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Degradation of Nitrobenzene Wastewater via Iron/Carbon Micro-electrolysis Enhanced by Ultrasound Coupled with Hydrogen Peroxide 被引量:3
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作者 Qin Yuejiao Yu Lisheng +2 位作者 Luo Shuai Jiao Weizhou Liu Youzhi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2017年第4期72-81,共10页
The zero valent iron/granular active carbon(ZVI/GAC) micro-electrolysis enhanced by ultrasound(US) coupled with hydrogen peroxide(H_2O_2) was investigated for the deep degradation of nitrobenzene-containing wastewater... The zero valent iron/granular active carbon(ZVI/GAC) micro-electrolysis enhanced by ultrasound(US) coupled with hydrogen peroxide(H_2O_2) was investigated for the deep degradation of nitrobenzene-containing wastewater. The results of scanning electron microscopy-energy dispersive X-rays analysis(SEM-EDS) demonstrated that continuously accelerated regeneration of ZVI and GAC in situ by US could improve the process for converting nitrobenzene(NB) to aniline(AN). H_2O_2 was decomposed catalytically by the byproduct Fe^(2+) ions generated in the micro-electrolysis process to hydroxyl radicals and the organic pollutants in the wastewater were finally mineralized to CO2 and H2O. Effects of the ZVI dosage, the ZVI/GAC mass ratio, the initial pH value and the H_2O_2 dosage on the efficiency for degradation of NB were studied in these experiments. The optimal operating conditions covered a ZVI dosage of 15 g/L, a ZVI/GAC mass ratio of 1:2,an initial pH value of 3 and a H_2O_2 dosage of 4 mL. In this case, the NB removal efficiency reached 97.72% and the total organic carbon(TOC) removal efficiency reached 73.42% at a NB concentration of 300 mg/L. The reduction of NB by USZVI/GAC followed the pseudo-first-order kinetics model, and the pseudo-first-order rate constants were given at different initial pH values. The reaction intermediates such as AN, benzoquinonimine, p-benzoquinone, p-nitrophenol and other organic acids were detected and a probable pathway for NB degradation has been proposed. 展开更多
关键词 iron/carbon MICRO-ELECTROLYSIS ULTRASOUND hydrogen peroxide NITROBENZENE wastewater treatment DEGRADATION mechanisms
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Fabrication of K-promoted iron/carbon nanotubes composite catalysts for the Fischer–Tropsch synthesis of lower olefins 被引量:4
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作者 Xuezhi Duan Di Wang +4 位作者 Gang Qian John C.Walmsley Anders Holmen De Chen Xinggui Zhou 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第2期309-315,共7页
K-promoted iron/carbon nanotubes composite(i.e., Fe K-OX) was prepared by a redox reaction between carbon nanotubes and K2FeO4followed by thermal treatments on a purpose as the Fischer–Tropsch catalyst for the dire... K-promoted iron/carbon nanotubes composite(i.e., Fe K-OX) was prepared by a redox reaction between carbon nanotubes and K2FeO4followed by thermal treatments on a purpose as the Fischer–Tropsch catalyst for the direct conversion of syngas to lower olefins. Its catalytic behaviors were compared with those of the other two Fe-IM and Fe K-IM catalysts prepared by impregnation method followed by thermal treatments. The novel Fe K-OX composite catalyst is found to exhibit higher hydrocarbon selectivity,lower olefins selectivity and chain growth probability as well as better stability. The catalyst structureperformance relationship has been established using multiple techniques including XRD, Raman, TEM and EDS elemental mapping. In addition, effects of additional potassium into the Fe K-OX composite catalyst on the FTO performance were also investigated and discussed. Additional potassium promoters further endow the catalysts with higher yield of lower olefins. These results demonstrated that the introduction method of promoters and iron species plays a crucial role in the design and fabrication of highly active,selective and stable iron-based composite catalysts for the FTO reaction. 展开更多
关键词 Fischer–Tropsch synthesis Lower olefins iron catalyst Potassium promoter carbon nanotubes
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High Cr white cast iron/carbon steel bimetal liner by lost foam casting with liquid-liquid composite process 被引量:10
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作者 Xiao Xiaofeng Ye Shengping +2 位作者 YinWeixin Zhou Xiaoguang Xue Qiong 《China Foundry》 SCIE CAS 2012年第2期136-142,共7页
Liners in wet ball mill for mineral processing industry must bear abrasive wear and corrosive wear, and consequently, the service life of the liner made from traditional materials, such as Hadfield steel and alloyed s... Liners in wet ball mill for mineral processing industry must bear abrasive wear and corrosive wear, and consequently, the service life of the liner made from traditional materials, such as Hadfield steel and alloyed steels, is typically less than ten months. Bimetal liner, made from high Cr white cast iron and carbon steel, has been successfully developed by using liquid-liquid composite lost foam casting process. The microstructure and interface of the composite were analyzed using optical microscope, SEM, EDX and XRD. Micrographs indicate that the boundary of bimetal combination regions is staggered like dogtooth, two liquid metals are not mixed, and the interface presents excellent metallurgical bonding state. After heat treatment, the composite liner specimens have shown excellent properties, including hardness 〉 61 HRC, fracture toughness ak 〉16.5 J.cm2 and bending strength 〉1,600 MPa. Wear comparison was made between the bimetal composite liner and alloyed steel liner in an industrial hematite ball mill of WISCO, and the results of eight-month test in wet grinding environment have proved that the service life of the bimetal composite liner is three times as long as that of the alloyed steel liner. 展开更多
关键词 bimetal liner liquid-liquid composite process lost foam casting high Cr white cast iron
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An Integrated Analysis on the Synergistic Reduction of Carbon and Pollution Emissions from China’s Iron and Steel Industry 被引量:1
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作者 Quanyin Tan Fei Liu Jinhui Li 《Engineering》 SCIE EI CAS CSCD 2024年第9期111-121,共11页
Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions... Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions in China,are challenged by the huge demand for steel.Carbon and pollutants often share common emission sources,indicating that emission reduction could be achieved synergistically.Here,we explored the inherent potential of measures to adjust feedstock composition and technological structure and to control the size of the ISI to achieve carbon emission reduction(CER)and pollution emission reduction(PER).We investigated five typical pollutants in this study,namely,petroleum hydrocarbon pollutants and chemical oxygen demand in wastewater,particulate matter,SO_(2),and NO_(x) in off gases,and examined synergies between CER and PER by employing cross elasticity for the period between 2022 and 2035.The results suggest that a reduction of 8.7%-11.7%in carbon emissions and 20%-31%in pollution emissions(except for particulate matter emissions)could be achieved by 2025 under a high steel scrap ratio(SSR)scenario.Here,the SSR and electric arc furnace(EAF)ratio serve critical roles in enhancing synergies between CER and PER(which vary with the type of pollutant).However,subject to a limited volume of steel scrap,a focused increase in the EAF ratio with neglection of the available supply of steel scrap to EAF facilities would lead to an increase carbon and pollution emissions.Although CER can be achieved through SSR and EAF ratio optimization,only when the crude steel production growth rate remains below 2.2%can these optimization measures maintain the emissions in 2030 at a similar level to that in 2021.Therefore,the synergistic effects between PER and CER should be considered when formulating a development route for the ISI in the future. 展开更多
关键词 iron and steel industry carbon and pollution emissions Synergistic reduction Technological structure Steel scrap Cross-elasticity
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Carbon Monoxide Modulates Auxin Transport and Nitric Oxide Signaling in Plants under Iron Deficiency Stress
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作者 Kaiyue Hong Yasmina Radani +2 位作者 Waqas Ahmad Ping Li Yuming Luo 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第1期45-61,共17页
Carbon monoxide(CO)and nitric oxide(NO)are signal molecules that enhance plant adaptation to environmental stimuli.Auxin is an essential phytohormone for plant growth and development.CO and NO play crucial roles in mo... Carbon monoxide(CO)and nitric oxide(NO)are signal molecules that enhance plant adaptation to environmental stimuli.Auxin is an essential phytohormone for plant growth and development.CO and NO play crucial roles in modulating the plant’s response to iron deficiency.Iron deficiency leads to an increase in the activity of heme oxygenase(HO)and the subsequent generation of CO.Additionally,it alters the polar subcellular distribution of Pin-Formed 1(PIN1)proteins,resulting in enhanced auxin transport.This alteration,in turn,leads to an increase in NO accumulation.Furthermore,iron deficiency enhances the activity of ferric chelate reductase(FCR),as well as the expression of the Fer-like iron deficiency-induced transcription factor 1(FIT)and the ferric reduction oxidase 2(FRO2)genes in plant roots.Overexpression of the long hypocotyl 1(HY1)gene,which encodes heme oxygenase,or the CO donor treatment resulted in enhanced basipetal auxin transport,higher FCR activity,and the expression of FIT and FRO2 genes under Fe deficiency.Here,a potential mechanism is proposed:CO and NO interact with auxin to address iron deficiency stress.CO alters auxin transport,enhancing its accumulation in roots and up-regulating key iron-related genes like FRO2 and IRT1.Elevated auxin levels affect NO signaling,leading to greater sensitivity in root development.This interplay promotes FCR activity,which is crucial for iron absorption.Together,these molecules enhance iron uptake and root growth,revealing a novel aspect of plant physiology in adapting to environmental stress. 展开更多
关键词 carbon monoxide nitric oxide AUXIN iron deficiency signal molecule PLANTS
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Solubility of iron(Ⅲ) and nickel(Ⅱ) acetylacetonates in supercritical carbon dioxide
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作者 Haixin Sun Jianlei Qi +4 位作者 Jianfei Sun Lin Li Kunpeng Yu Jintao Wu Jianzhong Yin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期29-34,共6页
As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates hav... As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range. 展开更多
关键词 iron(III)acetylacetonate Nickel(II)acetylacetonate Supercritical carbon dioxide Solubility measurement Correlation model Phase equilibrium
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Fertilization and Soil Ploughing Practices under Changing Physical Environment Lead to Soil Organic Carbon Dynamics under Conservation Agriculture in Rice-Wheat Cropping System: A Scoping Review
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作者 Salwinder Singh Dhaliwal Arvind Kumar Shukla +8 位作者 Sanjib Kumar Behera Sarwan Kumar Dubey Agniva Mandal Mehakpreet Kaur Randhawa Sharanjit Kaur Brar Gagandeep Kaur Amardeep Singh Toor Sohan Singh Walia Priyadarshani Arun Khambalkar 《Agricultural Sciences》 2024年第1期82-113,共32页
Ploughing and fertilization practices in rice-wheat system have deteriorated the soil carbon (C) pools. Conservation agriculture (CA) based management approaches have proven to enhance C sequestration and reverse the ... Ploughing and fertilization practices in rice-wheat system have deteriorated the soil carbon (C) pools. Conservation agriculture (CA) based management approaches have proven to enhance C sequestration and reverse the loss of soil-organic-carbon (SOC), which further enhances soil fertility. Different fractions of SOC pools react to the alterations in management practices and indicate changes in SOC dynamics as compared to total C in the soil. Higher SOC levels in soil have been observed in case of reduced/no-till (NT) practices than conventional tillage (CT). However, between CT and zero tillage/NT, total SOC stocks diminished with an increase in soil depth, which demonstrated that the benefits of SOC are more pronounced in the topsoil under NT. Soil aggregation provides physical protection to C associated with different-sized particles, thus, the improvement in soil aggregation through CA is an effective way to mitigate soil C loss. Along with less soil disturbance, residual management, suitable crop rotation, rational application of manures and fertilizers, and integrated nutrient management have been found to be effective in not only improving soil C stock but also enhancing the soil health and productivity. Thus, CA can be considered as a potential method in the build-up of SOC of soil in rice-wheat system. 展开更多
关键词 TILLAGE Conservation Agriculture Soil Organic carbon carbon Fractions Rice-Wheat System Organic Amendments
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Repair of Second-Generation Recycled Fine Aggregate of Waste Concrete from Freeze-Thaw Environment by Carbonation Treatment
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作者 Jie Huang Rongbin Jiang +1 位作者 Xiaobo Sun Yingyong Shuai 《Journal of Renewable Materials》 EI CAS 2024年第1期187-201,共15页
The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled ... The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled fine aggregate(SRFA)obtained from recycled fine aggregate concrete(RFAC)subjected to freeze-thaw(FT)cycles.Before and after carbonation,the properties of SRFA were evaluated.Carbonated second-generation recycled fine aggregate(CSRFA)at five substitution rates(0%,25%,50%,75%,100%)to replace SRFA was used to prepare carbonated second-generation recycled fine aggregate concrete(CSRFAC).The water absorption,porosity and mechanical properties of CSRFAC were tested,and its frost-resisting durability was evaluated.The results showed after carbonation treatment,the physical properties of SRFA was improved and met the requirements of II aggregate.The micro-hardness of the interfacial transition zone and attached mortar in CSRFA was 50.5%and 31.2%higher than that in SRFA,respectively.With the increase of CSRFA replacement rate,the water absorption and porosity of CSRFAC gradually decreased,and the mechanical properties and frost resistance of CSRFAC were gradually improved.Carbonation treatment effectively repairs the damage of SRFA caused by FT cycles and improves its application potential. 展开更多
关键词 carbonation treatment REPAIR freeze-thaw cycles second-generation recycled fine aggregate
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Tree mycorrhizal associations determine how biodiversity,large trees,and environmental factors drive aboveground carbon stock in temperate forests
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作者 Yue Chen Zikun Mao +2 位作者 Jonathan A.Myers Jinghua Yu Xugao Wang 《Forest Ecosystems》 SCIE CSCD 2024年第4期448-456,共9页
Biodiversity,large trees,and environmental conditions such as climate and soil have important effects on forest carbon stocks.However,recent studies in temperate forests suggest that the relative importance of these f... Biodiversity,large trees,and environmental conditions such as climate and soil have important effects on forest carbon stocks.However,recent studies in temperate forests suggest that the relative importance of these factors depends on tree mycorrhizal associations,whereby large-tree effects may be driven by ectomycorrhizal(EM)trees,diversity effects may be driven by arbuscular mycorrhizal(AM)trees,and environment effects may depend on differential climate and soil preferences of AM and EM trees.To test this hypothesis,we used forest-inventory data consisting of over 80,000 trees from 631 temperate-forest plots(30 m×30 m)across Northeast China to examine how biodiversity(species diversity and ecological uniqueness),large trees(top 1%of tree diameters),and environmental factors(climate and soil nutrients)differently regulate aboveground carbon stocks of AM trees,EM trees,and AM and EM trees combined(i.e.total aboveground carbon stock).We found that large trees had a positive effect on both AM and EM tree carbon stocks.However,biodiversity and environmental factors had opposite effects on AM vs.EM tree carbon stocks.Specifically,the two components of biodiversity had positive effects on AM tree carbon stocks,but negative effects on EM tree carbon stocks.Environmental heterogeneity(mean annual temperature and soil nutrients)also exhibited contrasting effects on AM and EM tree carbon stocks.Consequently,for the total carbon stock,the positive large-tree effect far surpasses the diversity and environment effect.This is mainly because when integrating AM and EM tree carbon stock into total carbon stock,the opposite diversity-effect(also environment-effect)on AM vs.EM tree carbon stock counteracts each other while the consistent positive large-tree effect on AM and EM tree carbon stock is amplified.In summary,this study emphasized a mycorrhizal viewpoint to better understand the determinants of overarching aboveground carbon profile across regional forests. 展开更多
关键词 BIODIVERSITY Ecological uniqueness Environment heterogeneity Large trees Mycorrhizal associations Tree carbon stock
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Central environmental protection inspection and carbon emission reduction: A tripartite evolutionary game model from the perspective of carbon neutrality
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作者 Zhen-Hua Zhang Dan Ling +2 位作者 Qin-Xin Yang Yan-Chao Feng Jing Xiu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期2139-2153,共15页
Since the carbon neutrality target was proposed,many countries have been facing severe challenges to carbon emission reduction sustainably.This study is conducted using a tripartite evolutionary game model to explore ... Since the carbon neutrality target was proposed,many countries have been facing severe challenges to carbon emission reduction sustainably.This study is conducted using a tripartite evolutionary game model to explore the impact of the central environmental protection inspection(CEPI)on driving carbon emission reduction,and to study what factors influence the strategic choices of each party and how they interact with each other.The research results suggest that local governments and manufacturing enterprises would choose strategies that are beneficial to carbon reduction when CEPI increases.When the initial willingness of all parties increases 20%,50%—80%,the time spent for the whole system to achieve stability decreases from 100%,60%—30%.The evolutionary result of“thorough inspection,regulation implementation,low-carbon management”is the best strategy for the tripartite evolutionary game.Moreover,the smaller the cost and the larger the benefit,the greater the likelihood of the three-party game stability strategy appears.This study has important guiding significance for other developing countries to promote carbon emission reduction by environmental policy. 展开更多
关键词 Central environmental protection INSPECTION Local government Manufacturing enterprise Tripartite evolutionary game carbon emission reduction
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Blasts Of Progress Xinjiang Bayi Iron and Steel's carbon reduction breakthroughs
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作者 Li Shimeng 《China Report ASEAN》 2024年第10期32-34,共3页
Facing dual challenges of climate change and energy crisis,the global iron and steel industry has been seeking to balance efficiency with energy conservation and environmental protection.Could the realities of blast f... Facing dual challenges of climate change and energy crisis,the global iron and steel industry has been seeking to balance efficiency with energy conservation and environmental protection.Could the realities of blast furnace operation possibly align with low-carbon circular development within China's iron and steel industry?Hydrogen-rich carbon circulating oxygen blast furnace (HyCROF)technology is gaining traction in the Chinese metallurgical industry. 展开更多
关键词 steel carbon BREAKTHROUGH
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Sulfur doped iron-nitrogen-hard carbon nanosheets as efficient and robust noble metal-free catalysts for oxygen reduction reaction in PEMFC
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作者 Bin Liu Jiawang Li +6 位作者 Bowen Yan Qi Wei Xingyu Wen Huarui Xie Huan He Pei Kang Shen Zhi Qun Tian 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期422-433,I0010,共13页
Transition metal-nitrogen-carbon(M-N-C)as a promising substitute for the conventional noble metalbased catalyst still suffers from low activity and durability for oxygen reduction reaction(ORR)in proton exchange membr... Transition metal-nitrogen-carbon(M-N-C)as a promising substitute for the conventional noble metalbased catalyst still suffers from low activity and durability for oxygen reduction reaction(ORR)in proton exchange membrane fuel cells(PEMFCs).To tackle the issue,herein,a new type of sulfur-doped ironnitrogen-hard carbon(S-Fe-N-HC)nanosheets with high activity and durability in acid media were developed by using a newly synthesized precursor of amide-based polymer with Fe ions based on copolymerizing two monomers of 2,5-thiophene dicarboxylic acid(TDA)as S source and 1,8-diaminonaphthalene(DAN)as N source via an amination reaction.The as-synthesized S-Fe-N-HC features highly dispersed atomic Fe Nxmoieties embedded into rich thiophene-S doped hard carbon nanosheets filled with highly twisted graphite-like microcrystals,which is distinguished from the majority of M-N-C with soft or graphitic carbon structures.These unique characteristics endow S-Fe-N-HC with high ORR activity and outstanding durability in 0.5 M H_(2)SO_(4).Its initial half-wave potential is 0.80 V and the corresponding loss is only 21 m V after 30,000 cycles.Meanwhile,its practical PEMFC performance is a maximum power output of 628.0 mW cm^(-2)and a slight power density loss is 83.0 m W cm^(-2)after 200-cycle practical operation.Additionally,theoretical calculation shows that the activity of Fe Nxmoieties on ORR can be further enhanced by sulfur doping at meta-site near FeN_(4)C.These results evidently demonstrate that the dual effect of hard carbon substrate and S doping derived from the precursor platform of amid-polymers can effectively enhance the activity and durability of Fe-N-C catalysts,providing a new guidance for developing advanced M-N-C catalysts for ORR. 展开更多
关键词 Transition metal-nitrogen-carbon Oxygen reduction reaction Hard carbon Amide based polymer reaction Proton exchange membrane cells
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Multifunctional MXene/Carbon Nanotube Janus Film for Electromagnetic Shielding and Infrared Shielding/Detection in Harsh Environments
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作者 Tufail Hassan Aamir Iqbal +14 位作者 Byungkwon Yoo Jun Young Jo Nilufer Cakmakci Shabbir Madad Naqvi Hyerim Kim Sungmin Jung Noushad Hussain Ujala Zafar Soo Yeong Cho Seunghwan Jeong Jaewoo Kim Jung Min Oh Sangwoon Park Youngjin Jeong Chong Min Koo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期543-560,共18页
Multifunctional,flexible,and robust thin films capable of operating in demanding harsh temperature environments are crucial for various cutting-edge applications.This study presents a multifunctional Janus film integr... Multifunctional,flexible,and robust thin films capable of operating in demanding harsh temperature environments are crucial for various cutting-edge applications.This study presents a multifunctional Janus film integrating highly-crystalline Ti_(3)C_(2)T_(x) MXene and mechanically-robust carbon nanotube(CNT)film through strong hydrogen bonding.The hybrid film not only exhibits high electrical conductivity(4250 S cm^(-1)),but also demonstrates robust mechanical strength and durability in both extremely low and high temperature environments,showing exceptional resistance to thermal shock.This hybrid Janus film of 15μm thickness reveals remarkable multifunctionality,including efficient electromagnetic shielding effectiveness of 72 dB in X band frequency range,excellent infrared(IR)shielding capability with an average emissivity of 0.09(a minimal value of 0.02),superior thermal camouflage performance over a wide temperature range(−1 to 300℃)achieving a notable reduction in the radiated temperature by 243℃ against a background temperature of 300℃,and outstanding IR detection capability characterized by a 44%increase in resistance when exposed to 250 W IR radiation.This multifunctional MXene/CNT Janus film offers a feasible solution for electromagnetic shielding and IR shielding/detection under challenging conditions. 展开更多
关键词 MXene/carbon nanotube Janus film Electromagnetic interference shielding Infrared shielding Thermal camouflage Infrared detection
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Flora, Structure and Carbon Sequestration of Vegetation in the Southeast of the Mono Biosphere Reserve in Togo Amidst Environmental Challenges
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作者 Gbétey Kokouvi Akpamou Kossi Adjossou +3 位作者 Hodabalo Egbelou Komlanvi Katche Akoete Kossi Hounkpati Kouami Kokou 《Open Journal of Forestry》 2024年第2期155-181,共27页
In most Sub-Saharan African countries such as Togo, people’s heavy dependence on ecosystem services is a major factor in accelerating the degradation of natural resources, which are already suffering as a result of c... In most Sub-Saharan African countries such as Togo, people’s heavy dependence on ecosystem services is a major factor in accelerating the degradation of natural resources, which are already suffering as a result of climatic factors. This study was initiated to contribute to the sustainable and rational management of forest resources in the south-east of the Mono Biosphere Reserve in Togo. It specifically aims to identify and characterize the flora of the residual forest ecosystems within the reserve through their specific diversity, demographic structure, and carbon sequestration potential. The study was carried out in the forest ecosystems of Avévé. The methodology used was based on the analysis of phytosociological, forestry, ecological, and regeneration inventory data. Overall, the study revealed that the RBMT still has floristically viable habitats, despite the anthropogenic pressures it is subject to revealed a floristic diversity of 160 plant species divided into 52 families and 135 genera. The most represented families are Rubiaceae (29.09%), followed by Fabaceae (27.94%). The most represented species are Mitragyna inermis (Willd.) Kuntze (24.38%), Lecaniodiscus cupanioides Planch. Ex Benth (X) and Lonchocarpus sericeus (Poir.) Kunth (10.93%). The high presence of Mitragyna inermis observed in all the ecological groups identified makes it the characteristic species of the flooded marshy areas of southeast Togo and contributes to the resilience of the ecosystems and populations in the study area. The Shannon index for the formation groups varies between (3.03 and 5.16) bits. Pielou’s equitability varies between (0.43 and 0.63) bits. The overall average density is estimated at 210 stems/ha, with an average diameter of 25.57 ± 21.77 m and an average height of 7.93 ± 3.83 m. The adjustment of the diameter classes of the plant groups to the Weibull distribution gave an “inverted J” shape with coefficient values of less than 1 overall, reflecting the existence of multispecific or uneven-aged stands. Assessment of the horizontal and vertical structure shows a predominance of the shrub layer in all the groups identified. The carbon sequestration potential is 41.89 T/Ha. Despite ongoing anthropogenic pressures, the Mono Biosphere Reserve abounds in a relatively rich diversity of flora, the preservation of which is essential for the survival of biodiversity and even for the riparian population. The data provided by this study would form the basis for sustainable management planning of the forest islands in the biosphere reserve. 展开更多
关键词 BIODIVERSITY Demographic Structure carbon Biosphere Reserve Forest Patches TOGO
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Current situation of carbon emissions and countermeasures in China's ironmaking industry 被引量:4
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作者 Chenmei Tang Zhengqi Guo +4 位作者 Jian Pan Deqing Zhu Siwei Li Congcong Yang Hongyu Tian 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第9期1633-1650,共18页
The iron and steel industry(ISI) involves high energy consumption and high pollution. ISI in China, a leading country in the ISI,consumed 15% of the country’s total energy and produced more than 50% of the global ISI... The iron and steel industry(ISI) involves high energy consumption and high pollution. ISI in China, a leading country in the ISI,consumed 15% of the country’s total energy and produced more than 50% of the global ISI’s carbon emissions. Therefore, in the context of global low-carbon economy and emission reduction requirements, low-carbon smelting technology in the ISI has attracted increasingly more attention in China. This review summarizes the current status of carbon emissions and energy consumption in China’s ISI and discusses the development status and prospects of low-carbon ironmaking technology. The main route to effectively reducing carbon emissions is to develop a gas-based direct reduction process and replace sintering with pelletizing, both of which focus on developing pelletizing technology. However,the challenge of pelletizing process development is to obtain high-quality iron concentrates. Consequently, the present paper also summarizes the development status of China’s mineral processing technology, including fine-grained mineral processing technology, magnetization roasting technology, and flotation collector application. This paper aims to provide a theoretical basis for the low-carbon development of China’s ISI in terms of a dressing–smelting combination. 展开更多
关键词 iron and steel industry carbon dioxide emissions low-carbon technology beneficiation technology
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Hollow Gradient-Structured Iron-Anchored Carbon Nanospheres for Enhanced Electromagnetic Wave Absorption 被引量:6
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作者 Cao Wu Jing Wang +14 位作者 Xiaohang Zhang Lixing Kang Xun Cao Yongyi Zhang Yutao Niu Yingying Yu Huili Fu Zongjie Shen Kunjie Wu Zhenzhong Yong Jingyun Zou Bin Wang Zhou Chen Zhengpeng Yang Qingwen Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期144-160,共17页
In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which c... In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications. 展开更多
关键词 Gradient structures carbon nanospheres Electromagnetic wave absorption Impedance matching
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Corrosion,mechanical and microstructural properties of aluminum 7075-carbon nanotube nanocomposites for robots in corrosive environments 被引量:2
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作者 Arun David Satheesh Kumar Gopal +1 位作者 Poovazhagan Lakshmanan Amith Sukumaran Chenbagam 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第6期1140-1151,共12页
The introduction of in-pipe robots for sewage cleaning provides researchers with new options for pipe inspection,such as leakage,crack,gas,and corrosion detection,which are standard applications common in the current ... The introduction of in-pipe robots for sewage cleaning provides researchers with new options for pipe inspection,such as leakage,crack,gas,and corrosion detection,which are standard applications common in the current industrial scenario.The question that is frequently overlooked in all these cases is the inherent resistance of the robots to corrosion.The mechanical,microstructural,and corrosion properties of aluminum 7075 incorporated with various weight percentages(0,0.5wt%,1wt%,and 1.5wt%)of carbon nanotubes(CNTs)are discussed.It is fabricated using a rotational ultrasonication with mechanical stirring(RUMS)-based casting method for improved corrosion resistance without compromising the mechanical properties of the robot.1wt%CNTs-aluminum nanocomposite shows good corrosion and mechanical properties,meeting the requirements imposed by the sewage environment of the robot. 展开更多
关键词 aluminum 7075 carbon nanotubes rotational ultrasonication with mechanical stirring mechanical characterization microstructure robot
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Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions 被引量:1
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作者 Yingli Li Zhishuncheng Li +5 位作者 Guangfei Qu Rui Li Shuaiyu Liang Junhong Zhou Wei Ji Huiming Tang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期26-36,共11页
In this study,ferric nitrate modified carbon nanotube composites (FCNT) were prepared by isovolumetric impregnation using carbon nanotubes (CNTs) as the carrier and ferric nitrates the active agent.The batch experimen... In this study,ferric nitrate modified carbon nanotube composites (FCNT) were prepared by isovolumetric impregnation using carbon nanotubes (CNTs) as the carrier and ferric nitrates the active agent.The batch experiments showed that FCNT could effectively oxidize As(III) to As(V) and react with it to form stable iron arsenate precipitates.When the dosage of FCNT was 0.1 g·L^(–1),pH value was 5–6,reaction temperature was 35℃ and reaction time was 2 h,the best arsenic removal effect could be achieved,and the removal rate of As(V) could reach 99.1%,which was always higher than 90%under acidic conditions.The adsorption results of FCNT were found to be consistent with Langmuir adsorption by static adsorption isotherm fitting,and the maximum adsorption capacity reached 118.3 mg·g^(-1).The material phase and property analysis by scanning electron microscopy,Brunauer–Emmett–Teller,Fourier transform infrared spectoscopy,X-ray photoelectron spectroscopy and other characterization methods,as well as adsorption isotherm modeling,were used to explore the adsorption mechanism of FCNT on arsenic.It was found that FCNT has microporous structure and nanostructure,and iron nanoparticles are loosely distributed on CNTs,which makes the material have good oxidation,adsorption and magnetic separation properties.Arsenic migrates on the surface of FCNT composites is mainly removed by forming insoluble compounds and co-precipitation.All the results show that FCNT treats arsenic at low cost with high adsorption efficiency,and the results also provide the experimental data basis and theoretical basis for arsenic contamination in groundwater. 展开更多
关键词 carbon nanotubes AS(V) ADSORPTION Nanocomposites Impregnation method
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Effects of Spin Transition and Cation Substitution on the Optical Properties and Iron Partitioning in Carbonate Minerals
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作者 HU Jun XU Liangxu +1 位作者 LIU Jin YUE Donghui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第1期350-357,共8页
The high-pressure behavior of deep carbonate dictates the state and dynamics of oxidized carbon in the Earth's mantle,playing a vital role in the global carbon cycle and potentially influencing long-term climate c... The high-pressure behavior of deep carbonate dictates the state and dynamics of oxidized carbon in the Earth's mantle,playing a vital role in the global carbon cycle and potentially influencing long-term climate change.Optical absorption and Raman spectroscopic measurements were carried out on two natural carbonate samples in diamond-anvil cells up to 60 GPa.Mg-substitution in high-spin siderite FeCO_(3)increases the crystal field absorption band position by approximately 1000 cm^(-1),but such an effect is marginal at>40 GPa when entering the low-spin state.The crystal field absorption band of dolomite cannot be recognized upon compression to 45.8 GPa at room temperature but,in contrast,the high-pressure polymorph of dolomite exhibits a strong absorption band at frequencies higher than(Mg,Fe)CO_(3)in the lowspin state by 2000–2500 cm^(-1).Additionally,these carbonate minerals show more complicated features for the absorption edge,decreasing with pressure and undergoing a dramatic change through the spin crossover.The optical and vibrational properties of carbonate minerals are highly correlated with iron content and spin transition,indicating that iron is preferentially partitioned into low-spin carbonates.These results shed new light on how carbonate minerals evolve in the mantle,which is crucial to decode the deep carbon cycle. 展开更多
关键词 carbonate petrology/mineralogy MANTLE high pressure diamond-anvil cell iron spin transition iron partitioning deep carbon cycle
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Selenium–nitrogen-co-doped carbon dots increase rice seedling growth and salt resistance 被引量:1
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作者 Yadong Li Ronghua Xu +5 位作者 Qianying Han Shang Lei Congli Ma Jingyi Qi Yingliang Liu Hongjie Wang 《The Crop Journal》 SCIE CSCD 2024年第5期1496-1501,共6页
Soil salinity seriously affects the utilization of farmland and threatens the crop production.Here,a selenium-nitrogen-co-doped carbon dots was developed,which increased rice seedling growth and alleviated its inhibit... Soil salinity seriously affects the utilization of farmland and threatens the crop production.Here,a selenium-nitrogen-co-doped carbon dots was developed,which increased rice seedling growth and alleviated its inhibition by salt stress by foliar spraying.The treatment activated Ca^(2+)and jasmonic acid signaling pathways and increased iron homeostasis,antioxidant defense,and cell wall development of rice seedlings.It could be used to increase crop resistance to environmental stress. 展开更多
关键词 carbon dots Rice seedling RESISTANCE Stress signaling iron homeostasis
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