Slug flow or high GVF(Gas Volume Fraction)conditions can cause pressure disturbance waves and alternating loads at the boundary of mechanical seals for multiphase pumps,endangering the safety of multiphase pump units....Slug flow or high GVF(Gas Volume Fraction)conditions can cause pressure disturbance waves and alternating loads at the boundary of mechanical seals for multiphase pumps,endangering the safety of multiphase pump units.The mechanical seal model is simplified by using periodic boundary conditions and numerical calculations are carried out based on the Zwart-Gerber-Belamri cavitation model.UDF(User Define Function)programs such as structural dynamics equations,alternating load equations,and pressure disturbance equations are embedded in numerical calculations,and the dynamic response characteristics of mechanical seal are studied using layered dynamic mesh technology.The results show that when the pressure disturbance occurs at the inlet,as the amplitude and period of the disturbance increase,the film thickness gradually decreases.And the fundamental reason for the hysteresis of the film thickness change is that the pressure in the high-pressure area cannot be restored in a timely manner.The maximum value of leakage and the minimum value of axial velocity are independent of the disturbance period and determined by the disturbance amplitude.The mutual interference between enhanced waves does not have a significant impact on the film thickness,while the front wave in the attenuated wave has a promoting effect on the subsequent film thickness changes,and the fluctuation of the liquid film cavitation rate and axial velocity under the attenuated wave condition deviates from the initial values.Compared with pressure disturbance conditions,alternating load conditions have a more significant impact on film thickness and leakage.During actual operation,it is necessary to avoid alternating load conditions in multiphase pump mechanical seals.展开更多
The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of ...The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of the liquid film inside the evaporator can significantly affect its evaporation capability.This work explores how change in shape of the liquid films affect the evaporation of the materials with non-Newtonian characteristics,achieved by changing the structure of the scraper.Examining the distribution of circumferential temperature,viscosity,and mass transfer of the flat liquid film shows that the film evaporates rapidly in shear-thinning region.Various wavy liquid films are developed by using shear-thinning theory,emphasizing the flow condition in the thinning area and the factors contributing to the exceptional evaporation capability.Further exploration is conducted on the spread patterns of the wavy liquid film and flat liquid film on the evaporation wall throughout the process.It is noted that breaking the wavy liquid film on the evaporating wall during evaporation is challenging due to its film-forming condition.For which the fundamental causes are demonstrated by acquiring the data regarding the flow rate and temperature of the liquid film.The definitive findings of the analysis reveal a significant improvement in the evaporation capability of the wavy liquid film.This enhancement is attributed to increasing the shear-thinning areas and maintaining the overall shape of the film throughout the entire evaporation process.展开更多
The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are ...The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are not clear. In the present study, a novel liquid film sensor is applied to measure the distributed signals of the liquid film in three-phase flow. Based on the liquid film signals, the liquid film characteristics including the structural characteristics and the nonlinear dynamics characteristics in three-phase flows are investigated for the first time. The structural characteristics including the proportion, the appearance frequency and the thickness of the liquid film are obtained and the influences of the liquid and gas superficial velocities and the oil content on them are investigated. To investigate the nonlinear dynamics characteristics of the liquid film with the changing flow conditions, the entropy analysis is introduced to successfully uncover and quantify the dynamic complexity of the liquid film behavior.展开更多
The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid...The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid films with different thicknesses were investigated using stereo microscopy and scanning electron microscopy(SEM).Meanwhile,the corrosion tendency and kinetics rule of metal plates after bias application were analyzed with the aid of electrochemical impedance spectroscopy(EIS)and scanning Kelvin probe(SKP).Results showed that under different humidity conditions,the amount of migrating corrosion products of silver for PCB-ImAg was limited,while on PCB-HASL both copper dendrites and precipitates such as sulfate and metal oxides of copper/tin were found under a high humidity condition(exceeding 85%).SKP results indicated that the cathode plate of two kinds of PCB materials had a higher corrosion tendency after bias application.An ECM model involving multi-metal reactions was proposed and the differences of ECM behaviors for two kinds of PCB materials were compared.展开更多
Structured packing is a good candidate for CO2 capture process because of its higher mass transfer efficiency and lower pressure drop. Now, the challenging problem of CO2 capture and storage demands more and more effi...Structured packing is a good candidate for CO2 capture process because of its higher mass transfer efficiency and lower pressure drop. Now, the challenging problem of CO2 capture and storage demands more and more efficiency equipment. The aim of the present study is to investigate the liquid film characteristics under counter current gas phase and throw some insight into the enhancing mechanism of mass transfer performance in structured packing. A high speed digital camera, non-intrusive measurement technique, was used. Water and air were working fluids. Experiments were carried out for different gas/liquid flow rates and different inclination angles. The time-average and instantaneous film widths for each set of flow parameters were calculated. It is shown that the effects of gas phase could be neglected for lower flow rate, and then, become more pronounced at higher flow rate. According to instantaneous film width, three different stages can be distinguished. One is the constant width of liquid film. The second is the slight decrease of film width and the smooth surface. This kind of character will lead to less interfacial area and deteriorate the packing mass transfer performance. For the third stage, the variation of film width shows clearly chaotic behavior. The prediction model was also developed in present work. The predicted and experimental results are in good agreement.展开更多
Knowledge of droplet dynamics provides the basis of predicting pressure drops, holdups and corrosion inhibitor distribution in multiphase flow. Droplet size and its distribution also determine the separation efficienc...Knowledge of droplet dynamics provides the basis of predicting pressure drops, holdups and corrosion inhibitor distribution in multiphase flow. Droplet size and its distribution also determine the separation efficiency between different phases. Experimental observations were conducted for droplet impingements with different fluids, droplet sizes and velocities, and film thicknesses. The observed transition boundaries were compared with the models developed by different authors. For impingement on a deep pool surface, the Marengo and Tropea correlation for splashing does not agree with the experimental results in this study. The Bai and Gosman critical Weber number for bouncing agrees with the water results but not the oil results. Three new correlations for transition boundaries between bouncing, coalescence, jetting and splashing were proposed and compared with the experimental observations.展开更多
Combined with the kinetic model of liquid film spreading, a new numerical method of solid-liquid-gas three-phase flow was developed for the moving of contact line, which was a hybrid method of computational fluid dyna...Combined with the kinetic model of liquid film spreading, a new numerical method of solid-liquid-gas three-phase flow was developed for the moving of contact line, which was a hybrid method of computational fluid dynamics and lattice Boltzmalm method (LBM). By taking the effect of molecule force in droplet and the wall surface on liquid film into account, the changing law of contact angle with different surface tensions was analyzed on glass and aluminum foil surfaces. Compared with experimental results, the standard deviation by using LBM is less than 0.5°, which validates the feasibility of LBM simulation on the dynamic process of liquid film spreading. In addition, oscillations are discovered both at the initial and end phases. The phenomenon of retraction is also found and the maximum retraction angle is 7.58°. The obtained result shows that the retraction is proved to be correlative with precursor film by tracking the volume change of liquid film contour. Furthermore, non-dimensional coefficient 2 is introduced to measure the liquid film retraction capacity.展开更多
Electrochemical measurement, optical microscopy, and scanning electron microscopy were employed to investigate the corrosion behavior of some low alloy steels. The steels were held under a thin liquid film of 0.5wt% N...Electrochemical measurement, optical microscopy, and scanning electron microscopy were employed to investigate the corrosion behavior of some low alloy steels. The steels were held under a thin liquid film of 0.5wt% NaCl aqueous solution. It is found that the steels with the same chemical composition but different micmstructures exhibit obviously different corrosion behaviors. However, the corrosion behavior of the steels with different compositions but the same microstructnres may be similar in the present investigation. The corrosion rate of bainite is slower than that of ferrite and pearlite. The corrosion products of bainite are uniform and fine. The size of carbon-rich phases produces a great impact on the corrosion of the steels, whether in the initial stage or in the long tenn. It is easy to induce large pitting for carbon-rich phases with large size, which damages the compactness of the rust layer.展开更多
The hydrodynamic study of the liquid film around Taylor bubbles in slug flow has great significance for understanding parallel flow and interaction between Taylor bubbles.The prediction models for liquid film thicknes...The hydrodynamic study of the liquid film around Taylor bubbles in slug flow has great significance for understanding parallel flow and interaction between Taylor bubbles.The prediction models for liquid film thickness mainly focus on stagnant flow,and some of them remain inaccurate performance.However,in the industrial process,the slug flow essentially is co-current flow.Therefore,in this paper,the liquid film thickness is studied by theoretical analysis and experimental methods under two conditions of stagnant and co-current flow.Firstly,under the condition of stagnant flow,the present work is based on Batchelor's theory,and modifies Batchelor's liquid film thickness model,which effectively improves its prediction accuracy.Under the condition of co-current flow,the prediction model of average liquid film thickness in slug flow is established by force and motion analysis.Taylor bubble length is introduced into the model as an important parameter.Dynamic experiments were carried out in the pipe with an inner diameter of 20 mm.The liquid film thickness,Taylor bubble velocity and length were measured by distributed ultrasonic sensor and intrusive cross-correlation conductivity sensor.Comparing the predicted value of the model with the measured results,the relative error is controlled within 10%.展开更多
Horizontal gas-liquid two-phase flows widely exist in chemical engineering,oil/gas production and other important industrial processes.Slug flow pattern is the main form of horizontal gas-liquid flows and characterize...Horizontal gas-liquid two-phase flows widely exist in chemical engineering,oil/gas production and other important industrial processes.Slug flow pattern is the main form of horizontal gas-liquid flows and characterized by intermittent motion of film region and slug region.This work aims to develop the ultrasonic Doppler method to realize the simultaneous measurement of the velocity profile and liquid film thickness of slug flow.A single-frequency single-channel transducer is adopted in the design of the field-programmable gate array based ultrasonic Doppler system.A multiple echo repetition technology is used to improve the temporal-spatial resolution for the velocity profile.An experiment of horizontal gas-liquid two-phase flow is implemented in an acrylic pipe with an inner diameter of 20 mm.Considering the aerated characteristics of the liquid slug,slug flow is divided into low-aerated slug flow,high-aerated slug flow and pseudo slug flow.The temporal-spatial velocity distributions of the three kinds of slug flows are reconstructed by using the ultrasonic velocity profile measurement.The evolution characteristics of the average velocity profile in slug flows are investigated.A novel method is proposed to derive the liquid film thickness based on the instantaneous velocity profile.The liquid film thickness can be effectively measured by detecting the position and the size of the bubbles nearly below the elongated gas bubble.Compared with the time of flight method,the film thickness measured by the Doppler system shows a higher accuracy as a bubble layer occurs in the film region.The effect of the gas distribution on the film thickness is uncovered in three kinds of slug flows.展开更多
The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative h...The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.展开更多
The proposed method is based on replacement of the unknown function by a truncated series of the shifted Legendre polynomial expansion. An approximate formula of the integer derivative is introduced. Special attention...The proposed method is based on replacement of the unknown function by a truncated series of the shifted Legendre polynomial expansion. An approximate formula of the integer derivative is introduced. Special attention is given to study the convergence analysis and derive an upper bound of the error for the presented approximate formula. The introduced method converts the proposed equation by means of collocation points to a system of algebraic equations with shifted Legendre coefficients. Thus, after solving this system of equations, the shifted Legendre coefficients are obtained. This efficient numerical method is used to solve the system of ordinary differential equations which describe the thin film flow and heat transfer with the effects of the thermal radiation, magnetic field, and slip velocity.展开更多
The heat transfer of hydrocarbon refrigerant across tube bundles have been widely used in refrigeration.Three-dimensional simulation model using volume of fluid(VOF) was presented to study the effects of tube shapes o...The heat transfer of hydrocarbon refrigerant across tube bundles have been widely used in refrigeration.Three-dimensional simulation model using volume of fluid(VOF) was presented to study the effects of tube shapes on flow pattern, film thickness and heat transfer of n-pentane across tube bundles, including circle, ellipse-shaped, egg-shaped and cam-shaped tube bundles. Simulation results agree well with experimental data in the literature. The liquid film thickness of sheet flow and heat transfer for different tube shapes were obtained numerically. The flow pattern transition occurs lower vapor quality for ellipse-shaped tube than other tube shapes. For sheet flow, the liquid film on circle tube and ellipseshaped tube is symmetrically distributed along the circumferential direction. However, the liquid film on egg-shaped tube at circumferential angles(θ) = 15°–60° is thicker than θ = 135°–165°. The liquid film on cam tube at θ = 15°–60° is slightly thinner than θ = 135°–165°. The liquid film thickness varies from thinner to thicker for ellipse-shaped, cam-shaped, egg-shape and circle within θ = 15°–60°. The effect of tube shape is insignificant on thin liquid film thickness. Ellipse-shaped tube has largest heat transfer coefficient for sheet flow. In practical engineering, the tube shape could be designed as ellipse to promote heat transfer.展开更多
The isothermal single-component multi-phase lattice Boltzmann method(LBM)combined with the particle motion model is used to simulate the detailed process of liquid film rupture induced by a single spherical particle.T...The isothermal single-component multi-phase lattice Boltzmann method(LBM)combined with the particle motion model is used to simulate the detailed process of liquid film rupture induced by a single spherical particle.The entire process of the liquid film rupture can be divided into two stages.In Stage 1,the particle contacts with the liquid film and moves into it due to the interfacial force and finally penetrates the liquid film.Then in Stage 2,the upper and lower liquid surfaces of the thin film are driven by the capillary force and approach to each other along the surface of the particle,resulting in a complete rupture.It is found that a hydrophobic particle with a contact angle of 106.7°shows the shortest rupture duration when the liquid film thickness is less than the particle radius.When the thickness of the liquid film is greater than the immersed depth of the particle at equilibrium,the time of liquid film rupture caused by a hydrophobic particle will be increased.On the other hand,a moderately hydrophilic particle can form a bridge in the middle of the liquid film to enhance the stability of the thin liquid film.展开更多
The impact of droplets on the liquid film is widely involved in industrial and agricultural fields.In recent years,plenty of works are limited to dry walls or stationary liquid films,and the research of multi-droplet ...The impact of droplets on the liquid film is widely involved in industrial and agricultural fields.In recent years,plenty of works are limited to dry walls or stationary liquid films,and the research of multi-droplet impact dynamic films is not sufficient.Based on this,this paper employs a coupled level set and volume of fluid(CLSVOF) method to numerically simulate two-droplet impingement on a dynamic liquid film.In our work,the dynamic film thickness,horizontal central distance between the droplets,droplets’ initial impact speed,and simultaneously the flow velocity of the moving film are analyzed.The evolution phenomenon and mechanism caused by the collision are analyzed in detail.We find that within a certain period of time,the droplet spacing does not affect the peripheral crown height;when the droplet spacing decreases or the initial impact velocity increases,the height of the peripheral crown increases at the beginning,and then,because the crown splashed under Rayleigh-Plateau instability,this results in the reduction of the crown height.At the same time,it is found that when the initial impact velocity increases,the angle between the upstream peripheral jet and the dynamic film becomes larger.The more obvious the horizontal movement characteristics,the more restrained the crown height;the spread length increases with the increase of the dynamic film speed,droplet spacing and the initial impact velocity.When the liquid film is thicker,more fluid enters the crown,due to the crown being unstable,the surface tension is not enough to overcome the weight of the rim at the end of the crown,resulting in droplets falling off.展开更多
The complex liquid film behaviors at flooding in an inclined pipe were investigated with computational fluid dynamic(CFD) approaches. The liquid film behaviors included the dynamic wave characteristics before flooding...The complex liquid film behaviors at flooding in an inclined pipe were investigated with computational fluid dynamic(CFD) approaches. The liquid film behaviors included the dynamic wave characteristics before flooding and the transition of flow pattern when flooding happened. The influences of the surface tension and liquid viscosity were specially analyzed. Comparisons of the calculated velocity at the onset of flooding with the available experimental results showed a good agreement. The calculations verify that the fluctuation frequency and the liquid film thickness are almost unaffected by the superficial gas velocity until the flooding is triggered due to the Kelvin–Helmholtz instability. When flooding triggered at the superficial liquid velocity larger than0.15 m·s-1, the interfacial wave developed to slug flow, while it developed to entrainment flow when it was smaller than 0.08 m·s-1. The interfacial waves were more easily torn into tiny droplets with smaller surface tension, eventually evolving into the mist flow. When the liquid viscosity increases, the liquid film has a thicker holdup with more intensive fluctuations, and more likely developed to the slug flow.展开更多
On account of limited knowledge of the breakup of power law liquid film, the process of its disintegration and atomization was studied by using a planar liquid film. A linear stability analysis was adopted to predict ...On account of limited knowledge of the breakup of power law liquid film, the process of its disintegration and atomization was studied by using a planar liquid film. A linear stability analysis was adopted to predict the breakup characteristics of the power law film. The predicting formulas of stripping breakup length and diameter of ligament were put forward presently. Through high-speed photography and laser light sheet illumination,different breakup characteristics of flat power law film under different conditions were derived. The characteristic dimension of breakup regimes were defined and extracted. The effects of several parameters(injection pressure,ambient pressure, nozzle structure and fluid property) on the stripping breakup length and spray angle were investigated. The results revealed that increasing both the velocity of liquid film and the ambient pressure facilitated the breakup of film, reduced the stripping breakup length and enlarged the spray angle in different extents. The comparison between theoretical and experimental results was conducted to validate the feasibility of the linear stability theory.展开更多
The flow of a freely falling liquid film of low Reynolds number down a vertical long periodic sine-shaped wavy plate of small corrugations is researched theoretically. A model based on perturbation method and power se...The flow of a freely falling liquid film of low Reynolds number down a vertical long periodic sine-shaped wavy plate of small corrugations is researched theoretically. A model based on perturbation method and power series is presented. A stream function is introduced into the governing equations and two sets of equations describing the film flow separately at zeroth and first order are developed. The zeroth order equation is solved directly. The first order equations is solved at the leading approximation. Effect of parameters Re, M, λ and ε on the free surface wave of film is discussed.展开更多
An approximate research on the flow of a two dimensional, steady laminar liquid film along a vertical, long periodic wavy wall is conducted based on boundary layer integration. An ordinary equation about the film evol...An approximate research on the flow of a two dimensional, steady laminar liquid film along a vertical, long periodic wavy wall is conducted based on boundary layer integration. An ordinary equation about the film evolution is derived. By analyzing the integral equation of the hydrodynamic boundary layer under different Reynolds number domains, the flow characteristics are studied preliminarily. Influences of wall waviness, flow rate on the film development are discussed.展开更多
Liquid film mulching is a new stage of agricultural mulching planting technology in China.In maize planting of arid area,liquid film mulching technology could improve physical-chemical properties,water content,tempera...Liquid film mulching is a new stage of agricultural mulching planting technology in China.In maize planting of arid area,liquid film mulching technology could improve physical-chemical properties,water content,temperature,water use efficiency and nutrient use efficiency of soil,thereby reaching the target of increasing yield and income.Meanwhile,it could decrease "white pollution",improve ecological environment of farmland,and realize good economic,social and ecological benefits.展开更多
基金the support of the National Natural Science Foundation of China(52372368)。
文摘Slug flow or high GVF(Gas Volume Fraction)conditions can cause pressure disturbance waves and alternating loads at the boundary of mechanical seals for multiphase pumps,endangering the safety of multiphase pump units.The mechanical seal model is simplified by using periodic boundary conditions and numerical calculations are carried out based on the Zwart-Gerber-Belamri cavitation model.UDF(User Define Function)programs such as structural dynamics equations,alternating load equations,and pressure disturbance equations are embedded in numerical calculations,and the dynamic response characteristics of mechanical seal are studied using layered dynamic mesh technology.The results show that when the pressure disturbance occurs at the inlet,as the amplitude and period of the disturbance increase,the film thickness gradually decreases.And the fundamental reason for the hysteresis of the film thickness change is that the pressure in the high-pressure area cannot be restored in a timely manner.The maximum value of leakage and the minimum value of axial velocity are independent of the disturbance period and determined by the disturbance amplitude.The mutual interference between enhanced waves does not have a significant impact on the film thickness,while the front wave in the attenuated wave has a promoting effect on the subsequent film thickness changes,and the fluctuation of the liquid film cavitation rate and axial velocity under the attenuated wave condition deviates from the initial values.Compared with pressure disturbance conditions,alternating load conditions have a more significant impact on film thickness and leakage.During actual operation,it is necessary to avoid alternating load conditions in multiphase pump mechanical seals.
基金supported by the National Natural Science Foundation of China (Grant Nos.52375172,52075093,and 51905089).
文摘The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of the liquid film inside the evaporator can significantly affect its evaporation capability.This work explores how change in shape of the liquid films affect the evaporation of the materials with non-Newtonian characteristics,achieved by changing the structure of the scraper.Examining the distribution of circumferential temperature,viscosity,and mass transfer of the flat liquid film shows that the film evaporates rapidly in shear-thinning region.Various wavy liquid films are developed by using shear-thinning theory,emphasizing the flow condition in the thinning area and the factors contributing to the exceptional evaporation capability.Further exploration is conducted on the spread patterns of the wavy liquid film and flat liquid film on the evaporation wall throughout the process.It is noted that breaking the wavy liquid film on the evaporating wall during evaporation is challenging due to its film-forming condition.For which the fundamental causes are demonstrated by acquiring the data regarding the flow rate and temperature of the liquid film.The definitive findings of the analysis reveal a significant improvement in the evaporation capability of the wavy liquid film.This enhancement is attributed to increasing the shear-thinning areas and maintaining the overall shape of the film throughout the entire evaporation process.
基金supported by the National Natural Science Foundation of China (42074142, 51527805, 41974139)China Postdoctoral Science Foundation (2020M680969, 2021T140099)the Fundamental Research Funds for the Central Universities (N2104013)。
文摘The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are not clear. In the present study, a novel liquid film sensor is applied to measure the distributed signals of the liquid film in three-phase flow. Based on the liquid film signals, the liquid film characteristics including the structural characteristics and the nonlinear dynamics characteristics in three-phase flows are investigated for the first time. The structural characteristics including the proportion, the appearance frequency and the thickness of the liquid film are obtained and the influences of the liquid and gas superficial velocities and the oil content on them are investigated. To investigate the nonlinear dynamics characteristics of the liquid film with the changing flow conditions, the entropy analysis is introduced to successfully uncover and quantify the dynamic complexity of the liquid film behavior.
基金Project(51271032)supported by the National Natural Science Foundation of China
文摘The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid films with different thicknesses were investigated using stereo microscopy and scanning electron microscopy(SEM).Meanwhile,the corrosion tendency and kinetics rule of metal plates after bias application were analyzed with the aid of electrochemical impedance spectroscopy(EIS)and scanning Kelvin probe(SKP).Results showed that under different humidity conditions,the amount of migrating corrosion products of silver for PCB-ImAg was limited,while on PCB-HASL both copper dendrites and precipitates such as sulfate and metal oxides of copper/tin were found under a high humidity condition(exceeding 85%).SKP results indicated that the cathode plate of two kinds of PCB materials had a higher corrosion tendency after bias application.An ECM model involving multi-metal reactions was proposed and the differences of ECM behaviors for two kinds of PCB materials were compared.
基金Supported by the National Natural Science Foundation of China (20070003154), the National High Technology Research and Development Program of China (2006AA05Z316, 2006AA030202), the Specialized Research Fund for Doctoral Program of Higher Education of China (20070003154), and the Key Program for International Cooperation of Science and Technology, China (2001CB711203).
文摘Structured packing is a good candidate for CO2 capture process because of its higher mass transfer efficiency and lower pressure drop. Now, the challenging problem of CO2 capture and storage demands more and more efficiency equipment. The aim of the present study is to investigate the liquid film characteristics under counter current gas phase and throw some insight into the enhancing mechanism of mass transfer performance in structured packing. A high speed digital camera, non-intrusive measurement technique, was used. Water and air were working fluids. Experiments were carried out for different gas/liquid flow rates and different inclination angles. The time-average and instantaneous film widths for each set of flow parameters were calculated. It is shown that the effects of gas phase could be neglected for lower flow rate, and then, become more pronounced at higher flow rate. According to instantaneous film width, three different stages can be distinguished. One is the constant width of liquid film. The second is the slight decrease of film width and the smooth surface. This kind of character will lead to less interfacial area and deteriorate the packing mass transfer performance. For the third stage, the variation of film width shows clearly chaotic behavior. The prediction model was also developed in present work. The predicted and experimental results are in good agreement.
文摘Knowledge of droplet dynamics provides the basis of predicting pressure drops, holdups and corrosion inhibitor distribution in multiphase flow. Droplet size and its distribution also determine the separation efficiency between different phases. Experimental observations were conducted for droplet impingements with different fluids, droplet sizes and velocities, and film thicknesses. The observed transition boundaries were compared with the models developed by different authors. For impingement on a deep pool surface, the Marengo and Tropea correlation for splashing does not agree with the experimental results in this study. The Bai and Gosman critical Weber number for bouncing agrees with the water results but not the oil results. Three new correlations for transition boundaries between bouncing, coalescence, jetting and splashing were proposed and compared with the experimental observations.
基金Project(U1261107)supported by the National Natural Science Foundation of China
文摘Combined with the kinetic model of liquid film spreading, a new numerical method of solid-liquid-gas three-phase flow was developed for the moving of contact line, which was a hybrid method of computational fluid dynamics and lattice Boltzmalm method (LBM). By taking the effect of molecule force in droplet and the wall surface on liquid film into account, the changing law of contact angle with different surface tensions was analyzed on glass and aluminum foil surfaces. Compared with experimental results, the standard deviation by using LBM is less than 0.5°, which validates the feasibility of LBM simulation on the dynamic process of liquid film spreading. In addition, oscillations are discovered both at the initial and end phases. The phenomenon of retraction is also found and the maximum retraction angle is 7.58°. The obtained result shows that the retraction is proved to be correlative with precursor film by tracking the volume change of liquid film contour. Furthermore, non-dimensional coefficient 2 is introduced to measure the liquid film retraction capacity.
基金supported by the Major State Basic Research and Development Program of China (No.2004CB619102)
文摘Electrochemical measurement, optical microscopy, and scanning electron microscopy were employed to investigate the corrosion behavior of some low alloy steels. The steels were held under a thin liquid film of 0.5wt% NaCl aqueous solution. It is found that the steels with the same chemical composition but different micmstructures exhibit obviously different corrosion behaviors. However, the corrosion behavior of the steels with different compositions but the same microstructnres may be similar in the present investigation. The corrosion rate of bainite is slower than that of ferrite and pearlite. The corrosion products of bainite are uniform and fine. The size of carbon-rich phases produces a great impact on the corrosion of the steels, whether in the initial stage or in the long tenn. It is easy to induce large pitting for carbon-rich phases with large size, which damages the compactness of the rust layer.
基金supported by National Natural Science Foundation of China(42074142,51527805)。
文摘The hydrodynamic study of the liquid film around Taylor bubbles in slug flow has great significance for understanding parallel flow and interaction between Taylor bubbles.The prediction models for liquid film thickness mainly focus on stagnant flow,and some of them remain inaccurate performance.However,in the industrial process,the slug flow essentially is co-current flow.Therefore,in this paper,the liquid film thickness is studied by theoretical analysis and experimental methods under two conditions of stagnant and co-current flow.Firstly,under the condition of stagnant flow,the present work is based on Batchelor's theory,and modifies Batchelor's liquid film thickness model,which effectively improves its prediction accuracy.Under the condition of co-current flow,the prediction model of average liquid film thickness in slug flow is established by force and motion analysis.Taylor bubble length is introduced into the model as an important parameter.Dynamic experiments were carried out in the pipe with an inner diameter of 20 mm.The liquid film thickness,Taylor bubble velocity and length were measured by distributed ultrasonic sensor and intrusive cross-correlation conductivity sensor.Comparing the predicted value of the model with the measured results,the relative error is controlled within 10%.
基金supported by the National Natural Science Foundation of China(41974139,42274148,42074142)。
文摘Horizontal gas-liquid two-phase flows widely exist in chemical engineering,oil/gas production and other important industrial processes.Slug flow pattern is the main form of horizontal gas-liquid flows and characterized by intermittent motion of film region and slug region.This work aims to develop the ultrasonic Doppler method to realize the simultaneous measurement of the velocity profile and liquid film thickness of slug flow.A single-frequency single-channel transducer is adopted in the design of the field-programmable gate array based ultrasonic Doppler system.A multiple echo repetition technology is used to improve the temporal-spatial resolution for the velocity profile.An experiment of horizontal gas-liquid two-phase flow is implemented in an acrylic pipe with an inner diameter of 20 mm.Considering the aerated characteristics of the liquid slug,slug flow is divided into low-aerated slug flow,high-aerated slug flow and pseudo slug flow.The temporal-spatial velocity distributions of the three kinds of slug flows are reconstructed by using the ultrasonic velocity profile measurement.The evolution characteristics of the average velocity profile in slug flows are investigated.A novel method is proposed to derive the liquid film thickness based on the instantaneous velocity profile.The liquid film thickness can be effectively measured by detecting the position and the size of the bubbles nearly below the elongated gas bubble.Compared with the time of flight method,the film thickness measured by the Doppler system shows a higher accuracy as a bubble layer occurs in the film region.The effect of the gas distribution on the film thickness is uncovered in three kinds of slug flows.
基金Supported by the National Natural Science Foundation of China (No. 59995550-3) and Science Funds from the Ministry of Education (No. 97000357).
文摘The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.
文摘The proposed method is based on replacement of the unknown function by a truncated series of the shifted Legendre polynomial expansion. An approximate formula of the integer derivative is introduced. Special attention is given to study the convergence analysis and derive an upper bound of the error for the presented approximate formula. The introduced method converts the proposed equation by means of collocation points to a system of algebraic equations with shifted Legendre coefficients. Thus, after solving this system of equations, the shifted Legendre coefficients are obtained. This efficient numerical method is used to solve the system of ordinary differential equations which describe the thin film flow and heat transfer with the effects of the thermal radiation, magnetic field, and slip velocity.
基金supported by National Natural Science Foundation of China (52006242)National Natural Science Foundation of China (52192623)+1 种基金Science Foundation of China University of Petroleum,Beijing (ZX20200126)Science and technology program for strategic cooperation of CNPC–China University of Petroleum (ZLZX2020-05)。
文摘The heat transfer of hydrocarbon refrigerant across tube bundles have been widely used in refrigeration.Three-dimensional simulation model using volume of fluid(VOF) was presented to study the effects of tube shapes on flow pattern, film thickness and heat transfer of n-pentane across tube bundles, including circle, ellipse-shaped, egg-shaped and cam-shaped tube bundles. Simulation results agree well with experimental data in the literature. The liquid film thickness of sheet flow and heat transfer for different tube shapes were obtained numerically. The flow pattern transition occurs lower vapor quality for ellipse-shaped tube than other tube shapes. For sheet flow, the liquid film on circle tube and ellipseshaped tube is symmetrically distributed along the circumferential direction. However, the liquid film on egg-shaped tube at circumferential angles(θ) = 15°–60° is thicker than θ = 135°–165°. The liquid film on cam tube at θ = 15°–60° is slightly thinner than θ = 135°–165°. The liquid film thickness varies from thinner to thicker for ellipse-shaped, cam-shaped, egg-shape and circle within θ = 15°–60°. The effect of tube shape is insignificant on thin liquid film thickness. Ellipse-shaped tube has largest heat transfer coefficient for sheet flow. In practical engineering, the tube shape could be designed as ellipse to promote heat transfer.
基金supported by the National Key Technologies Research and Development(R&D)Program by the Ministry of Science and Technology of China(No.2017YFB0406100)the National Natural Science Foundation of China(No.51676123)。
文摘The isothermal single-component multi-phase lattice Boltzmann method(LBM)combined with the particle motion model is used to simulate the detailed process of liquid film rupture induced by a single spherical particle.The entire process of the liquid film rupture can be divided into two stages.In Stage 1,the particle contacts with the liquid film and moves into it due to the interfacial force and finally penetrates the liquid film.Then in Stage 2,the upper and lower liquid surfaces of the thin film are driven by the capillary force and approach to each other along the surface of the particle,resulting in a complete rupture.It is found that a hydrophobic particle with a contact angle of 106.7°shows the shortest rupture duration when the liquid film thickness is less than the particle radius.When the thickness of the liquid film is greater than the immersed depth of the particle at equilibrium,the time of liquid film rupture caused by a hydrophobic particle will be increased.On the other hand,a moderately hydrophilic particle can form a bridge in the middle of the liquid film to enhance the stability of the thin liquid film.
基金Project supported by the Engineering Research Center of Eco-environment in the Three Gorges Reservoir Region(Grant No.KF2019-10)。
文摘The impact of droplets on the liquid film is widely involved in industrial and agricultural fields.In recent years,plenty of works are limited to dry walls or stationary liquid films,and the research of multi-droplet impact dynamic films is not sufficient.Based on this,this paper employs a coupled level set and volume of fluid(CLSVOF) method to numerically simulate two-droplet impingement on a dynamic liquid film.In our work,the dynamic film thickness,horizontal central distance between the droplets,droplets’ initial impact speed,and simultaneously the flow velocity of the moving film are analyzed.The evolution phenomenon and mechanism caused by the collision are analyzed in detail.We find that within a certain period of time,the droplet spacing does not affect the peripheral crown height;when the droplet spacing decreases or the initial impact velocity increases,the height of the peripheral crown increases at the beginning,and then,because the crown splashed under Rayleigh-Plateau instability,this results in the reduction of the crown height.At the same time,it is found that when the initial impact velocity increases,the angle between the upstream peripheral jet and the dynamic film becomes larger.The more obvious the horizontal movement characteristics,the more restrained the crown height;the spread length increases with the increase of the dynamic film speed,droplet spacing and the initial impact velocity.When the liquid film is thicker,more fluid enters the crown,due to the crown being unstable,the surface tension is not enough to overcome the weight of the rim at the end of the crown,resulting in droplets falling off.
基金Supported by the Major State Basic Research Development Program of China(2011CB706501)the National Natural Science Foundation of China(51276157)
文摘The complex liquid film behaviors at flooding in an inclined pipe were investigated with computational fluid dynamic(CFD) approaches. The liquid film behaviors included the dynamic wave characteristics before flooding and the transition of flow pattern when flooding happened. The influences of the surface tension and liquid viscosity were specially analyzed. Comparisons of the calculated velocity at the onset of flooding with the available experimental results showed a good agreement. The calculations verify that the fluctuation frequency and the liquid film thickness are almost unaffected by the superficial gas velocity until the flooding is triggered due to the Kelvin–Helmholtz instability. When flooding triggered at the superficial liquid velocity larger than0.15 m·s-1, the interfacial wave developed to slug flow, while it developed to entrainment flow when it was smaller than 0.08 m·s-1. The interfacial waves were more easily torn into tiny droplets with smaller surface tension, eventually evolving into the mist flow. When the liquid viscosity increases, the liquid film has a thicker holdup with more intensive fluctuations, and more likely developed to the slug flow.
基金Supported by the National Natural Science Foundation of China(11172205,11372219,51176137)
文摘On account of limited knowledge of the breakup of power law liquid film, the process of its disintegration and atomization was studied by using a planar liquid film. A linear stability analysis was adopted to predict the breakup characteristics of the power law film. The predicting formulas of stripping breakup length and diameter of ligament were put forward presently. Through high-speed photography and laser light sheet illumination,different breakup characteristics of flat power law film under different conditions were derived. The characteristic dimension of breakup regimes were defined and extracted. The effects of several parameters(injection pressure,ambient pressure, nozzle structure and fluid property) on the stripping breakup length and spray angle were investigated. The results revealed that increasing both the velocity of liquid film and the ambient pressure facilitated the breakup of film, reduced the stripping breakup length and enlarged the spray angle in different extents. The comparison between theoretical and experimental results was conducted to validate the feasibility of the linear stability theory.
基金Acknowledgement: This work is supported by Natural Science Foundation of Tianjin of China (No. 07JCYBJC01300).
文摘The flow of a freely falling liquid film of low Reynolds number down a vertical long periodic sine-shaped wavy plate of small corrugations is researched theoretically. A model based on perturbation method and power series is presented. A stream function is introduced into the governing equations and two sets of equations describing the film flow separately at zeroth and first order are developed. The zeroth order equation is solved directly. The first order equations is solved at the leading approximation. Effect of parameters Re, M, λ and ε on the free surface wave of film is discussed.
文摘An approximate research on the flow of a two dimensional, steady laminar liquid film along a vertical, long periodic wavy wall is conducted based on boundary layer integration. An ordinary equation about the film evolution is derived. By analyzing the integral equation of the hydrodynamic boundary layer under different Reynolds number domains, the flow characteristics are studied preliminarily. Influences of wall waviness, flow rate on the film development are discussed.
基金Supported by Water Conservancy Science and Technology Project in Shanxi Province(201427,2015 STBC3,Jinshuicaiwu[2019]110)
文摘Liquid film mulching is a new stage of agricultural mulching planting technology in China.In maize planting of arid area,liquid film mulching technology could improve physical-chemical properties,water content,temperature,water use efficiency and nutrient use efficiency of soil,thereby reaching the target of increasing yield and income.Meanwhile,it could decrease "white pollution",improve ecological environment of farmland,and realize good economic,social and ecological benefits.