Starch-Based Adhesives for Wood/Wood Composite Bonding: Review

Increasing global energy crisis and scarcity of petroleum resources has shifted focus of chemical industries to look for alternative raw material resources. The main focus of raw materials in wood adhesives, such as petroleum and natural gas [1] [2], would be gradually replaced by renewable biopolymers. Starch is a relatively inexpensive and renewable product from abundant plants, easy processing and it has been extensively used as binders, sizing materials, glues and pastes [3], but its bonding capacity is not strong enough to glue wood [4]. Extensive research has been carried out on improving the cohesive properties, especially water resistance, of starch-based adhesives. In starch-based wood adhesive many new approaches have come forward for effective use it in wood/wood composite adhesive giving comparable performance as synthetic adhesives. This review of starch-based adhesives is made with the focus on starch modification methods for improving properties of starch-based adhesives.

Modeling and Optimization of the Shear Strength of Cassava Starch-Based Adhesives Using Artificial Intelligence Methods

With the exponential growth of the computing power,machine learning techniques have been successully used in various applications.This paper intended to predict and optimize the shear strength of single lap cassava starch-based adhesive joints for comparison with the application of artificial intelligence(AI)methods.The shear strength was firstly determined by the experiment with three independent experimental variables(starch content,NaOH concentration and reaction temperature).The analysis of range(ANORA)and analysis of variance(ANOVA)were applied to investigate the optimal combination and the significance of each factor for the shear strength based on the orthogonal experiment.The performance of all AI models was char acterized by mean absolute error(MAE),root mean square error(RMSE)and regression coefficient(R^(2))compared with the experi-mental ones.The GA optimized ANN model was combined with the genetic algorithm(GA)to find the optimal combination of factors for the finalized optimized cassava starch adhesives(CSA-OP).The physicochemical prop-erties of the cassava starch and CSA-OP were determined by the FTIR,TGA and SEM EDS,respectively.The results showed that the numerical optimized condition of the GA optimized ANN model was superior to the orthogonal experimental optimized condition.The sensitivity analysis revealed that the relative importance of variables was consistent with the results from ANOVA.FTIR results showed that there were high hydroxyl groups in cassava starch.TGA results showed that the residue of CSA OP was higher than the assava starch.SEM EDS results showed that both the cassava starch and CSA OP had abundant carbon and oxygen functional groups.Consequently,the obtained results revealed that the use of AI methods was an adequate approach to model and optimize the experimental variables of the shear strength of single lap cassava starch-based adhesive joints.

Influence of Processing Variables on Some Physico-Chemical Properties and Quality of Manioc Starch-Based Adhesives

Bio-degradable cassava starch-based adhesives were produced from chemically gelatinized starch formulations. The varying combinations of process parameters applied include: concentration of gelatinization modifier, mass % borax/starch, and temperature of reaction mixture. The physico-chemical parameters for characterizing the adhesive samples were viscosity, density, pH and bonding strength. The effects of the variation of process parameters on the quality of the adhesives were assessed using response surface (central composite) designs with 2 factors, to relate the highest adhesive quality with the optimal combination of process factors. The adhesives produced using HCl as the gelatinization modifier were of a higher quality than those produced using NaOH with one of the most important quality assessment parameters which is the bond strength being 22.31 kPa at 0.01 M and 20% mass borax/starch and 11.60 kPa at 0.01 M and 8% mass borax/starch for HCl and NaOH respectively. The experimental results demonstrated that the optimal temperature for the production of the adhesive was 85˚C.

Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites

More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that are dangerous to health.Scientists have spent the last decade replacing formaldehyde and phenol with environmentally friendly substances such as glyoxal and tannin to create bio-based adhesives.This review covers recent advances in synthesizing glyoxal tannin-based resins,especially those made from sustainable raw material substitutes and changes made to synthetic processes to improve mechanical properties.The efficacy of using tannin-glyoxal adhesives in producing wood-based composites has been proven.The glyoxylate reaction forms cross-linked bridges between the aromatic sites of the tannin and glyoxal molecular structures.Glyoxal tannin adhesive with a greater percentage of glyoxal than tannin will produce an adhesive with better characteristics.The gel time reduces as the hardener concentration rises from 7.5%to 15%when glyoxal is used in adhesives.However,excessive amounts of glyoxal will result in a decrease in viscosity values.Glyoxal exhibits faster delivery degradation when it reaches a maximum temperature of approximately 130°C,although it initiates the curing process slightly slower at 110°C.Adding glyoxal to tannin-based adhesives can improve the mechanical properties of composite boards.The wet shear strength of the resulting plywood is increased by 105.4%with the addition of 5-weight percent tannin-based resin with glyoxal as a cross-linker in Soy Protein Adhesive.With glyoxal as a hardener,the panels produced showed good internal bond strengths(>0.35 MPa)and met the international standard specifications for interior-grade panels.

Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

Lignin is the most abundant aromatic natural polymer,and receiving great attention in replacing various petro-leum-based polymers.The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane(NIPU)adhesives to substitute current polyurethane(PU)adhesives that have been synthesized with toxic isocyanate and polyols.Crude hardwood kraft lignin(C-HKL)was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL(AS-HKL).Then,C-HKL,AS-HKL,and softwood sodium lignosulfonate(LS)were used for the synthesis of technical lignin-based NIPU adhesives through carbonation and polyamination and silane as a cross-linker.Their adhesion per-formance was determined for plywood.FTIR spectra showed the formation of urethane bonds and the reaction between lignin and silane.The NIPU adhesives prepared with C-HKL showed the highest adhesion strength among the three lignin-based NIPU adhesives.As the silane addition level increased,the adhesion strength of NIPU adhesives increased whereas formaldehyde emission decreased for all NIPU adhesives prepared.These results indicate that NIPU adhesives based on technical kraft lignin have a great potential as polyol for the synth-esis of bio-based NIPU adhesives for wood bonding.

Theoretical optimization of micropillar arrays for structurally stable bioinspired dry adhesives

Inspired by the excellent adhesion performances of setae structure from organisms,micro/nano-pillar array has become one of the paradigms for adhesive surfaces.The micropillar arrays are composed of the resin pillars for adhesion and the substrate with different elastic modulus for supporting.The stress singularity at the bi-material corner between the pillars and the substrate can induce the failure of the micropillar-substrate corner and further hinder the fabrication and application of micropillar arrays,yet the design for the stability of the micropillar array lacks systematical and quantitative guides.In this work,we develop a semi-analytical method to provide the full expressions for the stress distribution within the bi-material corner combining analytical derivations and numerical calculations.The predictions for the stress within the singularity field can be obtained based on the full expressions of the stress.The good agreement between the predictions and the FEM results demonstrates the high reliability of our method.By adopting the strain energy density factor approach,the stability of the pillar-substrate corner is assessed by predicting the failure at the corner.For the elastic mismatch between the pillar and substrate given in this paper,the stability can be improved by increasing the ratio of the shear modulus of the substrate to that of the micropillar.Our study provides accurate predictions for the stress distribution at the bi-material corner and can guide the optimization of material combinations of the pillars and the substrate for more stable bioinspired dry adhesives.

Mussel-inspired Methacrylic Gelatin-dopamine/Ag Nanoparticles/Graphene Oxide Hydrogels with Improved Adhesive and Antibacterial Properties for Applications as Wound Dressings

A novel strategy was developed to prepare the methacrylic gelatin-dopamine(GelMA-DA)/Ag nanoparticles(NPs)/graphene oxide(GO) composite hydrogels with good biocompatibility,mechanical properties,and antibacterial activity.Mussel-inspired DA was utilized to modify the GelMA molecules,which imparts good adhesive performance to the hydrogels.GO,interfacial enhancer,not only improves mechanical properties of the hydrogels,but also provides anchor sites for loading Ag NPs through numerous oxygencontaining functional groups on the surface.The experimental results show that the GelMA/Ag NPs/GO hydrogels have good biocompatibility,and exhibit a swelling rate of 202±16%,the lap shear strength of 147±17 kPa,and compressive modulus of 136±53 kPa,in the case of the Ag NPs/GO content of 2 mg/mL.Antibacterial activity of the hydrogels against both gram-negative and gram-positive bacteria is dependent on the Ag NPs/GO content derived from the release of Ag^(+).Furthermore,the GelMA/Ag NPs/GO hydrogels possess good adhesive ability,which is resistant to highly twisted state when stuck on the surface of pigskin.These results demonstrate promising potential of the GelMA-DA/Ag NPs/GO hydrogels as wound dressings for biomedical applications in clinical and emergent treatment.

Universal Encapsulation Adhesive for Lead Sedimentation and Attachable Perovskite Solar Cells with Enhanced Performance

In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ion-blocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity(RH)are superior to the devices encapsulated with polyisobutylene.The PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module(17.2%)encapsulated by PUA remains 92.6%within 1825 h.These results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead hazards.Moreover,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation.

Effect of Adhesive Type on the Quality of Coconut Shell Charcoal Briquettes Prepared by the Screw Extruder Machine

Indonesia is one of the largest coconut-producing countries in the world.The utilization of coconut shell waste into briquettes will increase the selling value and become a great export opportunity.However,the effect of adhesives on the quality of coconut shell charcoal briquettes made using screw extruder machine has not been widely studied.This study aims to determine the effect of adhesive type on the quality of coconut shell charcoal briquettes.The process of fabricating briquettes in this study included crushing,mixing,blending,pressing,and drying.In the mixing process,3 types of adhesives were used,namely tapioca flour(Briquette_1),cassava flour(Briquette_2),and modified cassava flour(Briquette_3)with a concentration of 5%of the weight of coconut shell charcoal powders.The quality of the resulting briquettes and commercial briquettes will be evaluated by moisture content,ash content,volatile matter,fixed carbon,calorific value,density,compressive,and drop test testing.The results of this research showed that the type of adhesive had a significant effect on the quality of the briquettes produced.Specimen Briquette_1 had better quality than commercial briquettes(Briquette_4)and other briquette specimens.The test results showed that Briquette_1 produced briquettes with better compressive strength and friability than the other specimens,at 6.95 N/mm^(2) and 4.44%,respectively.The moisture content,ash content,fixed carbon,and calorific value of Briquette_1 have met the requirements set by the Indonesian National Standard(SNI)number 01-6235-2000.Meanwhile,the volatile matter content and density of Briquette_1 are by the standards of Japan and the United States America(USA).

Preparation of Environmentally Friendly Urea-Hexanediamine-Glyoxal(HUG)Resin Wood Adhesive

Using non-toxic,low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal(UG)resin adhesive is a hot research topic that could be of great interest for the wood industry.However,urea-glyoxal(UG)resins prepared by just using glyoxal instead of formaldehyde usually yields a lower degree of polymerization.This results in a poorer bonding performance and water resistance of UG resins.A good solution is to pre-react urea to preform polyurea molecules presenting already a certain degree of polymerization,and then to condense these with glyoxal to obtain a novel UG resin.Therefore,in this present work,the urea was reacted with hexamethylene diamine to form a polyurea named HU,and then this was used to react it with different amounts of glyoxal to synthesize hexamethylenediamine-urea-glyoxal(HUG)polycondensation resins,and to use this for bonding plywood.The results show that the glyoxal can well react with HU polyuria via addition and schiff base reaction,and also the HUG resin exhibits excellent bonding strength and water resistance.The shear strength of the plywood bonded with this HUG at 160°C hot press temperature as high as 1.93 MPa,2.16 MPa and 1.61 MPa,respectively,which meets the requirement of the China national standard GB/T 9846-2015(≥0.7 MPa),and can be a good choice as a wood adhesive for industrial application.

Efficacy of Cyanoacrylate Tissue Adhesive Application in the Management of Corneal Perforations at Preah Ang Duong Hospital in Cambodia

Purpose: The study was to evaluate the efficacy of cyanoacrylate tissue adhesive (CTA) application in corneal perforations. Method: This was a prospective study on 20 patients of corneal perforations who received cyanoacrylate tissue adhesive application as treatment between March 2021 and March 2022 at Preah Ang Duong Hospital. The primary outcome measure was success rate of CTA application, while the secondary outcome was to measure postoperative best-corrected visual acuity (BCVA) and ocular complications. Results: The mean age of patients was 44.15 ± 16.05 years old and 7 (35%) were female. Causes of perforation were microbial infection in 12 patients (60%), trauma in 5 patients (25%), and sterile melting in 3 patients (15%). The perforation of size smaller than 1.5 mm was in 8 patients (40%) while 12 patients (60%) had perforated size between 1.5 mm to 3 mm. The perforation was 60% (12 patients) central, 25% (5 patients) paracentral, and 15% (3 patients) peripherally. Out of 20 patients, 5 patients (25%) received CTA application more than 1 time. The mean glue retention was 57.60 ± 31.84 days. Success rate of glue application (defined as intact globe without surgical intervention regardless of number of CTA applications) was 85%. At the last visit, 7 patients (35%) had BCVA of 6/120 or better. Common complications were uveitis (45%), ocular hypertension (30%), cataract (25%) and neovascularization (20%). No serious complications were found. Conclusion: Cyanoacrylate tissue adhesive is an effective treatment option in sealing corneal perforations with no serious complications. .

Termite Resistance of Heat-Treated Eucalyptus OSB Bonded with Eco-Friendly Castor Oil Adhesive

Over the last decade,the oriented strand board(OSB)market presented meaningful growth.However,as a woodbased product,because of its anatomical structure and chemical composition,OSB can be damaged by biodeterioration agents.Given that,the biodeterioration of OSB panels must be investigated to improve its durability.In this way,this work analyses the biological resistance against termites(Cryptotermes brevis and Nasutitermes corniger)of heat-treated OSB panels made with Eucalyptus wood glued with vegetable-based polyurethane-an ecofriendly and sustainable adhesive derived from castor oil.Various panels were produced with different layers compositions(face:core:face of 25:50:25 and 30:40:30)in wood mass proportion and were submitted to postproduction heat treatment(at 175℃ and 200℃)replacing the use of chemical insecticides.The influence of the layers variation and heat treatment temperature were evaluated,and these results were compared with commercial panels(made from pinus wood with insecticide).The results showed that the heat treatment did not improve the resistance against termite attack.However,all the experimental panels presented a satisfactory performance that was compatible with the commercial panels produced with insecticide available in the Brazilian market.The combination of Eucalyptus wood and castor oil adhesive to produce OSB,in any variation of layer composition,demonstrated natural resistance against termite attack compatible with the commercial panels,even without using chemical additives to increase durability.

Properties of Bark Particleboard Bonded with Demethylated Lignin Adhesives Derived from Leucaena leucocephala Bark

Lignin extraction from bark can maximize the utilization of biomass waste,offer cost-effectiveness,and promote environmental friendliness when employed as an adhesive material in bark particleboard production.Particles of fine(0.2 to 1.0 mm),medium(1.0 to 2.5 mm),and coarse(2.5 to 12.0 mm)sizes,derived from the bark of Leucaena leucocephala,were hot-pressed using a heating plate at 175℃for 7 min to create single-layer particleboards measuring 320 mm×320 mm×10 mm,targeting a density of 700 kg/m^(3).Subsequently,the samples were trimmed and conditioned at 20℃and 65%relative humidity.In this study,we compared bark particleboard bonded with urea formaldehyde(UF)adhesive to fine-sized particleboard bonded with demethylated lignin adhesive.The results indicated that bark particleboards utilizing demethylated lignin and UF adhesives exhibited similar qualities.Coarse particleboard showed differences in modulus of elasticity(MOE)and modulus of rupture(MOR),while medium-sized particles exhibited significant variations in moisture content(MC)and water absorption(WA).Furthermore,the thickness swelling of coarse and medium-sized particles under wet and oven-dried conditions exhibited notable distinctions.Overall,the demethylated lignin adhesive extracted from L.leucocephala bark demonstrated similar quality to UF adhesive,with particle size correlating inversely to the strength of the bark particleboard.

Endoscopic band ligation or endoscopic tissue adhesive injection in the treatment of gastric varices:Which is better?

The combination of endoscopic ultrasound with endoscopic treatment of type 1 gastric variceal hemorrhage may improve the robustness and generalizability of the findings in future studies.Moreover,the esophageal varices should also be included in the evaluation of treatment efficacy in subsequent studies to reach a more convincing conclusion.

Ginger oil-loaded transdermal adhesive patch treats post-traumatic stress disorder

Objective:To find a viable alternative to reduce the number of doses required for the patients with post-traumatic stress disorder(PTSD),and to improve efficacy and patient compliance.Methods: In this study,we used ginger oil,a phytochemical with potential therapeutic properties,to prepare ginger oil patches.High-performance liquid chromatography(HPLC)was used to quantify the main active component of ginger oil,6-gingerol.Transdermal absorption experiments were conducted to optimize the various pressure-sensitive adhesives and permeation enhancers,including their type and concentration.Subsequently,the ginger oil patches were optimized and subjected to content determination and property evaluations.A PTSD mouse model was established using the foot-shock method.The therapeutic effect of ginger oil patches on PTSD was assessed through pathological sections,behavioral tests,and the evaluation of biomarkers such as tumor necrosis factor-α(TNF-α),interleukin-6(IL-6),brain-derived neurotrophic factor(BDNF),and melatonin(MT).Results: The results demonstrated that ginger oil patches exerted therapeutic effects against PTSD by inhibiting inflammatory responses and modulating MT and BDNF levels.Pharmacokinetic experiments revealed that ginger oil patches maintained a stable blood drug concentration for at least one day,addressing the rapid metabolism drawback of 6-gingerol and enhancing its therapeutic efficacy.Conclusions: Ginger oil can be prepared as a transdermal drug patch that meets these requirements,and the bioavailability of the prepared patch is better than that of oral administration.It can improve PTSD with good patient compliance and ease of administration.Therefore,it is a promising therapeutic formulation for the treatment of PTSD.

Investigating the Mechanical and Thermal Properties of PDMS-Toughened Epoxy Resins for Advanced Adhesive Solutions

This study investigates the enhancement of mechanical and thermal properties in epoxy resins modified with polydimethylsiloxane (PDMS) for advanced adhesive applications. The research focuses on evaluating the tensile strength, thermal stability, and glass transition temperature (Tg) of PDMS-toughened epoxy resins. The primary objective of this study was to explore the use of polydimethylsiloxane (PDMS) as an impact modifier for epoxy resin. We successfully synthesized a grafting copolymer of diglycidyl ether bisphenol-A (DGEBA) and hydroxyl-terminated polydimethylsiloxane (HTPDMS) through the condensation of hydroxyl groups. Triethylene tetraamine (TETA) was employed as the curing agent to cross-link both DGEBA and the HTPDMS copolymer. The chemical structure of the DGEBA-HTPDMS grafting copolymer was confirmed using fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (NMR) spectroscopy. Tensile testing of the cured materials indicated that the elongation at break increased upon addition of PDMS. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed improved thermal stability for the DGEBA system with the incorporation of HTPDMS. These findings suggest that the Si-O-Si segments within the PDMS contribute to the improved mechanical and thermal properties of the DGEBA-based resin.

Polyurethane Hybrid-Based Wood Adhesive: Review

Based on commercially available polyvinyl alcohol (PVA) stabilised polyvinyl acetate (PVAc), emulsion adhesives are neither heat nor moisture-resistant and show weak strength at high relative humidity and high temperatures. Pre- or post-crosslinking is another method used to manufacture a conventional vinyl-based homopolymers or copolymers system with improved water resistance. Vinyl neodecanoate (VeoVa), N-methylolacrylamide (NMA), Methacrylamide, methacrylic acid (MAA), and other self-crosslinking comonomers are typically inserted to produce highly water-resistant vinyl based homopolymers or copolymers. Additionally, organic crosslinkers like glyoxal, glutaraldehyde, citric acid, tartaric acid, and the like, as well as inorganic crosslinkers like acidic metal salts like aluminium chloride, aluminium nitrate, boric acid, and the like, can be used to prepare the highly water-resistant vinyl based homopolymers or copolymers. It is also possible to combine the self-crosslinking comonomers with the organic crosslinkers. Recently, a different hybrid chemistry has been developed that improves lap shear strength, has outstanding water resistance, good durability, and doesn’t require any additional crosslinker agents. Two distinct polymers were combined to develop hybrid polymers. They usually involve mixing an organic polymer with a polymer. There are many capping agents that are used for polyurethanes to produce acrylics that are capped with polyurethane and used as an oligomer in PVAc wood glue. Here, in this paper, we reviewed the different hybrid chemistry based on polyurethane chemistry for wood bonding applications.

Reinforcing Effect of Graphene in Epoxy Adhesives: Review

Due to its great strength, hardness, and chemical resistance, epoxy adhesives are becoming more and more used. They continue to have drawbacks, nevertheless, such as poor thermal stability, and poor electrical conductivity. Two-dimensional graphene is a wonderful substance with exceptional qualities including high strength, high electrical conductivity, and large surface area. Because of these characteristics, graphene has been thoroughly researched for its prospective uses in a variety of industries, including electronics, energy storage, and biomedical engineering. The use of graphene as an additive in epoxy adhesives to enhance the characteristics of such materials is one of its promising uses. This paper reviewed the latest findings about graphene’s effects on epoxy adhesives. The various methods to produce graphene-epoxy composites and their improvements are discussed. This research additionally discusses the challenges associated with the production and processing of graphene-epoxy composites, as well as the mechanisms behind the improvements in mechanical, electrical, and thermal characteristics. The final section of this review discusses the challenges and prospective uses of graphene in epoxy adhesives in the future.

Polyvinyl Acetate and Vinyl Acetate-Ethylene Hybrid Adhesive: Synthesis, Characterization, and Properties

The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were effectively synthesized. Emulsions with various characteristics have been developed by adjusting the weight ratios between the vinyl acetate monomer and the VAE component. The impacts on the mechanical, thermal, and physical properties of the films were investigated using tests for pencil hardness, tensile shear strength, pH, contact angle measurement, differential scanning calorimetry (DSC), and viscosity. When 5.0 weight percent VAE was added, the tensile shear strength in dry conditions decreased by 18.75% after a 24-hour bonding period, the heat resistance decreased by 26.29% (as per WATT 91) and the tensile shear strength decreased by approximately 36.52% in wet conditions (per EN 204). The pristine sample’s results were also confirmed by the contact angle test. The interpenetrating network (IPN) formation in hybrid PVAc emulsion as primary bonds does not directly attach to PVAc and VAE chains. The addition of VAE reduced the mechanical properties (at dry conditions) and heat resistance as per WATT 91. Contact angle analysis demonstrated that PVAc adhesives containing VAE had increased water resistance when compared to conventional PVA stabilised PVAc homopolymer-based adhesives. When compared to virgin PVAc Homo, the water resistance of the PVAc emulsion polymerization was enhanced by the addition of VAE.

Silane Modification of Starch-Based Wood Adhesive: Review

Currently there has been a growing interest in substituting traditional synthetic polymers with biobased renewable polymers for adhesive applications. However, biobased renewable polymers such as starch suffer from few draw-backs like poor water resistance and mechanical strength. To become important potential alternatives of synthetic polymers, starch must have comparable physical, chemical, thermal and mechanical properties to that of synthetic polymers. To achieve this, starch has been modified by a series of crosslinkers like boric acid, citric acid, glyoxal, gluteraldehyde, etc. and silane modification. Silane modification by chloropropyl trimethoxysilane, γ-Methacryloxypropyl trimethoxy silane and vinyl trimethoxy silane is a suitable method to improve the performance in terms of mechanical and thermally. Silane forms covalent bonds with starch during starch modification resulted in enhanced shear strength and storage stability. A new research on biodegradable, renewable, environmentally friendly silane modification of starch-based wood adhesive that was prepared by reacting with various silanes. This paper, we reviewed silane as a modifying agent for starch-based wood adhesive.