In order to effectively reduce energy consumption and increase range mile,new energy vehicles represented by Tesla have greatly aroused the application of integrated magnesium(Mg)alloy die casting technology in automo...In order to effectively reduce energy consumption and increase range mile,new energy vehicles represented by Tesla have greatly aroused the application of integrated magnesium(Mg)alloy die casting technology in automobiles.Previously,the application of Mg alloys in automobiles,especially in automotive cockpit components,is quite extensive,while it has almost disappeared for a period of time due to its relatively high cost,causing a certain degree of information loss in the application technology of Mg alloy parts in automobiles.The rapid development of automotive technology has led to a higher requirement for the automotive components compared with those traditional one.Therefore,whatever the components themselves,or the Mg alloy materials and die casting process have to face an increasing challenge,needing to be upgraded.In addition,owing to its high integration characteristics,the application of Mg alloy die casting technology in large-sized and thin-walled automotive parts has inherent advantages and needs to be expanded urgently.Indeed,it necessitates exploring advance Mg alloys and new product structures and optimizing die casting processes.This article summarizes and analyzes the development status of thin-walled and large-sized die casting Mg alloy parts in passenger car cockpit and corresponding material selection methods,die casting processes as well as mold design techniques.Furthermore,this work will aid researchers in establishing a comprehensive understanding of the manufacture of thin-walled and large-sized die casting Mg alloy parts in automobile cockpit.It will also assist them in developing new Mg alloys with improved comprehensive performance and new processes to meet the high requirements for die casting automotive components.展开更多
Aspects of the general Vlasov theory are examined separately as applied to a thin-walled channel section cantilever beam under free-end end loading. In particular, the flexural bending and shear that arise under trans...Aspects of the general Vlasov theory are examined separately as applied to a thin-walled channel section cantilever beam under free-end end loading. In particular, the flexural bending and shear that arise under transverse shear and axial torsional loading are each considered theoretically. These analyses involve the location of the shear centre at which transverse shear forces when applied do not produce torsion. This centre, when taken to be coincident with the centre of twist implies an equivalent reciprocal behaviour. That is, an axial torsion applied concentric with the shear centre will twist but not bend the beam. The respective bending and shear stress conversions are derived for each action applied to three aluminium alloy extruded channel sections mounted as cantilevers with a horizontal principal axis of symmetry. Bending and shear are considered more generally for other thin-walled sections when the transverse loading axes at the shear centre are not parallel to the section = s centroidal axes of principal second moments of area. The fixing at one end of the cantilever modifies the St Venant free angular twist and the free warping displacement. It is shown from the Wagner-Kappus torsion theory how the end constrained warping generates an axial stress distribution that varies with the length and across the cross-section for an axial torsion applied to the shear centre. It should be mentioned here for wider applications and validation of the Vlasov theory that attendant papers are to consider in detail bending and torsional loadings applied to other axes through each of the centroid and the web centre. Therein, both bending and twisting arise from transverse shear and axial torsion applied to each position being displaced from the shear centre. Here, the influence of the axis position upon the net axial and shear stress distributions is to be established. That is, the net axial stress from axial torsional loading is identified with the sum of axial stress due to bending and axial stress arising from constrained warping displacements at the fixing. The net shear stress distribution overlays the distributions from axial torsion and that from flexural shear under transverse loading. Both arise when transverse forces are displaced from the shear centre.展开更多
Lithium-selenium(Li-Se)battery has attracted growing attention.Nevertheless,its practical application is still impeded by the shuttle effect of the formed polyselenides.Herein,we report in-situ hydrothermal weaving th...Lithium-selenium(Li-Se)battery has attracted growing attention.Nevertheless,its practical application is still impeded by the shuttle effect of the formed polyselenides.Herein,we report in-situ hydrothermal weaving the three-dimensional(3 D)highly conductive hierarchically interconnected nanoporous web by threading microporous metal organic framework MIL-68(Al)crystals onto multi-walled carbon nanotubes(MWCNTs).Such 3 D hierarchically nanoporous web(3 D MIL-68(Al)@MWCNTs web)with a very high surface area,a large amount of micropores,electrical conductivity and elasticity strongly traps the soluble polyselenides during the electrochemical reaction and significantly facilitates lithium ion diffusion and electron transportation.Molecular dynamic calculation confirmed the strong affinity of MIL-68(Al)for the adsorption of polyselenides,quite suitable for Li-Se battery.Their hexahedral channels(1.56 nm)are more efficient for the confinement of polyselenides and for the diffusion of electrolytes compared to their smaller triangular channels(0.63 nm).All these excellent characteristics of 3 D MIL-68(Al)@MWCNTs web with suitable confinement of a large amount of selenium and the conductive linkage between MIL-68(Al)host by MWCNTs result in a high capacity of 453 m Ah/g at 0.2 C with 99.5%coulombic efficiency after 200 cycles with significantly improved cycle stability and rate performance.The 3 D MIL-68(Al)@MWCNTs web presents a good performance in Li-Se battery in term of the specific capacity and cycling stability and also in terms of rate performance compared with all the metal-organic framework(MOF)based or MOF derived porous carbons used in Li-Se battery.展开更多
The inner hole parts played an oriented or supporting role in engineering machinery and equipment,which are prone to appear surface damages such as wear,strain and corrosion. The precise pulse plasma arc powder weldin...The inner hole parts played an oriented or supporting role in engineering machinery and equipment,which are prone to appear surface damages such as wear,strain and corrosion. The precise pulse plasma arc powder welding method is used for surface damage repairing of inner hole parts in this paper. The working principle and process of the technology are illustrated,and the microstructure and property of repairing layer by precise pulse plasma powder welding and CO2 gas shielded welding are tested and observed by microscope,micro hardness tester and X-ray residual stress tester etc. Results showed that the substrate deformation of thin-walled inner hole parts samples by precise pulse plasma powder welding is relatively small. The repair layer and substrate is metallurgical bonding,the transition zones( including fusion zone and heat affected zone) are relatively narrow and the welding quality is good. It showed that the thin-walled inner hole parts can be repaired by this technology and equipment.展开更多
The newly designed vacuum differential pressure casting (VDPC) unit was introduced, by which the capabilityof the VDPC process to produce thin-walled complicated Al-alloy castings, that are free from oxides, gas pore ...The newly designed vacuum differential pressure casting (VDPC) unit was introduced, by which the capabilityof the VDPC process to produce thin-walled complicated Al-alloy castings, that are free from oxides, gas pore andshrinkage cavity and thus enhance overall part quality, was studied. Experimental results were compared with those oftraditional gravity pouring and vacuum suction casting. The first series of experiments were focused on investigating thecastability of thin section Al-alloy casting. In the second series of experiments the metallographic evidence, castingstrength and soundness were examined. Finally, case studies of very interesting thin walled complicated casting applicationswere described. The advantages of the described technique have made possible to produce thin walled complicatedAl-alloy casting (up to a section thickness of 1 mm), which is not practical for gravity pouring and vacuum suction casting.展开更多
The paper deals with the application of multiwall carbon nanotubes(CNTs) to the adsorption of dyes from wastewater. Textile dyes are dangerous and diffused pollutant in wastewater, and the paper results confirmed the ...The paper deals with the application of multiwall carbon nanotubes(CNTs) to the adsorption of dyes from wastewater. Textile dyes are dangerous and diffused pollutant in wastewater, and the paper results confirmed the good adsorption ability of CNTs, with respect to classic active carbon, even for different dye types. The effect of surface treatments of CNTs was primarily investigated, revealing that neither the presence of residual catalyst nor common surface treatment(oxidation) affects the CNT's performances. Therefore less expensive nonpurified CNTs were assessed as good and economically convenient alternative for the process. In order to gain in generality in adsorption kinetic modelling, the parameters of the "best fitting" pseudo-second order model have been correlated to the main process variables(the dye initial concentration and the specific mass of CNTs.) setting-up a predictive kinetic model useful design new application of these materials in currently operating industrial operations for adsorption. In addition, isothermal data were used to screen all the relevant adsorption isotherms models and the Temkin model was confirmed as the more effective to accurately fit equilibrium data for any of the considered different dye types.展开更多
The spinning deformation of thin walled tube in necking process is simulated with a dynamic explicit FEM program,LS DYNA3D and the distributions of Cauchy strains and thickness are analyzed through time history to a...The spinning deformation of thin walled tube in necking process is simulated with a dynamic explicit FEM program,LS DYNA3D and the distributions of Cauchy strains and thickness are analyzed through time history to achieve a good understanding of the deformation in necking process by spinning and the numerical simulation results are in good agreement with the test results.展开更多
In the present paper, a series of hierarchical warping functions is developed to analyze the static and dynamic problems of thin walled composite laminated helicopter rotors composed of several layers with single clos...In the present paper, a series of hierarchical warping functions is developed to analyze the static and dynamic problems of thin walled composite laminated helicopter rotors composed of several layers with single closed cell. This method is the development and extension of the traditional constrained warping theory of thin walled metallic beams, which had been proved very successful since 1940s. The warping distribution along the perimeter of each layer is expanded into a series of successively corrective warping functions with the traditional warping function caused by free torsion or free beading as the first term, and is assumed to be piecewise linear along the thickness direction of layers. The governing equations are derived based upon the variational principle of minimum potential energy for static analysis and Rayleigh Quotient for free vibration analysis. Then the hierarchical finite element method. is introduced to form a,. numerical algorithm. Both static and natural vibration problems of sample box beams axe analyzed with the present method to show the main mechanical behavior of the thin walled composite laminated helicopter rotor.展开更多
A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the ...A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the oxidation temperature was determined. The process included sonication, oxidation and acid washing steps. The purity and yield after purification were determined and estimated by TEM. Moreover, for the first time, a loop structure for CVD SWNTs has been observed.展开更多
A lumped parameter-rigid elastic coupled dynamic model of two-stage planetary gears for a hybrid car is established through the inter-stage coupled method,in which the supports of the ring gear of planet set Ⅱ are re...A lumped parameter-rigid elastic coupled dynamic model of two-stage planetary gears for a hybrid car is established through the inter-stage coupled method,in which the supports of the ring gear of planet set Ⅱ are represented as an elastic foundation with radial and tangential uniform distributed stiffness,and the ring gear of planet set Ⅱ is modeled as an elastic continuum body. The natural frequencies based on the eigenvalue problem of dynamic model of planetary transmission are solved and the associated vibration modes are discussed. The rules are revealed which are the influences of the ring gear elastic supports stiffness and rim thickness on natural frequencies of planetary transmission. The theoretical analysis indicates that the vibration modes of planetary transmission with thin-walled ring gear on elastic supports are classified into seven types: Ⅰ/Ⅱ stage coupled rotational mode,Ⅰ stage translational mode,Ⅰ stage planet mode,Ⅱ stage translational mode,Ⅱ stage degenerate planet mode,Ⅱ stage distinct planet mode and purely ring gear mode. For each vibration mode, its properties are summarized. The numerical solutions show that the elastic supports stiffness and rim thickness of the ring gear of planet set Ⅱ have different influences on natural frequencies.展开更多
Density functional theory (DFT) is used to calculate adsorption of ethane molecules in single walled carbon nanotubes. A compari-son of DFT calculations and grand canonical ensemble Monte Carlo (GCMC) simulations is m...Density functional theory (DFT) is used to calculate adsorption of ethane molecules in single walled carbon nanotubes. A compari-son of DFT calculations and grand canonical ensemble Monte Carlo (GCMC) simulations is made first and the two methods are in good agree-ment. Adsorption isotherms and structures of ethane molecules inside the tubes have been studied by DFT for the nanotubes of diameters 0.954, 2.719 and 4.077 nm at 157 K and ambient temperature, 300 K. By using the grand potential, the positions of phase transitions are exactly lo-cated, and the effect of temperature and tube diameter on phase transitions and adsorption is discussed. We found that lowering temperature and increasing the pore size of several nanometer is preferable for the ethane adsorption when temperature is in the range of 157 K—300 K and op-erating pressure reaches several MPa. Layering transitions and capillary condensations are observed at 157 K in two larger pore diameters, while these phase transitions disappear or the hysteres is loops become very narrow at 300 K.展开更多
According to the reliability of material strength,the optimal design for the cross sectional size of thin walled box beam was studied.Firstly the cross sectional size as design random variable was determined,then its...According to the reliability of material strength,the optimal design for the cross sectional size of thin walled box beam was studied.Firstly the cross sectional size as design random variable was determined,then its stochastic nature was researched,with which the objective function is to seek the maximum reliability of the beam under given constraint conditions.This way is not the same as the conventional optimal design for the minimum weight of the material.With establishing the optimal objective,the reliability of the material under conditions of static and fatigue was considered.The corresponding calculated expressions are given.Normally the cross section sizes are fitted to the normal distribution,for the simplification of the design variable,the variation of the section size is assumed as a dependent variable proportional to the mean of the size.The way is different not only with the conventional optimal design but also with the common reliability design.The maximum reliability of material is obtained,meanwhile the area of the cross section is reduced,i.e.,the weight of the material is decreased.展开更多
Geopolitically Kengtung region was located in a most strategic place in Myanmar. It shares borders with China on the north and Thailand on the east. Kengtung is a place which forms a significant historical site in the...Geopolitically Kengtung region was located in a most strategic place in Myanmar. It shares borders with China on the north and Thailand on the east. Kengtung is a place which forms a significant historical site in the easternmost part of Myanmar. From the geopolitical point of view, the region was located in a most strategic place. Its situation forced to safeguard the region. The town lies on a critical point of Myanmar’s defences. The restriction of exacting money as a yearly tribute did not concern for Kengtung. The tradition of paying homage was appeased to the King. The ruling Sawbwa which achieved the valuable return presents of the Burmese King. Kengtung came in the first class, and was the most important of the Myanmar’s possessions east of the Thanlwin River. Its position may be roughly judged by the tribute paid to the King and the contigent it was bound to supply to the royal army. Therefore, Kengtung was very important for the security of Myanmar’s eastern frontier during the Konbaung period. It was like a small Union within an Empire together with multinational races of Myanmar. A good deed of past events blanket over the town till today.展开更多
This paper took Yanyi Wei for example to explore the architectural culture of Hakka walled vil ages in Gannan, including clan culture, defense culture, sacrificial culture, and feng shui culture. It pointed out that t...This paper took Yanyi Wei for example to explore the architectural culture of Hakka walled vil ages in Gannan, including clan culture, defense culture, sacrificial culture, and feng shui culture. It pointed out that there exist problems in Yanyi Wei, such as the disharmony between newly established houses and original buildings, the lack of proper maintenance, and the lack of heirs of walled village culture, and proposed reasonable suggestions about architectural conservation and cultural heritage.展开更多
To keep eddy currents at a tolerable level,thin-walled stainless steel vacuum chambers with wall thickness of 0.3 mm are needed in HAIF BRing magnets.To withstand atmospheric pressure the thin-walled vacuum chambers a...To keep eddy currents at a tolerable level,thin-walled stainless steel vacuum chambers with wall thickness of 0.3 mm are needed in HAIF BRing magnets.To withstand atmospheric pressure the thin-walled vacuum chambers are supported by ribs which is parallel to the magnetic field lines.In order to obtain the extremely high vacuum(XHV),the chambers have to be bakeable to 220-300℃.According to a given design requirement,the in-situ bake-out scheme of XHV thin-walled chambers with a narrow magnetic gap was studied,where the temperature of surrounding magnetic elements is strictly controlled to below 80℃.展开更多
By foaming and carbonization processes under atmospheric pressure, a novel thin-walled carbon foam with developed foam structure was successfully prepared from loose medium component(LMC) separated from raw coal by ex...By foaming and carbonization processes under atmospheric pressure, a novel thin-walled carbon foam with developed foam structure was successfully prepared from loose medium component(LMC) separated from raw coal by extraction and back-extraction method. The influences of foaming time, carbonization time, and micromolecule content on foam structure were investigated by scanning electron microscope and mercury injection data. Moreover, foaming mechanism of LMC was analyzed and expounded. The results showed that spherical pores and uniform ultrathin pore walls constitute threedimensional foam structure of carbon foam and foam structure is developed with well connectivity.The effects of foaming time, carbonization time, and micromolecule content on foam structure are significant. Especially, average pore diameters of carbon foams prepared from the extracts of LMC are much smaller. With the rise of extraction rate, average pore diameter decreases and pore size distribution is more concentrated on the aperture section of 0–10 μm.展开更多
For efficient solar energy conversion,the morphology engineering of hollow graphitic carbon nitride(gC3 N4)is one of the promising approachs benefiting from abundant exposed active sites and short photocarrier transpo...For efficient solar energy conversion,the morphology engineering of hollow graphitic carbon nitride(gC3 N4)is one of the promising approachs benefiting from abundant exposed active sites and short photocarrier transport distances,but is difficult to control on account of easy structural collapse.Herein,a facile supramolecular electrostatic self-assembly strategy has been developed for the first time to fabricate mesoporous thin-walled g-C3N4 microtubes(mtw-CNT)with shell thickness of ca.13 nm.The morphological control of g-C3N4 enhances specific surface area by 12 times,induces stronger optical absorption,widens bandgap by 0.18 e V,improves photocurrent density by 2.5 times,and prolongs lifetimes of charge carriers from bulk to surface,compared with those of bulk g-C3N4.As a consequence,the transformed g-C3N4 exhibits the optimum photocatalytic H2-production rate of 3.99 mmol·h^-1·g^-1(λ>420 nm)with remarkable apparent quantum efficiency of 8.7%(λ=420±15 nm)and long-term stability.Moreover,mtw-CNT also achieves high photocatalytic CO2-to-CO selectivity of 96%(λ>420 nm),much better than those on the most previously reported porous g-C3N4 photocatalysts prepared by the conventional hard-templating and soft-templating methods.展开更多
A dynamical moving pressure structural numerical calculation model using the internal ballistics calculation pressure-time results was constituted and the vicinity of the internal ballistics and quasiinternal ballisti...A dynamical moving pressure structural numerical calculation model using the internal ballistics calculation pressure-time results was constituted and the vicinity of the internal ballistics and quasiinternal ballistics structural model was checked. The Von Mises stresses obtained by the dynamical structural numerical model calculations and the Von Mises stresses calculated from the shot test strain measurements were compared. The difference for the worse case was 20% and for the best case was 0.1%.Furthermore, the model gave better agreement for the higher charge masses. The numerical structural quasi-internal ballistics computation model created was verified for the top charge mass which represents the highest stress condition and used in a gun barrel design.展开更多
Mitigation of blast pressure using water in a walled container was evaluated. A PETN (pentaerythritol tetranitrate) pellet of 1.4 g near the model wall was detonated on a steel plate. A water-filled container was pl...Mitigation of blast pressure using water in a walled container was evaluated. A PETN (pentaerythritol tetranitrate) pellet of 1.4 g near the model wall was detonated on a steel plate. A water-filled container was placed between the explosive and the wall. The pressure histories at six points, which corresponded to Hopkinson scaled distance of from 3.6 m·kg^-1/3 to 21.7 m·kg^-1/3 were evaluated along with dependence of mitigation effects on the amount of water and the position of the container. The presence of the water and the wall mitigated the peak overpressure near the explosion points and the positive impulse along all points. The mitigation effect was equivalent to 20-30% reduction of explosive weight based on discussion of the equivalent ratio. The presence of the water along the wall (not very close to the explosive) also mitigated the blast pressure.展开更多
Computer model is developed for non-steady and steady-state process of thin-walled tube extension by the rigid punch with curved profile. Rigid-plastic membrane shell theory with quadratic yield criterion is used. Tub...Computer model is developed for non-steady and steady-state process of thin-walled tube extension by the rigid punch with curved profile. Rigid-plastic membrane shell theory with quadratic yield criterion is used. Tube material normal anisotropy, work hardening, wall thickness variation and friction effects are considered. FORTRAN programs of the model predict distributions of the thickness, meridian stress, yield stress and pressure along curved generator of deformed tube and the tube extension force versus punch displacement relation. Model predictions are correlated with experimental data.展开更多
基金supported by the foundation of“Cold area new energy service engineering laboratory battery pack comprehensive test system”from Jilin Provincial Development and Reform Commission(2020C021-6)the National Natural Science Foundation of China(NNSFC,No.52371109).
文摘In order to effectively reduce energy consumption and increase range mile,new energy vehicles represented by Tesla have greatly aroused the application of integrated magnesium(Mg)alloy die casting technology in automobiles.Previously,the application of Mg alloys in automobiles,especially in automotive cockpit components,is quite extensive,while it has almost disappeared for a period of time due to its relatively high cost,causing a certain degree of information loss in the application technology of Mg alloy parts in automobiles.The rapid development of automotive technology has led to a higher requirement for the automotive components compared with those traditional one.Therefore,whatever the components themselves,or the Mg alloy materials and die casting process have to face an increasing challenge,needing to be upgraded.In addition,owing to its high integration characteristics,the application of Mg alloy die casting technology in large-sized and thin-walled automotive parts has inherent advantages and needs to be expanded urgently.Indeed,it necessitates exploring advance Mg alloys and new product structures and optimizing die casting processes.This article summarizes and analyzes the development status of thin-walled and large-sized die casting Mg alloy parts in passenger car cockpit and corresponding material selection methods,die casting processes as well as mold design techniques.Furthermore,this work will aid researchers in establishing a comprehensive understanding of the manufacture of thin-walled and large-sized die casting Mg alloy parts in automobile cockpit.It will also assist them in developing new Mg alloys with improved comprehensive performance and new processes to meet the high requirements for die casting automotive components.
文摘Aspects of the general Vlasov theory are examined separately as applied to a thin-walled channel section cantilever beam under free-end end loading. In particular, the flexural bending and shear that arise under transverse shear and axial torsional loading are each considered theoretically. These analyses involve the location of the shear centre at which transverse shear forces when applied do not produce torsion. This centre, when taken to be coincident with the centre of twist implies an equivalent reciprocal behaviour. That is, an axial torsion applied concentric with the shear centre will twist but not bend the beam. The respective bending and shear stress conversions are derived for each action applied to three aluminium alloy extruded channel sections mounted as cantilevers with a horizontal principal axis of symmetry. Bending and shear are considered more generally for other thin-walled sections when the transverse loading axes at the shear centre are not parallel to the section = s centroidal axes of principal second moments of area. The fixing at one end of the cantilever modifies the St Venant free angular twist and the free warping displacement. It is shown from the Wagner-Kappus torsion theory how the end constrained warping generates an axial stress distribution that varies with the length and across the cross-section for an axial torsion applied to the shear centre. It should be mentioned here for wider applications and validation of the Vlasov theory that attendant papers are to consider in detail bending and torsional loadings applied to other axes through each of the centroid and the web centre. Therein, both bending and twisting arise from transverse shear and axial torsion applied to each position being displaced from the shear centre. Here, the influence of the axis position upon the net axial and shear stress distributions is to be established. That is, the net axial stress from axial torsional loading is identified with the sum of axial stress due to bending and axial stress arising from constrained warping displacements at the fixing. The net shear stress distribution overlays the distributions from axial torsion and that from flexural shear under transverse loading. Both arise when transverse forces are displaced from the shear centre.
基金supported by the National Postdoctoral Program(2020M672782)National Natural Science Foundation of China(No.U1663225)+2 种基金Changjiang Scholars and Innovative Research Team in University(No.IRT15R52)National 111 project from the Ministry of Science and Technologythe Ministry of Education of China and the National Key R&D Program of China(No.2016YFA0202602)。
文摘Lithium-selenium(Li-Se)battery has attracted growing attention.Nevertheless,its practical application is still impeded by the shuttle effect of the formed polyselenides.Herein,we report in-situ hydrothermal weaving the three-dimensional(3 D)highly conductive hierarchically interconnected nanoporous web by threading microporous metal organic framework MIL-68(Al)crystals onto multi-walled carbon nanotubes(MWCNTs).Such 3 D hierarchically nanoporous web(3 D MIL-68(Al)@MWCNTs web)with a very high surface area,a large amount of micropores,electrical conductivity and elasticity strongly traps the soluble polyselenides during the electrochemical reaction and significantly facilitates lithium ion diffusion and electron transportation.Molecular dynamic calculation confirmed the strong affinity of MIL-68(Al)for the adsorption of polyselenides,quite suitable for Li-Se battery.Their hexahedral channels(1.56 nm)are more efficient for the confinement of polyselenides and for the diffusion of electrolytes compared to their smaller triangular channels(0.63 nm).All these excellent characteristics of 3 D MIL-68(Al)@MWCNTs web with suitable confinement of a large amount of selenium and the conductive linkage between MIL-68(Al)host by MWCNTs result in a high capacity of 453 m Ah/g at 0.2 C with 99.5%coulombic efficiency after 200 cycles with significantly improved cycle stability and rate performance.The 3 D MIL-68(Al)@MWCNTs web presents a good performance in Li-Se battery in term of the specific capacity and cycling stability and also in terms of rate performance compared with all the metal-organic framework(MOF)based or MOF derived porous carbons used in Li-Se battery.
文摘The inner hole parts played an oriented or supporting role in engineering machinery and equipment,which are prone to appear surface damages such as wear,strain and corrosion. The precise pulse plasma arc powder welding method is used for surface damage repairing of inner hole parts in this paper. The working principle and process of the technology are illustrated,and the microstructure and property of repairing layer by precise pulse plasma powder welding and CO2 gas shielded welding are tested and observed by microscope,micro hardness tester and X-ray residual stress tester etc. Results showed that the substrate deformation of thin-walled inner hole parts samples by precise pulse plasma powder welding is relatively small. The repair layer and substrate is metallurgical bonding,the transition zones( including fusion zone and heat affected zone) are relatively narrow and the welding quality is good. It showed that the thin-walled inner hole parts can be repaired by this technology and equipment.
文摘The newly designed vacuum differential pressure casting (VDPC) unit was introduced, by which the capabilityof the VDPC process to produce thin-walled complicated Al-alloy castings, that are free from oxides, gas pore andshrinkage cavity and thus enhance overall part quality, was studied. Experimental results were compared with those oftraditional gravity pouring and vacuum suction casting. The first series of experiments were focused on investigating thecastability of thin section Al-alloy casting. In the second series of experiments the metallographic evidence, castingstrength and soundness were examined. Finally, case studies of very interesting thin walled complicated casting applicationswere described. The advantages of the described technique have made possible to produce thin walled complicatedAl-alloy casting (up to a section thickness of 1 mm), which is not practical for gravity pouring and vacuum suction casting.
文摘The paper deals with the application of multiwall carbon nanotubes(CNTs) to the adsorption of dyes from wastewater. Textile dyes are dangerous and diffused pollutant in wastewater, and the paper results confirmed the good adsorption ability of CNTs, with respect to classic active carbon, even for different dye types. The effect of surface treatments of CNTs was primarily investigated, revealing that neither the presence of residual catalyst nor common surface treatment(oxidation) affects the CNT's performances. Therefore less expensive nonpurified CNTs were assessed as good and economically convenient alternative for the process. In order to gain in generality in adsorption kinetic modelling, the parameters of the "best fitting" pseudo-second order model have been correlated to the main process variables(the dye initial concentration and the specific mass of CNTs.) setting-up a predictive kinetic model useful design new application of these materials in currently operating industrial operations for adsorption. In addition, isothermal data were used to screen all the relevant adsorption isotherms models and the Temkin model was confirmed as the more effective to accurately fit equilibrium data for any of the considered different dye types.
文摘The spinning deformation of thin walled tube in necking process is simulated with a dynamic explicit FEM program,LS DYNA3D and the distributions of Cauchy strains and thickness are analyzed through time history to achieve a good understanding of the deformation in necking process by spinning and the numerical simulation results are in good agreement with the test results.
基金The project supported by the National Natural Science Foundation of China (19932030)
文摘In the present paper, a series of hierarchical warping functions is developed to analyze the static and dynamic problems of thin walled composite laminated helicopter rotors composed of several layers with single closed cell. This method is the development and extension of the traditional constrained warping theory of thin walled metallic beams, which had been proved very successful since 1940s. The warping distribution along the perimeter of each layer is expanded into a series of successively corrective warping functions with the traditional warping function caused by free torsion or free beading as the first term, and is assumed to be piecewise linear along the thickness direction of layers. The governing equations are derived based upon the variational principle of minimum potential energy for static analysis and Rayleigh Quotient for free vibration analysis. Then the hierarchical finite element method. is introduced to form a,. numerical algorithm. Both static and natural vibration problems of sample box beams axe analyzed with the present method to show the main mechanical behavior of the thin walled composite laminated helicopter rotor.
文摘A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the oxidation temperature was determined. The process included sonication, oxidation and acid washing steps. The purity and yield after purification were determined and estimated by TEM. Moreover, for the first time, a loop structure for CVD SWNTs has been observed.
基金Innovation Funded Project of Fujian Province,China(No.2015C0030)Natural Science Foundation of Guangdong Province,China(No.S2013020013855)
文摘A lumped parameter-rigid elastic coupled dynamic model of two-stage planetary gears for a hybrid car is established through the inter-stage coupled method,in which the supports of the ring gear of planet set Ⅱ are represented as an elastic foundation with radial and tangential uniform distributed stiffness,and the ring gear of planet set Ⅱ is modeled as an elastic continuum body. The natural frequencies based on the eigenvalue problem of dynamic model of planetary transmission are solved and the associated vibration modes are discussed. The rules are revealed which are the influences of the ring gear elastic supports stiffness and rim thickness on natural frequencies of planetary transmission. The theoretical analysis indicates that the vibration modes of planetary transmission with thin-walled ring gear on elastic supports are classified into seven types: Ⅰ/Ⅱ stage coupled rotational mode,Ⅰ stage translational mode,Ⅰ stage planet mode,Ⅱ stage translational mode,Ⅱ stage degenerate planet mode,Ⅱ stage distinct planet mode and purely ring gear mode. For each vibration mode, its properties are summarized. The numerical solutions show that the elastic supports stiffness and rim thickness of the ring gear of planet set Ⅱ have different influences on natural frequencies.
基金Supported by the State Key Fundamental Research Plan of China (No.G2000048010) and the Post Doctor Science Foundation of China.
文摘Density functional theory (DFT) is used to calculate adsorption of ethane molecules in single walled carbon nanotubes. A compari-son of DFT calculations and grand canonical ensemble Monte Carlo (GCMC) simulations is made first and the two methods are in good agree-ment. Adsorption isotherms and structures of ethane molecules inside the tubes have been studied by DFT for the nanotubes of diameters 0.954, 2.719 and 4.077 nm at 157 K and ambient temperature, 300 K. By using the grand potential, the positions of phase transitions are exactly lo-cated, and the effect of temperature and tube diameter on phase transitions and adsorption is discussed. We found that lowering temperature and increasing the pore size of several nanometer is preferable for the ethane adsorption when temperature is in the range of 157 K—300 K and op-erating pressure reaches several MPa. Layering transitions and capillary condensations are observed at 157 K in two larger pore diameters, while these phase transitions disappear or the hysteres is loops become very narrow at 300 K.
文摘According to the reliability of material strength,the optimal design for the cross sectional size of thin walled box beam was studied.Firstly the cross sectional size as design random variable was determined,then its stochastic nature was researched,with which the objective function is to seek the maximum reliability of the beam under given constraint conditions.This way is not the same as the conventional optimal design for the minimum weight of the material.With establishing the optimal objective,the reliability of the material under conditions of static and fatigue was considered.The corresponding calculated expressions are given.Normally the cross section sizes are fitted to the normal distribution,for the simplification of the design variable,the variation of the section size is assumed as a dependent variable proportional to the mean of the size.The way is different not only with the conventional optimal design but also with the common reliability design.The maximum reliability of material is obtained,meanwhile the area of the cross section is reduced,i.e.,the weight of the material is decreased.
文摘Geopolitically Kengtung region was located in a most strategic place in Myanmar. It shares borders with China on the north and Thailand on the east. Kengtung is a place which forms a significant historical site in the easternmost part of Myanmar. From the geopolitical point of view, the region was located in a most strategic place. Its situation forced to safeguard the region. The town lies on a critical point of Myanmar’s defences. The restriction of exacting money as a yearly tribute did not concern for Kengtung. The tradition of paying homage was appeased to the King. The ruling Sawbwa which achieved the valuable return presents of the Burmese King. Kengtung came in the first class, and was the most important of the Myanmar’s possessions east of the Thanlwin River. Its position may be roughly judged by the tribute paid to the King and the contigent it was bound to supply to the royal army. Therefore, Kengtung was very important for the security of Myanmar’s eastern frontier during the Konbaung period. It was like a small Union within an Empire together with multinational races of Myanmar. A good deed of past events blanket over the town till today.
文摘This paper took Yanyi Wei for example to explore the architectural culture of Hakka walled vil ages in Gannan, including clan culture, defense culture, sacrificial culture, and feng shui culture. It pointed out that there exist problems in Yanyi Wei, such as the disharmony between newly established houses and original buildings, the lack of proper maintenance, and the lack of heirs of walled village culture, and proposed reasonable suggestions about architectural conservation and cultural heritage.
文摘To keep eddy currents at a tolerable level,thin-walled stainless steel vacuum chambers with wall thickness of 0.3 mm are needed in HAIF BRing magnets.To withstand atmospheric pressure the thin-walled vacuum chambers are supported by ribs which is parallel to the magnetic field lines.In order to obtain the extremely high vacuum(XHV),the chambers have to be bakeable to 220-300℃.According to a given design requirement,the in-situ bake-out scheme of XHV thin-walled chambers with a narrow magnetic gap was studied,where the temperature of surrounding magnetic elements is strictly controlled to below 80℃.
基金supported by the National Natural Science Foundation of China (Nos. 51274201 and 51674260)the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20130095110006)
文摘By foaming and carbonization processes under atmospheric pressure, a novel thin-walled carbon foam with developed foam structure was successfully prepared from loose medium component(LMC) separated from raw coal by extraction and back-extraction method. The influences of foaming time, carbonization time, and micromolecule content on foam structure were investigated by scanning electron microscope and mercury injection data. Moreover, foaming mechanism of LMC was analyzed and expounded. The results showed that spherical pores and uniform ultrathin pore walls constitute threedimensional foam structure of carbon foam and foam structure is developed with well connectivity.The effects of foaming time, carbonization time, and micromolecule content on foam structure are significant. Especially, average pore diameters of carbon foams prepared from the extracts of LMC are much smaller. With the rise of extraction rate, average pore diameter decreases and pore size distribution is more concentrated on the aperture section of 0–10 μm.
基金financially supported by the National Natural Science Foundation of China(21902051)the Natural Science Foundation of Fujian Province(2017J01014 and 2019J05090)the Graphene Power and Composite Research Center of Fujian Province(2017H2001)。
文摘For efficient solar energy conversion,the morphology engineering of hollow graphitic carbon nitride(gC3 N4)is one of the promising approachs benefiting from abundant exposed active sites and short photocarrier transport distances,but is difficult to control on account of easy structural collapse.Herein,a facile supramolecular electrostatic self-assembly strategy has been developed for the first time to fabricate mesoporous thin-walled g-C3N4 microtubes(mtw-CNT)with shell thickness of ca.13 nm.The morphological control of g-C3N4 enhances specific surface area by 12 times,induces stronger optical absorption,widens bandgap by 0.18 e V,improves photocurrent density by 2.5 times,and prolongs lifetimes of charge carriers from bulk to surface,compared with those of bulk g-C3N4.As a consequence,the transformed g-C3N4 exhibits the optimum photocatalytic H2-production rate of 3.99 mmol·h^-1·g^-1(λ>420 nm)with remarkable apparent quantum efficiency of 8.7%(λ=420±15 nm)and long-term stability.Moreover,mtw-CNT also achieves high photocatalytic CO2-to-CO selectivity of 96%(λ>420 nm),much better than those on the most previously reported porous g-C3N4 photocatalysts prepared by the conventional hard-templating and soft-templating methods.
基金Ministry of Science, Industry, and Technology which supported this project under the Industrial Thesis Support Program
文摘A dynamical moving pressure structural numerical calculation model using the internal ballistics calculation pressure-time results was constituted and the vicinity of the internal ballistics and quasiinternal ballistics structural model was checked. The Von Mises stresses obtained by the dynamical structural numerical model calculations and the Von Mises stresses calculated from the shot test strain measurements were compared. The difference for the worse case was 20% and for the best case was 0.1%.Furthermore, the model gave better agreement for the higher charge masses. The numerical structural quasi-internal ballistics computation model created was verified for the top charge mass which represents the highest stress condition and used in a gun barrel design.
文摘Mitigation of blast pressure using water in a walled container was evaluated. A PETN (pentaerythritol tetranitrate) pellet of 1.4 g near the model wall was detonated on a steel plate. A water-filled container was placed between the explosive and the wall. The pressure histories at six points, which corresponded to Hopkinson scaled distance of from 3.6 m·kg^-1/3 to 21.7 m·kg^-1/3 were evaluated along with dependence of mitigation effects on the amount of water and the position of the container. The presence of the water and the wall mitigated the peak overpressure near the explosion points and the positive impulse along all points. The mitigation effect was equivalent to 20-30% reduction of explosive weight based on discussion of the equivalent ratio. The presence of the water along the wall (not very close to the explosive) also mitigated the blast pressure.
文摘Computer model is developed for non-steady and steady-state process of thin-walled tube extension by the rigid punch with curved profile. Rigid-plastic membrane shell theory with quadratic yield criterion is used. Tube material normal anisotropy, work hardening, wall thickness variation and friction effects are considered. FORTRAN programs of the model predict distributions of the thickness, meridian stress, yield stress and pressure along curved generator of deformed tube and the tube extension force versus punch displacement relation. Model predictions are correlated with experimental data.