Hydrodynamic Cavitation Enhanced SR-Aops Degradation of Organic Pollutants in Water:A Review

SR-AOP(sulfate radical advanced oxidation process)is a novel water treatment method able to eliminate refractory organic pollutants.Hydrodynamic cavitation(HC)is a novel green technology,that can effectively produce strong oxidizing sulfate radicals.This paper presents a comprehensive review of the research advancements in these fields and a critical discussion of the principal factors influencing HC-enhanced SR-AOP and the mechanisms of synergistic degradation.Furthermore,some insights into the industrial application of HC/PS are also provided.Current research shows that this technology is feasible at the laboratory stage,but its application on larger scales requires further understanding and exploration.In this review,some attention is also paid to the design of the hydrodynamic cavitation reactor and the related operating parameters.

Recent Developments in Hydrodynamic Cavitation Reactors:Cavitation Mechanism,Reactor Design,and Applications

Hydrodynamic cavitation is considered to be a promising technology for process intensification,due to its high energy efficiency,cost-effective operation,ability to induce chemical reactions,and scale-up possibilities.In the past decade,advancements have been made in the fundamental understanding of hydrodynamic cavitation and its main variables,which provide a basis for applications of hydrodynamic cavitation in radical-induced chemical reaction processes.Here,we provide an extensive review of these research efforts,including the fundamentals of hydrodynamic cavitation,the design of cavitation reactors,cavitation-induced reaction enhancement,and relevant industrial applications.Two types of hydrodynamic cavitation reactors—namely,stationary and rotational—are compared.The design parameters of a hydrodynamic cavitation reactor and reactor performance at the laboratory and pilot scales are discussed,and recommendations are made regarding optimal operation and geometric conditions.The commercial cavitation reactors that are currently on the market are reviewed here for the first time.The unique features of hydrodynamic cavitation have been widely applied to various chemical reactions,such as oxidization reactions and wastewater treatment,and to physical processes,such as emulsion generation and component extraction.The roles of radicals and gas bubble implosion are also thoroughly discussed.

Hydrodynamic cavitation as an efficient method for the formation of sub-100 nm O/W emulsions with high stability

Hydrodynamic cavitation,a newly developed process intensification technique,has demonstrated immense potential for intensifying diverse physical and chemical processes.In this study,hydrodynamic cavitation was explored as an efficient method for the formation of sub-100 nm oil-in-water(O/W) emulsions with high stability.O/W emulsion with an average droplet size of 27 nm was successfully prepared.The average droplet size of O/W emulsions decreased with the increase of the inlet pressure,number of cavitation passes and surfactant concentration.The formed emulsion exhibited admirable physical stability during 8 months.Moreover,the hydrodynamic cavitation method can be generalized to fabricate large varieties of O/W emulsions,which showed great potential for large-scale formation of O/W emulsions with lower energy consumption.

Upgradation of Heavy Crude Oil Via Hydrodynamic Cavitation Through Variations in Asphaltenes

In this work,Saudi heavy crude oil(SHCO)was upgraded by the hydrodynamic cavitation technique.The collapse of cavitation bubbles instantly produces extreme conditions such as high temperature,pressure,and jet flow and strong shear forces,which can play a significant role in the upgradation process.The results revealed that the viscosity and Conradson carbon residue of SHCO decreased from 13.61 to 7.22 mm^(2)/s and from 7.16%to 6.48%,respectively.True boiling point distillation findings showed that the vacuum residue(VR)decreased by 1%.Atmospheric-pressure photoionization Fourier-transform ion cyclotron resonance mass spectrometry,X-ray diffraction,dynamic light scattering,Fourier-transform infrared spectroscopy,and scanning electron microscopy were employed to characterize the molecular composition,crystalline structure,asphaltene aggregate particle size distribution,functional groups,and morphology,respectively,to understand the effects of hydrodynamic cavitation on asphaltenes.The obtained results demonstrate that hydrodynamic cavitation upgradation reduced the interaction forces between the asphaltene molecules,weakening the crystalline structure of the asphaltene aggregates,reducing the degree of association of the aromatic compounds in SHCO and asphaltenes,and decreasing the average particle size.The delayed coking properties of the VR were further investigated,and the cavitation treatment was found to decrease the coke yield by 1.85%and increase the liquid and gas yields by 1.52%and 0.33%,respectively.Hence,hydrodynamic cavitation can effectively enhance the processing performance of crude oil by improving the properties and structural characteristics of asphaltenes.

Experimental study on the degradation of Rhodamine B by hydrodynamic cavitation technique

Hydrodynamic cavitation is a new technique in wastewater treatment processes. The degradation of Rbodamine B was studied on a 220 liters hydrodynamic cavitation setup using multiple hole orifice plates in this paper. The experimental results showed that Rhodamine B was really decomposed by hydrodynamic cavitation. Some factors influencing degradation effect i.e. geometric parameters and operation conditions also were discussed. It was concluded there was the optimal ratio of total area of holes to crosssectional area of the pipe and the rate constant increased with a reduction in the value of the modified cavitional number.

Pressure characteristics of hydrodynamic cavitation reactor due to the combination of Venturi tubes with multi-orifice plates

The pressure characteristics in the throats of Venturi tube and behind triangular multi-orifice plates were experimentally investigated by a pressure data acquisition system of SINOCERA-YE6263, and the effect of throat length of Venturi tube, different geometric parameters of multi-orifice plate and their combinations on the time-averaged pressure, cavitation number, and pressure frequency spectrum, correlation function calculated by FFT were analyzed. The experimental results showed that the throat length of L/R= 40 made for improving the fluctuation energy and promoting the uniform energy distribution, appropriately decreasing the size and increasing the number of orifice could accelerate the uniform distribution of the fluctuation energy in frequency domain. In the combination reactors, the cavitation number behind multi-orifice plates was lower and the fluctuation of correlation function was more intense.

Intensification of the degradation of Acid RED-18 using hydrodynamic cavitation

In this work degradation of Acid Red-18(AR-18)was examined in the hydrodynamic cavitation reactor.Orifice plates with different holes geometry are used to determine the optimum plate to carry out the degradation based on cavitation number.The obtained optimum orifice plate is used as a cavitating device on varying parameters like initial AR-18 concentrations,pH,temperatures,and operating pressures of the reactor.A photocatalyst(TiO2)was prepared by the sol-gel method and used in combination with H2O2 to intensify the degradation of AR-18.The obtained optimum condition of hydrodynamic cavitation was again used in the ultrasonic cavitation reactor for the comparison.Hydrodynamic cavitation(orifice)given the highest degradation as compared to Hydrodynamic cavitation(Venturi)and Ultrasonic Cavitation with and without the use of TiO2.At TiO2(300 mg/L)dose,88.1%,70.4%and 64.8%degradation is obtained in HC-O,HC-V and UC reactor at initial AR-18 concentration(15 ppm),pH(3),Operating temperature(35C),and H2O2(300 mg/L).Hence the use of an advanced oxidation process can be successfully used with hydrodynamic cavitation to intensify the degradation of Acid Red-18 under the controlled operating parameters.

Optimization of cavitation venturi tube design for pico and nano bubbles generation

Hydrodynamic cavitaion venturi tube technique is used for pico and nano bubble generations in coal column flotation. In order to determine the optimal design of hydrodynamic cavitation venture tube for pico and nano bubble generation, a four-factor three-level Central Composite Design of Experimental was conducted for investigating four important design parameters of cavitation venturi tube governing the median size and the volume of pico and nano bubbles. The test results showed that maximum volume of pico and nano bubbles, 65–75%, and minimum mean pico and nano bubble size,150–240 nm, were achieved at the medium ratio of the diameter of outlet of the venturi-tube and diameter of throat(3–4), medium outlet angle(11–13°), high inlet angle(26–27°) and high ratio of the length of the throat and the diameter of throat(2.3–3). Study the effects of the producing pico and nano bubbles on fine coal flotation was performed in a 5 cm diameter 260 cm height flotation column. The optimal percentage of pico and nano bubbles was about 70%, which produced maximum combustible material recovery of 86% with clean coal ash content of 11.7%.

An experimental study on size distribution and zeta potential of bulk cavitation nanobubbles

Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and stability have a significant impact on the nanobubble flotation performance.In this paper,bulk nanobubbles generated based on the principle of hydrodynamic cavitation were investigated to determine the effects of different parameters(e.g.,surfactant(frother)dosage,air flow,air pressure,liquid flow rate,and solution pH value)on their size distribution and zeta potential,as measured using a nanoparticle analyzer.The results demonstrated that the nanobubble size decreased with increasing pH value,surfactant concentration,and cavitation-tube liquid flow rate but increased with increasing air pressure and increasing air flow rate.The magnitude of the negative surface charge of the nanobubbles was positively correlated with the pH value,and a certain relationship was observed between the zeta potential of the nanobubbles and their size.The structural parameters of the cavitation tube also strongly affected the characteristics of the nanobubbles.The results of this study offer certain guidance for optimizing the nanobubble flotation technology.

The Collapse Intensity of Cavities and the Concentration of Free Hydroxyl Radical Released in Cavitation Flow

Enhancing the chemical reaction processes by means of the energy released in the collapse of micro bubbles or cavities in the cavitation flow is a new research area. In the previous work, a new approach of measuring concentration of free hydroxyl radicals induced in cavitation flow by using methylene blue as the indicator was developed and used to study concentration of free radical induced in Venturi cavitation flow under various experimental conditions. In the present research, the radial evolution of a cavity bubble and the corresponding collapse pressure in sonic cavitation field are obtained by solving three different bubble dynamics equations： Rayleigh equation, Rayleigh-Plesset equation and Gilmore equation. By comparing with the experimental data on the radial evolution of a cavity bubble in the literature, it is found that the predicted results by the Gilmore equation, which takes account of the compressibility of fluid in addition to the viscosity and interfacial tension, agree with the experimental ones better than those by other two equations. Moreover, the theoretically predicted collapse pressures are consistent with the concentration of the free hydroxyl radical induced in the experimental venture. Thus, the concentration of the liberated free hydroxyl radical not only influences the reaction rate but also is used as an available parameter for measuring collapse intensity of cavities.

Dynamics of cavitation–structure interaction

Cavitation–structure interaction has become one of the major issues for most engineering applications. The present work reviews recent progress made toward developing experimental and numerical investigation for unsteady turbulent cavitating flow and cavitation–structure interaction. The goal of our overall efforts is to（1） summarize the progress made in the experimental and numerical modeling and approaches for unsteady cavitating flow and cavitation–structure interaction,（2） discuss the global multiphase structures for different cavitation regimes, with special emphasis on the unsteady development of cloud cavitation and corresponding cavitating flow-induced vibrations,with a high-speed visualization system and a structural vibration measurement system, as well as a simultaneous sampling system,（3） improve the understanding of the hydroelastic response in cavitating flows via combined physical and numerical analysis, with particular emphasis on the interaction between unsteady cavitation development and structural deformations. Issues including unsteady cavitating flow structures and cavitation–structure interaction mechanism are discussed.

Comparison of mechanical and column flotation performances on recovery of phosphate slimes in presence of nano-microbubbles

Fine particle flotation has been one of the main problems in many mineral processing plants.The bubble particle collision rate is very low for fine particles,which reduces flotation efficiency.Also,the existence of slimes is,generally,detrimental to the flotation process,affecting the selectivity and the quality of the concentrates.Besides,it causes an increase in reagents consumption.Hence,in most of processing plants,some of these particles are transmitted to the tailing ponds to reduce the effects of these problems and increase the selectivity of the process.Esfordi phosphate plant in Iran loses more than 30%of its capacity as particles with d 80 finer than 30μm.These fine particles with 15.9%P_(2)O_(5)content are transferred to tailing dam.Processing of fine particles is very important for phosphate industry from economic and environmental aspects.This study addressed the processing of fine tailings(slimes)from a phosphate ore concentrator via flotation,despite the traditional view that ultrafine particles do not float.Phosphate flotation performances in the presence and absence of nanobubbles(NBs)in both mechanical and column cells were compared according to the metallurgical results of the process.NBs(generated by hydrodynamic cavitation)have interesting and exclusive properties such as high stability,durability and high surface area per volume,leading to increase of their utilization in mining-metallurgy and environmental areas.The results of this study revealed that,in the absence of NBs,a concentrate containing 26.9%P_(2)O_(5)with a recovery of 29.13%was obtained using mechanical cells in comparison to 31.6%P_(2)O_(5)with a recovery of 32.74%obtained using column flotation.In the presence of NBs,the recoveries of the concentrate of the mechanical and column flotation increased to 40.49%and 41.26%with 28.47%and 30.43%P_(2)O_(5)contents,respectively.Comparative study showed that the column flotation was almost more efficient for processing the phosphate ore in the presence of the NBs,and had thicker froth layer compared to the mechanical flotation.

Computational study of different venturi and orifice type hydrodynamic cavitating devices

This paper reports optimization of various geometrical parameters of two types of hydrodynamic cavitation reactors （HC） such as venturi type and orifice type. Mostly orifice and venturi nozzles are used as HC reactor, a simple valve can also be used to cause cavitation which depends on geometry and area of opening. Different operating and geometrical parameters such as divergence angle, throat height/diameter to length ratio, number of holes and inlet pressure to the cavitating device were selected to study the inception, growth and dynamics of cavities. In this work, a comprehensive computational fluid dynamics simulation is performed to numerically investigate the 3-D flow behaviors within HC reactors using cavitational model with standard κ - ε Turbulence model. The study of different geometries of venturi type HC reactor （like slit, circular and elliptical） shows that 1：1 of the ratio of throat height/diameter to length and 6.5% of divergence angle is an optimum geometry for best cavitational activity. In case of orifice, 1：3 of the ratio of diameter to length is best for cavitation and an increase in the total flow area increases the cavitational yield.

Dynamic behaviors of cavitation bubble for the steady cavitating flow

In this paper, by introducing the flow velocity item into the classical Rayleigh-Plesset dynamic equation, a newequation, which does not involve the time term and can describe the motion of cavitation bubble in the steadycavitating flow, has been obtained. By solving the new motion equation using Runge-Kutta fourth order methodwith adaptive step size control, the dynamic behaviors of cavitation bubble driven by the varying pressure fielddownstream of a venturi cavitation reactor are numerically simulated. The effects of liquid temperature (correspondingto the saturated vapor pressure of liquid), cavitation number and inlet pressure of venturi on radial motionof bubble and pressure pulse due to the radial motion are analyzed and discussed in detail. Some dynamicbehaviors of bubble different from those in previous papers are displayed. In addition, the internal relationshipbetween bubble dynamics and process intensification is also discussed. The simulation results reported in thiswork reveal the variation laws of cavitation intensity with the flow conditions of liquid, and will lay a foundationfor the practical application of hydrodynamic cavitation technology.

An experimental investigation of transient cavitation control on a hydrofoil using hemispherical vortex generators

Unsteady cavitation causes noise,damage,and performance decline in the marine engineering and fluid machinery systems.Therefore,finding a method to control the cavitation and its destructive effects is important for the industrial applications.In this work,we proposed a passive method to control the unsteady behavior of transient cavitation at the medium Reynolds number.For this aim,we performed an experimental study using a high-speed camera to analyze the effects of hemispherical vortex generators(VGs)on the cavitation dynamics around a hydrofoil surface.In addition,the pressure pulsations induced by the collapse of the cavity structures in the wake region of the hydrofoil were captured with a pressure transducer mounted on the wall downstream of the hydrofoil.The results showed that the instability behaviors of the cavity structures on the hydrofoil were mitigated using the proposed cavitation passive control method.In addition,the pressure pulsations in the wake region of the hydrofoil were reduced significantly.It can be concluded that the suppression of cavitation instabilities can improve the operating life and reliability of the marine and hydraulic systems.