in bolls among all the cotton plant’s... Bacillus thuringiensis(Bt)cotton production is challenged by two main problems,i.e.,the low concentration of Bt protein at the boll setting stage and the lowest insect resistance in bolls among all the cotton plant’s organs.Therefore,increasing the Bt protein concentration at the boll stage,especially in bolls,has become the main goal for increasing insect resistance in cotton.In this study,two protein degradation inhibitors(ethylene diamine tetra acetic acid(EDTA)and leupeptin)were sprayed on the bolls,subtending leaves,and whole cotton plants at the peak flowering stage of two Bt cultivars(medium maturation Sikang 1(SK1))and early maturation Zhongmian 425(ZM425)in 2019 and 2020.The Bt protein content and protein degradation metabolism were assessed.The results showed that the Bt protein concentrations were enhanced by 21.3 to 38.8%and 25.0 to 38.6%in the treated bolls of SK1 and ZM425 respectively,while they were decreased in the subtending leaves of these treated bolls.In the treated leaves,the Bt protein concentrations increased by 7.6 to 23.5%and 11.2 to 14.9%in SK1 and ZM425,respectively.The combined application of EDTA and leupeptin to the whole cotton plant increased the Bt protein concentrations in both bolls and subtending leaves.The Bt protein concentrations in bolls were higher,increasing by 22.5 to 31.0%and 19.6 to 32.5%for SK1 and ZM425,respectively.The organs treated with EDTA or/and leupeptin showed reduced free amino acid contents,protease and peptidase activities and significant enhancements in soluble protein contents.These results indicated that inhibiting protein degradation could improve the protein content,thus increasing the Bt protein concentrations in the bolls or/and leaves of cotton plants.Therefore,the increase in the Bt protein concentration without yield reduction suggested that these two protein degradation inhibitors may be applicable for improving insect resistance in cotton production. 展开更多
关键词 Bt cotton Bt protein inhibition of protein degradation protein degradation metabolism
下载PDF
Highly Efficient Aligned Ion‑Conducting Network and Interface Chemistries for Depolarized All‑Solid‑State Lithium Metal Batteries 被引量:3
9
作者 Yongbiao Mu Shixiang Yu +12 位作者 Yuzhu Chen Youqi Chu Buke Wu Qing Zhang Binbin Guo Lingfeng Zou Ruijie Zhang Fenghua Yu Meisheng Han Meng Lin Jinglei Yang Jiaming Bai Lin Zeng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期102-119,共18页
Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact l... Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature. 展开更多
关键词 All-solid-state lithium metal batteries Composite solid electrolyte 3D printing Areal capacity Interfacial degradation
下载PDF
Peri-implant gas accumulation in response to magnesium-based musculoskeletal biomaterials:Reframing current evidence for preclinical research and clinical evaluation 被引量:1
10
作者 Yu Sun Heike Helmholz Regine Willumeit-Römer 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期59-71,共13页
Historically,the rapid degradation and massive gas release from magnesium(Mg)implants resulted in severe emphysema and mechanical failure.With the advent of new alloys and surface treatment methods,optimized Mg implan... Historically,the rapid degradation and massive gas release from magnesium(Mg)implants resulted in severe emphysema and mechanical failure.With the advent of new alloys and surface treatment methods,optimized Mg implants have re-entered clinics since last decade with reliable performance.However,the optimization aims at slowing down the degradation process,rather than exemption of the gas release.This study involved a systematic evaluation of current preclinical and clinical evidence,regarding the physical signs,symptoms,radiological features,pathological findings and complications potentially associated with peri±implant gas accumulation(PIGA)after musculoskeletal Mg implantation.The literature search identified 196 potentially relevant publications,and 51 papers were enrolled for further analysis,including 22 preclinical tests and 29 clinical studies published from 2005 to 2023.Various Mg-based materials have been evaluated in animal research,and the application of pure Mg and Mg alloys have been reported in clinical follow-ups involving multiple anatomical sites and musculoskeletal disorders.Soft tissue and intraosseous PIGA are common in both animal tests and clinical follow-ups,and potentially associated with certain adverse events.Radiological examinations especially micro-CT and clinical CT scans provide valuable information for quantitative and longitudinal analysis.While according to simulation tests involving Mg implantation and chemical processing,tissue fixation could lead to an increase in the volume of gas cavity,thus the results obtained from ex vivo imaging or histopathological evaluations should be interpreted with caution.There still lacks standardized procedures or consensus for both preclinical and clinical evaluation of PIGA.However,by providing focused insights into the topic,this evidence-based study will facilitate future animal tests and clinical evaluations,and support developing biocompatible Mg implants for the treatment of musculoskeletal disorders. 展开更多
关键词 Magnesium implant Degradation Hydrogen Gas release Postoperative follow-up
下载PDF
Melatonin delays leaf senescence in pak choi(Brassica rapa subsp.chinensis)by regulating biosynthesis of the second messenger cGMP 被引量:1
11
作者 Xuesong Liu Ronghui An +3 位作者 Guofeng Li Shufen Luo Huali Hu Pengxia Li 《Horticultural Plant Journal》 SCIE CAS CSCD 2024年第1期145-155,共11页
Melatonin(MT)is a low molecular weight compound with multiple biological functions in plants.It is known to delay leaf senescence in various species.However,no data are available on the MT signaling pathway in posthar... Melatonin(MT)is a low molecular weight compound with multiple biological functions in plants.It is known to delay leaf senescence in various species.However,no data are available on the MT signaling pathway in postharvest vegetables.This study demonstrates that MT increases cGMP concentration and the expression of the cGMP synthesis gene BcGC1 in pak choi.The c GMP inhibitor LY83583 destroys effect of MT delaying the leaf senescence.LY83583 also prevents MT treatment from reducing the expression of chlorophyll metabolism-related genes(BcNYC1,BcNOL,BcPPH1/2,BcSGR1/2,and BcPAO)and senescence genes(BcSAG12 and BcSAG21).It also inhibits MT from reducing the activity of the key chlorophyll catabolism enzymes Mg-dechelatase,pheophytinase,and pheide a oxygenase.Thus,the ability of MT to maintain high levels of chlorophyll metabolites is also destroyed.The Arabidopsis c GMP synthetic gene mutant atgc1 was used to confirm that delayed leaf senescence caused by MT is mediated,at least in part,by the second messenger c GMP. 展开更多
关键词 Pak choi MELATONIN CGMP Chlorophyll degradation Senescence
下载PDF
Understanding the oxidation chemistry of Ti_(3)C_(2)T_(x)(MXene)sheets and their catalytic performances 被引量:1
12
作者 Suvdanchimeg Sunderiya Selengesuren Suragtkhuu +9 位作者 Solongo Purevdorj Tumentsereg Ochirkhuyag Munkhjargal Bat-Erdene Purevlkham Myagmarsereejid Ashley DSlattery Abdulaziz SRBati Joseph GShapter Dorj Odkhuu Sarangerel Davaasambuu Munkhbayar Batmunkh 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期437-445,I0010,共10页
Transition metal carbides and nitrides(MXenes)nanosheets are attractive two-dimensional(2D)materials,but they suffer from oxidation/degradation issues during storage and/or applications due to their sensitivity to wat... Transition metal carbides and nitrides(MXenes)nanosheets are attractive two-dimensional(2D)materials,but they suffer from oxidation/degradation issues during storage and/or applications due to their sensitivity to water and oxygen.Despite the great research progress,the exact oxidation kinetics of Ti_(3)C_(2)T_(x)(MXene)and their final products after oxidation are not fully understood.Herein,we systematically tracked the oxidation process of few-layer Ti_(3)C_(2)T_(x) nanosheets in an aqueous solution at room temperature over several weeks.We also studied the oxidation effects on the electrocatalytic properties of Ti_(3)C_(2)T_(x) for hydrogen evolution reaction and found that the overpotential to achieve a current density of 10 mA cm^(-2)increases from 0.435 to 0.877 V after three weeks of degradation,followed by improvement to stabilized values of around 0.40 V after eight weeks.These results suggest that severely oxidized MXene could be a promising candidate for designing efficient catalysts.According to our detailed experimental characterization and theoretical calculations,unlike previous studies,black titanium oxide is formed as the final product in addition to white Ti(IV)oxide and disordered carbons after the complete oxidation of Ti_(3)C_(2)T_(x).This work presents significant advancements in better understanding of 2D Ti_(3)C_(2)T_(x)(MXene)oxidation and enhances the prospects of this material for various applications. 展开更多
关键词 2D materials MXene Chemical degradation CATALYSIS Hydrogen evolution reaction
下载PDF
Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe)octahedrons 被引量:1
13
作者 Hao Yuan Xinhai Sun +2 位作者 Shuai Zhang Weilong Shi Feng Guo 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期298-309,共12页
The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater.Herein,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)... The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater.Herein,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)composite photocatalyst was synthesized for visible light-driven photocatalytic/persulfate(PS)-activated tetracycline(TC)degradation.The electron spin resonance(ESR)spectra,scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light-driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe)photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system(·OH,·SO_(4-),^(1)O_(2),h^(+)and·O_(2)^(-))but also attributed to the consumption of electrons caused by the PS,which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of CDs.Finally,the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography-mass spectrometry technique.This research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts. 展开更多
关键词 Carbon dots MIL-101(Fe) PHOTOCATALYTIC Persulfate activation Tetracycline degradation
下载PDF
Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol 被引量:1
14
作者 Donghui Li Wenzhe Wu +6 位作者 Xue Ren Xixi Zhao Hongbing Song Meng Xiao Quanhong Zhu Hengjun Gai Tingting Huang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期130-144,共15页
The novel Fe-N co-doped ordered mesoporous carbon with high catalytic activity in m-cresol removal was prepared by urea-assisted impregnation and simple pyrolysis method.During the preparation of the Fe-NC catalyst,th... The novel Fe-N co-doped ordered mesoporous carbon with high catalytic activity in m-cresol removal was prepared by urea-assisted impregnation and simple pyrolysis method.During the preparation of the Fe-NC catalyst,the complexation of N elements in urea could anchor Fe,and the formation of C3N4during urea pyrolysis could also prevent migration and aggregation of Fe species,which jointly improve the dispersion and stability of Fe.The FeN4sites and highly dispersed Fe nanoparticles synergistically trigger the dual-site peroxymonosulfate (PMS) activation for highly efficient m-cresol degradation,while the ordered mesoporous structure of the catalyst could improve the mass transfer rate of the catalytic process,which together promote catalytic degradation of m-cresol by PMS activation.Reactive oxygen species (ROS) analytic experiments demonstrate that the system degrades m-cresol by free radical pathway mainly based on SO_(4)^(-)·and·OH,and partially based on·OH as the active components,and a possible PMS activation mechanism by 5Fe-50 for m-cresol degradation was proposed.This study can provide theoretical guidance for the preparation of efficient and stable catalysts for the degradation of organic pollutants by activated PMS. 展开更多
关键词 Degradation PEROXYMONOSULFATE Fe(II)/Fe(III)/FeN4 Ordered mesopores carbon Catalyst Radical
下载PDF
Carbon-doped CuFe_(2)O_(4) with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism 被引量:1
15
作者 Hong Qin Yangzhuo He +9 位作者 Piao Xu Yuan Zhu Han Wang Ziwei Wang Yin Zhao Haijiao Xie Quyang Tian Changlin Wang Ying Zeng Yicheng Li 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第4期732-747,共16页
Carbon-doped copper ferrite(C–CuFe_(2)O_(4))was synthesized by a simple two-step hydrothermal method,which showed enhanced tetracycline hydrochloride(TCH)removal efficiency as compared to the pure CuFe_(2)O_(4) in Fe... Carbon-doped copper ferrite(C–CuFe_(2)O_(4))was synthesized by a simple two-step hydrothermal method,which showed enhanced tetracycline hydrochloride(TCH)removal efficiency as compared to the pure CuFe_(2)O_(4) in Fenton-like reaction.A removal efficiency of 94%was achieved with 0.2 g L^(-1) catalyst and 20 mmol L^(-1) H_(2)O_(2) within 90 min.We demonstrated that 5%C–CuFe_(2)O_(4) catalyst in the presence of H_(2)O_(2) was significantly efficient for TCH degradation under the near-neutral pH(5–9)without buffer.Multiple techniques,including SEM,TEM,XRD,FTIR,Raman,XPS M€ossbauer and so on,were conducted to investigate the structures,morphologies and electronic properties of as-prepared samples.The introduction of carbon can effectively accelerate electron transfer by cooperating with Cu and Fe to activate H_(2)O_(2) to generate·OH and·O_(2)^(-).Particularly,theoretical calculations display that the p,p,d orbital hybridization of C,O,Cu and Fe can form C–O–Cu and C–O–Fe bonds,and the electrons on carbon can transfer to metal Cu and Fe along the C–O–Fe and C–O–Cu channels,thus forming electron-rich reactive centers around Fe and Cu.This work provides lightful reference for the modification of spinel ferrites in Fenton-like application. 展开更多
关键词 Fenton-like reaction CuFe_(2)O_(4) Tetracycline hydrochloride degradation
下载PDF
Predicting the Degradability of Bioceramics through a DFT-based Descriptor
16
作者 CHEN Mengjie WANG Qianqian +1 位作者 WU Chengtie HUANG Jian 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第10期1175-1181,I0007-I0009,共10页
Bioceramics have attracted extensive attention for bone defect repair due to their excellent bioactivity and degradability.However,challenges remain in matching the rate between bioceramic degradation and new bone for... Bioceramics have attracted extensive attention for bone defect repair due to their excellent bioactivity and degradability.However,challenges remain in matching the rate between bioceramic degradation and new bone formation,necessitating a deeper understanding of their degradation properties.In this study,density functional theory(DFT)calculations was employed to explore the structural and electronic characteristics of silicate bioceramics.These findings reveal a linear correlation between the maximum isosurface value of the valence band maximum(VBM_(Fmax))and the degradability of silicate bioceramics.This correlation was subsequently validated through degradation experiments.Furthermore,the investigation on phosphate bioceramics demonstrates the potential of this descriptor in predicting the degradability of a broader range of bioceramics.This discovery offers valuable insights into the degradation mechanism of bioceramics and holds promise for accelerating the design and development of bioceramics with controllable degradation. 展开更多
关键词 BIOCERAMICS SILICATE PHOSPHATE first PRINCIPLES degradation
下载PDF
Screening and pilot-scale evaluation of a highly efficient pesticide-degrading Pseudomonas sp.strain BL5
17
作者 Rui Chen Xinyu Zuo +6 位作者 He Bai Ruolin Qin Zhiguo Chen Yiyun Liu Wenqing Cao Jingpeng Song Xiaoqiang Jia 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期287-294,共8页
The widespread use of pesticides has caused serious harm to ecosystems,necessitating effective and environmentally friendly treatment methods.Bioremediation stands out as a promising approach for pollutant treatment,w... The widespread use of pesticides has caused serious harm to ecosystems,necessitating effective and environmentally friendly treatment methods.Bioremediation stands out as a promising approach for pollutant treatment,wherein the metabolic activities of microorganisms can transform toxic pesticides into compounds with lower or no toxicity.In this study,we obtained eight pesticide-degrading strains from pesticide-contaminated sites through continuous enrichment and screening.Four highly efficient pesticide-degrading strains(degradation ratios exceeding 80%)were identified.Among them,Pseudomonas sp.BL5 exhibited the strongest growth(exceeding 10^(9) CFU·ml^(-1))and outstanding degradation of benzene derivatives and chlorinated hydrocarbons at both laboratory and pilot scales,with degradation ratios exceeding 98%and 99.6%,respectively.This research provides new tools and insights for the bioremediation of pesticide-related pollutants. 展开更多
关键词 PESTICIDES PILOT-SCALE Degradation REMEDIATION Pseudomonas sp. BENZENE
下载PDF
Discrimination of polysorbate 20 by high-performance liquid chromatography-charged aerosol detection and characterization for components by expanding compound database and library
18
作者 Shi-Qi Wang Xun Zhao +10 位作者 Li-Jun Zhang Yue-Mei Zhao Lei Chen Jin-Lin Zhang Bao-Cheng Wang Sheng Tang Tom Yuan Yaozuo Yuan Mei Zhang Hian Kee Lee Hai-Wei Shi 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2024年第5期722-732,共11页
Analyzing polysorbate 20(PS20)composition and the impact of each component on stability and safety is crucial due to formulation variations and individual tolerance.The similar structures and polarities of PS20 compon... Analyzing polysorbate 20(PS20)composition and the impact of each component on stability and safety is crucial due to formulation variations and individual tolerance.The similar structures and polarities of PS20 components make accurate separation,identification,and quantification challenging.In this work,a high-resolution quantitative method was developed using single-dimensional high-performance liquid chromatography(HPLC)with charged aerosol detection(CAD)to separate 18 key components with multiple esters.The separated components were characterized by ultra-high-performance liquid chromatography-quadrupole time-of-flight mass spectrometry(UHPLC-Q-TOF-MS)with an identical gradient as the HPLC-CAD analysis.The polysorbate compound database and library were expanded over 7-time compared to the commercial database.The method investigated differences in PS20 samples from various origins and grades for different dosage forms to evaluate the composition-process relationship.UHPLC-Q-TOF-MS identified 1329 to 1511 compounds in 4 batches of PS20 from different sources.The method observed the impact of 4 degradation conditions on peak components,identifying stable components and their tendencies to change.HPLC-CAD and UHPLC-Q-TOF-MS results provided insights into fingerprint differences,distinguishing quasi products. 展开更多
关键词 Polysorbate 20 Component DATABASE DISCRIMINATION Degradation
下载PDF
Biodegradation of Crystalline Chitin:A Review of Recent Advancement,Challenges,and Future Study Directions
19
作者 SONG Jianlin SU Haipeng +1 位作者 SUN Jianan MAO Xiangzhao 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第5期1319-1328,共10页
Chitin is the second most abundant renewable polysaccharide on Earth.The degradation of chitin into soluble and bioactive N-acetyl chitooligosaccharides(NCOSs)and N-acetyl-D-glucosamine(GlcNAc)has emerged as a pivotal... Chitin is the second most abundant renewable polysaccharide on Earth.The degradation of chitin into soluble and bioactive N-acetyl chitooligosaccharides(NCOSs)and N-acetyl-D-glucosamine(GlcNAc)has emerged as a pivotal step in the efficient and sustainable utilization of chitin resources.However,because of its dense structure,high crystallinity,and poor solubility,chitin typically needs pretreatment via chemical,physical,and other methods before enzymatic conversion to enhance the accessibility between substrates and enzyme molecules.Consequently,there has been considerable interest in exploring the direct biological degradation of crystalline chitin as a cost-effective and environment-friendly technology.This review endeavors to present several biological methods for the direct degradation of chitin.We primarily focused on the importance of chitinase containing chitin-binding domain(CBD).Additionally,various modification strategies for increasing the degradation efficiency of crystalline chitin were introduced.Subsequently,the review systematically elucidated critical components of multi-enzyme catalytic systems,highlighting their potential for chitin degradation.Furthermore,the application of microorganisms in the degradation of crystalline chitin was also discussed.The insights in this review contribute to the explorations and investigations of enzymatic and microbial approaches for the direct degradation of crystalline chitin,thereby fostering advancements in biomass conversion. 展开更多
关键词 crystalline chitin CHITINASE biological degradation engineering MICROORGANISMS
下载PDF
BiOBr nanosheets coupling with biomass carbon derived from locust leaves for enhanced photocatalytic degradation of rhodamine B
20
作者 Hongtao Wang Xiangrui Fan +4 位作者 Mingming Yan Tianyu Guo Xingfa Li Chao Chen Yu Qi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期31-43,共13页
A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The... A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The morphology,structure and photoelectrochemical properties of the photocatalysts were characterized by means of SEM,TEM,XRD,XPS,FT-IR,BET,PL,UV-vis/DRS,and EIS techniques.The results showed that the introduction of BC significantly enhanced the photocatalytic activity.When the content of biomass carbon(BC)in a composite is 3%(based on the mass of BiOBr),the obtained BiOBr@BC-3 exhibits excellent photocatalytic activity,degrading 99%of RhB within 20 min.The excellent degradation efficiency after the introduction of BC can be attributed to the enhanced visible light absorption,narrower band gap,and fast electron-hole pair separation rate.The photocatalytic mechanism on the degradation of RhB was illustrated based on the radicals'trapping experiments and semiconductor energy band position.The proposed material is expected to be of significant application value in the field of wastewater treatment. 展开更多
关键词 DEGRADATION Rhodamine B ADSORPTION BiOBr Renewable energy
下载PDF
上一页 1 2 172 下一页 到第
使用帮助 返回顶部