In this study,a novel series of chiral 1,2-propanediol derivatives with different electron-donating and electron-withdrawing groups were synthesized and characterized by FT-IR and ~1H NMR.The helical twisting properti...In this study,a novel series of chiral 1,2-propanediol derivatives with different electron-donating and electron-withdrawing groups were synthesized and characterized by FT-IR and ~1H NMR.The helical twisting properties of all the chiral dopants were investigated by doping the chiral dopants into a nematic liquid crystal host（SLC-1717）.The results indicate that the donor-acceptor electron effect have a prominent influence on helical twisting property of the chiral nematic phase induced by the chiral dopants. Introducing electron-withdrawing groups into the terminal ends of chiral 1,2-propanediol can decrease the absolute values of the helical twisting power.In addition,the helix inversion temperatures of the induced chiral nematic phase are variational with the change of terminal groups.展开更多
Optical orbital angular momentum(OAM) is a special property of photons and has evoked research onto the light–matter interaction in both classical and quantum regimes. In classical optics, OAM is related to an optica...Optical orbital angular momentum(OAM) is a special property of photons and has evoked research onto the light–matter interaction in both classical and quantum regimes. In classical optics, OAM is related to an optical vortex with a helical phase structure. In quantum optics, photons with a twisted or helical phase structure will carry a quantized OAM. To our knowledge, however, so far, no experiment has demonstrated the fundamental property of the OAM at the single-photon level. In this Letter, we have demonstrated the average photon trajectories of twisted photons in a double-slit interference. We have experimentally captured the double-slit interference process of twisted photons by a time-gated intensified charge-coupled device camera, which is trigged by a heralded detection. Our work provides new perspectives for understanding the micro-behaviors of twisted particles and enables new applications in imaging and sensing.展开更多
基金supported in part by the National Natural Science Foundation of China(No.51173155)the Hebei Province Science Foundation of China(No.E2010001182)
文摘In this study,a novel series of chiral 1,2-propanediol derivatives with different electron-donating and electron-withdrawing groups were synthesized and characterized by FT-IR and ~1H NMR.The helical twisting properties of all the chiral dopants were investigated by doping the chiral dopants into a nematic liquid crystal host（SLC-1717）.The results indicate that the donor-acceptor electron effect have a prominent influence on helical twisting property of the chiral nematic phase induced by the chiral dopants. Introducing electron-withdrawing groups into the terminal ends of chiral 1,2-propanediol can decrease the absolute values of the helical twisting power.In addition,the helix inversion temperatures of the induced chiral nematic phase are variational with the change of terminal groups.
基金supported by the National Key R&D Program of China (Nos. 2017YFA0303800 and 2017YFA0303700)the National Natural Science Foundation of China (Nos. 11534006,11674184,and 11774183)+1 种基金the Natural Science Foundation of Tianjin(No. 16JCZDJC31300)the Collaborative Innovation Center of Extreme Optics
文摘Optical orbital angular momentum(OAM) is a special property of photons and has evoked research onto the light–matter interaction in both classical and quantum regimes. In classical optics, OAM is related to an optical vortex with a helical phase structure. In quantum optics, photons with a twisted or helical phase structure will carry a quantized OAM. To our knowledge, however, so far, no experiment has demonstrated the fundamental property of the OAM at the single-photon level. In this Letter, we have demonstrated the average photon trajectories of twisted photons in a double-slit interference. We have experimentally captured the double-slit interference process of twisted photons by a time-gated intensified charge-coupled device camera, which is trigged by a heralded detection. Our work provides new perspectives for understanding the micro-behaviors of twisted particles and enables new applications in imaging and sensing.
