The aim of study is to investigate the removal ability of some natural adsorbents for fluoride ion from aqueous solution. The batch dynamic adsorption method was carried out at neutral pH as the functions of contact t...The aim of study is to investigate the removal ability of some natural adsorbents for fluoride ion from aqueous solution. The batch dynamic adsorption method was carried out at neutral pH as the functions of contact time, adsorbent dose, adsorbate concentration, temperature and effect of co-anions, which are commonly present in water. The sorption kinetics and equilibrium adsorption isotherms of fluoride on natural adsorbing materials had been investigated at afore-mentioned optimized. Equilibrium adsorption isotherms, viz., Freundlich and Langmuir isotherms were investigated. Lagergren and Morris-Weber kinetic equations were employed to find the rate constants. The negative enthalpy ΔH = -46.54 KJ·mol-1 and Gibbs free energy calculated was ΔG288-333—(2.07785, 3.08966, 4.1064, 4.90716 and 5.38036 KJ·mol-1) respectively, envisage exothermic and spontaneous nature of sorption.展开更多
Modeling and forecasting of the groundwater water table are a major component of effective planning and management of water resources. One way to predict the groundwater level is analysis using a non-deterministic mod...Modeling and forecasting of the groundwater water table are a major component of effective planning and management of water resources. One way to predict the groundwater level is analysis using a non-deterministic model. This study assessed the performance of such models in predicting the groundwater level at Kashan aquifer. Data from 36 piezometer wells in Kashan aquifer for 1999 to 2010 were used. The desired statistical interval was divided into two parts and statistics for 1990 to 2004 were used for modeling and statistics from 2005 to 2010 were used for valediction of the model. The Akaike criterion and correlation coefficients were used to determine the accuracy of the prediction models. The results indicated that the AR(2) model more accurately predicted ground water level in the plains;using this model, the groundwater water table was predicted for up to 60 mo.展开更多
This work deals with isothermal and non-isothermal crystallization kinetics of electrically conductive polyvinylidene fluoride/poly(ethylene terephthalate) (PVDF/PET) based composites. It completes our previous work i...This work deals with isothermal and non-isothermal crystallization kinetics of electrically conductive polyvinylidene fluoride/poly(ethylene terephthalate) (PVDF/PET) based composites. It completes our previous work in which we related the crystallinity of these conductive PVDF/PET based composites to their through-plane resistivity [1]. Isothermal crystallization was described using the logarithmic form of the Avrami equation and it was observed that the crystallization rate of the PVDF phase inside the composite became slower compared to that of neat PVDF. In non-isothermal crystallization, the Avrami exponent of PVDF phase did not show any noticeable variation;however, that of PET phase, which contains the major part of the conductive carbon black (CB) and graphite (GR) additives, showed an evident decrease compared with neat PET. It was also observed that, at the same cooling rate, the crystallization rate of PVDF and PET phases inside the composite was slower than that of neat PVDF and PET.展开更多
Water sorption isotherms are unique for individual food materials and can be used directly to predict shelf life and determine proper storage conditions. In this context, the aim of this study was to determine the moi...Water sorption isotherms are unique for individual food materials and can be used directly to predict shelf life and determine proper storage conditions. In this context, the aim of this study was to determine the moisture adsorption isotherms of amaranth flour at 15℃, 25℃ and 35℃ in a range of water activity from 0.1 to 0.9. Experimental data were modeled using five equations commonly applied in the foods field. The goodness of the fit for each isotherm model was evaluated through the coefficient of determination, the variance due to error and the confidence interval of the estimated parameters. All models can predict the adsorption isotherms of amaranth flour, but the GAB equation gives a better understanding of the observed sorption behavior. Estimated adsorption monolayer water contents ranged from 6.4 g to 7.2 g of water per 100 g of dry material. It was observed by a weak dependence of water activity with temperature. For ensuring microbiological stability, water content in amaranth flour should not be higher than 13 g of water per 100 g of dry material.展开更多
Fluid flow and mixing of molten steel in a twin-slab-strand continuous casting tundish were investigated using a mixing model under non-isothermal conditions.This model led to a set of ordinary differential equations ...Fluid flow and mixing of molten steel in a twin-slab-strand continuous casting tundish were investigated using a mixing model under non-isothermal conditions.This model led to a set of ordinary differential equations that were solved with a Runge-Kutta algorithm.Steady state water modeling was carried out under non-isothermal conditions.Experimental data obtained from the water model were used to calibrate the mixing model.Owing to the presence of a mixed convection in the non-isothermal conditions,a channelizing flow would be created in the fluid inside the tundish.A mixing model was designed that was capable of predicting RTD（residence time distribution）curves for different cases in non-isothermal conditions.The relationship between RTD parameters and the Tu（tundish Richardson number）was obtained for various cases under non-isothermal conditions.The results show that the RTD parameters were completely different under isothermal and non-isothermal conditions.The comparison of the RTD curves between the isothermal and non-isothermal conditions presents that the extent of mixing in the tundish in non-isothermal conditions is lower than the mixing extent in isothermal conditions.展开更多
文摘The aim of study is to investigate the removal ability of some natural adsorbents for fluoride ion from aqueous solution. The batch dynamic adsorption method was carried out at neutral pH as the functions of contact time, adsorbent dose, adsorbate concentration, temperature and effect of co-anions, which are commonly present in water. The sorption kinetics and equilibrium adsorption isotherms of fluoride on natural adsorbing materials had been investigated at afore-mentioned optimized. Equilibrium adsorption isotherms, viz., Freundlich and Langmuir isotherms were investigated. Lagergren and Morris-Weber kinetic equations were employed to find the rate constants. The negative enthalpy ΔH = -46.54 KJ·mol-1 and Gibbs free energy calculated was ΔG288-333—(2.07785, 3.08966, 4.1064, 4.90716 and 5.38036 KJ·mol-1) respectively, envisage exothermic and spontaneous nature of sorption.
文摘Modeling and forecasting of the groundwater water table are a major component of effective planning and management of water resources. One way to predict the groundwater level is analysis using a non-deterministic model. This study assessed the performance of such models in predicting the groundwater level at Kashan aquifer. Data from 36 piezometer wells in Kashan aquifer for 1999 to 2010 were used. The desired statistical interval was divided into two parts and statistics for 1990 to 2004 were used for modeling and statistics from 2005 to 2010 were used for valediction of the model. The Akaike criterion and correlation coefficients were used to determine the accuracy of the prediction models. The results indicated that the AR(2) model more accurately predicted ground water level in the plains;using this model, the groundwater water table was predicted for up to 60 mo.
文摘This work deals with isothermal and non-isothermal crystallization kinetics of electrically conductive polyvinylidene fluoride/poly(ethylene terephthalate) (PVDF/PET) based composites. It completes our previous work in which we related the crystallinity of these conductive PVDF/PET based composites to their through-plane resistivity [1]. Isothermal crystallization was described using the logarithmic form of the Avrami equation and it was observed that the crystallization rate of the PVDF phase inside the composite became slower compared to that of neat PVDF. In non-isothermal crystallization, the Avrami exponent of PVDF phase did not show any noticeable variation;however, that of PET phase, which contains the major part of the conductive carbon black (CB) and graphite (GR) additives, showed an evident decrease compared with neat PET. It was also observed that, at the same cooling rate, the crystallization rate of PVDF and PET phases inside the composite was slower than that of neat PVDF and PET.
基金support of the Swedish International Development Agency(Sida).
文摘Water sorption isotherms are unique for individual food materials and can be used directly to predict shelf life and determine proper storage conditions. In this context, the aim of this study was to determine the moisture adsorption isotherms of amaranth flour at 15℃, 25℃ and 35℃ in a range of water activity from 0.1 to 0.9. Experimental data were modeled using five equations commonly applied in the foods field. The goodness of the fit for each isotherm model was evaluated through the coefficient of determination, the variance due to error and the confidence interval of the estimated parameters. All models can predict the adsorption isotherms of amaranth flour, but the GAB equation gives a better understanding of the observed sorption behavior. Estimated adsorption monolayer water contents ranged from 6.4 g to 7.2 g of water per 100 g of dry material. It was observed by a weak dependence of water activity with temperature. For ensuring microbiological stability, water content in amaranth flour should not be higher than 13 g of water per 100 g of dry material.
文摘Fluid flow and mixing of molten steel in a twin-slab-strand continuous casting tundish were investigated using a mixing model under non-isothermal conditions.This model led to a set of ordinary differential equations that were solved with a Runge-Kutta algorithm.Steady state water modeling was carried out under non-isothermal conditions.Experimental data obtained from the water model were used to calibrate the mixing model.Owing to the presence of a mixed convection in the non-isothermal conditions,a channelizing flow would be created in the fluid inside the tundish.A mixing model was designed that was capable of predicting RTD（residence time distribution）curves for different cases in non-isothermal conditions.The relationship between RTD parameters and the Tu（tundish Richardson number）was obtained for various cases under non-isothermal conditions.The results show that the RTD parameters were completely different under isothermal and non-isothermal conditions.The comparison of the RTD curves between the isothermal and non-isothermal conditions presents that the extent of mixing in the tundish in non-isothermal conditions is lower than the mixing extent in isothermal conditions.
