Decomposition of ammonium sulfate residue in a high solid/gas ratio suspension state with an industrial-scale reactor system(production line)

Ammonium sulfate residue is a particulate solid and is produced during the manufacture of ammonium sulfate fertilizer. The residue used in this study contained a large portion of calcium carbonate, from which active lime （CaO） was recovered via thermal decomposition. We used a purpose-built device to decom- pose the residue in a semi-suspension state. We found that CaO had the highest activity when residue was decomposed at 850-900 ~C. Our experiments indicated that ammonium sulfate residue should be decom- posed in a suspension state to produce active CaO. Based on our laboratory test findings, an industrial-scale production line with a high solid/gas ratio in a suspension state was devised. The optimal operating con- ditions for the decomposition of the ammonium sulfate residue to produce high quality CaO were also investigated.We found that the CaCO3 decomposition rate was high and the CaO product was highly active, averaging 170 s by the citric acid method. Morphology measurements showed that the CaO product had a porous structure and a large specific surface ensuring high activity.

Influence of the Gas Mixture Ratio on the Correlations Between the Excimer XeCl Emission and the Sealed Gas Temperature in Dielectric Barrier Discharge Lamps

For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.

Applying Improved Electrical Breakdown Model to Study Insulating Property of c-C_4F_8/N_2 Gas Mixture

Perfluorocyclobutane(c-C4F8) has been recently considered as a potential alternative to SF6,because of its high electro-negativity and extremely low environmental effect.However,due to its high boiling point,c-C4F8 should mixed with buffer gases such as N2 or CO2 in order to avoid the liquefaction at low temperature.This paper investigates insulating properties of c-C4F8/N2 gas mixtures from two aspects including electrical strength,and Global Warming Potential(GWP).Moreover,improved electrical breakdown model of gas mixtures is founded.Breakdown temperature and breakdown electrical field in gas mixtures can be obtained from rigorous Townsend criterion expression according to gas mixtures ratio and cross section data of gas mixtures in this model.Under the condition of different gas pressure(0.1~0.4 MPa),gas mixtures ratio(0～30%),and electrode gap(2~10 mm),breakdown voltages of gas mixtures are calculated by using of this model.Insulation strength of SF6/N2 mixed gas is compared with c-C4F8/N2 mixed gas in the same conditions.Research results show that theoretical computation corresponds with experiment.If the content of c-C4F8 or SF6 in mixtures is less than 30%,insulation strength between c-C4F8/N2 and SF6/N2 is very close.Considering two indexes(breakdown voltage,GWP),it is suitable for c-C4F8 content being 15%～20% in c-C4F8/N2 gas

Riemann problem for one-dimensional binary gas enhanced coalbed methane process

With an extended Langmuir isotherm, a Riemann problem for one-dimensional binary gas enhanced coalbed methane (ECBM) process is investigated. A new analytical solution to the Riemann problem, based on the method of characteristics, is developed by introducing a gas selectivity ratio representing the gas relative sorption affinity. The influence of gas selectivity ratio on the enhanced coalbed methane processes is identified.

Saturation Ion Current Densities in Inductively Coupled Hydrogen Plasma Produced by Large-Power Radio Frequency Generator

An experimental investigation of the saturation ion current densities （Jions） in hydrogen inductively coupled plasma （ICP） produced by a large-power （2-32 kW） radio frequency （RF） generator is reported, then some reasonable explanations are given out. With the increase of RF power, the experimental results show three stages： in the first stage （2-14 kW）, the electron temperature will rise with the increase of RF power in the ICP, thus, the Jions increases continually as the electron temperature rises in the ICP. In the second stage （14 20 kW）, as some H- ions lead to the mutual neutralization （MN）, the slope of Jio^s variation firstly decreases then increases. In the third stage （20-32 kW）, both the electronic detachment （ED） and the associative detachment （AD） in the ICP result in the destruction of H- ions, therefore, the increased amplitude of the Jions in the third stage is weaker than the one in the first stage. In addition, with the equivalent transformer model, we successfully Explain that the Jions at different radial locations in ICP has the same rule. Finally, it is found that the Jions has nothing to do with the outer/inner puffing gas pressure ratio, which is attributed to the high-speed movement of hydrogen molecules.

Thermodynamic behaviors of SiCl_2 in silicon deposition by gas phase zinc reduction of silicon tetrachloride

The modified Siemens process,which is the major process of producing polycrystalline silicon through current technologies,is a high temperature,slow,semi-batch process and the product is expensive primarily due to the large energy consumption.Therefore,the zinc reduction process,which can produce solar-grade silicon in a cost effective manner,should be redeveloped for these conditions.The SiCl2 generation ratio,which stands for the degree of the side reactions,can be decomposed to SiCl4 and ZnCl2 in gas phase zinc atmosphere in the exit where the temperature is very low.Therefore,the lower SiCl2 generation ratio is profitable with lower power consumption.Based on the thermodynamic data for the related pure substances,the relations of the SiCl2 generation ratio and pressure,temperature and the feed molar ratio（n（Zn）/n（SiCl4） are investigated and the graphs thereof are plotted.And the diagrams of Kpθ-T at standard atmosphere pressure have been plotted to account for the influence of temperature on the SiCl2 generation ratio.Furthermore,the diagram of Kpθ-T at different pressures have also been plotted to give an interpretation of the influence of pressure on the SiCl2 generation ratio.The results show that SiCl2 generation ratio increases with increasing temperature,and the higher pressure and excess gas phase zinc can restrict SiCl2 generation ratio.Finally,suitable operational conditions in the practical process of polycrystalline silicon manufacture by gas phase zinc reduction of SiCl4 have been established with 1200 K,0.2 MPa and the feed molar ratio（n（Zn） /n（SiCl4）） of 4 at the entrance.Under these conditions,SiCl2 generation ratio is very low,which indicates that the side reactions can be restricted and the energy consumption is reasonable.

Implementation of multilayer perceptron(MLP)and radial basis function(RBF)neural networks to predict solution gas-oil ratio of crude oil systems

Exact determination of pressure-volume-temperature(PVT)properties of the reservoir oils is necessary for reservoir calculations,reservoir performance prediction,and the design of optimal production conditions.The objective of this study is to develop intelligent and reliable models based on multilayer perceptron(MLP)and radial basis function(RBF)neural networks for estimating the solution gas–oil ratio as a function of bubble point pressure,reservoir temperature,oil gravity(API),and gas specific gravity.These models were developed and tested using a total of 710 experimental data sets representing the samples of crude oil from various geographical locations around the world.Performance of the developed MLP and RBF models were evaluated and investigated against a number of well-known empirical correlations using statistical and graphical error analyses.The results indicated that the proposed models outperform the considered empirical correlations,providing a strong agreement between predicted and experimental values,However,the developed RBF exhibited higher accuracy and efficiency compared to the proposed MLP model.

Crude oil cracking in deep reservoirs:A review of the controlling factors and estimation methods

The natural cracking of crude oils in deep reservoirs has gained great interest due to continuously increasing depth of petroleum exploration and exploitation.Complex oil compositions and surroundings as well as complicated geological evolutions make oil cracking in nature much more complex than industrial pyrolysis.So far,numerous studies,focused on this topic,have made considerable progress although there still exist some drawbacks.However,a comprehensive review on crude oil cracking is yet to be conducted.This article systematically reviews the controlling factors of oil cracking from six aspects,namely,oil compositions,temperature and time,pressure,water,minerals and solid organic matter.We compare previous experimental and modelling results and present new field cases.In the following,we evaluate the prevailing estimation methods for the extent of oil cracking,and elucidate other factors that may interfere with the application of these estimation methods.This review will be helpful for further investigations of crude oil cracking and provides a guide for estimation of the cracking extent of crude oils.

A new design of foam spray nozzle used for precise dust control in underground coal mines

In order to improve the utilization rate of foam,an arc jet nozzle was designed for precise dust control.Through theoretical analysis,the different demands of foam were compared amongst arc jets,flat jets and full cone jets when the dust source was covered identically by foam.It is proved that foam consumption was least when an arc jet was used.Foam production capability of an arc jet nozzle under different conditions was investigated through experiments.The results show that with the gas liquid ratio(GLR)increasing,the spray state of an arc jet nozzle presents successively water jet,foam jet and mist.Under a reasonable working condition range of foam production and a fixed GLR,foam production quantity increases at first,and then decreases with the increase of liquid supply quantity.When the inner diameter of the nozzle is 14 mm,the best GLR is 30 and the optimum liquid supply quantity is0.375 m^3/h.The results of field experiments show that the total dust and respirable dust suppression efficiency of arc jet nozzles is 85.8%and 82.6%respectively,which are 1.39 and 1.37 times higher than the full cone nozzles and 1.20 and 1.19 times higher than the fiat nozzles.

Carbon isotopic fractionation during vaporization of low molecular weight hydrocarbons(C6–C12)

Three series of laboratory vaporization experiments were conducted to investigate the carbon isotope fractionation of low molecular weight hydrocarbons（LMWHs）during their progressive vaporization.In addition to the analysis of a synthetic oil mixture,individual compounds were also studied either as pure single phases or mixed with soil.This allowed influences of mixing effects and diffusion though soil on the fractionation to be elucidated.The LMWHs volatilized in two broad behavior patterns that depended on their molecular weight and boiling point.Vaporization significantly enriched the ^13C present in the remaining components of the C6–C9 fraction,indicating that the vaporization is mainly kinetically controlled;the observed variations could be described with a Rayleigh fractionation model.In contrast,the heavier compounds（n-C10–n-C12）showed less mass loss and almost no significant isotopic fractionation during vaporization,indicating that the isotope characteristics remained sufficiently constant for these hydrocarbons to be used to identify the source of an oil sample,e.g.,the specific oil field or the origin of a spill.Furthermore,comparative studies suggested that matrix effects should be considered when the carbon isotope ratios of hydrocarbons are applied in the field.

Fouling Characteristics and Prevention Techniques for Membrane Bioreactor

Membrane fouling is the main problem of membrane bioreactors (MBR), which seriously influ- ences its wastewater treatment effect and running. The characteristics of microbiology and hydrodynamics concerning membrane fouling were investigated and the measure was put forward for optimum operation of MBR. The measure is that 1) the parameters of activated sludge concentration (X) and membrane flux should be lower than the critical values of X and membrane flux respectively, and 2) the activated sludge should be discharged periodically. The experimental results show that the combination backwashing of gas and perme- ated effluent is better than single gas backwashing or single permeated effluent backwashing. This technique can remove the cake layer deposited on the membrane surface, decrease the membrane fouling, and recover the membrane flux effectively. So it is effective for prevention of membrane fouling.

Determination of energy use efficiency and greenhouse gas emissions in peach production

The purpose of this study was to determine the energy use efficiency and greenhouse gas(GHG)emissions in peach production that took place in Kırklareli province of Turkey during the 2020-2021 production season.This study included calculations of energy input,energy output,energy use efficiency,specific energy,energy productivity,net energy,energy input types,GHG emissions and GHG ratio.Survey,observation and data calculations are related to the 2020-2021 production season.The data obtained from the study were collected from 16 different farms(reachable)through face-to-face surveys with full count method.Energy input and energy output were calculated as 19570.58 MJ/hm^(2) and 19471.94 MJ/hm^(2),respectively.With regards to production inputs,55.70% of the energy inputs consisted of chemical fertilizers energy(10900.03 MJ/hm^(2)),9.46% consisted of chemicals energy(1852.10 MJ/hm^(2)),9.32% consisted of human labour energy(1823.13 MJ/hm^(2)),7.65% consisted of electricity energy(1497.28 MJ/hm^(2)),6.91% consisted of diesel fuel energy(1351.52 MJ/hm^(2)),4.73% consisted of irrigation water energy(926.10 MJ/hm^(2)),3.43% consisted of machinery energy(671.98 MJ/hm^(2)),1.88% consisted of transportation energy(367.72 MJ/hm^(2)),0.88% consisted of farmyard manure energy(171.80 MJ/hm^(2))and 0.05%consisted of lime energy(8.94 MJ/hm^(2)).Energy use efficiency,specific energy,energy productivity and net energy were calculated as 0.99,1.91 MJ/kg,0.52 kg/MJ and-98.64 MJ/hm^(2),respectively.The consumed total energy input in production was classified as 28.60% direct energy,71.40% indirect energy,14.93% renewable energy and 85.07% non-renewable.Total GHG emissions and GHG ratio were calculated as 1683.24 kgCO_(2)-eq/hm^(2) and 0.16 kg CO_(2)-eq/kg,respectively.

MILD Combustion for Hydrogen and Syngas at Elevated Pressures

As gas recirculation constitutes a fundamental condition for the realization of MILD combustion, it is necessary to determine gas recirculation ratio before designing MILD combustor. MILD combustion model with gas recirculation was used in this simulation work to evaluate the effect of fuel type and pressure on threshold gas recirculation ratio of MILD mode. Ignition delay time is also an important design parameter for gas turbine combustor, this parameter is kinetically studied to analyze the effect of pressure on MILD mixture ignition. Threshold gas recirculation ratio of hydrogen MILD combustion changes slightly and is nearly equal to that of 10 MJ/Nm3syngas in the pressure range of 1-19 atm, under the conditions of 298 K fresh reactant temperature and 1373 K exhaust gas temperature, indicating that MILD regime is fuel flexible. Ignition delay calculation results show that pressure has a negative effect on ignition delay time of 10 MJ/Nm3syngas MILD mixture, because OH mole fraction in MILD mixture drops down as pressure increases, resulting in the delay of the oxidation process.

Gas selectivity of SILAR grown CdS nano-bulk junction

Nano-particles of cadmium sulphide were deposited on cleaned copper substrate by an automated se- quential ionic layer adsorption reaction （SILAR） system. The grown nano-bulk junction exhibits Schottky diode behavior. The response of the nano-bulk junction was investigated under oxygen and hydrogen atmospheric condi- tions. The gas response ratio was found to be 198% for Oxygen and 34% for Hydrogen at room temperature. An increase in the operating temperature of the nano-bulk junction resulted in a decrease in their gas response ratio. A logarithmic dependence on the oxygen partial pressure to the junction response was observed, indicating a Temkin isothermal behavior. Work function measurements using a Kelvin probe demonstrate that the exposure to an oxy- gen atmosphere fails to effectively separate the charges due to the built-in electric field at the interface. Based on the benefits like simple structure, ease of fabrication and response ratio the studied device is a promising candidate for gas detection applications.

An investigation of reaction furnace temperatures and sulfur recovery

In a modern day sulfur recovery unit(SRU),hydrogen sulfide(H_(2)S)is converted to elemental sulfur using a modified Claus unit.A process simulator called TSWEET has been used to consider the Claus process.The effect of the H_(2)S concentration,the H_(2)S/CO_(2) ratio,the input airflow rate,the acid gasflow of the acid gas(AG)splitter and the temperature of the acid gas feed at three different oxygen concentrations(in the air input)on the main burner temperature have been studied.Also the effects of the tail gas ratio and the catalytic bed type on the sulfur recovery were studied.The bed temperatures were optimized in order to enhance the sulfur recovery for a given acid gas feed and air input.Initially when the fraction of AG splitterflow to the main burner was increased,the temperature of the main burner increased to a maximum but then decreased sharply when theflow fraction was further increased;this was true for all three concentrations of oxygen.However,if three other parameters(the concentration of H_(2)S,the ratio H_(2)S/CO_(2) and theflow rate of air)were increased,the temperature of the main burner increased monotonically.This increase had differ-ent slopes depending on the oxygen concentration in the input air.But,by increasing the temperature of the acid gas feed,the temperature of the main burner decreased.In general,the concentration of oxygen in the input air into the Claus unit had little effect on the temperature of the main burner(This is true for all parameters).The optimal catalytic bed temperature,tail gas ratio and type of catalytic bed were also determined and these conditions are a minimum temperature of 300°C,a ratio of 2.0 and a hydrolysing Claus bed.

Data driven prediction of oil reservoir fluid properties

Accuracy of the fluid property data plays an absolutely pivotal role in the reservoir computational processes.Reliable data can be obtained through various experimental methods,but these methods are very expensive and time consuming.Alternative methods are numerical models.These methods used measured experimental data to develop a representative model for predicting desired parameters.In this study,to predict saturation pressure,oil formation volume factor,and solution gas oil ratio,several Artificial Intelligent(AI)models were developed.582 reported data sets were used as data bank that covers a wide range of fluid properties.Accuracy and reliability of the model was examined by some statistical parameters such as correlation coefficient(R2),average absolute relative deviation(AARD),and root mean square error(RMSE).The results illustrated good accordance between predicted data and target values.The model was also compared with previous works and developed empirical correlations which indicated that it is more reliable than all compared models and correlations.At the end,relevancy factor was calculated for each input parameters to illustrate the impact of different parameters on the predicted values.Relevancy factor showed that in these models,solution gas oil ratio has greatest impact on both saturation pressure and oil formation volume factor.In the other hand,saturation pressure has greatest effect on solution gas oil ratio.

Developing an authentication approach using SPME-GC-IRMS based on compound-specific δ^(13)C analysis of six typical volatiles in wine

An analytical method using gas chromatography isotope ratio mass spectrometry(GC-IRMS)combined with solid phase micro-extraction(SPME)was developed to measure the 613C values of six typical volatiles commonly occurring in wine(isoamyl acetate,2-octanone,limonene,2-phenylethanol,ethyl octanoate and ethyl decanoate)for the first time.SPME selected with a divinylbenzene/carboxen/polydimethylsiloxane fiber was combined with the GC-IRMS for pretreatment optimization.The optimized SPME parameters of extraction time,extraction temperature and salt concentration were 40 min,40℃ and 10%,respectively.The 613C values measured by SPME-GC-IRMS were in good agreement with those measured via elemental analyzer(EA)-IRMS and GC-IRMS.The differences range from 0.02‰to 0.44‰ with EA-IRMS and from 0 to 0.28‰ with GC-IRMS,indicating the high accuracy of the method.This newly established method measured the precision within 0.30‰ and was successfully validated to discriminate imported real wine samples with identical label but amazing price differences from different importers.

A new heuristic model for estimating the oil formation volume factor

The necessity of oil formation volume factor(Bo)determination does not need to be greatly emphasized.Different types of reservoir oil have specific conditions which impart the hydrocarbon's major properties,among which is the oil formation volume factor.Therefore,it seems imperative to construct a model capable of estimating the value of oil formation volume factor.Previous studies have resulted in a number of correlations for oil formation volume factor estimation;however,a large portion of them do not provide an acceptable accuracy(at least in some range of data)and cause a huge error at these points.Some others are not flexible enough to be tuned for a specific type of reservoir oil and a comprehensive piece of work does not exist as well in order to compare the applicability of the new models for estimating the oil formation volume factor.In this research,a model based on simulated annealing(SA)has been built in terms of temperature,solution gas-oil ratio,and gravity of oil and gas to predict the oil formation volume factor.This model is compared with the models proposed in the most recent studies,which shows the greater performance of the new method.In addition,in this paper the models of the recent years were compared with each other and their applicability were discussed.Aiming to compare the models,420 data points were selected and the estimated values of each model for oil formation volume factor were compared with their experimental ones.

Accumulation mechanism of mantle-derived helium resources in petroliferous basins, eastern China

A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate.Different types of helium-rich natural gas reservoirs(He>1000 ppm,1 ppm=1μmol mol^(-1))have been found in these basins:helium-rich CO_(2)gas reservoirs,helium-rich N_(2)gas reservoirs,and helium-rich hydrocarbon gas reservoirs.Based on the analysis of gas geochemical data,the source and accumulation mechanism of helium in these heliumrich natural gas reservoirs were discussed.Helium-rich natural gas has relatively high 3He/4He ratios(0.88-4.91 Ra,average 2.82 Ra).The ^(3)He/^(4)He ratio characteristics of mantle xenoliths and mantle-derived CO_(2)gas reservoirs indicate that the helium in these helium-rich natural gas reservoirs is mainly mantle-derived(>70%).The original mantle volatile is mainly CO_(2)with a low helium concentration(He<200 ppm),and the enrichment of mantle-derived helium in the gas reservoir is mainly related to the dissolution and mineralization of CO_(2).During this process,the CO_(2)/3He ratio decreases from 2×10^(9)to approximately 2×10^(6).As CO_(2)dissolves and mineralizes,the concentration of conservative gases(He and N_(2))increases in the remaining CO_(2)gas proportionally to the loss of CO_(2).Large amounts of carbonate minerals,such as dawsonite,which are relatively enriched in 13C,are found in CO_(2)reservoirs in eastern China.The relative enrichment of^(12)C in residual CO_(2)gas is important evidence of the dissolution and mineralization of CO_(2).The relative abundance of mantle-derived helium and N_(2)gas increases thousands of times during the dissolution and mineralization of CO_(2),which is the main accumulation mechanism of mantle-derived helium-rich CO_(2)gas reservoirs and helium-rich N_(2)gas reservoirs.Helium-rich gas from the mantle is mixed with alkane gas generated by organic matter in the sedimentary basin to form helium-rich hydrocarbon gas reservoirs.