In this paper, we intend to consider a kind of nonlinear Klein-Gordon equation coupled with Born-Infeld theory. By using critical point theory and the method of Nehari manifold, we obtain two existing results of infin...In this paper, we intend to consider a kind of nonlinear Klein-Gordon equation coupled with Born-Infeld theory. By using critical point theory and the method of Nehari manifold, we obtain two existing results of infinitely many high-energy radial solutions and a ground-state solution for this kind of system, which improve and generalize some related results in the literature.展开更多
This article presents the construction of a nonlocal Hirota equation with variable coefficients and its Darboux transformation.Using zero-seed solutions,1-soliton and 2-soliton solutions of the equation are constructe...This article presents the construction of a nonlocal Hirota equation with variable coefficients and its Darboux transformation.Using zero-seed solutions,1-soliton and 2-soliton solutions of the equation are constructed through the Darboux transformation,along with the expression for N-soliton solutions.Influence of coefficients that are taken as a function of time instead of a constant,i.e.,coefficient functionδ(t),on the solutions is investigated by choosing the coefficient functionδ(t),and the dynamics of the solutions are analyzed.This article utilizes the Lax pair to construct infinite conservation laws and extends it to nonlocal equations.The study of infinite conservation laws for nonlocal equations holds significant implications for the integrability of nonlocal equations.展开更多
In this paper,by an approximating argument,we obtain two disjoint and infinite sets of solutions for the following elliptic equation with critical Hardy-Sobolev exponents■whereΩis a smooth bounded domain in RN with ...In this paper,by an approximating argument,we obtain two disjoint and infinite sets of solutions for the following elliptic equation with critical Hardy-Sobolev exponents■whereΩis a smooth bounded domain in RN with 0∈?Ωand all the principle curvatures of?Ωat 0 are negative,a∈C1(Ω,R*+),μ>0,0<s<2,1<q<2 and N>2(q+1)/(q-1).By2*:=2N/(N-2)and 2*(s):(2(N-s))/(N-2)we denote the critical Sobolev exponent and Hardy-Sobolev exponent,respectively.展开更多
The paper discusses the statistical inference problem of the compound Poisson vector process(CPVP)in the domain of attraction of normal law but with infinite covariance matrix.The empirical likelihood(EL)method to con...The paper discusses the statistical inference problem of the compound Poisson vector process(CPVP)in the domain of attraction of normal law but with infinite covariance matrix.The empirical likelihood(EL)method to construct confidence regions for the mean vector has been proposed.It is a generalization from the finite second-order moments to the infinite second-order moments in the domain of attraction of normal law.The log-empirical likelihood ratio statistic for the average number of the CPVP converges to F distribution in distribution when the population is in the domain of attraction of normal law but has infinite covariance matrix.Some simulation results are proposed to illustrate the method of the paper.展开更多
In this paper, we study the relationship between the convergence of the sinusoidal series and the infinity integrals (any real number α ∈[0,1], parameter p > 0). First of all, we study the convergence of the seri...In this paper, we study the relationship between the convergence of the sinusoidal series and the infinity integrals (any real number α ∈[0,1], parameter p > 0). First of all, we study the convergence of the series (any real number α ∈[0,1], parameter p > 0), mainly using the estimation property of the order to obtain that the series diverges when 0 p ≤1-α, the series converges conditionally when 1-α p ≤1, and the series converges absolutely when p >1. In the next part, we study the convergence state of the infinite integral (any real number α ∈[0,1], parameter p > 0), and get that when 0 p ≤1-α, the infinite integral diverges;when 1-α p ≤1, the infinite integral conditionally converges;when p >1, the infinite integral absolutely converges. Comparison of the conclusions of the above theorem, it is not difficult to derive the theorem: the level of and the infinity integral with the convergence of the state (any real number α ∈[0,1], the parameter p >0), thus promoting the textbook of the two with the convergence of the state requires the function of the general term or the product of the function must be monotonically decreasing conditions.展开更多
In this paper, we study the fifth-order Camassa-Holm equation with weakly dissipative term. We first give the local well-posedness result and the blow up criterion. Then, we establish sufficient conditions to guarante...In this paper, we study the fifth-order Camassa-Holm equation with weakly dissipative term. We first give the local well-posedness result and the blow up criterion. Then, we establish sufficient conditions to guarantee that the solution exists globally in time. Finally, the infinite propagation speed of this equation is also investigated.展开更多
A novel ellipsoidal acoustic infinite element is proposed. It is based a new pressure representation, which can describe and solve the ellipsoidal acoustic field more exactly. The shape functions of this novel acousti...A novel ellipsoidal acoustic infinite element is proposed. It is based a new pressure representation, which can describe and solve the ellipsoidal acoustic field more exactly. The shape functions of this novel acoustic infinite element are similar to the (Burnett's) method, while the weight functions are defined as the product of the complex conjugates of the shaped functions and an additional weighting factor. The code of this method is cheap to generate as for 1-D element because only 1-D integral needs to be numerical. Coupling with the standard finite element, this method provides a capability for very efficiently modeling acoustic fields surrounding structures of virtually any practical shape. This novel method was deduced in brief and the conclusion was kept in detail. To test the feasibility of this novel method efficiently,in the examples the infinite elements were considered,excluding the finite elements relative. This novel ellipsoidal acoustic infinite element can deduce the analytic solution of an oscillating sphere. The example of a prolate spheroid shows that the novel infinite element is superior to the boundary element and other acoustic infinite elements. Analytical and numerical results of these examples show that this novel method is feasible.展开更多
It is not convenient to solve those engineering problems defined in an infinite field by using FEM. An infinite area can be divided into a regular infinite external area and a finite internal area. The finite internal...It is not convenient to solve those engineering problems defined in an infinite field by using FEM. An infinite area can be divided into a regular infinite external area and a finite internal area. The finite internal area was dealt with by the FEM and the regular infinite external area was settled in a polar coordinate. All governing equations were transformed into the Hamiltonian system. The methods of variable separation and eigenfunction expansion were used to derive the stiffness matrix of a new infinite analytical element.This new element, like a super finite element, can be combined with commonly used finite elements. The proposed method was verified by numerical case studies. The results show that the preparation work is very simple, the infinite analytical element has a high precision, and it can be used conveniently. The method can also be easily extended to a three-dimensional problem.展开更多
This paper examines the existence of general equilibrium in a discrete time economy with the infinite horizon incomplete markets.There is a single good at each node in the event tree.The existence of general equilibri...This paper examines the existence of general equilibrium in a discrete time economy with the infinite horizon incomplete markets.There is a single good at each node in the event tree.The existence of general equilibrium for the infinite horizon economy is proved by taking limit of equilibria in truncated economies in which trade stops at a sequence of dates.展开更多
It is given in Weil and Rosenlicht ([1], p. 15) that (resp. 2) for all non-negative integers m and n with m≠n if c is any even (resp. odd) integer. In the present paper we generalize this. Our purpose is to give othe...It is given in Weil and Rosenlicht ([1], p. 15) that (resp. 2) for all non-negative integers m and n with m≠n if c is any even (resp. odd) integer. In the present paper we generalize this. Our purpose is to give other integral sequences such that G.C.D.(ym,yn)=1 for all positive integers m and n with m≠n. Roughly speaking we show the following 1) and 2). 1) There are infinitely many polynomial sequences such that G.C.D.(fm(a),fn(a))=1 for all positive integers m and n with with m≠n and infinitely many rational?integers a. 2) There are polynomial sequences such that G.C.D.(gm(a,b),gn(a,b))=1 for all positive integers m and n with m≠n and arbitrary (rational or odd) integers a and b with G.C.D.(a,b)=1. Main results of the present paper are Theorems 1 and 2, and Corollaries 3, 4 and 5.展开更多
In this paper we deal with the existence of infinitely many critical points of the even functional I(u)=integral from n=Q to (F(x,u,Du))+integral from n=(?)Q to (G(x,u)), u∈W^(1,p)(Ω),where G(x, u)=integral from n=o...In this paper we deal with the existence of infinitely many critical points of the even functional I(u)=integral from n=Q to (F(x,u,Du))+integral from n=(?)Q to (G(x,u)), u∈W^(1,p)(Ω),where G(x, u)=integral from n=o to u (g(x,t)dt), under the weak structure conditions on F(x, u, q) by the Mountain Pass Lemma.展开更多
For the off-diagonal infinite dimensional Hamiltonian operators, which have at most countable eigenvalues, a necessary and sufficient condition of the eigenfunction systems to be complete in the sense of Cauchy princi...For the off-diagonal infinite dimensional Hamiltonian operators, which have at most countable eigenvalues, a necessary and sufficient condition of the eigenfunction systems to be complete in the sense of Cauchy principal value is presented by using the spectral symmetry and new orthogonal relationship of the operators. Moreover, the above result is extended to a more general case. At last, the completeness of eigenfunction systems for the operators arising from the isotropic plane magnetoelectroelastic solids is described to illustrate the effectiveness of the criterion. The whole results offer theoretical guarantee for separation of variables in Hamiltonian system for some mechanics equations.展开更多
The 2.5D finite/infinite element approach is adopted to study wave propagation problems caused by underground moving trains. The irregularities of the near field, including the tunnel structure and parts of the soil, ...The 2.5D finite/infinite element approach is adopted to study wave propagation problems caused by underground moving trains. The irregularities of the near field, including the tunnel structure and parts of the soil, are modeled by the finite elements, and the wave propagation properties of the far field extending to infinity are modeled by the infinite elements. One particular feature of the 2.5D approach is that it enables the computation of the three-dimensional response of the half-space, taking into account the load-moving effect, using only a two-dimensional profile. Although the 2.5D finite/infinite element approach shows a great advantage in studying the wave propagation caused by moving trains, attention should be given to the calculation aspects, such as the rules for mesh establishment, in order to avoid producing inaccurate or erroneous results. In this paper, some essential points for consideration in analysis are highlighted, along with techniques to enhance the speed of the calculations. All these observations should prove useful in making the 2.5D finite/infinite element approach an effective one.展开更多
On the basis of the one-dimension infinite element theory, the coordinate translation and shape function of 3D point-radiate 8-node and 4-node infinite elements are derived. They are coupled with 20-node and 8-node fi...On the basis of the one-dimension infinite element theory, the coordinate translation and shape function of 3D point-radiate 8-node and 4-node infinite elements are derived. They are coupled with 20-node and 8-node finite elements to compute the compression distortion of the prestressed anchorage segment. The results indicate that when the prestressed force acts on the anchorage head and segment, the stresses and the displacements in the rock around the anchorage head and segment concentrate on the zone center with the anchor axis, and they decrease with exponential forms. Therefore,the stresses and the displacement spindles are formed. The calculating results of the infinite element are close to the theoretical results. This indicates the method is right. This article introduces a new way to study the mechanism of prestressed anchors. The obtained results have an important role in the research of the anchor mechanism and engineering application.展开更多
The existence of high energy periodic solutions for the second-order Hamiltonian system -ü(t)+A(t)u(t)=▽F(t,u(t)) with convex and concave nonlinearities is studied, where F(t, u) = F1(t,u)+F2(t,...The existence of high energy periodic solutions for the second-order Hamiltonian system -ü(t)+A(t)u(t)=▽F(t,u(t)) with convex and concave nonlinearities is studied, where F(t, u) = F1(t,u)+F2(t,u). Under the condition that F is an even functional, infinitely many solutions for it are obtained by the variant fountain theorem. The result is a complement for some known ones in the critical point theory.展开更多
The infinite diluted activity coefficients of solvents in polyisopropyl methylacrylate was measured using inverse gas chromatography. The solvents used were benzene, toluene, ethyl benzene, methyl acetate, ethyl aceta...The infinite diluted activity coefficients of solvents in polyisopropyl methylacrylate was measured using inverse gas chromatography. The solvents used were benzene, toluene, ethyl benzene, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, methanol, ethanol isopropyl alcohol, butyl alcohol, 1,2-dichloroethane, and chloroform. It was observed that the infinite diluted activity coefficient of alcohols are well above those of the other solvents investigated.展开更多
A new dinuclear Y(3+) coordination polymer{[Y2(H2O)2(C(14)H8O4)3(C(12)H8N2)2]·3 H2O}n (1, C(14)H8 O4 = 2,2'-biphenyldicarboxylate, phen = 1,10-phenanthroline), has been obtained by means of a mi...A new dinuclear Y(3+) coordination polymer{[Y2(H2O)2(C(14)H8O4)3(C(12)H8N2)2]·3 H2O}n (1, C(14)H8 O4 = 2,2'-biphenyldicarboxylate, phen = 1,10-phenanthroline), has been obtained by means of a mixed-solvothermal method using ethylene glycol and water as solvent. The compound was characterized by elemental analysis, energy-dispersive X-ray spectroscopy(EDS), IR spectrum and single-crystal X-ray diffraction. The results reveal that 1 belongs to monoclinic system, space group C2/c with a = 24.249(3), b = 12.069(48), c = 22.7304(08) A, β = 113.480(7)°, Z = 4, V = 6102(2) A3, Dc = 1.462 g·cm^-3, F(000) = 2728, μ = 1.968 mm(-1), the final R = 0.0673, w R = 0.1508 and S = 1.085. Its structure can be regarded as a 1-D coordination polymer constructed by Y^3+ cations, 2,2A-biphenyldicarboxylate, 1,10-phenanthroline and water molecules. The compound not only contains two kinds of organic ligands, but also exhibits interesting wave-like infinite chains and 18-MR windows with the diameter of 4.070(7)A × 5.326(9)A. The structure is further stabilized by means of O–H…O hydrogen bonds and π-π stacking interactions. Furthermore, the luminescent properties(including emission spectrum, CIE chromaticity coordinate and decay curve) of 1 were also investigated in the solid-state at room temperature.展开更多
The recent observation of superconductivity in thin films of infinite-layer nickelate Nd_(0.8)Sr_(0.2)NiO_(2) has received considerable attention.Despite the many efforts to understand the superconductivity in infinit...The recent observation of superconductivity in thin films of infinite-layer nickelate Nd_(0.8)Sr_(0.2)NiO_(2) has received considerable attention.Despite the many efforts to understand the superconductivity in infinite-layer nickelates,a consensus on the underlying mechanism for the superconductivity has yet to be reached,partly owing to the challenges with the material synthesis.Here,we report the successful growth of superconducting infinite-layer Nd_(0.8)Sr_(0.2)NiO_(2) films by pulsed laser deposition and soft chemical reduction.The details on the growth process are discussed.展开更多
文摘In this paper, we intend to consider a kind of nonlinear Klein-Gordon equation coupled with Born-Infeld theory. By using critical point theory and the method of Nehari manifold, we obtain two existing results of infinitely many high-energy radial solutions and a ground-state solution for this kind of system, which improve and generalize some related results in the literature.
基金supported by the National Natural Science Foundation of China (Grant No.11505090)Liaocheng University Level Science and Technology Research Fund (Grant No.318012018)+2 种基金Discipline with Strong Characteristics of Liaocheng University–Intelligent Science and Technology (Grant No.319462208)Research Award Foundation for Outstanding Young Scientists of Shandong Province (Grant No.BS2015SF009)the Doctoral Foundation of Liaocheng University (Grant No.318051413)。
文摘This article presents the construction of a nonlocal Hirota equation with variable coefficients and its Darboux transformation.Using zero-seed solutions,1-soliton and 2-soliton solutions of the equation are constructed through the Darboux transformation,along with the expression for N-soliton solutions.Influence of coefficients that are taken as a function of time instead of a constant,i.e.,coefficient functionδ(t),on the solutions is investigated by choosing the coefficient functionδ(t),and the dynamics of the solutions are analyzed.This article utilizes the Lax pair to construct infinite conservation laws and extends it to nonlocal equations.The study of infinite conservation laws for nonlocal equations holds significant implications for the integrability of nonlocal equations.
文摘In this paper,by an approximating argument,we obtain two disjoint and infinite sets of solutions for the following elliptic equation with critical Hardy-Sobolev exponents■whereΩis a smooth bounded domain in RN with 0∈?Ωand all the principle curvatures of?Ωat 0 are negative,a∈C1(Ω,R*+),μ>0,0<s<2,1<q<2 and N>2(q+1)/(q-1).By2*:=2N/(N-2)and 2*(s):(2(N-s))/(N-2)we denote the critical Sobolev exponent and Hardy-Sobolev exponent,respectively.
基金Characteristic Innovation Projects of Ordinary Universities of Guangdong Province,China(No.2022KTSCX150)Zhaoqing Education Development Institute Project,China(No.ZQJYY2021144)Zhaoqing College Quality Project and Teaching Reform Project,China(Nos.zlgc202003 and zlgc202112)。
文摘The paper discusses the statistical inference problem of the compound Poisson vector process(CPVP)in the domain of attraction of normal law but with infinite covariance matrix.The empirical likelihood(EL)method to construct confidence regions for the mean vector has been proposed.It is a generalization from the finite second-order moments to the infinite second-order moments in the domain of attraction of normal law.The log-empirical likelihood ratio statistic for the average number of the CPVP converges to F distribution in distribution when the population is in the domain of attraction of normal law but has infinite covariance matrix.Some simulation results are proposed to illustrate the method of the paper.
文摘In this paper, we study the relationship between the convergence of the sinusoidal series and the infinity integrals (any real number α ∈[0,1], parameter p > 0). First of all, we study the convergence of the series (any real number α ∈[0,1], parameter p > 0), mainly using the estimation property of the order to obtain that the series diverges when 0 p ≤1-α, the series converges conditionally when 1-α p ≤1, and the series converges absolutely when p >1. In the next part, we study the convergence state of the infinite integral (any real number α ∈[0,1], parameter p > 0), and get that when 0 p ≤1-α, the infinite integral diverges;when 1-α p ≤1, the infinite integral conditionally converges;when p >1, the infinite integral absolutely converges. Comparison of the conclusions of the above theorem, it is not difficult to derive the theorem: the level of and the infinity integral with the convergence of the state (any real number α ∈[0,1], the parameter p >0), thus promoting the textbook of the two with the convergence of the state requires the function of the general term or the product of the function must be monotonically decreasing conditions.
文摘In this paper, we study the fifth-order Camassa-Holm equation with weakly dissipative term. We first give the local well-posedness result and the blow up criterion. Then, we establish sufficient conditions to guarantee that the solution exists globally in time. Finally, the infinite propagation speed of this equation is also investigated.
文摘A novel ellipsoidal acoustic infinite element is proposed. It is based a new pressure representation, which can describe and solve the ellipsoidal acoustic field more exactly. The shape functions of this novel acoustic infinite element are similar to the (Burnett's) method, while the weight functions are defined as the product of the complex conjugates of the shaped functions and an additional weighting factor. The code of this method is cheap to generate as for 1-D element because only 1-D integral needs to be numerical. Coupling with the standard finite element, this method provides a capability for very efficiently modeling acoustic fields surrounding structures of virtually any practical shape. This novel method was deduced in brief and the conclusion was kept in detail. To test the feasibility of this novel method efficiently,in the examples the infinite elements were considered,excluding the finite elements relative. This novel ellipsoidal acoustic infinite element can deduce the analytic solution of an oscillating sphere. The example of a prolate spheroid shows that the novel infinite element is superior to the boundary element and other acoustic infinite elements. Analytical and numerical results of these examples show that this novel method is feasible.
文摘It is not convenient to solve those engineering problems defined in an infinite field by using FEM. An infinite area can be divided into a regular infinite external area and a finite internal area. The finite internal area was dealt with by the FEM and the regular infinite external area was settled in a polar coordinate. All governing equations were transformed into the Hamiltonian system. The methods of variable separation and eigenfunction expansion were used to derive the stiffness matrix of a new infinite analytical element.This new element, like a super finite element, can be combined with commonly used finite elements. The proposed method was verified by numerical case studies. The results show that the preparation work is very simple, the infinite analytical element has a high precision, and it can be used conveniently. The method can also be easily extended to a three-dimensional problem.
基金This research was supported by a project of Financial MathematicsFinancial Engineering and Finan-cial Managementwhich is o
文摘This paper examines the existence of general equilibrium in a discrete time economy with the infinite horizon incomplete markets.There is a single good at each node in the event tree.The existence of general equilibrium for the infinite horizon economy is proved by taking limit of equilibria in truncated economies in which trade stops at a sequence of dates.
文摘It is given in Weil and Rosenlicht ([1], p. 15) that (resp. 2) for all non-negative integers m and n with m≠n if c is any even (resp. odd) integer. In the present paper we generalize this. Our purpose is to give other integral sequences such that G.C.D.(ym,yn)=1 for all positive integers m and n with m≠n. Roughly speaking we show the following 1) and 2). 1) There are infinitely many polynomial sequences such that G.C.D.(fm(a),fn(a))=1 for all positive integers m and n with with m≠n and infinitely many rational?integers a. 2) There are polynomial sequences such that G.C.D.(gm(a,b),gn(a,b))=1 for all positive integers m and n with m≠n and arbitrary (rational or odd) integers a and b with G.C.D.(a,b)=1. Main results of the present paper are Theorems 1 and 2, and Corollaries 3, 4 and 5.
文摘In this paper we deal with the existence of infinitely many critical points of the even functional I(u)=integral from n=Q to (F(x,u,Du))+integral from n=(?)Q to (G(x,u)), u∈W^(1,p)(Ω),where G(x, u)=integral from n=o to u (g(x,t)dt), under the weak structure conditions on F(x, u, q) by the Mountain Pass Lemma.
基金Supported by the National Natural Science Foundation of China under Grant No. 10962004the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No. 20070126002+1 种基金the Natural Science Foundation of Inner Mongolia under Grant No. 20080404MS0104the Research Foundation for Talented Scholars of Inner Mongolia University under Grant No. 207066
文摘For the off-diagonal infinite dimensional Hamiltonian operators, which have at most countable eigenvalues, a necessary and sufficient condition of the eigenfunction systems to be complete in the sense of Cauchy principal value is presented by using the spectral symmetry and new orthogonal relationship of the operators. Moreover, the above result is extended to a more general case. At last, the completeness of eigenfunction systems for the operators arising from the isotropic plane magnetoelectroelastic solids is described to illustrate the effectiveness of the criterion. The whole results offer theoretical guarantee for separation of variables in Hamiltonian system for some mechanics equations.
基金Science Council Under Grant No.NSC 89-2211-E-002-020
文摘The 2.5D finite/infinite element approach is adopted to study wave propagation problems caused by underground moving trains. The irregularities of the near field, including the tunnel structure and parts of the soil, are modeled by the finite elements, and the wave propagation properties of the far field extending to infinity are modeled by the infinite elements. One particular feature of the 2.5D approach is that it enables the computation of the three-dimensional response of the half-space, taking into account the load-moving effect, using only a two-dimensional profile. Although the 2.5D finite/infinite element approach shows a great advantage in studying the wave propagation caused by moving trains, attention should be given to the calculation aspects, such as the rules for mesh establishment, in order to avoid producing inaccurate or erroneous results. In this paper, some essential points for consideration in analysis are highlighted, along with techniques to enhance the speed of the calculations. All these observations should prove useful in making the 2.5D finite/infinite element approach an effective one.
文摘On the basis of the one-dimension infinite element theory, the coordinate translation and shape function of 3D point-radiate 8-node and 4-node infinite elements are derived. They are coupled with 20-node and 8-node finite elements to compute the compression distortion of the prestressed anchorage segment. The results indicate that when the prestressed force acts on the anchorage head and segment, the stresses and the displacements in the rock around the anchorage head and segment concentrate on the zone center with the anchor axis, and they decrease with exponential forms. Therefore,the stresses and the displacement spindles are formed. The calculating results of the infinite element are close to the theoretical results. This indicates the method is right. This article introduces a new way to study the mechanism of prestressed anchors. The obtained results have an important role in the research of the anchor mechanism and engineering application.
文摘The existence of high energy periodic solutions for the second-order Hamiltonian system -ü(t)+A(t)u(t)=▽F(t,u(t)) with convex and concave nonlinearities is studied, where F(t, u) = F1(t,u)+F2(t,u). Under the condition that F is an even functional, infinitely many solutions for it are obtained by the variant fountain theorem. The result is a complement for some known ones in the critical point theory.
基金Supported by the National Natural Science Foundation of China(No.29736170,No.29976011)
文摘The infinite diluted activity coefficients of solvents in polyisopropyl methylacrylate was measured using inverse gas chromatography. The solvents used were benzene, toluene, ethyl benzene, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, methanol, ethanol isopropyl alcohol, butyl alcohol, 1,2-dichloroethane, and chloroform. It was observed that the infinite diluted activity coefficient of alcohols are well above those of the other solvents investigated.
基金supported by the National Natural Science Foundation of China(No.21601095)the Youth Project of Nanyang Normal University(No.QN2017065)the Opening Laboratory Project of Nanyang Normal University(No.SYKF2016075)
文摘A new dinuclear Y(3+) coordination polymer{[Y2(H2O)2(C(14)H8O4)3(C(12)H8N2)2]·3 H2O}n (1, C(14)H8 O4 = 2,2'-biphenyldicarboxylate, phen = 1,10-phenanthroline), has been obtained by means of a mixed-solvothermal method using ethylene glycol and water as solvent. The compound was characterized by elemental analysis, energy-dispersive X-ray spectroscopy(EDS), IR spectrum and single-crystal X-ray diffraction. The results reveal that 1 belongs to monoclinic system, space group C2/c with a = 24.249(3), b = 12.069(48), c = 22.7304(08) A, β = 113.480(7)°, Z = 4, V = 6102(2) A3, Dc = 1.462 g·cm^-3, F(000) = 2728, μ = 1.968 mm(-1), the final R = 0.0673, w R = 0.1508 and S = 1.085. Its structure can be regarded as a 1-D coordination polymer constructed by Y^3+ cations, 2,2A-biphenyldicarboxylate, 1,10-phenanthroline and water molecules. The compound not only contains two kinds of organic ligands, but also exhibits interesting wave-like infinite chains and 18-MR windows with the diameter of 4.070(7)A × 5.326(9)A. The structure is further stabilized by means of O–H…O hydrogen bonds and π-π stacking interactions. Furthermore, the luminescent properties(including emission spectrum, CIE chromaticity coordinate and decay curve) of 1 were also investigated in the solid-state at room temperature.
基金Supported in part by the National Natural Science Foundation of China(Grant Nos.12074411 and 11888101)the National Key Research and Development Program of China(Grant Nos.2016YFA0300300 and 2017YFA0302900)+1 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB25000000)the Research Program of Beijing Academy of Quantum Information Sciences(Grant No.Y18G06).
文摘The recent observation of superconductivity in thin films of infinite-layer nickelate Nd_(0.8)Sr_(0.2)NiO_(2) has received considerable attention.Despite the many efforts to understand the superconductivity in infinite-layer nickelates,a consensus on the underlying mechanism for the superconductivity has yet to be reached,partly owing to the challenges with the material synthesis.Here,we report the successful growth of superconducting infinite-layer Nd_(0.8)Sr_(0.2)NiO_(2) films by pulsed laser deposition and soft chemical reduction.The details on the growth process are discussed.