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A Generalized Array Factor for Time-Modulated Hexagonal Based Antenna Array Geometry With Novel Trapezoidal Switching
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作者 Gopi Ram 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第9期1967-1972,共6页
The concept of the time-modulated array has been emerging as an alternative to the complex phase shifters,which lowers the cost of the array feeding network due to the utilization of radio frequency(RF)switches.The va... The concept of the time-modulated array has been emerging as an alternative to the complex phase shifters,which lowers the cost of the array feeding network due to the utilization of radio frequency(RF)switches.The various forms of hexagonal antenna array geometries can be used for applications like surveillance tracking in phased array radar and wireless communication systems.This work proposes the generalized array factor(AF)for the hexagonal antenna array geometry based on time modulation.The time modulation in generalized hexagonal geometry can maintain the fixed static amplitude excitation,giving more flexibility over time.Furthermore,a novel trapezoidal switching function is also proposed and applied to the generalized array factor to enable future researchers to use this array factor in the field of advancement to observe how switching schemes like trapezoidal and rectangular affect the array pattern's side lobe level(SLL).The generalized equation can be utilized for the analysis and synthesis of radiation characteristics of the time-modulated hexagonal array(TMHA),time-modulated concentric hexagonal array(TMCHA),time-modulated hexagonal cylindrical array(TMHCA),and time-modulated hexagonal concentric cylindrical array(TMHCCA).The numerical result illustrates the generation of AF of time-modulated hexagonal structures and also shows that the trapezoidal switching sequence outperforms the rectangular switch using the cat swarm optimization(CSO)approach. 展开更多
关键词 hexagonal array geometry radiation pattern time-modulation trapezoidal pulse
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Porous heterostructure of graphene/hexagonal boron nitride as an efficient electrocatalyst for hydrogen peroxide generation 被引量:2
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作者 Mengmeng Fan Zeming Wang +10 位作者 Yuying Zhao Qixin Yuan Jian Cui Jithu Raj Kang Sun Ao Wang Jingjie Wu Hao Sun Bei Li Liang Wang Jianchun Jiang 《Carbon Energy》 SCIE CSCD 2023年第5期138-151,共14页
Compared with the traditional heteroatom doping,employing heterostructure is a new modulating approach for carbon-based electrocatalysts.Herein,a facile ball milling-assisted route is proposed to synthesize porous car... Compared with the traditional heteroatom doping,employing heterostructure is a new modulating approach for carbon-based electrocatalysts.Herein,a facile ball milling-assisted route is proposed to synthesize porous carbon materials composed of abundant graphene/hexagonal boron nitride(G/h-BN)heterostructures.Metal Ni powder and nanoscale h-BN sheets are used as a catalytic substrate/hard template and“nucleation seed”for the formation of the heterostructure,respectively.As-prepared G/h-BN heterostructures exhibit enhanced electrocatalytic activity toward H_(2)O_(2) generation with 86%-95%selectivity at the range of 0.45-0.75 V versus reversible hydrogen electrode(RHE)and a positive onset potential of 0.79 versus RHE(defined at a ring current density of 0.3 mA cm^(-2))in the alkaline solution.In a flow cell,G/h-BN heterostructured electrocatalyst has a H_(2)O_(2) production rate of up to 762 mmol g_(catalyst)^(-1) h^(-1) and Faradaic efficiency of over 75%during 12 h testing,superior to the reported carbon-based electrocatalysts.The density functional theory simulation suggests that the B atoms at the interface of the G/h-BN heterostructure are the key active sites.This research provides a new route to activate carbon catalysts toward highly active and selective O_(2)-to-H_(2)O_(2) conversion. 展开更多
关键词 efficient electrocatalyst GRAPHENE H_(2)O_(2)generation hexagonal boron nitride porous heterostructure
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Thermal-induced interfacial behavior of a thin one-dimensional hexagonal quasicrystal film
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作者 Huayang DANG Dongpei QI +2 位作者 Minghao ZHAO Cuiying FAN C.S.LU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第5期841-856,共16页
In this paper,we investigate the interfacial behavior of a thin one-dimensional(1D)hexagonal quasicrystal(QC)film bonded on an elastic substrate subjected to a mismatch strain due to thermal variation.The contact inte... In this paper,we investigate the interfacial behavior of a thin one-dimensional(1D)hexagonal quasicrystal(QC)film bonded on an elastic substrate subjected to a mismatch strain due to thermal variation.The contact interface is assumed to be nonslipping,with both perfectly bonded and debonded boundary conditions.The Fourier transform technique is adopted to establish the integral equations in terms of interfacial shear stress,which are solved as a linear algebraic system by approximating the unknown phonon interfacial shear stress via the series expansion of the Chebyshev polynomials.The expressions are explicitly obtained for the phonon interfacial shear stress,internal normal stress,and stress intensity factors(SIFs).Finally,based on numerical calculations,we briefly discuss the effects of the material mismatch,the geometry of the QC film,and the debonded length and location on stresses and SIFs. 展开更多
关键词 one-dimensional(1D)hexagonal quasicrystal(QC)film stress intensity factor(SIF) thermal variation Chebyshev polynomial interfacial behavior
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High-Throughput Growth of Hexagonal Boron Nitride Film Using Porous-Structure Isolation Layer
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作者 Ruitao Jia Fangzhu Qing Xuesong Li 《Journal of Materials Science and Chemical Engineering》 CAS 2023年第3期45-51,共7页
Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitrid... Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. . 展开更多
关键词 hexagonal Boron Nitride Chemical Vapor Deposition Porous Structure Isolation Layer High Throughput
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Elastic Field of a Straight Dislocation in One Dimensional Hexagonal Quasicrystals *L 被引量:15
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作者 李显方 孙应飞 范天佑 《Journal of Beijing Institute of Technology》 EI CAS 1999年第1期66-71,共6页
Aim To study dislocation elasticity theory in quasicrystals. Methods A dislocation was separated into pure edge part and pure screw part and their superposition was used to find the elastic field. Results and Conclu... Aim To study dislocation elasticity theory in quasicrystals. Methods A dislocation was separated into pure edge part and pure screw part and their superposition was used to find the elastic field. Results and Conclusion The elastic solution of a straight dislocation parallel to the quasiperiodic axis in 1D hexagonal quasicrystals was obtained and the generalized Peach Koehler force on a dislocation in quasicrystals was given. 展开更多
关键词 hexagonal quasicrystal DISLOCATION elastic field Peach Koehler force
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Synthesis and photoluminescence properties of single-crystal ZnO hexagonal pyramids by PEG400-assisted thermal decomposition route 被引量:1
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作者 刘劲松 张朔 +6 位作者 李子全 朱孔军 陈建康 裘进浩 王春花 高雪琴 王莉萍 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第10期2459-2464,共6页
Large-scale synthesis of ZnO hexagonal pyramids was achieved by a simple thermal decomposition route of precursor at 240 oC in the presence of PEG400. The precursor was obtained by room-temperature solid-state grindin... Large-scale synthesis of ZnO hexagonal pyramids was achieved by a simple thermal decomposition route of precursor at 240 oC in the presence of PEG400. The precursor was obtained by room-temperature solid-state grinding reaction between Zn(CH3COO)2-2H2O and Na2CO3. Crystal structure and morphology of the products were analyzed and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The results of further experiments show that PEG400 has an important role in the formation of ZnO hexagonal pyramids. Difference between the single and double hexagonal pyramid structure may come from the special thermal decomposition reaction. The photoluminescence (PL) spectra of ZnO hexagonal pyramids exhibit strong near-band-edge emission at about 386 nm and weak green emission at about 550 nm. The Raman-active vibration at about 435 cm-1 suggests that the ZnO hexagonal pyramids have high crystallinity. 展开更多
关键词 ZnO hexagonal pyramids thermal decomposition route formation mechanism photoluminescence property
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Super Performance InGaP/GaAs Heterojunction Bipolar Transistor with Hexagonal Emitter
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作者 刘洪刚 袁志鹏 +1 位作者 和致经 吴德馨 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2003年第11期1135-1139,共5页
Super performance InGaP/GaAs heterojunction bipolar transistors (HBTs) with hexagonal emitter are described.The fabricated HBT shows excellent DC characteristics with low V CE offset voltage (<0 15V) and ... Super performance InGaP/GaAs heterojunction bipolar transistors (HBTs) with hexagonal emitter are described.The fabricated HBT shows excellent DC characteristics with low V CE offset voltage (<0 15V) and low knee voltage (<0 5V).Over 14V of the collector base breakdown voltage BV CBO and over 9V of the collector emitter breakdown voltage BV CEO are obtained.For a self aligned InGaP/GaAs HBT with 2μm×10μm emitter area,the f T is extrapolated to 92GHz and f max is extrapolated to 105GHz.These great values are obtained due to the hexagonal emitter and laterally etched undercut (LEU) of collector,indicating the great potential of InGaP/GaAs HBTs for high speed digital circuit and microwave power applications. 展开更多
关键词 HBT INGAP/GAAS hexagonal emitter
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基于运动方向预测UMHexagonS算法的改进 被引量:1
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作者 王艳营 《计算机系统应用》 2011年第12期177-180,157,共5页
为了进一步减少UMHexagonS算法的运算量,在详细分析UMHexagonS算法搜索过程的基础上,对运动方向的预测进行了研究,并将运动方向预测与UMHexagonS算法中的正方形搜索和非均匀多层次六边形搜索相结合,提出了一种改进算法。利用三个不同的... 为了进一步减少UMHexagonS算法的运算量,在详细分析UMHexagonS算法搜索过程的基础上,对运动方向的预测进行了研究,并将运动方向预测与UMHexagonS算法中的正方形搜索和非均匀多层次六边形搜索相结合,提出了一种改进算法。利用三个不同的序列进行测试仿真,测试仿真结果表明,在搜索精度和码率相似的情况下,改进后的UMHexagonS算法搜索点数明显减少。 展开更多
关键词 UMhexagonS算法 运动方向预测 正方形搜索 非均匀多层次六边形搜索
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使用动态模型的UMHexagonS算法优化
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作者 刘治 王玲 《计算机工程与应用》 CSCD 2014年第14期214-218,共5页
H.264取得了很好的编码效率,但是也具有很高的计算复杂度。对H.264中的非对称十字形多层次六边形格点搜索算法(UMHexagonS)进行了优化,分别对提前终止阈值、搜索窗口大小以及搜索模式提出了3种动态模型,提高了算法的自适应性。对六种不... H.264取得了很好的编码效率,但是也具有很高的计算复杂度。对H.264中的非对称十字形多层次六边形格点搜索算法(UMHexagonS)进行了优化,分别对提前终止阈值、搜索窗口大小以及搜索模式提出了3种动态模型,提高了算法的自适应性。对六种不同运动程度的视频序列进行了测试,实验结果表明,优化后的算法相对于原来的UMHexagonS算法平均减少了21.67%的编码时间以及47.49%的运动估计时间,同时只有0.02的峰值信噪比下降以及1.69%的比特率增加。 展开更多
关键词 非对称十字形多层次六边形格点搜索算法(UMhexagonS) 运动估计 动态模型 H 264
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Replacement of Flake Graphite in Aluminacarbon Refractories by Hexagonal Boron Nitride
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作者 LIANG Feng XUE Zhengliang +3 位作者 ZHAO Lei FANG Wei YE Linfeng LEI Zhongxing 《China's Refractories》 CAS 2014年第4期36-40,共5页
Three kinds of composite alumina refractories were prepared with tabular alumina (3-1 and 1-0 mm) as aggregates,tabular alumina powder,α-Al2 O3 micropowder,and Si powder as matrix,adding 3 mass% hexagonal boron ni... Three kinds of composite alumina refractories were prepared with tabular alumina (3-1 and 1-0 mm) as aggregates,tabular alumina powder,α-Al2 O3 micropowder,and Si powder as matrix,adding 3 mass% hexagonal boron nitride (h-BN),3 mass% flake graphite and 10 mass% flake graphite,respectively.Cold physical properties,hot modulus of rupture,oxidation resistance,thermal shock resistance and slag corrosion resistance of the specimens were compared.The results show that:(1) physical properties and hot modulus of rupture of Al2 O3-h-BN refractories are slightly different from those of low carbon Al2 O3-C refractories,but better than those of traditional Al2 O3-C refractories with 10 mass% graphite ; (2) Al2 O3-h-BN refractories have better thermal shock resistance and oxidation resistance than the carbon containing refractories,while similar slag resistance with low carbon Al2 O3-C refractories ; (3) h-BN can replace flake graphite as a starting material for the preparation of composite alumina refractories,considering the overall properties of the material. 展开更多
关键词 hexagonal boron nitride alumina-hexagonal boron nitride refractories alumina-carbon refractories flake graphite oxidation resistance
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Exact analytic solutions for an elliptic hole with asymmetric collinear cracks in a one-dimensional hexagonal quasi-crystal 被引量:18
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作者 郭俊宏 刘官厅 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第7期2610-2620,共11页
Using the complex variable function method and the technique of conformal mapping, the anti-plane shear problem of an elliptic hole with asymmetric colfinear cracks in a one-dimensional hexagonal quasi-crystal is solv... Using the complex variable function method and the technique of conformal mapping, the anti-plane shear problem of an elliptic hole with asymmetric colfinear cracks in a one-dimensional hexagonal quasi-crystal is solved, and the exact analytic solutions of the stress intensity factors (SIFs) for mode Ⅲ problem are obtained. Under the limiting conditions, the present results reduce to the Griffith crack and many new results obtained as well, such as the circular hole with asymmetric collinear cracks, the elliptic hole with a straight crack, the mode T crack, the cross crack and so on. As far as the phonon field is concerned, these results, which play an important role in many practical and theoretical applications, are shown to be in good agreement with the classical results. 展开更多
关键词 one-dimensional hexagonal quasi-crystals elliptic hole with asymmetric collinear cracks stress intensity factor complex variable function method
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Simulation on damage effectiveness of hexagonal prism aimable warhead with multi-point synchronous initiations 被引量:10
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作者 李元 温玉全 《Journal of Beijing Institute of Technology》 EI CAS 2014年第1期1-7,共7页
In order to study the impacts of warhead geometry and initiation pattern on the lethality of aimable warhead, multi-point synchronous initiated hexagonal prism and cylindrical warheads were compared through numerical ... In order to study the impacts of warhead geometry and initiation pattern on the lethality of aimable warhead, multi-point synchronous initiated hexagonal prism and cylindrical warheads were compared through numerical simulation, combined with theoretical formulas of fragment decelera- tion and target plugging. Enhancements of fragment velocity, kinetic energy and density toward the target and target destructions were analyzed. The results show that hexagonal prism warhead can produce dense fragment beams and enhance average velocity and kinetic energy with asymmetric eight-point initiation by 24. 13% and 54. 52% respectively, which are higher than those of the isomet- ric or same weight cylindrical warhead. The effective fragments are still relatively concentrated in an area of 8 m × 2 m for the hexagonal prism warhead when the distance between warhead and target is 40 m. 展开更多
关键词 aimable warhead hexagonal prism warhead multi-point initiation numerical simulation
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Hexagonal boron nitride adsorbent: Synthesis, performance tailoring and applications 被引量:7
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作者 Jun Xiong Jun Di +1 位作者 Wenshuai Zhu Huaming Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第1期99-111,I0004,共14页
Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specifi... Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specific surface area,h-BN-related nanostructures exhibit appealing adsorption propertiewhich can be widely applied for separation and purification towards energy and environment treatmenIn this review,recent progress in designing h-BN micro,nano-structure,controlled synthesis,performancoptimizing as well as energy and environment-related adsorption applications are summarized.Strategieto tailor the h-BN can be classified as morphology control,element doping,defect control and surfacmodification,focusing on how to optimize the adsorption performance.In order to insight the intrinsimechanism of tuning strategies for property optimization,the significant adsorption applications of h-Btowards hydrogen storage,CO2 capture,pollutants removal from water and adsorption desulfurization arpresented. 展开更多
关键词 hexagonal boron nitride ADSORBENT Structure tuning ENERGY ENVIRONMENT
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The interaction between a screw dislocation and a wedge-shaped crack in one-dimensional hexagonal piezoelectric quasicrystals 被引量:6
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作者 姜丽娟 刘官厅 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第4期245-251,共7页
Based on the fundamental equations of piezoelasticity of quasicrystal material,we investigated the interaction between a screw dislocation and a wedge-shaped crack in the piezoelectricity of one-dimensional hexagonal ... Based on the fundamental equations of piezoelasticity of quasicrystal material,we investigated the interaction between a screw dislocation and a wedge-shaped crack in the piezoelectricity of one-dimensional hexagonal quasicrystals.Explicit analytical solutions are obtained for stress and electric displacement intensity factors of the crack,as well as the force on dislocation.The derivation is based on the conformal mapping method and the perturbation technique.The influences of the wedge angle and dislocation location on the image force are also discussed.The results obtained in this paper can be fully reduced to some special cases already available or deriving new ones. 展开更多
关键词 one-dimensional hexagonal piezoelectric quasicrystals dislocation wedge-shaped crack interac-tion
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Crushing analysis and multi-objective optimization of bitubular hexagonal columns with ribs 被引量:3
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作者 ZOU Xiang GAO Guang-jun +4 位作者 DONG Hai-peng LI Jian ZHOU Xi-sai CHEN Wei GUAN Wei-yuan 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第5期1164-1173,共10页
In order to improve the crashworthiness of thin-walled columns, the energy absorption characteristics of three columns under quasi-static axial crushing loads were analyzed through LS-DYNA. Numerical results show that... In order to improve the crashworthiness of thin-walled columns, the energy absorption characteristics of three columns under quasi-static axial crushing loads were analyzed through LS-DYNA. Numerical results show that the energy absorption capability of the bitubular hexagonal columns with middle to middle(MTM) ribs is the best, followed by the bitubular hexagonal columns with corner to corner(CTC) ribs and the bitubular hexagonal columns without(NOT) ribs, respectively. Then, the MTM rib was optimized by using multi-objective particle swarm optimization algorithm. Through the analysis of the Pareto front for specific energy absorption(SEA, A_(se)) and peak crushing force(PCF, F_(pc)), it is found that there is a vertex on the Pareto front. The vertex has the design parameters of t_1=1.2 mm, t_2=1.2 mm, A_(se)=11.3729 k J/kg, F_(pc)=235.8491 kN. When the PCF is in a certain size, on the left of the vertex, the point with t_2=1.2 mm has the biggest SEA, meanwhile on the right of the vertex, the point with t_1=1.2 mm has the biggest SEA. Finally, the global sensitivity analysis was conducted to investigate the effect of two design parameters. The result is obtained that both SEA and PCF for MTM are more sensitive to t_1 rather than t_2 in the design domain. 展开更多
关键词 bitubular hexagonAL column axial CRUSHING CRASHWORTHINESS optimization global sensitivity ANALYSIS
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Electronic structure and flotation behavior of monoclinic and hexagonal pyrrhotite 被引量:6
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作者 赵翠华 吴伯增 陈建华 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第2期466-471,共6页
Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe... Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe 3d, while that of hexagonal pyrrhotite is from Fe 3d, Fe 3p and S 3s. The hexagonal pyrrhotite is more reactive than monoclinic pyrrhotite because of large density of states near the Fermi level. The hexagonal pyrrhotite shows antiferromagnetism. S—Fe bonds mainly exist in monoclinic pyrrhotite as the covalent bonds, while hexagonal pyrrhotite has no covalency. The main contributions of higest occupied molecular orbital(HOMO) and lowest unoccupied molecular obital(LUMO) for monoclinic pyrrhotite come from S and Fe. The main contribution of HOMO for hexagonal pyrrhotite comes from Fe, while that of LUMO comes from S. The coefficient of Fe atom is much larger than that of S atom of HOMO for hexagonal pyrrhotite, which contributes to the adsorption of Ca OH+ on the surface of hexagonal pyrrhotite when there is lime. As a result, lime has the inhibitory effect on the floatation of hexagonal pyrrhotite and the coefficient of Fe is very close to that of S for monoclinic pyrrhotite. Therefore, the existence of S prevents the adsorption of Ca OH+on the surface of monoclinic pyrrhotite, which leads to less inhibitory effect on the flotation of monoclinic pyrrhotite. 展开更多
关键词 monoclinic pyrrhotite hexagonal pyrrhotite electronic structure flotation behavior density functional theory
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Characterization of a Y-type hexagonal ferrite-based frequency tunable microwave absorber 被引量:3
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作者 Fang Xu Yang Bai +1 位作者 Kai Jiang Li-jie Qiao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第5期453-456,共4页
A Y-type hexaferrite rod with the composition of Ba2COl.8Cuo.2Fe12022 was presented as an absorbing material with high absorb- anee. Its high absorbance and wide absorption band result from ferromagnetic resonance (... A Y-type hexaferrite rod with the composition of Ba2COl.8Cuo.2Fe12022 was presented as an absorbing material with high absorb- anee. Its high absorbance and wide absorption band result from ferromagnetic resonance (FMR) that is self-biased by strong shape and mag- netocrystaUine anisotropy fields. Around the FMR frequency the specimen of the ferrite rods exhibits very high absorbance and the FMR frequency can be tuned by the rod dimension. In addition to the high absorbance and the wide tunable absorption band, the microwave ab- sorber has another advantage of light weight due to the use of the ferrite rods instead of ferrite slabs. 展开更多
关键词 hexagonal ferfite microwave materials microwave absorbers cobalt compounds ferromagnetic resonance
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Polarization properties of elliptical core non-hexagonal symmetry polymer photonic crystal fibre 被引量:13
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作者 张亚妮 苗润才 +3 位作者 任立勇 王韩毅 王丽莉 赵卫 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第6期1719-1724,共6页
In this paper, polarization properties and propagation characteristics of polymer photonic crystal fibres with elliptical core and non-hexagonal symmetry structure are investigated by using the full vectorial plane wa... In this paper, polarization properties and propagation characteristics of polymer photonic crystal fibres with elliptical core and non-hexagonal symmetry structure are investigated by using the full vectorial plane wave method. The results show that the birefringence of the fibre is induced by asymmetries of both the cladding and the core. Moreover, by adjusting the non-symmetrical ratio factor of cladding η from 0.4 to 1 in step 0.1, we find the optimized design parameters of the fibre with high birefringence and limited polarization mode dispersion, operating in a single mode regime at an appropriate wavelength range. The range of wavelength approaches the visible and near-infrared which is consistent with the communication windows of polymer optical fibres. 展开更多
关键词 birefringence elliptical core non-hexagonal symmetry POLYMER POLARIZATION
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Synthesis of a novel hexagonal porous TT-Nb2O5 via solid state reaction for high-performance lithium ion battery anodes 被引量:7
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作者 ZHOU Yu LIU Ke +4 位作者 ZHOU Yue NI Jia-hua DOU Ai-chun SU Ming-ru LIU Yun-jian 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第12期3625-3636,共12页
Hexagonal porous Nb2O5 was synthesized for the first time via a facile solid-state reaction.The structure and electrochemical properties have been optimized through tuning heating temperature.X-ray diffraction results... Hexagonal porous Nb2O5 was synthesized for the first time via a facile solid-state reaction.The structure and electrochemical properties have been optimized through tuning heating temperature.X-ray diffraction results indicate that pseudo hexagonal Nb2O5(TT-Nb2O5)and orthorhombic Nb2O5 have been synthesized at different temperatures.Hexagonal sheet and porous structure of Nb2O5 were characterized by scanning electron microscopy and N2-adsorption-desorption isotherms.The as-prepared TT-Nb2O5(heated at 600℃)shows the best performance with a remarkable charge capacity of 178 mA∙h/g at 0.2C,which is higher than that of T-Nb2O5.Even at 20℃,TT-Nb2O5 offers unprecedented rate capability up to 86 mA∙h/g.The high rate capacity is due to pseudocapacitive Li+intercalation mechanism of TT-Nb2O5.The reported results demonstrate that Nb2O5 with good crystal structure and high specific surface area is a powerful composite design for high-rate and safe anode materials. 展开更多
关键词 lithium-ion battery NB2O5 hexagonal porous sheet electrochemical performance
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A study of transition from n-to p-type based on hexagonal WO3 nanorods sensor 被引量:3
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作者 武雅乔 胡明 韦晓莹 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第4期208-214,共7页
Hexagonal WO3 nanorods are fabricated by a facile hydrothermal process at 180 ℃ using sodium tungstate and sodium chloride as starting materials. The morphology, structure, and composition of the prepared nanorods ar... Hexagonal WO3 nanorods are fabricated by a facile hydrothermal process at 180 ℃ using sodium tungstate and sodium chloride as starting materials. The morphology, structure, and composition of the prepared nanorods are studied by scanning electron microscopy, X-ray diffraction spectroscopy, and energy dispersive spectroscopy. It is found that the agglomeration of the nanorods is strongly dependent on the PH value of the reaction solution. Uniform and isolated WO3 nanorods with diameters ranging from 100 nm-150 nm and lengths up to several micrometers are obtained at PH = 2.5 and the nanorods are identified as being hexagonal in phase structure. The sensing characteristics of the WO3 nanorod sensor are obtained by measuring the dynamic response to NO2 with concentrations in the range 0.5 ppm-5 ppm and at working temperatures in the range 25 ℃-250 ℃. The obtained WO3 nanorods sensors are found to exhibit opposite sensing behaviors, depending on the working temperature. When being exposed to oxidizing NO2 gas, the WO3 nanorod sensor behaves as an n-type semiconductor as expected when the working temperature is higher than 50 ℃, whereas, it behaves as a p-type semiconductor below 50 ℃. The origin of the n- to p-type transition is correlated with the formation of an inversion layer at the surface of the WO3 nanorod at room temperature. This finding is useful for making new room temperature NO2 sensors based on hexagonal WO3 nanorods. 展开更多
关键词 hexagonAL W03 nanorods sensor hydrothermal method n- to p-type transition
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