The WRF-lake vertically one-dimensional(1D)water temperature model,as a submodule of the Weather Research and Forecasting(WRF)system,is being widely used to investigate water-atmosphere interactions.But previous appli...The WRF-lake vertically one-dimensional(1D)water temperature model,as a submodule of the Weather Research and Forecasting(WRF)system,is being widely used to investigate water-atmosphere interactions.But previous applications revealed that it cannot accurately simulate the water temperature in a deep riverine reservoir during a large flow rate period,and whether it can produce sufficiently accurate heat flux through the water surface of deep riverine reservoirs remains uncertain.In this study,the WRF-lake model was improved for applications in large,deep riverine reservoirs by parametric scheme optimization,and the accuracy of heat flux calculation was evaluated compared with the results of a better physically based model,the Delft3D-Flow,which was previously applied to different kinds of reservoirs successfully.The results show:(1)The latest version of WRF-lake can describe the surface water temperature to some extent but performs poorly in the large flow period.We revised WRF-lake by modifying the vertical thermal diffusivity,and then,the water temperature simulation in the large flow period was improved significantly.(2)The latest version of WRF-lake overestimates the reservoir-atmosphere heat exchange throughout the year,mainly because of underestimating the downward energy transfer in the reservoir,resulting in more heat remaining at the surface and returning to the atmosphere.The modification of vertical thermal diffusivity can improve the surface heat flux calculation significantly.(3)The longitudinal temperature variation and the temperature difference between inflow and outflow,which cannot be considered in the 1D WRF-lake,can also affect the water surface heat flux.展开更多
[Objective] The aim was to improve and restore destroyed riverine and water ecosystem and to prevent bio-diversity from deteriorating in Jari demonstration plot in Ethiopia. [Method] Biological engineering and natural...[Objective] The aim was to improve and restore destroyed riverine and water ecosystem and to prevent bio-diversity from deteriorating in Jari demonstration plot in Ethiopia. [Method] Biological engineering and naturalization were made use of to protect nature and restore wetland as per Succession Theory. [Result] Both of eco- environment and eco-functions of Mille River were restored through reconstruction of biocenosis in wetlands. [Conclusion] It is feasible to implement matched ecological projects in semiarid regions in East Africa, providing references for restoration and protection of local water resources.展开更多
Frequent soil landslide events are recorded in the Three Gorges Reservoir area,China,making it necessary to investigate the failure mode of such riverside landslides.Geotechnical centrifugal test is considered to be t...Frequent soil landslide events are recorded in the Three Gorges Reservoir area,China,making it necessary to investigate the failure mode of such riverside landslides.Geotechnical centrifugal test is considered to be the most realistic laboratory model,which can reconstruct the required geo-stress.In this study,the Liangshuijing landslide in the Three Gorgers Reservoir area is selected for a scaled centrifugal model experiment,and a water pump system is employed to retain the rainfall condition.Using the techniques of digital photography and pore water pressure transducers,water level fluctuation is controlled,and multi-physical data are thus obtained,including the pore water pressure,earth pressure,surface displacement and deep displacement.The analysis results indicate that:Three stages were set in the test(waterflooding stage,rainfall stage and drainage stage).Seven transverse cracks with wide of 1–5 mm appeared during the model test,of which 3 cracks at the toe landslide were caused by reservoir water fluctuation,and the cracks at the middle and rear part were caused by rainfall.During rainfall process,the maximum displacement of landslide model reaches 3 cm.And the maximum deformation of the model exceeds 12 cm at the drainage stage.The failure process of the slope model can be divided into four stages:microcracks appearance and propagation stage,thrust-type failure stage,retrogressive failure stage,and holistic failure stage.When the thrust-type zone caused by rainfall was connected or even overlapped with the retrogressive failure zone caused by the drainage,the landslide would start,which displayed a typical composite failure pattern.The failure mode and deformation mechanism under the coupling actions of water level fluctuation and rainfall are revealed in the model test,which could appropriately guide for the analysis and evaluation of riverside landslides.展开更多
Sea surface temperature (SST) proxies including B/Ca, Mg/Ca, St/Ca, U/Ca and δ180 were analyzed in the skeleton of a Porites coral collected from the Zhujiang River (Pearl River) Estuary (ZRE). These geochemica...Sea surface temperature (SST) proxies including B/Ca, Mg/Ca, St/Ca, U/Ca and δ180 were analyzed in the skeleton of a Porites coral collected from the Zhujiang River (Pearl River) Estuary (ZRE). These geochemical proxies are influenced by river runoff and this area of the northern South China Sea is strongly affected by seasonal freshwater floods. We assessed the robustness of each SST proxy through comparison with the local instrumental SST. Coral St/Ca shows the highest correlation with SST variations (r2=0.59), suggesting St/Ca is the most robust SST proxy. In contrast, coral δ180 (r2=0.46), B/Ca (r2=0.43) and U/Ca (r2=0.41) ratios were only moderately correlated with SST variations, suggesting that they are disturbed by some other factors in addition to SST. The poor correlation (r2=0.27) between SST and Mg/Ca indicates that Mg/Ca in coral skeletons is not a simple function of SST variations. This may ultimately limit the use of Mg/Ca as a coral paleothermometer.展开更多
Riverine sand dunes develop as a result of fluvial-aeolian interactions. The primarily barchan dune chains along the Xiangshui River(a branch of the Xar Moron River in the western part of the Horqin Sandy Land of Chin...Riverine sand dunes develop as a result of fluvial-aeolian interactions. The primarily barchan dune chains along the Xiangshui River(a branch of the Xar Moron River in the western part of the Horqin Sandy Land of China) form a typical riverine dune field. We collected a series of samples from the riverine sand dunes parallel to the direction of the prevailing wind and investigated the sand sources and formation mechanisms of these dunes by determining the grain size, heavy mineral content and optically stimulated luminescence(OSL) of the samples. The sand of the near-river dunes was coarser than the sand of the dunes distant from the river, indicating that coarse sand of the valley mainly deposited on near-river dunes. The heavy mineral analysis suggested that wind-sand activity levels were intense on the upwind dunes, but relatively weak on the downwind dunes. This indicated that the sand sources for the near-river dunes were more abundant than those of the distant dunes. Our OSL analysis of samples suggested that the deposition rates on dunes near the river were greater than the deposition rates on dunes distant from the river. The development of dunes along the river indicated that the river played an important role in dune formation and development. In addition, airflow fluctuation and the formation of the waveform dunes had a type of feedback relationship. Grain size, heavy mineral and OSL analyses are widely used methods in wind-sand research. Sand dune grain size characteristics reflect the effects of airflow on the transport and separation of sand materials, as well as the physical characteristics of the sand sources. Heavy mineral characteristics are often used to investigate the relationships between sediments and sand sources. OSL indicates dune age, revealing formation of dunes. Therefore, it is useful to explore dune sand sources, as well as the mechanisms underlying dune formation, by determining grain size, heavy mineral content and OSL. This study investigated the sand sources of riverine dunes and provided new information about riverine dune formation and development.展开更多
The tectonic uplifting and depression in the coastal zones results in the anormal distribution of riverine sediments. The coastal zones of tectonic depression areas received about 95% of the riveine sediments, whereas...The tectonic uplifting and depression in the coastal zones results in the anormal distribution of riverine sediments. The coastal zones of tectonic depression areas received about 95% of the riveine sediments, whereas the tectonic uplift belts received only 5% of that, which is the main reason for the variety of the coastline types and the changes in the coastline. On the basis of this anormal distribution of riverine sediments in Chinese coastline, this paper discusses the scope and time of the maximum transgression, the trend, rate and period of the coastline changes, and the impact of riverine sediments on the future changes in coastline.展开更多
Antibiotics released into the environment through anthropogenic activities exert selective pressure,driving bacteria towards increasing antimicrobial resistance.The prevalence of antibiotics and the ecological risks p...Antibiotics released into the environment through anthropogenic activities exert selective pressure,driving bacteria towards increasing antimicrobial resistance.The prevalence of antibiotics and the ecological risks posed in the riverine estuarine of Larut River and Sangga Besar River,which included wastewater effl uents from hospital,zoo,and poultry slaughterhouse sources were investigated.Solid phase extraction(SPE)followed by high-performance liquid chromatography tandem mass chromatography(HPLC-MS/MS)were used to extract and quantify the antibiotic residues from 22 antibiotics belonging to six major antibiotic classes(sulfonamide,macrolide,fl uoroquinolone,phenicol,trimethoprim,and tetracycline).Sixteen antibiotic residues were detected with concentrations ranging from limit of detection(LOD)to 1262.3 ng/L.Fluoroquinolones and macrolides were the most frequently detected compounds.Erythromycin,clarithromycin,and ofl oxacin detected in hospital and zoo effl uents posed a high risk to algae while tetracycline had low to medium ecological risks toward all the relevant organisms from aquatic environments(algae,invertebrate Daphnia magna,and fi sh).展开更多
The Zhujiang River Estuary is becoming eutrophic due to the impact of anthropogenic activities in the past decades.To understand nutrient dynamics and fluxes to the Lingdingyang water via four outlets(Humen,Jiaomen,Ho...The Zhujiang River Estuary is becoming eutrophic due to the impact of anthropogenic activities in the past decades.To understand nutrient dynamics and fluxes to the Lingdingyang water via four outlets(Humen,Jiaomen,Hongqimen and Hengmen),we investigated the spatial distribution and seasonal variation of dissolved nutrients in the Zhujiang River Estuary,based on fourteen cruises conducted from March 2015 to October 2017,covering both wet(April to September)and dry(October to March next year)seasons.Our results showed that riverine fluxes of dissolved inorganic nitrogen(DIN)and dissolved silicate(DSi)into the Lingdingyang water through four outlets varied seasonally due to the influence of river discharge,with the highest in spring and the lowest in winter.However,riverine flux of phosphate exhibited little significant seasonal variability.Riverine nutrients into the Lingdingyang water most resulted through Humen Outlet.The estuarine export fluxes of DIN out of the Zhujiang River Estuary derived from a box model were higher than fluxes of riverine nutrients in May,likely due to the influence of local sewage,while lower than riverine flux in August.The export fluxes of phosphate were higher than the fluxes of riverine phosphate in May and August.In contrast,large amounts of DSi were buried in the estuary in May and August.Although excess DIN was delivered into the Zhujiang River Estuary,eutrophication effect was not as severe as expected in the Zhujiang River Estuary,since the light limitation restricted the utilization of nutrients by phytoplankton.展开更多
Inorganic carbon, the great part of the riverine carbon exported to the ocean, plays an important role in the global carbon cycle and ultimately impacts the coupled carbon-climate system. An overview was made on both ...Inorganic carbon, the great part of the riverine carbon exported to the ocean, plays an important role in the global carbon cycle and ultimately impacts the coupled carbon-climate system. An overview was made on both methods and results of the riverine inorganic carbon researches. In addition to routine in situ survey, measurement and calculation, the direct precipitation method and the gas evolution technique were commonly used to analyze dissolved inorganic carbon in natural water samples. Soil CO2, carbonate minerals and atmospheric CO2 incorporated into riverine inorganic car- bon pool via different means, with bicarbonate ion being the dominant component. The concentration of inorganic carbon, the composition of carbon isotopes (8^13C and △^14C), and their temporal or spatial variations in the streams were controlled by carbon input, output and changes of carbon biogeochemistry within the riverine system. More accurate flux es- timation, better understanding of different influential processes, and quantitative determination of various inputs or outputs need to be well researched in future.展开更多
Lake Fibreno is a Mediterranean riverine lake located in Central Italy and fed by large flows of groundwater and characterized by the presence of a wide reed stand area and of the only floating island of the South Eur...Lake Fibreno is a Mediterranean riverine lake located in Central Italy and fed by large flows of groundwater and characterized by the presence of a wide reed stand area and of the only floating island of the South Europe. It is enclosed in a Natural Reserve recognized as Special Area of Conservation (SAC-IT6050015) for the presence of habitats and species (92/43/EEC) of relevant scientific interest. In this paper, we compare the plant-associated meio-macrobenthic invertebrates among sites with different environmental characteristics. Both vegetation and invertebrates of Lake Fibreno were well diversified and abundant and were composed of a mixing of species typical of lentic and lotic waters. Our results show that a gradient of orthophosphate and nitrite contents and current velocity appeared to be the driver factors affecting the flora and fauna spatial distribution at the sampling sites. To obtain a bioassessment of the ecological quality of the vegetation zone, we compared the riverine Lake Fibreno with typical lentic lakes previously studied in Central Italy. We selected metrics, such as macrophyte belt extent and taxa richness, invertebrate species richness and Shannon diversity, ETOM (Ephemeropta + Trichoptera + Odonata + Mollusca), ETOC (Ephemeropta + Trichoptera + Odonata + Coleoptera) and LCrM (Large Crustacea + Mollusca). The comparison indicated a good ecological status of the vegetation zone of Lake Fibreno mainly due to the continuous washout effects (dilution and fast water removal) which reduce the nutrient content available for phytoplankton and maintain the high transparency and good oxygenation of the lake waters.展开更多
Wuzhen is a typical riverine town south of the Yangtze River.Due to the World Internet Conference being held there,it seems to have become a place where CEOs a nd bosses of inter net compa n ies working on plans for t...Wuzhen is a typical riverine town south of the Yangtze River.Due to the World Internet Conference being held there,it seems to have become a place where CEOs a nd bosses of inter net compa n ies working on plans for the industry’s development gather.展开更多
Hydropeaking,which refers to rising or falling discharges caused by the turning on or off of hydro-turbines to generate electricity,is a topic of growing interest due to its impact on fluvial ecosystems.To date,most h...Hydropeaking,which refers to rising or falling discharges caused by the turning on or off of hydro-turbines to generate electricity,is a topic of growing interest due to its impact on fluvial ecosystems.To date,most hydropeaking studies have focused on the impact of peak fluctuations on invertebrate and fish communities,but little attention has been paid to its impact on riverine plants and how functional traits may make them resistant to hydropeaking.We performed a review to assess how a set of 32 plant functional traits can be expressed in riverine plant species,and found evidence of how such expression affects their capacity to cope with common sources of hydropeaking disturbance(i.e.,inundation,fast water drawdown,and rapid water fluctuations linked to up-ramping and down-ramping hydropeaking operations).The information here presented can simplify the evaluation of impacts on riverine plant communities worldwide,as well as to detect suitable species to successfully restore rivers affected by hydropower production.展开更多
Anthropogenic activities are regarded as the main sources of heavy metal pollution,yet few studies have investigated the effects of land-use setting on heavy metal accumulation in riverine sediments.Based on both tota...Anthropogenic activities are regarded as the main sources of heavy metal pollution,yet few studies have investigated the effects of land-use setting on heavy metal accumulation in riverine sediments.Based on both total contents and geochemical fractions,heavy metal pollution,risk and toxicity were determined in riverine sediment cores from different land-use areas(mountain area-MA,farm area-FA,city area-CA,and industrial area-LA)of the Yang River Basin in North China.The results showed that FA had higher contents of riverine sedimentary Cu;CA had higher contents of Cd;LA.had higher contents of both Cd and Zn.Most riverine sediments from FA and IA were contaminated with the investigated metals,although these concentrations were evaluated to have low potential ecological risk and no toxicity to benthic organisms.However,a high proportion of Cd in the B1 fraction of riverine sediments in IA indicating high risk should receive more attention.The B1 fraction largely determined the contamination,risk and toxicity levels associated with heavy metals in the riverine sediments of the Yang River Basin.展开更多
Although riverine carbon fluxes are a minor component of the global carbon cycle, the transfer of organic carbon from land to ocean represents a flux of potential carbon storage, irreversible over 103 to 104 a. Future...Although riverine carbon fluxes are a minor component of the global carbon cycle, the transfer of organic carbon from land to ocean represents a flux of potential carbon storage, irreversible over 103 to 104 a. Future carbon transfers through river basins are expected to accelerate, with respect to both sources and sinks, because of the large-scale human driven land-use and land-cover changes. Thus, the increased amounts of carbon transported to and sequestered in marine sediments (through fertilization by river-borne inorganic nutrients) may be an important net sink for anthropogenic CO2. Particularly, the humid tropics of South Asia are regions very sensitive to this lateral C transport because of high precipitation and high rates of land use and cover change. In this paper we report on the role of upland tributaries in the transport processes influencing the lateral carbon and nitrogen fluxes of the Godavari, a large tropical river of India. By far, dissolved inorganic carbon (DIC) is the dominant form of carbontransport in the river basin. It constitutes as much as 75% to the total carbonload. Particulate and dissolved organic carbon (POC and DOC) fluxes account for21% and 4%, respectively. In the upper basin, DOC fluxes exceed that of POC dueto large-scale anthropogenic activities. In contrast, tributaries in the central basin are characterized by comparable fluxes of POC and DOC. However, downriver POC export is 35% less than the import from upriver and tributaries due to theentrainment of sediments in river channels and dam sites. We argue that for highly disturbed watersheds in tropical regions, downstream transport of sediments and carbon requires long-term sampling programmes.展开更多
As flood extreme occurrences are projected to increase in intense and frequency due to climate change, the assessment of vulnerability and the identification of the most vulnerable areas, populations, assets and syste...As flood extreme occurrences are projected to increase in intense and frequency due to climate change, the assessment of vulnerability and the identification of the most vulnerable areas, populations, assets and systems are an urgent need. Vulnerability has been widely discussed and several flood projection tools have been developed using complex hydrological models. However, despite the significant contribution of flood projection maps to predicting the impact of potential floods, they are difficult and impractical to use by stakeholders and policy makers, while they have proven to be inefficient and out of date in several cases. This research aims to cover the gaps in coastal and riverine flood management, developing a method that models flood patterns, using geospatial data of past large flood disasters. The outcomes of this research produce a five scale vulnerability assessment method, which could be widely implemented in all sectors, including transport, critical infrastructure, public health, tourism, constructions etc. Moreover, they could facilitate decision making and provide a wide range of implementation by all stakeholders, insurance agents, land-use planners, risk experts and of course individual. According to this research, the majority of the elements exposed to flood hazards, lay at specific combinations between 1) elevation (Ei) and 2) distance from water-masses (Di), expressed as (Ei, Di), including: 1) in general landscapes: ([0 m, 1 m), [0 km, 6 km), [0 m - 3 m), [0 km, 3 km)) and ([0 m - 6 m), [0 km, 1 km)), 2) in low laying regions: ([0 m, 1 m), [0 km, 40 km), [0 m - 3 m), [0 km, 30 km)) and ([0 m - 6 m), [0 km, 15 km)) and 2) in riverine regions: ([0 m, 4 m), [0 km, 3 km)). All elements laying on these elevations and distances from water masses are considered extremely and highly vulnerable to flood extremes.展开更多
A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than ...A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological seasons. The DOC level during the flood season (1.18 mg L-1) was less than that during the non-flood season (1.40 mg L-1). Owing to the concomitance of the flushing and dilution effects of the runoff during the high-water period, the variation of riverine DOC concentration with discharge in the XJR differed from that reported in many other major rivers. The DOC export flux above the city of Wuzhou was about 0.62× 106 g C km-2 yr-1. The DOC transported during the "056" Massive Flood period comprised 30.35% of the annual total, while the discharge accounted for 36.32% of the total annual flow. The characteristics in riverine DOC concentration in the XJR were attributed to the combined effect of the geomorphologic, monsoon climatic and hydrological processes as well as land-use within the drainage basin.展开更多
While it is critical to accurately understand the sources and transformation of sulfate based on time-series analysis, there are limited studies on temporal variation of sulfate in rivers and on rock weathering by sul...While it is critical to accurately understand the sources and transformation of sulfate based on time-series analysis, there are limited studies on temporal variation of sulfate in rivers and on rock weathering by sulfuric acids.We conducted a monthly sampling campaign in the Beipan, Nanpan, and Hongshui Rivers over the course of one hydrological year. This study examined seasonal variations in riverine sulfate impacted by the monsoon climate in the upper reaches of the Xijiang River basin. In general, the SO_4^(2-) contents in these rivers dropped from relatively high levels to low values during the high-flow season, in response to increasing discharge. The sulfate was generally enriched in heavy isotopes during the low-flow season compared to the high-flow season. The calculated results indicate that the riverine sulfate was mainly derived from sulfide oxidation, but that evaporite dissolution could be an important source during the low-flow season, based on isotopic evidence. Mine drainage is likely an important source of sulfate to these rivers during the high-flow season due to contributions from fast surface flow, which responds to frequent heavy rain in monsoonal climate regions. Arelatively high proportion of HCO_3^- was found to be derived from rock weathering by sulfuric acid during the high-flow season when compared to that observed during the low-flow season. The results suggest that approximately one quarter of the HCO_3^- in the Hongshui River originated from carbonate weathering by sulfuric acid derived from the oxidation of sulfide. Such information on the specific dual isotopic characteristics of riverine sulfate throughout a hydrological year can provide unique evidence for understanding the temporal variability of sulfate concentrations and weathering processes in rivers.展开更多
The pesticides belong to a category of chemicals used worldwide as herbicides, insecticides, fungicides, ro-denticides, molluscicides, nematicides, and plant growth regulators in order to control weeds, pests and dis-...The pesticides belong to a category of chemicals used worldwide as herbicides, insecticides, fungicides, ro-denticides, molluscicides, nematicides, and plant growth regulators in order to control weeds, pests and dis-eases in crops as well as for health care of humans and animals. The positive aspect of application of pesti-cides renders enhanced crop/food productivity and drastic reduction of vector-borne diseases. However, their unregulated and indiscriminate applications have raised serious concerns about the entire environment in general and the health of humans, birds and animals in particular. Despite ban on application of some of the environmentally persistent and least biodegradable pesticides (like organochlorines) in many countries, their use is ever on rise. Pesticides cause serious health hazards to living systems because of their rapid fat solu-bility and bioaccumulation in non-target organisms. Even at low concentration, pesticides may exert several adverse effects, which could be monitored at biochemical, molecular or behavioral levels. The factors af-fecting water pollution with pesticides and their residues include drainage, rainfall, microbial activity, soil temperature, treatment surface, application rate as well as the solubility, mobility and half life of pesticides. In India organochlorine insecticides such as DDT and HCH constitute more than 70% of the pesticides used at present. Reports from Delhi, Bhopal and other cities and some rural areas have indicated presence of sig-nificant level of pesticides in fresh water systems as well as bottled drinking mineral water samples. The ef-fects of pesticides pollution in riverine systems and drinking water in India has been discussed in this review.展开更多
To better understand the Fe isotope characteristics of natural samples in the Karst area,the Fe isotope compositions of riverine suspended particulates,lake suspended particulates,lake sediments,porewaters,phytoplankt...To better understand the Fe isotope characteristics of natural samples in the Karst area,the Fe isotope compositions of riverine suspended particulates,lake suspended particulates,lake sediments,porewaters,phytoplanktons,and aerosols in the watersheds of Lake Aha(a mineralized water system)and Lake Hongfeng(a mesotrophic water system),which are located in the Karst area, southwest China,were investigated.The studied samples displayed a variable range betweenδ^(56)Fe=-2.03‰and 0.36‰.Aerosols and phytoplanktons have similar or slightly heavier Fe isotope compositions relative to the average of igneous rocks.Fe isotope compositions of riverine Suspended Particulate Matter(SPM)were mainly affected by the types of tributaries.Suspended particulates collected from tributaries seriously contaminated with coal mine drainages displayed negativeδ^(56)Fe values(-0.89‰to-0.31‰)during summer,and there were significant increases ofδ^(56)Fe values in winter,except AR2,which was polluted with both coal mine drainage and sewage effluent. Characteristics of lakes have important influences on Fe isotope compositions of suspended particulates,lake sediments,and porewaters.The epilimnetic particulate Fe of Lake Hongfeng hadδ^(56)Fe=-0.04‰to 0.13‰,while lighter Fe isotope compositions were measured for particulate Fe from Lake Aha,ranging from-0.42‰to-0.09‰.Sediments collected from Hou Wu(HW)station of Lake Hongfeng have an averageδ^(56)Fe value of 0.09‰and their corresponding porewaters have lighter Fe isotope compositions,ranging from-0.57‰to-0.31‰;no significant variations have been observed. For the Liang Jiang Kou(LJK)station of Lake Aha,the content of reactive Fe and the concentration of sulfate were all high.Due to the reactive Fe recycling,including dissimilatory Fe reduction,adsorption, and Fe-sulfide formation,porewaters sampled near the sediment surface have been found to have aδ^(56)Fe value as low as-2.03‰and an increase up to 0.12‰,with a burial depth of 10 cm.In contrast,an opposite variation trend was found for LJK sediments.Sediments sampled at 1-cm depth had a value ofδ^(56)Fe=-0.59‰and decrease as low as-1.75‰with burial depth.This investigation demonstrated that significant Fe isotope fractionations occur in surface environments.Fe isotope compositions of particulate Fe were seriously affected by Fe sources,and Fe biogeochemical recycling has an important influence on Fe isotope fractionations in lake sediments,especially when there are significant amounts of reactive Fe and sulfate.展开更多
We established a budget model of nitrogen (N) inputs and outputs between watersheds and waterbodies to determine the sources of riverine N in the Changjiang (Yangtze) River drainage area. Nitrogen inputs in the bu...We established a budget model of nitrogen (N) inputs and outputs between watersheds and waterbodies to determine the sources of riverine N in the Changjiang (Yangtze) River drainage area. Nitrogen inputs in the budget included N from synthetic fertilizer, biological fixation by leguminous and other crops, wet/dry atmospheric deposition, excreta from humans and animals, and crop residues. The total N input was estimated to be 17.6 Tg, of which 20% or 3.5 Tg N was transported into waterbodies. Of the total N transported into waterbodies, the largest proportion was N from animal waste (26%), followed by N from atmospheric wet/dry deposition (25%), synthetic fertilizer N (17%), N in sewage wastes (17%), N in human waste from rural areas (6%) and industrial wastewater N (9%). We studied the spatial patterns of N inputs and outputs by dividing the Changjiang River drainage area into four sub-basins, from upstream to downstream: the Tongtian River drainage area (TTD, the headwater drainage area, 138 000 l^n2, less disturbed by human activities); the Jinsha River drainage area (JSD, 347 000 km2, less disturbed by human activities, approx. 3 500 km upstream of the Changjiang estuary); the Pingshan-Yichang drainage area (PYD, 520 500 krn2, large-scale human disturbance, about 2 000 km upstream of the Changjiang estuary); and the Yichang-Datong drainage area (YDD, 699 900 km^2, large-scale httman disturbance, approx. 620 km upstream of the Changjiang estuary). The average N input into waterbodies was 2.3, 7.3, 24.1, and 28.2 kg N/ha in the TTD, JSD, PYD, and YDD sub-basins, respectively, suggesting an increase of N-components of more than 10 times from upstream to downstream areas.展开更多
基金the financial support from the National Key R&D Program of China(Grant No.2018YFE0196000)the National Natural Science Foundation of China(Grant No.52179069)。
文摘The WRF-lake vertically one-dimensional(1D)water temperature model,as a submodule of the Weather Research and Forecasting(WRF)system,is being widely used to investigate water-atmosphere interactions.But previous applications revealed that it cannot accurately simulate the water temperature in a deep riverine reservoir during a large flow rate period,and whether it can produce sufficiently accurate heat flux through the water surface of deep riverine reservoirs remains uncertain.In this study,the WRF-lake model was improved for applications in large,deep riverine reservoirs by parametric scheme optimization,and the accuracy of heat flux calculation was evaluated compared with the results of a better physically based model,the Delft3D-Flow,which was previously applied to different kinds of reservoirs successfully.The results show:(1)The latest version of WRF-lake can describe the surface water temperature to some extent but performs poorly in the large flow period.We revised WRF-lake by modifying the vertical thermal diffusivity,and then,the water temperature simulation in the large flow period was improved significantly.(2)The latest version of WRF-lake overestimates the reservoir-atmosphere heat exchange throughout the year,mainly because of underestimating the downward energy transfer in the reservoir,resulting in more heat remaining at the surface and returning to the atmosphere.The modification of vertical thermal diffusivity can improve the surface heat flux calculation significantly.(3)The longitudinal temperature variation and the temperature difference between inflow and outflow,which cannot be considered in the 1D WRF-lake,can also affect the water surface heat flux.
基金Supported by South-South Cooperation Project of SSC/SPFS-FAO-Ethiopia-China~~
文摘[Objective] The aim was to improve and restore destroyed riverine and water ecosystem and to prevent bio-diversity from deteriorating in Jari demonstration plot in Ethiopia. [Method] Biological engineering and naturalization were made use of to protect nature and restore wetland as per Succession Theory. [Result] Both of eco- environment and eco-functions of Mille River were restored through reconstruction of biocenosis in wetlands. [Conclusion] It is feasible to implement matched ecological projects in semiarid regions in East Africa, providing references for restoration and protection of local water resources.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41977244, 42007267)the National Key R&D Program of China (Grant No. 2017YFC1501301)
文摘Frequent soil landslide events are recorded in the Three Gorges Reservoir area,China,making it necessary to investigate the failure mode of such riverside landslides.Geotechnical centrifugal test is considered to be the most realistic laboratory model,which can reconstruct the required geo-stress.In this study,the Liangshuijing landslide in the Three Gorgers Reservoir area is selected for a scaled centrifugal model experiment,and a water pump system is employed to retain the rainfall condition.Using the techniques of digital photography and pore water pressure transducers,water level fluctuation is controlled,and multi-physical data are thus obtained,including the pore water pressure,earth pressure,surface displacement and deep displacement.The analysis results indicate that:Three stages were set in the test(waterflooding stage,rainfall stage and drainage stage).Seven transverse cracks with wide of 1–5 mm appeared during the model test,of which 3 cracks at the toe landslide were caused by reservoir water fluctuation,and the cracks at the middle and rear part were caused by rainfall.During rainfall process,the maximum displacement of landslide model reaches 3 cm.And the maximum deformation of the model exceeds 12 cm at the drainage stage.The failure process of the slope model can be divided into four stages:microcracks appearance and propagation stage,thrust-type failure stage,retrogressive failure stage,and holistic failure stage.When the thrust-type zone caused by rainfall was connected or even overlapped with the retrogressive failure zone caused by the drainage,the landslide would start,which displayed a typical composite failure pattern.The failure mode and deformation mechanism under the coupling actions of water level fluctuation and rainfall are revealed in the model test,which could appropriately guide for the analysis and evaluation of riverside landslides.
基金The National Basic Research Program(973 program) of China under contract No.2013CB956104the National Natural Science Foundation of China under contract Nos 41106054,41306109 and 41476038
文摘Sea surface temperature (SST) proxies including B/Ca, Mg/Ca, St/Ca, U/Ca and δ180 were analyzed in the skeleton of a Porites coral collected from the Zhujiang River (Pearl River) Estuary (ZRE). These geochemical proxies are influenced by river runoff and this area of the northern South China Sea is strongly affected by seasonal freshwater floods. We assessed the robustness of each SST proxy through comparison with the local instrumental SST. Coral St/Ca shows the highest correlation with SST variations (r2=0.59), suggesting St/Ca is the most robust SST proxy. In contrast, coral δ180 (r2=0.46), B/Ca (r2=0.43) and U/Ca (r2=0.41) ratios were only moderately correlated with SST variations, suggesting that they are disturbed by some other factors in addition to SST. The poor correlation (r2=0.27) between SST and Mg/Ca indicates that Mg/Ca in coral skeletons is not a simple function of SST variations. This may ultimately limit the use of Mg/Ca as a coral paleothermometer.
基金funded by the National Natural Science Foundation of China (41271025)the National Basic Research Program of China (2016YFA0601901)
文摘Riverine sand dunes develop as a result of fluvial-aeolian interactions. The primarily barchan dune chains along the Xiangshui River(a branch of the Xar Moron River in the western part of the Horqin Sandy Land of China) form a typical riverine dune field. We collected a series of samples from the riverine sand dunes parallel to the direction of the prevailing wind and investigated the sand sources and formation mechanisms of these dunes by determining the grain size, heavy mineral content and optically stimulated luminescence(OSL) of the samples. The sand of the near-river dunes was coarser than the sand of the dunes distant from the river, indicating that coarse sand of the valley mainly deposited on near-river dunes. The heavy mineral analysis suggested that wind-sand activity levels were intense on the upwind dunes, but relatively weak on the downwind dunes. This indicated that the sand sources for the near-river dunes were more abundant than those of the distant dunes. Our OSL analysis of samples suggested that the deposition rates on dunes near the river were greater than the deposition rates on dunes distant from the river. The development of dunes along the river indicated that the river played an important role in dune formation and development. In addition, airflow fluctuation and the formation of the waveform dunes had a type of feedback relationship. Grain size, heavy mineral and OSL analyses are widely used methods in wind-sand research. Sand dune grain size characteristics reflect the effects of airflow on the transport and separation of sand materials, as well as the physical characteristics of the sand sources. Heavy mineral characteristics are often used to investigate the relationships between sediments and sand sources. OSL indicates dune age, revealing formation of dunes. Therefore, it is useful to explore dune sand sources, as well as the mechanisms underlying dune formation, by determining grain size, heavy mineral content and OSL. This study investigated the sand sources of riverine dunes and provided new information about riverine dune formation and development.
文摘The tectonic uplifting and depression in the coastal zones results in the anormal distribution of riverine sediments. The coastal zones of tectonic depression areas received about 95% of the riveine sediments, whereas the tectonic uplift belts received only 5% of that, which is the main reason for the variety of the coastline types and the changes in the coastline. On the basis of this anormal distribution of riverine sediments in Chinese coastline, this paper discusses the scope and time of the maximum transgression, the trend, rate and period of the coastline changes, and the impact of riverine sediments on the future changes in coastline.
基金Supported by the Ministry of Higher Education of Malaysia(Nos.IOES-2014D,FP048-2013A,SF022-2013)the University Malaya(Nos.RU009D-2015,PG309-2016A)。
文摘Antibiotics released into the environment through anthropogenic activities exert selective pressure,driving bacteria towards increasing antimicrobial resistance.The prevalence of antibiotics and the ecological risks posed in the riverine estuarine of Larut River and Sangga Besar River,which included wastewater effl uents from hospital,zoo,and poultry slaughterhouse sources were investigated.Solid phase extraction(SPE)followed by high-performance liquid chromatography tandem mass chromatography(HPLC-MS/MS)were used to extract and quantify the antibiotic residues from 22 antibiotics belonging to six major antibiotic classes(sulfonamide,macrolide,fl uoroquinolone,phenicol,trimethoprim,and tetracycline).Sixteen antibiotic residues were detected with concentrations ranging from limit of detection(LOD)to 1262.3 ng/L.Fluoroquinolones and macrolides were the most frequently detected compounds.Erythromycin,clarithromycin,and ofl oxacin detected in hospital and zoo effl uents posed a high risk to algae while tetracycline had low to medium ecological risks toward all the relevant organisms from aquatic environments(algae,invertebrate Daphnia magna,and fi sh).
基金The Special Project for Marine Economic Development(Six Major Marine Industries)of Guangdong Province under contract No.GDNRC[2020]064the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)under contract Nos GML2019ZD0303,GML2019ZD0305 and GML2019ZD0402+2 种基金the Innovation Academy of South China Sea Ecology and Environmental Engineering,Chinese Academy of Sciences under contract Nos ISEE2019ZR02 and ISEE2019ZR03the National Natural Science Foundation of China under contract Nos 41676075 and 41706085the Department of Science and Technology of Guangdong Province under contract No.2018B030320005。
文摘The Zhujiang River Estuary is becoming eutrophic due to the impact of anthropogenic activities in the past decades.To understand nutrient dynamics and fluxes to the Lingdingyang water via four outlets(Humen,Jiaomen,Hongqimen and Hengmen),we investigated the spatial distribution and seasonal variation of dissolved nutrients in the Zhujiang River Estuary,based on fourteen cruises conducted from March 2015 to October 2017,covering both wet(April to September)and dry(October to March next year)seasons.Our results showed that riverine fluxes of dissolved inorganic nitrogen(DIN)and dissolved silicate(DSi)into the Lingdingyang water through four outlets varied seasonally due to the influence of river discharge,with the highest in spring and the lowest in winter.However,riverine flux of phosphate exhibited little significant seasonal variability.Riverine nutrients into the Lingdingyang water most resulted through Humen Outlet.The estuarine export fluxes of DIN out of the Zhujiang River Estuary derived from a box model were higher than fluxes of riverine nutrients in May,likely due to the influence of local sewage,while lower than riverine flux in August.The export fluxes of phosphate were higher than the fluxes of riverine phosphate in May and August.In contrast,large amounts of DSi were buried in the estuary in May and August.Although excess DIN was delivered into the Zhujiang River Estuary,eutrophication effect was not as severe as expected in the Zhujiang River Estuary,since the light limitation restricted the utilization of nutrients by phytoplankton.
基金Under the auspices of the National Natural Science Foundation of China (No. 40471120), the Specialized ResearchFund for the Doctoral Program of Higher Education (No. 20040558025), the '985 Project' of GIS and Remote Sensing for Geo-sciences from the Ministry of Education of China (No. 105203200400006), and the Guangdong Provincial Natural Science Founda-tion (No. 031548)
文摘Inorganic carbon, the great part of the riverine carbon exported to the ocean, plays an important role in the global carbon cycle and ultimately impacts the coupled carbon-climate system. An overview was made on both methods and results of the riverine inorganic carbon researches. In addition to routine in situ survey, measurement and calculation, the direct precipitation method and the gas evolution technique were commonly used to analyze dissolved inorganic carbon in natural water samples. Soil CO2, carbonate minerals and atmospheric CO2 incorporated into riverine inorganic car- bon pool via different means, with bicarbonate ion being the dominant component. The concentration of inorganic carbon, the composition of carbon isotopes (8^13C and △^14C), and their temporal or spatial variations in the streams were controlled by carbon input, output and changes of carbon biogeochemistry within the riverine system. More accurate flux es- timation, better understanding of different influential processes, and quantitative determination of various inputs or outputs need to be well researched in future.
文摘Lake Fibreno is a Mediterranean riverine lake located in Central Italy and fed by large flows of groundwater and characterized by the presence of a wide reed stand area and of the only floating island of the South Europe. It is enclosed in a Natural Reserve recognized as Special Area of Conservation (SAC-IT6050015) for the presence of habitats and species (92/43/EEC) of relevant scientific interest. In this paper, we compare the plant-associated meio-macrobenthic invertebrates among sites with different environmental characteristics. Both vegetation and invertebrates of Lake Fibreno were well diversified and abundant and were composed of a mixing of species typical of lentic and lotic waters. Our results show that a gradient of orthophosphate and nitrite contents and current velocity appeared to be the driver factors affecting the flora and fauna spatial distribution at the sampling sites. To obtain a bioassessment of the ecological quality of the vegetation zone, we compared the riverine Lake Fibreno with typical lentic lakes previously studied in Central Italy. We selected metrics, such as macrophyte belt extent and taxa richness, invertebrate species richness and Shannon diversity, ETOM (Ephemeropta + Trichoptera + Odonata + Mollusca), ETOC (Ephemeropta + Trichoptera + Odonata + Coleoptera) and LCrM (Large Crustacea + Mollusca). The comparison indicated a good ecological status of the vegetation zone of Lake Fibreno mainly due to the continuous washout effects (dilution and fast water removal) which reduce the nutrient content available for phytoplankton and maintain the high transparency and good oxygenation of the lake waters.
文摘Wuzhen is a typical riverine town south of the Yangtze River.Due to the World Internet Conference being held there,it seems to have become a place where CEOs a nd bosses of inter net compa n ies working on plans for the industry’s development gather.
基金supported by the Fundação para a Ciência e a Tecnologia(FCT)[scholarship reference number:PD/BD/143020/2018]The authors are also grateful to FCT for its support through funding UIDB/04625/2020 from the research unit CERISThis study has been also supported by the Spanish Ministry of Science and Innovation(Programa Estatal de Proyectos de I+D+i,Ref.PID2019-111252RA-I00 CTA).
文摘Hydropeaking,which refers to rising or falling discharges caused by the turning on or off of hydro-turbines to generate electricity,is a topic of growing interest due to its impact on fluvial ecosystems.To date,most hydropeaking studies have focused on the impact of peak fluctuations on invertebrate and fish communities,but little attention has been paid to its impact on riverine plants and how functional traits may make them resistant to hydropeaking.We performed a review to assess how a set of 32 plant functional traits can be expressed in riverine plant species,and found evidence of how such expression affects their capacity to cope with common sources of hydropeaking disturbance(i.e.,inundation,fast water drawdown,and rapid water fluctuations linked to up-ramping and down-ramping hydropeaking operations).The information here presented can simplify the evaluation of impacts on riverine plant communities worldwide,as well as to detect suitable species to successfully restore rivers affected by hydropower production.
基金This research was supported by the Youth Innovation Promotion Association CAS(No.2017059)the National Natural Science Foundation of China(Nos.41877368 and 41701546).
文摘Anthropogenic activities are regarded as the main sources of heavy metal pollution,yet few studies have investigated the effects of land-use setting on heavy metal accumulation in riverine sediments.Based on both total contents and geochemical fractions,heavy metal pollution,risk and toxicity were determined in riverine sediment cores from different land-use areas(mountain area-MA,farm area-FA,city area-CA,and industrial area-LA)of the Yang River Basin in North China.The results showed that FA had higher contents of riverine sedimentary Cu;CA had higher contents of Cd;LA.had higher contents of both Cd and Zn.Most riverine sediments from FA and IA were contaminated with the investigated metals,although these concentrations were evaluated to have low potential ecological risk and no toxicity to benthic organisms.However,a high proportion of Cd in the B1 fraction of riverine sediments in IA indicating high risk should receive more attention.The B1 fraction largely determined the contamination,risk and toxicity levels associated with heavy metals in the riverine sediments of the Yang River Basin.
文摘Although riverine carbon fluxes are a minor component of the global carbon cycle, the transfer of organic carbon from land to ocean represents a flux of potential carbon storage, irreversible over 103 to 104 a. Future carbon transfers through river basins are expected to accelerate, with respect to both sources and sinks, because of the large-scale human driven land-use and land-cover changes. Thus, the increased amounts of carbon transported to and sequestered in marine sediments (through fertilization by river-borne inorganic nutrients) may be an important net sink for anthropogenic CO2. Particularly, the humid tropics of South Asia are regions very sensitive to this lateral C transport because of high precipitation and high rates of land use and cover change. In this paper we report on the role of upland tributaries in the transport processes influencing the lateral carbon and nitrogen fluxes of the Godavari, a large tropical river of India. By far, dissolved inorganic carbon (DIC) is the dominant form of carbontransport in the river basin. It constitutes as much as 75% to the total carbonload. Particulate and dissolved organic carbon (POC and DOC) fluxes account for21% and 4%, respectively. In the upper basin, DOC fluxes exceed that of POC dueto large-scale anthropogenic activities. In contrast, tributaries in the central basin are characterized by comparable fluxes of POC and DOC. However, downriver POC export is 35% less than the import from upriver and tributaries due to theentrainment of sediments in river channels and dam sites. We argue that for highly disturbed watersheds in tropical regions, downstream transport of sediments and carbon requires long-term sampling programmes.
文摘As flood extreme occurrences are projected to increase in intense and frequency due to climate change, the assessment of vulnerability and the identification of the most vulnerable areas, populations, assets and systems are an urgent need. Vulnerability has been widely discussed and several flood projection tools have been developed using complex hydrological models. However, despite the significant contribution of flood projection maps to predicting the impact of potential floods, they are difficult and impractical to use by stakeholders and policy makers, while they have proven to be inefficient and out of date in several cases. This research aims to cover the gaps in coastal and riverine flood management, developing a method that models flood patterns, using geospatial data of past large flood disasters. The outcomes of this research produce a five scale vulnerability assessment method, which could be widely implemented in all sectors, including transport, critical infrastructure, public health, tourism, constructions etc. Moreover, they could facilitate decision making and provide a wide range of implementation by all stakeholders, insurance agents, land-use planners, risk experts and of course individual. According to this research, the majority of the elements exposed to flood hazards, lay at specific combinations between 1) elevation (Ei) and 2) distance from water-masses (Di), expressed as (Ei, Di), including: 1) in general landscapes: ([0 m, 1 m), [0 km, 6 km), [0 m - 3 m), [0 km, 3 km)) and ([0 m - 6 m), [0 km, 1 km)), 2) in low laying regions: ([0 m, 1 m), [0 km, 40 km), [0 m - 3 m), [0 km, 30 km)) and ([0 m - 6 m), [0 km, 15 km)) and 2) in riverine regions: ([0 m, 4 m), [0 km, 3 km)). All elements laying on these elevations and distances from water masses are considered extremely and highly vulnerable to flood extremes.
基金supported by the Natural Science Foundation of China (Grant Nos. 40871143 and 41071054)funds of China Geological Survey (karst[2011] Geo-surveying 01-01-23)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Guangdong Provincial Natural Science Foundation of China (Grant No. 7003669)
文摘A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological seasons. The DOC level during the flood season (1.18 mg L-1) was less than that during the non-flood season (1.40 mg L-1). Owing to the concomitance of the flushing and dilution effects of the runoff during the high-water period, the variation of riverine DOC concentration with discharge in the XJR differed from that reported in many other major rivers. The DOC export flux above the city of Wuzhou was about 0.62× 106 g C km-2 yr-1. The DOC transported during the "056" Massive Flood period comprised 30.35% of the annual total, while the discharge accounted for 36.32% of the total annual flow. The characteristics in riverine DOC concentration in the XJR were attributed to the combined effect of the geomorphologic, monsoon climatic and hydrological processes as well as land-use within the drainage basin.
基金financially supported by the Ministry of Science and Technology of China through Grant Nos.2016YFA0601000 and 2013CB956700National Natural Science Foundation of China(Grant Nos.41422303,41130536 and 41625006)
文摘While it is critical to accurately understand the sources and transformation of sulfate based on time-series analysis, there are limited studies on temporal variation of sulfate in rivers and on rock weathering by sulfuric acids.We conducted a monthly sampling campaign in the Beipan, Nanpan, and Hongshui Rivers over the course of one hydrological year. This study examined seasonal variations in riverine sulfate impacted by the monsoon climate in the upper reaches of the Xijiang River basin. In general, the SO_4^(2-) contents in these rivers dropped from relatively high levels to low values during the high-flow season, in response to increasing discharge. The sulfate was generally enriched in heavy isotopes during the low-flow season compared to the high-flow season. The calculated results indicate that the riverine sulfate was mainly derived from sulfide oxidation, but that evaporite dissolution could be an important source during the low-flow season, based on isotopic evidence. Mine drainage is likely an important source of sulfate to these rivers during the high-flow season due to contributions from fast surface flow, which responds to frequent heavy rain in monsoonal climate regions. Arelatively high proportion of HCO_3^- was found to be derived from rock weathering by sulfuric acid during the high-flow season when compared to that observed during the low-flow season. The results suggest that approximately one quarter of the HCO_3^- in the Hongshui River originated from carbonate weathering by sulfuric acid derived from the oxidation of sulfide. Such information on the specific dual isotopic characteristics of riverine sulfate throughout a hydrological year can provide unique evidence for understanding the temporal variability of sulfate concentrations and weathering processes in rivers.
文摘The pesticides belong to a category of chemicals used worldwide as herbicides, insecticides, fungicides, ro-denticides, molluscicides, nematicides, and plant growth regulators in order to control weeds, pests and dis-eases in crops as well as for health care of humans and animals. The positive aspect of application of pesti-cides renders enhanced crop/food productivity and drastic reduction of vector-borne diseases. However, their unregulated and indiscriminate applications have raised serious concerns about the entire environment in general and the health of humans, birds and animals in particular. Despite ban on application of some of the environmentally persistent and least biodegradable pesticides (like organochlorines) in many countries, their use is ever on rise. Pesticides cause serious health hazards to living systems because of their rapid fat solu-bility and bioaccumulation in non-target organisms. Even at low concentration, pesticides may exert several adverse effects, which could be monitored at biochemical, molecular or behavioral levels. The factors af-fecting water pollution with pesticides and their residues include drainage, rainfall, microbial activity, soil temperature, treatment surface, application rate as well as the solubility, mobility and half life of pesticides. In India organochlorine insecticides such as DDT and HCH constitute more than 70% of the pesticides used at present. Reports from Delhi, Bhopal and other cities and some rural areas have indicated presence of sig-nificant level of pesticides in fresh water systems as well as bottled drinking mineral water samples. The ef-fects of pesticides pollution in riverine systems and drinking water in India has been discussed in this review.
基金supported by the Natural Science Foundation of China(no40903008,90610037, 40721002,and 40331005)the Open Research Fund of State Key Laboratory of Environmental Geochemistry, Chinese Academy of Sciences(SKLEG9006)the Chinese important special project(No2009ZX07419-003)
文摘To better understand the Fe isotope characteristics of natural samples in the Karst area,the Fe isotope compositions of riverine suspended particulates,lake suspended particulates,lake sediments,porewaters,phytoplanktons,and aerosols in the watersheds of Lake Aha(a mineralized water system)and Lake Hongfeng(a mesotrophic water system),which are located in the Karst area, southwest China,were investigated.The studied samples displayed a variable range betweenδ^(56)Fe=-2.03‰and 0.36‰.Aerosols and phytoplanktons have similar or slightly heavier Fe isotope compositions relative to the average of igneous rocks.Fe isotope compositions of riverine Suspended Particulate Matter(SPM)were mainly affected by the types of tributaries.Suspended particulates collected from tributaries seriously contaminated with coal mine drainages displayed negativeδ^(56)Fe values(-0.89‰to-0.31‰)during summer,and there were significant increases ofδ^(56)Fe values in winter,except AR2,which was polluted with both coal mine drainage and sewage effluent. Characteristics of lakes have important influences on Fe isotope compositions of suspended particulates,lake sediments,and porewaters.The epilimnetic particulate Fe of Lake Hongfeng hadδ^(56)Fe=-0.04‰to 0.13‰,while lighter Fe isotope compositions were measured for particulate Fe from Lake Aha,ranging from-0.42‰to-0.09‰.Sediments collected from Hou Wu(HW)station of Lake Hongfeng have an averageδ^(56)Fe value of 0.09‰and their corresponding porewaters have lighter Fe isotope compositions,ranging from-0.57‰to-0.31‰;no significant variations have been observed. For the Liang Jiang Kou(LJK)station of Lake Aha,the content of reactive Fe and the concentration of sulfate were all high.Due to the reactive Fe recycling,including dissimilatory Fe reduction,adsorption, and Fe-sulfide formation,porewaters sampled near the sediment surface have been found to have aδ^(56)Fe value as low as-2.03‰and an increase up to 0.12‰,with a burial depth of 10 cm.In contrast,an opposite variation trend was found for LJK sediments.Sediments sampled at 1-cm depth had a value ofδ^(56)Fe=-0.59‰and decrease as low as-1.75‰with burial depth.This investigation demonstrated that significant Fe isotope fractionations occur in surface environments.Fe isotope compositions of particulate Fe were seriously affected by Fe sources,and Fe biogeochemical recycling has an important influence on Fe isotope fractionations in lake sediments,especially when there are significant amounts of reactive Fe and sulfate.
基金Supported by the Knowledge Innovation Program of Chinese Academy of Sciences (No.KZCX2-YW-Q07-02)the National Basic Research Program of China (973Program)(No.2010CB428706)+1 种基金the Fund for Creative Research Groups of NSFC(No.41121064)the National Natural Science Foundation of China (No.41106090)
文摘We established a budget model of nitrogen (N) inputs and outputs between watersheds and waterbodies to determine the sources of riverine N in the Changjiang (Yangtze) River drainage area. Nitrogen inputs in the budget included N from synthetic fertilizer, biological fixation by leguminous and other crops, wet/dry atmospheric deposition, excreta from humans and animals, and crop residues. The total N input was estimated to be 17.6 Tg, of which 20% or 3.5 Tg N was transported into waterbodies. Of the total N transported into waterbodies, the largest proportion was N from animal waste (26%), followed by N from atmospheric wet/dry deposition (25%), synthetic fertilizer N (17%), N in sewage wastes (17%), N in human waste from rural areas (6%) and industrial wastewater N (9%). We studied the spatial patterns of N inputs and outputs by dividing the Changjiang River drainage area into four sub-basins, from upstream to downstream: the Tongtian River drainage area (TTD, the headwater drainage area, 138 000 l^n2, less disturbed by human activities); the Jinsha River drainage area (JSD, 347 000 km2, less disturbed by human activities, approx. 3 500 km upstream of the Changjiang estuary); the Pingshan-Yichang drainage area (PYD, 520 500 krn2, large-scale human disturbance, about 2 000 km upstream of the Changjiang estuary); and the Yichang-Datong drainage area (YDD, 699 900 km^2, large-scale httman disturbance, approx. 620 km upstream of the Changjiang estuary). The average N input into waterbodies was 2.3, 7.3, 24.1, and 28.2 kg N/ha in the TTD, JSD, PYD, and YDD sub-basins, respectively, suggesting an increase of N-components of more than 10 times from upstream to downstream areas.