The high variability of shock in terrorist attacks poses a threat to people's lives and properties,necessitating the development of more effective protective structures.This study focuses on the angle gradient and...The high variability of shock in terrorist attacks poses a threat to people's lives and properties,necessitating the development of more effective protective structures.This study focuses on the angle gradient and proposes four different configurations of concave hexagonal honeycomb structures.The structures'macroscopic deformation behavior,stress-strain relationship,and energy dissipation characteristics are evaluated through quasi-static compression and Hopkinson pressure bar impact experiments.The study reveals that,under varying strain rates,the structures deform starting from the weak layer and exhibit significant interlayer separation.Additionally,interlayer shear slip becomes more pronounced with increasing strain rate.In terms of quasi-static compression,symmetric gradient structures demonstrate superior energy absorption,particularly the symmetric negative gradient structure(SNG-SMS)with a specific energy absorption of 13.77 J/cm~3.For dynamic impact,unidirectional gradient structures exhibit exceptional energy absorption,particularly the unidirectional positive gradient honeycomb structure(UPG-SML)with outstanding mechanical properties.The angle gradient design plays a crucial role in determining the structure's stability and deformation mode during impact.Fewer interlayer separations result in a more pronounced negative Poisson's ratio effect and enhance the structure's energy absorption capacity.These findings provide a foundation for the rational design and selection of seismic protection structures in different strain rate impact environments.展开更多
The novelty of this research lies in the successful fabrication of a 3D-printed honeycomb structure filled with nanofillers for acoustic properties,utilizing an impedance tube setup in accordance with ASTM standard E ...The novelty of this research lies in the successful fabrication of a 3D-printed honeycomb structure filled with nanofillers for acoustic properties,utilizing an impedance tube setup in accordance with ASTM standard E 1050-12.The Creality Ender-3,a 3D printer,was used for printing the honeycomb structures,and polylactic acid(PLA)material was employed for their construction.The organic,inorganic,and polymeric compounds within the composites were identified using fourier transformation infrared(FTIR)spectroscopy.The structure and homogeneity of the samples were examined using a field emission scanning electron microscope(FESEM).To determine the sound absorption coefficient of the 3D printed honeycomb structure,numerous samples were systematically developed using central composite design(CCD)and analysed using response surface methodology(RSM).The RSM mathematical model was established to predict the optimum values of each factor and noise reduction coefficient(NRC).The optimum values for an NRC of 0.377 were found to be 1.116 wt% carbon black,1.025 wt% aluminium powder,and 3.151 mm distance between parallel edges.Overall,the results demonstrate that a 3Dprinted honeycomb structure filled with nanofillers is an excellent material that can be utilized in various fields,including defence and aviation,where lightweight and acoustic properties are of great importance.展开更多
The impedance matching of absorbers is a vital factor affecting their microwave absorption(MA)properties.In this work,we controllably synthesized Material of Institute Lavoisier 88C(MIL-88C)with varying aspect ratios(...The impedance matching of absorbers is a vital factor affecting their microwave absorption(MA)properties.In this work,we controllably synthesized Material of Institute Lavoisier 88C(MIL-88C)with varying aspect ratios(AR)as a precursor by regulating oil bath conditions,followed by one-step thermal decomposition to obtain carbon-coated iron-based composites.Modifying the precursor MIL-88C(Fe)preparation conditions,such as the molar ratio between metal ions and organic ligands(M/O),oil bath temperature,and oil bath time,influenced the phases,graphitization degree,and AR of the derivatives,enabling low filler loading,achieving well-matched impedance,and ensuring outstanding MA properties.The MOF-derivatives 2(MD_(2))/polyvinylidene Difluoride(PVDF),MD_(3)/PVDF,and MD4/PVDF absorbers all exhibited excellent MA properties with optimal filler loadings below 20 wt%and as low as 5 wt%.The MD_(2)/PVDF(5 wt%)achieved a maximum effective absorption bandwidth(EAB)of 5.52 GHz(1.90 mm).The MD_(3)/PVDF(10 wt%)possessed a minimum reflection loss(RL_(min))value of−67.4 at 12.56 GHz(2.13 mm).A symmetric gradient honeycomb structure(SGHS)was constructed utilizing the high-frequency structure simulator(HFSS)to further extend the EAB,achieving an EAB of 14.6 GHz and a RL_(min) of−59.0 dB.This research offers a viable inspiration to creating structures or materials with high-efficiency MA properties.展开更多
High-speed impact threats and terrorist actions on the battlefield require the development of more effective protective materials and structures,and various protective structure is designed according their energy-abso...High-speed impact threats and terrorist actions on the battlefield require the development of more effective protective materials and structures,and various protective structure is designed according their energy-absorbing characteristics.In this research,the deformation behavior,microscopic failure modes and energy absorption characteristics of re-entrant hexagonal structure,regular hexagonal structure and regular quadrilateral structure are studied under different strain rates impact.The re-entrant hexagonal structure forms a“X”-shaped deformation zone,the regular quadrilateral and regular hexagonal structure form an“I”-shaped deformation zone.The microscopic appearance of the section is a mixed fracture form.The effects of the topological shape,cell angle,and cell height on the impact behavior of the structure were evaluated.When the cell height is fixed and the cell angle is changed,the energy absorption of the structure increase and then decrease as the relative density increase.The mechanical properties of the structure are optimal when the relative density is about 18.6%and the cell angle is22.5°.When the cell angle is fixed and the cell height is changed,as the relative density increases,the energy absorption of the structure gradually increases.The regular quadrilateral structure and the reentrant hexagonal structure experienced clear strain rate effects under dynamic impact conditions;the regular hexagonal structure did not exhibit obvious strain rate effects.The results presented herein provide a basis for further rational design and selection of shock-resistant protective structures that perform well in high-speed impact environments.展开更多
With the rapid development of fifth-generation mobile com-munication technology and wearable electronic devices,electromagnetic interference and radiation pollution caused by electromagnetic waves have attracted world...With the rapid development of fifth-generation mobile com-munication technology and wearable electronic devices,electromagnetic interference and radiation pollution caused by electromagnetic waves have attracted worldwide attention.Therefore,the design and development of highly efficient EMI shielding materials are of great importance.In this work,the three-dimensional graphene oxide(GO)with regular honeycomb structure(GH)is firstly constructed by sacrificial template and freeze-dry-ing methods.Then,the amino functionalized FeNi alloy particles(f-FeNi)are loaded on the GH skeleton followed by in-situ reduction to prepare rGH@FeNi aerogel.Finally,the rGH@FeNi/epoxy EMI shielding com-posites with regular honeycomb structure is obtained by vacuum-assisted impregnation of epoxy resin.Benefitting from the construction of regular honeycomb structure and electromagnetic synergistic effect,the rGH@FeNi/epoxy composites with a low rGH@FeNi mass fraction of 2.1 wt%(rGH and f-FeNi are 1.2 and 0.9 wt%,respectively)exhibit a high EMI shielding effectiveness(EMI SE)of 46 dB,which is 5.8 times of that(8 dB)for rGO/FeNi/epoxy composites with the same rGO/FeNi mass fraction.At the same time,the rGH@FeNi/epoxy composites also possess excellent thermal stability(heat-resistance index and temperature at the maximum decomposition rate are 179.1 and 389.0°C respectively)and mechanical properties(storage modulus is 8296.2 MPa).展开更多
Dirac states composed of Px,y orbitals have been reported in many two-dimensional (2D) systems with honeycomb lattices recently. Their potential importance has aroused strong interest in a comprehensive understandin...Dirac states composed of Px,y orbitals have been reported in many two-dimensional (2D) systems with honeycomb lattices recently. Their potential importance has aroused strong interest in a comprehensive understanding of such states. Here, we construct a four-band tight-binding model for the Px,y-orbital Dirac states considering both the nearest neighbor hopping interactions and the lattice-buckling effect. We find that Px,y-orbital Dirac states are accompanied with two addi- tional narrow bands that are flat in the limit of vanishing n bonding, which is in agreement with previous studies. Most importantly, we analytically obtain the linear dispersion relationship between energy and momentum vector near the Dirac cone. We find that the Fermi velocity is determined not only by the hopping through n bonding but also by the hopping through ~ bonding of Px,y orbitals, which is in contrast to the case of pz-orbital Dirac states. Consequently, Px,y-orbital Dirac states offer more flexible engineering, with the Fermi velocity being more sensitive to the changes of lattice constants and buckling angles, if strain is exerted. We further validate our tight-binding scheme by direct first-principles calcula- tions of model-materials including hydrogenated monolayer Bi and Sb honeycomb lattices. Our work provides a more in-depth understanding of Px,y-orbital Dirac states in honeycomb lattices, which is useful for the applications of this family of materials in nanoelectronics.展开更多
The non-destructive testing of brazed joint in honeycomb structure with thin panel ( thickness : 0. 2 mm) was studied by ultrasonic C-scan method. Samples with different types of artificial defect were designed; th...The non-destructive testing of brazed joint in honeycomb structure with thin panel ( thickness : 0. 2 mm) was studied by ultrasonic C-scan method. Samples with different types of artificial defect were designed; the characteristic signal and the main parameters of the test were determined by the pre-experiment, and then parameters were optimized by orthogonal design, finally the optimum process was verified by a single panel sample. The multiple reflection echoes were chosen as the characteristic signal. The optimal C-scan results were achieved when the 20 MHz focus probe was used, and the pass band range for received signal were selected as 8 - 17. 5 MHz. The defects such as incomplete penetration and core damage can be detected with ultrasonic C-scan, and the detection accuracy can reach to 1 ram.展开更多
In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gu...In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.展开更多
Using the method of elasticity, an analytical approach is developed to analyze the shear stress in a honeycomb wing structure with a large aspect ratio under the condition of free torsion. The formulas of shear stress...Using the method of elasticity, an analytical approach is developed to analyze the shear stress in a honeycomb wing structure with a large aspect ratio under the condition of free torsion. The formulas of shear stress, warping and angle of twist are derived. These formulas are both useful and convenient from the point of view in the structure design.展开更多
Wave propagation in two-dimensional hierarchical honeycomb structures with two- order hierarchy is investigated by using the symplectic algorithm. By applying the variational prin- ciple to the dual variables, the wav...Wave propagation in two-dimensional hierarchical honeycomb structures with two- order hierarchy is investigated by using the symplectic algorithm. By applying the variational prin- ciple to the dual variables, the wave propagation problem is transformed into a two-dimensional symplectie eigenvalue problem. The band gaps and spatial filtering phenomena are examined to find the stop bands and directional stop bands. Special attention is directed to the effects of the relative density and the length ratio on the band gaps and phase constant surfaces. This work provides new opportunities for designing hierarchical honeycomb structures in sound insulation applications.展开更多
The development of heterogeneous acid catalysts with higher activity than homogeneous acid catalysts is critical and still challenging.In this study,acidic poly(ionic liquid)s with swelling ability(SAPILs)were designe...The development of heterogeneous acid catalysts with higher activity than homogeneous acid catalysts is critical and still challenging.In this study,acidic poly(ionic liquid)s with swelling ability(SAPILs)were designed and synthesized via the free radical copolymerization of ionic liquid monomers,sodium p-styrenesulfonate,and crosslinkers,followed by acidification.The 31P nuclear magnetic resonance chemical shifts of adsorbed trimethylphosphine oxide indicated that the synthesized SAPILs presented moderate and single acid strength.The thermogravimetric analysis results in the temperature range of 300–345°C revealed that the synthesized SAPILs were more stable than the commercial resin Amberlite IR-120(H)(245°C).Cryogenic scanning electron microscopy testing demonstrated that SAPILs presented unique three-dimensional(3D)honeycomb structure in water,which was ascribed to the swelling-induced self-assembly of the molecules.Moreover,we used SAPILs with micron-sized honeycomb structure in water as catalysts for the hydrolysis of cyclohexyl acetate to cyclohexanol,and determined that their catalytic activity was much higher than that of homogeneous acid catalysts.The equilibrium concentrations of all reaction components inside and outside the synthesized SAPILs were quantitatively analyzed using a series of simulated reaction mixtures.Depending on the reaction mixture,the concentration of cyclohexyl acetate inside SAPIL-1 was 7.5–23.3 times higher than that outside of it,which suggested the high enrichment ability of SAPILs for cyclohexyl acetate.The excellent catalytic performance of SAPILs was attributed to their 3D honeycomb structure in water and high enrichment ability for cyclohexyl acetate,which opened up new avenues for designing highly efficient heterogeneous acid catalysts that could eventually replace conventional homogeneous acid catalysts.展开更多
Thermal infrared camouflage technology has attracted increasing attention with the progress of infrared surveillance technologies.Inspired by honeycombs,a thermal infrared camouflage film with honeycomb sandwich struc...Thermal infrared camouflage technology has attracted increasing attention with the progress of infrared surveillance technologies.Inspired by honeycombs,a thermal infrared camouflage film with honeycomb sandwich structure based on fluid and temperature control is proposed to cloak objects and display false targets in the thermal infrared spectrum.The structure and manufacturing method of the film are introduced,and the fluid and temperature control system is established and tested to explore the thermal infrared characteristics of the film composed of different thermal units.The camouflage performance of the film is intuitively displayed through the temperature frequency histograms of the infrared images photographed by an infrared camera.The temperature control accuracy of the thermal infrared camouflage system and the dynamic camouflage response of the film are evaluated by the temperature distribution map of each pixel in infrared images and the salient degree values.Furthermore,the influential factors on the camouflage responding time are investigated,including the heating and cooling time of the liquid,the flow rate of pumps inside the driving module,and the energy loss along the liquid lines.An application of displaying false target is also introduced and tested.The results show that the camouflage film has a well camouflage effect and a wide adjustment temperature range,showing promise for a broad range of potential applications,such as counter-surveillance,thermal control and heat shielding.展开更多
Based on the symmetric re-entrant honeycomb(S-RH)structure with negative Poisson’s ratios,a novel asymmetric and rotatable re-entrant honeycomb(AR-RH)structure was proposed.Both the S-RH structure and AR-RH structure...Based on the symmetric re-entrant honeycomb(S-RH)structure with negative Poisson’s ratios,a novel asymmetric and rotatable re-entrant honeycomb(AR-RH)structure was proposed.Both the S-RH structure and AR-RH structure were produced by the 3D printing technology.Through experimental test and finite element simulation,the deformation mechanism and energy absorption characteristics of the AR-RH structure and the S-RH structure with negative Poisson’s ratios at different impact velocities were compared.The experimental test and finite element simulation results show that the novel AR-RH structure with negative Poisson’s ratios has stronger energy absorption capacity than the S-RH structure,and it has been verified that the rotatability of AR-RH can indeed absorb energy.Furthermore,the degree of asymmetry of the AR-RH structure was discussed.展开更多
A flexible asymmetric supercapacitor with high energy density was constructed by using a flexible substrate of carbonized silk-fabrics decorated with carbon nanotube, electroplating MnO2 nanosheets and dip-coating act...A flexible asymmetric supercapacitor with high energy density was constructed by using a flexible substrate of carbonized silk-fabrics decorated with carbon nanotube, electroplating MnO2 nanosheets and dip-coating activated carbon powders as the positive and the negative electrodes, respectively. By controlling the electroplating time, the MnO2 nanosheets can be self-assembled to honeycomb structure and showed excellent electrochemical performance in 1 mol/L Na2SO4 electrolyte with SC950-EP30 performing the best. It exhibited a high specific capacitance(1110.85 F/g at a current density of 1 A/g based on the mass of MnO2) and superior rate capability(77.44% capacity retention from 1 A/g to 10 A/g).Thus, the optimal asymmetric device assembled with this material as positive electrode can deliver a maximum energy density of 43.84 Wh/kg and a maximum power density of 6.62 kW/kg.展开更多
This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (...This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.展开更多
Honeycomb structures and other sandwich materials are being used as designs which have demanded high-stiffness and lightweight structures. The embedding design can further decrease the total weight of the products. Em...Honeycomb structures and other sandwich materials are being used as designs which have demanded high-stiffness and lightweight structures. The embedding design can further decrease the total weight of the products. Embedding will inevitably generate defect of the honeycomb and cause stress concentration. This study mainly discusses the tensile stress distribution near the defect in a quantitative way with the finite element and analytical method. The prediction function of the stress distribution is proposed. X and y directional stress distribution properties are found. These results are proved to be validate through a representative defect case. The bending stress distribution is investigated through material mechanics method and the prediction equation of the maximum bending stress is given.展开更多
The new-generation electronic components require a balance between electromagnetic interference shielding efficiency and open structure factors such as ventilation and heat dissipation.In addition,realizing the tunabl...The new-generation electronic components require a balance between electromagnetic interference shielding efficiency and open structure factors such as ventilation and heat dissipation.In addition,realizing the tunable shielding of porous shields over a wide range of wavelengths is even more challenging.In this study,the well-prepared thermoplastic polyurethane/carbon nanotubes composites were used to fabricate the novel periodic porous flexible metamaterials using fused deposition modeling 3D printing.Particularly,the investigation focuses on optimization of pore geometry,size,dislocation configuration and material thickness,thus establishing a clear correlation between structural parameters and shielding property.Both experimental and simulation results have validated the superior shielding performance of hexagon derived honeycomb structure over other designs,and proposed the failure shielding size(D_(f)≈λ/8-λ/5)and critical inclined angle(θf≈43°-48°),which could be used as new benchmarks for tunable electromagnetic shielding.In addition,the proper regulation of the material thickness could remarkably enhance the maximum shielding capability(85-95 dB)and absorption coefficient A(over 0.83).The final innovative design of the porous shielding box also exhibits good shielding effectiveness across a broad frequency range(over 2.4 GHz),opening up novel pathways for individualized and diversified shielding solutions.展开更多
On the basis about studying free bending for box beam with rectangular cross_section filled by honeycomb core,supplementary displacements and stresses of restrained bending for such beam were analyzed.The hypothesis f...On the basis about studying free bending for box beam with rectangular cross_section filled by honeycomb core,supplementary displacements and stresses of restrained bending for such beam were analyzed.The hypothesis for separated variables was adopted to solve displacement.According to this,three aspect equations of geometrical,physical and balance were obtained.With Galerkin's method,it is summed up as two_order ordinary differential equations with the attenuation character.Analysis makes clear that attenuation speed of stress is concerned with a big load or a small one,geometric dimensions of cross_section of beam,and physical parameter of material.展开更多
The compressive behaviour of paper honeycombs is studied by means of an experimental analysis. Experiment results show how geometry aspects of hexagonal paper honeycombs, e.g. the height of paper honeycomb, the thickn...The compressive behaviour of paper honeycombs is studied by means of an experimental analysis. Experiment results show how geometry aspects of hexagonal paper honeycombs, e.g. the height of paper honeycomb, the thickness and length of honeycomb cell-wall, the drawing ratio of hexagonal honeycomb, affect the compressive properties of the paper honeycombs. It is in good agreement with the theory model. The constraint factor K of the critical buckling stress is mainly determined by the length of honeycomb cell-wail. It can be described as K=1.54 for B type paper honeycombs and K=3.32 for D type paper honeycombs. The plateau stress is the power exponent function of the thickness to length ratio of honeycomb cell-wall, and the experiment results show that the constant is 13.2 and the power exponent is 1.77. The research results can be used to characterize and improve efficiently the compressive properties of paper honeycombs.展开更多
In this article,theoretical calculations on the bending performance(bending strength and bending modulus)of fiberglass reinforced plastic(FRP)honeycomb sandwich structures were conducted initially,and then the bending...In this article,theoretical calculations on the bending performance(bending strength and bending modulus)of fiberglass reinforced plastic(FRP)honeycomb sandwich structures were conducted initially,and then the bending performance of two FRP honeycomb sandwich structures with different thicknesses were measured by the Aerospace Materials Failure Analysis Center.By comparing and analyzing the theoretical calculations and experimental results,it was found that the theoretical calculated bending strength and bending modulus were in good agreement with those of the experimental tested within 26.5%.When designers and technicians conduct theoretical calculations on the performance of FRP honeycomb sandwich structures,they can use the formulas derived in this article,which will more accurately predict the mechanical properties of components made of composite materials.展开更多
基金financially supported by National Natural Science Foundation of China,China (Grant No.52022012)National Key R&D Program for Young Scientists of China,China (Grant No.2022YFC3080900)。
文摘The high variability of shock in terrorist attacks poses a threat to people's lives and properties,necessitating the development of more effective protective structures.This study focuses on the angle gradient and proposes four different configurations of concave hexagonal honeycomb structures.The structures'macroscopic deformation behavior,stress-strain relationship,and energy dissipation characteristics are evaluated through quasi-static compression and Hopkinson pressure bar impact experiments.The study reveals that,under varying strain rates,the structures deform starting from the weak layer and exhibit significant interlayer separation.Additionally,interlayer shear slip becomes more pronounced with increasing strain rate.In terms of quasi-static compression,symmetric gradient structures demonstrate superior energy absorption,particularly the symmetric negative gradient structure(SNG-SMS)with a specific energy absorption of 13.77 J/cm~3.For dynamic impact,unidirectional gradient structures exhibit exceptional energy absorption,particularly the unidirectional positive gradient honeycomb structure(UPG-SML)with outstanding mechanical properties.The angle gradient design plays a crucial role in determining the structure's stability and deformation mode during impact.Fewer interlayer separations result in a more pronounced negative Poisson's ratio effect and enhance the structure's energy absorption capacity.These findings provide a foundation for the rational design and selection of seismic protection structures in different strain rate impact environments.
文摘The novelty of this research lies in the successful fabrication of a 3D-printed honeycomb structure filled with nanofillers for acoustic properties,utilizing an impedance tube setup in accordance with ASTM standard E 1050-12.The Creality Ender-3,a 3D printer,was used for printing the honeycomb structures,and polylactic acid(PLA)material was employed for their construction.The organic,inorganic,and polymeric compounds within the composites were identified using fourier transformation infrared(FTIR)spectroscopy.The structure and homogeneity of the samples were examined using a field emission scanning electron microscope(FESEM).To determine the sound absorption coefficient of the 3D printed honeycomb structure,numerous samples were systematically developed using central composite design(CCD)and analysed using response surface methodology(RSM).The RSM mathematical model was established to predict the optimum values of each factor and noise reduction coefficient(NRC).The optimum values for an NRC of 0.377 were found to be 1.116 wt% carbon black,1.025 wt% aluminium powder,and 3.151 mm distance between parallel edges.Overall,the results demonstrate that a 3Dprinted honeycomb structure filled with nanofillers is an excellent material that can be utilized in various fields,including defence and aviation,where lightweight and acoustic properties are of great importance.
基金financially supported by the National Natural Science Foundation of China(51972049,52073010,and 52373259)the Projects of the Science and Technology Department of Jilin Province(20230201132GX)the Projects of the Education Department of Jilin Province(JJKH20220123KJ)。
文摘The impedance matching of absorbers is a vital factor affecting their microwave absorption(MA)properties.In this work,we controllably synthesized Material of Institute Lavoisier 88C(MIL-88C)with varying aspect ratios(AR)as a precursor by regulating oil bath conditions,followed by one-step thermal decomposition to obtain carbon-coated iron-based composites.Modifying the precursor MIL-88C(Fe)preparation conditions,such as the molar ratio between metal ions and organic ligands(M/O),oil bath temperature,and oil bath time,influenced the phases,graphitization degree,and AR of the derivatives,enabling low filler loading,achieving well-matched impedance,and ensuring outstanding MA properties.The MOF-derivatives 2(MD_(2))/polyvinylidene Difluoride(PVDF),MD_(3)/PVDF,and MD4/PVDF absorbers all exhibited excellent MA properties with optimal filler loadings below 20 wt%and as low as 5 wt%.The MD_(2)/PVDF(5 wt%)achieved a maximum effective absorption bandwidth(EAB)of 5.52 GHz(1.90 mm).The MD_(3)/PVDF(10 wt%)possessed a minimum reflection loss(RL_(min))value of−67.4 at 12.56 GHz(2.13 mm).A symmetric gradient honeycomb structure(SGHS)was constructed utilizing the high-frequency structure simulator(HFSS)to further extend the EAB,achieving an EAB of 14.6 GHz and a RL_(min) of−59.0 dB.This research offers a viable inspiration to creating structures or materials with high-efficiency MA properties.
基金supported by the National Natural Science Foundation of China(Grant No.51874041)the National Outstanding Youth Science Fund Project of National Natural Science Foundation of China(Grant No.52202012)。
文摘High-speed impact threats and terrorist actions on the battlefield require the development of more effective protective materials and structures,and various protective structure is designed according their energy-absorbing characteristics.In this research,the deformation behavior,microscopic failure modes and energy absorption characteristics of re-entrant hexagonal structure,regular hexagonal structure and regular quadrilateral structure are studied under different strain rates impact.The re-entrant hexagonal structure forms a“X”-shaped deformation zone,the regular quadrilateral and regular hexagonal structure form an“I”-shaped deformation zone.The microscopic appearance of the section is a mixed fracture form.The effects of the topological shape,cell angle,and cell height on the impact behavior of the structure were evaluated.When the cell height is fixed and the cell angle is changed,the energy absorption of the structure increase and then decrease as the relative density increase.The mechanical properties of the structure are optimal when the relative density is about 18.6%and the cell angle is22.5°.When the cell angle is fixed and the cell height is changed,as the relative density increases,the energy absorption of the structure gradually increases.The regular quadrilateral structure and the reentrant hexagonal structure experienced clear strain rate effects under dynamic impact conditions;the regular hexagonal structure did not exhibit obvious strain rate effects.The results presented herein provide a basis for further rational design and selection of shock-resistant protective structures that perform well in high-speed impact environments.
基金supports from the National Natural Science Foundation of China(U21A2093 and 51903145)Natural Science Basic Research Plan for Distinguished Young Scholars in Shaanxi Province of China(2019JC-11)and Fundamental Research Funds for the Central Universities(D5000210627)This work is also financially supported by Polymer Electromagnetic Functional Materials Innovation Team of Shaanxi Sanqin Scholars.
文摘With the rapid development of fifth-generation mobile com-munication technology and wearable electronic devices,electromagnetic interference and radiation pollution caused by electromagnetic waves have attracted worldwide attention.Therefore,the design and development of highly efficient EMI shielding materials are of great importance.In this work,the three-dimensional graphene oxide(GO)with regular honeycomb structure(GH)is firstly constructed by sacrificial template and freeze-dry-ing methods.Then,the amino functionalized FeNi alloy particles(f-FeNi)are loaded on the GH skeleton followed by in-situ reduction to prepare rGH@FeNi aerogel.Finally,the rGH@FeNi/epoxy EMI shielding com-posites with regular honeycomb structure is obtained by vacuum-assisted impregnation of epoxy resin.Benefitting from the construction of regular honeycomb structure and electromagnetic synergistic effect,the rGH@FeNi/epoxy composites with a low rGH@FeNi mass fraction of 2.1 wt%(rGH and f-FeNi are 1.2 and 0.9 wt%,respectively)exhibit a high EMI shielding effectiveness(EMI SE)of 46 dB,which is 5.8 times of that(8 dB)for rGO/FeNi/epoxy composites with the same rGO/FeNi mass fraction.At the same time,the rGH@FeNi/epoxy composites also possess excellent thermal stability(heat-resistance index and temperature at the maximum decomposition rate are 179.1 and 389.0°C respectively)and mechanical properties(storage modulus is 8296.2 MPa).
基金Project supported by the National Key Research and Development Projects of China(Grant No.2016YFA0202300)the National Natural Science Foundation of China(Grant No.61390501)+1 种基金the Science Fund from the Chinese Academy of Sciences(Grant No.XDPB0601)the US Army Research Office
文摘Dirac states composed of Px,y orbitals have been reported in many two-dimensional (2D) systems with honeycomb lattices recently. Their potential importance has aroused strong interest in a comprehensive understanding of such states. Here, we construct a four-band tight-binding model for the Px,y-orbital Dirac states considering both the nearest neighbor hopping interactions and the lattice-buckling effect. We find that Px,y-orbital Dirac states are accompanied with two addi- tional narrow bands that are flat in the limit of vanishing n bonding, which is in agreement with previous studies. Most importantly, we analytically obtain the linear dispersion relationship between energy and momentum vector near the Dirac cone. We find that the Fermi velocity is determined not only by the hopping through n bonding but also by the hopping through ~ bonding of Px,y orbitals, which is in contrast to the case of pz-orbital Dirac states. Consequently, Px,y-orbital Dirac states offer more flexible engineering, with the Fermi velocity being more sensitive to the changes of lattice constants and buckling angles, if strain is exerted. We further validate our tight-binding scheme by direct first-principles calcula- tions of model-materials including hydrogenated monolayer Bi and Sb honeycomb lattices. Our work provides a more in-depth understanding of Px,y-orbital Dirac states in honeycomb lattices, which is useful for the applications of this family of materials in nanoelectronics.
文摘The non-destructive testing of brazed joint in honeycomb structure with thin panel ( thickness : 0. 2 mm) was studied by ultrasonic C-scan method. Samples with different types of artificial defect were designed; the characteristic signal and the main parameters of the test were determined by the pre-experiment, and then parameters were optimized by orthogonal design, finally the optimum process was verified by a single panel sample. The multiple reflection echoes were chosen as the characteristic signal. The optimal C-scan results were achieved when the 20 MHz focus probe was used, and the pass band range for received signal were selected as 8 - 17. 5 MHz. The defects such as incomplete penetration and core damage can be detected with ultrasonic C-scan, and the detection accuracy can reach to 1 ram.
文摘In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.
文摘Using the method of elasticity, an analytical approach is developed to analyze the shear stress in a honeycomb wing structure with a large aspect ratio under the condition of free torsion. The formulas of shear stress, warping and angle of twist are derived. These formulas are both useful and convenient from the point of view in the structure design.
基金Project supported by the National Basic Research Program of China(No.2011CB610300)the National Natural Science Foundation of China(Nos.11172239 and 11372252)+3 种基金the Doctoral Program Foundation of Education Ministry of China(No.20126102110023)the Fundamental Research Funds for the Central Universities(Nos.310201401JCQ01001 and 3102015ZY036)China Postdoctoral Science Foundation(No.2013M540724)Shaanxi postdoctoral research projects
文摘Wave propagation in two-dimensional hierarchical honeycomb structures with two- order hierarchy is investigated by using the symplectic algorithm. By applying the variational prin- ciple to the dual variables, the wave propagation problem is transformed into a two-dimensional symplectie eigenvalue problem. The band gaps and spatial filtering phenomena are examined to find the stop bands and directional stop bands. Special attention is directed to the effects of the relative density and the length ratio on the band gaps and phase constant surfaces. This work provides new opportunities for designing hierarchical honeycomb structures in sound insulation applications.
文摘The development of heterogeneous acid catalysts with higher activity than homogeneous acid catalysts is critical and still challenging.In this study,acidic poly(ionic liquid)s with swelling ability(SAPILs)were designed and synthesized via the free radical copolymerization of ionic liquid monomers,sodium p-styrenesulfonate,and crosslinkers,followed by acidification.The 31P nuclear magnetic resonance chemical shifts of adsorbed trimethylphosphine oxide indicated that the synthesized SAPILs presented moderate and single acid strength.The thermogravimetric analysis results in the temperature range of 300–345°C revealed that the synthesized SAPILs were more stable than the commercial resin Amberlite IR-120(H)(245°C).Cryogenic scanning electron microscopy testing demonstrated that SAPILs presented unique three-dimensional(3D)honeycomb structure in water,which was ascribed to the swelling-induced self-assembly of the molecules.Moreover,we used SAPILs with micron-sized honeycomb structure in water as catalysts for the hydrolysis of cyclohexyl acetate to cyclohexanol,and determined that their catalytic activity was much higher than that of homogeneous acid catalysts.The equilibrium concentrations of all reaction components inside and outside the synthesized SAPILs were quantitatively analyzed using a series of simulated reaction mixtures.Depending on the reaction mixture,the concentration of cyclohexyl acetate inside SAPIL-1 was 7.5–23.3 times higher than that outside of it,which suggested the high enrichment ability of SAPILs for cyclohexyl acetate.The excellent catalytic performance of SAPILs was attributed to their 3D honeycomb structure in water and high enrichment ability for cyclohexyl acetate,which opened up new avenues for designing highly efficient heterogeneous acid catalysts that could eventually replace conventional homogeneous acid catalysts.
基金the National Natural Science Foundation of China for the support(No.51175101)on this paper。
文摘Thermal infrared camouflage technology has attracted increasing attention with the progress of infrared surveillance technologies.Inspired by honeycombs,a thermal infrared camouflage film with honeycomb sandwich structure based on fluid and temperature control is proposed to cloak objects and display false targets in the thermal infrared spectrum.The structure and manufacturing method of the film are introduced,and the fluid and temperature control system is established and tested to explore the thermal infrared characteristics of the film composed of different thermal units.The camouflage performance of the film is intuitively displayed through the temperature frequency histograms of the infrared images photographed by an infrared camera.The temperature control accuracy of the thermal infrared camouflage system and the dynamic camouflage response of the film are evaluated by the temperature distribution map of each pixel in infrared images and the salient degree values.Furthermore,the influential factors on the camouflage responding time are investigated,including the heating and cooling time of the liquid,the flow rate of pumps inside the driving module,and the energy loss along the liquid lines.An application of displaying false target is also introduced and tested.The results show that the camouflage film has a well camouflage effect and a wide adjustment temperature range,showing promise for a broad range of potential applications,such as counter-surveillance,thermal control and heat shielding.
基金This work is supported by the State Key for Strength and Vibration of Mechanical Structures of Xi’an Jiaotong University(No.SV2018-KF-32)the Natural Science Foundation of Guangdong Province of China(2020A1515011064).
文摘Based on the symmetric re-entrant honeycomb(S-RH)structure with negative Poisson’s ratios,a novel asymmetric and rotatable re-entrant honeycomb(AR-RH)structure was proposed.Both the S-RH structure and AR-RH structure were produced by the 3D printing technology.Through experimental test and finite element simulation,the deformation mechanism and energy absorption characteristics of the AR-RH structure and the S-RH structure with negative Poisson’s ratios at different impact velocities were compared.The experimental test and finite element simulation results show that the novel AR-RH structure with negative Poisson’s ratios has stronger energy absorption capacity than the S-RH structure,and it has been verified that the rotatability of AR-RH can indeed absorb energy.Furthermore,the degree of asymmetry of the AR-RH structure was discussed.
基金financially supported by the National Natural Science Foundation of China(No.51672151)973 Program of China(No.2014CB932401)
文摘A flexible asymmetric supercapacitor with high energy density was constructed by using a flexible substrate of carbonized silk-fabrics decorated with carbon nanotube, electroplating MnO2 nanosheets and dip-coating activated carbon powders as the positive and the negative electrodes, respectively. By controlling the electroplating time, the MnO2 nanosheets can be self-assembled to honeycomb structure and showed excellent electrochemical performance in 1 mol/L Na2SO4 electrolyte with SC950-EP30 performing the best. It exhibited a high specific capacitance(1110.85 F/g at a current density of 1 A/g based on the mass of MnO2) and superior rate capability(77.44% capacity retention from 1 A/g to 10 A/g).Thus, the optimal asymmetric device assembled with this material as positive electrode can deliver a maximum energy density of 43.84 Wh/kg and a maximum power density of 6.62 kW/kg.
文摘This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.
文摘Honeycomb structures and other sandwich materials are being used as designs which have demanded high-stiffness and lightweight structures. The embedding design can further decrease the total weight of the products. Embedding will inevitably generate defect of the honeycomb and cause stress concentration. This study mainly discusses the tensile stress distribution near the defect in a quantitative way with the finite element and analytical method. The prediction function of the stress distribution is proposed. X and y directional stress distribution properties are found. These results are proved to be validate through a representative defect case. The bending stress distribution is investigated through material mechanics method and the prediction equation of the maximum bending stress is given.
基金supported by the National Key R&D Program of China(2023YFB4603504)the International Science&Technology Innovation Cooperation Project of Sichuan Province(2024YFHZ0232)+2 种基金the International Science&Technology Cooperation Project of Chengdu(2021-GH03-00009-HZ)the Program for Featured Directions of Engineering Multi-disciplines of Sichuan University(2020SCUNG203)the Program of Innovative Research Team for Young Scientists of Sichuan Province(22CXTD0019).
文摘The new-generation electronic components require a balance between electromagnetic interference shielding efficiency and open structure factors such as ventilation and heat dissipation.In addition,realizing the tunable shielding of porous shields over a wide range of wavelengths is even more challenging.In this study,the well-prepared thermoplastic polyurethane/carbon nanotubes composites were used to fabricate the novel periodic porous flexible metamaterials using fused deposition modeling 3D printing.Particularly,the investigation focuses on optimization of pore geometry,size,dislocation configuration and material thickness,thus establishing a clear correlation between structural parameters and shielding property.Both experimental and simulation results have validated the superior shielding performance of hexagon derived honeycomb structure over other designs,and proposed the failure shielding size(D_(f)≈λ/8-λ/5)and critical inclined angle(θf≈43°-48°),which could be used as new benchmarks for tunable electromagnetic shielding.In addition,the proper regulation of the material thickness could remarkably enhance the maximum shielding capability(85-95 dB)and absorption coefficient A(over 0.83).The final innovative design of the porous shielding box also exhibits good shielding effectiveness across a broad frequency range(over 2.4 GHz),opening up novel pathways for individualized and diversified shielding solutions.
文摘On the basis about studying free bending for box beam with rectangular cross_section filled by honeycomb core,supplementary displacements and stresses of restrained bending for such beam were analyzed.The hypothesis for separated variables was adopted to solve displacement.According to this,three aspect equations of geometrical,physical and balance were obtained.With Galerkin's method,it is summed up as two_order ordinary differential equations with the attenuation character.Analysis makes clear that attenuation speed of stress is concerned with a big load or a small one,geometric dimensions of cross_section of beam,and physical parameter of material.
基金This project is supported by Guangdong Provincial Key Laboratory Foundation of Higher Education Institutions, China.
文摘The compressive behaviour of paper honeycombs is studied by means of an experimental analysis. Experiment results show how geometry aspects of hexagonal paper honeycombs, e.g. the height of paper honeycomb, the thickness and length of honeycomb cell-wall, the drawing ratio of hexagonal honeycomb, affect the compressive properties of the paper honeycombs. It is in good agreement with the theory model. The constraint factor K of the critical buckling stress is mainly determined by the length of honeycomb cell-wail. It can be described as K=1.54 for B type paper honeycombs and K=3.32 for D type paper honeycombs. The plateau stress is the power exponent function of the thickness to length ratio of honeycomb cell-wall, and the experiment results show that the constant is 13.2 and the power exponent is 1.77. The research results can be used to characterize and improve efficiently the compressive properties of paper honeycombs.
文摘In this article,theoretical calculations on the bending performance(bending strength and bending modulus)of fiberglass reinforced plastic(FRP)honeycomb sandwich structures were conducted initially,and then the bending performance of two FRP honeycomb sandwich structures with different thicknesses were measured by the Aerospace Materials Failure Analysis Center.By comparing and analyzing the theoretical calculations and experimental results,it was found that the theoretical calculated bending strength and bending modulus were in good agreement with those of the experimental tested within 26.5%.When designers and technicians conduct theoretical calculations on the performance of FRP honeycomb sandwich structures,they can use the formulas derived in this article,which will more accurately predict the mechanical properties of components made of composite materials.