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Self-diffusion Coefficient Model Based on Activation Energy and Free Volume
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作者 尹小勇 宋海华 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第6期488-492,共5页
A new model for self-diffusion coefficients was proposed based oil both the concepts of molecular free volume and activation energy. The unknown parameters of this model were clearly defined and compared with the Chap... A new model for self-diffusion coefficients was proposed based oil both the concepts of molecular free volume and activation energy. The unknown parameters of this model were clearly defined and compared with the Chapman-Enskog model. At the same time a new method for calculating activation energy was devised and applied to the new model. In addition, the free volume was defined by implementing the generic van der Waals equation of state, the radial distribution function of which was obtained by using the Morsali- Goharshadi empirical formula. Under the same conditions, the new model was better than the original free volume model. 展开更多
关键词 free volume Potential energy barrier Self-diffusion coefficient Pair correlation function
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Comparison of the Free Volume of LiCl-Added SPPO Membrane and SPPO-PES Blend Membrane by Positron Annihilation Method
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作者 Htwe Htwe YIN 黄环 +1 位作者 唐世彪 马庆力 《Plasma Science and Technology》 SCIE EI CAS CSCD 2007年第5期575-577,共3页
Positron annihilation lifetime spectroscopy (PALS) is a powerful technique for the study of free volume in polymers. The lifetime of ortho-positronium (o-Ps), a bound state of an electron and a positron, can be us... Positron annihilation lifetime spectroscopy (PALS) is a powerful technique for the study of free volume in polymers. The lifetime of ortho-positronium (o-Ps), a bound state of an electron and a positron, can be used to assess the pore size, while the intensity can be used to characterize the number of pores. Based on the values of the long-lived o-Ps components in the lifetime spectra, the radii and fractional free volumes of sulfonated poly (2,6-dimethyl-1,4- phenyleneoxide) (SPPO) membranes with added LiCl and SPPO-PES (Polyethersulfone) blend were compared. Free volume radii in both kinds of membranes are discussed. 展开更多
关键词 positron annihilation free volume pore size SPPO polymer blend
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Investigation of the free volume and ionic conducting mechanism of poly(ethylene oxide)-LiClO_4 polymeric electrolyte by positron annihilating lifetime spectroscopy
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作者 龚静 宫振丽 +3 位作者 闫晓丽 高舒 张忠良 王波 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第10期478-484,共7页
The positron annihilation lifetime and ionic conductivity are each measured as a function of organophilic rectorite(OREC) content and temperature in a range from 160 K to 300 K.According to the variation of ortho-po... The positron annihilation lifetime and ionic conductivity are each measured as a function of organophilic rectorite(OREC) content and temperature in a range from 160 K to 300 K.According to the variation of ortho-positronium(o-Ps) lifetime with temperature,the glassy transition temperature is determined.The continuous maximum entropy lifetime(MELT) analysis clearly shows that the OREC and temperature have important effects on o-Ps lifetime and free volume distribution.The experimental results show that the temperature dependence of ionic conductivity obeys the Vogel-Tammann-Fulcher(VTF) and Williams-Landel-Ferry(WLF) equations,implying a free-volume transport mechanism.A linear least-squares procedure is used to evaluate the apparent activation energy related to the ionic transport in the VTF equation and several important parameters in the WLF equation.It is worthwhile to notice that a direct linear relationship between the ionic conductivity and free volume fraction is established using the WLF equation based on the free volume theory for nanocomposite electrolyte,which indicates that the segmental chain migration and ionic migration and diffusion could be explained by the free volume theory. 展开更多
关键词 POSITRON free volume polymeric electrolyte ionic conduction
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Free Volume Properties of Interpenetrating Polymer Networks Probed by Positron Annihilation
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作者 HE Chun-qing DAI Yi-qun +5 位作者 ZHANG Shao-ping WANG Bo WANG Shao-jie WANG Gui-you HU Chun-pu ( Department of Physics, Wuhan University, Wuhan 430072, China Institute of Material Science and Engineering,East China University of Science and Technology,Shanghai 《Wuhan University Journal of Natural Sciences》 CAS 2000年第1期62-62,共1页
Positron annihilation lifetime (PAL) spectroscopy was applied to investigate the free volume properties of two types of simultaneous interpenetrating polymer networks (SINs), stoichiometric SINs and non--stoichiometri... Positron annihilation lifetime (PAL) spectroscopy was applied to investigate the free volume properties of two types of simultaneous interpenetrating polymer networks (SINs), stoichiometric SINs and non--stoichiometric SINs. PU/VER SINs are all composed of polyurethane(PU) and vinyl ester resin (VER)with different compositions. Mean free volume size in PU/VER deceased with the increase of VER weight percentage, and the relative intensity, relevant to free volume content, increased with VER contents. The effect of chemical bonds between PU networks and VER networks to free volume properties was observed. Results revealed that chemical bonds between the two networks led to molecular denser packing, free volume contraction and made stoichoimetric PU/VER SINs a miscible system. 展开更多
关键词 IPN SIN free volume positron annihilation
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A new model for electromigration grain boundary noise based on free volume
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作者 何亮 杜磊 +4 位作者 庄奕琪 陈华 陈文豪 李伟华 孙鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第9期525-530,共6页
Grain boundary plays a key role in electromigration process of polycrystal interconnection. We take a free volume to represent a 'vacancy-ion complex' as a function of grain boundary specific resistivity, and develo... Grain boundary plays a key role in electromigration process of polycrystal interconnection. We take a free volume to represent a 'vacancy-ion complex' as a function of grain boundary specific resistivity, and develop a new characterisation model for grain boundary noise. This model reveals the internal relation between the boundary scattering section and electromigration noise. Comparing the simulation result with our experimental result, we find the source as well as the form of noise change in the electromigration process. In order to describe the noise enhancement at grain boundary quantitatively, we propose a new parameter--grain boundary noise enhancement factor, which reflects that the grain boundary noise can characterise the electromigration damage sensitively. 展开更多
关键词 free volume ELECTROMIGRATION grain boundary noise
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Gas Permeability and Free Volume Hole Properties of Interpenetrating Polymer Network Studied by Positrons
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作者 QI Ning GONG Wei +3 位作者 WANG Zhifen WANG Bo YANG Yurun HU Chunpu 《Wuhan University Journal of Natural Sciences》 CAS 2007年第2期271-274,共4页
A series of polyurethane/epoxy resin interpenetrating polymer networks (PU/ER IPN) were studied by positron annihilation lifetime spectroscopy (PALS). The effects of epoxy resin type and content on the free volume... A series of polyurethane/epoxy resin interpenetrating polymer networks (PU/ER IPN) were studied by positron annihilation lifetime spectroscopy (PALS). The effects of epoxy resin type and content on the free volume properties in IPN were investigated. We found that in PU/ER IPN, the free volume hole size and fractional free volume showed a negative deviation due to closer segmental chain packing through some chemical bonding between PU and epoxy resin. Direct relationship between the gas permeability and the free volume has been established based on the free volume theory. Experimental results revealed that the free volume plays an important role in determining the gas diffusion and permeability. 展开更多
关键词 interpenetrating polymer network positron annihilation free volume gas permeability
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Prediction of the viscosity of natural gas at high temperature and high pressure using free-volume theory and entropy scaling 被引量:1
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作者 Wei Xiong Lie-Hui Zhang +5 位作者 Yu-Long Zhao Qiu-Yun Hu Ye Tian Xiao He Rui-Han Zhang Tao Zhang 《Petroleum Science》 SCIE EI CSCD 2023年第5期3210-3222,共13页
Eighteen models based on two equations of state(EoS),three viscosity models,and four mixing rules were constructed to predict the viscosities of natural gases at high temperature and high pressure(HTHP)conditions.For ... Eighteen models based on two equations of state(EoS),three viscosity models,and four mixing rules were constructed to predict the viscosities of natural gases at high temperature and high pressure(HTHP)conditions.For pure substances,the parameters of free volume(FV)and entropy scaling(ES)models were found to scale with molecular weight,which indicates that the ordered behavior of parameters of Peng-Robinson(PR)and Perturbed-Chain Statistical Associating Fluid Theory(PC-SAFT)propagates to the behavior of parameters of viscosity model.Predicting the viscosities of natural gases showed that the FV and ES models respectively combined with MIX4 and MIX2 mixing rules produced the best accuracy.Moreover,the FV models were more accurate for predicting the viscosities of natural gases than ES models at HTHP conditions,while the ES models were superior to PRFT models.The average absolute relative deviations of the best accurate three models,i.e.,PC-SAFT-FV-MIX4,tPR-FVMIX4,and PC-SAFT-ES-MIX2,were 5.66%,6.27%,and 6.50%,respectively,which was available for industrial production.Compared with the existing industrial models(corresponding states theory and LBC),the proposed three models were more accurate for modeling the viscosity of natural gas,including gas condensate. 展开更多
关键词 VISCOSITY Friction theory free volume theory Entropy scaling PC-SAFT Equation of state
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Constraints on Characteristics and Distribution of Gas Hydrate and Free Gas Using Broad-Band Processing of Three-Dimensional Seismic Data 被引量:2
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作者 WANG Xiujuan ZHOU Jilin +7 位作者 LI Sanzhong LI Lixia LI Jie LI Yuanping WANG Linfei SU Pibo JIN Jiapeng GONG Zhi 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第5期1233-1247,共15页
Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have ... Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have been confirmed by logging,coring,and production tests in the foraminifera-rich silty sediments with complex bottom-simulating reflectors(BSRs).The broad-band processing is conducted on conventional three-dimensional(3D)seismic data to improve the image and detection accuracy of gas hydratebearing layers and delineate the saturation and thickness of gas hydrate-and free gas-bearing sediments.Several geophysical attributes extracted along the base of the gas hydrate stability zone are used to demonstrate the variable distribution and the controlling factors for the differential enrichment of gas hydrate.The inverted gas hydrate saturation at the production zone is over 40% with a thickness of 90 m,showing the interbedded distribution with different boundaries between gas hydrate-and free gas-bearing layers.However,the gas hydrate saturation value at the adjacent canyon is 70%,with 30-m-thick patches and linear features.The lithological and fault controls on gas hydrate and free gas distributions are demonstrated by tracing each gas hydrate-bearing layer.Moreover,the BSR depths based on broad-band reprocessed 3D seismic data not only exhibit variations due to small-scale topographic changes caused by seafloor sedimentation and erosion but also show the upward shift of BSR and the blocky distribution of the coexistence of gas hydrate and free gas in the Pearl River Mouth Basin. 展开更多
关键词 gas hydrate free gas shift of BSR broad-band processing
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Free radicals trigger the closure of open pores in lignin-derived hard carbons toward improved sodium-storage capacity 被引量:1
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作者 Wen-Jun Ji Zong-Lin Yi +8 位作者 Ming-Xin Song Xiao-Qian Guo Yi-Lin Wang Yi-Xuan Mao Fang-Yuan Su Jing-Peng Chen Xian-Xian Wei Li-Jing Xie Cheng-Meng Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期551-559,共9页
The chemical activation of various precursors is effective for creating additional closed pores in hard carbons for sodium storage.However,the formation mechanism of closed pores under the influence of pore-forming ag... The chemical activation of various precursors is effective for creating additional closed pores in hard carbons for sodium storage.However,the formation mechanism of closed pores under the influence of pore-forming agents is not well understood.Herein,an effective chemical activation followed by a high-temperature self-healing strategy is employed to generate interconnected closed pores in lignin-derived hard carbon(HCs).By systematic experimental design combined with electron paramagnetic res-onance spectroscopy,it can be found that the content of free radicals in the carbon matrix influences the closure of open pores at high temperatures.Excessively high activation temperature(>700 C)leads to a low free radical concentration,making it difficult to achieve self-healing of open pores at high tempera-tures.By activation at 700°C,a balance between pore making and self-healing is achieved in the final hard carbon.A large number of free radicals triggers rapid growth and aggregation of carbon microcrys-tals,blocking pre-formed open micropores and creating additional interconnected closed pores in as-obtained hard carbons.As a result,the optimized carbon anode(LK-700-1300)delivers a high reversible capacity of 330.8 mA h g^(-1) at 0.03 A g^(-1),which is an increase of 86 mA h g^(-1) compared to the pristine lignin-derived carbon anode(L-700-1300),and exhibits a good rate performance(202.1 mA h g^(-1) at 1 A g^(-1)).This work provides a universal and effective guidance for tuning closed pores of hard carbons from otherprecursors. 展开更多
关键词 Hard carbon Chemical activation free radical SELF-HEALING Closed pores Sodium ion batteries
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GLOBAL SOLUTIONS TO 1D COMPRESSIBLE NAVIER-STOKES/ALLEN-CAHN SYSTEM WITH DENSITY-DEPENDENT VISCOSITY AND FREE-BOUNDARY 被引量:1
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作者 丁时进 李颖花 王喻 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期195-214,共20页
This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depen... This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depends on the density in the form ofη(ρ)=ρ^(α).The existence of unique global H^(2m)-solutions(m∈N)to the free boundary problem is proven for when 0<α<1/4.Furthermore,we obtain the global C^(∞)-solutions if the initial data is smooth. 展开更多
关键词 Navier-Stokes/Allen-Cahn system density-dependent viscosity free boundary global solutions
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Metagenomic analysis revealing the metabolic role of microbial communities in the free amino acid biosynthesis of Monascus rice vinegar during fermentation 被引量:1
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作者 Hang Gao Jian Zhang +4 位作者 Li Liu Lijun Fu Yan Zhao Germán Mazza Xin Zhang 《Food Science and Human Wellness》 SCIE CAS CSCD 2024年第4期2317-2326,共10页
Free amino acid(FAA)is the important component of vinegar that infl uences quality perception and consumer acceptance.FAA is one of the major metabolites produced by microorganisms;however,the microbial metabolic netw... Free amino acid(FAA)is the important component of vinegar that infl uences quality perception and consumer acceptance.FAA is one of the major metabolites produced by microorganisms;however,the microbial metabolic network on FAA biosynthesis remains unclear.Through metagenomic analysis,this work aimed to elucidate the roles of microbes in FAA biosynthesis during Monascus rice vinegar fermentation.Taxonomic profiles from functional analyses showed 14 dominant genera with high contributions to the metabolism pathways.The metabolic network for FAA biosynthesis was then constructed,and the microbial distribution in different metabolic pathways was illuminated.The results revealed that 5 functional genera were closely involved in FAA biosynthesis.This study illuminated the metabolic roles of microorganisms in FAA biosynthesis and provided crucial insights into the functional attributes of microbiota in vinegar fermentation. 展开更多
关键词 Monascus rice vinegar Metagenomic analysis free amino acid synthesis Metabolic pathway Microbial distribution
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Assessment of Monitor Units and Gamma Pass Rate for 6 MV and Flattening Filter Free (FFF) Beams in Volumetric Modulated Arc Therapy (VMAT)
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作者 Kwame Anokye Amoabeng Anne Beate Langeland Marthinsen +4 位作者 Francis Hasford Samuel Nii Adu Tagoe Evelyn Anaafi Mark Pokoo-Aikins Theresa Bebaaku Dery 《International Journal of Medical Physics, Clinical Engineering and Radiation Oncology》 2023年第1期1-8,共8页
Background: In linear accelerators, the treatment field’s uniform intensity is achieved by including a flattening filter in the beam. However, to produce more conformal dose distributions, contemporary radiotherapy p... Background: In linear accelerators, the treatment field’s uniform intensity is achieved by including a flattening filter in the beam. However, to produce more conformal dose distributions, contemporary radiotherapy practice now frequently uses fluence and aperture modifying techniques, such as volumetric modulated arc therapy. In these circumstances, the flattening filter in the beam manufacturing process is no longer required. It is therefore necessary to compare the monitor units of 6 MV and flattening filter free plans and how it influences the gamma pass rates to determine which is best for treating cervical cancer with pelvic lymph node metastasis. Methods: VMAT plans for fifteen patients with cervical cancer with pathological pelvic lymph node metastasis were included in this study. Each patient had two VMAT plans using conventional 6 MV beam with flattening filter and one with flattening filter free beam (FFF). The VMAT plans were made using two arcs, and then recalculated to give the planned dose distribution to the detectors in a Delta4 phantom. The VMAT plans were irradiated on the Delta4 phantom using an Elekta linear accelerator (6 MV). Results: The mean monitor unit for the 6 MV plans was 506.3 MU and a standard deviation of 48.6 while that of the FFF plans had a mean MU of 701.5 with a standard deviation of 87.6. The total monitor units (MUs) for the FFF plans were significantly greater than the 6 MV plans (p = 6.1 × 10<sup>-5</sup>). Conclusion: Flattening filter free (FFF) plans require more numbers of monitor units in comparison to conventional 6 MV filtered beams for external radiation of cervical cancer with pelvic lymph nodes involvement. 展开更多
关键词 Monitor Units Gamma Pass Rate Flattening Filter free Multileaf Collimator
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母体产前血清AFP、Freeβ-HCG、uE3检测对筛查胎儿染色体异常的临床价值 被引量:1
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作者 王玉敏 杨可可 张卫云 《青岛医药卫生》 2024年第2期113-116,共4页
目的探讨产前母体血清甲胎蛋白(AFP)、游离β绒毛膜促性腺激素(Free-β-HCG)、雌三醇(uE3)检测对筛查胎儿染色体异常的临床价值。方法选取我院2021年9月—2023年3月100例高风险孕妇进行无创DNA检测,根据染色体状态分为阳性组、阴性组。... 目的探讨产前母体血清甲胎蛋白(AFP)、游离β绒毛膜促性腺激素(Free-β-HCG)、雌三醇(uE3)检测对筛查胎儿染色体异常的临床价值。方法选取我院2021年9月—2023年3月100例高风险孕妇进行无创DNA检测,根据染色体状态分为阳性组、阴性组。对比2组孕12周时血清AFP、Freeβ-HCG、uE3及NT值水平,Logistic回归分析血清各指标对胎儿染色体异常的影响因素;ROC分析孕12周时血清各指标联合检测对胎儿染色体异常的预测价值。结果阳性组孕12周时血清AFP、uE3均低于阴性组、血清Freeβ-HCG及NT值均高于阴性组(P<0.05);分析认为孕12周时血清AFP、uE3为胎儿染色体异常的保护因素、Freeβ-HCG及NT值为胎儿染色体异常的危险因素(P<0.05);ROC分析孕12周时检测母体血清AFP、Freeβ-HCG、uE3水平对预测胎儿染色体异常的AUC分别为0.654、0.673、0.664,其联合检测对预测胎儿染色体异常的AUC为0.717。结论产前母体血清AFP、Freeβ-HCG、uE3联合检测在胎儿染色体异常的筛查中均具有较高的预测价值,3者联合检测的预测效能更高,可广泛应用于早期临床筛查中。 展开更多
关键词 AFP freeβ-HCG UE3 产前筛查 染色体异常
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CONVEXITY OF THE FREE BOUNDARY FOR AN AXISYMMETRIC INCOMPRESSIBLE IMPINGING JET
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作者 王晓慧 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期234-246,共13页
This paper is devoted to the study of the shape of the free boundary for a threedimensional axisymmetric incompressible impinging jet.To be more precise,we will show that the free boundary is convex to the fluid,provi... This paper is devoted to the study of the shape of the free boundary for a threedimensional axisymmetric incompressible impinging jet.To be more precise,we will show that the free boundary is convex to the fluid,provided that the uneven ground is concave to the fluid. 展开更多
关键词 Euler system axisymmetric impinging jet INCOMPRESSIBLE free boundary CONVEXITY
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Practical operating flexibility of a bifunctional freestanding membrane for efficient anion exchange membrane water electrolysis across all current ranges
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作者 Hong-Jin Son Jeemin Hwang +4 位作者 Min Young Choi Seung Hee Park Jae Hyuk Jang Byungchan Han Sung Hoon Ahn 《Carbon Energy》 SCIE EI CAS CSCD 2024年第9期306-324,共19页
This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic conditions.Here,a rapid and mild synthesis technique f... This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic conditions.Here,a rapid and mild synthesis technique for fabricating fibrous membrane-type catalyst electrodes is developed.Our method leverages the contrasting oxidation states between the sulfur-doped NiFe(OH)2 shell and the metallic Ni core,as revealed by electron energy loss spectroscopy.Theoretical evaluations confirm that the S–NiFe(OH)_(2) active sites optimize free energy for alkaline water electrolysis intermediates.This technique bypasses traditional energy-intensive processes,achieving superior bifunctional activity beyond current benchmarks.The symmetric AEM water electrolyzer demonstrates a current density of 2 A cm^(-2) at 1.78 V at 60℃ in 1 M KOH electrolyte and also sustains ampere-scale water electrolysis below 2.0 V for 140 h even in ambient conditions.These results highlight the system's operational flexibility and structural stability,marking a significant advance-ment in AEM water electrolysis technology. 展开更多
关键词 AEM water electrolysis fibrous membrane iR correction free operational stability symmetric configuration
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Performance Analysis of Curved Track G2T-FSO(Ground-to-Train Free Space Optical)Model under Various Weather Conditions
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作者 Mohammed A.Alhartomi Mohammad F.L.Abdullah +5 位作者 Wafi A.B.Mabrouk Mohammed S.M.Gismalla Ahmed Alzahmi Saeed Alzahrani Mohammad R.Altimania Mohammed S.Alsawat 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第12期2087-2105,共19页
The demand for broadband data services on high-speed trains is rapidly growing as more people commute between their homes and workplaces.However,current radio frequency(RF)technology cannot adequately meet this demand... The demand for broadband data services on high-speed trains is rapidly growing as more people commute between their homes and workplaces.However,current radio frequency(RF)technology cannot adequately meet this demand.In order to address the bandwidth constraint,a technique known as free space optics(FSO)has been proposed.This paper presents a mathematical derivation and formulation of curve track G2T-FSO(Ground-to-train Free Space Optical)model,where the track radius characteristics is 2667 m,divergence angle track is 1.5°for train velocity at V=250 km/h.Multiple transmitter configurations are proposed to maximize coverage range and enhance curve track G2T-FSO link performance under varying weather conditions.The curved track G2T-FSO model was evaluated in terms of received power,signal-to-noise ratio(SNR),bit error rate(BER),and eye diagrams.The results showed maximum coverage lengths of 618,505,365,and 240 m for 4Tx/1Rx,3Tx/1Rx,2Tx/1Rx,and 1Tx/1Rx configurations,respectively.The analyzed results demonstrate that the G2T-FSO link can be effectively implemented under various weather conditions. 展开更多
关键词 free space optics curve track ground-to-train communications geometrical loss weather conditions
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Yolk free egg substitute improves the serum phospholipid profile of mice with metabolic syndrome based on lipidomic analysis
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作者 Zhihui Yu Lingyu Fan +3 位作者 Fei Tai Lixin Zhang Xiaoyu Zhang Yisheng Chen 《Food Science and Human Wellness》 SCIE CSCD 2024年第1期482-493,共12页
In this study,the impacts of egg consumption on mice model of metabolic syndrome(Met S)were comparatively investigated.Mice were divided into five groups(n=8):normal diet group(ND),high-fat diet group(HFD),HFD with wh... In this study,the impacts of egg consumption on mice model of metabolic syndrome(Met S)were comparatively investigated.Mice were divided into five groups(n=8):normal diet group(ND),high-fat diet group(HFD),HFD with whole egg group(WE),HFD with free-yolk egg substitute group(YFES),and HFD with lovastatin group(Lov).Main biochemical indexes and a non-targeted lipidomic analysis were employed to insight the lipid profile changes in serum.It was revealed that WE could significantly improve serum biochemical indexes by reducing body weight,low-density lipoprotein cholesterol(LDL-C)and total cholesterol(TC),while increasing high-density lipoprotein cholesterol.YFES exhibited remarkably better performance in increasing phosphatidylglycerol and phosphatidic acids,while decreasing phosphatidylinositol than WE.A total of 50 differential lipids biomarkers tightly related to glycerophospholipids metabolism were screened out.Carnitine C18:2 and C12:1,SM(d18:0/12:0),and SM(d18:1/14:1)were significantly upregulated in YFES compared to WE.YFES reduced expression of SREBP-1c and Cpt1a,while did not affect the expression of PPAR-α.Sphingomyelin biomarkers were positively related to the TC(|r|>0.6),while PPAR-αwas negatively correlated with triglyceride and LDL-C levels.To sum up,YFES attenuated HFD-induced Met S by improving the serum phospholipids,which account for its modulation of glycerophospholipid metabolism. 展开更多
关键词 Metabolic syndrome Whole egg Yolk free egg substitute SERUM LIPIDOMICS
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Evolution of free amino acids, biogenic amines and volatile compounds in fermented sausages inoculated with Lactiplantibacillus plantarum and Staphylococcus simulans
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作者 Xuefei Shao Huhu Wang +3 位作者 Xiangyu Song Mingyuan Huang Jian Sun Xinglian Xu 《Food Science and Human Wellness》 SCIE CAS CSCD 2024年第6期3642-3651,共10页
Lactic acid bacteria and coagulase-negative staphylococci play an important role in the production of fermented sausages,such as inhibiting the growth of undesirable bacteria and antioxidant.In this study,the effects ... Lactic acid bacteria and coagulase-negative staphylococci play an important role in the production of fermented sausages,such as inhibiting the growth of undesirable bacteria and antioxidant.In this study,the effects of inoculation with different starter cultures(Lactiplantibacillus plantarum HN108 and Staphylococcus simulans NJ209)on the free amino acids(FAAs),biogenic amines(BAs)and volatile compounds of fermented sausages were investigated using an amino acid analyzer,ultra performance liquid chromatography and gas chromatography-ion mobility spectrometry,respectively.The pH and carbonyl content of the inoculated group was significantly lower than those in the control group(P<0.05).L.plantarum HN108 significantly reduced the content of FAAs and BAs in fermented sausage production(P<0.05),while S.simulans NJ209 promoted the formation of FAAs(especially bitter amino acids)and exhibited slight BAs-reducing activity.In addition,L.plantarum HN108 promoted the formation of volatile compounds such as ketones,alcohols and alkenes in sausages.In conclusion,L.plantarum HN108 could contribute to reducing the content of putrescine and tyramine and forming the desirable flavor compounds in fermented sausages.Thus,L.plantarum HN108 is expected to be a starter culture that can improve the safety and flavor of fermented sausages. 展开更多
关键词 Fermented sausages Starter cultures free amino acids Biogenic amines Volatile compounds
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Lithium-Metal Free Sulfur Battery Based on Waste Biomass Anode and Nano-Sized Li_(2)S Cathode
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作者 Pejman Salimi Eleonora Venezia +6 位作者 Somayeh Taghavi Sebastiano Tieuli Lorenzo Carbone Mirko Prato Michela Signoretto Jianfeng Qiu Remo Proietti Zaccaria 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期39-47,共9页
The realization of a stable lithium-metal free(LiMF)sulfur battery based on amorphous carbon anode and lithium sulfide(Li_(2)S)cathode is here reported.In particular,a biomass waste originating full-cell combining a c... The realization of a stable lithium-metal free(LiMF)sulfur battery based on amorphous carbon anode and lithium sulfide(Li_(2)S)cathode is here reported.In particular,a biomass waste originating full-cell combining a carbonized brewer's spent grain(CBSG)biochar anode with a Li_(2)S-graphene composite cathode(Li_(2)S70Gr30)is proposed.This design is particularly attractive for applying a cost-effective,high performance,environment friendly,and safe anode material,as an alternative to standard graphite and metallic lithium in emerging battery technologies.The anodic and cathodic materials are characterized in terms of structure,morphology and composition through X-ray diffraction,scanning and transmission electron microscopy,X-ray photoelectron and Raman spectroscopies.Furthermore,an electrochemical characterization comprising galvanostatic cycling,rate capability and cyclic voltammetry tests were carried out both in half-cell and full-cell configurations.The systematic investigation reveals that unlike graphite,the biochar electrode displays good compatibility with the electrolyte typically employed in sulfur batteries.The CBSG/Li_(2)S70Gr30 full-cell demonstrates an initial charge and discharge capacities of 726 and 537 mAh g^(-1),respectively,at 0.05C with a coulombic efficiency of 74%.Moreover,it discloses a reversible capacity of 330 mAh g^(-1)(0.1 C)after over 300 cycles.Based on these achievements,the CBSG/Li_(2)S70Gr30 battery system can be considered as a promising energy storage solution for electric vehicles(EVs),especially when taking into account its easy scalability to an industrial level. 展开更多
关键词 biochars ether-based electrolytes lithium sulfide lithium-metal free batteries superior cycling stability
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Study on Free-Standing Riser Under Different Working Conditions Based on 3D Co-Rotational Beam Element
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作者 HUANG Chen GU Ji-jun +3 位作者 JIA Ji-chuan CHEN Lei-lei WANG Shu-jiang GAO Lei 《China Ocean Engineering》 SCIE EI CSCD 2024年第5期725-738,共14页
When the free standing riser(FSR)is in service in the ocean,its mechanical properties are affected by various factors,including complex ocean current forces,buoyancy of the buoyancy can,and torque caused by the deflec... When the free standing riser(FSR)is in service in the ocean,its mechanical properties are affected by various factors,including complex ocean current forces,buoyancy of the buoyancy can,and torque caused by the deflection of the upper floating body.These loads have a great influence on the deformation and internal force of the FSR.The static performance of FSR is investigated in this research under various working conditions.The finite element model of FSR is established based on the co-rotational method.The arc length approach is used to solve the model.The load is exerted in increments.The current load on the riser changes with the configuration of the riser.The accuracy of the numerical method is verified by Abaqus software.The calculation time is also compared.Then,the effects of uniform current,actual current and floating body yaw motion on FSR are studied by parameter analysis.Additionally,the influence of the FSR on the ocean current after the failure of part of the buoyancy can chamber is analyzed.The results show that the numerical model based on the co-rotational method can effectively simulate the large rotation and torsion behavior of FSR.This method has high computational efficiency and precision,and this method can quickly improve the efficiency of numerical calculation of static analysis of deep-water riser.The proposed technology may serve as an alternative to the existing proprietary commercial software,which uses a complex graphical user interface. 展开更多
关键词 free standing riser(FSR) co-rotational method finite element method ocean current nonlinear analysis TORSION
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