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Analysis of Urban Agglomeration Network Structure Based on Baidu Migration Data: A Case Study of the Guangdong-Hong Kong-Macao Greater Bay Urban Agglomeration
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作者 XIA Yuan WANG Bin 《Journal of Landscape Research》 2024年第4期47-50,共4页
The inter-city linkage heat data provided by Baidu Migration is employed as a characterization of inter-city linkages in order to facilitate the study of the network linkage characteristics and hierarchical structure ... The inter-city linkage heat data provided by Baidu Migration is employed as a characterization of inter-city linkages in order to facilitate the study of the network linkage characteristics and hierarchical structure of urban agglomeration in the Greater Bay Area through the use of social network analysis method.This is the inaugural application of big data based on location services in the study of urban agglomeration network structure,which represents a novel research perspective on this topic.The study reveals that the density of network linkages in the Greater Bay Area urban agglomeration has reached 100%,indicating a mature network-like spatial structure.This structure has given rise to three distinct communities:Shenzhen-Dongguan-Huizhou,Guangzhou-Foshan-Zhaoqing,and Zhuhai-Zhongshan-Jiangmen.Additionally,cities within the Greater Bay Area urban agglomeration play different roles,suggesting that varying development strategies may be necessary to achieve staggered development.The study demonstrates that large datasets represented by LBS can offer novel insights and methodologies for the examination of urban agglomeration network structures,contingent on the appropriate mining and processing of the data. 展开更多
关键词 Baidu migration data Social network analysis Urban agglomeration network structure Greater Bay Area urban agglomeration
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Rail Internal Defect Detection Method Based on Enhanced Network Structure and Module Design Using Ultrasonic Images
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作者 Fupei Wu Xiaoyang Xie Weilin Ye 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第6期277-288,共12页
Improving the detection accuracy of rail internal defects and the generalization ability of detection models are not only the main problems in the field of defect detection but also the key to ensuring the safe operat... Improving the detection accuracy of rail internal defects and the generalization ability of detection models are not only the main problems in the field of defect detection but also the key to ensuring the safe operation of high-speed trains.For this reason,a rail internal defect detection method based on an enhanced network structure and module design using ultrasonic images is proposed in this paper.First,a data augmentation method was used to extend the existing image dataset to obtain appropriate image samples.Second,an enhanced network structure was designed to make full use of the high-level and low-level feature information in the image,which improved the accuracy of defect detection.Subsequently,to optimize the detection performance of the proposed model,the Mish activation function was used to design the block module of the feature extraction network.Finally,the pro-posed rail defect detection model was trained.The experimental results showed that the precision rate and F1score of the proposed method were as high as 98%,while the model’s recall rate reached 99%.Specifically,good detec-tion results were achieved for different types of defects,which provides a reference for the engineering application of internal defect detection.Experimental results verified the effectiveness of the proposed method. 展开更多
关键词 Ultrasonic detection Rail defects detection Deep learning Enhanced network structure Module design
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DNEF:A New Ensemble Framework Based on Deep Network Structure
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作者 Siyu Yang Ge Song +2 位作者 Yuqiao Deng Changyu Liu Zhuoyu Ou 《Computers, Materials & Continua》 SCIE EI 2023年第12期4055-4072,共18页
Deep neural networks have achieved tremendous success in various fields,and the structure of these networks is a key factor in their success.In this paper,we focus on the research of ensemble learning based on deep ne... Deep neural networks have achieved tremendous success in various fields,and the structure of these networks is a key factor in their success.In this paper,we focus on the research of ensemble learning based on deep network structure and propose a new deep network ensemble framework(DNEF).Unlike other ensemble learning models,DNEF is an ensemble learning architecture of network structures,with serial iteration between the hidden layers,while base classifiers are trained in parallel within these hidden layers.Specifically,DNEF uses randomly sampled data as input and implements serial iteration based on the weighting strategy between hidden layers.In the hidden layers,each node represents a base classifier,and multiple nodes generate training data for the next hidden layer according to the transfer strategy.The DNEF operates based on two strategies:(1)The weighting strategy calculates the training instance weights of the nodes according to their weaknesses in the previous layer.(2)The transfer strategy adaptively selects each node’s instances with weights as transfer instances and transfer weights,which are combined with the training data of nodes as input for the next hidden layer.These two strategies improve the accuracy and generalization of DNEF.This research integrates the ensemble of all nodes as the final output of DNEF.The experimental results reveal that the DNEF framework surpasses the traditional ensemble models and functions with high accuracy and innovative deep ensemble methods. 展开更多
关键词 Machine learning ensemble learning deep ensemble deep network structure CLASSIFICATION
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Transition of plasticity and fracture mode of Zr-Al-Ni-Cu bulk metallic glasses with network structures 被引量:1
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作者 蔡安辉 丁大伟 +4 位作者 安伟科 周果君 罗云 李江鸿 彭勇宜 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第8期2617-2623,共7页
Effect of network structure on plasticity and fracture mode of Zr?Al?Ni?Cu bulk metallic glasses (BMGs) was investigated. The microstructures of transversal and longitudinal sections were exposed by chemical etch... Effect of network structure on plasticity and fracture mode of Zr?Al?Ni?Cu bulk metallic glasses (BMGs) was investigated. The microstructures of transversal and longitudinal sections were exposed by chemical etching and observed by scanning electron microscopy (SEM). The mechanical properties were examined by room-temperature uniaxial compression test. The results show that both plasticity and fracture mode are significantly affected by the network structure and the alteration occurs when the size of the network structure reaches up to a critical value. When the cell size (dc) of the network structure is ~3μm, Zr-based BMGs characterize in plasticity that decreases with increasingdc. The fracture mode gradually transforms from single 45° shear fracture to double 45° shear fracture and then cleavage fracture with increasingdc. In addition, the mechanisms of the transition of the plasticity and the fracture mode for these Zr-based BMGs are also discussed. 展开更多
关键词 bulk metallic glass PLASTICITY fracture mode network structure
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Fabrication and abrasive wear properties of metal matrix composites reinforced with three-dimensional network structure 被引量:2
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作者 WANG Shouren GENG Haoran +3 位作者 LI Kunshan SONG Bo WANG Yingzi HUI Linhai 《Rare Metals》 SCIE EI CAS CSCD 2006年第6期671-679,共9页
Reticulated polyurethane was chosen as the preceramic material for preparing the porous preform using the replication process. The immersing and sintering processes were each performed twice for fabricating a high-por... Reticulated polyurethane was chosen as the preceramic material for preparing the porous preform using the replication process. The immersing and sintering processes were each performed twice for fabricating a high-porosity and super-strong skeleton. The aluminum magnesium matrix composites reinforced with three-dimensional network structure were prepared using the infiltration technique by pressure assisting and vacuum driving. Light interfacial reactions have played a profitable role in most of the ceramic-metal systems. The metal matrix composites interpenetrated with the ceramic phase have a higher wear resistance than the metal matrix phase. The volume fraction of ceramic reinforcement has a significant effect on the abrasive wear, and the wear rate can be decreased with the increase of the volume fraction of reinforcement. 展开更多
关键词 metal matrix composites INFILTRATION fficdon and wear three dimensional network structure MICROstructure
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Optimal network structure to induce the maximal small-world effect 被引量:1
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作者 张争珍 许文俊 +1 位作者 曾上游 林家儒 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第2期623-627,共5页
In this paper, the general efficiency, which is the average of the global efficiency and the local efficiency, is defined to measure the communication efficiency of a network. The increasing ratio of the general effic... In this paper, the general efficiency, which is the average of the global efficiency and the local efficiency, is defined to measure the communication efficiency of a network. The increasing ratio of the general efficiency of a small-world network relative to that of the corresponding regular network is used to measure the small-world effect quantitatively. The more considerable the small-world effect, the higher the general efficiency of a network with a certain cost is. It is shown that the small-world effect increases monotonically with the increase of the vertex number. The optimal rewiring probability to induce the best small-world effect is approximately 0.02 and the optimal average connection probability decreases monotonically with the increase of the vertex number. Therefore, the optimal network structure to induce the maximal small-world effect is the structure with the large vertex number (〉 500), the small rewiring probability (≈0.02) and the small average connection probability (〈 0.1). Many previous research results support our results. 展开更多
关键词 small-world network communication efficiency optimal network structure
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Evaluation and optimization analysis of high-speed rail network structure in Northeast China under the background of northeast revitalization 被引量:1
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作者 XU Shaojie WANG Fuyuan WANG Kaiyong 《Regional Sustainability》 2021年第4期349-362,共14页
The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adop... The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adoption of the operation frequency data of HSR from 12306 website,and based on the HSR connection strength model and social network analysis model,as well as according to the HSR connection strength,HSR network density,centrality,agglomeration subgroup,and other indicators,we analyzed the characteristics of HSR network structure in Northeast China.Results show that the number of HSR cities in Northeast China is small,cities in HSR network generally exhibit weak connectivity,and the existence of HSR network marginalizes cities such as Ulanhot,Baicheng,and Songyuan,which significantly reduce the overall network connectivity of Northeast China.The overall centrality of HSR network in Northeast China is characterized by“one axis,four edges”;specifically,the one axis is located in Harbin-Dalian transportation line and the four edges are located on both sides of the main axis of Harbin-Dalian transportation line.Eight agglomeration subgroups(four double city subgroups and four multi city subgroups)have formed in Northeast China.The core status of Shenyang in HSR network is improved significantly,and“one axis and two wings”HSR network in Liaoning Province is improved significantly.With the gradual expansion of Chaoyang-Fuxin,Dandong-Benxi,and Jilin-Yanji branch networks,the“point axis”HSR network mode in Northeast China has gradually developed and matured.In the future,it is recommended to rely on eight agglomerating subgroups to encrypt HSR network structure,create secondary node central cities,and gradually build a new pattern of opening up in Northeast China. 展开更多
关键词 Social network analysis High-speed rail network structure Operation frequency Intercity connection intensity network density analysis Northeast China
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A Tree-Based Data Collecting Network Structure for Wireless Sensor Networks 被引量:3
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作者 Chi-Tsun Cheng Chi K. Tse Francis C. M. Lau 《Journal of Electronic Science and Technology of China》 2008年第3期274-278,共5页
In a sensor network with a large number of densely populated sensor nodes, a single target of interest may be detected by multiple sensor nodes simultaneously. Data collected from the sensor nodes are usually highly c... In a sensor network with a large number of densely populated sensor nodes, a single target of interest may be detected by multiple sensor nodes simultaneously. Data collected from the sensor nodes are usually highly correlated, and hence energy saving using in-network data fusion becomes possible. A traditional data fusion scheme starts with dividing the network into clusters, followed by electing a sensor node as cluster head in each cluster. A cluster head is responsible for collecting data from all its cluster members, performing data fusion on these data and transmitting the fused data to the base station. Assuming that a sensor node is only capable of handling a single node-to-node transmission at a time and each transmission takes T time-slots, a cluster head with n cluster members will take at least nT time-slots to collect data from all its cluster members. In this paper, a tree-based network structure and its formation algorithms are proposed. Simulation results show that the proposed network structure can greatly reduce the delay in data collection. 展开更多
关键词 CLUSTER data transmission network structure sensor network trees
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Two Network Structure Indicators for Conventional Public Transit
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作者 Min Fu Hao Wang +2 位作者 Wei Wang Sida Luo De Zhao 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2016年第5期90-96,共7页
The significance of network structure indicators for the planning and management of conventional public transit is widely acknowledged.In order to improve and enrich the conventional public transit assessment system,t... The significance of network structure indicators for the planning and management of conventional public transit is widely acknowledged.In order to improve and enrich the conventional public transit assessment system,two network structure indicators are proposed.Firstly,according to the obvious defects lying in the traditional no-linear coefficient,the realistic no-linear coefficient γRNL,a modified no-linear coefficient indicator,is put forward,which takes into account the effects of barriers in a city.Secondly,to cover the gap of an indicator which can reflect the coverage homogeneity of a transit network,the length dimension LDis proposed on the basis of Fractal Theory.Finally,a case study is applied to verify the validity and practicability of the two indicators in problem diagnosis using regression analysis.The results validate that γRNLcan evaluate the detour of bus lines more reasonably than the previous no-linear coefficient because it reflects the layout of bus lines,and LDcan represent the rate of change of the network density,adding a new member to the scheme of network structure indicators for public transit. 展开更多
关键词 conventional public transit network structure indicator realistic no-linear coefficient length dimension fractal theory
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Synthesis and 2D H-bonded Cd(Ⅱ) Network Structure of [Cd(C_(10)H_(15)N_3)Cl_2]
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作者 边贺东 徐靖源 +4 位作者 顾文 阎世平 廖代正 姜宗慧 程鹏 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第6期710-712,共3页
The title complex [CdLCl2] 1 (C10H15CdCl2N3, Mr = 360.55) has been synthesized by the reaction of CdCl22.5H2O with the tridentate Schiff base L, N,N-dimethyl-N-pyridin-2-yl- methylene-1,2-diaminoethane, which is deriv... The title complex [CdLCl2] 1 (C10H15CdCl2N3, Mr = 360.55) has been synthesized by the reaction of CdCl22.5H2O with the tridentate Schiff base L, N,N-dimethyl-N-pyridin-2-yl- methylene-1,2-diaminoethane, which is derived from the condensation reaction of pyridine-2- carboxaldehyde and N,N-dimethylethylenediamine. It crystallizes in the monoclinic system, space group C2/c with a = 25.054(13), b = 7.532(4), c = 16.119(8) ? b = 116.238(8)? V = 2728(2) ?, Z = 8, Dc = 1.756 g/cm3, m(MoKa) = 1.970 mm-1, F(000) = 1424, R = 0.0297 and wR = 0.0625. Crystal analyses reveal that the cadmium atom is coordinated by two chlorine atoms and three N atoms from the tridentate ligand in a distorted tetragonal pyramidal environment. Each complex molecule is connected with four surrounding ones to form 2D network by hydrogen bonds along the bc plane. The chlorine atoms act as acceptors and the carbon atoms of the tridentate Schiff base as donors with the CH…Cl distances in the range of 3.518~3.752 ? 展开更多
关键词 crystal structures cadmium(Ⅱ) complex 2D network structure hydrogen bonds
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Spatial network structure of transportation carbon emission efficiency in China and its influencing factors
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作者 Haiqin Shao Zhaofeng Wang 《Chinese Journal of Population,Resources and Environment》 2021年第4期295-303,共9页
Grasping the spatial correlation structure of transportation carbon emission efficiency(TCEE)and its influencing factors is significant for promoting high-quality and coordinated development of the transportation indu... Grasping the spatial correlation structure of transportation carbon emission efficiency(TCEE)and its influencing factors is significant for promoting high-quality and coordinated development of the transportation industry and the relevant region.Based on the ideal point cross-efficiency(IPCE)model,the social network analysis method was employed herein to explore the spatial correlation network structure of China’s provincial TCEE and its influencing factors.The results obtained showed the following outcomes.(1)During the study period,China’s provincial TCEE formed a complex and multithreaded network association relationship,but its network association structure was still relatively loose and presented the hierarchical gradient characteristics of dense in the east and sparse in the west.(2)The correlation of China’s TCEE formed a block segmentation based on the regional boundaries,and its factional structure was relatively obvious.The eastern region was closely connected with the central region,and generally connected with the western and northeastern regions.The central region was mainly connected with the eastern and western regions,and relatively less connected with the northeastern region.Besides,the northeastern region was weakly connected with the western region.(3)Shanghai,Beijing,Zhejiang,Guangdong,Jiangsu,Tianjin,and other developed provinces were in the core leading position in the TCEE network,which significantly impacted the spatial correlation of TCEE.However,Heilongjiang,Jilin,Xinjiang,Qinghai,and other remote provinces in the northeast and northwest were at the absolute edge of the network,which weakly impacted the spatial correlation of TCEE.(4)Provincial distance,economic development-level difference,transportation intensity difference,and transportation structure difference had significant negative impacts on the spatial correlation network of China’s provincial TCEE.In contrast,the energy-saving technology level difference had a significant positive impact on it.The regression coefficients of transportation energy structure and environmental regulation differences were positive but insignificant;their response mechanism and effects need to be improved and enhanced. 展开更多
关键词 Transportation carbon emission efficiency Spatial network structure Influencing factor Social network analysis
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Network structure and its effects on the strength of Fe-C-Si-Mn alloy castings
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作者 张丁非 《Journal of Chongqing University》 CAS 2004年第2期12-15,共4页
Fe-C-Si-Mn alloy castings used as blades in hydroelectric generators are studied and found to contain network structures after some heat treatments. Castings after annealing and normalizing were analyzed by microscope... Fe-C-Si-Mn alloy castings used as blades in hydroelectric generators are studied and found to contain network structures after some heat treatments. Castings after annealing and normalizing were analyzed by microscope and transmission electron microscopy (TEM). The network formed during annealing was proved by TEM to be pearlite with very fine slices, while that formed during normalizing was proved by TEM and micro-hardness to be martensite or bainite. A theoretical analysis together with experimental studies has proved that the pearlite network is caused by carbon content increase in the interdendritic regions to which carbon atoms transfered from dendritic arms due to lower manganese content there during annealing, while the martensite or bainite network results from the higher hardenability of interdendritic regions where manganese content is higher. Experiments reveal that higher heating temperature or longer heating time enlarges the network size due to manganese homogenization. The network structure has a strengthening function like reinforcing rib, and the smaller the network size, the greater its strengthening capability. 展开更多
关键词 network structure Fe-C-Si-Mn alloys strengthening
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Study on Cognitive Optical Network Structure and Self-optimization with the Application of Artificial Intelligence Technology
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作者 Shengzhe Liang 《Modern Electronic Technology》 2020年第1期1-5,共5页
Cognitive optical network is the intermediate to combine artificial intelligence technology with network,and also the important network technology to promote network intelligence level constantly.In the paper,it analy... Cognitive optical network is the intermediate to combine artificial intelligence technology with network,and also the important network technology to promote network intelligence level constantly.In the paper,it analyzes the cognitive optical network structure with the application of artificial intelligence technology by starting from the basic conditions of cognitive network and cognitive optional network on the basis of fully understanding the connotation of cognitive network and cognitive optical network,and explores its self-governance functions,so as to better realize the self-optimization and self-configuration of network. 展开更多
关键词 Artificial intelligence technology Cognitive optical network network structure SELF-OPTIMIZATION
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Study on the Interior Market Network Structure and Its Efficiency in a Knowledge Based Company
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作者 Zuanhuang Lin Yuqi Han Liping Lin 《Chinese Business Review》 2005年第7期49-53,62,共6页
A knowledge based company is the microcosmic foundation of the knowledge economy, the design of its organization structure should amplify the company competence to be agile to the knowledge elements. This paper expoun... A knowledge based company is the microcosmic foundation of the knowledge economy, the design of its organization structure should amplify the company competence to be agile to the knowledge elements. This paper expounds an interior market network structure which is fit for the company intellectual capital operation, and analyses this organization pattern about the reasons of existence, the effectiveness of growing up in scale, the economies of knowledge distribution and the efficiency of operation, and it will provide some beneficial theoretical guidance about how can a company improve its competition competence in the knowledge environment through organization innovation. 展开更多
关键词 knowledge based company interior market network structure efficiency intellectual capital operation
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Research on Multi-Layer Distributed HF Radio Network Structure
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作者 Hui Dai Chun-Jiang Wang Quan Yu 《Journal of Electronic Science and Technology of China》 2008年第1期16-20,共5页
High frequency(HF)transmission is an important communication techniques.However,conven-tional point-to-point transmission can be easily destroyed,which limits its utilization in practice.HF networking communication ... High frequency(HF)transmission is an important communication techniques.However,conven-tional point-to-point transmission can be easily destroyed,which limits its utilization in practice.HF networking communication has the capability against demolishment.The network structure is one of the key factors for HF networking communication.In this paper,a novel analysis method of the network connectedness based on the eigenvalue is derived,and a multi-layer distributed HF radio network structure is proposed.Both the theore-tical analysis and the computer simulation results verify that the application of the proposed network structure in the HF radio communication can improve the anti-demolishment ability of the HF network efficiently. 展开更多
关键词 High frequency (HF) communication high frequency (HF) network military communication network structure.
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Thermoreversible Thickening and Self-assembly Behaviors of pH/Temperature Dually Responsive Microgels with Interpenetrating Polymer Network Structure 被引量:1
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作者 刘晓云 杨军 +1 位作者 闫伟霞 査刘生 《Journal of Donghua University(English Edition)》 EI CAS 2014年第3期312-315,共4页
The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN micr... The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN microgels) were synthesized by seed emulsion polymerization. The results obtained by dynamic laser light scattering( DLLS) show that the microgels have good pH /temperature dual sensitivities. The temperature sensitive component and the pH sensitive component inside the microgels have little interference with each other. The rheological properties of the concentrated PNIPAM /PAA IPN microgel dispersions as a function of temperature at pH 4. 0 or 7. 0 were investigated by viscometer,and the results displayed that only at pH 7. 0 the dispersions presented thermoreversible thickening behavior. Then the PNIPAM /PAA fibers were prepared by self-assembly of the PNIPAM /PAA IPN microgels in the ice-crystal templates formed by unidirectional liquid nitrogen freezing method. Field emission scanning electron microscopy( FESEM) images indicate that the PNIPAM /PAA fibers are rounded,randomly orientated and interweaved. 展开更多
关键词 interpenetrating polymer network(IPN) structure pH and temperature sensitivity thermo-thickening self-assembly
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Flow Properties of Entrained Flow Gasifier Fine Slag and Network Structure of its Molten Slag
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作者 ZHOU Li REN Qiangqiang +2 位作者 YANG Guiyun XU Jing LI Wei 《Journal of Thermal Science》 SCIE EI CAS CSCD 2023年第5期1878-1888,共11页
The entrained flow gasification has been identified as the most promising gasification technology.Serious environmental pollution and waste of land resources are caused by the increasing amount of storage and producti... The entrained flow gasification has been identified as the most promising gasification technology.Serious environmental pollution and waste of land resources are caused by the increasing amount of storage and production of coal gasification slag.The aim of this work is to explore the feasibility of high-temperature combustion and melting technology for treating coal gasification fine slag and determine the important parameters of system operation.The flow properties and molten slag structure characteristics of three fine slags from different entrained flow gasifiers were studied.Depending on the melting mechanism of melt-dissolution,the melting time of fine slags is short.Three fine slags all produce glassy slags,which is conducive to slag discharge.The degree of polymerization of silicate melt is proportionate to the amount of SiO_(2)in the slag.A part of Al^(3+)exist in the form of[AlO_(4)]^(5-)because of the effect of CaO and Na_(2)O,as the network former.Finally,the degree of polymerization of the three type molten slag was calculated by considering the role of Si and Al in molten slag and the property of each one. 展开更多
关键词 entrained flow gasification slag fusion process viscosity temperature characteristic molten slag aluminosilicate network structure
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Influence of Al_(2)O_(3)/SiO_(2) Ratio on the Structure and Properties of Na^(+)/K^(+)Ion Exchange Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) Glasses
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作者 吴建磊 CHEN Junzhu +4 位作者 TIAN Xiaokun LI Jiahao GAO Wenkai YUE Yunlong 康俊峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期606-612,共7页
In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)... In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)O_(3)/SiO_(2) ratio,the simple structural units Q_(1) and Q_(2) transformed into highly aggregated structural units Q_(3) and Q_(4),indicating the increase of polymerization degree of glass network.Meanwhile,the coefficient of thermal expansion decreased from 9.23×10^(-6)℃^(-1) to 8.88×10^(-6)℃^(-1).The characteristic temperatures such as melting,forming,softening and glass transition temperatures increased with the increase of Al_(2)O_(3)/SiO_(2) ratio,while the glasses working temperature range became narrow.The increasing Al_(2)O_(3)/SiO_(2) ratio and prolonging ion-exchange time enhanced the surface compressive stress(CS)and depth of stress layer(DOL).However,the increase of ion exchange temperature increased the DOL and decreased the CS affected by stress relaxation.There was a good linear relationship between stress relaxation and surface compressive stress.Chemical strengthening significantly improved the hardness of glasses,which reached the maximum value of(622.1±10)MPa for sample with Al_(2)O_(3)/SiO_(2) ratio of 0.27 after heat treated at 410℃for 2 h. 展开更多
关键词 network structure viscosity ion exchange aluminosilicate glass
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Effect of Fe_(2)O_(3)on the Structure,Physical Properties and Crystallization of CaO-Al_(2)O_(3)-SiO_(2)Glass
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作者 张峰 XIONG Dehua +7 位作者 谢俊 张继红 HAN Jianjun CHEN Dequan WEN Zhongquan FAN Zhenhua CHEN Lina SUN Tengfei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期954-961,共8页
The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structur... The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structure,thermal and mechanical properties,and crystallization behavior changes were investigated by nuclear magnetic resonance spectrometer,Fourier-transform infrared spectro-photometer,X-ray diffractometer,differential scanning calorimetry and field emission scanning electron microscope measurements.The change of Q^(n)in glass structures reveals the glass network connectivity decreases due to the increasing content of Fe_(2)O_(3)addition,resulting in the increasing of non-bridging number in glass structure.The glass densities slightly rise from 2.644 to 2.681 g/cm^(3),while Vickers’s hardness increases at first,from 6.469 to 6.901 GPa,then slightly drops to 6.745 GPa,with Fe_(2)O_(3)content increase.There is almost no thermal expansion coefficient change from different Fe_(2)O_(3)content.The glass transmittance in visible range gradually decreases with higher Fe_(2)O_(3)content,resulting from the strong absorption of Fe^(2+)and Fe^(3+)ions.The calculated activation energy from thermal analysis results first decreases from 282.70 to 231.18 kJ/mol,and then increases to 244.02 kJ/mol,with the Fe_(2)O_(3)content increasing from 0.10wt%to 1.30wt%.Meanwhile,the maximum Avrami constant of 2.33 means the CAS glasses exhibit two-dimensional crystallization.All of the CAS glass-ceramics samples contain main crystal phase of anorthite,the microstructure appears lamellar and columnar crystals. 展开更多
关键词 calcium aluminosilicate glass network structure physical properties CRYSTALLIZATION
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Drivers for Inter-city Innovation Networks Across Chinese Cities:Modelling Physical Versus Intangible Effects
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作者 GAO Yujie SCHERNGELL Thomas NEULÄNDTNER Martina 《Chinese Geographical Science》 SCIE CSCD 2024年第4期706-721,共16页
Cross-region innovation is widely recognized as an important source of the long-term regional innovation capacity.In the recent past,a growing number of studies has investigated the network structure and mechanisms of... Cross-region innovation is widely recognized as an important source of the long-term regional innovation capacity.In the recent past,a growing number of studies has investigated the network structure and mechanisms of cross-region innovation collaboration in various contexts.However,existing research mainly focuses on physical effects,such as geographical distance and high-speed railway connections.These studies ignore the intangible drivers in a changing environment,the more digitalized economy and the increasingly solidified innovation network structure.Thus,the focus of this study is on estimating determinants of innovation networks,especially on intangible drivers,which have been largely neglected so far.Using city-level data of Chinese patents(excluding Hong Kong,Macao,and Taiwan Province of China),we trace innovation networks across Chinese cities over a long period of time.By integrating a measure on Information and Communications Technology(ICT)development gap and network structural effects into the general proximity framework,this paper explores the changing mechanisms of Chinese innovation networks from a new perspective.The results show that the structure of cross-region innovation networks has changed in China.As mechanisms behind this development,the results confirm the increasingly important role of intangible drivers in Chinese inter-city innovation collaboration when controlling for effects of physical proximity,such as geographical distance.Since digitalization and coordinated development are the mainstream trends in China and other developing countries,these countries'inter-city innovation collaboration patterns will witness dramatic changes under the influence of intangible drivers. 展开更多
关键词 inter-city innovation network co-patents information and communications technology development network structural effect spatial interaction model China
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