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Evaluation of Total Hydrocarbons Levels and Traces Metals in Water and Sediment from Main Outfall Drain in Al-Nassiriya City/Southern Iraq 被引量:1
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作者 Afrah A. Maktoof Basim Y. ALKhafaji Zahraa Z. Al-janabi 《Natural Resources》 2014年第13期795-803,共9页
This study was conducted during Dec2011-Nov2012 on three stations located in the south sector of Main Outfall Drain (MOD) River. Station 1 was near Al-Holandee Bridge which was the general carriage way in the center o... This study was conducted during Dec2011-Nov2012 on three stations located in the south sector of Main Outfall Drain (MOD) River. Station 1 was near Al-Holandee Bridge which was the general carriage way in the center of Al-Nassiriya city, station 2 was 20 km far from the first station, while station 3 was in the beginning of the new branch. This study reveals the Seasonal Variation of Total petroleum hydrocarbons (TPHs) in both surface waters, sediment and it is related with trace metals nickel and vanadium in water (dissolved, particulate) and sediment (residual and exchangeable) phases. Also, the study shows the relationships between the concentration of Ni and V with Total Organic Carbon (TOC%) in the sediment. 展开更多
关键词 total Petroleum hydrocarbons Traces METALS Water Sediment MAIN OUTFALL DRAIN
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The Impact Of Oil Spill To The Total Petroleum Hydrocarbon(Tph)Concentration In Fishes At North Coastal Of Karawang Regency,West Java Province 被引量:1
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作者 Waluyo Dzikri Wahyudi +1 位作者 Amdani Herlina Adelina Meria Uli Sagala 《Journal of Marine Science》 2020年第2期11-18,共8页
The coastal area is one of the areas that is quite vulnerable to the threat of pollution caused by human activities,including pollution caused by oil spills(hydrocarbons)in the sea.The incident can be caused by severa... The coastal area is one of the areas that is quite vulnerable to the threat of pollution caused by human activities,including pollution caused by oil spills(hydrocarbons)in the sea.The incident can be caused by several factors including the explosion,leakage of petroleum pipelines on the seabed,leakage of tanks or petroleum tankers at sea and disposal of waste petroleum products into the environment.Oil spills continuously can cause environmental contamination and pollution both aquatic and terrestrial.If the petroleum hydrocarbons enter sea waters,some of them will be absorbed by aquatic organisms because the nature of the petroleum hydrocarbons is difficult to decompose in waters.The intentional and unintentional entry of hazardous and toxic substances into marine ecosystems such as petroleum hydrocarbons and chemical solvents resulting from industrial wastes has become a serious problem for human health and the environment.The purpose of this study was to determine the concentration of Total Petroleum Hydrocarbon(TPH)contained in fish in coastal waters of Karawang Regency,West Java Province.This research was conducted in September-November 2019 by taking several fish samples at Ciparage Jaya Fish Auction Place,Betok Mati and Sungai Buntu Rive with a total sample of 24 fish,and taking seawater samples in the three study sites.TPH analysis was carried out at the Integrated Chemistry Laboratory,Bogor Agricultural University.TPH values in fish at Ciparage-1,Ciparage-2,Betok Mati and Sungai Buntu stations,in general,have different mean values but are almost uniform,each at 6.82;6.82;7.45 and 5.12 mg/kg.Based on the average TPH concentration in fish,it can be said that the average TPH in fish at Betok Mati station is relatively higher compared to other stations.TPH values in all fish samples exceed the safe threshold,which is a maximum of 0.002 mg/kg.Based on the results of the Bioaccumulation factor(BAF)analysis showed that the average TPH in fish was 6.55 mg/kg and the average TPH in the waters was 11.23 mg/l,so the BAF value was 58.35 which means that the absorption rate of TPH by fish organisms against the concentration of TPH in the waters of 58.35%.The analysis shows that the value of Ecological Hazard Assessment(EHA)is 3743.33 which means that the level of influence of the hazard on ecosystems and organisms is 3743.33.This value exceeds the recommended threshold according to the European Union,which is a maximum of 0.002 mg/l. 展开更多
关键词 total petroleum hydrocarbon Bioaccumulation factor Ecological hazard assessment Coastal Karawang Regency
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Comparison on Determination Results of Methane and Total Hydrocarbons by Glass Syringe Method and Air Bag Method
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作者 Chen Miao Huang Yiyao +1 位作者 Guo Yan Chen Shuchi 《Meteorological and Environmental Research》 CAS 2019年第4期106-109,共4页
Samples at different setting time were determined by glass syringe method and air bag method, and their results were analyzed. The results showed that concentrations of methane and total hydrocarbons obviously decline... Samples at different setting time were determined by glass syringe method and air bag method, and their results were analyzed. The results showed that concentrations of methane and total hydrocarbons obviously declined with the prolonging of setting time by glass syringe method, and recovery rate of sample declined to 60% after 8 h. In air bag method, analysis results of methane and total hydrocarbons were stabler, and recovery rate of sample was 93% after 8 h. 展开更多
关键词 SYRINGE AIR BAG METHANE total hydrocarbons
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Laboratory Design Criteria for Monitoring Biostimulated Bioremediation of a Crude Oil Contaminated Soil in Niger Delta Using Total Petroleum Hydrocarbon
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作者 Justin Nnaemeka Okorondu 《Journal of Geoscience and Environment Protection》 2023年第1期139-149,共11页
The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/... The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/sediment in muddy, dry soil and wetlands. Though, there have been varied environmental conditions that have hampered the success of the bioremediation process. This study has evaluated the effectiveness of a biostimulated bioremediation of crude oil-impacted soil using some design criteria—nutrient amendment (NPK fertilizer) and moisture content. Soil sample sets—A, B, C, D, E, F, and G were impacted with crude oil at a ratio of 10 g/kg and amended with varying amounts of nutrient 30, 60, and 80 g of N.P.K fertilizer. The medium for the inoculation of the nutrient was water and the volume of water applied varied from 30% to 80% saturation. The soil sample sets were harvested at an interval of 3 months for 180 days to determine the concentration of total petroleum hydrocarbon left in the soil. The analysis of the total petroleum hydrocarbon was achieved using a GC-FID with a capillary column and autosampler. Soil samples were extracted with mixed solvent dichloromethane and acetone at a 1:1 ratio. The total petroleum hydrocarbon results show that biostimulated bioremediation achieved better results in soil sample sets with low moisture content (30% water saturation) and moderate nutrient amendment. The biodegradation of the sample sets with high water saturation and a high nutrient amendment was slow with a higher amount of total hydrocarbon content at the end of the 180 days. The variability in the hydrocarbon degradation pattern of contaminated soil shows that biostimulated bioremediation achieved better results in soils with low moisture content than in soil environments with high water content (saturation). More so, nutrient overdosing of the substrate hampered the effectiveness of the remediation process. 展开更多
关键词 BIOREMEDIATION SOIL NUTRIENT Moisture Content total Petroleum hydrocarbon Crude Oil
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Degradation Characteristics and Community Structure of a Hydrocarbon Degrading Bacterial Consortium 被引量:8
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作者 Li Zheng Gu Guizhou +1 位作者 Zhao Chaocheng Zhao Dongfeng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2015年第3期15-24,共10页
A hydrocarbon degrading bacterial consortium KO5-2 was isolated from oil-contaminated soil of Karamay in Xinjiang, China, which could remove 56.9% of 10 g/L total petroleum hydrocarbons(TPH) at 30 ℃ after 7 days of i... A hydrocarbon degrading bacterial consortium KO5-2 was isolated from oil-contaminated soil of Karamay in Xinjiang, China, which could remove 56.9% of 10 g/L total petroleum hydrocarbons(TPH) at 30 ℃ after 7 days of incubation, and could also remove 100% of fluorene, 98.93% of phenanthrene and 65.73% of pyrene within 3, 7 and 9 days, respectively. Twelve strains from six different genera were isolated from KO5-2 and only eight ones were able to utilize the TPH. The denaturing gradient gel electrophoresis(DGGE) was used to investigate the microbial community shifts in five different carbon sources(including TPH, saturated hydrocarbons, fluorene, phenanthrene and pyrene). The test results indicated that the community compositions of KO5-2 in carbon sources of TPH and saturated hydrocarbons, respectively, were roughly the same, while they were distinctive in the three different carbon sources of PAHs. Rhodococcus sp. and Pseudomonas sp. could survive in the five kinds of carbon sources. Bacillus sp., Sphingomonas sp. and Ochrobactrum sp. likely played key roles in the degradation of saturated hydrocarbons, PAHs and phenanthrene, respectively. This study showed that specific bacterial phylotypes were associated with different contaminants and complex interactions between bacterial species, and the medium conditions influenced the biodegradation capacity of the microbial communities involved in bioremediation processes. 展开更多
关键词 bacterial consortium community structure degradation characteristics total petroleum hydrocarbons (TPH) denaturing gradient gel electrophoresis (DGGE)
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Orderly coexistence and accumulation models of conventional and unconventional hydrocarbons in Lower Permian Fengcheng Formation,Mahu sag,Junggar Basin 被引量:7
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作者 ZHI Dongming TANG Yong +3 位作者 HE Wenjun GUO Xuguang ZHENG Menglin HUANG Liliang 《Petroleum Exploration and Development》 CSCD 2021年第1期43-59,共17页
By using the latest geological,seismic,drilling and logging data,this article studies the basic conditions for the formation of the total petroleum system and the orderly coexisting characteristics and accumulation mo... By using the latest geological,seismic,drilling and logging data,this article studies the basic conditions for the formation of the total petroleum system and the orderly coexisting characteristics and accumulation models of conventional&unconventional reservoirs in the Lower Permian Fengcheng Formation in the Junggar Basin.Controlled by thermal evolution,hydrocarbon generation and expulsion process of the high-quality source rocks in alkaline lake as well as the characteristics of multi-type reservoirs(conglomerate,sandstone,dolomite and shale),conventional structure-lithologic reservoirs and tight oil and shale oil reservoirs controlled by source-reservoir structure have been formed.On the plane,mature conventional reservoirs,medium-high mature tight oil,and medium-high mature shale oil reservoirs coexist orderly from the slope area around Mahu sag to the sag.Based on the orderly coexisting characteristics of conventional and unconventional reservoirs in the Fengcheng Formation,it is clear that oil and gas in the Fengcheng Formation accumulate continuously over a large area in three accumulation models:integrated source-reservoir,source-reservoir in close contact,and separated source-reservoir model.The three accumulation models differ in relationship between source-reservoir structure,reservoir lithology and spatial distribution,hydrocarbon migration,oil and gas type.It is pointed out that the conventional&unconventional oil and gas should be explored and developed as a whole to achieve an overall breakthrough of the total petroleum system.This study is expected to enrich the geological theory of oil and gas enrichment in continental basins and to provide an analogy for exploration and research in other hydrocarbon-rich sags. 展开更多
关键词 Junggar Basin Lower Permian Fengcheng Formation unconventional hydrocarbons orderly coexistence accumulation models shale oil total petroleum system
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Petroleum Hydrocarbon Transport through Saturated-unsaturated Media: A Numerical Model and Practice
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作者 Wu Keqin Fu Jianfang Miao Tao 《Meteorological and Environmental Research》 CAS 2019年第3期69-73,共5页
The mathematical model of migration of total petroleum hydrocarbons in unsaturated media was described,including convection,molecular diffusion,mechanical dispersion and adsorption,and chemical reactions.By finite ele... The mathematical model of migration of total petroleum hydrocarbons in unsaturated media was described,including convection,molecular diffusion,mechanical dispersion and adsorption,and chemical reactions.By finite element method,a numerical model of evaluating petroleum hydrocarbon migration through contaminated soils was created and applied to the environmental investigations of a relocated mechanical factory in Shanghai.The model consisted of three compacted soil layers:plain fill,sandy silt and silty clay.The results showed that pollutants in the sandy silt traveled faster than that in the plain fill and silty clay.The same decreasing trend of migration velocity was observed in all of the three soil layers.After 180 d,the concentrations of pollutants in the sandy silt can be as low as 40% of the original maximum,while its counterpart in the silty clay is 64%. 展开更多
关键词 total PETROLEUM hydrocarbons Contaminated SITE SATURATED-UNSATURATED MEDIA Finite element analysis
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Reclamation of Smaller Volumes of Petroleum Hydrocarbon Contaminated Soil Using an Innovative Reactor System: A Case Study Evaluation of the Design
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作者 Mark E. Zappi Rakesh Bajpai +2 位作者 Rafael Hernandez Katherine Taconi Daniel Gang 《Agricultural Sciences》 2017年第7期600-615,共16页
Petroleum products contamination is a world-wide problem that threatens polluting groundwater and surface water systems. However, the problem is not only large-scale in scope when viewed from a case-by-case basis. Man... Petroleum products contamination is a world-wide problem that threatens polluting groundwater and surface water systems. However, the problem is not only large-scale in scope when viewed from a case-by-case basis. Many fueling, construction, agricultural, and industrial activities result in the problem of managing smaller quantities of these soils from an ecological safety perspective. Landfilling has been the disposal method of choice in the US;however, this option is becoming economically prohibitive and it does not really offer a true degradation fate for the pollutants. This study focused on the proving of an innovative biocell design that afforded a high level of petroleum degradation within a simple and cost effective design. Additionally, the design offered a remediation solution for sites not easily accessed. Soil contaminated with both diesel fuel and gasoline collected from a former filling station was used in this on-site remediation case study. Rapid biodegradation of the petroleum products were observed at the initiation of the study with rates leveling off as the study progressed with the final total petroleum hydrocarbon concentration being 10 mg/kg at Day 90. Oxygen uptake rates were monitored and found to nicely track both microbial activity and pollutant removal dynamics. The biocell design met all expectations by being effective, yet simple to build and operate. 展开更多
关键词 BIOREMEDIATION total Petroleum hydrocarbons Biocells Oil CONTAMINATION Cost-Effective Management Practices Small Quantity CONTAMINATION
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Bioprospecting of Hydrocarbonoclastic Representative Bacteria
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作者 Asime Oba Barka John +6 位作者 Jamilu Garba Asitonka James Oba Kwata Veronica John Stephen Bitrus Balami Okeke Uchechukwu Jasini Athanda Musa Anthony Ofili 《Journal of Environmental Protection》 2022年第6期449-458,共10页
This study was designed and carried out to characterize hydrocarbonoclastic microbial communities in soil polluted with artisanal refined hydrocarbon at Trans Amadi, Phalga Local Government Area of Rivers State, Niger... This study was designed and carried out to characterize hydrocarbonoclastic microbial communities in soil polluted with artisanal refined hydrocarbon at Trans Amadi, Phalga Local Government Area of Rivers State, Nigeria. Heterotrophic bacteria count ranged from 8.0 × 10<sup>5</sup> cfu/gm for sample TSAS1, and 2.1 × 10<sup>6</sup> cfu/gm for sample TSAS2 while TSAS3 was too numerous to count (TNTC). Hydrocarbon utilizing bacteria count ranged from 1.1 × 10<sup>5</sup> cfu/gm for TSAS1, and 5.9 × 10<sup>4</sup> cfu/gm for TSAS2, while TSAS3 was 5.4 × 10<sup>4</sup> cfu/gm. Physiochemical parameters of the soil were determined. The ranges obtained were pH 6.6, conductivity 125 μs/cm, temperature 27.3°C, moisture 7.72, total nitrogen 0.056%, phosphate 1.554 ppm, potassium 145.87 ppm, lead 7.02 ppm, cadmium 0.41 ppm, nickel 1.96 ppm, copper 1.14 ppm, total petroleum hydrocarbon 1487.24181 ppm, polycyclic aromatic hydrocarbon 12.85287 ppm. Isolates of hydrocarbon utilizing bacteria characterized belonged to the genera Escherichia coli, Klebsiella sp., Lactobacillus sp., Enterobacter sp., Serratia sp., and Proteus sp. The findings in this study have revealed the abilities of these groups of bacteria to be employed in bioremediation/biodegradation clean-up practices. Thus the polluted soil may harbour important genera of bacterial species that may have beneficial applications in environmental microbiology for future remediation processes. 展开更多
关键词 BIOPROSPECTING hydrocarbonoclastic Bacteria total Petroleum hydrocarbons Polycyclic Aromatic hydrocarbons Crude Oil SOIL
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Assessing Earthworm Influence on Remediating Potentials of Soil Micro-Organisms, and Bioavailable Hydrocarbon Pollutant in the Niger Delta, Nigeria
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作者 Tambeke Nornu Gbarakoro Victoria Oluwaseyi Koshoffa Francis David Sikoki 《Journal of Geoscience and Environment Protection》 2023年第3期277-292,共16页
In the Niger Delta region of Nigeria, oil explorations and exploitations abound, causing environmental pollution with serious consequences on soil ecosystem and its biodiversity. In spite of the relationship between m... In the Niger Delta region of Nigeria, oil explorations and exploitations abound, causing environmental pollution with serious consequences on soil ecosystem and its biodiversity. In spite of the relationship between microbes and fauna in soil ecosystem, such that both organisms can metabolize certain range of petroleum hydrocarbon substrates with the fauna influencing the remediation potentials of bacteria, yet soil fauna is still not fully considered in bioremediation. The influence of earthworm;Lumbricus terrestris on the remediating potentials of soil bacteria in petroleum hydrocarbon contaminated soils was investigated. Eighteen pots were filled with 700 g of soil each, with nine treated with mixture of 3 levels crude oil and remediated with earthworm, while the other nine had no earthworm. The total petroleum hydrocarbon (TPH), soil physical, nutrient compositions, and TPH degrading bacteria biodiversity were determined before contamination or commencement of study and thirty days after. The results showed a decrease in TPH concentration of 55.58%, 62.57% and 67.07% in 1 ml, 2 ml and 3 ml crude oil contaminated soil, respectively. Species richness and abundance of bacteria organisms increased with high relative abundance in soils remediated with earthworms, hydrocarbon utilizing bacteria increased from less than 0.1 cfu/g to 0.4 cfu/g, and total heterotrophic bacteria 1.6 cfu/g at the end of the study. Earthworms increased rate of remediation potentials of bacteria, such that within 30 days post remediation treatment, 34.14% of reduced concentration was achieved over soil samples without earthworms at 3 ml, and 25.14% at 2 ml concentration. Reduction in pH levels in remediated soils was between 6.39 to 6.17 and 6.74 to 6.72 in unremediated soils, while moisture content was 6.73% to 6.77% unremediated and 5.85% to 6.62% in earthworm remediated soils. Total organic carbon, nitrates in soils inoculated with earthworms were lower in concentration than those without earthworms. Reverse was the case with potassium, phosphate and phosphorous concentrations which were above those without earthworms. Results indicate statistically, significant difference between reduction in TPH in earthworm remediated soils and unremediated soils, pointing out that earthworm is a good candidate for facilitation of bacteria remediation-petroleum hydrocarbon contamination. 展开更多
关键词 Petroleum hydrocarbon Contamination Bacteria Biodiversity Soil Fauna total Organic Carbon NITRATES
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Prognostication of hydrocarbon generative potential in the onshore and offshore Niger Delta, Nigeria using TOC content and rock-eval pyrolysis techniques
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作者 Nyantakyi E.K. Li Tao +2 位作者 Hu Wangshui Borkloe J.K. Nagre R.D. 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2014年第2期138-144,共7页
This article prognosticates the hydrocarbon generation potential of core samples from fields A, B, C and D in Niger delta, Nigeria. The objectives of this study are to characterize the quality of these core samples by... This article prognosticates the hydrocarbon generation potential of core samples from fields A, B, C and D in Niger delta, Nigeria. The objectives of this study are to characterize the quality of these core samples by organic geochemical analyses. A total of ten core samples collected from fields A, B, C and D in Niger delta were analyzed using total organic carbon(TOC) content analysis, rock-eval pyrolysis technique. The analytical results of the studied core samples reveal that they have generally high total organic carbon contents(TOC), suggesting that conditions in the Niger delta favour organic matter production and preservation. There is a variation in the kerogen types and this may be attributed to the relative stratigraphic positions of the core samples within the Niger delta. The rock-eval results indicate that the samples from fields C and D contain predominantly Type II kerogen with a capacity to generate oil and gas and hence have good generative potential. The samples from fields A and B contain mainly Type III kerogen and are gas-prone with moderate generative potential. 展开更多
关键词 尼日尔三角洲 热解技术 尼日利亚 生烃潜力 TOC 岩石 潜力预测 干酪根类型
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Correlation of Sillimanite &Kaliophilite Minerals, TOC, Ro, and MBT from Drill Cutting of Well BS-03 in the Development of Shale Hydrocarbon, Brownshale Formation, Bengkalis Trough, Central Sumatra Basin, Indonesia
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作者 Aris Buntoro Mohammad Nurcholis +1 位作者 Basuki Rahmad Allen Haryanto Lukmana 《Open Journal of Yangtze Oil and Gas》 2020年第4期216-230,共15页
Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a bri... Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a brittle mineral as a potassium bearing in the sand-shale series, which contributes to the clay diagenesis process. In the development of shale hydrocarbon in the Brownshale formation in the Bengkalis Trough, Central Sumatra Basin, using the correlation of the XRD (bulk and clay oriented), TOC, Ro, and MBT analysis results from the drill cuttings of well BS-03, so that the fracable zone interval can be determined. From this correlation, it shows that the presence of sillimanite and kaliophilite minerals as minor minerals greatly affects the changes in shale character and hydrocarbon generation, where at depth intervals of 10,780 ft downward (sand series-shale) there is an interesting phenomenon, <i>i.e. </i> low MBT, low TOC, and high Ro, so it is believed that the depth interval of 10,780 ft downward is a fracable zone interval (brittle shale) which is a good candidate for hydraulic fracking planning, while the upper depth interval is a fracture barrier. 展开更多
关键词 Sillimanite & Kaliophilite Minerals TOC (total Organic Carbon) Ro (Vitrinite Reflectance) MBT (Methylene Blue Test) Shale hydrocarbon
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环境空气监测用氮中甲烷气体标准物质质量评估 被引量:2
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作者 王翀 吕怡兵 +7 位作者 杨婧 谭铃 吴海 丁萌萌 杨静 王德发 李和通 马焕敏 《中国环境监测》 CAS CSCD 北大核心 2024年第4期30-36,共7页
为了解和掌握当前环境空气非甲烷总烃监测所使用的氮中甲烷气体标准物质的质量状况,通过对全国范围内开展环境空气非甲烷总烃监测的实验室中的99家进行使用情况调查,发现共涉及35家制造商。选择其中使用占比较高的10家,另外再随机选取6... 为了解和掌握当前环境空气非甲烷总烃监测所使用的氮中甲烷气体标准物质的质量状况,通过对全国范围内开展环境空气非甲烷总烃监测的实验室中的99家进行使用情况调查,发现共涉及35家制造商。选择其中使用占比较高的10家,另外再随机选取6家,通过匿名采购等方式获取31瓶氮中甲烷气体标准物质。经两家测试单位分别测试后,采用归一化偏差(E_(n))法和相对偏差法两种方法评价所选标准物质的量值准确性和监测适用性,同时依照相关国家计量技术规范评估其证书完整性和规范性。结果显示,两种方法的评价结果一致。16家制造商中,14家的27瓶气体标准物质定值准确,2家的4瓶气体标准物质定值不准确;9家证书相对完整、规范,其余7家普遍存在缺少标准物质唯一标识等问题,部分制造商甚至存在涉嫌冒用证书、证书中的定值浓度超出认定范围等问题。鉴于氮中甲烷气体标准物质是保障非甲烷总烃监测结果准确性、可比性和可溯源性的重要基础,且制造商数量众多,建议使用者加强标准物质质量评估工作,并审查其所附证书的规范性。 展开更多
关键词 环境空气监测 非甲烷总烃 气体标准物质 质量评估
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燃煤机组烟气挥发性有机物排放特征 被引量:1
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作者 陈超 刘卫平 +6 位作者 汤国锋 丁一 张建伟 朱希峰 王家伟 汪涛 张永生 《洁净煤技术》 CAS CSCD 北大核心 2024年第3期161-169,共9页
为了解不同容量燃煤机组烟气挥发性有机物(VOCs)的排放特性和不同尾部空气污染物控制设备(APCDs)对VOCs的控制作用,在福建省国投云顶湄洲湾电力公司400 MW亚临界对冲燃烧机组和1 000 MW超超临界切圆燃烧机组进行在线法和离线法采样测试... 为了解不同容量燃煤机组烟气挥发性有机物(VOCs)的排放特性和不同尾部空气污染物控制设备(APCDs)对VOCs的控制作用,在福建省国投云顶湄洲湾电力公司400 MW亚临界对冲燃烧机组和1 000 MW超超临界切圆燃烧机组进行在线法和离线法采样测试,获取烟气中甲烷、非甲烷总烃和其他VOCs的全流程浓度。结果表明,1 000 MW机组SCR前的非甲烷总烃质量浓度(24.66 mg/m^(3))低于400 MW机组(33.36 mg/m^(3))。由于1 000 MW机组负荷和炉膛温度高,且煤在切圆燃烧炉内比对冲燃烧停留时间长,故煤燃烧更彻底。两机组SCR系统均能脱除超过70%的非甲烷总烃,400 MW和1 000 MW机组的SCR脱除效果分别为88.43%和74.32%。而在静电除尘过程(ESP)中,高压静电场可能会导致飞灰释放部分VOCs,增加烟气VOCs浓度。经所有APCDs后,400 MW机组和1 000 MW机组的VOCs排放质量浓度分别为8.40和8.47 mg/m^(3),整体脱除率为73.98%和63.02%,几乎未检出甲烷。离线测试结果:印尼煤燃烧后VOCs主要为正己烷、苯系物和苯甲醛。各固体样品(如煤、灰、石膏)有机物浓度分析显示,VOCs种类与机组大小无明显关联。这些发现有助于深入理解燃煤电厂对空气质量影响及优化污染控制设备设计。燃煤电厂实际运营中需依具体情况优化污染控制设备,以达到最大脱除效果,也需考虑机组大小和运行效率,有效控制VOCs排放。 展开更多
关键词 挥发性有机物 排放特性 印尼煤 机组容量 燃煤烟气 非甲烷总烃
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沧东凹陷孔二段页岩生排烃效率及对含油性的影响
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作者 冯家乐 杨升宇 +6 位作者 胡钦红 马斌玉 文家成 王旭阳 蒲秀刚 韩文中 张伟 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第2期45-56,共12页
渤海湾盆地沧东凹陷孔二段页岩油资源潜力巨大,且通过水平井钻控获得了稳产工业油流。应用常规热解和分步热解技术,优化生排烃物质平衡法,提出了基于原始生烃潜力和现今残余生烃潜力的页岩生烃和排烃效率氢指数平衡计算方法,并探索成熟... 渤海湾盆地沧东凹陷孔二段页岩油资源潜力巨大,且通过水平井钻控获得了稳产工业油流。应用常规热解和分步热解技术,优化生排烃物质平衡法,提出了基于原始生烃潜力和现今残余生烃潜力的页岩生烃和排烃效率氢指数平衡计算方法,并探索成熟度以外孔二段页岩排烃效率的主控因素及其与含油性的关系。选取深度和成熟度较为接近的样品,以排除成熟度这一公认的生排烃效率指标的影响。结果表明,页岩有机质丰度和类型、微观孔隙结构和岩石类型等是控制其生排烃效率的重要因素。Ⅲ型干酪根产物以轻烃为主,排烃效率变化大且普遍高于Ⅰ型和Ⅱ型干酪根。Ⅰ型和Ⅱ型干酪根在TOC超过3%以后,排烃效率随TOC的增加而增大。墨水瓶型孔对液态烃的滞留能力强于狭缝型孔;对气态烃而言墨水瓶型孔反而是利于排烃的优势通道。纹层状页岩比薄层状页岩具有更低的排烃效率。生排烃共同控制着页岩的含油量,页岩中含油量与排烃效率整体呈负相关,但与生烃潜力、生烃效率和滞留烃率的乘积呈明显的正相关性,展示了生排烃效率计算方法的可靠性和实用性。 展开更多
关键词 沧东凹陷 孔二段 页岩油 排烃效率 含油量 生烃潜力平衡法
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Geophysical prediction of organic matter abundance in source rocks based on geochemical analysis:A case study of southwestern Bozhong Sag,Bohai Sea,China 被引量:1
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作者 Xiang Wang Guang-Di Liu +5 位作者 Xiao-Lin Wang Jin-Feng Ma Zhen-Liang Wang Fei-Long Wang Ze-Zhang Song Chang-Yu Fan 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期31-53,共23页
The Bozhong Sag is the largest petroliferous sag in the Bohai Bay Basin,and the source rocks of Paleogene Dongying and Shahejie Formations were buried deeply.Most of the drillings were located at the structural high,a... The Bozhong Sag is the largest petroliferous sag in the Bohai Bay Basin,and the source rocks of Paleogene Dongying and Shahejie Formations were buried deeply.Most of the drillings were located at the structural high,and there were few wells that met good quality source rocks,so it is difficult to evaluate the source rocks in the study area precisely by geochemical analysis only.Based on the Rock-Eval pyrolysis,total organic carbon(TOC)testing,the organic matter(OM)abundance of Paleogene source rocks in the southwestern Bozhong Sag were evaluated,including the lower of second member of Dongying Formation(E_(3)d2L),the third member of Dongying Formation(E_(3)d_(3)),the first and second members of Shahejie Formation(E_(2)s_(1+2)),the third member of Shahejie Formation(E_(2)s_(3)).The results indicate that the E_(2)s_(1+2)and E_(2)s_(3)have better hydrocarbon generative potentials with the highest OM abundance,the E_(3)d_(3)are of the second good quality,and the E_(3)d2L have poor to fair hydrocarbon generative potential.Furthermore,the well logs were applied to predict TOC and residual hydrocarbon generation potential(S_(2))based on the sedimentary facies classification,usingΔlogR,generalizedΔlogR,logging multiple linear regression and BP neural network methods.The various methods were compared,and the BP neural network method have relatively better prediction accuracy.Based on the pre-stack simultaneous inversion(P-wave impedance,P-wave velocity and density inversion results)and the post-stack seismic attributes,the three-dimensional(3D)seismic prediction of TOC and S_(2)was carried out.The results show that the seismic near well prediction results of TOC and S_(2)based on seismic multi-attributes analysis correspond well with the results of well logging methods,and the plane prediction results are identical with the sedimentary facies map in the study area.The TOC and S_(2)values of E_(2)s_(1+2)and E_(2)s_(3)are higher than those in E_(3)d_(3)and E_(3)d_(2)L,basically consistent with the geochemical analysis results.This method makes up the deficiency of geochemical methods,establishing the connection between geophysical information and geochemical data,and it is helpful to the 3D quantitative prediction and the evaluation of high-quality source rocks in the areas where the drillings are limited. 展开更多
关键词 total organic carbon(TOC) Residual hydrocarbon generation potential(S_(2)) Geophysical prediction Seismic attribute Bozhong Sag Bohai Bay Basin
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直测法测定环境空气中非甲烷总烃的研究
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作者 王玉祥 白玛旺堆 +4 位作者 程滢 杨文武 吴莹 陈诚 秦艳红 《中国环保产业》 2024年第10期69-72,共4页
本研究建立了一种单通道低温捕集单氢火焰离子化检测器(FID)直接测定环境空气中甲烷和非甲烷总烃含量的方法。甲烷和非甲烷总烃在1000—5000ppb和50—1000ppb浓度内与其峰面积呈线性关系,检出限分别为14.99ppb和5.55ppb,精密度为0.72%—... 本研究建立了一种单通道低温捕集单氢火焰离子化检测器(FID)直接测定环境空气中甲烷和非甲烷总烃含量的方法。甲烷和非甲烷总烃在1000—5000ppb和50—1000ppb浓度内与其峰面积呈线性关系,检出限分别为14.99ppb和5.55ppb,精密度为0.72%—1.00%,准确性为-2.92%—4.54%;系统空白为0ppb和3.95ppb;零点漂移和量程漂移分别为-3.7—-0.9ppb和-0.30%—-0.12%,环境空气氧气和湿度对测定无明显影响,本方法满足环境空气非甲烷总烃连续自动监测技术规定的要求。 展开更多
关键词 非甲烷总烃 直测法 环境空气
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Sources of ambient non-methane hydrocarbon compounds and their impacts on O_(3) formation during autumn,Beijing 被引量:6
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作者 Fangjie Li Shengrui Tong +7 位作者 Chenhui Jia Xinran Zhang Deng Lin Wenqian Zhang Weiran Li Lili Wang Maofa Ge Lixin Xia 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第4期85-97,共13页
The field observation of 54 non-methane hydrocarbon compounds(NMHCs)was conducted from September 1 to October 20 in 2020 during autumn in Haidian District,Beijing.The mean concentration of total NMHCs was 29.81±1... The field observation of 54 non-methane hydrocarbon compounds(NMHCs)was conducted from September 1 to October 20 in 2020 during autumn in Haidian District,Beijing.The mean concentration of total NMHCs was 29.81±11.39 ppbv during this period,and alkanes were the major components.There were typical festival effects of NMHCs with lower concentration during the National Day.Alkenes and aromatics were the dominant groups in ozone formation potential(OFP)and OH radical loss rate(L_(OH)).The positive matrix factorization(PMF)running results revealed that vehicular exhaust became the biggest source in urban areas,followed by liquefied petroleum gas(LPG)usage,solvent usage,and fuel evaporation.The box model coupled with master chemical mechanism(MCM)was applied to study the impacts of different NMHCs sources on ozone(O_(3))formation in an O_(3)episode.The simulation results indicated that reducing NMHCs concentration could effectively suppress O_(3)formation.Moreover,reducing traffic-related emissions of NMHCs was an effective way to control O_(3)pollution at an urban site in Beijing. 展开更多
关键词 non-methane hydrocarbon compounds Festival effects OZONE Source apportionment Master chemical mechanism
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利用直井、导眼井和水平井确定水平井钻遇有效厚度——以L油田C区块为例
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作者 张豆娟 郭海敏 +3 位作者 张奎华 傅爱兵 肖丽 陈存元 《长江大学学报(自然科学版)》 2024年第6期68-78,共11页
关于水平井钻遇位置的有效厚度如何合理确定,目前还没有很好的解决办法。因此探讨如何综合利用直井、导眼井以及水平井资料确定水平井钻遇位置有效厚度的问题十分必要。首先结合区块内直井、导眼井和水平井的资料综合建立相对比较完善... 关于水平井钻遇位置的有效厚度如何合理确定,目前还没有很好的解决办法。因此探讨如何综合利用直井、导眼井以及水平井资料确定水平井钻遇位置有效厚度的问题十分必要。首先结合区块内直井、导眼井和水平井的资料综合建立相对比较完善的有效厚度标准,依据试油、试采、有效厚度标准、测录井资料、地层对比以及井所处的构造位置综合识别直井、导眼井和水平井的油层。然后由直井、导眼井资料综合确定单井有效厚度和目的层段的平均净毛比。对于井轨迹基本顺构造线的水平井,根据测井解释油层段、井斜、方位计算出油层段钻遇的垂直厚度,将钻遇垂直厚度乘以目的层段的平均净毛比计算水平井钻遇位置的有效厚度。最后综合井轨迹基本顺构造线的水平井钻遇位置的有效厚度和直井、导眼井的有效厚度来绘制储量计算单元的有效厚度等值图,其中水平井钻遇位置的有效厚度对于直井井控较差的储量计算单元的有效厚度等值图绘制具有重要参考价值。 展开更多
关键词 水平井 随钻资料 自然伽马相对值 全烃相对值 钻遇有效厚度
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微型气体监测仪比对用非甲烷总烃采样装置
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作者 张亚飞 李亚飞 李学辉 《山东化工》 CAS 2024年第2期236-238,共3页
设计出一种微型气体监测仪比对用非甲烷总烃采样装置,并描述其具体结构和使用方法。该采样装置包括承接组件、导向组件和过滤组件。承接组件包括装配筒、承接辊,主要是对装置结构起到承接作用,外接进风管的装配筒内部设有电加热网和随... 设计出一种微型气体监测仪比对用非甲烷总烃采样装置,并描述其具体结构和使用方法。该采样装置包括承接组件、导向组件和过滤组件。承接组件包括装配筒、承接辊,主要是对装置结构起到承接作用,外接进风管的装配筒内部设有电加热网和随动叶轮,可以对抽取的环境废气进行加热,规避温湿度的影响。导向组件包括导向环、弧形导向边、链轮传动组、传动杆和辅助辊,不仅起到定向导向作用,而且凸部的传感器能够触发驱动装置和链轮传动组,通过齿轮带动放卷辊和收卷辊的定向运动。过滤组件包括保护壳、清洁辊、控制器、齿轮组、放卷辊、收卷辊和滤网布,滤网布对从弧形采样口进入的气体进行过滤,当对应弧形采样口处的滤网布堵塞满杂质时,进而触发启动驱动装置使得放卷辊放卷滤网布,收卷辊收卷滤网布,从而更换滤网布的使用位置,避免对应弧形采样口处的滤网布产生堵塞,影响采样样品气体的质量。该采样装置整体结构简单、易操作,能够显著提高样品气体的采样质量。 展开更多
关键词 气体监测仪 非甲烷总烃 采样装置 过滤组件
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