目的预测燃机透平叶片热障涂层孔隙率,加速热障涂层的研发及工艺优化,解决传统实验方法效率低、成本高的问题,为重型燃气轮机热障涂层研发及工业实际生产中的具体工艺参数调控提供一定指导。方法采用MATLAB图像二值化处理技术计算陶瓷...目的预测燃机透平叶片热障涂层孔隙率,加速热障涂层的研发及工艺优化,解决传统实验方法效率低、成本高的问题,为重型燃气轮机热障涂层研发及工业实际生产中的具体工艺参数调控提供一定指导。方法采用MATLAB图像二值化处理技术计算陶瓷层的孔隙率数据,训练机器学习模型,预测不同工艺参数下热障涂层陶瓷层的孔隙率,并通过实验验证测试涂层的硬度和孔隙率。结果GradientBoosting Regression模型能够实现对热障涂层孔隙率的准确预测,喷涂功率、送粉率和喷涂距离对孔隙率的影响较大。机器学习具有一定的外延性,模型的R值(Related Coefficient,R)由0.8344提高到0.9430,R2值(Square of Related Coefficient,R^(2))从0.6962提高到0.8892,而MAE的值(Mean Absolute Error,MAE)从1.3440降低到1.0394,RMSE值(Root Mean Squared Error,RMSE)由1.8810减少到1.7128。随孔隙率的降低,等离子喷涂8YSZ陶瓷涂层的硬度由3.98 GPa增加到5.54 GPa,弹性模量由62.36 GPa提高到84.30 GPa。该模型准确预测了不同工艺下的涂层孔隙率。结论喷涂功率、送粉率和喷涂距离决定了热障涂层的孔隙率,热障涂层的孔隙率与其硬度和弹性模量息息相关。本工作利用机器学习准确预测了不同工艺下的涂层孔隙率,证明机器学习算法在重型燃气轮机透平叶片热障涂层研发、工艺优化及生产中具有一定的应用前景。展开更多
Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their ...Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.展开更多
大宗工业副产品或废弃物(如粒化高炉矿渣、粉煤灰等)作为辅助胶凝材料用于硅酸盐水泥及混凝土中已有不短的时间。利用辅助胶凝材料可有效缓解水泥生产所带来的制备能耗高、自然资源消耗大、二氧化碳排放等问题。在胶凝材料性能不大幅降...大宗工业副产品或废弃物(如粒化高炉矿渣、粉煤灰等)作为辅助胶凝材料用于硅酸盐水泥及混凝土中已有不短的时间。利用辅助胶凝材料可有效缓解水泥生产所带来的制备能耗高、自然资源消耗大、二氧化碳排放等问题。在胶凝材料性能不大幅降低的前提下,要实现大比例取代(≥30%(质量分数))硅酸盐水泥,激发辅助胶凝材料的活性是关键。然而,从材料学观点出发,过往基于宏观性能的经验测试方法,对辅助胶凝材料活性的理解仍相当碎片化。除比表面积等物理性质外,多数辅助胶凝材料的水硬活性取决于其中玻璃相的溶解-沉淀反应。辅助胶凝材料中的玻璃体结构可简化为网络调整体(如Ca、Na等)和网络形成体(如Si、Al等)的物质的量比,如解聚度。近来对Ca OSi O2-Al2O3体系玻璃体的研究,进一步增强了对玻璃体聚合度的理解。玻璃体的溶解与聚合程度及溶液组成(如溶液的饱和程度、阴阳离子类型及浓度、p H等)密切相关。同时,沉淀的生成也会显著改变玻璃体的溶解动力学。本文归纳了辅助胶凝材料玻璃体结构与水硬活性的研究进展,分别对表征辅助胶凝材料玻璃体结构的解聚度及玻璃体中Si(Qn(m Al))聚合程度进行了介绍,分析了玻璃体结构在不同激发条件下的反应活性,以期为制备性能稳定和耐久性优良的低碳建筑材料提供参考。展开更多
文摘目的预测燃机透平叶片热障涂层孔隙率,加速热障涂层的研发及工艺优化,解决传统实验方法效率低、成本高的问题,为重型燃气轮机热障涂层研发及工业实际生产中的具体工艺参数调控提供一定指导。方法采用MATLAB图像二值化处理技术计算陶瓷层的孔隙率数据,训练机器学习模型,预测不同工艺参数下热障涂层陶瓷层的孔隙率,并通过实验验证测试涂层的硬度和孔隙率。结果GradientBoosting Regression模型能够实现对热障涂层孔隙率的准确预测,喷涂功率、送粉率和喷涂距离对孔隙率的影响较大。机器学习具有一定的外延性,模型的R值(Related Coefficient,R)由0.8344提高到0.9430,R2值(Square of Related Coefficient,R^(2))从0.6962提高到0.8892,而MAE的值(Mean Absolute Error,MAE)从1.3440降低到1.0394,RMSE值(Root Mean Squared Error,RMSE)由1.8810减少到1.7128。随孔隙率的降低,等离子喷涂8YSZ陶瓷涂层的硬度由3.98 GPa增加到5.54 GPa,弹性模量由62.36 GPa提高到84.30 GPa。该模型准确预测了不同工艺下的涂层孔隙率。结论喷涂功率、送粉率和喷涂距离决定了热障涂层的孔隙率,热障涂层的孔隙率与其硬度和弹性模量息息相关。本工作利用机器学习准确预测了不同工艺下的涂层孔隙率,证明机器学习算法在重型燃气轮机透平叶片热障涂层研发、工艺优化及生产中具有一定的应用前景。
基金National Natural Science Foundation of China (52072088, 52072089)Natural Science Foundation of Heilongjiang Province (LH2023E061)+1 种基金Scientific and Technological Innovation Leading Talent of Harbin Manufacturing (2022CXRCCG001)Fundamental Research Funds for the Central Universities (3072023CFJ1003)。
文摘Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.
基金funded by Open Research Fund of State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Central South University, China (No. Kfkt2020-01)Hunan Provincial Natural Science Foundation, China (No. 2021JJ40774)the Project of State Key Laboratory of High Performance Complex Manufacturing, Central South University, China (No. ZZYJKT2021-01)。
基金This work was supported by the National Natural Science Foundation of China(No.21973022)Guangdong Basic and Applied Basic Research Foundation(No.2023A1515012353).
文摘大宗工业副产品或废弃物(如粒化高炉矿渣、粉煤灰等)作为辅助胶凝材料用于硅酸盐水泥及混凝土中已有不短的时间。利用辅助胶凝材料可有效缓解水泥生产所带来的制备能耗高、自然资源消耗大、二氧化碳排放等问题。在胶凝材料性能不大幅降低的前提下,要实现大比例取代(≥30%(质量分数))硅酸盐水泥,激发辅助胶凝材料的活性是关键。然而,从材料学观点出发,过往基于宏观性能的经验测试方法,对辅助胶凝材料活性的理解仍相当碎片化。除比表面积等物理性质外,多数辅助胶凝材料的水硬活性取决于其中玻璃相的溶解-沉淀反应。辅助胶凝材料中的玻璃体结构可简化为网络调整体(如Ca、Na等)和网络形成体(如Si、Al等)的物质的量比,如解聚度。近来对Ca OSi O2-Al2O3体系玻璃体的研究,进一步增强了对玻璃体聚合度的理解。玻璃体的溶解与聚合程度及溶液组成(如溶液的饱和程度、阴阳离子类型及浓度、p H等)密切相关。同时,沉淀的生成也会显著改变玻璃体的溶解动力学。本文归纳了辅助胶凝材料玻璃体结构与水硬活性的研究进展,分别对表征辅助胶凝材料玻璃体结构的解聚度及玻璃体中Si(Qn(m Al))聚合程度进行了介绍,分析了玻璃体结构在不同激发条件下的反应活性,以期为制备性能稳定和耐久性优良的低碳建筑材料提供参考。
