Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and The...Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and Thermal Gravity(TG)analysis that the blended material was superior in thermal behaviors to the material made from either Nomex or Viscose FR filament,when the ratio of Nomex and Lenzing Viscose FR reached 80∶20,and excellent thermal properties were achieved with the value of Limiting Oxygen Index(LOI)up to 36.1%.Blending Nomex and Viscose FR filaments may be recommended for better fire retardant property of related fabric.展开更多
In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The ver...In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The vertical burning test showed that the afterflame time of alginate fiber was 0 s, but alginate presented serious smoldering behavior with the afterglow time of 605 s and damaged length of 85 mm, while the afterglow time of FRV was 0 s. When the FRV was incorporated into alginate with the weight ratio of 50/ 50, the afterglow time and damaged length were significantly reduced to 85 s and 35 mm, indicating the smoldering of alginate can be effectively decreased. The morphology and chemical structure of the alginate residual demonstrated that it was seriously destroyed during smoldering process, which was ascribed to its relative low initial thermal degradation temperature. Based on the thermal properties analysis, alginate and FRV fibers shared the concurrence of rapid degradation in the same temperature region of 250-300 ℃, through which, the compact and stable char formed by FRV can prevent the heat transmission and suppress the smoldering of alginate. Further, the cone calorimeter results demonstrated that the time to ignition （TTI） significantly increased and peak heat release rate （PHRR） decreased for alginate/FRV （50/50） compared with FRV. With this research, a new method to overcome the smoldering of alginate was proposed by blending with FRV展开更多
In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in sit...In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in situ condensation reaction so as to suppress their candlewick effect. Fourier transform infrared spectroscopy（FTIR）, X-ray photoelectron spectroscopy（XPS） and scanning electron microscopy（SEM） demonstrated that the ramie fibers wrapped chemically by FR（FR-RF） were obtained successfully. Thermogravimatric test showed that the PP/FR-RF composite had more residue and better thermal stability at high temperatures than the PP/RF composite. Cone calorimeter（CC） results indicated that the peak of heat release rate（PHRR） and total heat release（THR） correspondingly decreased by 23.4% and 12.5% compared with the values of neat PP/RF. The PP/FR-RF composite created a continuous and compact char layer after the combustion. Combining FTIR analysis of char residue after CC test with heat conduction coefficient results, it could be concluded that the charring of FR on RF greatly weakened the candlewick effect of RF, and more char residue in the RF domain facilitated the formation of more continuous and compact char layer in the whole combustion zone, consequently protected PP composites during combustion, resulting in the better flame retardancy of PP/FR-RF composite than that of PP/RF composite.展开更多
A non-halogen highly flame-retardant 0.9mm optical fiber and 2.0mm simplex optical cord, which are harmonized with the ecosystem, have been developed. The characteristics of them are presented in this paper.
文摘Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and Thermal Gravity(TG)analysis that the blended material was superior in thermal behaviors to the material made from either Nomex or Viscose FR filament,when the ratio of Nomex and Lenzing Viscose FR reached 80∶20,and excellent thermal properties were achieved with the value of Limiting Oxygen Index(LOI)up to 36.1%.Blending Nomex and Viscose FR filaments may be recommended for better fire retardant property of related fabric.
基金supported by the Fundamental Research Funds for the Central Universities(No. CUSF-DH-D2016012)
文摘In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The vertical burning test showed that the afterflame time of alginate fiber was 0 s, but alginate presented serious smoldering behavior with the afterglow time of 605 s and damaged length of 85 mm, while the afterglow time of FRV was 0 s. When the FRV was incorporated into alginate with the weight ratio of 50/ 50, the afterglow time and damaged length were significantly reduced to 85 s and 35 mm, indicating the smoldering of alginate can be effectively decreased. The morphology and chemical structure of the alginate residual demonstrated that it was seriously destroyed during smoldering process, which was ascribed to its relative low initial thermal degradation temperature. Based on the thermal properties analysis, alginate and FRV fibers shared the concurrence of rapid degradation in the same temperature region of 250-300 ℃, through which, the compact and stable char formed by FRV can prevent the heat transmission and suppress the smoldering of alginate. Further, the cone calorimeter results demonstrated that the time to ignition （TTI） significantly increased and peak heat release rate （PHRR） decreased for alginate/FRV （50/50） compared with FRV. With this research, a new method to overcome the smoldering of alginate was proposed by blending with FRV
基金financially supported by the National Natural Science Foundation of China(Nos.50933005 and 51121001)the Program for Changjiang Scholars and Innovative Research Team in Universities(IRT1026)
文摘In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in situ condensation reaction so as to suppress their candlewick effect. Fourier transform infrared spectroscopy（FTIR）, X-ray photoelectron spectroscopy（XPS） and scanning electron microscopy（SEM） demonstrated that the ramie fibers wrapped chemically by FR（FR-RF） were obtained successfully. Thermogravimatric test showed that the PP/FR-RF composite had more residue and better thermal stability at high temperatures than the PP/RF composite. Cone calorimeter（CC） results indicated that the peak of heat release rate（PHRR） and total heat release（THR） correspondingly decreased by 23.4% and 12.5% compared with the values of neat PP/RF. The PP/FR-RF composite created a continuous and compact char layer after the combustion. Combining FTIR analysis of char residue after CC test with heat conduction coefficient results, it could be concluded that the charring of FR on RF greatly weakened the candlewick effect of RF, and more char residue in the RF domain facilitated the formation of more continuous and compact char layer in the whole combustion zone, consequently protected PP composites during combustion, resulting in the better flame retardancy of PP/FR-RF composite than that of PP/RF composite.
文摘A non-halogen highly flame-retardant 0.9mm optical fiber and 2.0mm simplex optical cord, which are harmonized with the ecosystem, have been developed. The characteristics of them are presented in this paper.
