Isotropic sintering shrinkage of 3D glass-ceramic nanolattices:backbone preforming and mechanical enhancement

There is a perpetual pursuit for free-form glasses and ceramics featuring outstanding mechanical properties as well as chemical and thermal resistance.It is a promising idea to shape inorganic materials in three-dimensional(3D)forms to reduce their weight while maintaining high mechanical properties.A popular strategy for the preparation of 3D inorganic materials is to mold the organic–inorganic hybrid photoresists into 3D micro-and nano-structures and remove the organic components by subsequent sintering.However,due to the discrete arrangement of inorganic components in the organic-inorganic hybrid photoresists,it remains a huge challenge to attain isotropic shrinkage during sintering.Herein,we demonstrate the isotropic sintering shrinkage by forming the consecutive–Si–O–Si–O–Zr–O–inorganic backbone in photoresists and fabricating 3D glass–ceramic nanolattices with enhanced mechanical properties.The femtosecond(fs)laser is used in two-photon polymerization(TPP)to fabricate 3D green body structures.After subsequent sintering at 1000℃,high-quality 3D glass–ceramic microstructures can be obtained with perfectly intact and smooth morphology.In-suit compression experiments and finite-element simulations reveal that octahedral-truss(oct-truss)lattices possess remarkable adeptness in bearing stress concentration and maintain the structural integrity to resist rod bending,indicating that this structure is a candidate for preparing lightweight and high stiffness glass–ceramic nanolattices.3D printing of such glasses and ceramics has significant implications in a number of industrial applications,including metamaterials,microelectromechanical systems,photonic crystals,and damage-tolerant lightweight materials.

Deep learning for determining pure isotropic proton spectra from solidstate spectra

Recently,an article on ^(1)H solid-state NMR spectra was published,in which the authors proposed a deep learning approach to infer the pure isotropic proton NMR spectra obtained at an infinite magic angle spinning(MAS)rate.This approach even allowed to obtain,by far,the best resolved ^(1)H spectra of molecular solids[1](https://doi.org/10.1002/anie.202216607).Deep learning based artificial intelligence is developing rapidly,and its application is deepening.Currently,there are many applications of deep learning in the field of magnetic resonance,such as the reconstruction of the under-sampled multidimensional spectra[2-4],the deconvolution of two-dimensional NMR spectra[5]and noise suppression and weak peak retrial[6],etc.

Numerical modeling of seismic wavefields in transversely isotropic media with a compact staggered-grid finite difference scheme

To deal with the numerical dispersion problem, by combining the staggeredgrid technology with the compact finite difference scheme, we derive a compact staggered- grid finite difference scheme from the first-order velocity-stress wave equations for the transversely isotropic media. Comparing the principal truncation error terms of the compact staggered-grid finite difference scheme, the staggered-grid finite difference scheme, and the compact finite difference scheme, we analyze the approximation accuracy of these three schemes using Fourier analysis. Finally, seismic wave numerical simulation in transversely isotropic （VTI） media is performed using the three schemes. The results indicate that the compact staggered-grid finite difference scheme has the smallest truncation error, the highest accuracy, and the weakest numerical dispersion among the three schemes. In summary, the numerical modeling shows the validity of the compact staggered-grid finite difference scheme.

Elasto-plastic analysis of masonry with anisotropic plastic material model

This paper establishes an anisotropic plastic material model to analyze the elasto-plastic behavior of masonry in plane stress state.Being an anisotropic material,masonry has different constitutive relation and fracture energies along each orthotropic axes.Considering the unique material properties of masonry,a new yield criterion for masonry is proposed combining the Hill's yield criterion and the Rankine's yield criterion.The new yield criterion not only introduces compression friction coefficient of shear but also considers yield functions for independent stress state along two material axes of tension.To solve the involved nonlinear equations in numerical analysis,several nonlinear methods are implemented,including Newton-Raphson method for nonlinear equations and Implicit Euler backward mapping algorithm to update stresses.To verify the proposed material model of masonry,a series of tests are operated.The simulation results show that the new developed material model implements successfully.Compared with isotropic material model,the proposed model performs better in elasto-plastic analysis of masonry in plane stress state.The proposed anisotropic model is capable of simulating elasto-plastic behavior of masonry and can be used in related applications.

Assimilation of temperature and salinity using isotropic and anisotropic recursive filters in Tropic Pacific

A data assimilation scheme used in the updated Ocean three-dimensional Variational Assimila- tion System （OVALS）, OVALS2, is described. Based on a recursive filter （RF） to estimate the background error covariance （BEC） over a predetermined scale, this new analysis system can be implemented with anisotropic and isotropic BECs. Similarities and differences of these two BEC schemes are briefly discussed and their impacts on the model simulation are also investigated. An idealized experiment demonstrates the ability of the updated analysis system to construct different BECs. Furthermore, a set of three years experiments is implemented by assimilating expendable bathythermograph （XBT） and ARGO data into a Tropical Pacific circulation model. The TAO and WOA01 data are used to validate the assimilation results. The results show that the model simu- lations are substantially improved by OVALS2. The inter-comparison of isotropic and anisotropic BEC shows that the corresponding temperature and salinity produced by the anisotropic BEC are almost as good as those obtained by the isotropic one. Moreover, the result of anisotropic RF is slightly closer to WOA01 and TAO than that of isotropic RF in some special area （e.g. the cold tongue area in the Tropic Pacific）.

ISOTROPICALIZED SPLINE INTEGRAL EQUATION METHOD FOR THE ANALYSIS OF ANISOTROPIC PLATES

In the view of Reissner's and Kirchhoff's theories, respectively, we formulate the isotropicalized governing equations for the anisotropic plates, and give the proof of the equivalence relation between these two plate-models for the simply-supported rectangular orthotropic plates. The well-known fundamental solutions of the isotrqpic plates are utlized for the spline integral equation analysis of anisotropic plates.Even with sparse meshes the satisfactory results can be obtained. The analysis of plates on two-parameter elastic foundation is so simple as the common case that only a few terms should be added to the formulas of fictitious loads.

The Effects of Chemical (isotropic) and Anisotropic Etching Processes on the Roughening of Nanocomposite Substrates

Simulation results of roughening of nanocomposite materials during both isotropic and anisotropic etching processes based on the level set method are presented. It is clearly shown that the presence of two phases with different etching rates affects the development of surface roughness and that some roughness characteristics obey simple scaling laws. In addition, certain scaling laws that describe the time dependence of the root mean square （rms） roughness w for various etching processes and different characteristics of the nanocomposite materials are determined.

Stability of Geothermal Convection in Anisotropic River Beds

The onset of thermal convection, due to heating from below in a system consisting of a fluid layer overlying a porous layer with anisotropic permeability and thermal diffusivity, is investigated analytically. The porous medium is both anisotropic in permeability whose principal axes are oriented in a direction that is oblique to the gravity vector and in thermal conductivity with principal directions coincident with the coordinate axes. The Beavers-Joseph condition is applied at the interface between the two layers. Based on parallel flow approximation theory, a linear stability analysis is conducted to study the geothermal river beds system and documented the effects of the physical parameters describing the problem. The critical Rayleigh numbers for both the fluid and porous layers corresponding, to the onset of convection arising from sudden heating and cooling at the boundaries are also predicted. The results obtained are in agreement with those found in the past for particular isotropic and anisotropic cases and for limiting cases concerning pure porous media and for pure fluid layer. It has demonstrated that the effects of anisotropic parameters are highly significant.

Comparisons between Isotropic and Anisotropic TV Regularizations in Inverse Acoustic Scattering

This article compares the isotropic and anisotropic TV regularizations used in inverse acoustic scattering. It is observed that compared with the traditional Tikhonov regularization, isotropic and anisotropic TV regularizations perform better in the sense of edge preserving. While anisotropic TV regularization will cause distortions along axes. To minimize the energy function with isotropic and anisotropic regularization terms, we use split Bregman scheme. We do several 2D numerical experiments to validate the above arguments.

The Behavior of Recycled Concrete through the Application of an Isotropic Damage Model

The main goal of this paper is to describe the mechanical behavior of the CDW recycled concrete in compression, using an isotropic damage model adapted to the variation of the replacement rate of natural aggregates by recycled ones. The isotropic model by Mazars was used as a constitutive equation for the CDW concrete and its adjustment parameters, A and B, were written as quadratic polynomials according to the aggregates replacement rate. The model was evaluated for conventional and recycled concretes. For the latter ones, the aggregates replacement ratios evaluated were 50% and 100%. The results show good approximation between the analytical and numerical values obtained with the adapted isotropic damage model and experimental concrete results for both compressive and flexural strength.

Applying resolved-scale linearly forced isotropic turbulence in rational subgrid-scale modeling

In previous attempts of rational subgrid-scale (SGS) modeling by employing the Kolmogorov equation of filtered (KEF) quantities, it was necessary to assume that the resolved-scale second-order structure function is stationary. Forced isotropic turbulence is often used as a framework for establishing and validating such SGS models based on stationary restrictions, for it generates statistical stationary samples. However, traditional forcing method at low wavenumbers cannot provide an analytic form of forcing term for a complete KEF in physical space, which has been illustrated to be essential in the modeling of such SGS models. Thus, an alternative forcing method giving an analytic forcing term in physical space is needed for rational SGS modeling. Giving an analytic linear driving term in physical space, linearly forced isotropic turbulence should be considered an ideal theoretical framework for rational SGS modeling. In this paper, we demonstrate the feasibility of establishing a rational SGS model with stationary restriction based on linearly forced isotropic turbulence. The performance of this rational SGS model is validated. We, therefore, propose the use of linearly forced isotropic turbulence as a complement to free-decaying isotropic turbulence and low-wavenumber forced isotropic turbulence for SGS model validations.

Torsional vibration of a pipe pile in transversely isotropic saturated soil

This study considers the torsional vibration of a pipe pile in a transversely isotropic saturated soil layer. Based on Biot＇s poroelastic theory and the constitutive relations of the transversely isotropic medium, the dynamic governing equations of the outer and inner transversely isotropic saturated soil layers are derived. The Laplace transform is used to solve the governing equations of the outer and inner soil layers. The dynamic torsional response of the pipe pile in the frequency domain is derived utilizing 1D elastic theory and the continuous conditions at the interfaces between the pipe pile and the soils. The time domain solution is obtained by Fourier inverse transform. A parametric study is conducted to demonstrate the influence of the anisotropies of the outer and inner soil on the torsional dynamic response of the pipe pile.

Pure bending of simply supported circular plate of transversely isotropic functionally graded material

This paper considers the pure bending problem of simply supported transversely isotropic circular plates with elastic compliance coefficients being arbitrary functions of the thickness coordinate. First, the partial differential equation, which is satisfied by the stress functions for the axisymmetric deformation problem is derived. Then, stress functions are obtained by proper manipulation. The analytical expressions of axial force, bending moment and displacements are then deduced through integration. And then, stress functions are employed to solve problems of transversely isotropic functionally graded circular plate, with the integral constants completely determined from boundary conditions. An elasticity solution for pure bending problem, which coincides with the available solution when degenerated into the elasticity solutions for homogenous circular plate, is thus obtained. A numerical example is finally presented to show the effect of material inhomogeneity on the elastic field in a simply supported circular plate of transversely isotropic functionally graded material (FGM).

THE NON-AXISYMMETRICAL DYNAMIC RESPONSE OF TRANSVERSELY ISOTROPIC SATURATED POROELASTIC MEDIA

The Blot's wave equations of transversely isotropic saturated poroelastic media excited hy non-axisymmetrical harmonic source were solved by means of Fourier expansion and Hankel transform. Then the components of total stress in porous media are expressed with the solutions of Biot's wave equations. The method of research on non-axisymmetrical dynamic response of saturated porous media is discussed, and a numerical result is presented.

Dynamic analysis of slab track on multi-layered transversely isotropic saturated soils subjected to train loads

The dynamic responses of a slab track on transversely isotropic saturated soils subjected to moving train loads are investigated by a semi-analytical approach. The track model is described as an upper Euler beam to simulate the rails and a lower Euler beam to model the slab. Rail pads between the rails and slab are represented by a continuous layer of springs and dashpots. A series of point loads are formulated to describe the moving train loads. The governing equations of track-ground systems are solved using the double Fourier transform, and the dynamic responses in the time domain are obtained by the inverse Fourier transform. The results show that a train load with high velocity will generate a larger response in transversely isotropic saturated soil than the lower velocity load, and special attention should be paid on the pore pressure in the vicinity of the ground surface. The anisotropic parameters of a surface soil layer will have greater influence on the displacement and excess pore water pressure than those of the subsoil layer. The traditional design method taking ground soil as homogeneous isotropic soil is unsafe for the case of RE 〈 1 and RG 〈 1, so a transversely isotropic foundation model is of great significance to the design for high train velocities.

Diffraction of SH-waves by topographic features in a layered transversely isotropic half-space

Abstract： The scattering of plane SH-waves by topographic features in a layered transversely isotropic （TI） half-space is investigated by using an indirect boundary element method （IBEM）. Firstly, the anti-plane dynamic stiffness matrix of the layered TI half-space is established and the free fields are solved by using the direct stiffness method. Then, Green＇s functions are derived for uniformly distributed loads acting on an inclined line in a layered TI half-space and the scattered fields are constructed with the deduced Green＇s functions. Finally, the free fields are added to the scattered ones to obtain the global dynamic responses. The method is verified by comparing results with the published isotropic ones. Both the steady-state and transient dynamic responses are evaluated and discussed. Numerical results in the frequency domain show that surface motions for the TI media can be significantly different from those for the isotropic case, which are strongly dependent on the anisotropy property, incident angle and incident frequency. Results in the time domain show that the material anisotropy has important effects on the maximum duration and maximum amplitudes of the time histories.

A methodology to determine the elastic properties of anisotropic rocks from a single uniaxial compression test

This paper introduces a new methodology to measure the elastic constants of transversely isotropic rocks from a single uniaxial compression test.We first give the mathematical proof that a uniaxial compression test provides only four independent strain equations.As a result,the exact determination of all five independent elastic constants from only one test is not possible.An approximate determination of the Young’s moduli and the Poisson’s ratios is however practical and efficient when adding the Saint-Venant relation as the fifth equation.Explicit formulae are then developed to calculate both secant and tangent definitions of the five elastic constants from a minimum of four strain measurements.The results of this new methodology applied on three granitic samples demonstrate a significant stress-induced nonlinear behavior,where the tangent moduli increase by a factor of three to four when the rock is loaded up to 20 MPa.The static elastic constants obtained from the uniaxial compression test are also found to be significantly smaller than the dynamic ones obtained from the ultrasonic measurements.

Nonlinear amplitude versus angle inversion for transversely isotropic media with vertical symmetry axis using new weak anisotropy approximation equations

In VTI media,the conventional inversion methods based on the existing approximation formulas are difficult to accurately estimate the anisotropic parameters of reservoirs,even more so for unconventional reservoirs with strong seismic anisotropy.Theoretically,the above problems can be solved by utilizing the exact reflection coefficients equations.However,their complicated expression increases the difficulty in calculating the Jacobian matrix when applying them to the Bayesian deterministic inversion.Therefore,the new reduced approximation equations starting from the exact equations are derived here by linearizing the slowness expressions.The relatively simple form and satisfactory calculation accuracy make the reduced equations easy to apply for inversion while ensuring the accuracy of the inversion results.In addition,the blockiness constraint,which follows the differentiable Laplace distribution,is added to the prior model to improve contrasts between layers.Then,the concept of GLI and an iterative reweighted least-squares algorithm is combined to solve the objective function.Lastly,we obtain the iterative solution expression of the elastic parameters and anisotropy parameters and achieve nonlinear AVA inversion based on the reduced equations.The test results of synthetic data and field data show that the proposed method can accurately obtain the VTI parameters from prestack AVA seismic data.

Recycle for Sludge Scrap of Nd-Fe-B Sintered Magnet as Isotropic Bonded Magnet

The reduction diffusion method was performed for the sludge scrap of Nd-Fe-B sintered magnets with adding Ca metal to recover the oxidized Nd-Fe-B phase. After washing the resultant powders to remove Ca metal component, the powders obtained were recycled as an isotropic magnetic powder by the melt spinning method. The magnetic properties of powders as recycled were inferior, especially for the coercivity value, due to the deletion of rare earth metals during the washing process. The adjustment of metal composition, i.e., the addition of Nd metal, at the melt spinning process improved the magnetic properties to be B r=～0.75 T, H cj=～0.93 mA·m -1, and (BH) max=～91 kJ·m -3. The magnetic properties of the bonded magnets prepared from the composition-adjusted powders were B r=～0.66 T, H cj=～0.92 mA·m -1, and (BH) max=～70 kJ·m -3, which are approximately comparable to the commercially available MQPB boned one (B r=～0.73 T, H cj=～0.79 mA·m -1, and (BH) max=～86 kJ·m -3).

Influence of polymer additives on turbulent energy cascading in forced homogeneous isotropic turbulence studied by direct numerical simulations

Direct numerical simulations （DNS） were performed for the forced homogeneous isotropic turbulence （FHIT） with/without polymer additives in order to elaborate the characteristics of the turbulent energy cascading influenced by drag-reducing effects. The finite elastic non-linear extensibility-Peterlin model （FENE-P） was used as the conformation tensor equation for the viscoelastic polymer solution. Detailed analyses of DNS data were carried out in this paper for the turbulence scaling law and the topological dynamics of FHIT as well as the important turbulent parameters, including turbulent kinetic energy spectra, enstrophy and strain, velocity structure function, small-scale intermittency, etc. A natural and straightforward definition for the drag reduction rate was also proposed for the drag-reducing FHIT based on the decrease degree of the turbulent kinetic energy. It was found that the turbulent energy cascading in the FHIT was greatly modified by the drag-reducing polymer additives. The enstrophy and the strain fields in the FH1T of the polymer solution were remarkably weakened as compared with their Newtonian counterparts. The small-scale vortices and the small-scale intermittency were all inhibited by the viscoelastic effects in the FHIT of the polymer solution. However, the scaling law in a fashion of extended self-similarity for the FHIT of the polymer solution, within the presently simulated range of Weissenberg numbers, had no distinct differences compared with that of the Newtonian fluid case.