期刊文献+
共找到86,636篇文章
< 1 2 250 >
每页显示 20 50 100
Applications and functions of rare-earth ions in perovskite solar cells 被引量:1
1
作者 Limin Cang Zongyao Qian +5 位作者 Jinpei Wang Libao Chen Zhigang Wan Ke Yang Hui Zhang Yonghua Chen 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第3期36-51,共16页
The emerging perovskite solar cells have been recognized as one of the most promising new-generation photovoltaic technologies owing to their potential of high efficiency and low production cost. However, the current ... The emerging perovskite solar cells have been recognized as one of the most promising new-generation photovoltaic technologies owing to their potential of high efficiency and low production cost. However, the current perovskite solar cells suffer from some obstacles such as non-radiative charge recombination, mismatched absorption, light induced degradation for the further improvement of the power conversion efficiency and operational stability towards practical application. The rare-earth elements have been recently employed to effectively overcome these drawbacks according to their unique photophysical properties. Herein, the recent progress of the application of rare-earth ions and their functions in perovskite solar cells were systematically reviewed. As it was revealed that the rare-earth ions can be coupled with both charge transport metal oxides and photosensitive perovskites to regulate the thin film formation, and the rare-earth ions are embedded either substitutionally into the crystal lattices to adjust the optoelectronic properties and phase structure, or interstitially at grain boundaries and surface for effective defect passivation. In addition, the reversible oxidation and reduction potential of rare-earth ions can prevent the reduction and oxidation of the targeted materials. Moreover, owing to the presence of numerous energetic transition orbits, the rare-earth elements can convert low-energy infrared photons or high-energy ultraviolet photons into perovskite responsive visible light, to extend spectral response range and avoid high-energy light damage. Therefore, the incorporation of rare-earth elements into the perovskite solar cells have demonstrated promising potentials to simultaneously boost the device efficiency and stability. 展开更多
关键词 PEROVSKITE solar cells rare-earth ions power conversion efficiency
下载PDF
Influence of rare-earth ions on structural and magnetic properties of CdFe_2O_4 ferrites 被引量:3
2
作者 Ashok Gadkari Tukaram Shinde Pramod Vasambekar 《Rare Metals》 SCIE EI CAS CSCD 2010年第2期168-173,共6页
Nano-sized powders of rare-earth ions added CdFe2O4 ferrites were synthesized by oxalate co-precipitation method.The influence of R ions(R = Sm3+, Y3+, and La3+) on the microstructure and magnetic properties of C... Nano-sized powders of rare-earth ions added CdFe2O4 ferrites were synthesized by oxalate co-precipitation method.The influence of R ions(R = Sm3+, Y3+, and La3+) on the microstructure and magnetic properties of CdFe2O4 ferrites was studied.XRD, SEM, FTIR, and magnetic hysteresis loops were used for analyzing the samples.The addition of R ions alters the structure of the powders and decreases the crystalline size, lattice constant, and grain size.The magnetic properties such as saturation magnetization, remanent magnetization, and magnetic moment increased due to addition of rare-earth ions in CdFe2O4 ferrite.The formation of secondary phase on the grain boundaries supports the abnormal growth.FTIR spectra show two absorption bands.Results suggest that the magnetic properties depend on the particular method of preparation and additives. 展开更多
关键词 nanoparticle rare-earth ions magnetization grain size hysteresis
下载PDF
Simulating resonance-mediated two-photon absorption enhancement in rare-earth ions by a rectangle phase modulation
3
作者 齐大龙 郑烨 +6 位作者 程文静 姚云华 邓联忠 冯东海 贾天卿 孙真荣 张诗按 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第1期329-334,共6页
Improving the up-conversion luminescence efficiency crucial in several related application areas. In this work, of rare-earth ions via the multi-photon absorption process is we theoretically propose a feasible scheme ... Improving the up-conversion luminescence efficiency crucial in several related application areas. In this work, of rare-earth ions via the multi-photon absorption process is we theoretically propose a feasible scheme to enhance the resonance-mediated two-photon absorption in Er3+ ions by shaping the femtosecond laser field with a rectangle phase modulation. Our theoretical results show that the resonance-mediated two-photon absorption can be decomposed into the on-resonant and near-resonant parts, and the on-resonant part mainly comes from the contribution of laser central frequency components, while the near-resonant part mainly results from the excitation of low and high laser frequency components. So, the rectangle phase modulation can induce a constructive interference between the two parts by properly designing the modulation depth and width, and finally realizes the resonance-mediated two-photon absorption enhancement. More- over, our results also show that the enhancement efficiency of resonance-mediated two-photon absorption depends on the laser pulse width (or laser spectral bandwidth), final state transition frequency, and intermediate and final state absorption bandwidths. The enhancement efficiency modulation can be attributed to the relative weight manipulation of on-resonant and near-resonant two-photon absorption in the whole excitation process. This study presents a clear physical insight for the quantum control of resonance-mediated two-photon absorption in the rare-earth ions, and there will be an important significance for improving the up-conversion luminescence efficiency of rare-earth ions. 展开更多
关键词 coherent quantum control femtosecond pulse shaping two-photon absorption rare-earth ions
下载PDF
Simulation of Intermediate State Absorption Enhancement in Rare-Earth Ions by Polarization Modulated Femtosecond Laser Field
4
作者 Wen-Jing Cheng Shi-Hua Zhao 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第11期23-27,共5页
We extend the third perturbation theory to study the polarization control behavior of the intermediate state absorption in Nd^(3+)ions. The results show that coherent interference can occur between the single-photo... We extend the third perturbation theory to study the polarization control behavior of the intermediate state absorption in Nd^(3+)ions. The results show that coherent interference can occur between the single-photon and three-photon excitation pathways, and depends on the central frequency of the femtosecond laser field. Moreover,single-photon and three-photon absorptions have different polarization control efficiencies, and the relative weight of three-photon absorption in the whole excitation processes can increase with increasing the laser intensity.Therefore, the enhancement or suppression of the intermediate state absorption can be realized and manipulated by properly designing the intensity and central frequency of the polarization modulated femtosecond laser field.This research can not only enrich theoretical research methods for the up-conversion luminescence manipulation of rare-earth ions, but also can provide a clear physical picture for understanding and controlling multi-photon absorption in a multiple energy level system. 展开更多
关键词 ab Simulation of Intermediate State Absorption Enhancement in rare-earth ions by Polarization Modulated Femtosecond Laser Field
下载PDF
Additive Effects of Rare-Earth Ions in Sodium Aluminoborate Glasses Using <sup>23</sup>Na and <sup>27</sup>Al Magic Angle Spinning Nuclear Magnetic Resonance
5
作者 Shunichi Kaneko Yomei Tokuda Hirokazu Masai 《New Journal of Glass and Ceramics》 2017年第3期58-76,共19页
We conducted structural analysis of xNa2O-yY2O3-5B2O3-3Al2O3 and xNa2O-yLa2O3-5B2O3-3Al2O3 glasses to elucidate the additive effects of rare-earth ions in these sodium aluminoborate glasses, and investigated the local... We conducted structural analysis of xNa2O-yY2O3-5B2O3-3Al2O3 and xNa2O-yLa2O3-5B2O3-3Al2O3 glasses to elucidate the additive effects of rare-earth ions in these sodium aluminoborate glasses, and investigated the local environment surrounding Na+ in them by using 23Na and 27Al magic angle spinning?nuclear magnetic resonance (MAS NMR) spectroscopy. The amount of higher-coordinated Al species ([5]Al and [6]Al) gradually increased in response to an increase in the ratios of Y2O3 to Al2O3 and La2O3 to Al2O3 in each type of glass, respectively. Moreover, the difference in the cation field strength (CFS) between Y3+ and La3+ was observed to affect the generation of [5]Al and [6]Al, especially when the amount of these ions in the glasses increased. In addition to the above, the coordination number of Na+ ions increased with an increase in the number of rare earth ions, confirmed by comparing results with NMR spectra of crystalline Na2Al2B2O7. The latter possibly occurred due to the oxygen concentration on Al[5] and Al[6]. Finally, it was confirmed that the formation of [5]Al and [6]Al decreases molar volume in oxide glasses, which might be partially due to better atomic packing of [5]Al and [6]Al. 展开更多
关键词 NMR Aluminoborate rare-earth
下载PDF
Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy
6
作者 Tongyue Li Ziliang Xie +5 位作者 Wenjiao Zhou Huan Tong Dawen Yang Anjia Zhang Yuan Wu Xiping Song 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期127-135,共9页
This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with t... This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed homogeneously.Upon hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase precipitated.The alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period observed.The reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral interstices.These results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field. 展开更多
关键词 rare-earth high-entropy alloy hydrogen absorption capacity pressure–composition–temperature curves KINETICS
下载PDF
Solid-state quantum nodes based on color centers and rare-earth ions coupled with fiber Fabrye-Pérot microcavities
7
作者 Ruo-Ran Meng Xiao Liu +3 位作者 Ming Jin Zong-Quan Zhou Chuan-Feng Li Guang-Can Guo 《Chip》 EI 2024年第1期84-101,共18页
High-performance optical quantum memories serving as quantum nodes are crucial for the distribution of remote entanglement and the construction of large-scale quantum networks.Notably,quantum systems based on single e... High-performance optical quantum memories serving as quantum nodes are crucial for the distribution of remote entanglement and the construction of large-scale quantum networks.Notably,quantum systems based on single emitters can achieve deterministic spin–photon entanglement,which greatly simplifies the difficulty of constructing quantum network nodes.Among them,optically interfaced spins embedded in solid-state systems,as atomic-like emitters,are important candidate systems for implementing long-lived quantum memory due to their stable physical properties and robustness to decoherence in scalable and compact hardware.To enhance the strength of light-matter interactions,optical microcavities can be exploited as an important tool to generate high-quality spin–photon entanglement for scalable quantum networks.They can enhance the photon collection probability and photon generation rate of specific optical transitions and improve the coherence and spectral purity of emitted photons.For solid-state systems,open Fabry–Pérot cavities can couple single emitters that are not in proximity to the surface,avoiding significant spectral diffusion induced by the interfaces while maintaining the wide tunability,which enables addressing of multiple single emitters in the frequency and spatial domain within a single device.This review described the characteristics of single emitters as quantum memories with a comparison to atomic ensembles,the cavity-enhancement effect for single emitters and the advantages of different cavities,especially fiber Fabry–Pérot microcavities.Finally,recent experimental progress on solid-state single emitters coupled with fiber Fabry–Pérot microcavities was also reviewed,with a focus on color centers in diamond and silicon carbide,as well as rare-earth dopants. 展开更多
关键词 Quantum nodes Deterministic spin-photon entanglement Fiber Fabry-Pérot microcavities Color centers rare-earth dopants
原文传递
Rare-earth ions coordination enhanced ratiometric fluorescent sensing platform for quantitative visual analysis of antibiotic residues in real samples 被引量:1
8
作者 Shihao Xu Lingfei Li +3 位作者 Dan Lin Liang Yang Zhenyang Wang Changlong Jiang 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第6期278-281,共4页
Levofloxacin(LVFX)as a representative drug of quinolone antibiotics is widely used in clinical,and its residues enriched in water bodies and sideline products seriously damage human health.It is imperative to develop ... Levofloxacin(LVFX)as a representative drug of quinolone antibiotics is widely used in clinical,and its residues enriched in water bodies and sideline products seriously damage human health.It is imperative to develop a real-time/on-site sensing method for monitoring residual antibiotics.Here,we report a portable sensing platform by utilizing a composite fluorescent nanoprobe constructed by the cerium ions(Ce^(3+))coordination functionalized Cd Te quantum dots(QDs)for the visual and quantitative detection of LVFX residues.This fluorescent probe provides a distinct color variation from red to green,which shows a good linear relationship to LVFX residues concentrations in the range of 0-6.0μmol/L with a sensitive limit of detection(LOD)of 16.3 nmol/L.The smartphone platform with Color Analyzer App installed,which could accomplish quantified detection of LVFX in water,milk,and raw pork with a LOD of 27.9nmol/L.The facile sensing method we proposed realizes rapid visualization of antibiotics residual in the environment and provides a practical application pathway in food safety and human health. 展开更多
关键词 rare-earth ions Ratiometric fluorescence probe Smartphone sensing platform Quantitative detection LEVOFLOXACIN
原文传递
Electrical switching in cadmium ferrite with different rare-earth ions(Sm^(3+), Y^(3+), and La^(3+)) 被引量:1
9
作者 Sanjeev P.Dalawai Ashok B.Gadkari Pramod N.Vasambekar 《Rare Metals》 SCIE EI CAS CSCD 2015年第2期133-136,共4页
The cadmium ferrite and 5 % rare-earth ions(Sm^3+, Y^3+, and La^3+) added Cd ferrites were synthesized by oxalate co-precipitation method and characterized by X-ray diffraction(XRD), Fourier transform infrared ... The cadmium ferrite and 5 % rare-earth ions(Sm^3+, Y^3+, and La^3+) added Cd ferrites were synthesized by oxalate co-precipitation method and characterized by X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), and scanning electron microscope(SEM) techniques. All ferrite samples under investigation exhibit current-controlled negative resistance type I–E characteristics at room temperature. The required electrical-switching field in cadmium ferrite is higher than that for 5 % Sm^3+, Y^3+, and La^3+added cadmium ferrites. The5% addition of Sm^3+, Y^3+, and La^3+ in cadmium ferrite is found to decrease the grain size in this ferrite. This decrement in the grain size makes the required switching field to decrease in cadmium ferrite. No aging effect for electrical switching is observed in these ferrites. 展开更多
关键词 rare-earth ions Current-controlled negativeresistance type electrical switching Grain size Cd ferrite
原文传递
Na^(+)/K^(+)-ATPase:ion pump,signal transducer,or cytoprotective protein,and novel biological functions 被引量:2
10
作者 Songqiang Huang Wanting Dong +1 位作者 Xiaoqian Lin Jinsong Bian 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第12期2684-2697,共14页
Na^(+)/K^(+)-ATPase is a transmembrane protein that has important roles in the maintenance of electrochemical gradients across cell membranes by transporting three Na^(+)out of and two K^(+)into cells.Additionally,Na^... Na^(+)/K^(+)-ATPase is a transmembrane protein that has important roles in the maintenance of electrochemical gradients across cell membranes by transporting three Na^(+)out of and two K^(+)into cells.Additionally,Na^(+)/K^(+)-ATPase participates in Ca^(2+)-signaling transduction and neurotransmitter release by coordinating the ion concentration gradient across the cell membrane.Na^(+)/K^(+)-ATPase works synergistically with multiple ion channels in the cell membrane to form a dynamic network of ion homeostatic regulation and affects cellular communication by regulating chemical signals and the ion balance among different types of cells.Therefo re,it is not surprising that Na^(+)/K^(+)-ATPase dysfunction has emerged as a risk factor for a variety of neurological diseases.However,published studies have so far only elucidated the important roles of Na^(+)/K^(+)-ATPase dysfunction in disease development,and we are lacking detailed mechanisms to clarify how Na^(+)/K^(+)-ATPase affects cell function.Our recent studies revealed that membrane loss of Na^(+)/K^(+)-ATPase is a key mechanism in many neurological disorders,particularly stroke and Parkinson's disease.Stabilization of plasma membrane Na^(+)/K^(+)-ATPase with an antibody is a novel strategy to treat these diseases.For this reason,Na^(+)/K^(+)-ATPase acts not only as a simple ion pump but also as a sensor/regulator or cytoprotective protein,participating in signal transduction such as neuronal autophagy and apoptosis,and glial cell migration.Thus,the present review attempts to summarize the novel biological functions of Na^(+)/K^(+)-ATPase and Na^(+)/K^(+)-ATPase-related pathogenesis.The potential for novel strategies to treat Na^(+)/K^(+)-ATPase-related brain diseases will also be discussed. 展开更多
关键词 ANTIBODY biological functions cellular communication electrochemical gradient ion balance ion channels Na^(+)/K^(+)-ATPase neurological diseases neurotransmitter release signal transduction
下载PDF
Monolithic crystalline silicon solar cells with SiN_x layers doped with Tb^(3+) and Yb^(3+) rare-earth ions 被引量:3
11
作者 Ing-Song Yu Shao-Chun Wu +3 位作者 Lucile Dumont Julien Cardin Christophe Labbé Fabrice Gourbilleau 《Journal of Rare Earths》 SCIE EI CAS CSCD 2019年第5期515-519,共5页
In this study, we propose the fabrication of monolithic crystalline silicon solar cells with Tb^(3+) and Yb^(3+)-doped silicon nitride(SiN_x) layers by low-cost screen-printing methods. The performances of c-Si solar ... In this study, we propose the fabrication of monolithic crystalline silicon solar cells with Tb^(3+) and Yb^(3+)-doped silicon nitride(SiN_x) layers by low-cost screen-printing methods. The performances of c-Si solar cells can be enhanced by rare-earth ions doped SiN_x layers via the mechanism of spectrum conversion.These SiN_x doped and codoped thin films were deposited by reactive magnetron co-sputtering and integrated as the antireflection coating layers in c-Si solar cells. The characterizations of SiN_x, SiN_x:Tb^(3+) tand SiN_x:Tb^(3+)-Yb^(3+) thin films were conducted by means of photoluminescence, Rutherford backscattering spectroscopy, Ellipsometry spectroscopy and Fourier transform infrared measurements. Their composition and refractive index was optimized to obtain good anti-reflection coating layer for c-Si solar cells.Transmission electron microscopy performs the uniform coatings on the textured emitter of c-Si solar cells. After the metallization process, we demonstrate monolithic c-Si solar cells with spectrum conversion layers, which lead to a relative increase by 1.34% in the conversion efficiency. 展开更多
关键词 Crystalline SILICON solar cell Spectrum conversion SILICON NITRIDE Down-shifting rare-earth ion ANTI-REFLECTion coating
原文传递
Recent developments and applications on high-performance cast magnesium rare-earth alloys 被引量:62
12
作者 Guohua Wu Cunlong Wang +1 位作者 Ming Sun Wenjiang Ding 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2021年第1期1-20,共20页
During the past decades,with the increasing demands in lightweight structural materials,Mg alloys with low density and high performance have been extensively investigated and partly applied in some industries.Especial... During the past decades,with the increasing demands in lightweight structural materials,Mg alloys with low density and high performance have been extensively investigated and partly applied in some industries.Especially when rare earth(RE)elements are added as major alloying elements to Mg alloys,the alloy strength and creep resistance are greatly improved,which have promoted several series of Mg-RE alloys.This paper reviews the progress and developments of high-performance Mg-RE alloys in recent years with emphasis on cast alloys.The main contents include the alloy design,melt purification,grain refinement,castability,novel liquid casting and semisolid forming approaches,and the industrial applications or trials made of Mg-RE alloys.The review will provide insights for future developments of new alloys,techniques and applications of Mg alloys. 展开更多
关键词 Magnesium alloys rare-earth elements HIGH-PERFORMANCE DEVELOPMENTS Applications CAST
下载PDF
Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries 被引量:1
13
作者 Wenli Shu Junxian Li +3 位作者 Guangwan Zhang Jiashen Meng Xuanpeng Wang Liqiang Mai 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期142-168,共27页
Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonethel... Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries. 展开更多
关键词 Prussian blue analogs Transition metal ions dissolution Suppression strategies Aqueous sodium-ion batteries Aqueous potassium-ion batteries
下载PDF
Self-aldol condensation of aldehydes over Lewis acidic rare-earth cations stabilized by zeolites 被引量:2
14
作者 Tingting Yan Sikai Yao +3 位作者 Weili Dai Guangjun Wu Naijia Guan Landong Li 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第4期595-605,共11页
The self-aldol condensation of aldehydes was investigated with rare-earth cations stabilized by[Si]Beta zeolites in parallel with bulk rare-earth metal oxides.Good catalytic performance was achieved with all Lewis aci... The self-aldol condensation of aldehydes was investigated with rare-earth cations stabilized by[Si]Beta zeolites in parallel with bulk rare-earth metal oxides.Good catalytic performance was achieved with all Lewis acidic rare-earth cations stabilized by zeolites and yttrium appeared to be the best metal choice.According to the results of several complementary techniques,i.e.,temperature-programmed surface reactions,in situ diffuse reflectance infrared Fourier transform spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,the reaction pathway and mechanism of the aldehyde self-aldol condensation over Y/Beta catalyst were studied in more detail.Density functional theory calculations revealed that aldol dehydration was the rate-limiting step.The hydroxyl group at the open yttrium site played an important role in stabilizing the transition state of the aldol dimer reducing the energy barrier for its hydration.Lewis acidic Y(OSi)(OH)2 stabilized by zeolites in open configurations were identified as the preferred active sites for the self-aldol condensation of aldehydes. 展开更多
关键词 Self-aldol condensation ALDEHYDE rare-earth cations Zeolite Lewis acid
下载PDF
Determination of Carbon and Nitrogen Isotope Fractions in Tartaric Acid, Oxalic Acid, Glucose and Fructose—National Center of High Technologies of Georgia
15
作者 Lamzira Pharulava Levani Eliashvili +1 位作者 Vakhtang Betlemidze Bachana Sulava 《American Journal of Analytical Chemistry》 CAS 2024年第8期229-240,共12页
Tartaric acid, oxalic acid, glucose, and fructose are highly important compounds. A comprehensive study of these substances is fascinating from a scientific perspective. They are key components found in wine, vegetabl... Tartaric acid, oxalic acid, glucose, and fructose are highly important compounds. A comprehensive study of these substances is fascinating from a scientific perspective. They are key components found in wine, vegetables, and fruits. Understanding the isotopic compositions in organic compounds is crucial for comprehending various biochemical processes and the nature of substances present in different natural products. Tartaric acid, oxalic acid, glucose, and fructose are widely distributed compounds, including in vegetables and fruits. Tartaric acid plays a significant role in determining the quality and taste properties of wine, while oxalic acid is also prevalent but holds great interest for further research, especially in terms of carbon isotopic composition. We can unveil the mechanisms of processes that were previously impossible to study. Glucose and fructose are the most common monosaccharides in the hexose group, and both are found in fruits, with sweeter fruits containing higher amounts of these substances. In addition to fruits, wheat, barley, rye, onions, garlic, lentils, peppers, dried fruits, beans, broccoli, cabbage, tomatoes, and other foods are also rich sources of fructose and glucose. To determine the mass fraction of the carbon-13 isotope in these compounds, it is important to study their changes during natural synthesis. These compounds can be modified with a carbon center. According to the existing isotopic analysis method, these compounds are converted into carbon oxide or dioxide [1]. At this point, the average carbon content in the given compound is determined, but information about isotope-modified centers is lost. Dilution may occur through the transfer of other carbon-containing organic compounds in the sample or by dilution with natural carbon or carbon dioxide during the transfer process. This article discusses the possibility of carbon-13 isotope propagation directly in these compounds, both completely modified and modified with individual carbon centers. The literature provides information on determining carbon-13 substance in organic compounds, both with a general approach and for individual compounds [2] [3]. 展开更多
关键词 Tartaric Acid Oxalic Acid GLUCOSE FRUCTOSE Mass Spectrum ion Current Intensity Mass Line Mass Number Molecular and Fragment ions CARBON Carbon Center
下载PDF
Rare-earth and trace elements and hydrogen and oxygen isotopic compositions of Cretaceous kaolinitic sediments from the Lower Benue Trough, Nigeria: provenance and paleoclimatic significance 被引量:2
16
作者 Anthony T.Bolarinwa Sunday O.Idakwo David L.Bish 《Acta Geochimica》 EI CAS CSCD 2019年第3期350-363,共14页
This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma... This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma–mass spectrometry and isotope ratio mass spectrometry was used to investigate trace and rareearth element geochemistry and hydrogen and oxygen isotopic compositions. These data were then used to infer the sediments' provenance and paleoclimatic conditions during their deposition. The sediments contained low concentrations of most trace elements, with the exceptions of Zr(651–1352 ppm), Ba(56–157 ppm), V(38–90 ppm),and Sr(15.1–59.6 ppm). Average values of Co and Ni were1.5 and 0.7 ppm, respectively. Trace and rare earth element values were lower than corresponding values for upper continental crust and Post-Archean Australian Shale, with the exception of Zr. The samples showed only slight light rare-earth enrichment and nearly flat heavy rare-earth depletion patterns, with negative Eu and Tm anomalies,typical of felsic sources. Geochemical parameters such as La/Sc, Th/Sc, and Th/Co ratios support that the kaolinitic sediments were derived from a felsic rock source, likely deposited in an oxic environment.^(18 )O values ranged from+ 15.4 to + 21.2% for the investigated samples, consistent with a residual material derived from chemicalweathering of felsic rock and redeposited in a sedimentary basin(typical values of + 19 to + 21.2%). While in the basin, the sediments experienced extended interactions with meteoric water enriched in d D and d16 O. However,the variation in d D and d16 O values for the investigated samples is attributed to the high temperature of formation(54–91 °C). The d D and d^(18 )O values suggest that the sediments, although obtained from different localities within the Lower Benue Trough, formed under similar hot,tropical climatic conditions. 展开更多
关键词 rare-earth and trace elements Oxygen/ hydrogen isotopic composition Kaolinitic SEDIMENTS LOWER Benue TROUGH NIGERIA
下载PDF
Insights on advanced g‐C_(3)N_(4)in energy storage:Applications,challenges,and future
17
作者 Xiaojie Yang Jian Peng +7 位作者 Lingfei Zhao Hang Zhang Jiayang Li Peng Yu Yameng Fan Jiazhao Wang Huakun Liu Shixue Dou 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期22-78,共57页
Graphitic carbon nitride(g‐C_(3)N_(4))is a highly recognized two‐dimensional semiconductor material known for its exceptional chemical and physical stability,environmental friendliness,and pollution‐free advantages... Graphitic carbon nitride(g‐C_(3)N_(4))is a highly recognized two‐dimensional semiconductor material known for its exceptional chemical and physical stability,environmental friendliness,and pollution‐free advantages.These remarkable properties have sparked extensive research in the field of energy storage.This review paper presents the latest advances in the utilization of g‐C_(3)N_(4)in various energy storage technologies,including lithium‐ion batteries,lithium‐sulfur batteries,sodium‐ion batteries,potassium‐ion batteries,and supercapacitors.One of the key strengths of g‐C_(3)N_(4)lies in its simple preparation process along with the ease of optimizing its material structure.It possesses abundant amino and Lewis basic groups,as well as a high density of nitrogen,enabling efficient charge transfer and electrolyte solution penetration.Moreover,the graphite‐like layered structure and the presence of largeπbonds in g‐C_(3)N_(4)contribute to its versatility in preparing multifunctional materials with different dimensions,element and group doping,and conjugated systems.These characteristics open up possibilities for expanding its application in energy storage devices.This article comprehensively reviews the research progress on g‐C_(3)N_(4)in energy storage and highlights its potential for future applications in this field.By exploring the advantages and unique features of g‐C_(3)N_(4),this paper provides valuable insights into harnessing the full potential of this material for energy storage applications. 展开更多
关键词 g‐C_(3)N_(4) lithium‐ion batteries lithium‐sulfur batteries potassium‐ion batteries sodium‐ion batteries SUPERCAPACITORS
下载PDF
Theoretical study of differential cross sections for the ionization of helium by fast proton impact
18
作者 M Mondal B Mandal +2 位作者 T Mistry D Jana M Purkait 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第11期255-264,共10页
We present the angular distribution of the ejected electron for single ionization of He by fast proton impact.A fourbody formalism of the three-Coulomb wave is applied to calculate the triple differential cross sectio... We present the angular distribution of the ejected electron for single ionization of He by fast proton impact.A fourbody formalism of the three-Coulomb wave is applied to calculate the triple differential cross sections at several impact energies in the scattering,perpendicular and azimuthal planes.Moreover,the three-body formalism of three-Coulomb,two-Coulomb and first Born approximation models has also been used to study the many-body effect on electron emission and the validity of the models.In the three-Coulomb wave model,the final state wave function incorporates distortion due to the three-body mutual Coulombic interaction.In this formalism,we use an uncorrelated and correlated Born initial state,which consists of a plane wave for the incoming projectile times a two-electron bound state wavefunction of the helium atom representing the 1s2(1S)state.But,in the case of the three-body formalism,the initial state wavefunction consists of a long-range Coulomb distortion for the incoming projectile and one active electron of the He atom described by the Roothaan–Hartree–Fock wavefunction.The structure with a single or two peaks with unequal intensity is observed in the angular distributions of the triple differential cross sections for the different kinematic conditions.In addition,the influence of static electron correlations is investigated using different bound state wavefunctions for the ground state of the He target.In the four-body formalism,the present computations are very fast by reducing a nine-dimensional integral to a two-dimensional real integral.Despite the simplicity and speed of the proposed quadrature,the comparison shows that the obtained results are in reasonable agreement with the experiment and are compatible with those of other theories. 展开更多
关键词 ionIZATion cross sections COLLISion ATOMS ions
下载PDF
In situ luminescence measurements of GaN/Al_(2)O_(3) film under different energy proton irradiations
19
作者 蒋文丽 欧阳潇 +6 位作者 仇猛淋 英敏菊 陈琳 庞盼 张春雷 张耀锋 廖斌 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期704-710,共7页
Ion beam-induced luminescence(IBIL) experiments were performed to investigate the in situ luminescence of GaN/Al_(2)O_(3) at varying ion energies,which allowed for the measurement of defects at different depths within... Ion beam-induced luminescence(IBIL) experiments were performed to investigate the in situ luminescence of GaN/Al_(2)O_(3) at varying ion energies,which allowed for the measurement of defects at different depths within the material.The energies of H^(+)were set to 500 keV,640 keV and 2 MeV,the Bragg peaks of which correspond to the GaN film,GaN/Al_(2)O_(3) heterojunction and Al_(2)O_(3) substrate,respectively.A photoluminescence measurement at 250 K was also performed for comparison,during which only near band edge(NBE) and yellow band luminescence in the GaN film were observed.The evolution of the luminescence of the NBE and yellow band in the GaN film was discussed,and both exhibited a decrease with the fluence of H^(+).Additionally,the luminescence of F centers,induced by oxygen vacancies,and Cr^(3+),resulting from the ^(2)E →^(4)A_(2) radiative transition in Al_(2)O_(3),were measured using 2 MeV H^(+).The luminescence intensity of F centers increases gradually with the fluence of H^(+).The luminescence evolution of Cr^(3+)is consistent with a yellow band center,attributed to its weak intensity,and it is situated within the emission band of the yellow band in the GaN film.Our results show that IBIL measurement can effectively detect the luminescence behavior of multilayer films by adjusting the ion energy.Luminescence measurement can be excited by various techniques,but IBIL can satisfy in situ luminescence measurement,and multilayer structural materials of tens of micrometers can be measured through IBIL by adjusting the energy of the inducing ions.The evolution of defects at different layers with ion fluence can be obtained. 展开更多
关键词 ion beam-induced luminescence(IBIL) GaN/Al_(2)O_(3) ion beam
下载PDF
New approach to measuring topological phase transitions utilizing Floquet technology
20
作者 Xue-Ying Yang Wei Wu Ping-Xing Chen 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期282-288,共7页
The Floquet technique provides a novel anomalous topological phase for non-equilibrium phase transitions.Based on the high symmetry of the quantum anomalous Hall model,the findings suggest a one-to-one correspondence ... The Floquet technique provides a novel anomalous topological phase for non-equilibrium phase transitions.Based on the high symmetry of the quantum anomalous Hall model,the findings suggest a one-to-one correspondence between the average spin texture and the Floquet quasi-energy spectrum.A new approach is proposed to directly measure the quasienergy spectrum,replacing previous measurements of the average spin texture.Finally,we proposed a reliable experimental scheme based on ion trap platforms.This scheme markedly reduces the measurement workload,improves the measurement fidelity,and is applicable to multiple platforms such as cold atoms and nuclear magnetic resonance. 展开更多
关键词 topological phase transition Floquet technique ion trap
下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部