Hydrochemistry of the lakes in the southern Badain Jaran Desert and its paleosalinity reconstruction

The reconstruction of paleohydrology,especially paleosalinity,is an important component of paleoenvironmental research.Researches on the modern characteristics of lake water chemistry and the relationship between lake salinity and hydrochemistry are the basis of paleoenvironment reconstruction.The modern hydrochemical characteristics and the relationship between ion composition and salinity of modern lakes are the basis of paleosalinity reconstruction.In this study,hydrochemical analysis of 21 lakes in the Badain Jaran Desert(BJD)was carried out.The relationships between the Sr/Ca and Mg/Ca ratios and total dissolved solids(TDS)were analyzed.The results show that Na^(+),K^(+),Cl-and SO_(4)^(2-)have high positive correlations with TDS,and Mg^(2+),Sr^(2+),CO_(3)_(2-)and HCO_(3)^(-)have lower correlations with TDS.The Sr/Ca and Mg/Ca ratios do not increase linearly with TDS.Hydrochemical analysis indicates that the studied lakes are in the carbonate precipitation stage and that evaporation is the main factor controlling lake evolution in the BJD.The relationships between the Mg/Ca and Sr/Ca ratios and TDS are mainly influenced by lake evolution stage and the hydrochemical types of the lakes.On the basis of comprehensive previous studies,the factors affecting lake evolution,the Mg and Sr partition coefficients and other hydrochemical parameters that change with lake evolution all affect the relationship between chemical composition and salinity.To reconstruct paleosalinity more accurately,more detailed research on the modern hydrochemical characteristics of lakes and the relationship between the element ratios of carbonates and water salinity should be carried out.

Application of hydrochemistry and strontium isotope for understanding the hydrochemical characteristics and genesis of strontium-rich groundwater in karst area,Gongcheng County,Southwest China

Understanding the hydrochemical characteristics and genesis mechanisms of strontium-rich groundwater is pivotal for supporting the exploitation and utilization of natural strontium-rich groundwater.In this research,27 groundwater samples were collected.By analyzing major ion chemistry and strontium isotope data,and considering the hydrogeological context,various analytical approaches,including multivariate statistics,ion ratios,and isotopes,were used to reveal the characteristics and genesis mechanisms of strontium-rich groundwater in the study area.The findings indicate that the predominant hydrochemical type of groundwater is HCO_(3)-Ca,with Ca^(2+)and HCO_(3)^(-)as the primary cations and anions.The hydrochemistry of the strontium-rich groundwater is predominantly influenced by rock weathering processes.A combination of factors,including ion exchange,and anthropogenic activities,shapes the compositional characteristics of the groundwater in the region.The dissolution of calcite due to weathering emerges as the principal source of strontium in the groundwater.While ion exchange processes are not conducive to strontium enrichment in groundwater,their effect is relatively limited.The impact of human activities on the groundwater is minor.

Hydrochemistry of Groundwater in the Rice Cultivation Area of Maga: Analysis of the Mineralization Process

The use of groundwater for drinking water supply to the population is increasingly practiced in the rice cultivation area of Maga. However, there is a lack of knowledge about the hydrochemical characteristics of this water due to a lack of quality control. This study aims to contribute to the understanding of mineralization processes in order to establish the hydrochemical profile of the water in the area. The methodological approach consisted of collecting fifteen water samples from wells and boreholes during six campaigns for physicochemical analysis, and studying them through methods of interpreting hydrochemical data. The analysis results show that these waters are moderately mineralized. The water facies are mainly of the bicarbonate sodium and potassium type, as well as the bicarbonate calcium and magnesium type. Calculation of saturation indices demonstrates that evaporite minerals show lower degrees of saturation than carbonate minerals, with gypsum, anhydrite, and halite being in a highly undersaturated state. The mineralization of groundwater originates from the dissolution of surrounding rocks on the one hand, and anthropogenic activities involving exchanges between alkalis (Na+ and K+) in the aquifer and alkaline earth (Ca2+ and Mg2+), resulting in the fixation of alkaline earth and the dissolution of alkalis.

Genesis of Neogene Formation Waters in the Central Qaidam Basin:Clues from Hydrochemistry and Stable D-O-S-Sr Isotopes

Geological explorations have revealed plentiful Neogene formation waters in anticlines in the central Qaidam Basin(QB).However,the hydrochemistry and origin of these waters are obscure.In this study,the hydrochemistry and DO-S-Sr isotopes of these formation waters were determined to study their origin and evolution.The formation waters are enriched in Na-Ca-Cl,and depleted in Mg-K-SO4-HCO3ions with elevated Li-B-Br-Sr elements.The D-O isotopes prove that the formation waters originated from weak-evaporated meteoric waters,and experienced water-rock interactions.Ion comparisons and Caexcess-Nadeficitdiagrams suggest that solute sources of these waters include evaporite dissolution,waterrock interaction,and minor residual lake brines.Bacterial sulfate reduction and water-rock interactions are supported by the high S-Sr isotopes.The enriched Li-B-Br-Sr concentrations of these waters are in accord with the high geochemical background values of the QB.Regarding the genesis of the formation waters,it can be concluded that meteoric waters from the southern Kunlun Mountains were discharged into the basin,weakly evaporated,and then infiltrated into the Neogene strata through faults leaching the soluble ions and mixing with residual lake brines,and all experienced water-rock interactions and a sulphate reduction process.

Palaeoclihlatic Indicators of China's Quaternary Saline Lake Sediments and Hydrochemistry

In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.

Groundwater hydrochemistry and isotope geochemistry in the Turpan Basin, northwestern China

The Turpan Basin is located in the arid zone of northwestern China and is a typical closed inland basin surrounded by high mountains. It is one of the most arid regions in the world and, as a result, the groundwater in this area is very important for both domestic and agricultural uses. In the present study, the relationships of major elements（K＋, Na＋, Ca2＋, Mg2＋, HCO3-, SO42- and Cl-） and environmental isotopes（δ18O, δ2H and T） in groundwater were analyzed to investigate the evolution of the regional hydrochemistry within the Turpan Basin. The hydrochemistry results demonstrate that groundwater with high total dissolved solids（TDS） concentration is dominated by sodium chloride（Na-Cl） and sodium sulfate（Na-SO4） type water, whereas that with low TDS concentration（typically from near mountain areas） is dominated by calcium bicarbonate（Ca-HCO3） type water. The evolution of groundwater hydrochemistry within the Turpan Basin is a result of calcium carbonate precipitation, evaporation concentration, cation exchange and dissolution of evaporites（i.e. halite, mirabilite and gypsum）. Furthermore, evaporite dissolution associated with irrigation practice plays a key role in the groundwater salinization, especially in the central part of the basin. Environmental isotopes reveal that the groundwater is recharged by precipitation in the mountain areas and fast vertical infiltration of irrigation return flow. In the southern sub-basin the shallow groundwater and the deep groundwater is separated at a depth of about 40 m, with substantial differences in terms of hydrochemical and isotopic characteristics. The results are useful for decision making related to sustainable water resource utilization in the Turpan Basin and other regions in northwestern China.

Diurnal and seasonal variation of glacier meltwater hydrochemistry in Qiyi glacierized catchment in Qilian Mountains, Northwest China: implication for chemical weathering

In glacierized catchments, glacier runoff typically shows a strong diurnal cycle in the ablation season(June-September). To elucidate the effect of these processes on the chemical weathering, fresh snowfall and water samples were collected and studied from the supraglacial river, proglacial river,and gauging site in Qiyi glacierized catchment Qilian Mountains, Northwestern China, in the summer of2011. The pH and electronic conductivity(EC) were determined in the field, and the concentrations of major ions(Na^+, K^+, Mg^(2+), Ca^(2+), Cl^-, SO_4^(2-), NO_3^-) were measured. The results indicated that EC linearly increased with increasing distance from the glacial snout, and the concentrations of major ions increased with increasing water-rock interaction time. Along the flow path of the glacier runoff, Na^+ and Cl^-are more concentrated than other ions in the supraglacial river while Mg^(2+) and SO_4^(2-)are more concentrated than other ions at the gauging site. The discharge, pH, EC,and the concentrations of major ions exhibited significant diurnal variation along the flow path. On the other hand, the amplitude of variation diminished from upstream to downstream along the flow path.The chemical weathering rate(Na^++K^++Mg^(2+)+Ca^(2+))was determined to be 10.9 t/yr/km^2. Moreover,further research indicated that the sampling method influenced the assessment of chemical weathering rates. When the sample was collected randomly in one diurnal cycle of hydrography, the estimated ionic flux could deviate-47%~73% based on estimated hourly data. In contrast, if three samples were collected at peak, base flow and the discharge decreasing rate starts to slow down in one diurnal cycle of hydrography, respectively, the deviation would be less than 15%. The smaller the diurnal variation of discharge, the smaller deviation calculated.

INVESTIGATION ON FUNDAMENTAL CHARACTERISTICS OF HYDROCHEMISTRY IN HEAD AREA OF THE CANGJIANG RIVER

The results of water sample analyses and investigation in the head area of the Changjiang River reveal that the characteristics of hydrochemistry of the river vary with drainage basins. In the drainage basin of the Tuotuo River, the mineral concentration of water is generally high, ions of Cl and Na+ are obviously dominant. The water tends to be salty, and the type of hydrochemistry is rather complex. In the drainage basin of the Dam River, the mineral concentration is mainly in a low and middle level, ions of HCO3- and Ca2+ are higher than others, and the type of hydrochemistry is relatively simple. The ground water in deep layers plays an important role in recharging surface water, and the stable recharging results in little change in chemical composition of surface water.

Hydrochemistry of the meltwater streams on Fildes Peninsula, King George Island, Antarctica

King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that af fect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runof fs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input.

Hydrochemistry of Rain Water and Atmospheric Pollution in Baghdad,Iraq

The atmospheric pollution in Baghdad was investigated by using rainwater as a media for monitoring of pollution and also compared with the atmosphere pollution at reference stations of Al-Sulaimaniya in north of Iraq and Al-Rutbah in Western Desert of Iraq. Rainwater sampling carried out at period extended from Nov.2007 to April 2008.Thirty five samples of rainwater were collected at seven monitoring

Hydrochemistry as Indicator to Select the Suitable Locations for Water Storage in Tharthar Valley, Al-Jazira Area, Iraq

Four locations were chosen according to geomorphologic and engineering criterion to store the water on the midstream of Tharthar valley, water samples were collected from the four locations to evaluate the hydrochemical properties as indicator to select the more suitable location, these locations are Hatra, Abu-Hamam, Tlol Al-Baj and Al-Sukkariah from the north to the south respectively. Also, the groundwater samples were collected from two shallow wells on the banks. The samples were analyzed to determine the concentrations of most common anions and cations in the water Ca2+, Mg2+, Na+, K+, CO32-, HCO3-, Cl–, SO42+. Also, pH, EC and TDS were measured. The results reflect high variations in concentrations of the soluble materials, the concentrations of these components are highly increased in locations of Tlol Al-Baj and Al-Sukkariah in comparison with the locations of Hatra and Abu-Hamam. The variation in geology of the area along the valley was represented a main role on the quality of water. These results can help to select the suitable locations of small dam (dams) to store the water in the valley and prevent the problem of salinity. According to the results, the northern part of midstream (north of Abu-Hamam) is suitable for water storage and the dam construction. While the locations of the downstream enriched by local sources of salts.

Hydrochemistry and Quality Assessment of Water in Tannur Dam, Southern Jordan

The study was undertaken to assess the physicochemical and chemical quality of the Tannur dam water in southern Jordan. The water samples were collected in two intervals the first during May 2015 and the second during September 2015. All samples were analyzed for temperature, conductivity, dissolved oxygen, pH, major cations (Ca2+, Mg2+, K+, Na+), and major anions (Cl-, NO3-, HCO3- and SO42-). The hydrogeochemical analyses of thirty-six water samples were used to determine the properties and type of water in the Tannur dam. The ion concentration in the water samples was from dissolution of carbonate rocks and ion exchange processes in clay. The general chemistry of water samples was typical alkaline earth waters with prevailing bicarbonate chloride. The PHREEQC Hydrogeochemical modeling was used to obtain the saturation indices of specific mineral phases, which might be related to interaction with water and aquifer, and to identify the chemical species of the dissolved ions. Calcite and dolomite solubility were assessed in terms of saturation index where they show positive values indication oversaturated SI > 0. The hydrogeochemistry behavior is rather complicated and is affected by anthropogenic and natural sources. The positive correlation values between various parameters indicate that most of ions result from same lithological sources. The abundance of the major ions in water samples is in the following order: HCO3-> Ca2+ > Cl- > NO3- > SO42-) > Na+ > Mg2+ > K+. Water samples of the Tannur dam are generally very hard, high to very high saline and medium alkaline in nature. High total hardness (TH) and total dissolved solids (TDS) in some samples identify the permissible for domestic and irrigation purposes. According to the residual sodium carbonate, SAR and conductivity values, the studied water is suitable for agricultural purposes.

Hydrochemistry of Umm Er Radhuma Groundwater

Umm Er Radhuma Aquifer (UER) is the most important groundwater aquifer in Saudi Arabia, extending over 1.6 M·km2 in the eastern part of the Arabian Peninsula, forming the main aquifer throughout the Rub’ Al-Khali (RAK). Groundwater salinity increased from west to east, reaching more than 27,000 mg/L near the border with the United Arab Emirates, where a Na+-Ca2+Clˉ- water type dominated. Gibbs diagrams indicated that the dissolution/precipitation of carbonates and evaporation/precipitation of minerals, especially anhydrite, gypsum, and halite account for the solutes and salinity in groundwater. Most of the samples plot above the 1:1 line of (Ca2+ + Mg2+) against , indicating other sources of Ca2+ and Mg2+ in the groundwater along with dolomite and calcium carbonate minerals. Phreeqc model indicated that the main clay minerals are kaolinite and gibbsite which had major effect on the cation exchange process as indicated by the Chloro-Alkaline index (CAI), where most of groundwater samples had values greater than zero which indicated the occurrence of reverse ion exchange between the groundwater and its host aquifer. The water type Na+-Ca2+Clˉ-dominated in the eastern part of the aquifer as the anaerobic conditions prevailed and the reduction of sulphate took place.

Hydrochemistry of the Mixed Dead Sea-Red Sea Water under Different Impoundment Scenarios as a Time Dependent State

The expected water mixing process between Red/Dead Sea water during the proposed conveyance projects is the main target of this research. The project will ensue transporting Red Sea water to recover and maintain certain level of the Dead Sea, mostly will reach -395 m. It is found that, the two different water bodies with different EC values or different densities (salinities) are relatively divided by stable plane. This plane is defined as the BARZACH PLANE. In this study, the mixing process occurred between the Red Sea with the Dead Sea waters, located at 20% - 24% of the Dead Sea column depth based on the Barzach Plane level. During a laboratory experimental work, it is found that the mixed Red/Dead Sea water evaporates in a high rate until certain level where the solution attains oversaturated conditions with different dissolved solids. At this stage, a thin layer of solids suddenly formed and floated at the surface of the dense brine. The salinity of the captured water is so dense that floated salt layer cannot be dissolved. In addition, the formed floated salt layer at the surface prevents the below captured water to evaporate and at this stage, stalactites start to form until the excess dissolved solids are not oversaturated with any mineral.

Sanitary Surveys and Hydrochemistry of Groundwater in Two Urban Towns (Ado-Ekiti and Ijero-Ekiti), Southwestern Nigeria

Groundwater contamination in urban cities is imminent in the phase of increased anthropogenic activities apart from the contribution of geogenic contaminants. This study examined the sanitary surveys and hydrochemistry of groundwater in Ado-Ekiti and Ijero-Ekiti to establish the contaminants’ sources, decipher the effects of urbanization on population and explain any relationship between the surveys and the groundwater chemistry. Sanitary surveys of 30 randomly selected wells each from Ado-Ekiti and Ijero-Ekiti were executed by administering and processing appropriately designed questionnaires that addressed salient problems of hygiene and sanitation. The results of the surveys were grouped into very high risk, high risk, intermediate risk, and low risk classes. Subsequently, at each location, in situ parameters (temperature (°C), pH and EC (μS/cm)) were measured using a portable Multi-parameter TestrTM 35 Series S/N: 1382654. At each well, water samples were collected into clean polyethylene bottles in triplicates for cation, anions and e-coli evaluations, respectively. Water samples for cations were acidified by adding two drops of concentrated nitric acid. All samples were kept in a refrigerator at a low temperature of about 4°C before being taken to the Federal University of Technology, Akure, for analyses. Ion chromatography was employed for the anions analysis while the cations were determined using an Atomic Absorption Spectrophotometer Buck 210 model. Membrane filter technique was employed for the e-coli estimation. From the results of the hydrochemistry, the Nitrate Pollution Index (NPI) and Modified Nitrate Pollution Index (MNPI) were estimated and classified into;clean unpolluted, light pollution, moderate pollution, significant pollution, very significant pollution waters. Sanitary surveys in the two cities showed that in the very low risk, intermediate and high-risk categories, Ado-Ekiti had 33.33%, 56.67% and 10% representations, while Ijero-Ekiti had 50%, 23.33% and 26.67% representations, respectively. This observation showed that Ado-Ekiti with higher population and humans’ activities compared to Ijero-Ekiti was less susceptible to pollution. Urbanization has no direct effects on sanitary surveys. The pH of wells’ water in Ado-Ekiti ranged from 4.8 - 8.2, EC (μS/cm) from 101 - 1008, while at Ijero-Ekiti, the pH and EC (μS/cm) varied from 2.1 - 13.8 and 80 - 1008 respectively. Ado-Ekiti wells’ water was more acidic than that of Ijero-Ekiti. Chemical concentrations (mg/L) of Ca2+, Mg2+, Na+, K+, , and Clˉ of the wells’ water in both cities were within WHO-approved standards for drinking water. However, with average concentrations of 142.17 (mg/L) and 252.71 (mg/L) at Ado-Ekiti and Ijero-Ekiti, respectively, exceeded the standard in many locations. Susceptibility to pollution classification employing TDS, NPI and MNPI showed that Ijero-Ekiti was more susceptible to pollution compared to Ado-Ekiti. This assertion was supported by statistical analysis employing correlation, cluster analysis, and principal component analysis. This study showed that urbanization had no direct effects on sanitary surveys and groundwater quality. Pollution of wells’ water in the two cities was, mainly from anthropogenic activities. However, Ijero-Ekiti, with significant anthropogenic activities, had its wells’ water more susceptible to pollution. Sanitary surveys are a complementary method to water quality monitoring.

Reassessing Groundwater Potentials and Subsurface water Hydrochemistry in a Tropical Anambra Basin, Southeastern Nigeria

This review presented a detailed re-assessment of the hydrogeology and hydrochemistry of the Tropical Anambra Basin.It identified and discussed the major geological formations and their groundwater potentials.The geological examination showed that the Ajali Formation is confined in places forming an artesian condition;the potentials of this aquifer decline in the western basin due to a decrease in thickness.The sandstone associates of the Nsukka Formation are aquiferous and have produced high-pressure artesian boreholes along the Oji River.The Imo Shale is characterized by permeability stability all over much of the intermediate unit.The Bende-Ameki aquifer has a lesser amount of groundwater when equated to other formations;the geologic characteristics do not produce favorable hydrogeological conditions for groundwater occurrence.The stratigraphical and structural framework suggested the presence of an efficient throughflow in the basin.Based on physical and chemical parameters of water quality,the basin holds water of acceptable quality.While there are considerable investigations on the hydrogeology and hydrochemistry,studies are short of analysis of the hydrogeochemical evolution of groundwater,water quality index,heavy metals pollution index as well as total hazard quotient.Suitability of groundwater based on agricultural water quality indices(e.g.SAR)is also salient.Therefore,future studies should address these owing to increasing dependence on groundwater.

Re-examination of Hydrochemistry and Groundwater Potentials of Cross River and Imo-Kwa-Ibo Intersecting Tropical Basins of South-South Nigeria

This review attempted a detailed description of geological and hydrogeological configurations of Cross River and Imo-Akwa Ibo basins.It presented a synthesis of hydrochemistry and a description of the hydrogeological configurations of the two basins.Hydrogeologically,most areas under Cross River and Imo-Kwa-Ibo are poor in terms of groundwater potentials.Based on the hydrochemistry,the basins hold water of excellent quality.Groundwater sources fall in soft to moderately hard classes.The entire sources groundwater has a TDS concentration of less than 500 mg/l.Groundwater classification based on electrical conductivity(EC)showed EC levels were less than 500μS/cm.Most of the examined cations and anions are within WHO reference guidelines for drinking water quality.However,no broad analysis of water quality based on water quality indices.Also,studies modeling pollution or the impact of land use changes on groundwater quality are wanting.Thus,further analysis of the hydrochemistry of groundwater aquifers is recommended.

Hydrochemistry and carbon isotope characteristics of Nujiang River water:Implications for CO_(2) budgets of rock weathering in the Tibetan Plateau

The Tibetan Plateau is one of the most complicated geographical units worldwide in terms of its tectonic and environmental background.Although a hotspot for continental weathering and carbon cycling studies,accurate determination of the weathering carbon budget is challenging in this area,especially sink and source flux quantification and the controlling mechanisms.Compared with other major rivers on the plateau,the Nujiang River is characterized by less human disturbance and maintains a relatively pristine state.This study investigates the high spatiotemporal resolution hydrochemistry and dual-carbon isotope composition(δ~(13)C_(DIC)andΔ~(14)C_(DIC))of river water in the Nujiang River Basin.The results revealed that the solutes and dissolved inorganic carbon in the river water are predominantly derived from rock weathering by carbonic and sulfuric acids,mainly due to the carbonate weathering process,and significantly enhanced by deep carbon sourcing from hot springs in the fault zone.The average contributions of geological and modern carbon in the main stream of the Nujiang River are 35.2%and 64.8%,respectively,and sulfide oxidation contributes>90%of sulfate ions in the river water.After considering the involvement of sulfuric acid generated by sulfide oxidation during rock weathering,the calculated consumption fluxes of atmospheric CO_(2) by silicate and carbonate weathering in the watershed were decreased by approximately 52.0%and 37.4%,respectively,compared with those calculated ignoring this process.Rock weathering of the Nujiang River Basin is a“CO_(2) sink”on a short time scale,while the participation of sulfuric acid makes it a“CO_(2) source”on a geological time scale.The high-frequency observations of ion concentrations,elemental ratios,and calculated contributions of different rock weathering materials indicate that carbonate rock weathering is more sensitive to temperature and runoff variations than silicate rock weathering,with the solute contribution from carbonate weathering increasing significantly during monsoon period.The material input from different rock types is dominated by the hydrological pathways and water-rock reaction times in the basin.This study reveals the river solute origins and weathering CO_(2) sequestration effect in response to a monsoonal climate in one of the most representative pristine plateau watersheds in the world,which is of great importance for elucidating the weathering control mechanisms and CO_(2) net sourcesink effect in plateau watersheds.

Hydrochemical characteristics and the ecological effect of algal carbonic anhydrase in carbon cycle in the Taiyuan section of Fenhe River

Water scarcity and pollution pose a threat to the sustainable development of cities and society.Therefore,it is crucial to analyze the hydrochemical characteristics and carbon dynamics of waterdeficient areas.Taking the Taiyuan section of Fenhe River as the research object,we systematically explored the hydrochemical characteristics of surface water and its evolutionary processes,as well as the ecological effect of algal carbonic anhydrase in carbon cycle using the hydrochemical evolution method and correlation analysis.The ternary diagram demonstrates that the main water chemical type in Fenhe River was SO^(2-)_(4)·Cl^(-)-Na^(+).The Gibbs and end-member diagrams of each ion display that the chemical composition of surface water was mainly controlled by silicate decomposition.The chemical ions originated mainly from dissolution of some minerals,such as plagioclase,halite,dolomite,calcite,and gypsum.The diatoms had a lower CO_(2)requirement because they exhibited a higher abundance at a lower partial pressure of CO_(2)(p CO_(2)).However,high CO_(2)concentration had a positive effect on cyanobacteria,which reduced the active transport of HCO_(3)^(-),saved the energy needed for this part of active transport,and indirectly improved the overall photosynthetic efficiency of algae.Carbonic anhydrase(CA)activity was significantly negatively correlated with p CO_(2)and positively correlated with HCO_(3)^(-)concentration,indicating that CA in water promoted the conversion of CO_(2)to HCO_(3)^(-).The HCO_(3)^(-)generated from this process continued to participate in the erosion of silicate rocks,sequestering CO_(2)in the form of Ca CO_(3),which has a non-negligible impact on the carbon sink in the Fenhe River.These consequences may have important implications for the biogeochemical cycling occurring in urban water.

Geochemical and Isotopic Techniques Constraints on the Origin,Evolution,and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan,SE China

Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt of China,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal resources.This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence time.The results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization levels.The hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m.Molar ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water chemistry.Additionally,geothermal waters experienced varying degrees of mixing with cold water during their ascent.Theδ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic.Theδ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock.Age dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.