Functional Optical Fiber Sensors Detecting Imperceptible Physical/Chemical Changes for Smart Batteries

The battery technology progress has been a contradictory process in which performance improvement and hidden risks coexist.Now the battery is still a“black box”,thus requiring a deep understanding of its internal state.The battery should“sense its internal physical/chemical conditions”,which puts strict requirements on embedded sensing parts.This paper summarizes the application of advanced optical fiber sensors in lithium-ion batteries and energy storage technologies that may be mass deployed,focuses on the insights of advanced optical fiber sensors into the processes of one-dimensional nano-micro-level battery material structural phase transition,electrolyte degradation,electrode-electrolyte interface dynamics to three-dimensional macro-safety evolution.The paper contributes to understanding how to use optical fiber sensors to achieve“real”and“embedded”monitoring.Through the inherent advantages of the advanced optical fiber sensor,it helps clarify the battery internal state and reaction mechanism,aiding in the establishment of more detailed models.These advancements can promote the development of smart batteries,with significant importance lying in essentially promoting the improvement of system consistency.Furthermore,with the help of smart batteries in the future,the importance of consistency can be weakened or even eliminated.The application of advanced optical fiber sensors helps comprehensively improve the battery quality,reliability,and life.

Some of the Chemical and Physical Characteristics of the Graff River in Kut City, Iraq

Some of the chemical and physical water qualities of the Graff River in the city of Kut were studied, and for two sites of the river, One was at the Crimea site, the other in the Jihad district, and for the period from October/2018 to March/2019, Seven variables of river water have been analyzed: temperature PH, electrical conductivity, TDS, turbidity, alkaline, and chloride. The results showed that most of the chemical and physical water properties of the river were in normal proportions and did not rise, except for the turbidity, which was at a very high level, and that the pH values were close to the basal side. The results of the statistical analysis revealed positive significant relationships between the pH and (chloride and TDS). On the other hand, between electrical conductivity and both previous variables as well. And a negative significant connection between temperature and alkaline.

Physical and Chemical Properties of Horns Sheaths Particles for the Manufacture of Composite Materials

Salvaged cow horns from slaughterhouses have been transformed into fine particles for a physical characterization that has led us to determine the humidity rate (2.34% ± 0.054%), the actual density situated between 0.586 g/cm3 and 0.732 g/cm3, the swelling rate (12%), and one chemical characterization that permitted us to determine the rate of dry matters (97.05%), of mineral matters (2.5%), of protein matters (94.52%). From these weak values, it can easily be seen that cow horn case doesn’t absorb much water and improve the mechanical characteristics of the composite;the high rate of protein shows that keratin which is the structural molecule favors its gripping as reinforcing element in the manufacturing of composite materials.

Engineering and Physical Bases of Development and Creation of Plasmochemical Reactors for Mobile Facilities for Medical Waste Disposal

This paper presents the results of the development and creation of plasma-chemical reactors for mobile and stationary installations for the destruction and disposal of solid, liquid, gaseous and mixed medical waste based on the domestic plasma generator PUN-1, with air as the plasma-forming gas. The design and principle of operation of plasma-chemical reactors installed on mobile experimental and industrial plants “Plazmon-1,2,3”, as well as the main features of the plasma waste disposal process are described.

FCF-LDH/BiVO_(4)with synergistic effect of physical enrichment and chemical adsorption for efficient reduction of nitrate

Photoelectrochemical NO_(3)^(-)reduction(PEC NITRR)not only provides a promising solution for promoting the global nitrogen cycle,but also converts NO_(3)^(-)to the important chemicals(NH_(3)).However,it is still a great challenge to prepare catalysts with excellent NO_(3)^(-)adsorption/activation capacity to achieve high NITRR.Herein,we designed a novel Fe^(2+)~Cu^(2+)Fe^(3+)LDH/BiVO_(4)(FCF-LDH/BVO)catalyst with synergistic effect of chemical adsorption and physical enrichment.Fe^(2+)in FCF-LDH/BVO provides the rich Lewis acid sites for the adsorption of NO_(3)^(-),and the appropriate layer spacing of FCF-LDH further promotes the physical enrichment of NO_(3)^(-)in its interior,thus realizing the effective contact between NO_(3)^(-)and active sites(Fe^(2+)).FCF-LDH/BVO showed excellent NH_(3)production performance(FE_(NH_(3))=66.1%,r_(NH_(3))=13.8μg h^(-1)cm^(-2))and selectivity(FE_(NO_(2)^(-))=2.5%,r_(NO_(2)^(-))=4.9μg h^(-1)cm^(-2))in 0.5 mol L^(-1)Na_(2)SO_(4)electrolyte.In addition,FCF-LDH/BVO maintains the desirable PEC stability for six cycle experiments,showing great potential for practical application.The^(14)NO_(3)^(-)and^(15)NO_(3)^(-)isotope test provides strong evidence for further verification of the origin of N in the generated NH_(3).This LDH catalyst has a great potential in PEC removal of NO_(3)^(-)from groundwater.

Changing Rules of Physical and Chemical Properties of Eucalyptus uraphylla spp. Forest at Different Ages in Southwest Yunnan Province

[Objective] The aim was to study on changing rules of physical and chemical properties of Eucalyptus uraphylla spp. forest at different ages in Southwest of Yunnan Province. [Method] In the research, field survey and laboratory analysis were adopted to study on physical and chemical properties of soils for the Eucalyptus uraphylla spp. at the first cutting ages in Lancang County. [Result] With the increasing of forest ages, for physical properties of soils, soil bulk density was increasing, and soil structure became poor; water contents in soils and capillary porosity were improving, but total soil porosity and non-capillary porosity were decreasing. For chemical properties, pH of soil dropped, but soil acidity improved; organic matter, total N, hydrolysable nitrogen, available phosphorus, and available potassium all declined; exchangeable Ca and Mg were improving due to fertilization and Ca and Mg lower consumption. The results showed that plays important roles in water absorption of soils and vegetation growth were improved with age increase by Eucalyptus uraphylla spp. forest, but ventilation and fertility declined accordingly. [Conclusion] The research indicated that dry branches and fallen leaves should be preserved and nutrient cycling should be protected during introduction and management of Eucalyptus uraphylla spp. to guarantee the nutrients in dry branches and leaves are back to soils, providing theoretical references for management of forest plantation and environment protection.

Increasing significance of advanced physical/chemical processes in the development and application of sustainable wastewater treatment systems

The awareness of the problem of the scarcity of water of high quality has strongly changed the approach of wastewater treatment.Currently,there is an increasing need for the beneficial reuse of treated wastewater and to recover valuable products and energy from the wastewater.Because microbiological treatment methods are,only to a limited part,able to satisfy these needs,the role and significance of physical/chemical processes in wastewater treatment are gaining more and more interest.The specific future role and aim of the various physical/chemical treatment processes can be categorized in five groups:improvement of the performance of microbiological treatment processes,achievement of the high quality required for reuse of the effluent,recovery of valuable components and energy from the wastewater for beneficial reuse,desalination of brackish water and seawater,and treatment of concentrated liquid or solid waste residues produced in a wastewater treatment process.Development of more environmentally sustainable wastewater treatment chains in which physical/chemical processes play a crucial role,also requires application of process control and modeling strategies.This is briefly introduced by the elaboration of treatment scenarios for three specific wastewaters.

Effects of Different Application Amounts of Potassium Fulvate on Yield and Quality of Tomato and Soil Physical and Chemical Properties

This study was conducted to study the optimum dosage of potassium ful- vate （PF） on greenhouse tomato, the effects of different amounts of PF on yield and quality of greenhouse tomato and soil physical and chemical properties were investigated by a field plot experiment. The results showed that the bottom applica- tion of PF increased tomato yield, plant dry matter weight and root dry matter weight by 14.0%, 14.4 and 50.6%, respectively; Vc and soluble sugar content of tomato increased by 1＆5% and 10.0%, respectively; and soil bulk density de- creased by 3.6%, and CEC increased by 5.0%. All the indexes increased with the increase of PF application amount, and reached the maximum value when the PF application rate was 4 500 kg/hm2. In consideration of the cost of fertilizer and all indexes, the optimum dosaqe of PF fertilizer was 4 500 kg/hm2.

Changing Rule of Physical and Chemical Indicators of Sediment in Tilapia Aquaculture Ponds

To provide basic information for studying balancing mechanism of nutrition environment in aquaculture ponds, sediment samples were collected periodically during the breeding process of tilapia in ponds. Then various types of nutrient content of the samples were detected and the changing rule was summarized. The results showed that dry weight of the sediment and content of TP, TN and TOC generally presented a trend of first increasing and then decreasing. The main production period of each nutrient was from July to September and the production percentage was close to 80% of the total production. The content of NH4^＋-N increased gradually and reached a peak in early August, then maintained at the peak level. NO2^--N content of the sediment in each pond was basically the same in the earlier aquaculture stage and decreased in middle stage with a big difference, then rose again in the later stage.

Soil Physical and Chemical Properties of Five Subtropical Forests in Lingao of Hainan

With 5 types of typical forests as research object, the physical and chemical properties of different types of forests were analyzed by sample plot investigation method. The results showed that： the soil total porosity was the highest in the Casuarina equisetifolia forest （46.168%）, but the lowest in the Encalyptus robusta forest （39.46%）. The soil capillary porosity was the highest in the Acacia mangium forest （22.57%）, but the lowest in the secondary forest （18.95%）. The soil water content was the highest in the C. equisetifolia forest, with a mean value of 27.85%, but the lowest in the secondary forest, with a mean value of 4.34%. The soil pH values were in the range of 4.81-6.59, the soils in the A. mangium forest, C. equisetifolia forest and E. robusta forest were strongly acidic （pH 4.5-5.5）, and the soils in the secondary forest and C. nucifera forest were weakly acidic. The soils had organic matter contents in the range of 0.34-28.68 g/kg, and showed an order of A. mangium forest〉C. equisetifolia forest〉E. robusta forest〉secondary forest〉C. nucifera forest, with a decreasing trend with the soil depth increasing. The soil total N contents were in the range of 0.10-1.63 g/kg, the A. mangium forest showed the highest soil total N contents, while the C. nucifera forest exhibited the lowest soil total N contents; the soil total P contents were in the range of 0.21-1.74 g/kg, and the E. robusta forest had the highest soil total P contents; and the soil total K contents were in the range of 0.16-2.15 g/kg, and the A. mangium forest exhibited the highest soil total K contents. The soil available P contents were in the range of 0.98-132.46 mg/kg; and the secondary forests had the highest soil available P contents; and the soil rapidly available K contents were in the range of 3.03-27.35 mg/kg, and the C. nucifera forest exhibited the highest soil rapidly available K contents. The soil ammonium N contents were in the range of 1.38-5.15 mg/kg, and the nitrate N contents were in the range were in the range of 0.56 -3.51 mg/kg. The A. mangium forest showed the highest soil nitrate N contents （with a mean value of 2.29 mg/kg） and ammonium N contents （with a mean value of 3.93 mg/kg）. For the same forest type, with the increase of soil depth, the nitrate nitrogen and ammonium nitrogen content also showed a decreasing trend.

Research on Physical and Chemical Properties of Corynebacterium glutamicum in Fermentation Process of the Glucose of Wheat Starch

[Objective] This study aimed to investigate the physical and chemical char- acteristic of Corynebacterium glutamicum in fermentation process of the glucose of wheat starch. [Method] The purity of glutamic acid in fermentation period, optical density and cell viability of bacteria were detected as indicators for regression com- parison and analysis. [Result] The relative error d=-3.316 6% within the experimental range of Warburg trace breathing apparatus and double function analyzer. The linear relationship was s1=（1-d）s2. During the fermentation process of the glucose of wheat starch, the average cell activity was 6.24 μA and the maximum cell activity was 6.61 μA. [Conclusion] Compared with optical density, cell viability can more accurate- ly reflect the physical and chemical properties of Corynebacterium glutamicum in fermentation process of the glucose of wheat starch. There was certain correlation between cell membrane phospholipids and cell viability.

The autophagy-lysosome pathway:a potential target in the chemical and gene therapeutic strategies for Parkinson’s disease

Parkinson’s disease is a common neurodegenerative disease with movement disorders associated with the intracytoplasmic deposition of aggregate proteins such asα-synuclein in neurons.As one of the major intracellular degradation pathways,the autophagy-lysosome pathway plays an important role in eliminating these proteins.Accumulating evidence has shown that upregulation of the autophagy-lysosome pathway may contribute to the clearance ofα-synuclein aggregates and protect against degeneration of dopaminergic neurons in Parkinson’s disease.Moreover,multiple genes associated with the pathogenesis of Parkinson’s disease are intimately linked to alterations in the autophagy-lysosome pathway.Thus,this pathway appears to be a promising therapeutic target for treatment of Parkinson’s disease.In this review,we briefly introduce the machinery of autophagy.Then,we provide a description of the effects of Parkinson’s disease–related genes on the autophagy-lysosome pathway.Finally,we highlight the potential chemical and genetic therapeutic strategies targeting the autophagy–lysosome pathway and their applications in Parkinson’s disease.

Classification and Distribution of Common Aroma Components in Tobacco Leaf Based on Their Physical and Chemical Properties

[Objective] This study was aimed to find a new method for the classification of common aroma components in tobacco leaves. [Method] Sixty-four common aroma components in tobacco leaves were classified by cluster analysis based on their relative molecular weight. The contents and distribution of aroma components in another 71 C3F and 64 B2F tobacco leaf samples were analyzed by using the new method. [Result] The 64 common aroma components were divided into three categories trough the cluster analysis based on their molecular weight. CategoryⅠ consisted of 12 aroma components which had high molecular weight（281.308±21.536on average） and high boiling point（371.311±29.904 ℃ on average）. Category Ⅱ included 27 components which had low molecular weight（103.722 ± 13.115 on average） and low boiling point（176.132±42.342 ℃ on average）. Category Ⅲ included 25components which had middle molecular weight（175.393 ± 24.906 on average） and middle boiling point（250.562±45.431 ℃ on average）. The content of high-molecularweight aroma components in middle leaves（547.344±224.391 μg/g） was much higher than that in upper leaves（477.549±182.066 μg/g）. The content of low-molecularweight aroma component in middle leaves（17.468±3.459 μg/g） was also significantly higher than that in upper leaves（15.936±3.456 μg/g）. The content of middle-molecular-weight aroma component in middle leaves（44.931 ±8.953 μg/g） was extremely significantly higher than that in upper leaves（37.997±6.042 μg/g）. [Conclusion] This study proposed a new way to classify the aroma components in flue-cured tobacco leaves using the relative molecular weight as the index, which will provide theoretical reference for developing special tobacco leaves.

Effects of Green Manure Mixed Cropping Patterns on Physical and Chemical Properties of Soil and Economic Characters of Flue-cured Tobacco

[Objective] The aim was to clear the suitable green manure cropping pat- terns in Xiangxi tobacco-planting areas. [Method] 8 treatments were set to study the effects of the monoculture and mixed cropping of common vetch （Vicia gigantea Bge.）, perennial ryegrass （Lofium） and rapeseed （Brassica campestris L.） on physi- cal and chemical properties of soil and economic characters of flue-cured tobacco. [Result] （1） Green manure turnover can reduce soil bulk density by 1.08%-8.62%, and the effect of green manure mixed cropping pattern was the best. （2） Green manure turnover also can increase the soil nutrient, soil organic matter, total nitro- gen （N）, total phosphorus （P）, total potassium （K）, alkali-hydrolyzale N, rapidly available P and rapidly available K by 1.44%-6.10%, 0.01-0.12 g/kg, 1.89%- 11.32%, 0.12%-3.56%, 1.06%-11.76%, 0.04%-18.93% and 0.98%-23.12%, respec- tively, and the effect of the monoculture of common vetch was the best.（3） The overall change of soil pH was not obvious.（4）Green manure turnover can increase the yield and output of flue-cured tobacco, and the effect of the monoculture of common vetch was the best. [Conclusion] The monoculture of common vetch can be generalized in the dry land of Xiangxi tobacco-planting areas.

Comparative Study of Physico-Chemical and Biological Water Quality Upstream and Downstream of the Manantali Dam and Hydropower Plant from 2019 to 2023

The comparative study is designed to monitor the physico-chemical and biological quality of the water upstream and downstream of the Manantali hydroelectric dam. The physico-chemical parameters are sampled at 3 measuring points located at Station 1 of the dam’s reservoir, immediately downstream of the dam and hydroelectric power station at the level of the damping basin, and at the Bafing-Bakoye confluence at Bafoulabe (Bafing side), the biological parameter (ichthyological fauna) is characterized by ichthyological inventories of landings in the various fishing camps around the reservoir and at the Mahina market (Bafing side). The study assesses the environmental impact of hydroelectric structures and facilities on the physico-chemical and biological quality of the water. Physical parameters such as temperature, conductivity, pH, turbidity and chemical parameters such as dissolved oxygen, nitrite, nitrate, manganese, hydrogen sulfide, ammonium, iron, silica and phosphorus are measured in order to identify the various variations existing between the different measurement points. Analysis of the values obtained shows very high similarities between the various measuring points, and most parameters comply with WHO standards, with the exception of turbidity, manganese, hydrogen sulfide and iron. These data attest to good water quality, allowing normal development of flora and fauna with a low level of degradation. Comparative analysis of the ichthyological fauna shows the existence of 34 species of fish belonging to 11 families at the fishing camps around the Manantali dam reservoir, and 37 species belonging to 12 families at Mahina on the Bafing River. At Mahina on the Bafing, the specific composition of the catches is characterized by the presence of the Claroteidae family and four species (Alestes sp., Brycinus leuciscus, Auchenoglanis occidentalis, Distichodus engycephalus) not recorded at the camps. In contrast, all the fish families recorded in the camps are present in Mahina, and only one species (Hydrocynus brevis) is absent from the Mahina landings. The difference in species richness could be explained by the upwelling of some fish from the Bakoye to the Bafing at the confluence. The Shannon diversity index of 4.07 at Mahina is higher than the 2.98 recorded at camp level, and the equitability index of 0.78 at Mahina and 0.58 at the camp level indicate average diversity and the non-dominance of one species over the others. The diversification index values of 3.09 and 3.08 at camp level and Mahina respectively show that the number of theoretical habitats is three.

Assessment of the Variations in Soil Physicochemical Parameters of the Natural Forest and Plantations in Orumba North Local Government Area, Anambra State, Nigeria

Soil physicochemical parameters are the physical and chemical characteristics of soil such as pH, bulk density, organic carbon, nitrogen content, and nutrient levels at different soil depths. These parameters vary from one vegetation to the other and from one soil to the other. The study assessed the variations in soil physicochemical parameters of the natural forest and plantations in Agu Eke (Eke bush) in Etti village, Nanka and Umunnebo village, Ufuma both located in Orumba North Local Government Area, Anambra State. The experimental research design and stratified random sampling methods were used for the study and a total of 12 soil samples were collected at 30 cm depth from the selected locations of natural forest, cashew and palm plantations. The samples were analyzed using laboratory Varian AA240 Atomic Absorption Spectrophotometer, after which the result was subjected to statistical analysis—Analysis of Variance (ANOVA). The study found that there was no significant difference (variation) between the moisture contents of natural forests and the plantations;that is, the moisture contents were the same. It was also found that there was no significant variation between the bulk densities of the natural forest, oil plantation, and cashew plantation, meaning that the bulk densities were significantly the same. However, there were significant variations in nitrogen, potassium and phosphates, with p-values: sig = .000 < .05, sig = .010 < .05 and sig = .000 < .05, respectively. That is, the nitrogen and phosphate contents of the natural forest significantly vary more than those of the oil palm and cashew plantations, which probably means that by reducing natural forest to plantation, the nitrogen and phosphate contents of the natural forest reduced from what it used to be when the lands were mere forests. This shows that plantations do not have the same function of maintaining or improving soil quality as natural forests. The study recommended adopting a sustainable plantation agricultural system, such as using diverse nutrient sources (manure and compost), in order to maintain the desired soil quality.

Edge effect during microwave plasma chemical vapor deposition diamond-film:Multiphysics simulation and experimental verification

This study focused on the investigation of the edge effect of diamond films deposited by microwave plasma chemical vapor de-position.Substrate bulge height△h is a factor that affects the edge effect,and it was used to simulate plasma and guide the diamond-film deposition experiments.Finite-element software COMSOL Multiphysics was used to construct a multiphysics(electromagnetic,plasma,and fluid heat transfer fields)coupling model based on electron collision reaction.Raman spectroscopy and scanning electron microscopy were performed to characterize the experimental growth and validate the model.The simulation results reflected the experimental trends observed.Plasma discharge at the edge of the substrate accelerated due to the increase in△h(△h=0-3 mm),and the values of electron density(n_(c)),molar concentration of H(C_(H)),and molar concentration of CH_(3)(C_(CH_(3)))doubled at the edge(for the special concave sample with△h=−1 mm,the active chemical groups exhibited a decreased molar concentration at the edge of the substrate).At=0-3 mm,a high diamond growth rate and a large diamond grain size were observed at the edge of the substrate,and their values increased with.The uniformity of film thickness decreased with.The Raman spectra of all samples revealed the first-order characteristic peak of dia-mond near 1332 cm^(−1).When△h=−1 mm,tensile stress occurred in all regions of the film.When△h=1-3 mm,all areas in the film ex-hibited compressive stress.

Effect of fire severity on physical and biochemical soil properties in Zagros oak(Quercus brantii Lindl.)forests in Iran

Fire affects the physical and chemical properties and soil biological activity of natural ecosystems. This study was conducted in the Miyan Tang region, Ilam Province in western Iran. The study site was 110 hectares, where we sampled soils in areas that were classified by fire severity： low （LS）, high （HS） and medium severity （MS）, and unburned （UB）, which served as the control. In each severity class, 25 transect points were randomly selected for measurement. Around each transect plot center, 3 soil samples were selected randomly and soils collected from the 0 to 20 cm depth were combined into a composite sample that was used in laboratory analysis to represent conditions at that point. Plots in the UB and LS fire classes had similar soil conditions and had higher values of factors such as saturated moisture, organic carbon, carbon dioxide, and silt and clay content. In contrast, plots in the HS and MS fire severity classes were clustered in the positive direction along the first axis that represented gradients in soil acidity, electrical conductivity, cation exchange capacity, accessible phosphorus, accessible potassium, bulk density, and sand. Soil attributes were similar in areas of HS and MS fire severity classes, whereas soil conditions in the LS class and UB controls were most similar. Fire in the LS areas either did not significantly alter the physicalchemical soil properties and microbial basal respiration, or soils were able to recover quickly after being burned.

Recent progress on confinement of polysulfides through physical andchemical methods

With high theoretical energy density and the natural abundance of S, lithium-sulfur （Li-S） batteries areconsidered to be the promising next generation high-energy rechargeable energy storage devices. How-ever, issues including electronical insulation of S, the lithium polysulfides （LiPSs） dissolution and the shortcycle lifespan have prevented Li-S batteries from being practical applied. Feasible settlements of confiningLiPSs to reduce the loss of active substances and improve the cycle stability include wrapping sulfur withcompact layers, designing matrix with porous or hollow structures, adding adsorbents owning stronginteraction with sulfur and inserting polysulfide barriers between cathodes and separators. This reviewcategorizes them into physical and chemical confinements according to the influencing mechanism. Withfurther discussion of their merits and flaws, synergy of the physical and chemical confinement is believedto be the feasible avenue that can guide Li-S batteries to the practical application.

Separator coatings as efficient physical and chemical hosts of polysulfides for high-sulfur-loaded rechargeable lithium–sulfur batteries

Lithium-sulfur batteries(LSBs)are promising alternative energy storage devices to the commercial lithium-ion batteries.However,the LSBs have several limitations including the low electronic conductivity of sulfur(5×10^-30S cm^-1),associated lithium polysulfides(PSs),and their migration from the cathode to the anode.In this study,a separator coated with a Ketjen black(KB)/Nafion composite was used in an LSB with a sulfur loading up to 7.88 mg cm^-2to mitigate the PS migration.A minimum specific capacity(Cs)loss of 0.06%was obtained at 0.2 C-rate at a high sulfur loading of 4.39 mg cm^-2.Furthermore,an initial areal capacity up to 6.70 mAh cm^-2 was obtained at a sulfur loading of 7.88 mg cm^-2.The low Cs loss and high areal capacity associated with the high sulfur loading are attributed to the large surface area of the KB and sulfonate group(SO3^-)of Nafion,respectively,which could physically and chemically trap the PSs.