This paper creates 3D solid model and assembly of U RJ 92-6 oil tank and analyses its strength by integrated CAD/CAE/CAM software I-D EAS. Through integrated simulation in computer, design efficiency and quality of oi...This paper creates 3D solid model and assembly of U RJ 92-6 oil tank and analyses its strength by integrated CAD/CAE/CAM software I-D EAS. Through integrated simulation in computer, design efficiency and quality of oil tank is greatly improved. Adopting integrated CAD/CAE/CAM software to carry out integrated research to equ ipment and products, we will be able to take overall analysis in aspects of 3-D solid modeling, pre-assembly and strength, etc., to realize non-paper designi ng and parallel designing. Problems can be found and settled during designing, w hich will increase designing efficiency and one-time success rate and realize o ptimum designing for products.展开更多
This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmen...This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmental burden caused by the discharge of untreated sludge. Sludge sample was cultured in other to isolate microorganisms for the sludge treatment. The selected strain of the organisms after screening were Aspergillus flavus, Aspergillus niger, Verticillus sp, Penicillum sp, and Microsporium audouinii. Bioreactors (labeled A, B, C, D and O) were designed for the treatment of petroleum sludge. These reactors contain 2.0 × 10<sup>-2</sup> m<sup>3</sup> of the diluted sludge samples and the isolated organisms for the treatment process. On a weekly basis, the control reactors received 1.5 × 10<sup>-3</sup> m<sup>3</sup> of fresh and saline water respectively. After 12 weeks of treatment, sludge physicochemical characteristics showed distinct variations. From the result, reactor D was the best in terms of remediating the sludge as compared to other reactors. Friedman non-parametric test was performed to check if the weeks of treatment affected the reduction of the total hydrocarbon content (THC) in the five reactors and also checked for significant differences in the THC after treatments. The drop in the THC of the treated sludge ranged from 56.0% to 67.3%. These results showed the possibility of enhanced biodegradation of petroleum sludge by hydrocarbon utilizing microorganisms (fungi).展开更多
-The temperature distributions obtained by different methods of analysis for solving thermal transfer of reinforced concrete (R. C.) submarine oil tanks (RCSOT), including flat wall method, cylinder wall method and fi...-The temperature distributions obtained by different methods of analysis for solving thermal transfer of reinforced concrete (R. C.) submarine oil tanks (RCSOT), including flat wall method, cylinder wall method and finite element method, are compared with the experimental data of thermal transfer of RCSOT. The precision and scope of applicability of different methods are discussed. The principle for selecting analysis method for solving thermal transfer of RCSOT is given. The analytical and experimental temperature distributions show that the wall of RCSOT should consist of double walls and empty space between them should be filled with sand or other heat insulation materials to reduce the temperature difference of the wall and to prevent concrete from cracking.展开更多
To automatically detect oil tanks in polarimetric synthetic aperture radar(SAR) images, a coastal oil tank detection method is proposed based on recognition of T-shaped harbor. First of all, the T-shaped harbor is d...To automatically detect oil tanks in polarimetric synthetic aperture radar(SAR) images, a coastal oil tank detection method is proposed based on recognition of T-shaped harbor. First of all, the T-shaped harbor is detected to locate the region of interest(ROI) of oil tanks. Then all suspicious targets in the ROI are extracted by the segmentation of strong scattering targets and the classifier of H/α. The template targets are selected from the suspicious targets by the combination of a proposed circular degree parameter and the similarity parameter(SP) of the polarimetric coherency matrix. Finally, oil tanks are detected according to the statistics of the similarity parameter between each suspicious target and template targets in ROI. Polarimetric SAR data acquired by RADARSAT-2 over Berkeley and Singapore areas are used for testing. Experiment results show that most of the targets are correctly detected and the overall detection rate is close to 80%.The false rate is effectively reduced by the proposed algorithm compared with the method without T-shaped harbor recognition.展开更多
In order to ensure the safety in using a large cylindrical storage tank,it is necessary to regularly detect its defonnatioii.The traditional total station method has high accuracy in determining the deformation,howeve...In order to ensure the safety in using a large cylindrical storage tank,it is necessary to regularly detect its defonnatioii.The traditional total station method has high accuracy in determining the deformation,however,it has a low measxirement efficiency.Long-term observation means,there are more risks in the petrochemical plant,therefore,this paper proposes the usage of the 3D laser scanner,replacing the traditional total station to determine the defbnnation of a large cylindrical storage tank.The Matlab program,is compiled to calculate the point cloud data,while the tank deformation is analyzed from two different points which are,the local concave convex degree and the ovality degree.It is concluded that,the difference between the data obtained by 3D laser scanning,and total station is within the range of oil tank deformation limit,therefore,3D laser scanner can be used for oil tank deformation detection.展开更多
In this paper, the relationship model between the oil volume and the vertically tilting parameter (α), the horizontally tilting parameter (β) and the displayed height of oil (h*) is first constructed with the tilted...In this paper, the relationship model between the oil volume and the vertically tilting parameter (α), the horizontally tilting parameter (β) and the displayed height of oil (h*) is first constructed with the tilted oil tank. Then, based on the data of the oil output volume at different time of day, an optimization model of oil-volume marking with tilted oil tank is established. Finally, parameters α = 2.2° and β = 3.05° are estimated by using nonlinear least squares method and the marking number of the tank-volume meter is given.展开更多
As international maritime organization (IMO) draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy ...As international maritime organization (IMO) draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy steel with chromium contents was studied in O2-CO2-SO2-H2 S wet gas environment. Corrosion rate was measured, and the microstructure and morphology of corrosion product film were characterized by scanning electron microscopy (SEM). The phase and chemical composition of the corrosion product film were investigated by X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS), respectively. The effect of misorientation distribution on corro- sion resistance of steel was evaluated by electron backscattered diffraction (EBSD). The results showed that corro- sion rate decreased with increasing chromium content in the low-alloy steel, and the corrosion type was general corrosion. The phenomenon of chromium enrichment was found in corrosion product film consisting of a-FeOOH, γ- FeOOH, sulphur, FeS2 and Fel-xS. The increase of chromium content decreases the amount of high-angle grain boundaries, thus resulting in the improvement of corrosion resistance.展开更多
Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank (COT) bottom plate service environment (10% NaCl solution, pH = 0.85). The corrosion behavior of inclusion was studied by in-situ ...Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank (COT) bottom plate service environment (10% NaCl solution, pH = 0.85). The corrosion behavior of inclusion was studied by in-situ scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It was found that pitting corrosion was inclined to occur around the place where inclusions exist. After initial corrosion, an area of 10-20μm in diameter was formed as a cireinate cathode around the edge of inclusion. MnS inclusion dissolved in the simulated COT corrosion solution before low-alloy steel matrix, and pitting was formed at the place where MnS dissolved. TiO2 inclusion dissolved in the simulated COT corrosion solution after low alloy steel matrix, and pitting was formed at the place where steel matrix dissolved. The corrosion tended to occur at the area where the curvature radius of inclusion is smaller. The size of round TiO2 inclusions had little influence on corrosion behavior in this certain environment.展开更多
E32 grade corrosion resistant steel was welded with welding wires with three different S contents. The mi crostructure, mechanical properties, inclusions, and corrosion behavior of welded joint were investigated. The ...E32 grade corrosion resistant steel was welded with welding wires with three different S contents. The mi crostructure, mechanical properties, inclusions, and corrosion behavior of welded joint were investigated. The joint coupon corrosion test and potentiodynamic polarization test were carried out under the simulated corrosion environ- ment of the inner bottom plates of cargo oil tanks. The pitting initiation and propagation mechanism of the weld metal were studied by scanning electron microscopy and infinite focus. The results indicated that the microstructures of three kinds of weld metals are all composed of acicular ferrite, ferrite side-plate and proeutectoid ferrite. The micro- structure of heat affected zone is composed predominantly of bainite. Joint welded with low S filler wire has good me- chanical properties. S can decrease free corrosion potential and increase the corrosion tendency. The pitting initiation is oxide inclusion or sulfide oxide inclusion complex. S can induce the formation of occluded area and promote the corrosion propagation. The chemical compositions of weld metal is similar to base metal, which can limit the galvanic corrosion between weld metal and base metal, and avoid formation of corrosion step.展开更多
A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 clas...A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 class ship plate steel is 4.27 mm, which is clearly inadequate compared with the standard adopted by International Maritime Organization. Outer rust layer of specimens starts to peel off after 77 days and becomes fragmented after 98 days. X-ray diffraction, scanning electron micros- copy, and Raman spectroscopy revealed that the resulting rust is composed of σ-FeOOH (the main protective phase), Fe2O3, FeS, elemental S, and FeSO4. FeSO4 in the interface of the base and rust layer leads to localized corrosion. Elemental sulfur forms on the surface of σ-FeOOH, and the quantity and size thereof increase with increasing corrosion time. Furthermore, layered elemental sulfur promotes fracture and peels off the rust layer.展开更多
The necessity for safety in oil-gas storage and transportation has led to increasing technical requirements for on-line monitoring of damaged pores and oil leakage from tanks. In this study, the severity of damage of ...The necessity for safety in oil-gas storage and transportation has led to increasing technical requirements for on-line monitoring of damaged pores and oil leakage from tanks. In this study, the severity of damage of the oil tank at the micron level was detected by terahertz time-domain spectroscopy(THz-TDS), which is of great significance for the early detection and prevention of oil leakage. The THz amplitude(EP) was related to the severity of damaged according to the THz-TDS measurement of oil tanks with various degrees of damage, including intact, partially damaged, completely damaged, and seriously damaged points.Absorption and scattering effects co-occurred when the THz wave penetrated the tanks, with the collective tendencies being used to expressly monitor oil leakage from tanks. When the oil tank was damaged to form micron-level pores and the crude oil had not overflowed, the pore size was close to THz wavelength and the Mie scattering effect was obvious. After further destruction of the pores, the crude oil gradually spilled over and the scattering effect was gradually transformed from Mie scattering to Rayleigh scattering. In addition, the polar molecules in crude oil have strong resonance under the irradiation of THz wave, and the THz wave has strong attenuation. Eventually, surface tension of the oil flattens the surface of the tank, the scattering effect is gradually suppressed and replaced by the absorption effect. Absorption and scattering caused by THz waves passing through tanks coexist and have competing relationships. The change rule of EPcan successfully prove the phenomenon and can be considered as an important alternative for application to predict the degree of tank damage. Therefore, in this study, the detection of pores as small as micrometers on the oil tank was expected to greatly prevent oil leakage accidents and improve the safety of oil and gas storage and transportation.展开更多
Based on the improved particle swarm optimization(PSO) algorithm,an optimization approach for the cargo oil tank design(COTD) is presented in this paper.The purpose is to design an optimal overall dimension of the car...Based on the improved particle swarm optimization(PSO) algorithm,an optimization approach for the cargo oil tank design(COTD) is presented in this paper.The purpose is to design an optimal overall dimension of the cargo oil tank(COT) under various kinds of constraints in the preliminary design stage.A non-linear programming model is built to simulate the optimization design,in which the requirements and rules for COTD are used as the constraints.Considering the distance between the inner shell and hull,a fuzzy constraint is used to express the feasibility degree of the double-hull configuration.In terms of the characteristic of COTD,the PSO algorithm is improved to solve this problem.A bivariate extremum strategy is presented to deal with the fuzzy constraint,by which the maximum and minimum cargo capacities are obtained simultaneously.Finally,the simulation demonstrates the feasibility and effectiveness of the proposed approach.展开更多
This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameter...This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameters were collected at 60 m, 80 m, 100 m, 200 m and control plot for 4 weeks at the Bonny. Rainwater parameters were investigated using standard laboratory tests. Data analyses were done using Analysis of variance, pairwise t-test and Pearson’s correlation statistical tools. Results show that emission rates, volatile organic compound (VOC) noise and flare temperature decreased with increasing distance from flare points and crude oil storage tanks. Findings further revealed the emission rates varied significantly with distance away from the gas flaring point (F = 6.196;p = 0.004). The mean concentration of pollutants between gas flare site and crude oil storage tank showed that CO (0.02 ± 0.001 - 0.002 ±0.001), SPM (0.011 ± 0.001 - 0.01 ± 0.001), VOC (0.005 ± 0.001 - 0.01 ± 0.001) and NO<sub>2</sub> (0.04 ± 0.001 - 0.005 ± 0.000) had significant variations (p > 0.05) with CO, O<sub>3</sub> and NO<sub>2</sub> having higher concentrations at the gas flare site while SPM, and VOC were higher around the crude oil storage tank site. Wind turbulence was higher around the gas flaring point (4.93 TKE) than the crude oil storage tank (4.55 TKE). Similarly, there was significant variation in the sun radiation, precipitation, and wind speed caused by gas flaring (1582.25 w/m<sup>2</sup>, 436.25 mm, 0.53 m/s) and crude oil storage tank (1536.25 w/m<sup>2</sup>, 3.91.41 mm, 0.51 m/s). There were also significant variations in flared temperature (F = 22.144;p = 0.001);NO<sub>2</sub> (F = 8.250;p = 0.001), CO (F = 6.000;p = 0.004) and VOC (F = 5.574;p = 0.006) with distance from the gas flaring point. The variation in the rainwater parameters with distance from the gas flaring indicated significant variations in pH (F = 5.594;p = 0.006). The study showed that the concentration of VOC and particulates were high in the supposedly control area which is perceived to be safe for human habitation. Significant variations exist in emission rate (p = 0.015), flare temperature (p = 0.001), NO<sub>2</sub> (p = 0.003), VOC (p = 0.001), noise (p = 0.041), hydrogen carbonate (p = 0.037) and chromium (p = 0.032) between the gas flaring and crude oil storage tank. Regular monitoring is advocated to mitigate the harmful effects of the pollutants.展开更多
The method of using multiplexing technique to realize the optically powered multiple detection system is presented. As this system adopted novel time and pulse width multiplexing techniques, reliable separation and er...The method of using multiplexing technique to realize the optically powered multiple detection system is presented. As this system adopted novel time and pulse width multiplexing techniques, reliable separation and error code correcting techniques, it realizes optically powered multiple channel and parameters detection, and successfully applied in the oil tanks for temperature, pressure, liquid level and reserve measurings.展开更多
Crude oil is a kind of water/oil emulsion, which the oil phase consists of organic molecules with different molecular weights such as alkanes, paraffin, asphaltene, and resins. Due to the change in physicochemical con...Crude oil is a kind of water/oil emulsion, which the oil phase consists of organic molecules with different molecular weights such as alkanes, paraffin, asphaltene, and resins. Due to the change in physicochemical conditions during the production, transportation, storage, and refining, heavier molecules can precipitate from crude oil. Thus, viscous sludge formed at the bottom of storage tanks can cause many problems including reduction of storage capacity of tank, oil contamination, corrosion, repair costs, environmental pollution, etc. The reduction of sludge viscosity can be achieved by reduction of its interfacial tension. In this study, different chemical and physical factors, influencing prepared emulsions(made of sludge, water and surfactant), such as surfactants, solvents, temperature, pressure, and mixing conditions were investigated. Results showed that non-ionic surfactants(like bitumen emulsifier), and solvents(such as mixed xylene, AW-400, and AW-402), injection of additives, applying pressure, and mixing operations had a positive effect on reduction of emulsion viscosity. All experiments were carried out with sludge obtained from crude oil storage tanks at Kharg Island,Iran.展开更多
The features of acoustic bathymetry of sludge in crude oil tanks are considered. Different parameters of crude oil and sludge which are important for the selection of acoustic parameters such as sound speed, the acous...The features of acoustic bathymetry of sludge in crude oil tanks are considered. Different parameters of crude oil and sludge which are important for the selection of acoustic parameters such as sound speed, the acoustic impedances of “oil-sludge” boundaries and sound attenuation are analyzed and compared with experimental data. The main sources of errors of sludge volume estimation are discussed.展开更多
A dynamic experiment for oil dispersion into a water column was performed with a 21 m long, 0.5 m wide, and 1 m high wind-driven wave tank. At wind velocity between 6-12 m/s and with the oil slide kept constant (about...A dynamic experiment for oil dispersion into a water column was performed with a 21 m long, 0.5 m wide, and 1 m high wind-driven wave tank. At wind velocity between 6-12 m/s and with the oil slide kept constant (about 1 um), the rate of the oil content increase in the water column could be approximated from the difference between the dispersion rate (R) of the oil slick and the coagulation rate (R’) of the dispersed oil slick. Assuming the coagulation rate is directly proportional to the concentration of the water dispersed oil slick (i. e. R’ =KC),, the integral form of the dynamic model can be expressed as C=R*[1-exp(-K*t)]/K and parameters R and K can be regressed with a computer. The relative deviation of model results from the experimental data was mainly less than 10%. The oil slick dispersion rate (R) had exponential relationship with the wind velocity (V), and can be fitted with a formula R=A*(U+1)B.The fitted constant of the coagulation rate, K(0.8-3.0* 10-3 min-1) did not have significant展开更多
文摘This paper creates 3D solid model and assembly of U RJ 92-6 oil tank and analyses its strength by integrated CAD/CAE/CAM software I-D EAS. Through integrated simulation in computer, design efficiency and quality of oil tank is greatly improved. Adopting integrated CAD/CAE/CAM software to carry out integrated research to equ ipment and products, we will be able to take overall analysis in aspects of 3-D solid modeling, pre-assembly and strength, etc., to realize non-paper designi ng and parallel designing. Problems can be found and settled during designing, w hich will increase designing efficiency and one-time success rate and realize o ptimum designing for products.
文摘This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmental burden caused by the discharge of untreated sludge. Sludge sample was cultured in other to isolate microorganisms for the sludge treatment. The selected strain of the organisms after screening were Aspergillus flavus, Aspergillus niger, Verticillus sp, Penicillum sp, and Microsporium audouinii. Bioreactors (labeled A, B, C, D and O) were designed for the treatment of petroleum sludge. These reactors contain 2.0 × 10<sup>-2</sup> m<sup>3</sup> of the diluted sludge samples and the isolated organisms for the treatment process. On a weekly basis, the control reactors received 1.5 × 10<sup>-3</sup> m<sup>3</sup> of fresh and saline water respectively. After 12 weeks of treatment, sludge physicochemical characteristics showed distinct variations. From the result, reactor D was the best in terms of remediating the sludge as compared to other reactors. Friedman non-parametric test was performed to check if the weeks of treatment affected the reduction of the total hydrocarbon content (THC) in the five reactors and also checked for significant differences in the THC after treatments. The drop in the THC of the treated sludge ranged from 56.0% to 67.3%. These results showed the possibility of enhanced biodegradation of petroleum sludge by hydrocarbon utilizing microorganisms (fungi).
文摘-The temperature distributions obtained by different methods of analysis for solving thermal transfer of reinforced concrete (R. C.) submarine oil tanks (RCSOT), including flat wall method, cylinder wall method and finite element method, are compared with the experimental data of thermal transfer of RCSOT. The precision and scope of applicability of different methods are discussed. The principle for selecting analysis method for solving thermal transfer of RCSOT is given. The analytical and experimental temperature distributions show that the wall of RCSOT should consist of double walls and empty space between them should be filled with sand or other heat insulation materials to reduce the temperature difference of the wall and to prevent concrete from cracking.
基金supported by the National Key R&D Program of China(2017YFB0502700)the National Natural Science Foundation of China(61490693+3 种基金61771043)the High-Resolution Earth Observation Systems(41-Y20A14-9001-15/1630-Y20A12-9004-15/1630-Y20A10-9001-15/16)
文摘To automatically detect oil tanks in polarimetric synthetic aperture radar(SAR) images, a coastal oil tank detection method is proposed based on recognition of T-shaped harbor. First of all, the T-shaped harbor is detected to locate the region of interest(ROI) of oil tanks. Then all suspicious targets in the ROI are extracted by the segmentation of strong scattering targets and the classifier of H/α. The template targets are selected from the suspicious targets by the combination of a proposed circular degree parameter and the similarity parameter(SP) of the polarimetric coherency matrix. Finally, oil tanks are detected according to the statistics of the similarity parameter between each suspicious target and template targets in ROI. Polarimetric SAR data acquired by RADARSAT-2 over Berkeley and Singapore areas are used for testing. Experiment results show that most of the targets are correctly detected and the overall detection rate is close to 80%.The false rate is effectively reduced by the proposed algorithm compared with the method without T-shaped harbor recognition.
基金National Natural Science Foundation of China(project number:41661091)Lanzhou Jiaotong University Excellent Platform Support Project(201806)。
文摘In order to ensure the safety in using a large cylindrical storage tank,it is necessary to regularly detect its defonnatioii.The traditional total station method has high accuracy in determining the deformation,however,it has a low measxirement efficiency.Long-term observation means,there are more risks in the petrochemical plant,therefore,this paper proposes the usage of the 3D laser scanner,replacing the traditional total station to determine the defbnnation of a large cylindrical storage tank.The Matlab program,is compiled to calculate the point cloud data,while the tank deformation is analyzed from two different points which are,the local concave convex degree and the ovality degree.It is concluded that,the difference between the data obtained by 3D laser scanning,and total station is within the range of oil tank deformation limit,therefore,3D laser scanner can be used for oil tank deformation detection.
文摘In this paper, the relationship model between the oil volume and the vertically tilting parameter (α), the horizontally tilting parameter (β) and the displayed height of oil (h*) is first constructed with the tilted oil tank. Then, based on the data of the oil output volume at different time of day, an optimization model of oil-volume marking with tilted oil tank is established. Finally, parameters α = 2.2° and β = 3.05° are estimated by using nonlinear least squares method and the marking number of the tank-volume meter is given.
基金Item Sponsored by National Science and Technology Major Project of the Ministry of Science and Technology of China(2011ZX05016-004)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2011BAE25B00)
文摘As international maritime organization (IMO) draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy steel with chromium contents was studied in O2-CO2-SO2-H2 S wet gas environment. Corrosion rate was measured, and the microstructure and morphology of corrosion product film were characterized by scanning electron microscopy (SEM). The phase and chemical composition of the corrosion product film were investigated by X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS), respectively. The effect of misorientation distribution on corro- sion resistance of steel was evaluated by electron backscattered diffraction (EBSD). The results showed that corro- sion rate decreased with increasing chromium content in the low-alloy steel, and the corrosion type was general corrosion. The phenomenon of chromium enrichment was found in corrosion product film consisting of a-FeOOH, γ- FeOOH, sulphur, FeS2 and Fel-xS. The increase of chromium content decreases the amount of high-angle grain boundaries, thus resulting in the improvement of corrosion resistance.
基金Item Sponsored by National Science and Technology Major Project of the Ministry of Science and Technology of China(2011ZX05016-004)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2011BAE25B00)
文摘Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank (COT) bottom plate service environment (10% NaCl solution, pH = 0.85). The corrosion behavior of inclusion was studied by in-situ scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It was found that pitting corrosion was inclined to occur around the place where inclusions exist. After initial corrosion, an area of 10-20μm in diameter was formed as a cireinate cathode around the edge of inclusion. MnS inclusion dissolved in the simulated COT corrosion solution before low-alloy steel matrix, and pitting was formed at the place where MnS dissolved. TiO2 inclusion dissolved in the simulated COT corrosion solution after low alloy steel matrix, and pitting was formed at the place where steel matrix dissolved. The corrosion tended to occur at the area where the curvature radius of inclusion is smaller. The size of round TiO2 inclusions had little influence on corrosion behavior in this certain environment.
基金Sponsored by National Key Technology Research and Development Program of China(2011BAE25B01)
文摘E32 grade corrosion resistant steel was welded with welding wires with three different S contents. The mi crostructure, mechanical properties, inclusions, and corrosion behavior of welded joint were investigated. The joint coupon corrosion test and potentiodynamic polarization test were carried out under the simulated corrosion environ- ment of the inner bottom plates of cargo oil tanks. The pitting initiation and propagation mechanism of the weld metal were studied by scanning electron microscopy and infinite focus. The results indicated that the microstructures of three kinds of weld metals are all composed of acicular ferrite, ferrite side-plate and proeutectoid ferrite. The micro- structure of heat affected zone is composed predominantly of bainite. Joint welded with low S filler wire has good me- chanical properties. S can decrease free corrosion potential and increase the corrosion tendency. The pitting initiation is oxide inclusion or sulfide oxide inclusion complex. S can induce the formation of occluded area and promote the corrosion propagation. The chemical compositions of weld metal is similar to base metal, which can limit the galvanic corrosion between weld metal and base metal, and avoid formation of corrosion step.
文摘A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 class ship plate steel is 4.27 mm, which is clearly inadequate compared with the standard adopted by International Maritime Organization. Outer rust layer of specimens starts to peel off after 77 days and becomes fragmented after 98 days. X-ray diffraction, scanning electron micros- copy, and Raman spectroscopy revealed that the resulting rust is composed of σ-FeOOH (the main protective phase), Fe2O3, FeS, elemental S, and FeSO4. FeSO4 in the interface of the base and rust layer leads to localized corrosion. Elemental sulfur forms on the surface of σ-FeOOH, and the quantity and size thereof increase with increasing corrosion time. Furthermore, layered elemental sulfur promotes fracture and peels off the rust layer.
基金This work was supported by the National Natural Science Foundation of China(Grant No.11804392)the Science Foundation of China University of Petroleum,Beijing(Grant Nos.ZX20190163,2462020YXZZ019and 2462020YXZZ017)。
文摘The necessity for safety in oil-gas storage and transportation has led to increasing technical requirements for on-line monitoring of damaged pores and oil leakage from tanks. In this study, the severity of damage of the oil tank at the micron level was detected by terahertz time-domain spectroscopy(THz-TDS), which is of great significance for the early detection and prevention of oil leakage. The THz amplitude(EP) was related to the severity of damaged according to the THz-TDS measurement of oil tanks with various degrees of damage, including intact, partially damaged, completely damaged, and seriously damaged points.Absorption and scattering effects co-occurred when the THz wave penetrated the tanks, with the collective tendencies being used to expressly monitor oil leakage from tanks. When the oil tank was damaged to form micron-level pores and the crude oil had not overflowed, the pore size was close to THz wavelength and the Mie scattering effect was obvious. After further destruction of the pores, the crude oil gradually spilled over and the scattering effect was gradually transformed from Mie scattering to Rayleigh scattering. In addition, the polar molecules in crude oil have strong resonance under the irradiation of THz wave, and the THz wave has strong attenuation. Eventually, surface tension of the oil flattens the surface of the tank, the scattering effect is gradually suppressed and replaced by the absorption effect. Absorption and scattering caused by THz waves passing through tanks coexist and have competing relationships. The change rule of EPcan successfully prove the phenomenon and can be considered as an important alternative for application to predict the degree of tank damage. Therefore, in this study, the detection of pores as small as micrometers on the oil tank was expected to greatly prevent oil leakage accidents and improve the safety of oil and gas storage and transportation.
基金the National Special Fund for Agro-scientific Research in the Public Interest(No.201003024)
文摘Based on the improved particle swarm optimization(PSO) algorithm,an optimization approach for the cargo oil tank design(COTD) is presented in this paper.The purpose is to design an optimal overall dimension of the cargo oil tank(COT) under various kinds of constraints in the preliminary design stage.A non-linear programming model is built to simulate the optimization design,in which the requirements and rules for COTD are used as the constraints.Considering the distance between the inner shell and hull,a fuzzy constraint is used to express the feasibility degree of the double-hull configuration.In terms of the characteristic of COTD,the PSO algorithm is improved to solve this problem.A bivariate extremum strategy is presented to deal with the fuzzy constraint,by which the maximum and minimum cargo capacities are obtained simultaneously.Finally,the simulation demonstrates the feasibility and effectiveness of the proposed approach.
文摘This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameters were collected at 60 m, 80 m, 100 m, 200 m and control plot for 4 weeks at the Bonny. Rainwater parameters were investigated using standard laboratory tests. Data analyses were done using Analysis of variance, pairwise t-test and Pearson’s correlation statistical tools. Results show that emission rates, volatile organic compound (VOC) noise and flare temperature decreased with increasing distance from flare points and crude oil storage tanks. Findings further revealed the emission rates varied significantly with distance away from the gas flaring point (F = 6.196;p = 0.004). The mean concentration of pollutants between gas flare site and crude oil storage tank showed that CO (0.02 ± 0.001 - 0.002 ±0.001), SPM (0.011 ± 0.001 - 0.01 ± 0.001), VOC (0.005 ± 0.001 - 0.01 ± 0.001) and NO<sub>2</sub> (0.04 ± 0.001 - 0.005 ± 0.000) had significant variations (p > 0.05) with CO, O<sub>3</sub> and NO<sub>2</sub> having higher concentrations at the gas flare site while SPM, and VOC were higher around the crude oil storage tank site. Wind turbulence was higher around the gas flaring point (4.93 TKE) than the crude oil storage tank (4.55 TKE). Similarly, there was significant variation in the sun radiation, precipitation, and wind speed caused by gas flaring (1582.25 w/m<sup>2</sup>, 436.25 mm, 0.53 m/s) and crude oil storage tank (1536.25 w/m<sup>2</sup>, 3.91.41 mm, 0.51 m/s). There were also significant variations in flared temperature (F = 22.144;p = 0.001);NO<sub>2</sub> (F = 8.250;p = 0.001), CO (F = 6.000;p = 0.004) and VOC (F = 5.574;p = 0.006) with distance from the gas flaring point. The variation in the rainwater parameters with distance from the gas flaring indicated significant variations in pH (F = 5.594;p = 0.006). The study showed that the concentration of VOC and particulates were high in the supposedly control area which is perceived to be safe for human habitation. Significant variations exist in emission rate (p = 0.015), flare temperature (p = 0.001), NO<sub>2</sub> (p = 0.003), VOC (p = 0.001), noise (p = 0.041), hydrogen carbonate (p = 0.037) and chromium (p = 0.032) between the gas flaring and crude oil storage tank. Regular monitoring is advocated to mitigate the harmful effects of the pollutants.
基金This subject is subsidized by Hebei Education Commission
文摘The method of using multiplexing technique to realize the optically powered multiple detection system is presented. As this system adopted novel time and pulse width multiplexing techniques, reliable separation and error code correcting techniques, it realizes optically powered multiple channel and parameters detection, and successfully applied in the oil tanks for temperature, pressure, liquid level and reserve measurings.
文摘Crude oil is a kind of water/oil emulsion, which the oil phase consists of organic molecules with different molecular weights such as alkanes, paraffin, asphaltene, and resins. Due to the change in physicochemical conditions during the production, transportation, storage, and refining, heavier molecules can precipitate from crude oil. Thus, viscous sludge formed at the bottom of storage tanks can cause many problems including reduction of storage capacity of tank, oil contamination, corrosion, repair costs, environmental pollution, etc. The reduction of sludge viscosity can be achieved by reduction of its interfacial tension. In this study, different chemical and physical factors, influencing prepared emulsions(made of sludge, water and surfactant), such as surfactants, solvents, temperature, pressure, and mixing conditions were investigated. Results showed that non-ionic surfactants(like bitumen emulsifier), and solvents(such as mixed xylene, AW-400, and AW-402), injection of additives, applying pressure, and mixing operations had a positive effect on reduction of emulsion viscosity. All experiments were carried out with sludge obtained from crude oil storage tanks at Kharg Island,Iran.
文摘The features of acoustic bathymetry of sludge in crude oil tanks are considered. Different parameters of crude oil and sludge which are important for the selection of acoustic parameters such as sound speed, the acoustic impedances of “oil-sludge” boundaries and sound attenuation are analyzed and compared with experimental data. The main sources of errors of sludge volume estimation are discussed.
文摘A dynamic experiment for oil dispersion into a water column was performed with a 21 m long, 0.5 m wide, and 1 m high wind-driven wave tank. At wind velocity between 6-12 m/s and with the oil slide kept constant (about 1 um), the rate of the oil content increase in the water column could be approximated from the difference between the dispersion rate (R) of the oil slick and the coagulation rate (R’) of the dispersed oil slick. Assuming the coagulation rate is directly proportional to the concentration of the water dispersed oil slick (i. e. R’ =KC),, the integral form of the dynamic model can be expressed as C=R*[1-exp(-K*t)]/K and parameters R and K can be regressed with a computer. The relative deviation of model results from the experimental data was mainly less than 10%. The oil slick dispersion rate (R) had exponential relationship with the wind velocity (V), and can be fitted with a formula R=A*(U+1)B.The fitted constant of the coagulation rate, K(0.8-3.0* 10-3 min-1) did not have significant