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酸分馏效应对GasBench-IRMS测定碳酸盐碳、氧同位素的影响
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作者 王楠 赵彦彦 田有荣 《质谱学报》 EI CAS CSCD 北大核心 2024年第3期401-411,I0004,共12页
本文利用在线制样装置(GasBench)和稳定同位素比质谱仪(IRMS)测试一系列碳酸盐标准物质和现代海洋浮游有孔虫样品,在不同测试条件下,分析不同性状碳酸盐矿物的氧同位素分馏程度,计算氧同位素酸分馏系数,探讨酸分馏效应对不同碳酸盐矿物... 本文利用在线制样装置(GasBench)和稳定同位素比质谱仪(IRMS)测试一系列碳酸盐标准物质和现代海洋浮游有孔虫样品,在不同测试条件下,分析不同性状碳酸盐矿物的氧同位素分馏程度,计算氧同位素酸分馏系数,探讨酸分馏效应对不同碳酸盐矿物氧同位素测定的影响机制和控制因素,以及对氧同位素测试值(δ^(18)O_(m))的校正方法。结果表明,酸分馏效应对氧同位素值的影响主要是由于生成的CO_(2)气体与顶空瓶中气态水(高温时主要影响)或酸中游离态自由水(低温时主要影响)之间发生氧同位素交换引起的。不同性状碳酸盐标准物质的氧同位素酸分馏系数具有显著差异,且与氧同位素组成相关。δ^(18)O_(m)值发生偏移的程度与反应温度、样品量、磷酸含水量以及酸中游离态和气态水的氧同位素组成与样品氧同位素组成之间的差异等因素有关。氧同位素酸分馏效应与信号强度具有显著相关性。建议精确称量相同质量的标准物质和样品,遵循信号强度匹配的原则,并采用多种标准物质线性校正的方法有效校正氧同位素分馏现象。在较低的反应温度(25℃)下,氧同位素分馏程度较轻微,δ^(18)O分析精度更高,优于0.05‰。本方法为精确测定碳酸盐中碳、氧同位素组成提供了参考,可有效提高相关的测试精度。 展开更多
关键词 在线制样装置-稳定同位素比质谱仪(GasBench-irmS) 磷酸法 碳酸盐 氧同位素 酸分馏效应
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Molecular dynamics simulation of the flow mechanism of shear-thinning fluids in a microchannel
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作者 杨刚 郑庭 +1 位作者 程启昊 张会臣 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期516-525,共10页
Shear-thinning fluids have been widely used in microfluidic systems,but their internal flow mechanism is still unclear.Therefore,in this paper,molecular dynamics simulations are used to study the laminar flow of shear... Shear-thinning fluids have been widely used in microfluidic systems,but their internal flow mechanism is still unclear.Therefore,in this paper,molecular dynamics simulations are used to study the laminar flow of shear-thinning fluid in a microchannel.We validated the feasibility of our simulation method by evaluating the mean square displacement and Reynolds number of the solution layers.The results show that the change rule of the fluid system's velocity profile and interaction energy can reflect the shear-thinning characteristics of the fluids.The velocity profile resembles a top-hat shape,intensifying as the fluid's power law index decreases.The interaction energy between the wall and the fluid decreases gradually with increasing velocity,and a high concentration of non-Newtonian fluid reaches a plateau sooner.Moreover,the velocity profile of the fluid is related to the molecule number density distribution and their values are inversely proportional.By analyzing the radial distribution function,we found that the hydrogen bonds between solute and water molecules weaken with the increase in velocity.This observation offers an explanation for the shear-thinning phenomenon of the non-Newtonian flow from a micro perspective. 展开更多
关键词 molecular dynamics simulation non-Newtonian fluid microchannel SHEAR-THINNING
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Microchannel reactive distillation for the conversion of aqueous ethanol to ethylene
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作者 Johnny Saavedra-Lopez Stephen D.Davidson +6 位作者 Paul H.Humble Dan R.Bottenus Vanessa Lebarbier Dagle Yuan Jiang Charles J.Freeman Ward E.Te Grotenhuis Robert A.Dagle 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第11期481-493,共13页
Here we demonstrate the proof-of-concept for microchannel reactive distillation for alcohol-to-jet application:combining ethanol/water separation and ethanol dehydration in one unit operation.Ethanol is first distille... Here we demonstrate the proof-of-concept for microchannel reactive distillation for alcohol-to-jet application:combining ethanol/water separation and ethanol dehydration in one unit operation.Ethanol is first distilled into the vapor phase,converted to ethylene and water,and then the water co-product is condensed to shift the reaction equilibrium.Process intensification is achieved through rapid mass transfer-ethanol stripping from thin wicks using novel microchannel architectures-leading to lower residence time and improved separation efficiency.Energy savings are realized with integration of unit operations.For example,heat of condensing water can offset vaporizing ethanol.Furthermore,the dehydration reaction equilibrium shifts towards completion by immediate removal of the water byproduct upon formation while maintaining aqueous feedstock in the condensed phase.For aqueous ethanol feedstock(40%_w),71% ethanol conversion with 91% selectivity to ethylene was demonstrated at 220℃,600psig,and 0.28 h^(-1) wt hour space velocity.2.7 stages of separation were also demonstrated,under these conditions,using a device length of 8.3 cm.This provides a height equivalent of a theoretical plate(HETP),a measure of separation efficiency,of ^(3).3 cm.By comparison,conventional distillation packing provides an HETP of ^(3)0 cm.Thus,9,1 × reduction in HETP was demonstrated over conventional technology,providing a means for significant energy savings and an example of process intensification.Finally,preliminary process economic analysis indicates that by using microchannel reactive distillation technology,the operating and capital costs for the ethanol separation and dehydration portion of an envisioned alcoholto-jet process could be reduced by at least 35% and 55%,respectively,relative to the incumbent technology,provided future improvements to microchannel reactive distillation design and operability are made. 展开更多
关键词 Catalytic distillation Ethanol dehydration Process intensification microchannel Alcohol-to-jet process
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Overall Assessment of Heat Transfer for a Rarefied Flow in a Microchannel with Obstacles Using Lattice Boltzmann Method
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作者 Siham Hammid Khatir Naima +7 位作者 Omolayo M.Ikumapayi Cheikh Kezrane Abdelkrim Liazid Jihad Asad Mokdad Hayawi Rahman Farhan Lafta Rashid Naseer Ali Hussien Younes Menni 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期273-299,共27页
The objective of this investigation is to assess the effect of obstacles on numerical heat transfer and fluid flow momentum in a rectangular microchannel(MC).Two distinct configurations were studied:one without obstac... The objective of this investigation is to assess the effect of obstacles on numerical heat transfer and fluid flow momentum in a rectangular microchannel(MC).Two distinct configurations were studied:one without obstacles and the other with alternating obstacles placed on the upper and lower walls.The research utilized the thermal lattice Boltzmann method(LBM),which solves the energy and momentum equations of fluids with the BGK approximation,implemented in a Python coding environment.Temperature jump and slip velocity conditions were utilized in the simulation for the MC and extended to all obstacle boundaries.The study aims to analyze the rarefaction effect,with Knudsen numbers(Kn)of 0.012,0.02,and 0.05.The outcomes indicate that rarefaction has a significant impact on the velocity and temperature distribution.The presence of nine obstacles led to slower fluid movement inside the microchannel MC,resulting in faster cooling at the outlet.In MCs with obstacles,the rarefaction effect plays a crucial role in decreasing the Nusselt number(Nu)and skin friction coefficient(Cf).Furthermore,the study demonstrated that the obstacles played a crucial role in boosting fluid flow and heat transfer in the MC.The findings suggest that the examined configurations could have potential applications as cooling technologies in micro-electro-mechanical systems and microdevice applications. 展开更多
关键词 MICROFLUID rarefied flow LBM microchannel Knudsen number numerical simulation
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Effect of boundary slip on electroosmotic flow in a curved rectangular microchannel
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作者 刘勇波 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第7期303-309,共7页
The aim of this study is to numerically investigate the impact of boundary slip on electroosmotic flow(EOF) in curved rectangular microchannels. Navier slip boundary conditions were employed at the curved microchannel... The aim of this study is to numerically investigate the impact of boundary slip on electroosmotic flow(EOF) in curved rectangular microchannels. Navier slip boundary conditions were employed at the curved microchannel walls. The electric potential distribution was governed by the Poisson–Boltzmann equation, whereas the velocity distribution was determined by the Navier–Stokes equation. The finite-difference method was employed to solve these two equations. The detailed discussion focuses on the impact of the curvature ratio, electrokinetic width, aspect ratio and slip length on the velocity. The results indicate that the present problem is strongly dependent on these parameters. The results demonstrate that by varying the dimensionless slip length from 0.001 to 0.01 while maintaining a curvature ratio of 0.5 there is a twofold increase in the maximum velocity. Moreover, this increase becomes more pronounced at higher curvature ratios. In addition, the velocity difference between the inner and outer radial regions increases with increasing slip length. Therefore, the incorporation of the slip boundary condition results in an augmented velocity and a more non-uniform velocity distribution. The findings presented here offer valuable insights into the design and optimization of EOF performance in curved hydrophobic microchannels featuring rectangular cross-sections. 展开更多
关键词 electroosmotic flow(EOF) curved rectangular microchannels slip boundary conditions
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Numerical Simulation of Droplet Generation in Coaxial Microchannels
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作者 Zongjun Yin Rong Su Hui Xu 《Fluid Dynamics & Materials Processing》 EI 2024年第3期487-504,共18页
In this study,numerical simulations of the pinching-off phenomena displayed by the dispersed phase in a continuous phase have been conducted using COMSOL Multiphysics(level-set method).Four flow patterns,namely“drop ... In this study,numerical simulations of the pinching-off phenomena displayed by the dispersed phase in a continuous phase have been conducted using COMSOL Multiphysics(level-set method).Four flow patterns,namely“drop flow”,“jet flow”,“squeeze flow”,and“co-flow”,have been obtained for different flow velocity ratios,channel diameter ratios,density ratios,viscosity ratios,and surface tension.The flow pattern map of two-phase flow in coaxial microchannels has been obtained accordingly,and the associated droplet generation process has been critically discussed considering the related frequency,diameter,and pinch-off length.In particular,it is shown that the larger the flow velocity ratio,the smaller the diameter of generated droplets and the shorter the pinch-off length.The pinch-off length of a droplet is influenced by the channel diameter ratio and density ratio.The changes in viscosity ratio have a negligible influence on the droplet generation pinching frequency.With an increase in surface tension,the frequency of generation and pinch-off length of droplets decrease,but for small surface tension the generation diameter of droplet increases. 展开更多
关键词 Droplet generation characteristics coaxial microchannels flow patterns pinch-off length
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Gas microchannel plate-pixel detector for X-ray polarimetry
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作者 Huan-Bo Feng Hong-Bang Liu +16 位作者 Dong Wang Zi-Li Li Shu-Lin Liu Qian Liu Hang-Zhou Li Bin-Long Wang Yan-Jun Xie Zong-Wang Fan Hui Wang Ran Chen Di-Fan Yi Rui-Ting Ma Fei Xie Bo Peng Xiang-Ming Sun Jin Li En-Wei Liang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期60-73,共14页
POLAR-2 is a gamma-ray burst(GRB)polarimeter that is designed to study the polarization in GRB radiation emissions,aiming to improve our knowledge of related mechanisms.POLAR-2 is expected to utilize an on-board polar... POLAR-2 is a gamma-ray burst(GRB)polarimeter that is designed to study the polarization in GRB radiation emissions,aiming to improve our knowledge of related mechanisms.POLAR-2 is expected to utilize an on-board polarimeter that is sensitive to soft X-rays(2-10 keV),called low-energy polarization detector.We have developed a new soft X-ray polari-zation detector prototype based on gas microchannel plates(GMCPs)and pixel chips(Topmetal).The GMCPs have bulk resistance,which prevents charging-up effects and ensures gain stability during operation.The detector is composed of low outgassing materials and is gas-sealed using a laser welding technique,ensuring long-term stability.A modulation factor of 41.28%±0.64% is obtained for a 4.5 keV polarized X-ray beam.A residual modulation of 1.96%±0.58% at 5.9 keV is observed for the entire sensitive area. 展开更多
关键词 X-ray polarimetry Gas microchannel plate-pixel detector Gamma-ray bursts
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Applying the Shearlet-Based Complexity Measure for Analyzing Mass Transfer in Continuous-Flow Microchannels
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作者 Elena Mosheva Ivan Krasnyakov 《Fluid Dynamics & Materials Processing》 EI 2024年第8期1743-1758,共16页
Continuous-flow microchannels are widely employed for synthesizing various materials,including nanoparticles,polymers,and metal-organic frameworks(MOFs),to name a few.Microsystem technology allows precise control over... Continuous-flow microchannels are widely employed for synthesizing various materials,including nanoparticles,polymers,and metal-organic frameworks(MOFs),to name a few.Microsystem technology allows precise control over reaction parameters,resulting in purer,more uniform,and structurally stable products due to more effective mass transfer manipulation.However,continuous-flow synthesis processes may be accompanied by the emergence of spatial convective structures initiating convective flows.On the one hand,convection can accelerate reactions by intensifying mass transfer.On the other hand,it may lead to non-uniformity in the final product or defects,especially in MOF microcrystal synthesis.The ability to distinguish regions of convective and diffusive mass transfer may be the key to performing higher-quality reactions and obtaining purer products.In this study,we investigate,for the first time,the possibility of using the information complexity measure as a criterion for assessing the intensity of mass transfer in microchannels,considering both spatial and temporal non-uniformities of liquid’s distributions resulting from convection formation.We calculate the complexity using shearlet transform based on a local approach.In contrast to existing methods for calculating complexity,the shearlet transform based approach provides a more detailed representation of local heterogeneities.Our analysis involves experimental images illustrating the mixing process of two non-reactive liquids in a Y-type continuous-flow microchannel under conditions of double-diffusive convection formation.The obtained complexity fields characterize the mixing process and structure formation,revealing variations in mass transfer intensity along the microchannel.We compare the results with cases of liquid mixing via a pure diffusive mechanism.Upon analysis,it was revealed that the complexity measure exhibits sensitivity to variations in the type of mass transfer,establishing its feasibility as an indirect criterion for assessing mass transfer intensity.The method presented can extend beyond flow analysis,finding application in the controlling of microstructures of various materials(porosity,for instance)or surface defects in metals,optical systems and other materials that hold significant relevance in materials science and engineering. 展开更多
关键词 Shearlet analysis complexity measure entropy measure CONVECTION microchannels double-diffusive instability
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A comprehensive review on microchannel heat sinks for electronics cooling
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作者 Zhi-Qiang Yu Mo-Tong Li Bing-Yang Cao 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第2期133-162,共30页
The heat generation of electronic devices is increasing dramatically,which causes a serious bottleneck in the thermal management of electronics,and overheating will result in performance deterioration and even device ... The heat generation of electronic devices is increasing dramatically,which causes a serious bottleneck in the thermal management of electronics,and overheating will result in performance deterioration and even device damage.With the development of micro-machining technologies,the microchannel heat sink(MCHS)has become one of the best ways to remove the considerable amount of heat generated by high-power electronics.It has the advantages of large specific surface area,small size,coolant saving and high heat transfer coefficient.This paper comprehensively takes an overview of the research progress in MCHSs and generalizes the hotspots and bottlenecks of this area.The heat transfer mechanisms and performances of different channel structures,coolants,channel materials and some other influencing factors are reviewed.Additionally,this paper classifies the heat transfer enhancement technology and reviews the related studies on both the single-phase and phase-change flow and heat transfer.The comprehensive review is expected to provide a theoretical reference and technical guidance for further research and application of MCHSs in the future. 展开更多
关键词 microchannel heat sink thermal management of electronics microscale heat transfer heat transfer enhancement
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Effect of the Geometrical Parameter of OpenMicrochannel on Pool Boiling Enhancement
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作者 Ali M.H.Al-Obaidy Ekhlas M.Fayyadh Amer M.Al-Dabagh 《Frontiers in Heat and Mass Transfer》 EI 2024年第5期1421-1442,共22页
High heat dissipation is required for miniaturization and increasing the power of electronic systems.Pool boiling is a promising option for achieving efficient heat dissipation at low wall superheat without the need f... High heat dissipation is required for miniaturization and increasing the power of electronic systems.Pool boiling is a promising option for achieving efficient heat dissipation at low wall superheat without the need for moving parts.Many studies have focused on improving heat transfer efficiency during boiling by modifying the surface of the heating element.This paper presents an experimental investigation on improving pool boiling heat transfer using an open microchannel.The primary goal of this work is to investigate the impact of the channel geometry characteristics on boiling heat transfer.Initially,rectangular microchannels were prepared on a circular copper test piece with a diameter of 20 mm.Then,the boiling characteristics of these microchannels were compared with those of a smooth surface under saturated conditions using deionized water.In this investigation,a wire-cutting electrical discharge machine(EDM)machine was used to produce parallel microchannels with channel widths of 0.2,0.4,and 0.8 mm.The fin thicknesses were 0.2,0.4,and 0.6 mm,while the channel depth remained constant at 0.4 mm.The results manifested that the surface featuring narrower fins and broader channels achieved superior performance.The heat transfer coefficient(HTC)was enhanced by a maximum of 248%,and the critical heat flux(CHF)was enhanced by a maximum of 101%compared to a plain surface.Eventually,the obtained results were compared with previous research and elucidated a good agreement. 展开更多
关键词 Pool boiling microchannel surface geometrical parameter heat transfer enhancement critical heat flux
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气相色谱-同位素质谱(GC-C-IRMS)测定饮料酒中乙醇^(13)C/^(12)C比值方法研究 被引量:19
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作者 陈文斌 钟其顶 +4 位作者 王道兵 陶宏兵 武竹英 熊正河 蒙健宗 《酿酒科技》 北大核心 2013年第5期90-93,共4页
建立了以有机溶剂稀释法为前处理方法测定饮料酒中乙醇碳稳定同位素比率的气相色谱-燃烧-稳定同位素比值质谱法(GC-C-IRMS)。通过条件优化,在将乙醇稀释至8 g/L并采用Wax色谱柱进行有效分离后,可实现对乙醇中碳同位素比值的有效测定。... 建立了以有机溶剂稀释法为前处理方法测定饮料酒中乙醇碳稳定同位素比率的气相色谱-燃烧-稳定同位素比值质谱法(GC-C-IRMS)。通过条件优化,在将乙醇稀释至8 g/L并采用Wax色谱柱进行有效分离后,可实现对乙醇中碳同位素比值的有效测定。结果表明,该法操作简便,稳定性好,准确度高,可为通过乙醇同位素比值差异实现饮料酒的真实性鉴别提供技术方法。 展开更多
关键词 饮料酒 乙醇 碳同位素 δ13C irmS
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SNIF-NMR和IRMS技术在葡萄酒质量评价中的初步研究 被引量:11
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作者 蒋露 薛洁 +1 位作者 林奇 王异静 《食品与发酵工业》 CAS CSCD 北大核心 2008年第11期139-143,共5页
利用SNIF-NMR和IRMS技术测定葡萄酒中稳定性同位素D/H和18O/16O的比值。结果表明,通过测定乙醇分子中甲基位(D/H)Ⅰ和次甲基位点(D/H)Ⅱ的含量,可判断葡萄酒在酿造前是否进行了加糖操作,而通过测定葡萄酒水分中18O/16O的比值,可鉴别全... 利用SNIF-NMR和IRMS技术测定葡萄酒中稳定性同位素D/H和18O/16O的比值。结果表明,通过测定乙醇分子中甲基位(D/H)Ⅰ和次甲基位点(D/H)Ⅱ的含量,可判断葡萄酒在酿造前是否进行了加糖操作,而通过测定葡萄酒水分中18O/16O的比值,可鉴别全汁葡萄酒和半汁葡萄酒。研究结果为中国葡萄酒的质量评价提供了一种新的技术手段。 展开更多
关键词 SNIF-NMR irmS 葡萄酒 稳定同位素分析
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东北羊草草原综合生态因子对微生物生长的作用──IRM模型的研究 被引量:7
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作者 张崇邦 杨靖春 +1 位作者 管致锦 祖元刚 《生态学报》 CAS CSCD 北大核心 1995年第2期207-213,共7页
本文从分解者亚系统水平研究了东北羊草草原土壤中微生物生长的季节变化.多种生态因子的季节变化及环境因子对微生物的综合作用规律。微生物总数,总生物量和总呼吸强度的季节动态呈单峰上凸式曲线变化,8月份有明显的高峰值出现,它... 本文从分解者亚系统水平研究了东北羊草草原土壤中微生物生长的季节变化.多种生态因子的季节变化及环境因子对微生物的综合作用规律。微生物总数,总生物量和总呼吸强度的季节动态呈单峰上凸式曲线变化,8月份有明显的高峰值出现,它们分别为:2689.0×10 ̄4个/g·干土、25.41×10 ̄(03)g/g·干土、0.8952×10 ̄(-3)gCO_2/g·干土·d。土壤生态因子的季节变化与土壤微生物呈现不同程度的正相关和负相关。同时利用IRM的模型─—探讨了生态因子对微生物生长的综合作用规律:生态因子对微生物生长的综合作用指数r_n在整个生长季节中为0.00318-0.1115,其中7-9月份r_n较大,对出生物生长的限制作用较小,微生物生长较快,5、6和10月份r_n较小,对微生物生长限制作用较大,微生物生长较慢。 展开更多
关键词 草原 羊草草原 微生物生长 irm模型 生态因子
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基于Multi-Agent的机构投资者IRMS原型设计 被引量:4
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作者 姜继娇 杨乃定 贾晓霞 《计算机工程与应用》 CSCD 北大核心 2003年第36期34-36,95,共4页
从机构投资者IRMS作为复杂适应系统CAS(ComplexAdaptiveSystem)角度,引入Multi-Agent建模思想,构建了机构投资者IRMS的原型,该原型强调战略、组织、方法、信息、文化和过程集成性;考虑决策者的有限理性,基于行为金融理论给出了Multi-Ag... 从机构投资者IRMS作为复杂适应系统CAS(ComplexAdaptiveSystem)角度,引入Multi-Agent建模思想,构建了机构投资者IRMS的原型,该原型强调战略、组织、方法、信息、文化和过程集成性;考虑决策者的有限理性,基于行为金融理论给出了Multi-Agent模式下各Agent间的优化算法。 展开更多
关键词 金融市场 证券组合理论 MULTI-AGENT 机构投资者 irmS 行为金融学 微观结构理论 风险管理
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生烃动力学模拟实验结合GC-IRMS测定在有效气源岩判识中的应用 被引量:48
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作者 熊永强 耿安松 +4 位作者 刘金钟 王云鹏 刘德汉 贾蓉芬 申家贵 《地球化学》 CAS CSCD 北大核心 2002年第1期21-25,共5页
采用动力学模拟实验对Ⅰ型干酪根的生烃过程进行了模拟,并对热解产物中的正烷烃组分进行了GC-IRMS分析。分析结果表明,当Ro<1.6%时,C8+正烷烃的碳同位素组成主要继承了母质的特征,而随热演化程度的变化不显著,因此可用于油(气)/源对... 采用动力学模拟实验对Ⅰ型干酪根的生烃过程进行了模拟,并对热解产物中的正烷烃组分进行了GC-IRMS分析。分析结果表明,当Ro<1.6%时,C8+正烷烃的碳同位素组成主要继承了母质的特征,而随热演化程度的变化不显著,因此可用于油(气)/源对比。当Ro在1.6%~2.0%之间时,C8+正烷烃迅速裂解,其δ13C显著增重。Ro>2.0%之后,C1—C4气态烃随热演化程度的增加,逐渐富集13C,其δ13C与Ro之间的关系明显受升温速率的影响,所以由模拟实验获得的δ13C1-Ro关系式不适用于高—过成熟的气源岩研究;而δ13C1-F(甲烷生成率)的关系则不受升温速率的影响,适用范围较宽,故可用于高演化阶段的有效气源岩的判识。 展开更多
关键词 Ⅰ型干酪根 生烃动力学 模拟实验 GC-irmS 气源岩 碳同位素
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IRM-2近交系小鼠的生殖生长特性 被引量:11
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作者 王月英 周继文 +6 位作者 王汝勤 赵忠萍 岳井银 吴红英 刘鹏 张荷清 穆传杰 《中国实验动物学报》 CAS CSCD 2001年第2期103-106,共4页
目的 获取IRM 2近交系小鼠的生殖生长特性的有关资料。方法 ICR JCL为母本 ,以 61 5小鼠为父本杂交选育的近交系小鼠IRM 2 ,现已繁育至第 38代。经过对其生殖、生长特性的观察和测定来取得相关资料。结果 该小鼠出生后 45d性成熟 ;... 目的 获取IRM 2近交系小鼠的生殖生长特性的有关资料。方法 ICR JCL为母本 ,以 61 5小鼠为父本杂交选育的近交系小鼠IRM 2 ,现已繁育至第 38代。经过对其生殖、生长特性的观察和测定来取得相关资料。结果 该小鼠出生后 45d性成熟 ;繁殖能力强 ,平均每窝产仔数为 8只以上 ,最高可达 1 5只 ;生长发育迅速 ,出生后 60d体重可达 2 8g以上 ,各脏器重均高于亲代鼠。结论 从各项指标来看 ,IRM 展开更多
关键词 生殖生长 父本杂交 窝产仔数 母本 繁育 品系 选育 出生后 近交系小鼠 ICR
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论MIS、IRM和KM的关系 被引量:3
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作者 孔德超 周九常 《河南图书馆学刊》 2003年第4期21-24,共4页
本文阐述MISIRMKM的兴起背景以及各自的管理特色的基础上 ,对三者关系进行探讨和分析 ,认为三者相互作用形成一个“信息知识管理体系” ,在该体系中 ,MIS是基础 ,IRM是一个必要的层面 。
关键词 管理信息系统 信息资源管理 知识管理 MIS irm KM 关系 信息知识管理体系
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GasBenchⅡ-IRMS测定葡萄酒水中δ^(18)O方法研究 被引量:13
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作者 王道兵 钟其顶 +2 位作者 高红波 程涛 黄占斌 《质谱学报》 EI CAS CSCD 北大核心 2014年第4期355-360,共6页
葡萄酒水中氧同位素比值(δ18O)对于葡萄酒真实性的鉴别具有重要意义。本研究考察了反应瓶气密性、样品体积、平衡时间和乙醇含量等因素对葡萄酒水中δ18O测定的影响,建立并优化了GasBenchⅡ-IRMS测定葡萄酒水中δ18O比值的在线分析方... 葡萄酒水中氧同位素比值(δ18O)对于葡萄酒真实性的鉴别具有重要意义。本研究考察了反应瓶气密性、样品体积、平衡时间和乙醇含量等因素对葡萄酒水中δ18O测定的影响,建立并优化了GasBenchⅡ-IRMS测定葡萄酒水中δ18O比值的在线分析方法。结果表明,当葡萄酒样品体积为200~1 000μL,反应时间为24~48h时,测定同一葡萄酒水中δ18O重复性和再现性的标准偏差(1σ)均小于0.1‰。该方法操作简便,符合测定要求,可连续测定大批量样品。模拟实验表明,葡萄酒水中δ18O与自来水加入量呈线性负相关,这个特点可用于葡萄酒掺水的鉴别。 展开更多
关键词 GasBench Ⅱ-irmS 葡萄酒 氧同位素比值(δ18O)
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Kiel Ⅳ-IRMS双路在线分析微量碳酸盐的碳氧同位素 被引量:5
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作者 杨会 唐伟 +3 位作者 吴夏 王华 应启和 涂林玲 《岩矿测试》 CAS CSCD 北大核心 2014年第4期480-485,共6页
石笋能重建百年、十年的气候事件,为达到空间高分辨率,对微量碳酸盐的检测提出了更高要求,传统磷酸酸解法的样品用量大(约10 mg)已经无法满足微量样品的分析,而激光探针质谱分析方法需对检测结果进行校正。本文采用KielⅣ-IRMS双路在... 石笋能重建百年、十年的气候事件,为达到空间高分辨率,对微量碳酸盐的检测提出了更高要求,传统磷酸酸解法的样品用量大(约10 mg)已经无法满足微量样品的分析,而激光探针质谱分析方法需对检测结果进行校正。本文采用KielⅣ-IRMS双路在线分析技术对微量碳酸盐样品的碳、氧同位素进行检测研究其可行性,并以GBW 04405和NBS 19为例研究了不同样品量的碳酸盐标准样品在不同反应时间对同位素分馏的影响。结果表明,由于标准样品所需的反应时间不同,从而导致同位素分馏值的差异。对样品量为4~85μg的标准样品GBW 04405进行检测,δ13C、δ18O测量值分别为0.574‰±0.027‰、-8.519‰±0.065‰,与推荐值0.57‰±0.03‰、-8.49‰±0.14‰基本一致,表明该方法能够满足微量碳酸盐测试的要求。将KielⅣ-IRMS双路在线分析技术与GasbenchⅡ-IRMS检测方法进行对比,对于标准样品GBW 04405,KielⅣ-IRMS所用样品量约为50μg,δ13C、δ18O测量值分别为0.576‰±0.012‰、-8.501‰±0.050‰,GasbenchⅡ-IRMS所用样品量约为140μg,δ13C、δ18O测量值分别为0.569‰±0.034‰、-8.590‰±0.099‰。表明KielⅣ-IRMS方法相比于GasbenchⅡ-IRMS方法所需样品量少,精度高,结果重现性好,该方法在碳酸盐样品的应用上能达到空间高分辨率。 展开更多
关键词 微量碳酸盐 碳同位素 氧同位素 KielⅣ-irmS双路在线分析 GasbenchⅡ-irmS在线分析
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SNIF-NMR和IRMS技术在原产地葡萄酒鉴定中的应用 被引量:10
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作者 薛洁 蒋露 《食品与发酵工业》 CAS CSCD 北大核心 2011年第10期154-158,共5页
利用点特异性天然同位素分馏核磁共振技术(SNIF-NMR)和同位素比质谱仪(IRMS)技术测定葡萄酒中稳定性同位素D/H、18O/16O和13C/12C的比值,结果表明(D/H)Ⅱ、R、δ18O‰对产地的鉴别提供着主要信息,而(D/H)Ⅰ与δ13C‰提供了较次要的信息... 利用点特异性天然同位素分馏核磁共振技术(SNIF-NMR)和同位素比质谱仪(IRMS)技术测定葡萄酒中稳定性同位素D/H、18O/16O和13C/12C的比值,结果表明(D/H)Ⅱ、R、δ18O‰对产地的鉴别提供着主要信息,而(D/H)Ⅰ与δ13C‰提供了较次要的信息,单独使用SNIF-NMR结果只能区别开环境差异很大的地区,加上δ13C‰后,可将温差大的地区区别开,但对环境相似的地区仍无法有效鉴别,最后将(D/H)Ⅱ、R、δ13C‰、δ18O‰同时考虑,对于环境相似的地区也可以有效鉴别。研究结果为中国葡萄酒原产地鉴别提供了一种新的技术手段。 展开更多
关键词 SNIF-NMR irmS 葡萄酒 稳定同位素分析 原产地
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