All-solid-state flexible asymmetric supercapacitors with high energy and power densities based on NiCo_2S_4@MnS and active carbon

Electrode material based on a novel core–shell structure consisting of NiCoS（NCS） solid fiber core and Mn S（MS） sheet shell（NCS@MS） in situ grown on carbon cloth（CC） has been successfully prepared by a simple sulfurization-assisted hydrothermal method for high performance supercapacitor. The synthesized NiCoS@Mn S/CC electrode shows high capacitance of 1908.3 F gat a current density of 0.5 A gwhich is higher than those of NiCoSand Mn S at the same current density. A flexible all-solid-state asymmetric supercapacitor（ASC） is constructed by using NiCoS@Mn S/CC as positive electrode, active carbon/CC as negative electrode and KOH/poly（vinyl alcohol）(PVA) as electrolyte. The optimized ASC shows a maximum energy density of 23.3 Wh kgat 1 A g, a maximum power density of about7.5 kw kgat 10 A gand remarkable cycling stability. After 9000 cycles, the ASC still exhibited67.8% retention rate and largely unchanged charge/discharge curves. The excellent electrochemical properties are resulted from the novel core–shell structure of the NiCoS@Mn S/CC electrode, which possesses both high surface area for Faraday redox reaction and superior kinetics of charge transport. The NiCoS@Mn S/CC electrode shows a promising potential for energy storage applications in the future.

Design and Preparation of High Elastic Modulus Self-compacting Concrete for Pre-stressed Mass Concrete Structures

Requirements of self-compacting concrete （SCC） applied in pre-stressed mass concrete structures include high fluidity, high elastic modulus, low adiabatic temperature rise and low drying shrinkage, which cannot be satisfied by ordinary SCC. In this study, in order to solve the problem, a few principles of SCC design were proposed and the effects of binder amount, fly ash （FA） substitution, aggregate content and gradation on the workability, temperature rise, drying shrinkage and elastic modulus of SCC were investigated. The results and analysis indicate that the primary factor influencing the fluidity was paste content, and the main methods improving the elastic modulusof SCC were a lower sand ratio and an optimized coarse aggregate gradation. Lower adiabatic temperature rise and drying shrinkage were beneficial for decreasing the cement content. Further, based on the optimization of mixture, a C50 grade SCC （with binder amount of only 480 kg/ m3, fly ash substitution of 40%, sand ratio of 51% and proper coarse aggregate gradation （Vs.~0 mm： V10-16 ram： V16.20 mm= 30%： 30%：40%）） with superior workability was successfully prepared. The temperature rise and drying shrinkage of the prepared SCC were significantly reduced, and the elastic modulus reached 37.6 GPa at 28 d.

PROBABILITY MODEL AND SOLUTION ON EARTHQUAKE EFFECTS COMBINATION IN ALONG WIND RESISTANT DESIGN OF TALL-FLEXIBLE BUILDINGS

A model on the earthquake effects combination in wind resistant design of high-rise flexible structures is proposed in accordance with the probability method. Based on the Turkstra criteria, the stochastic characters of wind velocity, earthquake ground acceleration and excitations occurrence probability are taken into account and then the combination of the earthquake effects in structure wind resistant design is analyzed with the convolution approach. The results indicate that as for the tall flexible buildings whose lateral force is governed by wind loading, the maximum lateral loads verification with respect to the wind resistant design combined with earthquake effects may be more unfavorable compared with that in terms of the earthquake resistant design involving wind effects.

Constructing a 3D multichannel structure to enhance performance of Ni–Co–Mn hydroxide electrodes for flexible supercapacitors

The balancing of the electrochemical performance,mechanical stability,and processing technology for applying supercapacitors to flexible and wearable electronics continues to encounter severe challenges.Herein,we prepare Ni-Co-Mn hydroxide electrodes with a threedimensional multichannel structure via a simple hydrothermal method.These are constructed using vertically contiguous nano sheets with a uniform thickness and rough surface.The electrodes can provide numerous electroactive sites and accelerate the transmission of electrolyte ions.The relationship between the structure and electrochemical performances is verified by experiments and theoretical calculations.Two-dimensional(2D)planar and one-dimensional(1D)fiber electrodes are prepared using a flexible carbon cloth(CC)and carbon fiber(CF),respectively,as substrates.The assembled quasi-solid-state flexible asymmetric supercapacitor(FASC)with a twodimensional sandwich structure using NiCoMn-OH/CC as the electrode achieves a remarkable energy density of73.8 Wh·kg^(-1)at a power density of 1.03 kW·kg^(-1).The quasi-solid-state FASC with a 1D linear structure using NiCoMn-OH/CF as the electrode also attains a high energy density(12.9 Wh·kg^(-1)at a power density of0.75 W·kg^(-1)).Moreover,the electrochemical performances of the NiCoMn/CC//AC/CC and NiCoMn/CF//AC/CF FASCs are not disturbed at different bending angles(0°,45°,90°,135°and 180°),This indicates the superior flexibility of the devices.We also assemble a self-powered energy-harvesting storage system by integrating FASCs and commercial solar cells to verify its practicability.It displays sustainable development potential for energy storage.

High-Rise Residential Reinforced Concrete Building Optimisation

In the last few decades structure optimisation has become a main task in a civil engineering project. As a matter of fact, due to the complexity and particularity of every structure, the great amount of variables and design criteria to considerate and many other factors, a general optimisation’s method is not simple to formulate. As a result, this paper focuses on how to provide a successful optimisation method for a particular building type, high-rise reinforced concrete buildings. The optimization method is based on decomposition of the main structure into substructures: floor system, vertical load resisting system, lateral load resisting system and foundation system;then each of the subsystems using the design criteria established at the building codes is improved. Due to the effect of the superstructure optimisation on the foundation system, vertical and lateral load resisting system is the last to be considered after the improvement of floor. Finally, as a case example, using the method explained in the paper, a 30-story-high high-rise residential building complex is analysed and optimised, achieving good results in terms of structural behaviour and diminishing the overall cost of the structure.

大型履带吊上楼面板施工过程有限元分析

珠海某项目由框架、核心筒及双层交叉桁架结构体系组成,采用在地下室顶板上铺设路基箱的加固方式,部分构件先地面拼装再吊装等施工工艺,同时对履带吊行走路线进行严格的规划。在现有结构上进行钢结构吊装,对下部混凝土结构影响较大,采用MIDAS GEN有限元分析软件对下部混凝土结构的裂缝和应力变化情况进行有限元分析,模拟履带吊全施工过程。分析结果表明:在地下室顶板上铺设路基箱的加固方式,可以有效降低下部混凝土结构的最大变形及应力,满足国家规范要求。

Experimental study on the effect of flexible joints of a deep-buried tunnel across an active fault under high in-situ stress conditions

During dislocation,a tunnel crossing the active fault will be damaged to varying degrees due to its permanent stratum displacement.Most previous studies did not consider the influence of the tunnel’s deep burial and the high in-situ stress,so the results were not entirely practical.In this paper,the necessity of solving the anti-dislocation problem of deep-buried tunnels is systemically discussed.Through the model test of tunnels across active faults,the differences in failures between deep-buried tunnels and shallow-buried tunnels were compared,and the dislocation test of deep-buried segmental tunnels was carried out to analyze the external stress change,lining strain,and failure mode of tunnels.The results are as follows.(1)The overall deformation of deep-buried and shallow-buried tunnels is both Sshaped.The failure mode of deep-buried tunnels is primarily characterized by shear and tensile failure,resulting in significant compressive deformation and a larger damaged area.In contrast,shallow-buried tunnels mainly experience shear failure,with the tunnel being sheared apart at the fault crossing,leading to more severe damage.(2)After the segmental structure design of the deep-buried tunnel,the “S”deformation pattern is transformed into a “ladder”pattern,and the strain of the tunnel and the peak stress of the external rock mass are reduced;therefore,damages are significantly mitigated.(3)Through the analysis of the distribution of cracks in the tunnel lining,it is found that the tunnel without a segmental structure design has suffered from penetrating failure and that cracks affect the entire lining.The cracks in a flexible segmental tunnel affect about 66.6% of the entire length of the tunnel,and cracks in a tunnel with a short segmental tunnel only affect about 33.3% of the entire length of the tunnel.Therefore,a deep-buried tunnel with a short segmental tunnel can yield a better anti-dislocation effect.(4)By comparing the shallow-buried segmental tunnel in previous studies,it is concluded that the shallow-buried segmental tunnel will also suffer from deformation outside the fault zone,while the damages to the deep-buried segmental tunnel are concentrated in the fault zone,so the anti-dislocation protection measures of the deep-buried tunnel shall be provided mainly in the fault zone.The results of the above study can provide theoretical reference and technical support for the design and reinforcement measures of the tunnel crossing active fault under high in-situ stress conditions.

Combined centralized and decentralized control for high-precision spacecraft

The improved structural filter combined with Positive Position Feedback(PPF) controller is investigated for high-precision attitude control of flexible spacecraft which consists of rigid central body and flexible appendages.PPF controller is adopted for high frequency vibration suppression,while the improved structural filter is used for suppression of low frequency vibration.After introducing PPF controller,the vibration frequencies are changed.In view of the frequency uncertainties,an improved structural filter is designed,and the stability study for the centralized control system is conducted.The simulation results show that the performance of spacecraft control system is improved,and the control inputs remain unchanged.

乌兹别克斯坦9度区某超高层建筑结构设计与优化

对于9度设防地区的超高层建筑,其结构设计基本由地震作用控制,因此抗震设计尤为重要。建筑消能减震技术可在提高结构地震安全储备的同时,降低整体工程造价,是结构优化设计的有效措施。对位于9度区的超高层建筑进行了结构方案选型对比、结构方案优化、减震设计方案比选、剪力墙内嵌钢板优化。结果显示,钢骨混凝土框架⁃核心筒方案相对于钢框架⁃支撑方案具备更高的成本优势;框架⁃核心筒方案可通过精细化设计作进一步优化;在此基础上,对钢骨混凝土框架⁃核心筒方案采用两种消能减震方案进行比选,结果表明,采用黏滞阻尼器方案的结构抗震性能明显优于采用黏滞阻尼墙方案;最后通过增大剪力墙竖向分布钢筋配筋率,对低区核心筒墙肢中的内嵌钢板进行了优化。

地震和风耦合作用下超高层连体结构易损性分析

为探究超高层连体结构在多灾害耦合作用下的设计与安全性能,以苏州超塔为例,开展地震和风耦合作用下的多灾害易损性分析.根据设计资料建立结构有限元模型,分别开展结构在地震作用下以及地震和风耦合作用下的易损性分析,探究结构在多灾害耦合作用下的响应规律.结果表明,地震和风耦合作用下结构联合易损性随着地震动和风荷载强度的增大而增加,且地震动对结构的破坏占主导作用.地震与风耦合作用时结构达到中等破坏、严重破坏和倒塌破坏的概率均比仅地震作用时有所增加.当风速达到40 m/s时,结构在罕遇地震下达到3种破坏状态的概率分别为99.77%、91.56%和46.54%,相比于仅罕遇地震作用下分别提高了1.11%、10.73%和14.65%,相比于一般高层连体结构在同样的灾害耦合作用下分别提高了0.27%、6.26%和14.34%.

成都中海天府新区超高层项目结构设计

成都中海天府新区超高层项目建筑高度488.9m,为西南地区已建和在建的最高建筑物。塔楼采用巨柱框架⁃伸臂桁架⁃核心筒结构体系,具有8个环带桁架层和2个伸臂层,无外围巨型斜撑,次框架柱不连续的特点。介绍塔楼结构设计策略,包括结构整体性能参数、抗震性能目标和关键构件的性能水准的设定。阐述基础、环带桁架、伸臂桁架、巨型钢管混凝土柱、角部大悬挑、塔冠的结构布置及设计;进行了次框架结构的防连续倒塌分析以及加强层楼板、水平支撑、斜柱、斜墙等关键构件的计算分析;给出了与巨柱、伸臂相连的关键节点的构造措施以及结构长期荷载效应下的施工模拟结果和处理措施等。结果表明,结构体系及布置合理安全,各构件能够满足预定的性能目标。

不同结构因子下带连廊高层建筑外墙火竖向蔓延数值模拟

目的 研究带连廊高层建筑发生火灾时火焰蔓延的变化规律,为该类建筑的防火设计提供参考。方法 应用火灾数值模拟软件FDS建立一个33层带连廊建筑模型,分别改变结构因子、窗口数量两种因素进行模拟,分析该模型在不同条件下的温度分布等温线和温度曲线。结果 结构因子为0.4、0.8、1.2,窗口数量为二、三、四时,达到危险温度540℃,火焰融合高度随结构因子和窗口数量增加而上升;随着结构因子的增加,火焰融合高度提高了0.25~12.5 m;随着窗口数量的增加,火焰融合高度上升了0.9~6.37 m;结论 带连廊高层建筑外墙火焰蔓延高度受结构因子和窗口数量影响;随着窗口数量增加,结构因子对火焰融合高度影响越大,结构因子越大,火焰融合高度越高;建议带连廊高层建筑连廊部分结构因子小于0.8,并选用结构因子为0.8时的火焰融合高度作为外部蔓延防火阻隔区高度。

高层剪力墙结构多目标智能设计方法

高层剪力墙结构智能设计包括智能建模和智能优化两个环节。目前智能建模环节缺乏梁自动化布置和荷载自动化布置;智能优化环节只考虑材料成本而未考虑施工的便捷性。此外,现有的智能设计方法均局限于单标准层的高层剪力墙结构。为此,该文提出了高层剪力墙结构多目标智能设计方法,包括多标准层高层剪力墙结构的智能建模和多目标优化。多标准层高层剪力墙结构智能建模包含剪力墙智能布置、梁自动化布置、板自动化布置和荷载自动化布置;以材料成本和施工便捷性为目标,采用分步优化策略和基于小生境技术的遗传算法对高层剪力墙结构进行多目标优化。通过实际工程算例对所提出的方法进行了验证,结果表明,所提出的高层剪力墙结构多目标智能设计方法稳定、可靠,可以较好地兼顾材料成本和施工的便捷性,并能显著缩短设计周期。

锥面分段开孔高速刀柄的设计方法

根据高速刀柄在不同过盈量下的联接性能分析结果与不同转速下的锥面接触应力分布规律,提出了一种锥面分段开孔高速刀柄的设计方法,即对刀柄定位锥面按照锥体素线长度均等分成前、中、后三段,并在各段的中等分处周向均布一组盲孔,通过调控盲孔的数量与尺寸使刀柄锥面达到一定的柔度。文章阐述了盲孔开设参数对锥面接触应力、柔度的影响规律和参数确定原则,给出了以HSK-E50为原型的锥面分段开孔设计案例,采用有限元分析其极限转速和锥面接触应力分布情况。结果表明,锥面分段开孔刀柄与原型刀柄相比,极限转速提高了约10.79%,锥面接触应力分布显著均匀。

PDMS包封CPCM制备三明治结构织物及热性能分析

为解决正十八烷在使用过程中的相泄露问题,以细菌纤维素膜为支撑载体、聚二甲基硅氧烷为包封材料,通过真空浸渍和热固处理制备形稳性复合相变材料。正十八烷浸渍率高达84.9%,潜热能为212.70 J/g,可经受100次热循环测试。经180°弯折后回弹角为156.4°,回弹角相较于包封前提高了131.7%。以复合相变材料为中间层、涤棉混纺织物为外层,经由聚二甲基硅氧烷粘合和固化处理,制得三明治结构织物。吸热饱和后,三明治织物表面温度比普通织物延时降温310 s,在日照模型和人体热管理测试中其覆盖的空间内部温度比普通织物覆盖处降低0.9℃,显示出优异的储热和隔热性能。

基于MBD的高层建筑施工工艺结构化表征

针对高层建筑施工过程中的庞大内容和复杂的组织关系,本文首先深入分析了二维纸质工艺图纸和文件作为技术交底形式所带来的抽象性、理解困难、规范性差及数据一致性难以保障等问题。基于对高层建筑施工工艺特性和信息集成需求的分析,本文规范化定义了施工工艺的要素和属性,提出了基于工艺结构树的施工工艺信息组织管理方法,并构建了多层级工艺信息模型以实现工艺信息的结构化表达。借鉴制造业的MBD理念,本文以工艺结构树为数据组织核心,结合BIM模型与工艺信息卡片,提出了集成几何设计与施工工艺信息的三维施工工艺结构化表征框架。最后,通过开发交互式作业指导系统并结合实际案例验证,完成了项目主体、工艺和各类资源的有序整合,为智能建造提供了理论与方法支持。

面向应用型人才培养的多高层建筑结构设计课程教学方法探讨

多高层建筑结构设计课程将以培养应用型人才为目标,以知识传授、能力培养、素质提高为核心。课堂教学将基础理论知识具体化、形象化;结合工程实例,引导学生对现行规范条文加以融会贯通;引入体验式教学模式,通过基于设计软件的实践训练,将理论知识与实践相结合,培养学生的实践能力和创新能力。

近断层脉冲型随机地震动模拟方法及结构动力可靠度研究

以集集脉冲型地震动记录为数据集建立了一种改进的参数化近断层脉冲型随机地震动模型.首先,采用MP03模型和人工蜂群算法从实际地震动记录提取低频脉冲部分,建立随机低频脉冲模型;采用谱表示-随机函数法生成高频部分,二者叠加生成近断层脉冲型随机地震动.然后,采用蒙特卡罗模拟(MCS)法和直接概率积分法(DPIM)分别研究非线性单自由度体系和高层框架结构在不同类型地震动作用下的动力可靠度.结果表明:DPIM与MCS法计算结果相比基本吻合,但计算效率得到较大提升,可以很好地用于非线性结构的时变可靠度研究;脉冲型地震动与非脉冲型地震动相比能够对结构造成更大的变形,极大降低了结构的可靠度,且近断层距越小影响越显著,低频脉冲是使结构可靠度降低的主要因素,而高频部分对结构可靠度的影响较小.

超高层建筑钢结构施工的关键技术和措施

随着城市化的不断推进,超高层建筑的兴建成为城市发展的一种趋势。在超高层建筑中,钢结构因其轻质、高强度等特点,成为超高层建筑的首选方案。文中通过对钢结构特征的分析,深入剖析了超高层建筑中的钢结构施工流程及影响因素。在此基础上,详细讨论了柱基础检查、钢柱吊装和钢柱连接等关键技术与应用措施,包括了施工过程中的质量监控、安全管理和技术检测等方面,旨在为超高层建筑钢结构施工提供可行的解决方案。

超高层异形爬架综合施工技术研究

杭州西站TOD项目超高层建筑外立面轮廓线先外扩再内收,为此采用了异形爬架,通过两阶段垂直爬升和内收俯爬进行作业。本研究介绍了异形爬架的主要特点,明确爬架断面分区、机位布置,分析解决爬升流程技术要点和难点。给出爬架附着支座在悬挑板上的计算校核;结合爬架外扩内收的结构变形,通过定型化防护网搭接解决扇形空隙防护区域,并设置防倾构造保障架体安全,可为同类工程施工提供参考。