Di(4-bromophenyl)ketone and various aromatic diamines as the monomers,a series of novel poly(imino ketone)s (PIKs)have been synthesized via palladium-catalyzed aryl amination,which is Hartwig-Buchwald polycondensation...Di(4-bromophenyl)ketone and various aromatic diamines as the monomers,a series of novel poly(imino ketone)s (PIKs)have been synthesized via palladium-catalyzed aryl amination,which is Hartwig-Buchwald polycondensation reaction.The structures of PIKs are characterized by means of elemental analysis,FT-IR,~1H-NMR and UV-Vis spectroscopy. The results show a good agreement with the proposed structure.The general properties of PIKs are studied by DSC,TG and wide-angle X-ray diffraction,the solubility behavior is...展开更多
In this paper,A MySAS package,which is verified on Windows XP,can easily convert two-dimensional data in small angle neutron and X-ray scattering analysis,operate individually and execute one particular operation as n...In this paper,A MySAS package,which is verified on Windows XP,can easily convert two-dimensional data in small angle neutron and X-ray scattering analysis,operate individually and execute one particular operation as numerical data reduction or analysis,and graphical visualization.This MySAS package can implement the input and output routines via scanning certain properties,thus recalling completely sets of repetition input and selecting the input files.On starting from the two-dimensional files,the MySAS package can correct the anisotropic or isotropic data for physical interpretation and select the relevant pixels.Over 50 model functions are fitted by the POWELL code using x^2 as the figure of merit function.展开更多
The neutron response function and detection efficiency of a spherical proton recoil proportional counter (SP) play key roles in precise measurement of neutron spectra of the interior materials.In this paper,the respon...The neutron response function and detection efficiency of a spherical proton recoil proportional counter (SP) play key roles in precise measurement of neutron spectra of the interior materials.In this paper,the response functions and detection efficiency of three SPs developed at CAEP are simulated by Geant4.The simulated spectra are compared with pulse-height spectra measured at 0.165,0.575,1.4,and 14.1 MeV of incident neutrons.And the calculated detector efficiencies agree within 5%with the data obtained by neutron activation.展开更多
The flame retardancy of aromatic thermotropic liquid crystal phosphorus-containing copolyester,TLCP,on PET was investigated.The results show that the presence of TLCP promotes char formation of the substrate and enhan...The flame retardancy of aromatic thermotropic liquid crystal phosphorus-containing copolyester,TLCP,on PET was investigated.The results show that the presence of TLCP promotes char formation of the substrate and enhances thermal stability of char,hence delay its decomposition.SEM pictures show that the char formed from PET/TLCP is more compact, therefore is more resistant to fire and heat than that from pure PET.Evolved gas analysis by I.R measurements indicates that TLCP would decompose to produce phosphor...展开更多
The molecular geometries and electronic structures of two isomers of benzotrifuroxan (BTF) have been studied using ab initio molecular orbital method at the HF/6 31G * level. The calculated results show that the...The molecular geometries and electronic structures of two isomers of benzotrifuroxan (BTF) have been studied using ab initio molecular orbital method at the HF/6 31G * level. The calculated results show that the hexanitroso isomer has much higher energy than the tetracyclic form and is unstable. Infrared frequencies have been calculated for the stable tetracyclic structure and scaled by 0.89. The scaled frequencies agree well with the available experimental results, and have been used to derive the standard thermodynamic functions, heat capacity( Cp °), entropy( S °) and enthalpy( H° H 298 °).展开更多
Alumina coating is used to improve the performance of high-temperature oxidation resistance,which can be fabricated on the surface of hydrogen resistance steel by two methods,thermal oxidation of arc ion plated Al coa...Alumina coating is used to improve the performance of high-temperature oxidation resistance,which can be fabricated on the surface of hydrogen resistance steel by two methods,thermal oxidation of arc ion plated Al coating and reactive magnetron sputtering.Elemental composition,structures and surface morphologies of the coating were analyzed and compared in this paper.The surface of the coatings,which was made by the first method,was composed of α-Al2O3 phase and internal was Fe-Al alloy phase.The Alumina coatings made by the second method were amorphous.In addition,appearances of Alumina coatings fabricated by these two methods were quit different,which were grey and transparent respectively.Both of the two kinds of coatings meet to the needs of high-temperature oxidation resistance.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(No.15076017).
文摘Di(4-bromophenyl)ketone and various aromatic diamines as the monomers,a series of novel poly(imino ketone)s (PIKs)have been synthesized via palladium-catalyzed aryl amination,which is Hartwig-Buchwald polycondensation reaction.The structures of PIKs are characterized by means of elemental analysis,FT-IR,~1H-NMR and UV-Vis spectroscopy. The results show a good agreement with the proposed structure.The general properties of PIKs are studied by DSC,TG and wide-angle X-ray diffraction,the solubility behavior is...
基金Supported by Science and Technology Foundation of China Academy of Engineering Physics(No.2010A0103002)Innovation Foundation of Institute of Nuclear Physics and Chemistry,CAEP(No.2009CX01)
文摘In this paper,A MySAS package,which is verified on Windows XP,can easily convert two-dimensional data in small angle neutron and X-ray scattering analysis,operate individually and execute one particular operation as numerical data reduction or analysis,and graphical visualization.This MySAS package can implement the input and output routines via scanning certain properties,thus recalling completely sets of repetition input and selecting the input files.On starting from the two-dimensional files,the MySAS package can correct the anisotropic or isotropic data for physical interpretation and select the relevant pixels.Over 50 model functions are fitted by the POWELL code using x^2 as the figure of merit function.
文摘The neutron response function and detection efficiency of a spherical proton recoil proportional counter (SP) play key roles in precise measurement of neutron spectra of the interior materials.In this paper,the response functions and detection efficiency of three SPs developed at CAEP are simulated by Geant4.The simulated spectra are compared with pulse-height spectra measured at 0.165,0.575,1.4,and 14.1 MeV of incident neutrons.And the calculated detector efficiencies agree within 5%with the data obtained by neutron activation.
文摘The flame retardancy of aromatic thermotropic liquid crystal phosphorus-containing copolyester,TLCP,on PET was investigated.The results show that the presence of TLCP promotes char formation of the substrate and enhances thermal stability of char,hence delay its decomposition.SEM pictures show that the char formed from PET/TLCP is more compact, therefore is more resistant to fire and heat than that from pure PET.Evolved gas analysis by I.R measurements indicates that TLCP would decompose to produce phosphor...
文摘The molecular geometries and electronic structures of two isomers of benzotrifuroxan (BTF) have been studied using ab initio molecular orbital method at the HF/6 31G * level. The calculated results show that the hexanitroso isomer has much higher energy than the tetracyclic form and is unstable. Infrared frequencies have been calculated for the stable tetracyclic structure and scaled by 0.89. The scaled frequencies agree well with the available experimental results, and have been used to derive the standard thermodynamic functions, heat capacity( Cp °), entropy( S °) and enthalpy( H° H 298 °).
文摘Alumina coating is used to improve the performance of high-temperature oxidation resistance,which can be fabricated on the surface of hydrogen resistance steel by two methods,thermal oxidation of arc ion plated Al coating and reactive magnetron sputtering.Elemental composition,structures and surface morphologies of the coating were analyzed and compared in this paper.The surface of the coatings,which was made by the first method,was composed of α-Al2O3 phase and internal was Fe-Al alloy phase.The Alumina coatings made by the second method were amorphous.In addition,appearances of Alumina coatings fabricated by these two methods were quit different,which were grey and transparent respectively.Both of the two kinds of coatings meet to the needs of high-temperature oxidation resistance.
