A novel fiber optic sensor based on hydrogel-immobilized enzyme complex was developed for the simultaneous measurement of dual-parameter,the leap from a single parameter detecting fiber optic sensor to a fiber optic s...A novel fiber optic sensor based on hydrogel-immobilized enzyme complex was developed for the simultaneous measurement of dual-parameter,the leap from a single parameter detecting fiber optic sensor to a fiber optic sensor that can continuously detect two kinds of parameters was achieved.By controlling the temperature from high to low,the function of fiber sulfide sensor and fiber DCP sensor can be realized,so as to realize the continuous detection of dual-parameter.The different variables affecting the sensor performance were evaluated and optimized.Under the optimal conditions,the response curves,linear detection ranges,detection limits and response times of the dual-parameter sensor for testing sulfide and DCP were obtained,respectively.The sensor displays high selectivity,good repeatability and stability,which have good potentials in analyzing sulfide and DCP concentration of practical water samples.展开更多
The regularization contributes to the resolution and stability in geophysical inversion. The authors apply dual-parameter shaping regularization to full waveform inversion, aiming at two points ： （ 1 ） improving th...The regularization contributes to the resolution and stability in geophysical inversion. The authors apply dual-parameter shaping regularization to full waveform inversion, aiming at two points ： （ 1 ） improving the boundary resolution, and （2） increasing convergence. Firstly, the forward modeling is done, and the inversion is processed with the optimal solution. Compared with classical Tikhonov regularization scheme, the method re fleets better resolution and stronger convergence. Then, Marmousi model is experimented and inversed, and the deep structure has a sharper outline. The phase residual comparison illustrates weaker cycle-slipping. And a choice scheme of parameter is applied in FWI.展开更多
By using 1-methyl-2-formyl-5 -Y-substituted pyrrole (4-nitrophenyl)hydrazones as a model for nitrogen-containing heterocyclic aromatic compounds, the emission wavelength [lambda(max(em))] values df their fluorescence ...By using 1-methyl-2-formyl-5 -Y-substituted pyrrole (4-nitrophenyl)hydrazones as a model for nitrogen-containing heterocyclic aromatic compounds, the emission wavelength [lambda(max(em))] values df their fluorescence spectra have been measured. Correlation results show that the Delta E-em values are mainly affected by polar effects, but spin-delocalizatin effects also exist.展开更多
For oil and gas pipeline monitoring applications, this paper proposed a dual-parameter fusion distributed fiber optic sensor system that enables distributed temperature and distributed vibration measurements in a sing...For oil and gas pipeline monitoring applications, this paper proposed a dual-parameter fusion distributed fiber optic sensor system that enables distributed temperature and distributed vibration measurements in a single fiber. Through the fiber-scattering spectrum time domain detection combined with coded pulse sequence and Raman scattering spectrum is obtained, which realizes high-resolution temperature measurement and wide-band vibrational wave measurement. The experimental results show that, on 10 km optical fiber measurement, temperature resolution up to 0.1?C and vibration response frequency range 20 Hz - 5 kHz. This sensing system achieves temperature and vibration dual-parameter measurements with fiber optics, greatly simplifying the system and facilitating installation and it can be widely used in oil and gas pipeline monitoring.展开更多
The fluorescence emission wavelength [lambda(max(em))] values of three types of benzaldehyde derivatives, namely, ethylene acetals (1-Ys), 4-nitrophenylhydrazones (2-Ys) and phenylhydrazones (3-Ys), have been measured...The fluorescence emission wavelength [lambda(max(em))] values of three types of benzaldehyde derivatives, namely, ethylene acetals (1-Ys), 4-nitrophenylhydrazones (2-Ys) and phenylhydrazones (3-Ys), have been measured. Correlation analyses by the dual-parameter equation show that the lambda(max(em)) values of 1-Ys are mainly affected by the spin-delocalization effects of the substituents, while those of 2-Ys are mainly affected by the polar effects. However, those of 3-Ys are independent of the substituents.展开更多
The fluorescence quenching coefficient (Ksv) and the quenching rate constant kq of ten para-substituted styrenes (1-Ys) have been measured and correlation-analyzed by both the dual-parameter equation (Eq. 1) with (ρx...The fluorescence quenching coefficient (Ksv) and the quenching rate constant kq of ten para-substituted styrenes (1-Ys) have been measured and correlation-analyzed by both the dual-parameter equation (Eq. 1) with (ρxσx+ρ'σ') and the single-parameter equation (Eq. 2) with ρxσx. Ex-cellent results have been obtained for the correlation of KSV against (ρxσmb+ρ'σ'JJ) or (ρxσ+ +ρ'σ'JJ). Our results suggest that, possibly, there might be no need to use excited-state substituent constant for the fluorecence quenching process of excited states of styrenes.展开更多
Nitrogen hyperfine splitting constants (aN values) of seven symmetrically para-disubstituted diphenyl nitroxides (1-Y's) were measured by EPR and used in conjunction with five literature values in our correlation ...Nitrogen hyperfine splitting constants (aN values) of seven symmetrically para-disubstituted diphenyl nitroxides (1-Y's) were measured by EPR and used in conjunction with five literature values in our correlation analysis. The correlation of these ON values by single-parameter Eq. 1 and dual-parameter Eq. 2 shows that the application of Eq. 2 does not significantly improve the correlation. But our data can also be interpreted by the proposition that the spin-delocalization effect is not completely nonexistent and that it might have revealed itself through the aN values of two very weakly polar substituents with pronounced spin-stabilizing abilities, i.e., SMe and SiMe3.展开更多
In this paper,it is shown that the differential reflectivity Z_(DR) is related to drop size distribution(DSD)and the spectral shape variation of different truncated diameters.Z_(DR) is a sensitive function to variatio...In this paper,it is shown that the differential reflectivity Z_(DR) is related to drop size distribution(DSD)and the spectral shape variation of different truncated diameters.Z_(DR) is a sensitive function to variation of DSD of the spectra.The effects of shape variation of DSD on rainfall can be deduced with a(Z_H,Z_(DR))dual-parameter technique,which is effective to improve the accuracy of rainfall measurement and is of the priority of identifying large particles of hydrometeors(especially hailstone)from the rain region.展开更多
基金Funded by the Natural Science Foundation of Hubei Province(No.2022CFB861)the Wenhua College Research and Innovation Team(No.2022T01)。
文摘A novel fiber optic sensor based on hydrogel-immobilized enzyme complex was developed for the simultaneous measurement of dual-parameter,the leap from a single parameter detecting fiber optic sensor to a fiber optic sensor that can continuously detect two kinds of parameters was achieved.By controlling the temperature from high to low,the function of fiber sulfide sensor and fiber DCP sensor can be realized,so as to realize the continuous detection of dual-parameter.The different variables affecting the sensor performance were evaluated and optimized.Under the optimal conditions,the response curves,linear detection ranges,detection limits and response times of the dual-parameter sensor for testing sulfide and DCP were obtained,respectively.The sensor displays high selectivity,good repeatability and stability,which have good potentials in analyzing sulfide and DCP concentration of practical water samples.
文摘The regularization contributes to the resolution and stability in geophysical inversion. The authors apply dual-parameter shaping regularization to full waveform inversion, aiming at two points ： （ 1 ） improving the boundary resolution, and （2） increasing convergence. Firstly, the forward modeling is done, and the inversion is processed with the optimal solution. Compared with classical Tikhonov regularization scheme, the method re fleets better resolution and stronger convergence. Then, Marmousi model is experimented and inversed, and the deep structure has a sharper outline. The phase residual comparison illustrates weaker cycle-slipping. And a choice scheme of parameter is applied in FWI.
文摘By using 1-methyl-2-formyl-5 -Y-substituted pyrrole (4-nitrophenyl)hydrazones as a model for nitrogen-containing heterocyclic aromatic compounds, the emission wavelength [lambda(max(em))] values df their fluorescence spectra have been measured. Correlation results show that the Delta E-em values are mainly affected by polar effects, but spin-delocalizatin effects also exist.
文摘For oil and gas pipeline monitoring applications, this paper proposed a dual-parameter fusion distributed fiber optic sensor system that enables distributed temperature and distributed vibration measurements in a single fiber. Through the fiber-scattering spectrum time domain detection combined with coded pulse sequence and Raman scattering spectrum is obtained, which realizes high-resolution temperature measurement and wide-band vibrational wave measurement. The experimental results show that, on 10 km optical fiber measurement, temperature resolution up to 0.1?C and vibration response frequency range 20 Hz - 5 kHz. This sensing system achieves temperature and vibration dual-parameter measurements with fiber optics, greatly simplifying the system and facilitating installation and it can be widely used in oil and gas pipeline monitoring.
文摘The fluorescence emission wavelength [lambda(max(em))] values of three types of benzaldehyde derivatives, namely, ethylene acetals (1-Ys), 4-nitrophenylhydrazones (2-Ys) and phenylhydrazones (3-Ys), have been measured. Correlation analyses by the dual-parameter equation show that the lambda(max(em)) values of 1-Ys are mainly affected by the spin-delocalization effects of the substituents, while those of 2-Ys are mainly affected by the polar effects. However, those of 3-Ys are independent of the substituents.
基金Project supported by the National Natural Science Foundation of China
文摘The fluorescence quenching coefficient (Ksv) and the quenching rate constant kq of ten para-substituted styrenes (1-Ys) have been measured and correlation-analyzed by both the dual-parameter equation (Eq. 1) with (ρxσx+ρ'σ') and the single-parameter equation (Eq. 2) with ρxσx. Ex-cellent results have been obtained for the correlation of KSV against (ρxσmb+ρ'σ'JJ) or (ρxσ+ +ρ'σ'JJ). Our results suggest that, possibly, there might be no need to use excited-state substituent constant for the fluorecence quenching process of excited states of styrenes.
基金Project supported by the National Natural Science Foundation of China.
文摘Nitrogen hyperfine splitting constants (aN values) of seven symmetrically para-disubstituted diphenyl nitroxides (1-Y's) were measured by EPR and used in conjunction with five literature values in our correlation analysis. The correlation of these ON values by single-parameter Eq. 1 and dual-parameter Eq. 2 shows that the application of Eq. 2 does not significantly improve the correlation. But our data can also be interpreted by the proposition that the spin-delocalization effect is not completely nonexistent and that it might have revealed itself through the aN values of two very weakly polar substituents with pronounced spin-stabilizing abilities, i.e., SMe and SiMe3.
基金National Disaster Reduction Foundation(96-020-01-07)of China,KZ 951-B1-405 Western Brilliance of the Chinese Academy of Sciences.
文摘In this paper,it is shown that the differential reflectivity Z_(DR) is related to drop size distribution(DSD)and the spectral shape variation of different truncated diameters.Z_(DR) is a sensitive function to variation of DSD of the spectra.The effects of shape variation of DSD on rainfall can be deduced with a(Z_H,Z_(DR))dual-parameter technique,which is effective to improve the accuracy of rainfall measurement and is of the priority of identifying large particles of hydrometeors(especially hailstone)from the rain region.
