In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd...In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd/carbon nanosphere(CNS),obtained via immobilization of ultrafine Pd nanoparticles onto CNS,are developed and employed for both selective H_(2)generation from HCOOH dehydrogenation and O_(2)evolution from H_(2)O_(2)decomposition.In these reactions,the highest activities for Pd/CNS-800(i.e.,calcinated at 800℃)are 2478 h−1 and 993 min^(−1)for H_(2)and O_(2)evolution,respectively.The highly efficient and selective“on-off”switch for selective H_(2)generation from HCOOH is successfully realized by pH adjustment.This novel and highly efficient nanocatalyst Pd/CNS-800 not only provides new approaches for the promising application of HCOOH and H_(2)O_(2)as economic and safe H_(2)and O_(2)carriers,respectively,for fuel cells,but also promotes the development of“on-off”switch for on-demand H_(2)evolution.展开更多
Natural properties of high speed on-off valves can be described through their on-off behavior and spool movement (static and oscillating) characteristics. High speed on-off valves can be combined with actuators in sys...Natural properties of high speed on-off valves can be described through their on-off behavior and spool movement (static and oscillating) characteristics. High speed on-off valves can be combined with actuators in systems into four typical types of composite valves whose static characteristics are related not only to the structures of the single valves and the composite ones, but also to the PWM control modes. It is proved that the composite valves have similar features as those of servo valves. The nonlinear specific properties of single valves composited can be completely compensated by the suitable PWM control modes.展开更多
There is a relatively complex flow state inside the high speed on-off valve,which often produces low pressure area and oil reflux in the high-speed opening and closing process of the spool,causing cavitation and vorte...There is a relatively complex flow state inside the high speed on-off valve,which often produces low pressure area and oil reflux in the high-speed opening and closing process of the spool,causing cavitation and vortex and other phenomena.These phenomena will affect the stability of the internal flow field of the plate valve and the flow characteristics of the high speed on-off valve.Aiming at the problems of small flow rate and instability of internal flow field,a new spool structure was designed.The flow field models of two-hole and three-hole plate spools with different openings were established,and software ANSYS Workbench was chosen to mesh the model.The standard k−εturbulence model was selected for numerical simulation using FLUENT software.The pressure distribution and velocity distribution under the same pressure and different opening degree were obtained.The structure and parameters of the optimization model were also obtained.The stability analysis of flow field under different pressure was carried out.The results demonstrate that the three-hole spool has a similar flow field change with the two-hole spool,but it does not create a low pressure zone,and the three-hole spool can work stably at 2 MPa or less.This method improves the appearance of low pressure area and oil backflow in the process of high speed opening and closing of spool.The stability of flow field and the flow rate of high speed switch valve are improved.Finally,the products designed in this paper are compared with existing hydraulic valve products.The results show that the three-hole plate type high speed on-off valve designed in this paper maintains the stability of the internal flow field under the condition of 200 Hz and large opening degree,and realizes the increase of flow rate.展开更多
In this paper, we propose a dual-threshold based secure On-Off transmission scheme, where signals are transmitted only if the channel condition can guarantee secure and reliable communication. First, we present a dyna...In this paper, we propose a dual-threshold based secure On-Off transmission scheme, where signals are transmitted only if the channel condition can guarantee secure and reliable communication. First, we present a dynamic access strategy to increase access efficiency, which provides an access region for the intended user. Then, we propose an emission control policy to transmit signals according to the current channel condition, which declines the influence of channel estimation errors and guarantees qualities of communication links. Furthermore, we give a comprehensive performance analysis for the proposed scheme in terms of connection outage probability(COP) and secrecy outage probability(SOP), and present a dual-threshold optimization model to further support the performance. Numerical results verify that the secure On-Off transmission scheme can increase the system secure energy efficiency and guarantee reliable and secure communication.展开更多
Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunn...Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunnel length was only a function of the turn-on interval of DC. The potential of Al foil broke at on-off controlling DC by the result from anode polarization curves and potential-time （E-t） responding curves. When DC was switched on, the potential increased abruptly over pitting potential, leading to nucleation of pits at the surface and the growth of tunnels at special length. When DC was switched off, the potential decreased rapidly to a passive value, leading to stoppage of nucleation and death of tunnels. By this way, the longest tunnel length can be controlled and a non-piercing layer can be obtained. Hence, etching of Al foil at this current is beneficial for maintaining a good mechanical strength.展开更多
To improve the switching time of the control force in standard sky-hook ON-OFF semi-active control algorithm,a stateadjust coefficient was adopted in the improved ON-OFF( ION-OFF)algorithm. In considering of the ridin...To improve the switching time of the control force in standard sky-hook ON-OFF semi-active control algorithm,a stateadjust coefficient was adopted in the improved ON-OFF( ION-OFF)algorithm. In considering of the riding comfort and the handling stability of vehicle, a comprehensive performance assessment criterion on suspension system was established with the utilization of the corresponding passive suspension system. Several simulations and analyses were conducted on improved ON-OFF semi-active suspension system with the comparison of passive suspension system and ON-OFF semi-active suspension system. The simulation results showed that the optimal comprehensive performance of the improved ON-OFF suspension system could be achieved when the state-adjust coefficient equalled 0. 6 as the vehicle running on C level road with the speed of 10 m/s,and the comprehensive performance was better than ON-OFF suspension system. Conclusions could be drawn from the frequency domain analysis that the performance of riding comfort and handling stability were both improved in the low resonance frequency and the mid-frequency range. The fact could be known that the comprehensive performance of the suspension system was associated with the frequency of the riding road and the sprung mass( SM) with the analysis of affecting factors.展开更多
基金National Natural Science Foundation of China,Grant/Award Number:21805166111 Project of China,Grant/Award Number:D20015+1 种基金Ministryof Education,Hubei province,China,Grant/Award Number:T2020004Foundation of Science and Technology Bureau of Yichang City,Grant/Award Number:A21‐3‐012。
文摘In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd/carbon nanosphere(CNS),obtained via immobilization of ultrafine Pd nanoparticles onto CNS,are developed and employed for both selective H_(2)generation from HCOOH dehydrogenation and O_(2)evolution from H_(2)O_(2)decomposition.In these reactions,the highest activities for Pd/CNS-800(i.e.,calcinated at 800℃)are 2478 h−1 and 993 min^(−1)for H_(2)and O_(2)evolution,respectively.The highly efficient and selective“on-off”switch for selective H_(2)generation from HCOOH is successfully realized by pH adjustment.This novel and highly efficient nanocatalyst Pd/CNS-800 not only provides new approaches for the promising application of HCOOH and H_(2)O_(2)as economic and safe H_(2)and O_(2)carriers,respectively,for fuel cells,but also promotes the development of“on-off”switch for on-demand H_(2)evolution.
文摘Natural properties of high speed on-off valves can be described through their on-off behavior and spool movement (static and oscillating) characteristics. High speed on-off valves can be combined with actuators in systems into four typical types of composite valves whose static characteristics are related not only to the structures of the single valves and the composite ones, but also to the PWM control modes. It is proved that the composite valves have similar features as those of servo valves. The nonlinear specific properties of single valves composited can be completely compensated by the suitable PWM control modes.
基金Project(51975164)supported by the National Natural Science Foundation of ChinaProject(201908230358)supported by the China Scholarship CouncilProject supported by the Fundamental Research Foundation for Universities of Heilongjiang Province,China。
文摘There is a relatively complex flow state inside the high speed on-off valve,which often produces low pressure area and oil reflux in the high-speed opening and closing process of the spool,causing cavitation and vortex and other phenomena.These phenomena will affect the stability of the internal flow field of the plate valve and the flow characteristics of the high speed on-off valve.Aiming at the problems of small flow rate and instability of internal flow field,a new spool structure was designed.The flow field models of two-hole and three-hole plate spools with different openings were established,and software ANSYS Workbench was chosen to mesh the model.The standard k−εturbulence model was selected for numerical simulation using FLUENT software.The pressure distribution and velocity distribution under the same pressure and different opening degree were obtained.The structure and parameters of the optimization model were also obtained.The stability analysis of flow field under different pressure was carried out.The results demonstrate that the three-hole spool has a similar flow field change with the two-hole spool,but it does not create a low pressure zone,and the three-hole spool can work stably at 2 MPa or less.This method improves the appearance of low pressure area and oil backflow in the process of high speed opening and closing of spool.The stability of flow field and the flow rate of high speed switch valve are improved.Finally,the products designed in this paper are compared with existing hydraulic valve products.The results show that the three-hole plate type high speed on-off valve designed in this paper maintains the stability of the internal flow field under the condition of 200 Hz and large opening degree,and realizes the increase of flow rate.
基金supported in part by National Natural Science Foundation of China under Grants No. 61871404, 61401510, 61521003, 61501516
文摘In this paper, we propose a dual-threshold based secure On-Off transmission scheme, where signals are transmitted only if the channel condition can guarantee secure and reliable communication. First, we present a dynamic access strategy to increase access efficiency, which provides an access region for the intended user. Then, we propose an emission control policy to transmit signals according to the current channel condition, which declines the influence of channel estimation errors and guarantees qualities of communication links. Furthermore, we give a comprehensive performance analysis for the proposed scheme in terms of connection outage probability(COP) and secrecy outage probability(SOP), and present a dual-threshold optimization model to further support the performance. Numerical results verify that the secure On-Off transmission scheme can increase the system secure energy efficiency and guarantee reliable and secure communication.
基金This study was financially supported by Beijing Education Commission,China.
文摘Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunnel length was only a function of the turn-on interval of DC. The potential of Al foil broke at on-off controlling DC by the result from anode polarization curves and potential-time （E-t） responding curves. When DC was switched on, the potential increased abruptly over pitting potential, leading to nucleation of pits at the surface and the growth of tunnels at special length. When DC was switched off, the potential decreased rapidly to a passive value, leading to stoppage of nucleation and death of tunnels. By this way, the longest tunnel length can be controlled and a non-piercing layer can be obtained. Hence, etching of Al foil at this current is beneficial for maintaining a good mechanical strength.
基金Military Scientific Project,China(No.2013ZB06)Innovation Engineering Project of General Armament Department,China(No.2015YY04)
文摘To improve the switching time of the control force in standard sky-hook ON-OFF semi-active control algorithm,a stateadjust coefficient was adopted in the improved ON-OFF( ION-OFF)algorithm. In considering of the riding comfort and the handling stability of vehicle, a comprehensive performance assessment criterion on suspension system was established with the utilization of the corresponding passive suspension system. Several simulations and analyses were conducted on improved ON-OFF semi-active suspension system with the comparison of passive suspension system and ON-OFF semi-active suspension system. The simulation results showed that the optimal comprehensive performance of the improved ON-OFF suspension system could be achieved when the state-adjust coefficient equalled 0. 6 as the vehicle running on C level road with the speed of 10 m/s,and the comprehensive performance was better than ON-OFF suspension system. Conclusions could be drawn from the frequency domain analysis that the performance of riding comfort and handling stability were both improved in the low resonance frequency and the mid-frequency range. The fact could be known that the comprehensive performance of the suspension system was associated with the frequency of the riding road and the sprung mass( SM) with the analysis of affecting factors.
