Morphotype dependence of Globigerinoides ruber(white)and Trilobatus sacculifer Mg/Ca ratios in the western tropical Pacific:implications for reconstructing the mixed-layer depth

Planktonic foraminifer Globigerinoides ruber(white)and Trilobatus sacculifer are the most frequently used mixedlayer dwelling species for reconstructing past oceanic environments.Specifically,the Mg/Ca ratios of these two foraminiferal species have been used for reconstructing tropical/subtropical changes in sea surface temperature(SST).However,these two species have different morphotypes,of which the spatial and temporal differences in Mg/Ca ratios and their influencing factors are still unclear.Our objective is to investigate the potential differences between the Mg/Ca ratios of these different morphotypes of G.ruber(white)and T.sacculifer in the western Philippine Sea(WPS)and determine their implications for the reconstruction of SST and upper-ocean structure.Mg/Ca measurements are made on two basic morphotypes of G.ruber(white)[sensu stricto(s.s.)and sensu lato(s.l.)]and T.sacculifer[with(w)and without(w/o)a sac-like final chamber]on samples of Site MD06-3047B from the WPS.Our results reveal that Mg/Ca ratios of different G.ruber morphotypes show consistent differences;and those of T.sacculifer morphotypes show staged variations since MIS 3.It is suggested to select a single morphotype for reconstructing SST changes using the Mg/Ca ratios of G.ruber and T.sacculifer in the WPS.Furthermore,the Mg/Ca ratios between G.ruber s.s.and G.ruber s.l.[Δ(Mg/Ca)_(G.ruber s.s.-s.l.)]downcore MD06-3047B covaries with indexes of summer monsoon.Combining with the core-top results,showing regional variation of differences in theΔ(Mg/Ca)_(G.ruber s.s.-s.l.)over the western tropical Pacific,we propose thatΔ(Mg/Ca)_(G.ruber s.s.-s.l.)may tend to reflect summer mixed layer depth.

A 31-year Global Diurnal Sea Surface Temperature Dataset Created by an Ocean Mixed-Layer Model

A dataset of hourly sea surface temperature(SST) from the period 1 January 1982 to 31 December 2012, and covering the global ocean at a resolution of 0.3°× 0.3°, was created using a validated ocean mixed-layer model(MLSST). The model inputs were heat flux and surface wind speed obtained from the Coupled Forecast System Reanalysis dataset. Comparisons with in-situ data from the Tropical Atmosphere Ocean array and the National Data Buoy Center showed that the MLSST fitted very well with observations, with a mean bias of 0.07℃, and a root-mean-square error(RMSE) and correlation coefficient of 0.37℃ and 0.98, respectively. Also, the MLSST fields successfully reproduced the diurnal cycle of SST in the in-situ data, with a mean bias of -0.005℃ and RMSE of 0.26℃. The 31-year climatology revealed that the diurnal range was small across most regions, with higher values in the eastern and western equatorial Pacific, northern Indian Ocean, western Central America, northwestern Australia, and several coastal regions. Significant seasonal variation of diurnal SST existed in all basins. In the Atlantic and Pacific basins, this seasonal pattern was oriented north–south, following the variation in solar insolation, whereas in the Indian basin it was dominated by monsoonal variability. At the interannual scale, the results highlighted the relationship between diurnal and interannual variations of SST, and revealed that the diurnal warming in the central equatorial Pacific could be a potential climatic indicator for ENSO prediction.

A new method for the estimation of oceanic mixed-layer depth using shipboard X-band radar images

Shipboard X-band radar images acquired on 24 June 2009 are used to study nonlinear internal wave characteristics in the northeastern South China Sea.The studied images show three nonlinear internal waves in a packet.A method based on the Radon Transform technique is introduced to calculate internal wave parameters such as the direction of propagation and internal wave velocity from backscatter images.Assuming that the ocean is a two-layer finite depth system,we can derive the mixed-layer depth by applying the internal wave velocity to the mixed-layer depth formula.Results show reasonably good agreement with in-situ thermistor chain and conductivity-temperature-depth data sets.

Illite-smectite Mixed-layer Minerals in the Alteration Volcanic Ashes under Submarine Environment

The clay mineralogy of the clay intervals interbedded with siliceous mudstones across the Permian-Triassic boundary (PTB) in Pengda, Guiyang, Guizhou province, was investigated by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The clay mineral assemblages of the sediments are mainly I/S clays and minor smectite, kaolinite, and illite as reveled by XRD analyses. The peak-shape parameters BB1 and BB2 of I/S clays of the representative clay bed PL-01 are 4.7° and 4.4°, and the peak position of the low angle reflection is at 6.8° 2θ (13.6 ), suggesting that the I/S clays has a IS type of ordering. However, the presence of multi-order reflections and their intensities are different from those of completely ordered 1∶1 mixed-layer I/S clay rectorite, indicating that I/S clays of the Pengda section have partially ordered IS structures. HRTEM observations show that most of the I/S clays exhibit an IS stacking ordering. However, in some areas within a IS particle, smectite layer is observed in doublets, triplets, and quartets, which are interstratified by various amounts of illite layers, suggesting the presence of other irregular stacking in addition to the major 1∶1 IS ordered stacking. Transformation of smectite layer into illite layers is also observed in the I/S clays, suggesting that the Pengda I/S clays are derived from smectite illitization, in good agreement with the clay mineral assemblage. The I/S clays of the Pengda section contain up to 45% to 95% smectite layer, the notably higher contents of smectite layer relative to those of other PTB stratigraphic sets in south China can be attributed to difference in alteration and smectite illitization processes due to different sedimentary environments.

Study of the Stacking Sequences of an Irregular Mixed-Layer Illite/Smectite (I/S) Clay Mineral—with a Discussion on the Existence of Minerals with Two-Dimentional Lattice and One-Dimentional Quasi-Lattice

There are two aspects in the study of irregular mixed-layer clay minerals: one is the kinds and ratios of their basic structural unit layers and the other is the junction probabilities of the unit layers. Irregular mixed-layer illite/smectite clay minerals (I/S) are widespread in nature. While studying the clay minerals from the Permian-Triassic (P/T) boundary bed, the authors found that I/S clay minerals are developed in all P/T boundary clay layers in areas from the northwest to southeast of China. Systematic mineralogical studies of the I/S clay minerals from Hunan, Hubei, Sichuan and Zhejiang were made by means of X-ray, infrared spectroscopic, electron microscopic and chemical analyses and a deepened study of the stacking sequences of their structural unit layers was conducted by the MacEwan one—dimentional direct Fourier transform. It was found that the stacking of the illite and smectite crystal layers along the c axis can be derived from Fibonacci sequences. Hence, the authors propose that such I/S clay minerals are possessed of two—dimentional crystal lattice and one—dimentional quasicrystal lattice.

Evolution of kaolinite subgroup minerals and mixed-layer illite/smectite in the Paleogene Damintun Depression in Liaohe Basin of China and its implication for paleotemperature

The oil-rich Damintun Depression is located in the Liaohe Basin, Northeast China, and was formed during the Paleogene. The major oil-producing strata in the depression are mudstone and shale. To explore the burial diagenetic history of the basin and the formation thresholds of hydrocarbons, the characters of the kaolinite subgroup minerals and mixed-layer illite/smectite in the mudstone and the shale are studied by using X-ray diffraction, electron probe, scanning electron microscope, and Fourier infrared spectrum. The kaolinite subgroup consists of kaolinite and halloysite. The kaolinite is flake-like or vermiform-like. The halloysite is in long tubular shape and its length is related to its iron content. A longer tube has lower iron content. The crystallinity of kaolinite is 0.40 ~20, and its degree of order increases from 0.03 to 1.17 with the burial depth. Kaolinite is in disorder when the buried depth is less than or equal to 2479 m, and it is partially ordered when the buried depth is greater than 2479 m. Kaolinite is supposed to turn into dickite when the depth is greater than 2550 m, but low penetrability and low poros- ity of the shale and mudstone prevent such a change. The mixed-layer illite/smectite changes from disorder to order continually as the buried depth increases. Its disorder （RoI/S）, as defined by illite layer content （I%）, is smaller than 50% at depths less than 2550.25 m. Based on Hoffman ＆ Hower＇s model, the paleo-geothermal gradients of 3.37-3.76℃/100 m （3.57℃/100 m on average） can be derived in the Paleocene Damintun Depression, which is significantly higher than the present geothermal gradient （2.9℃00 m）. The threshold depth of the oil formation in the depression is about 2550 m.

Occurrence of mixed-layer illite/smectite at temperature of 285℃ in an active hydrothermal system and its significance

THE progressive transformation of smectite into illite via mixed-layer illite/smectite (I/S) phases occurs during hydrothermal alteration, burial diagenesis and regional metamorphism. The proportion of illite or smectite (also indicated by their expandability) and ordering of I/S, interpreted by X-ray powder diffraction (XRD) profiles, have long been used as geothermometers in sedimentary basins. It is found that R=1 ordering mixed-layer I/S still exists

Limited Sea Surface Temperature Cooling Due to the Barrier Layer Promoting Super Typhoon Mangkhut(2018)

This study investigates the impact of the salinity barrier layer(BL)on the upper ocean response to Super Typhoon Mangkhut(2018)in the western North Pacific.After the passage of Mangkhut,a noticeable increase(~0.6 psu)in sea surface salinity and a weak decrease(<1℃)in sea surface temperature(SST)were observed on the right side of the typhoon track.Mangkhut-induced SST change can be divided into the three stages,corresponding to the variations in BL thickness and SST before,during,and after the passage of Mangkhut.During the pre-typhoon stage,SST slightly warmed due to the entrainment of BL warm water,which suppressed the cooling induced by surface heat fluxes and horizontal advection.During the forced stage,SST cooling was controlled by entrainment,and the preexisting BL reduced the total cooling by 0.89℃ d-1,thus significantly weakening the overall SST cooling induced by Mangkhut.During the relaxation stage,the SST cooling was primarily caused by the entrainment.Our results indicate that a preexisting BL can limit typhoon-induced SST cooling by suppressing the entrainment of cold thermocline water,which contributed to Mangkhut becoming the strongest typhoon in 2018.

Effect of Mixed Vegetation of Different Heights on Open Channel Flows

Vegetation of different heights commonly grows in natural rivers, canals and wetlands and affects the biodiversity and morphological process. The role of vegetation has drawn great attention in river ecosystems and environmental management. Due to the complexity of the vegetated flow, most previous research focuses on the effect of uniformed one-layered vegetation on the flow structure and morphological process. However, less attention was paid to the impact of the mixing vegetation of different heights, which is more realistic and often occurs in natural riverine environments. This paper aims to investigate the effect of mixing three-layered vegetation on flow characteristics, particularly the velocity distrbution, via a novel experiment. Experiments were performed in a titling water flume fully covered with vegetation of three heights (10, 15 and 20 cm) arranged in a staggered pattern, which is partially submerged. Velocities at different positions along a half cross-section were measured using a mini propeller velocimeter. Observed results showed that the velocity has a distinct profile directly behind vegetation and behind the vegetation gap. The overall profile has two distinct reflections about ? below or near the top of short vegetation (h): the velocity remains almost constant in the bottom layer ( h) the velocities directly behind the middle after short vegetation increase much faster than those directly behind the short after tall vegetation. The finding in this study would help river riparian and ecosystem management. .

Interannual Salinity Variability in the Tropical Pacific in CMIP5 Simulations

Salinity variability and its causes in the tropical Pacific are analyzed using observations, reanalysis products and model simulations. The mixed-layer salinity(MLS) budget analyses from observations and reanalysis products indicate that its interannual evolution is closely related to ENSO and is predominantly governed by surface forcing and surface advection in the western-central equatorial Pacific. It is found that the observed MLS tendency leads Nin?o3.4 by about 12 months due to the effect of negative freshwater flux(evaporation minus precipitation). These observation-based analyses are used to evaluate the corresponding simulation using GFDL-ESM2 M. It is evident that the model can simulate the spatiotemporal variations of MLS with some discrepancies compared to observations. In the warm pool of the equatorial Pacific the MLS tendency in the model is sensitive to ocean dynamics, however model biases cause the tendency to be underestimated. In particular, the freshwater flux is overestimated while the ocean surface zonal current and vertical velocity at the base of the mixed layer are underestimated. Due to model biases in representing the related physics, the effects of surface forcing on the simulated MLS budget are overestimated and those of subsurface and surface advection are relatively weak. Due to weaker surface advection and subsurface forcing than observed, the simulated compensations for surface forcing are suppressed, and the simulated MLS tendency that leads Nin?o3.4 by 8–10 months, which is shorter than the observed lead time. These results are useful for the interpretation of observational analyses and other model simulations in the tropical Pacific.

Using genetic algorithms to calibrate a dimethylsulfide production model in the Arctic Ocean

The global climate is intimately connected to changes in the polar oceans. The variability of sea ice coverage affects deep-water formations and large-scale thermohaline circulation patterns. The polar radiative budget is sensitive to sea-ice loss and consequent surface albedo changes. Aerosols and polar cloud microphysics are crucial players in the radioactive energy balance of the Arctic Ocean. The main biogenic source of sulfate aerosols to the atmosphere above remote seas is dimethylsulfide (DMS). Recent research suggests the flux of DMS to the Arctic atmosphere may change markedly under global warming. This paper describes climate data and DMS production (based on the five years from 1998 to 2002) in the region of the Barents Sea (30–35°E and 70–80°N). A DMS model is introduced together with an updated calibration method. A genetic algorithm is used to calibrate the chlorophyll-a (CHL) measurements (based on satellite SeaWiFS data) and DMS content (determined from cruise data collected in the Arctic). Significant interannual variation of the CHL amount leads to significant interannual variability in the observed and modeled production of DMS in the study region. Strong DMS production in 1998 could have been caused by a large amount of ice algae being released in the southern region. Forcings from a general circulation model (CSIRO Mk3) were applied to the calibrated DMS model to predict the zonal mean sea-to-air flux of DMS for contemporary and enhanced greenhouse conditions at 70–80°N. It was found that significantly decreasing ice coverage, increasing sea surface temperature and decreasing mixed-layer depth could lead to annual DMS flux increases of more than 100% by the time of equivalent CO2 tripling (the year 2080). This significant perturbation in the aerosol climate could have a large impact on the regional Arctic heat budget and consequences for global warming.

Influences of the Great Whirl on surface chlorophyll a concentration off the Somali Coast in 2017

The general features of the Great Whirl(GW)off the Somali Coast in 2017 and its influences on chlorophyll a(Chl a)concentration were studied by using satellite data and model outputs.Results show that GW,which initiated at7°N,53°E on June 13,had a lifetime of 153 d with an average amplitude of 16 cm and an average radius of 205 km.After the formation of GW,the concentration of Chl a in the interior of GW showed a downward trend throughout its life cycle,except in early July and mid-October.In early July,the Chl a blooms in the interior of GW were attributed to the combined effect of three processes.They are eddy horizontal transportation,the deepening of the mixed layer caused by the monsoon and eddy pumping,and the upward transportation of nutrients caused by eddy-induced Ekman pumping.In October,the Chl a blooms were probably due to the weakening of GW.During the period,water exchange occurred more frequently across the eddy,thus phytoplanktons were imported into the interior of GW.

Characterization of Soil Clay Minerals of the River Nile Sediments, Sohag Region, Egypt： Decomposition of X-Ray Diffraction Patterns

Up till now all the clay mineral studies on the soils of the River Nile flood plain in Egypt could not trace the very rapid mineral change observed in these soils. So, the clay mineralogy of the River Nile flood plain soils in Sohag region, Egypt, has been studied using the method of numerical analysis of X-ray diffraction recordings （curve decomposition） as a new, powerful tool for precise mineral identification. The X-ray patterns of the studied soil clay fraction show that 2：1 clay minerals are much more abundant than kaolinite and that this clay fraction contains fair amounts of K-feldspar and quartz. XRD pattems obtained on the 〈 2 μm fraction of the River Nile sediments indicate the presence of smectite, mixed-layer illite-expanding minerals, kaolinite, mica-illite and chlorite. The decomposed XRD patterns reveal significant changes in the mineralogy of the clays. The major clay phases present in the 4-11 20 range are well crystallized illite （10 A）, poorly crystallized illite （10.2-10.4 A）, two mixed-layer I-S （illite/smectite） minerals, one with a peak near 13.5 A （rich-smectite） and the other near 11 A （rich-illite）.

Remote sensing observations of phytoplankton increases triggered by successive typhoons

Phytoplankton blooms in the Western North Pacific, triggered by two successive typhoons with different intensities and translation speeds under different pre-existing oceanic conditions, were observed and analyzed using remotely sensed chlorophyll-a （Chl-a）, sea surface temperature （SST）, and sea surface height anomaly （SSHA） data, as well as typhoon parameters and CTD （conductivity, temperature, and depth） profiles. Typhoon Sinlaku, with relatively weaker intensity and slower translation speed, induced a stronger phytoplankton bloom than Jangrni with stronger intensity and faster translation speed （Chl-a〉0.18 mg-m-3 versus Chl- a〈 0.15 mg.m-3） east of Taiwan Island. Translation speed may be one of the important mechanisms that affect phytoplankton blooms in the study area. Pre-existing cyclonic circulations provided a relatively unstable thermodynamic structure for Sinlaku, and therefore cold water with rich nutrients could be brought up easily. The mixed-layer deepening caused by Typhoon Sinlaku, which occurred first, could have triggered an unfavorable condition for the phytoplankton bloom induced by Typhoon Jangmi which followed afterwards. The sea surface temperature cooling by Jangmi was suppressed due to the presence of the thick upper-ocean mixed-layer, which prevented the deeper cold water from being entrained into the upper-ocean mixed layer, leading to a weaker phytoplankton augment. The present study sug- gests that both wind （including typhoon translation speed and intensity） and pre-existing conditions （e.g., mixed- layer depths, eddies, and nutrients） play important roles in the strong phytoplankton bloom, and are responsible for the stronger phytoplankton bloom after Sinlaku＇s passage than that after Jangmi＇s passage. A new typhoon- influencing parameter is introduced that combines the effects of the typhoon forcing （including the typhoon intensity and translation speed） and the oceanic pre- condition. This parameter shows that the forcing effect of Sinlaku was stronger than that of Jangmi.

SST biases over the Northwest Pacific and possible causes in CMIP5 models

In this paper, the features and possible causes of sea surface temperature(SST) biases over the Northwest Pacific are investigated based on a mixed-layer heat budget analysis in 21 coupled general circulation models(CGCMs) from phase 5 of the Coupled Model Inter-comparison Project(CMIP5). Most CMIP5 models show cold SST biases throughout the year over the Northwest Pacific. The largest biases appear during summer, and the smallest biases occur during winter. These cold SST biases are seen at the basin scale and are mainly located in the inner region of the low and mid-latitudes. According to the mixed-layer heat budget analysis, overestimation of upward net sea surface heat fluxes associated with atmospheric processes are primarily responsible for the cold SST biases. Among the different components of surface heat fluxes, overestimated upward latent heat fluxes induced by the excessively strong surface winds contribute the most to the cold SST biases during the spring, autumn, and winter seasons. Conversely, during the summer, overestimated upward latent heat fluxes and underestimated downward solar radiations at the sea surface are equally important. Further analysis suggests that the overly strong surface winds over the Northwest Pacific during winter and spring are associated with excessive precipitation over the Maritime Continent region,whereas those occurring during summer and autumn are associated with the excessive northward extension of the intertropical convergence zone(ITCZ). The excessive precipitation over the Maritime Continent region and the biases in the simulated ITCZ induce anomalous northeasterlies, which are in favor of enhancing low-level winds over the North Pacific. The enhanced surface wind increases the sea surface evaporation, which contributes to the excessive upward latent heat fluxes. Thus, the SST over the Northwest Pacific cools.

Sensitivity study of subgrid scale ocean mixing under sea ice using a two-column ocean grid in climate model CESM

Brine drainage from sea ice formation plays a critical role in ocean mixing and seasonal variations of halocline in polar oceans. The horizontal scale of brine drainage and its induced convection is much smaller than a climate model grid and a model tends to produce false ocean mixing when brine drainage is averaged over a grid cell. A two-column ocean grid （TCOG） scheme was implemented in the Community Earth System Model （CESM） using coupled sea ice-ocean model setting to explicitly solve the different vertical mixing in the two sub- columns of one model grid with and without brine rejection. The fraction of grid with brine rejection was tested to be equal to the lead fraction or a small constant number in a series of sensitivity model runs forced by the same atmospheric data from 1978 to 2009. The model results were compared to observations from 29 ice tethered profilers （ITP） in the Arctic Ocean Basin from 2004 to 2009. Compared with the control run using a regular ocean grid, the TCOG simulations showed consistent reduction of model errors in salinity and mixed layer depth （MLD）. The model using a small constant fraction grid for brine rejection was found to produce the best model comparison with observations, indicating that the horizontal scale of the brine drainage is very small compared to the sea ice cover and even smaller than the lead fraction. Comparable to models using brine rejection parameterization schemes, TCOG achieved more improvements in salinity but similar in MLD.