Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid)(PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and l...Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid)(PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature(Tg). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer(RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.展开更多
The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as ...The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as the representative of small organics. The effects of phenol on adsorption equilibrium, kinetics and thermodynamics were studied systematically. The results indicate that APTC is a potential adsorbent for MG. The presence of phenol decreases the adsorption capacity of APTC for MG, but improves the rate of adsorption, while the adsorption characteristics, such as equilibrium, kinetics and thermodynamics are not affected by phenol. The adsorption equilibrium data follow Langmuir isotherm and the kinetic data are well described by the pseudo-second-order kinetic model. The adsorption process follows intra-particle diffusion model and the adsorption rate is determined by more than one process. Thermodynamic study shows that the adsorption is an endothermic and spontaneous physisorption process.展开更多
The simulation of 295/80R22. 5 tire building process from tire building to curing was developed using ABAQUS software,which covered four stages: gluing of components on main drum,gluing of components on auxiliary drum...The simulation of 295/80R22. 5 tire building process from tire building to curing was developed using ABAQUS software,which covered four stages: gluing of components on main drum,gluing of components on auxiliary drum,building process of green tire and shaping process of green tire. Results showed that material distribution of the simulated structure had good consistence with the real tire structure. Therefore,the tire building process simulation can be used to judge the rationality of tire construction design and to determine the shapes of different tire components. In order to optimize the construction design,a reverse simulation method was proposed to design the semi-product components such as apex,tread,and shoulder pad. The semi-product components determined by utilizing the reverse simulation method were assembled again into a tire. Results show that the simulated material distribution is consistent with the material distribution of design tire,which proves effectiveness and reliability of the reverse simulation method.展开更多
基金supported by the National Natural Science Foundation of China(50933001,51221102)the National Science Fund for Distinguished Young Scholars(50725310)+3 种基金the National Basic Research Program of China(2011 CB606003)the Beijing Nova Program(Z131102000413015)the Beijing Municipal Training Program Foundation for the Talents(2013D003034 00041)the Goodyear Tire & Rubber Company
文摘Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid)(PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature(Tg). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer(RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.
基金Supported by National Key Technologies R&D Program of China(No.2006BAC02A12)
文摘The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as the representative of small organics. The effects of phenol on adsorption equilibrium, kinetics and thermodynamics were studied systematically. The results indicate that APTC is a potential adsorbent for MG. The presence of phenol decreases the adsorption capacity of APTC for MG, but improves the rate of adsorption, while the adsorption characteristics, such as equilibrium, kinetics and thermodynamics are not affected by phenol. The adsorption equilibrium data follow Langmuir isotherm and the kinetic data are well described by the pseudo-second-order kinetic model. The adsorption process follows intra-particle diffusion model and the adsorption rate is determined by more than one process. Thermodynamic study shows that the adsorption is an endothermic and spontaneous physisorption process.
基金National Natural Science Foundation of China (No.51405201)
文摘The simulation of 295/80R22. 5 tire building process from tire building to curing was developed using ABAQUS software,which covered four stages: gluing of components on main drum,gluing of components on auxiliary drum,building process of green tire and shaping process of green tire. Results showed that material distribution of the simulated structure had good consistence with the real tire structure. Therefore,the tire building process simulation can be used to judge the rationality of tire construction design and to determine the shapes of different tire components. In order to optimize the construction design,a reverse simulation method was proposed to design the semi-product components such as apex,tread,and shoulder pad. The semi-product components determined by utilizing the reverse simulation method were assembled again into a tire. Results show that the simulated material distribution is consistent with the material distribution of design tire,which proves effectiveness and reliability of the reverse simulation method.
