Achieving flexible electronics with comfort and durability comparable to traditional textiles is one of the ultimate pursuits of smart wearables.Ink printing is desirable for e-textile development using a simple and i...Achieving flexible electronics with comfort and durability comparable to traditional textiles is one of the ultimate pursuits of smart wearables.Ink printing is desirable for e-textile development using a simple and inexpensive process.However,fabricating high-performance atop textiles with good dispersity,stability,biocompatibility,and wearability for high-resolution,large-scale manufacturing,and practical applications has remained challenging.Here,waterbased multi-walled carbon nanotubes(MWCNTs)-decorated liquid metal(LM)inks are proposed with carbonaceous gallium–indium micro-nanostructure.With the assistance of biopolymers,the sodium alginate-encapsulated LM droplets contain high carboxyl groups which non-covalently crosslink with silk sericin-mediated MWCNTs.E-textile can be prepared subsequently via printing technique and natural waterproof triboelectric coating,enabling good flexibility,hydrophilicity,breathability,wearability,biocompatibility,conductivity,stability,and excellent versatility,without any artificial chemicals.The obtained e-textile can be used in various applications with designable patterns and circuits.Multi-sensing applications of recognizing complex human motions,breathing,phonation,and pressure distribution are demonstrated with repeatable and reliable signals.Self-powered and energy-harvesting capabilities are also presented by driving electronic devices and lighting LEDs.As proof of concept,this work provides new opportunities in a scalable and sustainable way to develop novel wearable electronics and smart clothing for future commercial applications.展开更多
As a natural organic polymer,xanthan gum(XG)can alleviate the plastic deformation of gel ink under strong stress and realize the reasonable regulation of the rheological properties of gel ink.However,as the double-hel...As a natural organic polymer,xanthan gum(XG)can alleviate the plastic deformation of gel ink under strong stress and realize the reasonable regulation of the rheological properties of gel ink.However,as the double-helix structure connected by hydrogen bonds cannot resist the mechanical environment of strong stress,XG shows poor shear resistance.In this study,a polymer gel with interpenetrating polymer network structure was prepared by esterifying XG,taking polystyrene maleic anhydride(SMA)as the modifier.In addition to retaining the excellent rheological properties of XG,the generated polymer gel also exhibited high shear resistance.The optimal addition amount of the esterification reaction modifier was determined as mXG:mSMA=5:3 according to the gel ink standard.With this amount,the viscosity of the modified xanthan gum(SXG)gel increased to 1578.8 mPa·s and 100.7 mPa·s at shear rates of 4 s1 and 383 s1,respectively,and the shear resistance increased more than 2 times compared to the unmodified one.It is because of the ester bond formed by esterification that the reaction strengthens the interaction between molecular segments,enabling the new gel to resist to strong mechanical stress.The new polymer gel studied in this paper and the proposed mechanism of action provide new insights for the development of high-end gel ink and also provide theoretical support for the study of rheological properties of non-Newtonian fluids.展开更多
Ceramics with proper pore sizes and geometry are critical to many applications,so that lots of efforts have been made to achieve the goal.Direct ink writing(DIW),an additive manufacturing technique,is cost-effective a...Ceramics with proper pore sizes and geometry are critical to many applications,so that lots of efforts have been made to achieve the goal.Direct ink writing(DIW),an additive manufacturing technique,is cost-effective and accessible.It is interesting to study the ability to control the pore size and geometry by the DIW technique.In this study,alumina ceramics were prepared with special focus on the pore configuration and the performance of printed samples was tested.The porous structures with different pore sizes(minimum pore size of 200μm)and different shapes(honeycomb,lattice and triangle)were printed.The printed structures shrunk uniformly and maintained the original geometry after firing,they did not show any visible defects or deformations,and the microstructure was uniform and dense.It was found the honeycomb structures exhibited superior mechanical strength at the same porosity compared to lattice and triangle structures,which reached 55 MPa with a porosity of 70%.The high strength with the high porosity was attributed to the highly controlled microstructure,i.e.,uniform pore sizes,pore shapes and interconnectivity.展开更多
In order to research how the size of the ink flow channel is affected by the interaction of adjacent ink areas,according to the method of fluid-solid interaction,this paper analyzes the size of the ink flow channel of...In order to research how the size of the ink flow channel is affected by the interaction of adjacent ink areas,according to the method of fluid-solid interaction,this paper analyzes the size of the ink flow channel of two ink rollers' rotation.Firstly,this paper simulates the situation of only one ink area.Secondly,this paper simulates the situation of five adjacent ink areas.Then,through comparing the simulation results of two above situations,it' s obvious that the interaction of adjacent ink areas has big effects on the ink pressure and the size of ink flow channel.At last,this paper gets the main factor that affects the size of ink flow channel in the different situations.展开更多
基金funded by The Hong Kong Polytechnic University(Project No.1-WZ1Y,1-YXAK,1-W21C).
文摘Achieving flexible electronics with comfort and durability comparable to traditional textiles is one of the ultimate pursuits of smart wearables.Ink printing is desirable for e-textile development using a simple and inexpensive process.However,fabricating high-performance atop textiles with good dispersity,stability,biocompatibility,and wearability for high-resolution,large-scale manufacturing,and practical applications has remained challenging.Here,waterbased multi-walled carbon nanotubes(MWCNTs)-decorated liquid metal(LM)inks are proposed with carbonaceous gallium–indium micro-nanostructure.With the assistance of biopolymers,the sodium alginate-encapsulated LM droplets contain high carboxyl groups which non-covalently crosslink with silk sericin-mediated MWCNTs.E-textile can be prepared subsequently via printing technique and natural waterproof triboelectric coating,enabling good flexibility,hydrophilicity,breathability,wearability,biocompatibility,conductivity,stability,and excellent versatility,without any artificial chemicals.The obtained e-textile can be used in various applications with designable patterns and circuits.Multi-sensing applications of recognizing complex human motions,breathing,phonation,and pressure distribution are demonstrated with repeatable and reliable signals.Self-powered and energy-harvesting capabilities are also presented by driving electronic devices and lighting LEDs.As proof of concept,this work provides new opportunities in a scalable and sustainable way to develop novel wearable electronics and smart clothing for future commercial applications.
基金supported by Shanxi Provincial Science and Technology Achievement Transformation Guidance Special Program of China(202104021301052)Shanxi Provincial Patent Transformation Special Plan Project(202202054,202306013).
文摘As a natural organic polymer,xanthan gum(XG)can alleviate the plastic deformation of gel ink under strong stress and realize the reasonable regulation of the rheological properties of gel ink.However,as the double-helix structure connected by hydrogen bonds cannot resist the mechanical environment of strong stress,XG shows poor shear resistance.In this study,a polymer gel with interpenetrating polymer network structure was prepared by esterifying XG,taking polystyrene maleic anhydride(SMA)as the modifier.In addition to retaining the excellent rheological properties of XG,the generated polymer gel also exhibited high shear resistance.The optimal addition amount of the esterification reaction modifier was determined as mXG:mSMA=5:3 according to the gel ink standard.With this amount,the viscosity of the modified xanthan gum(SXG)gel increased to 1578.8 mPa·s and 100.7 mPa·s at shear rates of 4 s1 and 383 s1,respectively,and the shear resistance increased more than 2 times compared to the unmodified one.It is because of the ester bond formed by esterification that the reaction strengthens the interaction between molecular segments,enabling the new gel to resist to strong mechanical stress.The new polymer gel studied in this paper and the proposed mechanism of action provide new insights for the development of high-end gel ink and also provide theoretical support for the study of rheological properties of non-Newtonian fluids.
基金financial support from the Scientific and Technological Key Project of Henan Province in 2023(232102230110)the National Natural Science Foundation of China(NSFC)(Grant No.51902290)+1 种基金the Young Top-Notch Talent Program of Zhengzhou University(No.125/32310189)the Science and Technology Program of the State Administration for Market Regulation(2021MK062)。
文摘Ceramics with proper pore sizes and geometry are critical to many applications,so that lots of efforts have been made to achieve the goal.Direct ink writing(DIW),an additive manufacturing technique,is cost-effective and accessible.It is interesting to study the ability to control the pore size and geometry by the DIW technique.In this study,alumina ceramics were prepared with special focus on the pore configuration and the performance of printed samples was tested.The porous structures with different pore sizes(minimum pore size of 200μm)and different shapes(honeycomb,lattice and triangle)were printed.The printed structures shrunk uniformly and maintained the original geometry after firing,they did not show any visible defects or deformations,and the microstructure was uniform and dense.It was found the honeycomb structures exhibited superior mechanical strength at the same porosity compared to lattice and triangle structures,which reached 55 MPa with a porosity of 70%.The high strength with the high porosity was attributed to the highly controlled microstructure,i.e.,uniform pore sizes,pore shapes and interconnectivity.
基金Supported by the National Natural Science Foundation of China(No.51105009)the National Science and Technology Support Program(No.2012BAF13B05)
文摘In order to research how the size of the ink flow channel is affected by the interaction of adjacent ink areas,according to the method of fluid-solid interaction,this paper analyzes the size of the ink flow channel of two ink rollers' rotation.Firstly,this paper simulates the situation of only one ink area.Secondly,this paper simulates the situation of five adjacent ink areas.Then,through comparing the simulation results of two above situations,it' s obvious that the interaction of adjacent ink areas has big effects on the ink pressure and the size of ink flow channel.At last,this paper gets the main factor that affects the size of ink flow channel in the different situations.
