Changes in Sediment Sources in the Southern Muddy Area of Weihai,China,Since the Late Pleistocene:A Record from Rare Earth Elements

The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea interactions since the late Pleistocene.This study investigates the evolution of sediment sources and their responses to environmental changes since the late Pleistocene,using core WHZK01 collected from the nearshore muddy area in southern Weihai for rare earth element(REE)analysis.In doing so,this work highlights the changing patterns of material sources and the primary control factors.The results reveal that the sedimentary deposits in core WHZK01 exhibit distinct terrestrial characteristics.Discriminant function analysis(F_(D))and source discrimination dia-grams both suggest that the primary sources of these deposits are the Yellow River and adjacent small and medium-sized rivers,although the sources vary among different sedimentary units.Furthermore,the DU3 layer(17.82-25.10 m)displays typical riverine sedimentation,dominated by terrestrial detrital input,primarily from the local rivers,namely the Huanglei and Muzhu Rivers.The material in the DU2 layer(14.91-17.82 m)is mainly influenced by a mixture of the Qinglong and Yellow Rivers.The DU1 layer(0-14.91 m)is influenced by sea-level changes during the Holocene,with the Yellow River being the primary source,although there is also some input from local rivers.The changes in sea level during the Holocene and the input of Yellow River material carried by the coastal currents of the Yellow Sea are identified as the main controlling factors for the changes in material sources in the study area since the late Pleistocene,with small and mediumsized rivers also exerting some influence on the material sources.The above mentioned findings not only contribute to a better understanding of the source-sink systems of the Yellow River and adjacent small and mediumsized rivers but also deepen our understanding of the late Quaternary land-sea interactions in the Shandong Peninsula.

Ecological environmental quality evaluation and driving factor analysis of the Lijiang River Basin,based on Google Earth Engine

For regional ecological management,it is important to evaluate the quality of ecosystems and analyze the underlying causes of ecological changes.Using the Google Earth Engine(GEE)platform,the remote sensing ecological index(RSEI)was calculated for the Lijiang River Basin in Guangxi Zhuang Autonomous Region for 1991,2001,2011,and 2021.Spatial autocorrelation analysis was employed to investigate spatiotemporal variations in the ecological environmental quality of the Lijiang River Basin.Furthermore,geographic detectors were used to quantitatively analyze influencing factors and their interaction effects on ecological environmental quality.The results verified that:1)From 1991 to 2021,the ecological environmental quality of the Lijiang River Basin demonstrated significant improvement.The area with good and excellent ecological environmental quality in proportion increased by 19.69%(3406.57 km^(2)),while the area with fair and poor ecological environmental quality in proportion decreased by 10.76%(1860.36 km^(2)).2)Spatially,the ecological environmental quality of the Lijiang River Basin exhibited a pattern of low quality in the central region and high quality in the periphery.Specifically,poor ecological environmental quality characterized the Guilin urban area,Pingle County,and Lingchuan County.3)From 1991 to 2021,a significant positive spatial correlation was observed in ecological environmental quality of the Lijiang River Basin.Areas with high-high agglomeration were predominantly forests and grasslands,indicating good ecological environmental quality,whereas areas with low-low agglomeration were dominated by cultivated land and construction land,indicating poor ecological environmental quality.4)Annual average precipitation and temperature exerted the most significant influence on the ecological environmental quality of the basin,and their interactions with other factors had the great influence.This study aimed to enhance understanding of the evolution of the ecological environment in the Lijiang River Basin of Guangxi Zhuang Autonomous Region and provide scientific guidance for decision-making and management related to ecology in the region.

Transient postseismic slip and aftershock triggering:A case study of the 2008 M_W7.9 Wenchuan Earthquake,China

In this study,we investigate how a stress variation generated by a fault that experiences transient postseismic slip(TPS)affects the rate of aftershocks.First,we show that the postseismic slip from Rubin-Ampuero model is a TPS that can occur on the main fault with a velocity-weakening frictional motion,that the resultant slip function is similar to the generalized Jeffreys-Lomnitz creep law,and that the TPS can be explained by a continuous creep process undergoing reloading.Second,we obtain an approximate solution based on the Helmstetter-Shaw seismicity model relating the rate of aftershocks to such TPS.For the Wenchuan sequence,we perform a numerical fitting of the cumulative number of aftershocks using the Modified Omori Law(MOL),the Dieterich model,and the specific TPS model.The fitting curves indicate that the data can be better explained by the TPS model with a B/A ratio of approximately 1.12,where A and B are the parameters in the rate-and state-dependent friction law respectively.Moreover,the p and c that appear in the MOL can be interpreted by the B/A and the critical slip distance,respectively.Because the B/A ratio in the current model is always larger than 1,the model could become a possible candidate to explain aftershock rate commonly decay as a power law with a p-value larger than 1.Finally,the influence of the background seismicity rate r on parameters is studied;the results show that except for the apparent aftershock duration,other parameters are insensitive to r.

The Influence of the Closure of the East Paleo-Tethys Ocean on Southern South China:Evidences from Kinematics and^(40)Ar/^(39)Ar Geochronology of the Rongxian Ductile Shear Zone in Southeastern Guangxi

The Triassic was a crucial period in the tectonic evolution of the South China Block.Research on tectonic deformation during this period provides information on intracontinental orogenic mechanisms in South China.In this study,alongside thermochronological analyses,we examine the macroscopic and microscopic structural features of the Rongxian ductile shear zone,located south of the Darongshan granite in the southeastern part of Guangxi Province,on the southern margin of South China.Sinistral shear is indicated by the characteristics of rotatedσ-type feldspar porphyroclasts,stretching lineations defined by elongated quartz grains and the orientations of quartz c-axes.LA-ICP-MS U-Pb dating of zircons from two samples of granitic mylonite and one of granite yielded ages of ca.256 Ma.Furthermore,two samples of granitic mylonite yield muscovite^(40)Ar/^(39)Ar plateau ages of 249-246 Ma.These results indicate that the Rongxian ductile shear zone resulted from Early Triassic deformation of the late Permian Darongshan granite.This deformation was likely related to the closure of the eastern Paleo-Tethys Ocean and the subsequent collision of the South China and Indochina blocks,during the early stage of the Indosinian orogeny.

The cooling models of Earth’s early mantle

The thermal state of the early Earth’s interior and its way of cooling are crucial for its subsequent evo-lution.Earth is initially hot as it acquired enormous heat in response to violent processes during its formation,e.g.,the Moon-forming giant impact,the segregation and formation of its metallic core,the tidal interaction with the early Moon,and the decay of radioactive elements,etc.In the meantime,the cooling mechanisms of early Earth’s mantle remain elusive despite their importance,and the previously proposed cooling models of the mantle are controversial.In this paper,we first reviewed several prevalent parameter-ized thermal evolution models of the early mantle.The models give unrealistic predictions since they were estab-lished solely based on a single tectonic regime,such as the stagnant-lid regime,or relied on the disputable existence of the plate tectonics prior to-3.5 Ga.Then we argue that the mantle should have started to cool down from a very hot state after the solidification of the ferocious magma ocean.Instead of using one single scaling law to describe a single-stage model,we suggest that an episodic multi-stage cooling model(EMCM)of the early mantle could be more plausible to account for the mantle’s early cooling process.The model reconciles with the fact that the mantle cools down from a hot state prior to*3.5 Ga and can also explain the well-constrained post-3.5 Ga thermal history of the mantle.

Geochronology and Geochemistry of Ore-related Granitoids in the Giant Gariatong Rb Deposit,Tibet and Implications for Rb Metallogeny in China

Rubidium(Rb)deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites.This study investigates a newly-discovered giant Rb deposit at Gariatong in the Central Lhasa terrane in Tibet.Detailed field studies and logging data revealed that the Rb mineralization mainly occurs in monzogranite and is related to greisenization.LA-ICP-MS U-Pb dating of zircon yielded ages of 19.1±0.2 Ma and 19.0±0.2 Ma for greisenized monzogranite and fresh monzogranite,respectively.The monzogranites are characterized as strongly peraluminous,with high contents of SiO2,Al2O3,K2O and Na2O as well as a high differentiation index.They are enriched in light rare earth and large ion lithophile elements with significant negative Eu anomalies and depleted high fieldstrength elements.Petrological and geochemical features of these ore-related monzogranites suggest that they are highly fractionated S-type granites,derived from remelting of crustal materials in a post-collisional setting.The geochemistry of zircon and apatite points to a low oxygen fugacity of the ore-related monzogranite during the magma’s evolution.The discovery of the Gariatong Rb deposit suggests that the Central Lhasa terrane may be an important region for rare metal mineralization.

A palaeoearthquake event and its age revealed by the travertine layer along the Litang fault in the southeastern margin of the Qinghai-Tibetan plateau

The Litang fault(LTF),located in the southeast of the Qinghai-Tibetan Plateau,is known for its high level of present-day seismicity,whereas its Pleistocene activity has been scarcely documented.This study focused on a tract of banded travertine deposits precipitated from thermal waters along the NW–SE-trending LTF trace.The role of travertine deposits in recording neotectonic activity has been studied by identifying their internal structure.Typical soft-sediment deformation structures observed within the banded travertines include micro folds,liquefied breccia,and liquefied diapirs.These deformed structures,which are restricted to a single unit separated unconformably by undeformed layers,can be traced for tens of meters,indicating that they were formed by seismic shaking triggered by LTF activity.The deformation of the banded travertine layers is attributed to the combined effects of seismic shaking,liquefaction,and fluidization,and it can be related to a paleo earthquake event with a magnitude of MS>5.The U-series ages obtained from the banded travertine deposits perturbed by the earthquakes are in the range of 130.59–112.94 ka,indicating an important fault-assisted neotectonic activity that occurred during the Middle–Late Pleistocene.Analysis of such structures,in combination with the use of U-series dating methods,can yield a reliable timing of neotectonic activity and provide new evidence for under-standing the seismotectonic setting of the Litang area.

Origin of the Yueguang gold deposit in Xinhua, Hunan Province, South China: insights from fl uid inclusion and hydrogen–oxygen stable isotope analysis

The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province.

Discovery and Significance of the Triassic–Late Paleozoic Double-layered Basement in the Songliao Basin:Based on the Complete Coring Data from ICDP Borehole SK2

The Songliao Basin(SLB)covers an area of approximately 260,000 km2in northeastern Asia and preserves a continuous and complete Cretaceous terrestrial record(Wang et al.,2021).The region is the most important petroliferous sedimentary basin in China because of its continual annual oil and gas equivalent production of tens of millions of tons(ca.220–440 million barrels per year)since 1959.The SLB was previously thought to have developed on Hercynian basement and accumulated continuous sedimentary deposits during the Late Jurassic and Cretaceous(Wan et al.,2013;Wang et al.,2016).

U-Pb zircon ages and petrogeochemistry and tectonic implications of gabbro and granite in southwest Lahad Datu area of Sabah, Malaysia

The southwest Lahad Datu felsic rocks were previously thought to have formed in the late Triassic as part of the microcontinental crystalline basement.Based on U-Pb ages,geochemistry,and the Hfisotopes of zircon from the southeastern Sabah gabbro and granite,in this study,the tectonic properties of the Sabah area during the Triassic were investigated.The weighted average U-Pb zircon ages of the gabbro and granite samples were determined to be(230.9±2.5)Ma and(207.1±3.3)Ma,respectively.The granite had SiO_(2) contents of 66.54%-79.47%,low TiO_(2) contents of 0.08%-0.3%,Al_(2)O_(3) contents of 10.97%-16.22%,Na_(2)O contents of 5.91 %-6.39%,and low K_(2)O contents of 0.15%-0.65%.The chondrite-normalized rare earth element(REE) patterns exhibit light REE enrichment,with right-sloping curves.The primitive mantle-normalized trace element spider diagrams exhibit Th,U,La,Sr,and Zr enrichment and Nb,Ta,P and Ti depletions,i.e.,the geochemical characteristics of typical island arc igneous rocks.The tectonic discriminant diagram indicates that the granite is a volcanic arc granite.The Hf isotopic an alysis of gabbro zircon revealed that the zircons have ε_(Hf)(t)values of 12.08-16.24(mean of 14.32) and two-stage model ages(t_(DM2)) of 223-491 Ma(mean of 347 Ma).This indicates that the diagenetic magma of the gabbro was mainly derived from melting of newly formed crustal materials.The ophiolite in southeast Sabah has existed since the early Late Triassic.The crystalline basement granite in southeastern S abah was emplaced lasted from late Triassic to early Cretaceous.Based on previous studies and global plate reconstruction models,it is speculated that the southeastern Sabah granite may have been formed in an island arc setting,i.e.,where the oceanic crust of the Paleo-Tethys Ocean collided with the oceanic crust of the Panthalassa Ocean.

Macro-micro behaviors and failure mechanism of frozen weakly cemented mudstone

Understanding the mechanical properties and multiscale failure mechanism of frozen soft rock is an important prerequisite for the construction safety of tunnels,artificially frozen ground and other infrastructure in cold regions.In this study,the triaxial compression test are performed on mudstone in the weakly cemented soft rock strata in the mining area of western China,and the mechanical characteristics and failure mechanism of weakly cemented mudstone are systematically investigated under the combined action of freezing and loading.Furthermore,the quantitative relationship between the microstructural parameters and the macroscopic strength and deformation parameters is established based on fractal theory.Thus,the failure mechanism of frozen weakly cemented mudstone is revealed on both micro- and macro-scales.The results show that temperature and confining pressure significantly affects the elastic modulus and peak strength of weakly cemented mudstone.With decreasing temperature,the compressive strength increases,while the corresponding peak strain decreases gradually.On the deformation curve,the plastic deformation stage is shortened,and the brittle fracture feature at the post-peak stage is more prominent,and the elastic modulus correspondingly increases with decreasing temperature.Under low-temperature conditions,most of the weakly cemented mudstone undergoes microscopic shear failure along the main fracture surface.The micro-fracture morphology characteristics of weakly cemented mudstone under different temperatures are quantified via the fractal dimension,and an approximately exponential relationship can be obtained among the fractal dimension and the temperature,compressive strength and elastic modulus.

Early Triassic Silicic Volcanics of South China:Petrogenesis and Constraints on the Geodynamic Evolution of the Paleo-Tethys Ocean Region

The only occurrence of Lower Triassic silicic volcanic rocks within the South China Block is in the Qinzhou Bay area of Guangxi Province.LA-ICP-MS zircon U-Pb dating reveals that volcanic rocks of the Beisi and Banba formations formed between 248.8±1.6 and 246.5±1.3 Ma,coeval with peraluminous granites of the Qinzhou Bay Granitic Complex.The studied rhyolites and dacites are characterized by high SiO_(2),K_(2)O,and Al_(2)O_(3),and low MgO,CaO,and P_(2)O_(5) contents and are classified as high-K calc-alkaline S-type rocks,with A/CNK=0.98-1.19.The volcanic rocks are depleted in high field strength elements,e.g.,Nb,Ta,Ti,and P,and enriched in large ion lithophile elements,e.g.,Rb,K,Sr,and Ba.Although the analyzed volcanic rocks have extremely enriched zircon Hf isotopic compositions(ε_(Hf)(t)=-29.1 to-6.9),source discrimination indicators and high calculated Ti-in-zircon temperatures(798-835℃)reveal that magma derived from enriched lithospheric mantle not only provided a heat source for anatectic melting of the metasedimentary protoliths but was also an endmember component of the S-type silicic magma.The studied early Triassic volcanics are inferred to have formed immediately before closure of the Paleo-Tethys Ocean in this region,as the associated subduction would have generated an extensional setting in which the mantle-derived upwelling and volcanic activity occurred.

Extensive Resetting of Feldspar Pb Isotopic Composition in Archean–Paleoproterozoic Granitic Rocks from the Kongling Terrane,South China:Implications for Tracing Thermal Evolutionary History

Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb isotopic composition of feldspar hosted in granitic rocks(thirteen Archean and one Paleoproterozoic)from the northern Kongling terrane,Yangtze Craton,South China,is analyzed.The samples reveal a substantial variation in their Pb isotopic composition,spanning the gap between the 1.9 Ga and present-day geochrons,which indicates extensive resetting by later tectonothermal events.This resetting was interpreted to have likely resulted from Paleoproterozoic and Neoproterozoic tectonothermal events related to the assembly and breakup of the Columbia and Rodinia supercontinents.These results suggest that Pb isotopes should be used cautiously when tracing magma sources and petrogenesis in magmatic rocks that have experienced post-magmatic reworking.However,the in situ Pb isotopic composition of feldspar in ancient granitoids may also potentially be used to reveal later tectonothermal events.The extensive resetting of the Pb isotopic composition in feldspar by regional thermal events may also provide new insights into our understanding of the Pb isotope paradox.

Microfacies and diagenetic alteration in a semi-deep to deep lacustrine shale: The Yanchang Formation in the Ordos Basin, China

The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic diagram are proposed in this study.Through detailed petrographic,mineralogical,and elemental analyses,four distinct shale types are identified:argillaceous shale,siliceous shale,calcareous shale,and carbonate,clay,and silt-bearing shale.The main diagenetic process in argillaceous shale is the transformation of illite to smectite,negatively impacting shale porosity.Siliceous shale undergoes carbonate cementation and quartz dissolution,contributing to increased porosity,particularly in mesopores.Calcareous shale experiences diagenesis characterised by carbonate formation and dissolution,with a prevalence of siderite.In carbonate,clay,and silt-bearing shale,the dissolution of K-feldspar contributes to illitization of kaolinite.Argillaceous shale,characterised by more clay minerals and lower mesopore volume,is identified as a potential hydrocarbon seal.Siliceous shale,with the highest pore volume and abundant inter-mineral pores,emerges as a promising shale oil reservoir.These findings contribute to a comprehensive understanding of shale properties,aiding in the prediction of shale oil exploration potential in the studied area.

Quantifying the Effects of Near-Surface Viscosity on Seismic Acquisition Geometry: A case study from Chepaizi Exploration Area, Junggar Basin (NW China)

The Chepaizi Exploration Area,Junggar Basin(NW China)holds substantial importance for seismic exploration endeavors,yet it poses notable challenges due to the intricate nature of its subsurface and near-surface conditions.To address these challenges,we introduce a novel and comprehensive workflow tailored to evaluate and optimize seismic acquisition geometries while considering the impacts of near-surface viscosity.By integrating geological knowledge,historical seismic data,and subsurface modeling,we conduct simulations employing the visco-acoustic wave equation and reverse-time migration to produce detailed subsurface images.The quality of these images is quantitatively evaluated using a local similarity metric,a pivotal tool for evaluating the accuracy of seismic imaging.The culmination of this workflow results in an automated optimization strategy for acquisition geometries that enhances subsurface exploration.Our proposed methodology underscores the importance of incorporating near-surface viscosity effects in seismic imaging,offering a robust framework for improving the accuracy of subsurface imaging.Herein,we aim to contribute to the advancement of seismic imaging methodologies by providing valuable insights for achieving high-quality seismic exploration outcomes in regions characterized by complex subsurface and near-surface conditions.

Material Composition of the Newly Discovered Zongzhuo Formation Sedimentary Mélange in the Dingri Area,Southern Tibet,and its Constraints on the Basin Controlling Dingri-Gamba Fault

The study of sedimentary mélanges holds pivotal importance in understanding orogenic processes and unveiling geodynamic mechanisms.In this study,we present findings on zircon U-Pb isotopes and whole-rock elemental data concerning the recently uncovered Zongzhuo Formation sedimentary mélanges within the Dingri area.Field observations reveal the predominant composition of the Zongzhuo Formation,characterized by a matrix of sandstone-mudstone mixed with sand-conglomerates within native blocks exhibiting soft sediment deformation.Moreover,exotic blocks originating from littoral-neritic seas display evidence of landslide deformation.Our study identifies the depositional environment of the Zongzhuo Formation in Dingri as a slope turbidite fan,with its provenance traced back to the passive continental margin.Notably,this contrasts with the Zongzhuo Formation found in the Jiangzi-Langkazi area.Based on existing data,we conclude that the Zongzhuo Formation in the Dingri area was influenced by the Dingri-Gamba fault and emerged within a fault basin of the passive continental margin due to Neo-Tethys oceanic subduction during the Late Cretaceous period.Its provenance can be attributed to the littoral-neritic sea of the northern Tethys Himalaya region.This study holds significant implications for understanding the tectonic evolution of Tethys Himalaya and for reevaluating the activity of the Dingri-Gamba fault,as it controls the active deposition of the Zongzhuo Formation.

Formation of large-and medium-sized Cretaceous volcanic reservoirs in the offshore Bohai Bay Basin,East China

Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.

The Spatiotemporal Distribution Characteristics of Cloud Types and Phases in the Arctic Based on CloudSat and CALIPSO Cloud Classification Products

The cloud type product 2B-CLDCLASS-LIDAR based on CloudSat and CALIPSO from June 2006 to May 2017 is used to examine the temporal and spatial distribution characteristics and interannual variability of eight cloud types(high cloud, altostratus, altocumulus, stratus, stratocumulus, cumulus, nimbostratus, and deep convection) and three phases(ice,mixed, and water) in the Arctic. Possible reasons for the observed interannual variability are also discussed. The main conclusions are as follows:(1) More water clouds occur on the Atlantic side, and more ice clouds occur over continents.(2)The average spatial and seasonal distributions of cloud types show three patterns: high clouds and most cumuliform clouds are concentrated in low-latitude locations and peak in summer;altostratus and nimbostratus are concentrated over and around continents and are less abundant in summer;stratocumulus and stratus are concentrated near the inner Arctic and peak during spring and autumn.(3) Regional averaged interannual frequencies of ice clouds and altostratus clouds significantly decrease, while those of water clouds, altocumulus, and cumulus clouds increase significantly.(4) Significant features of the linear trends of cloud frequencies are mainly located over ocean areas.(5) The monthly water cloud frequency anomalies are positively correlated with air temperature in most of the troposphere, while those for ice clouds are negatively correlated.(6) The decrease in altostratus clouds is associated with the weakening of the Arctic front due to Arctic warming, while increased water vapor transport into the Arctic and higher atmospheric instability lead to more cumulus and altocumulus clouds.

The occurrence characteristics of oil in shales matrix from organic geochemical screening data and pore structure properties:An experimental study Author links open overlay panel

The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space.

Quantitative geochemical reconstruction of Eocene paleoenvironment in Fushun Basin,northeast China

The quantitative estimation of key parameters of paleotemperature and paleoprecipitation is crucial for paleoclimate reconstruction.Geochemical data from mod-ern sediments are highly consistent with climate data,and their relationship can provide an important reference for the quantitative reconstruction of the paleoclimate.In this study,detailed inorganic geochemical analysis was carried out using high-precision sampling of the Paleogene(LFD-1 well)Guchengzi,Jijuntun and Xiloutian Formations in the Fushun Basin located in the mid-latitudes of the Northern Hemisphere.The Eocene Guchengzi Formation(54.51–47.8 Ma)and Jijuntun Formation(47.8–41.2 Ma)in the Fushun Basin were found to have been deposited under a humid climate.The lower(41.2–40.1 Ma)and upper(40.1–37.8 Ma)parts of the Xiloutian Formation were character-ized by semiarid and semihumid–semiarid climates,respec-tively,which is very similar to the paleoclimatic information reflected by organic carbon isotopes.The Eocene Thermal Maximum 2(ETM2,~53.7 Ma),Early Eocene Climatic Optimum(EECO,~53.1–46.5 Ma),Eocene Thermal Maxi-mum 3(ETM 3,~52.8 Ma),and Middle Eocene Climatic Optimum(MECO,~40.7–40.1 Ma)events significantly enhanced chemical weathering during these periods.The rapid increase in pCO_(2)concentration leads to an increase in temperature,precipitation,and surface runoff,exhibiting strong chemical weathering.The mean annual temperature(MATa)and mean annual precipitation(MAPa,MAPb,and MAPc)were estimated using parameters,such as the corrosion index without potassium(CIA-K),CaO/Al_(2)O_(3),and(Na_(2)O+K_(2)O)/Al_(2)O_(3).Comparing MAPa,MAPb,and MAPc with the MAP estimated using pollen data,MAPa and MAPb were found to be more sensitive to the climate during high precipitation periods(precipitation>1000 mm,Guchengzi Formation),and the recovered average precipi-tation was similar to MAP.In contrast,MAPc was more sensitive to the climate during low precipitation periods(precipitation<1000 mm,Jijuntun,and Xiloutian Forma-tions),with higher accuracy.To fully consider the influence of soluble inorganic salts Ca^(2+)and Na^(+),multivariate linear equations of CIA-K and CaO/Al_(2)O_(3)with CIA,and CIA-K and CaO/Al_(2)O_(3)with MAP were constructed,namely MAPd and MAPe.The results show that MAPe has the highest per-formance and can be effectively used to estimate the change of paleoprecipitation in Northeast Asia.