Artificially cemented soils have been widely used as filling materials in highway and railway construction.The shear strength evolution of filling materials upon moist variation can determine the stability of subgrade...Artificially cemented soils have been widely used as filling materials in highway and railway construction.The shear strength evolution of filling materials upon moist variation can determine the stability of subgrade and embankments.This study conducted water retention tests,MIP tests,and multi-stage triaxial shear tests on cement-treated granite residual soil(GRS)to determine its water retention curve(WRC)upon free drying,pore structure,and peak shear strength qf,respectively.The water retention behavior and shear strength evolution upon free drying were modeled based on the dual-porosity structure of cement-treated GRS and the effective stress principle,respectively.Results show that the drying-WRC is bimodal and higher cement dosage yields a more severe decrease in the water retention capacity within a specific suction range.For a given confining pressure,the peak shear strength qf increased with increasing cement dosage or suction value s.The peak shear strength qf also solely depends on the suction value in the peak stress state.In addition,the cement-treated GRS has a bimodal pore size distribution curve,and its macro-and micro-void ratios remain almost unchanged after free drying.The bimodal drying-WRC of the cement-treated GRS can be modeled by differentiating the water retention mechanisms in macro-and micro-pores.Moreover,using the macro-pore degree of saturation as the effective stress parameterχ=S_(rM),the q_(f)–p′_(f)relationship(where p′_(f)is the effective mean pressure at failure)under various suction and stress conditions can be unified,and the q_(f)–s relationships at various net confining pressuresσ_(3),net can be well reproduced.These findings can help design subgrade and embankments constructed by artificially cemented GRS and assess their safe operation upon climate change.展开更多
Many empirical models have been developed to describe the soil water retention curve (SWRC). In this study, a fractal model for SWRC was derived with a specially constructed Menger sponge to describe the fractal scali...Many empirical models have been developed to describe the soil water retention curve (SWRC). In this study, a fractal model for SWRC was derived with a specially constructed Menger sponge to describe the fractal scaling behavior of soil; relationships were established among the fractal dimension of SWRC, the fractal dimension of soil mass, and soil texture; and the model was used to estimate SWRC with the estimated results being compared to experimental data for verification. The derived fractal model was in a power-law form, similar to the Brooks-Corey and Campbell empirical functions. Experimental data of particle size distribution (PSD), texture, and soil water retention for 10 soils collected at different places in China were used to estimate the fractal dimension of SWRC and the mass fractal dimension. The fractal dimension of SWRC and the mass fractal dimension were linearly related. Also, both of the fractal dimensions were dependent on soil texture, i.e., clay and sand contents. Expressions were proposed to quantify the relationships. Based on the relationships, four methods were used to determine the fractal dimension of SWRC and the model was applied to estimate soil water content at a wide range of tension values. The estimated results compared well with the measured data having relative errors less than 10% for over 60% of the measurements. Thus, this model, estimating the fractal dimension using soil textural data, offered an alternative for predicting SWRC.展开更多
The runoff generated from mountainous regions is recognized as the main water source for inland river basins in arid environments. Thus, the mechanisms by which catchments retain water in soils are to be understood. T...The runoff generated from mountainous regions is recognized as the main water source for inland river basins in arid environments. Thus, the mechanisms by which catchments retain water in soils are to be understood. The water storage capacity of soil depends on its depth and capacity to retain water under gravita- tional drainage and evapotranspiration. The latter can be studied through soil water retention curve (SWRC), which is closely related to soil properties such as texture, bulk density, porosity, soil organic carbon conteMt, and so on. The present study represented SWRCs using HYDRUS-1D. In the present study, we measured pl^ysical and hydraulic properties of soil samples collected from Sabina przewalskii forest (south-facing slope with highest solar radiation), shrubs (west-facing slope with medium radiation), and Picea crassifolia forest (north-facing slope with lowest radiation), and analyzed the differences in soil water storage capacity of these soil samples. Soil water content of those three vegetation covers were also measured to validate the soil water storage capacity and to analyze the relationship between soil organic matter content and soil water content. Statistical analysis showed that different vegetation covers could lead to different soil bulk densities and differences in soil water retention on the three slope aspects. Sand content, porosity, and organic carbon content of the P. crassifolia forest were rela- tively greater compared with those of the S. przewalskii forest and shrubs. However, silt content and soil bulk density were relatively smaller than those in the S. przewalskii forest and shrubs. In addition, there was a sig- nificant linear positive relationship between averaged soil water content and soil organic matter content (P〈0.0001). However, this relationship is not significant in the P. crassifolia forest. As depicted in the SWRCs, the water storage capacity of the soil was 39.14% and 37.38% higher in the P. crassifolia forest than in the S. przewalskii forest and shrubs, respectively, at a similar soil depth.展开更多
The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model pa...The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model parameter m from the fractal dimension. We compared two approaches previously proposed by van Genuchten and Lenhard et al. for estimating m from the pore size distribution index of the Brooks and Corey (BC) model. In both approaches we used a relationship between the pore size distribution index of the BC model and the fractal dimension of the SWRC. A dataset containing 75 samples from the UNSODA unsaturated soil hydraulic database was used to evaluate the two approaches. The statistical parameters showed that the approach by Lenhard et al. provided better estimates of the parameter m. Another dataset containing 72 samples from the literature was used to validate Lenhard's approach in which the SWRC fractal dimension was estimated from the clay content. The estimated SWRC of the second dataset was compared with those obtained with the Rosetta model using sand, silt, and clay contents. Root mean square error values of the proposed fractal approach and Rosetta were 0.081 and 0.136, respectively, indicating that the proposed fractal approach performed better than the Rosetta model.展开更多
Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics frompartic...Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics fromparticle-size distribution data. Predictive capabilities of three fractal models, i.e, Tyler-Wheatcraft model,Rieu-Sposito model, and Brooks-Corey model, were fully evaluated in this work using experimental datafrom an international database and literature. Particle-size distribution data were firstly interpolated into20 classes using a van Genuchten-type equation. Fractal dimensions of the tortuous pore wall and the poresurface were then calculated from the detailed particle-size distribution and incorporated as a parameter infractal water retention models. Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressurehead ranges. Tyler-Wheatcraft and Brooks-Corey models led to reasonable agreements for both coarse- andmedium-textured soils, while the latter showed applicability to a broader texture range. In contrast, Rieu-Sposito model was more suitable for fine-textured soils. Fractal models produced a better estimation of watercontents at low pressure heads than at high pressure heads.展开更多
Comprehensive assessments of ecosystem services in environments under the influences of human activities and climate change are critical for sustainable regional ecosystem management. Therefore,integrated interdiscipl...Comprehensive assessments of ecosystem services in environments under the influences of human activities and climate change are critical for sustainable regional ecosystem management. Therefore,integrated interdisciplinary modelling has become a major focus of ecosystem service assessment. In this study, we established a model that integrates land use/cover change(LUCC), climate change, and water retention services to evaluate the spatial and temporal variations of water retention services in the Loess Plateau of China in the historical period(2000–2015) and in the future(2020–2050). An improved Markov-Cellular Automata(Markov-CA) model was used to simulate land use/land cover patterns, and ArcGIS 10.2 software was used to simulate and assess water retention services from 2000 to 2050 under six combined scenarios, including three land use/land cover scenarios(historical scenario(HS), ecological protection scenario(EPS), and urban expansion scenario(UES)) and two climate change scenarios(RCP4.5 and RCP8.5, where RCP is the representative concentration pathway). LUCCs in the historical period(2000–2015) and in the future(2020–2050) are dominated by transformations among agricultural land, urban land and grassland. Urban land under UES increased significantly by 0.63×10^(3) km^(2)/a, which was higher than the increase of urban land under HS and EPS. In the Loess Plateau, water yield decreased by 17.20×10^(6) mm and water retention increased by 0.09×10^(6) mm in the historical period(2000–2015),especially in the Interior drainage zone and its surrounding areas. In the future(2020–2050), the pixel means of water yield is higher under RCP4.5 scenario(96.63 mm) than under RCP8.5 scenario(95.46mm), and the pixel means of water retention is higher under RCP4.5 scenario(1.95 mm) than under RCP8.5 scenario(1.38 mm). RCP4.5-EPS shows the highest total water retention capacity on the plateau scale among the six combined scenarios, with the value of 1.27×10^(6) mm. Ecological restoration projects in the Loess Plateau have enhanced soil and water retention. However, more attention needs to be paid not only to the simultaneous increase in water retention services and evapotranspiration but also to the type and layout of restored vegetation. Furthermore, urbanization needs to be controlled to prevent uncontrollable LUCCs and climate change. Our findings provide reference data for the regional water and land resources management and the sustainable development of socio-ecological systems in the Loess Plateau under LUCC and climate change scenarios.展开更多
Biochar has been used as an environment-friendly enhancer to improve the hydraulic properties(e.g.suction and water retention)of soil.However,variations in densities alter the properties of the soil ebiochar mix.Such ...Biochar has been used as an environment-friendly enhancer to improve the hydraulic properties(e.g.suction and water retention)of soil.However,variations in densities alter the properties of the soil ebiochar mix.Such density variations are observed in agriculture(loosely compacted)and engineering(densely compacted)applications.The influence of biochar amendment on gas permeability of soil has been barely investigated,especially for soil with different densities.The major objective of this study is to investigate the water retention capacity,and gas permeability of biochar-amended soil(BAS)with different biochar contents under varying degree of compaction(DOC)conditions.In-house produced novel biochar was mixed with the soil at different amendment rates(i.e.biochar contents of 0%,5%and 10%).All BAS samples were compacted at three DOCs(65%,80%and 95%)in polyvinyl chloride(PVC)tubes.Each soil column was subjected to dryingewetting cycles,during which soil suction,water content,and gas permeability were measured.A simplified theoretical framework for estimating the void ratio of BAS was proposed.The experimental results reveal that the addition of biochar significantly decreased gas permeability kg as compared with that of bare soil(BS).However,the addition of 5%biochar is found to be optimum in decreasing kg with an increase of DOC(i.e.k_(g,65%)>k_(g,80%)>k_(g,95%))at a relatively low suction range(<200 kPa)because both biochar and compaction treatment reduce the connected pores.展开更多
Targeting the problem of available water conservation in sand fixation, the sand-fixing and grass-planting materials were prepared with clay modified by emulsifying vegetable waxes and octylphenol polyoxyethylene eth...Targeting the problem of available water conservation in sand fixation, the sand-fixing and grass-planting materials were prepared with clay modified by emulsifying vegetable waxes and octylphenol polyoxyethylene ether (OP4). The water retention property was studied in simulating desertification environmental climate and the materials were characterized by means of UV-Vis, SEM, FTIR, XRD and TGA measurements. The experimental result showed that the materials had excellent water retention properties, due to that vegetable waxes adhered evenly to clay particle surfaces, made the clay pores changing from hydrophilic to hydrophobic and so inhibited the water evaporation. Grass-planting experiment showed that, with reasonable mass ratio of clay, vegetable waxes and surfactant, the materials not only inhibited water evaporation but also maintained sound air permeability so shat the germination rate and survival rate of grass were significantly improved.展开更多
The durability of silty clay embankments is partially controlled by the moisture migration, which depends on soil hydraulic properties. This paper presents an experimental study of hydraulic properties of compacted bi...The durability of silty clay embankments is partially controlled by the moisture migration, which depends on soil hydraulic properties. This paper presents an experimental study of hydraulic properties of compacted binary silty clay. Specimens with different mixing ratios and dry densities were prepared. Scanning electron microscopy and mercury intrusion porosimetry were used to characterise the microstructure of silty clay. Thereafter, falling-head permeability tests and water retention tests were conducted to study the permeability and water retention property, respectively. The results demonstrate that clay particles are dispersed and show preferred arrangements after compaction when the clay content is 100%. As the clay content decreases, the arrangement of clay particles is gradually disturbed because of the existence of silt particles, causing the formation of large pores around silt particles. When the dry density increases, the pores around silt particles significantly decrease. Moreover, the permeability of silty clay decreases but the water retention capacity increases with increasing clay content and dry density. This is because the silty clay with larger clay content and dry density has fewer large pores, which greatly restrains the flow of water. Both the permeability and water retention property of silty clay can be predicted from pore size distribution parameters.展开更多
CDW (construction and demolition wastes) present a high amount of aggregate chips covered with mortar. This results in high absorption of water with a direct impact in particle breakage or disaggregation. It is supp...CDW (construction and demolition wastes) present a high amount of aggregate chips covered with mortar. This results in high absorption of water with a direct impact in particle breakage or disaggregation. It is supposed that intra particle suction plays an important role in this phenomenon. However, WRCs (water retention curves) of CDW are not well understood. In this work, the WRCs of dynamically compacted specimens of aggregates recycled from the demolition of the National Stadium in Brasilia are studied. The objective of this study is to obtain WRCs of the recycled materials by using the pressure plate and filter paper methods. The breaking effect during compaction is quantified from the grain size distribution curves. The particle breakage during compaction increases when the energy is augmented. The results from the WRCs were incorporated into a pore size capillary model to predict pore size distribution.展开更多
Aiming at the problem of available water conservation in desertification ecological restoration, we prepared the water retention materials with montmorillonite(MMT) modified by Castor Oil Polyoxyethylene Ether(10)...Aiming at the problem of available water conservation in desertification ecological restoration, we prepared the water retention materials with montmorillonite(MMT) modified by Castor Oil Polyoxyethylene Ether(10)(EL-10) emulsifying vegetable waxes. The water retention property was studied in simulated desertification climate, and the materials were analyzed and characterized by UV-Vis, SEM, FTIR and XRD measurements. Moreover, a UV carbon arc lamp was used to test the resistance to aging. The experimental results show that the emulsion has good dispersity. Both the water retention property and the aging resistance performance of the modified clay were excellent. The lamellar structure and chemical composition of MMT had no obvious changes before and after modification. The surfaces of clay particles were coated uniformly with modified MMT, so the loose clay particles were cemented together by vegetable waxes. Meanwhile, the original big hydrophilic pores between the clay particles turned into capillary hydrophobic pores. So the clay particles formed a bonding layer which could inhibit water evaporation. Grass-planting experiment showed that reasonable mass ratio of vegetable waxes and EL-10 was 1:18. The materials not only had great water retention property but also maintained sound air permeability so that the germination rate of grass seed significantly increased from 8% to 52%.展开更多
The importance of soil water retention characteristics in modelling the hydro-mechanical response of unsaturated soils has been well recognised by many investigators in recent years.Determination of strain-dependent s...The importance of soil water retention characteristics in modelling the hydro-mechanical response of unsaturated soils has been well recognised by many investigators in recent years.Determination of strain-dependent soil water retention curve(SWRC)is likely to be extraordinarily difficult.The first two authors have recently shown that SWRC can be computed from the gradation curve and the calculation result is consistent with the experimental results obtained from pressure plate tests.In this paper,based on a hypothesis related to change in the pore size distribution(POSD)due to volumetric strain of soil skeleton,a method to compute strain-dependent SWRC is presented.It is found that at initial degrees of saturation higher than 0.8,the influence of volumetric strain may be marginal whilst at initial degrees of saturation lower than 0.8,its influence is likely to be substantial.In all cases,the gradation curve of the soil affects the SWRC.展开更多
The goal of this study was to evaluate the water retention value (WRV) of a test solid substrate and a fungal cell in solid state fermentation (SSF). WRV is the ratio of the weight of water retained after centrifu...The goal of this study was to evaluate the water retention value (WRV) of a test solid substrate and a fungal cell in solid state fermentation (SSF). WRV is the ratio of the weight of water retained after centrifugation under specific conditions by a wet sample to the oven dry weight of the same sample. SSF refers to the microbial fermentation, which takes place in the absence or near absence of free water, thus being close to the natural environment. Many factors are involved in a successful SSF process. In addition to biological parameters, the SSF process is also dependent on physical factors such as WRV. A centrifugal technique has been modified and applied to the evaluation of WRV. Wheat bran, soybean hulls and rapeseed meal were used as model substrate. Aspergillus awamori and Aspergillus oryzae were used as model microorganism. Results revealed that the ability of wheat bran to retain water in the solid substrate is 56% higher than that of soybean hulls and rapeseed meal. In the term of fungal cell, the ability of A. oryzae to retain water in the cells was higher (73% higher) than that ofA. awamori. In addition, through oven method moisture content loss from A. awamori is 46% higher than that from A. oryzae during drying process. Nevertheless, it can be seen that A. oryzae is able to retain water content about 5 times higher than A. awamori. Through this results, we found that WRV varies depending on solid substrates and microorganisms. This initial information can be beneficial in the SSF process to be carried out.展开更多
In order to understand the origin, the extent and the space distribution of the seasonal anthropic pollution parameters in the water retention located in mountainous area thickly populated and which water resources is...In order to understand the origin, the extent and the space distribution of the seasonal anthropic pollution parameters in the water retention located in mountainous area thickly populated and which water resources is intended for the production of drinking water for serving a population of approximately 800,000 inhabitants, two sampling campaigns were carried out for the two seasons of the year known as the dry and rainy season. The samples were then conveyed and analyzed in laboratory. The parameters retained for this study were primarily the physicochemical parameters (pH, conductivity and temperature), measured in situ and second the major anthropic origins anions of (, , and ). The results of the study show that overall the anthropic pollution parameters undergo an important seasonal variation of their concentration between the dry and rainy periods although they remain high in any season compared to the quality standards of natural water of the European Union. Their space distribution within retention remains overall random and is not function of the seasons. However, surrounding areas of the retention and the discharge system of the seasonal rivers (Mayos) which feed it present in rainy season space distributions of concentrations in anions of anthropic origin enumerated above highest.展开更多
The unsatisfactory nutrient slow-release and water-retention performance of traditional biochar-based compound fertilizers(BCF)severely limit their practical application.Herein,a new type of slow-release fertilizer wi...The unsatisfactory nutrient slow-release and water-retention performance of traditional biochar-based compound fertilizers(BCF)severely limit their practical application.Herein,a new type of slow-release fertilizer with high water retention was fabricated via the incorporation of hydrotalcite and starch into BCF,named as HS-BCF.The waterretention and nutrient releasing performance of the prepared HS-BCF and related nutrient slow-release mechanism were investigated.The results showed that the incorporation of hydrotalcite and starch into BCF could increase the soil water-retention ratio by 5-10%points.The accumulated N,P,and K leaching amounts of HS-BCF in soil within 30 days were 49.4%,13.3%,and 87.4%of BCF at most,respectively.Kinetic analysis indicated that the release of nutrients from HS-BCF was attributed to the coupling of the diffusion-controlled and relaxation-controlled mechanism.Moreover,hydrotalcite could bind with P in HS-BCF,contributing to the enhanced durability of P in HS-BCF.Finally,pot experiments showed that the N-P-K utilization efficiencies of HS-BCF were all higher than those of BCF due to a better synchronization between the nutrient release of HS-BCF and the uptake of tomato plants.Overall,the study may provide a promising strategy for simultaneously improving the water-retention and slow-release performance of traditional biochar-based fertilizers.展开更多
Biochar has the potential to provide a multitude of benefits when used in soil remediation and increasing soil organic matter enrichment.Nevertheless,the intricated,hydrophobic pores and groups weaken its water-holdin...Biochar has the potential to provide a multitude of benefits when used in soil remediation and increasing soil organic matter enrichment.Nevertheless,the intricated,hydrophobic pores and groups weaken its water-holding capacity in dry,sandy soils in arid lands.In order to combat this issue,starch-carbon-based material(SB),sodium alginate-carbon-based material(SAB),and chitosan-carbon-based material(CB)have been successfully synthesized through the graft-polymerization of biochar(BC).A series of soil column simulations were used to scrutinize the microstructure of the carbon-based material and explore its water absorption properties and its effects on sandy soil water infiltration,water retention,and aggregation.The results indicated that SB,SAB,and CB achieved water maximum absorption rates of 155,188,and 172 g g^(−1),respectively.Considering their impact on sandy soils,SB,SAB,and CB lengthened infiltration times by 1920,3330,and 3880 min,respectively,whilst enhancing the water retention capabilities of the soil by 18%,25%,and 23%in comparison to solely adding BC.The utilization of these innovative materials notably encouraged the formation of sandy soil aggregates ranging from 2.0 to 0.25 mm,endowing the aggregates with enhanced structural stability.Findings from potting experiments suggested that all three carbonbased materials were conducive to the growth of soybean seeds.Thus,it is evident that the carbon-based materials have been fabricated with success,and they have great potential not only to significantly augment the water retention capacities and structural robustness of sandy soils in arid areas,but also to bolster the development of soil aggregates and crop growth.These materials possess significant application potential for enhancing the quality of sandy soils in arid and semi-arid regions.展开更多
The soil water retention curve is an important hydraulic function for the study of flow transport processes in unsaturated soils. The objective of this study was to develop a soil water retention function using a gene...The soil water retention curve is an important hydraulic function for the study of flow transport processes in unsaturated soils. The objective of this study was to develop a soil water retention function using a generalized fractal approach. The model exhibits asymmetry between the solid phase and pore phase, which is in marked contrast to the symmetry between phases present in a conventional fractal model. The retention function includes 4 parameters: the saturated water content θs, the air entry value ha, the fractal dimension Df, and an empirical parameter β, characterizing the complicated soil pore structures. Sixty one data sets, covering a wide range of soil structure and textural properties, were used to evaluate the applicability of the proposed soil water retention function. The retention function is shown to be a general model, which incorporates several existing retention models. The values of β/θs and (θs-θr )/β were used as indexes to quantify the relationships between the proposed retention function and the existing retention models. The proposed function fits all the data very well, whereas other tested models only match about 16%-48% of the soil retention data.展开更多
Assessment of soil water retention in arid region is an input required parameter in precision water management at large scale.Investigations were carried out in Tanta catchment in the middle Nile Delta,Egypt(30145 N,3...Assessment of soil water retention in arid region is an input required parameter in precision water management at large scale.Investigations were carried out in Tanta catchment in the middle Nile Delta,Egypt(30145 N,30155 E),where collecting soil samples covered different hydrological soil groups and land-uses.Based on the natural resource conservation service curve number model(NRCS-CN),CN approach was used to investigate the effect of spatio-temporal variations of different land-uses on soil water retention.Potential soil water retention from 1990 to 2015 was reduced by 118.1 m^(3) per hectare with decreasing cropland area.Urbanization encroachment from 1990 to 2015 was increased by 2.13%by decreasing cropland with 15.3%(5300 ha in 2015).This resulted in losing the potential soil water retention by 625,968.42 m^(3) water for the whole catchment area.Impact of land degradation was pronounced,where 2.65%,29.35%,and 1.11%of the initial crop land-use in 1990 were converted to bare soil,fallow,and urban area,respectively in 2015.Implementation of(S)value of the NRCS-CN model with GIS technique provides useful measure to identify land-use changes of potential water storage capacity at catchment scale.展开更多
The cellulose-based hydrogel has been widely applied for soil water retention and nutrient re-lease agents for several decades.Embedding the inorganic materials into hydrogels is an excellent strategy to improve the i...The cellulose-based hydrogel has been widely applied for soil water retention and nutrient re-lease agents for several decades.Embedding the inorganic materials into hydrogels is an excellent strategy to improve the inherent limits of the cellulose-based hydrogel.Notably,municipal sludge-derived hydrochar(HC)has reduced the environmental burden and offered a potential hydrogel carrier to control water-retention and nutrient-release.However,the above function for plant growth of hydrochar-embedded carboxymethyl cellulose-g-poly(acrylic acid)(CMC-g-PAA/HC)is unknown,and relevant reports are lacking.This study investigated the water retention,nutri-ent release behavior,and effect of germination and plant growth of CMC-g-PAA/HC hydrogel.Characterization results showed that HC was successfully incorporated into CMC-g-PAA/HC with 6.0%higher thermostability,7.2-21.0%lower swelling ratio(SR)in water,and substantial SR in phosphate solution(P-solution).The water loss rate of CMC-g-PAA/HC in P-solution or wa-ter owned a more significant temperature response(7.9-15.0 folds)than CMC-g-PAA(8.2-10.0 folds).Moreover,4.0%higher n value and more 18.5%released P for CMC-g-PAA/HC were also observed.These phenomena were due to restricting the polymer chains movement and the wa-ter molecules diffusion inside the hydrogels with HC.Phytotoxicity assessments showed that HC in CMC-g-PAA/HC could effectively alleviate the inhibition effects on rape germination retained with 78.3%germination vigor and 80.0%germination ratio,even dramatically improved plant growth to 28 d.The results of this study demonstrated a new route for developing eco-friendly CMC-g-PAA/HC hydrogel,advantageous as a water retention agent and nutrient carrier in arid and semiarid regions.展开更多
This study assessed the applicability of chitin nanocrystals prepared by 2,2,6,6-Tetramethyl-1-Piperidine-1-oxyl radical(TEMPO)-mediated oxidation in traditional papermaking coating color systems.The𝛼-chitin n...This study assessed the applicability of chitin nanocrystals prepared by 2,2,6,6-Tetramethyl-1-Piperidine-1-oxyl radical(TEMPO)-mediated oxidation in traditional papermaking coating color systems.The𝛼-chitin nanocrystals(CTNCs)with different carboxyl content,size,and morphology were prepared from crab shells by alkali pretreatment and TEMPO-mediated oxidation in the water at pH 10,and then the ratio of CTNCs to latex was applied to traditional coating color system to replace part of latex.The results showed that when the amount of NaClO added as co-oxidant in the oxidation was 15.0 mmol/g of chitin,the carboxyl content of alkali-pretreated CTNCs was up to 0.76 mmol/g.The amount of carboxyl groups presented a linear relation with the degree of individualization of nanocrystals and dispersion.When the ratio of latex to CTNCs was 90꞉10,the water retention value of the coating was 92%lower than that of the pure latex system,and the rheological property was better.The relationship between the addition amount of CTNCs and the surface strength and the coverage of coating layers were also studied,and results showed that when the ratio of latex to CTNCs was 95꞉5,the surface strength was the highest of 1.45 m/s,and the coverage of coating layers rate reached the highest of 78%.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.52379104,42202298)Joint fund of National Natural Science Foundation of China-Railway Corporation for basic research of high-speed railway (Grant No.U1934208).
文摘Artificially cemented soils have been widely used as filling materials in highway and railway construction.The shear strength evolution of filling materials upon moist variation can determine the stability of subgrade and embankments.This study conducted water retention tests,MIP tests,and multi-stage triaxial shear tests on cement-treated granite residual soil(GRS)to determine its water retention curve(WRC)upon free drying,pore structure,and peak shear strength qf,respectively.The water retention behavior and shear strength evolution upon free drying were modeled based on the dual-porosity structure of cement-treated GRS and the effective stress principle,respectively.Results show that the drying-WRC is bimodal and higher cement dosage yields a more severe decrease in the water retention capacity within a specific suction range.For a given confining pressure,the peak shear strength qf increased with increasing cement dosage or suction value s.The peak shear strength qf also solely depends on the suction value in the peak stress state.In addition,the cement-treated GRS has a bimodal pore size distribution curve,and its macro-and micro-void ratios remain almost unchanged after free drying.The bimodal drying-WRC of the cement-treated GRS can be modeled by differentiating the water retention mechanisms in macro-and micro-pores.Moreover,using the macro-pore degree of saturation as the effective stress parameterχ=S_(rM),the q_(f)–p′_(f)relationship(where p′_(f)is the effective mean pressure at failure)under various suction and stress conditions can be unified,and the q_(f)–s relationships at various net confining pressuresσ_(3),net can be well reproduced.These findings can help design subgrade and embankments constructed by artificially cemented GRS and assess their safe operation upon climate change.
基金Project supported by the National Natural Science Foundation of China (Nos. 50479011 and 50279025).
文摘Many empirical models have been developed to describe the soil water retention curve (SWRC). In this study, a fractal model for SWRC was derived with a specially constructed Menger sponge to describe the fractal scaling behavior of soil; relationships were established among the fractal dimension of SWRC, the fractal dimension of soil mass, and soil texture; and the model was used to estimate SWRC with the estimated results being compared to experimental data for verification. The derived fractal model was in a power-law form, similar to the Brooks-Corey and Campbell empirical functions. Experimental data of particle size distribution (PSD), texture, and soil water retention for 10 soils collected at different places in China were used to estimate the fractal dimension of SWRC and the mass fractal dimension. The fractal dimension of SWRC and the mass fractal dimension were linearly related. Also, both of the fractal dimensions were dependent on soil texture, i.e., clay and sand contents. Expressions were proposed to quantify the relationships. Based on the relationships, four methods were used to determine the fractal dimension of SWRC and the model was applied to estimate soil water content at a wide range of tension values. The estimated results compared well with the measured data having relative errors less than 10% for over 60% of the measurements. Thus, this model, estimating the fractal dimension using soil textural data, offered an alternative for predicting SWRC.
基金sponsored by the National Natural Science Foundation of China (91025015)
文摘The runoff generated from mountainous regions is recognized as the main water source for inland river basins in arid environments. Thus, the mechanisms by which catchments retain water in soils are to be understood. The water storage capacity of soil depends on its depth and capacity to retain water under gravita- tional drainage and evapotranspiration. The latter can be studied through soil water retention curve (SWRC), which is closely related to soil properties such as texture, bulk density, porosity, soil organic carbon conteMt, and so on. The present study represented SWRCs using HYDRUS-1D. In the present study, we measured pl^ysical and hydraulic properties of soil samples collected from Sabina przewalskii forest (south-facing slope with highest solar radiation), shrubs (west-facing slope with medium radiation), and Picea crassifolia forest (north-facing slope with lowest radiation), and analyzed the differences in soil water storage capacity of these soil samples. Soil water content of those three vegetation covers were also measured to validate the soil water storage capacity and to analyze the relationship between soil organic matter content and soil water content. Statistical analysis showed that different vegetation covers could lead to different soil bulk densities and differences in soil water retention on the three slope aspects. Sand content, porosity, and organic carbon content of the P. crassifolia forest were rela- tively greater compared with those of the S. przewalskii forest and shrubs. However, silt content and soil bulk density were relatively smaller than those in the S. przewalskii forest and shrubs. In addition, there was a sig- nificant linear positive relationship between averaged soil water content and soil organic matter content (P〈0.0001). However, this relationship is not significant in the P. crassifolia forest. As depicted in the SWRCs, the water storage capacity of the soil was 39.14% and 37.38% higher in the P. crassifolia forest than in the S. przewalskii forest and shrubs, respectively, at a similar soil depth.
基金Supported by the National Natural Science Foundation of China (Nos.50979106 and 50779067)
文摘The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model parameter m from the fractal dimension. We compared two approaches previously proposed by van Genuchten and Lenhard et al. for estimating m from the pore size distribution index of the Brooks and Corey (BC) model. In both approaches we used a relationship between the pore size distribution index of the BC model and the fractal dimension of the SWRC. A dataset containing 75 samples from the UNSODA unsaturated soil hydraulic database was used to evaluate the two approaches. The statistical parameters showed that the approach by Lenhard et al. provided better estimates of the parameter m. Another dataset containing 72 samples from the literature was used to validate Lenhard's approach in which the SWRC fractal dimension was estimated from the clay content. The estimated SWRC of the second dataset was compared with those obtained with the Rosetta model using sand, silt, and clay contents. Root mean square error values of the proposed fractal approach and Rosetta were 0.081 and 0.136, respectively, indicating that the proposed fractal approach performed better than the Rosetta model.
基金Project supported by the National Natural Science Foundation of China (No, 49971041), the National Key Basic Research Support Foundation (NKBRSF) of China (No. G1999011803) the Director Foundation of the Institute of Soil Science, CAS (No. ISSDF0004).
文摘Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics fromparticle-size distribution data. Predictive capabilities of three fractal models, i.e, Tyler-Wheatcraft model,Rieu-Sposito model, and Brooks-Corey model, were fully evaluated in this work using experimental datafrom an international database and literature. Particle-size distribution data were firstly interpolated into20 classes using a van Genuchten-type equation. Fractal dimensions of the tortuous pore wall and the poresurface were then calculated from the detailed particle-size distribution and incorporated as a parameter infractal water retention models. Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressurehead ranges. Tyler-Wheatcraft and Brooks-Corey models led to reasonable agreements for both coarse- andmedium-textured soils, while the latter showed applicability to a broader texture range. In contrast, Rieu-Sposito model was more suitable for fine-textured soils. Fractal models produced a better estimation of watercontents at low pressure heads than at high pressure heads.
基金supported by the State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau(A314021402–202110)the Science Foundation of Hubei Province,China(2021CFB295)the National Natural Science Foundation of China(42077451)。
文摘Comprehensive assessments of ecosystem services in environments under the influences of human activities and climate change are critical for sustainable regional ecosystem management. Therefore,integrated interdisciplinary modelling has become a major focus of ecosystem service assessment. In this study, we established a model that integrates land use/cover change(LUCC), climate change, and water retention services to evaluate the spatial and temporal variations of water retention services in the Loess Plateau of China in the historical period(2000–2015) and in the future(2020–2050). An improved Markov-Cellular Automata(Markov-CA) model was used to simulate land use/land cover patterns, and ArcGIS 10.2 software was used to simulate and assess water retention services from 2000 to 2050 under six combined scenarios, including three land use/land cover scenarios(historical scenario(HS), ecological protection scenario(EPS), and urban expansion scenario(UES)) and two climate change scenarios(RCP4.5 and RCP8.5, where RCP is the representative concentration pathway). LUCCs in the historical period(2000–2015) and in the future(2020–2050) are dominated by transformations among agricultural land, urban land and grassland. Urban land under UES increased significantly by 0.63×10^(3) km^(2)/a, which was higher than the increase of urban land under HS and EPS. In the Loess Plateau, water yield decreased by 17.20×10^(6) mm and water retention increased by 0.09×10^(6) mm in the historical period(2000–2015),especially in the Interior drainage zone and its surrounding areas. In the future(2020–2050), the pixel means of water yield is higher under RCP4.5 scenario(96.63 mm) than under RCP8.5 scenario(95.46mm), and the pixel means of water retention is higher under RCP4.5 scenario(1.95 mm) than under RCP8.5 scenario(1.38 mm). RCP4.5-EPS shows the highest total water retention capacity on the plateau scale among the six combined scenarios, with the value of 1.27×10^(6) mm. Ecological restoration projects in the Loess Plateau have enhanced soil and water retention. However, more attention needs to be paid not only to the simultaneous increase in water retention services and evapotranspiration but also to the type and layout of restored vegetation. Furthermore, urbanization needs to be controlled to prevent uncontrollable LUCCs and climate change. Our findings provide reference data for the regional water and land resources management and the sustainable development of socio-ecological systems in the Loess Plateau under LUCC and climate change scenarios.
基金The authors would like to acknowledge the National Natural Science Foundation of China(Grant No.41907252)Shantou University Scientific Research Fund(Grant No.NTF17007)
文摘Biochar has been used as an environment-friendly enhancer to improve the hydraulic properties(e.g.suction and water retention)of soil.However,variations in densities alter the properties of the soil ebiochar mix.Such density variations are observed in agriculture(loosely compacted)and engineering(densely compacted)applications.The influence of biochar amendment on gas permeability of soil has been barely investigated,especially for soil with different densities.The major objective of this study is to investigate the water retention capacity,and gas permeability of biochar-amended soil(BAS)with different biochar contents under varying degree of compaction(DOC)conditions.In-house produced novel biochar was mixed with the soil at different amendment rates(i.e.biochar contents of 0%,5%and 10%).All BAS samples were compacted at three DOCs(65%,80%and 95%)in polyvinyl chloride(PVC)tubes.Each soil column was subjected to dryingewetting cycles,during which soil suction,water content,and gas permeability were measured.A simplified theoretical framework for estimating the void ratio of BAS was proposed.The experimental results reveal that the addition of biochar significantly decreased gas permeability kg as compared with that of bare soil(BS).However,the addition of 5%biochar is found to be optimum in decreasing kg with an increase of DOC(i.e.k_(g,65%)>k_(g,80%)>k_(g,95%))at a relatively low suction range(<200 kPa)because both biochar and compaction treatment reduce the connected pores.
基金Funded by the National Natural Science Foundation of China(No.50772131)the Main Project of Ministry of Education of China(No.106086)the Fundamental Research Funds for the Central Universities of China University of Mining and Technology(Beijing)(No.2010YJ05)
文摘Targeting the problem of available water conservation in sand fixation, the sand-fixing and grass-planting materials were prepared with clay modified by emulsifying vegetable waxes and octylphenol polyoxyethylene ether (OP4). The water retention property was studied in simulating desertification environmental climate and the materials were characterized by means of UV-Vis, SEM, FTIR, XRD and TGA measurements. The experimental result showed that the materials had excellent water retention properties, due to that vegetable waxes adhered evenly to clay particle surfaces, made the clay pores changing from hydrophilic to hydrophobic and so inhibited the water evaporation. Grass-planting experiment showed that, with reasonable mass ratio of clay, vegetable waxes and surfactant, the materials not only inhibited water evaporation but also maintained sound air permeability so shat the germination rate and survival rate of grass were significantly improved.
基金Projects(51908069, 51908073, 51838001, 51878070) supported by the National Natural Science Foundation of ChinaProject(2019SK2171) supported by the Key Research and Development Program of Hunan Province, China+2 种基金Project(kfj190605) supported by the Open Fund of Engineering Laboratory of Spatial Information Technology of Highway Geological Disaster Early Warning in Hunan Province (Changsha University of Science & Technology),ChinaProject(2019IC04) supported by the Double First-Class Scientific Research International Cooperation Expansion Project of Changsha University of Science & Technology, ChinaProject(kq1905043) supported by the Training Program for Excellent Young Innovators of Changsha, China。
文摘The durability of silty clay embankments is partially controlled by the moisture migration, which depends on soil hydraulic properties. This paper presents an experimental study of hydraulic properties of compacted binary silty clay. Specimens with different mixing ratios and dry densities were prepared. Scanning electron microscopy and mercury intrusion porosimetry were used to characterise the microstructure of silty clay. Thereafter, falling-head permeability tests and water retention tests were conducted to study the permeability and water retention property, respectively. The results demonstrate that clay particles are dispersed and show preferred arrangements after compaction when the clay content is 100%. As the clay content decreases, the arrangement of clay particles is gradually disturbed because of the existence of silt particles, causing the formation of large pores around silt particles. When the dry density increases, the pores around silt particles significantly decrease. Moreover, the permeability of silty clay decreases but the water retention capacity increases with increasing clay content and dry density. This is because the silty clay with larger clay content and dry density has fewer large pores, which greatly restrains the flow of water. Both the permeability and water retention property of silty clay can be predicted from pore size distribution parameters.
文摘CDW (construction and demolition wastes) present a high amount of aggregate chips covered with mortar. This results in high absorption of water with a direct impact in particle breakage or disaggregation. It is supposed that intra particle suction plays an important role in this phenomenon. However, WRCs (water retention curves) of CDW are not well understood. In this work, the WRCs of dynamically compacted specimens of aggregates recycled from the demolition of the National Stadium in Brasilia are studied. The objective of this study is to obtain WRCs of the recycled materials by using the pressure plate and filter paper methods. The breaking effect during compaction is quantified from the grain size distribution curves. The particle breakage during compaction increases when the energy is augmented. The results from the WRCs were incorporated into a pore size capillary model to predict pore size distribution.
基金Funded by the National High-tech Research and Development Program of China(863 Program)(No.2001AA322100)the National Natural Science Foundation of China(No.50772131)+1 种基金the Main Project of Ministry of Education of China(No.106086)the Fundamental Research Funds for the Central Universities of China University of Mining and Technology(Beijing)(No.2012YJ05)
文摘Aiming at the problem of available water conservation in desertification ecological restoration, we prepared the water retention materials with montmorillonite(MMT) modified by Castor Oil Polyoxyethylene Ether(10)(EL-10) emulsifying vegetable waxes. The water retention property was studied in simulated desertification climate, and the materials were analyzed and characterized by UV-Vis, SEM, FTIR and XRD measurements. Moreover, a UV carbon arc lamp was used to test the resistance to aging. The experimental results show that the emulsion has good dispersity. Both the water retention property and the aging resistance performance of the modified clay were excellent. The lamellar structure and chemical composition of MMT had no obvious changes before and after modification. The surfaces of clay particles were coated uniformly with modified MMT, so the loose clay particles were cemented together by vegetable waxes. Meanwhile, the original big hydrophilic pores between the clay particles turned into capillary hydrophobic pores. So the clay particles formed a bonding layer which could inhibit water evaporation. Grass-planting experiment showed that reasonable mass ratio of vegetable waxes and EL-10 was 1:18. The materials not only had great water retention property but also maintained sound air permeability so that the germination rate of grass seed significantly increased from 8% to 52%.
文摘The importance of soil water retention characteristics in modelling the hydro-mechanical response of unsaturated soils has been well recognised by many investigators in recent years.Determination of strain-dependent soil water retention curve(SWRC)is likely to be extraordinarily difficult.The first two authors have recently shown that SWRC can be computed from the gradation curve and the calculation result is consistent with the experimental results obtained from pressure plate tests.In this paper,based on a hypothesis related to change in the pore size distribution(POSD)due to volumetric strain of soil skeleton,a method to compute strain-dependent SWRC is presented.It is found that at initial degrees of saturation higher than 0.8,the influence of volumetric strain may be marginal whilst at initial degrees of saturation lower than 0.8,its influence is likely to be substantial.In all cases,the gradation curve of the soil affects the SWRC.
文摘The goal of this study was to evaluate the water retention value (WRV) of a test solid substrate and a fungal cell in solid state fermentation (SSF). WRV is the ratio of the weight of water retained after centrifugation under specific conditions by a wet sample to the oven dry weight of the same sample. SSF refers to the microbial fermentation, which takes place in the absence or near absence of free water, thus being close to the natural environment. Many factors are involved in a successful SSF process. In addition to biological parameters, the SSF process is also dependent on physical factors such as WRV. A centrifugal technique has been modified and applied to the evaluation of WRV. Wheat bran, soybean hulls and rapeseed meal were used as model substrate. Aspergillus awamori and Aspergillus oryzae were used as model microorganism. Results revealed that the ability of wheat bran to retain water in the solid substrate is 56% higher than that of soybean hulls and rapeseed meal. In the term of fungal cell, the ability of A. oryzae to retain water in the cells was higher (73% higher) than that ofA. awamori. In addition, through oven method moisture content loss from A. awamori is 46% higher than that from A. oryzae during drying process. Nevertheless, it can be seen that A. oryzae is able to retain water content about 5 times higher than A. awamori. Through this results, we found that WRV varies depending on solid substrates and microorganisms. This initial information can be beneficial in the SSF process to be carried out.
文摘In order to understand the origin, the extent and the space distribution of the seasonal anthropic pollution parameters in the water retention located in mountainous area thickly populated and which water resources is intended for the production of drinking water for serving a population of approximately 800,000 inhabitants, two sampling campaigns were carried out for the two seasons of the year known as the dry and rainy season. The samples were then conveyed and analyzed in laboratory. The parameters retained for this study were primarily the physicochemical parameters (pH, conductivity and temperature), measured in situ and second the major anthropic origins anions of (, , and ). The results of the study show that overall the anthropic pollution parameters undergo an important seasonal variation of their concentration between the dry and rainy periods although they remain high in any season compared to the quality standards of natural water of the European Union. Their space distribution within retention remains overall random and is not function of the seasons. However, surrounding areas of the retention and the discharge system of the seasonal rivers (Mayos) which feed it present in rainy season space distributions of concentrations in anions of anthropic origin enumerated above highest.
基金Key Research and Development Project of Science and Technology Department of Zhejiang Province(2023C02019)National Key Research and Development Program of China(2022YFE0127800)+2 种基金National Natural Science Foundation of China(22006018)talent starting-up project of research development fund of Zhejiang A&F University(2034020103)Overseas Expertise Introduction Project for Discipline Innovation(111 Project D18008).
文摘The unsatisfactory nutrient slow-release and water-retention performance of traditional biochar-based compound fertilizers(BCF)severely limit their practical application.Herein,a new type of slow-release fertilizer with high water retention was fabricated via the incorporation of hydrotalcite and starch into BCF,named as HS-BCF.The waterretention and nutrient releasing performance of the prepared HS-BCF and related nutrient slow-release mechanism were investigated.The results showed that the incorporation of hydrotalcite and starch into BCF could increase the soil water-retention ratio by 5-10%points.The accumulated N,P,and K leaching amounts of HS-BCF in soil within 30 days were 49.4%,13.3%,and 87.4%of BCF at most,respectively.Kinetic analysis indicated that the release of nutrients from HS-BCF was attributed to the coupling of the diffusion-controlled and relaxation-controlled mechanism.Moreover,hydrotalcite could bind with P in HS-BCF,contributing to the enhanced durability of P in HS-BCF.Finally,pot experiments showed that the N-P-K utilization efficiencies of HS-BCF were all higher than those of BCF due to a better synchronization between the nutrient release of HS-BCF and the uptake of tomato plants.Overall,the study may provide a promising strategy for simultaneously improving the water-retention and slow-release performance of traditional biochar-based fertilizers.
基金Bingtuan Science and Technology Program(2021DB019,2022CB001-01,2022CB001-07)National Natural Science Foundation of China(42275014).
文摘Biochar has the potential to provide a multitude of benefits when used in soil remediation and increasing soil organic matter enrichment.Nevertheless,the intricated,hydrophobic pores and groups weaken its water-holding capacity in dry,sandy soils in arid lands.In order to combat this issue,starch-carbon-based material(SB),sodium alginate-carbon-based material(SAB),and chitosan-carbon-based material(CB)have been successfully synthesized through the graft-polymerization of biochar(BC).A series of soil column simulations were used to scrutinize the microstructure of the carbon-based material and explore its water absorption properties and its effects on sandy soil water infiltration,water retention,and aggregation.The results indicated that SB,SAB,and CB achieved water maximum absorption rates of 155,188,and 172 g g^(−1),respectively.Considering their impact on sandy soils,SB,SAB,and CB lengthened infiltration times by 1920,3330,and 3880 min,respectively,whilst enhancing the water retention capabilities of the soil by 18%,25%,and 23%in comparison to solely adding BC.The utilization of these innovative materials notably encouraged the formation of sandy soil aggregates ranging from 2.0 to 0.25 mm,endowing the aggregates with enhanced structural stability.Findings from potting experiments suggested that all three carbonbased materials were conducive to the growth of soybean seeds.Thus,it is evident that the carbon-based materials have been fabricated with success,and they have great potential not only to significantly augment the water retention capacities and structural robustness of sandy soils in arid areas,but also to bolster the development of soil aggregates and crop growth.These materials possess significant application potential for enhancing the quality of sandy soils in arid and semi-arid regions.
基金Supported by the National Basic Research Program of China (973 Program) (2010CB951102)the National Natural Science Foundation of China (51039007, 50979076)the Open Research Fund of Key Laboratory for Water Requirement and Regulation, Ministry of Agriculture (CWRR200901)
文摘The soil water retention curve is an important hydraulic function for the study of flow transport processes in unsaturated soils. The objective of this study was to develop a soil water retention function using a generalized fractal approach. The model exhibits asymmetry between the solid phase and pore phase, which is in marked contrast to the symmetry between phases present in a conventional fractal model. The retention function includes 4 parameters: the saturated water content θs, the air entry value ha, the fractal dimension Df, and an empirical parameter β, characterizing the complicated soil pore structures. Sixty one data sets, covering a wide range of soil structure and textural properties, were used to evaluate the applicability of the proposed soil water retention function. The retention function is shown to be a general model, which incorporates several existing retention models. The values of β/θs and (θs-θr )/β were used as indexes to quantify the relationships between the proposed retention function and the existing retention models. The proposed function fits all the data very well, whereas other tested models only match about 16%-48% of the soil retention data.
文摘Assessment of soil water retention in arid region is an input required parameter in precision water management at large scale.Investigations were carried out in Tanta catchment in the middle Nile Delta,Egypt(30145 N,30155 E),where collecting soil samples covered different hydrological soil groups and land-uses.Based on the natural resource conservation service curve number model(NRCS-CN),CN approach was used to investigate the effect of spatio-temporal variations of different land-uses on soil water retention.Potential soil water retention from 1990 to 2015 was reduced by 118.1 m^(3) per hectare with decreasing cropland area.Urbanization encroachment from 1990 to 2015 was increased by 2.13%by decreasing cropland with 15.3%(5300 ha in 2015).This resulted in losing the potential soil water retention by 625,968.42 m^(3) water for the whole catchment area.Impact of land degradation was pronounced,where 2.65%,29.35%,and 1.11%of the initial crop land-use in 1990 were converted to bare soil,fallow,and urban area,respectively in 2015.Implementation of(S)value of the NRCS-CN model with GIS technique provides useful measure to identify land-use changes of potential water storage capacity at catchment scale.
基金This work was funded by the National Undergraduate Training Program for Innovation and Entrepreneurship(No.202010288024Z)National Natural Science Foundation of China(No.42107398)+1 种基金Natural Science Foundation of Jiangsu Province(BK20210358)China Postdoctoral Science Foundation(2020M68618).
文摘The cellulose-based hydrogel has been widely applied for soil water retention and nutrient re-lease agents for several decades.Embedding the inorganic materials into hydrogels is an excellent strategy to improve the inherent limits of the cellulose-based hydrogel.Notably,municipal sludge-derived hydrochar(HC)has reduced the environmental burden and offered a potential hydrogel carrier to control water-retention and nutrient-release.However,the above function for plant growth of hydrochar-embedded carboxymethyl cellulose-g-poly(acrylic acid)(CMC-g-PAA/HC)is unknown,and relevant reports are lacking.This study investigated the water retention,nutri-ent release behavior,and effect of germination and plant growth of CMC-g-PAA/HC hydrogel.Characterization results showed that HC was successfully incorporated into CMC-g-PAA/HC with 6.0%higher thermostability,7.2-21.0%lower swelling ratio(SR)in water,and substantial SR in phosphate solution(P-solution).The water loss rate of CMC-g-PAA/HC in P-solution or wa-ter owned a more significant temperature response(7.9-15.0 folds)than CMC-g-PAA(8.2-10.0 folds).Moreover,4.0%higher n value and more 18.5%released P for CMC-g-PAA/HC were also observed.These phenomena were due to restricting the polymer chains movement and the wa-ter molecules diffusion inside the hydrogels with HC.Phytotoxicity assessments showed that HC in CMC-g-PAA/HC could effectively alleviate the inhibition effects on rape germination retained with 78.3%germination vigor and 80.0%germination ratio,even dramatically improved plant growth to 28 d.The results of this study demonstrated a new route for developing eco-friendly CMC-g-PAA/HC hydrogel,advantageous as a water retention agent and nutrient carrier in arid and semiarid regions.
基金support for this work from National Natural Science Foundation of China(No.31370583).
文摘This study assessed the applicability of chitin nanocrystals prepared by 2,2,6,6-Tetramethyl-1-Piperidine-1-oxyl radical(TEMPO)-mediated oxidation in traditional papermaking coating color systems.The𝛼-chitin nanocrystals(CTNCs)with different carboxyl content,size,and morphology were prepared from crab shells by alkali pretreatment and TEMPO-mediated oxidation in the water at pH 10,and then the ratio of CTNCs to latex was applied to traditional coating color system to replace part of latex.The results showed that when the amount of NaClO added as co-oxidant in the oxidation was 15.0 mmol/g of chitin,the carboxyl content of alkali-pretreated CTNCs was up to 0.76 mmol/g.The amount of carboxyl groups presented a linear relation with the degree of individualization of nanocrystals and dispersion.When the ratio of latex to CTNCs was 90꞉10,the water retention value of the coating was 92%lower than that of the pure latex system,and the rheological property was better.The relationship between the addition amount of CTNCs and the surface strength and the coverage of coating layers were also studied,and results showed that when the ratio of latex to CTNCs was 95꞉5,the surface strength was the highest of 1.45 m/s,and the coverage of coating layers rate reached the highest of 78%.