A new type of heavy metal chelating agent,potassium diisopropyl dithiophosphate was synthesized and the treatment of sediment contaminated by heavy metals by this chelator was investigated.The results indicated that w...A new type of heavy metal chelating agent,potassium diisopropyl dithiophosphate was synthesized and the treatment of sediment contaminated by heavy metals by this chelator was investigated.The results indicated that when the dosage of potassium diisopropyl dithiophosphate was 3%(mass),the stabilization rate of heavy metals in sediment,such as Pb,Cu,Cd,could reach more than 85%,and the effect was better than inorganic stabilization chemicals,like Na2S and Na3PO4. After treatment the sediment could meet the US standards for heavy metals waste landfill.Meanwhile,the maximum leaching capacity of the treated sediment was much lower than the case with inorganic stabilization chemicals,and such stabilization effect could be obtained in a wide range of pH. The heavy metals in sediment after treatment could be transformed from exchangeable to organically bound and residue,reducing secondary contamination risk when the environment has changed.展开更多
文摘基于水生植物生长影响因子特征,综合考虑光照、营养盐、悬浮物、水动力、温度及底质等因素,初步提出了野外条件下水生植物恢复判别函数;通过对野外环境主要生境因子的耦合数值仿真,首次建立了基于投影寻踪原理的水生植物恢复判别模型;以苦草做为恢复目标种,选择长江中下游地区典型浅水湖泊——高淳固城湖为例,对模型进行了应用,结果表明:固城湖现状生境条件下,可能恢复苦草的水域面积约3.25 km2,占湖泊总面积的10.5%,其中北部湖区与湖心区恢复面积较大,南部湖区也有局部水域适合苦草恢复重建,但面积较小,约0.65 km2.
文摘A new type of heavy metal chelating agent,potassium diisopropyl dithiophosphate was synthesized and the treatment of sediment contaminated by heavy metals by this chelator was investigated.The results indicated that when the dosage of potassium diisopropyl dithiophosphate was 3%(mass),the stabilization rate of heavy metals in sediment,such as Pb,Cu,Cd,could reach more than 85%,and the effect was better than inorganic stabilization chemicals,like Na2S and Na3PO4. After treatment the sediment could meet the US standards for heavy metals waste landfill.Meanwhile,the maximum leaching capacity of the treated sediment was much lower than the case with inorganic stabilization chemicals,and such stabilization effect could be obtained in a wide range of pH. The heavy metals in sediment after treatment could be transformed from exchangeable to organically bound and residue,reducing secondary contamination risk when the environment has changed.