Significant lake expansion has accelerated permafrost degradation on the Qinghai-Tibet Plateau

In recent years, lakes on the Qinghai-Tibet Plateau have become more responsive to climate change. In September 2011, Zonag Lake in Hoh Xil experienced sudden drainage, the water eventually flowed into Yanhu Lake, which caused Yanhu Lake to continue to expand. The potential collapse of Yanhu Lake could directly threaten the operational safety of the adjacent Qinghai-Tibet Highway, Qinghai-Tibet Railway. To explore the implications of expanding lakes on the surrounding permafrost, we selected Hoh Xil Yanhu Lake on the Qinghai-Tibet Plateau to study the effect of lake expansion on permafrost degradation. The permafrost degradation in the Yanhu Lake basin from October 2017 to December 2022 was inverted using Sentinel-1 satellite image data and small baseline subset interferometry synthetic aperture radar(SBAS-In SAR) technology. Additionally, permafrost degradation from February 2007 and February 2010 was analyzed using advanced land observing satellite phased array-type L-band synthetic aperture radar(ALOS PALSAR) satellite images and differential interferometric synthetic aperture radar(D-In SAR) technique. The results showed that the permafrost around Yanhu Lake experienced accelerated degradation. Prior to the expansion of Yanhu Lake, the average annual deformation rate along the line of sight(LOS) direction was 6.7 mm/yr. After the expansion, the rate increased to 20.9 mm/yr. The integration of spatial-temporal distribution maps of surface subsidence, Wudaoliang borehole geothermal data, meteorological data, Yanhu Lake surface area changes, and water level changes supports the assertion that the intensified permafrost degradation could be attributed to lake expansion rather than the rising air temperature. Furthermore, permafrost degradation around Yanhu Lake could impact vital infrastructure such as the adjacent Qinghai-Tibet Highway and Qinghai-Tibet Railway.

Can soil remediation agents synergistically mitigate rice Cd content and CH_(4)emission from karst paddies?

Rice(Oryza sativa L.)paddies are increasingly threatened by cadmium(Cd)pollution,and potentially serve as CH_(4)emitters to the atmosphere.Remediation agents widely mitigate Cd pollution in paddy soil,however,we know little about their regulations on CH_(4)emission.Here,via adding biochar(B),sulfhydryl-modified palygorskite(SMP),and selenium foliar fertilizer(SFF),we conducted a pot experiment to investigate soil and rice Cd contents together with in-situ CH_(4)f luxes.Compared to CK,the addition of SMP,SFF,and B-SMP reduced Cd in brown rice by 25%to 50%,25%,and 50%to 75%,respectively.Agents 7%B,7%B-0.01%SMP,and SFF reduced CH_(4)emissions by 8.46%,5.30%,and 4.11%,respectively.CH_(4)emission increased gradually along the growing season,with the cumulative CH_(4)fluxes ranging between 338.82 and 619.13 kg hm^(-2).Our results highlight that mixed 7%B-0.01%SMP and SFF showed collaborative eff ects on Cd remediation and CH_(4)emission.This study reveals the feasibility of reducing Cd pollution and CH_(4)emission in karst rice paddies,which hopes to supplement the knowledge of collaborative controls on soil remediation and carbon emission.

Sedimentary Environment and Mineralization of the Black Shale Polymetallic Layer in the Early Cambrian,SW China:Constraints from in situ LA-ICP-MS Analysis of Pyrite

A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differentiation mechanism between polymetallic deposits(Ni-Mo and V),the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite.The results show that δ^(34)S values of pyrite vary widely from−7.8‰to 28‰in the Gezhongwu profile,while the δ^(34)S values are relatively uniform(from 27.8‰to 38.4‰)in the Haishan profile.The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform;this indicates that the δ^(34)SO_(4)^(2−)values in seawater must be differently distributed in depositional environments.The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid,while the V layer mainly originates from seawater.Overall,the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.

A local rainfall-triggered giant landslide occurred in a region along a high-speed railway on the Qinghai‒Tibetan Plateau

An increasing number of geological hazards along high-speed railways on the Qinghai‒Tibetan Plateau have occurred and have resulted in a profound influence on old infrastructure,which has attracted increasing attention.The landslide event that occurred on September 15,2022,in Jiujiawan village,Xining city,Qinghai Province,is a typical case.Based on field investigations and remote sensing interpretations,a comprehensive analysis was conducted on the landslide.Additionally,the potential secondary failure of the current Jiujiawan landslide was assessed using Fast Lagrangian Analysis of Continua in Three Dimensions(FLAC3D).Based on the application of the small baseline subset-interferometric synthetic aperture radar(SBAS-InSAR)technique to SAR images from February 24,2017 to September 14,2022,a significant westward horizontal deformation was found to have been formed prior to the occurrence of the landslide.The maximum annual average deformation rate in the line of sight(LOS)direction reached-45 mm/yr,with a maximum cumulative deformation of-178 mm.This value was consistent with the continual increase in annual precipitation(2.51 mm/yr)prior to the occurrence of the landslide.The accumulated precipitation before the landslide was 279.8 mm,accounting for 54.2%of the total annual precipitation,with a particularly notable surge in monthly precipitation observed during August(250.3 mm).Additionally,the occurrence of a seismic event with a magnitude of Ms 6.9 in Menyuan County,80 km away from Xining,could be a potential triggering factor to the landslide,as evidenced by an abrupt subsidence alteration observed prior to and following the earthquake.The maximum subsidence in the line of sight(LOS)direction exceeded 11 mm,exhibiting a highly consistent spatial distribution with the occurrence range of landslides.These results suggest that the Jiujiawan landslide was likely induced by earthquake events in the early stage and heavy rainfall in the later stage.The FLAC3D numerical simulation show that after the landslide,the slope remained marginally stable under natural conditions;however,it is susceptible to reactivation with heavy rainfall.

Study on the effect and mechanism of Swertia mussotii Franch. in the treatment of primary biliary cholangitis based on bioinformatics and in vitro experiments

Background:Primary biliary cholangitis(PBC)is a chronic biliary autoimmune liver disease characterized by intrahepatic cholestasis.Swertia mussotii Franch.(SMF)is a Tibetan medicine with hepatoprotective and anti-inflammatory activities.In this study,the therapeutic effect and potential mechanisms of SMF on PBC were investigated by bioinformatics analysis and in vitro experimental validation,with the aim of promoting the progress of SMF and PBC research.Methods:We first explored the therapeutic effects and key targets of SMF on PBC using a network pharmacology approach,further screened the core targets using the GSE79850 dataset,and finally validated the results using molecular docking techniques and in vitro experiments.Results:By bioinformatics analysis,we identified core targets of SMF for PBC treatment(STAT3,JAK2,TNF-α,and IL-1β)and important signaling pathways:JAK-STAT,TNF,and PI3K-AKT.The molecular docking results showed that the significant components of SMF had good binding properties to the core targets.In vitro experiments showed that SMF extracts improved the extent of epithelial-mesenchymal transition in human intrahepatic biliary epithelial cells and had a significant reversal effect on epithelial-mesenchymal transition process markers and potential targets in PBC.Conclusion:SMF may exert its therapeutic effects on PBC by acting on important targets such as STAT3,JAK2,TNF-α,IL-1β,Vimentin,and E-cadherin and the pathways in which they are involved.

Effect of cold stratification on the temperature range for germination of Pinus koraiensis

Germination at low spring temperatures may offer a competitive advantage for the growth and survival of plant species inhabiting temperate forest ecosystems.Pinus koraiensis is a dominant species in temperate forests of northeastern China.Its seeds exhibit primary morphophysiological dormancy following dispersal in autumn,limiting natural or artificial regeneration:direct seeding and planting seedlings in spring.The aim of this study was to determine the optimum cold stratification temperature that induces germination to increase towards lower temperatures.Seeds from two populations(Changbaishan and Liangshui)were cold stratified at 0,5 and 10℃.Germination to incubation temperatures(10/5,20/10,25/15 and 30/20℃;14/10 h day/night)were determined after 2 and 4 weeks,and 5.5 and6.5 months of cold stratification.After 5.5 months,approximately 68-91%of seeds from both populations germinated at incubation temperatures of 25/15℃and 30/20℃,regardless of cold stratification temperatures.When the cold stratification temperature was reduced to 0℃and the period increased to 6.5 months,germination at 10/5℃significantly improved,reaching 37%and 64%for the Changbaishan and Liangshui populations,respectively.After 6.5 months of cold stratification,there was a significant linear regression between cold stratification temperatures and germination at10/5℃.The range in temperatures allowing for germination gradually expanded to include lower temperatures with decreasing cold stratification temperatures from 10 to 5℃and further to 0℃.

Large-scale characteristics of thermokarst lakes across the source area of the Yellow River on the Qinghai-Tibetan Plateau

As significant evidence of permafrost degradation,thermokarst lakes play an important role in the permafrost regions by regulating hydrology,ecology,and biogeochemistry.In the Sources Area of the Yellow River(SAYR),permafrost degradation has accelerated since the 1980s,and numerous thermokarst lakes have been discovered.In this paper,we use Sentinel-2 images to extract thermokarst lake boundaries and perform a regional-scale study on their geometry across the permafrost region in the SAYR.We also explored the spatiotemporal variations and potential drivers from the perspectives of the permafrost,climate,terrain and vegetation conditions.The results showed that there were 47,518 thermokarst lakes in 2021 with a total area of 190.22×106 m^(2),with an average size of 4,003.3 m^(2).The 44,928 ponds(≤10,000 m^(2))predominated the whole lake number(94.1%)but contributed to a small portion of the total lake area(28.8%).With 2,590 features(5.9%),small-sized(10,000 to 100,000 m^(2))and large-sized lakes(>100,000 m^(2))constituted up to 71.2%of the total lake area.Thermokarst lakes developed more significantly in warm permafrost regions than in cold permafrost areas;74.1%of lakes with a total area of 119.6×106 m^(2)(62.9%),were distributed in warm permafrost regions.Most thermokarst lakes were likely to develop within the elevation range of 4,500~4,800 m,on flat terrain(slope<10°),on SE and S aspects and in alpine meadow areas.The thermokarst lakes in the study region experienced significant shrinkage between 1990 and 2021,characterized by obvious lake drainage;the lake numbers decreased by 5418(56.1%),with a decreasing area of 58.63×106 m^(2)(49.0%).This shrinkage of the thermokarst lake area was attributable mainly to the intensified degradation of rich-ice permafrost thawing arising from continued climate warming,despite the wetting climatic trend.

The gut microbiome and metabolome of Himalayan Griffons(Gyps himalayensis):insights into the adaptation to carrion-feeding habits in avian scavengers

Background:Himalayan Griffons(Gyps himalayensis),large scavenging raptors widely distributed in Qinghai-Tibetan Plateau,have evolved a remarkable ability to feed on carcasses without suffering any adverse effects.The gut microbiome plays an important role in animal physiological and pathological processes,and has also been found to play a health protective role in the vulture adaptation to scavenging.However,the microbial taxonomic diversity(including nonculturable and culturable microbes),functions,and metabolites related to Himalayan Griffons have not been fully explored.Methods:In the present study,the 28 fecal samples of the Himalayan Griffons and 8 carrion samples were collected and sequenced using high-throughput 16 S rRNA gene sequencing methods to analyze the composition and functional structures of the microbiomes.Twelve fecal samples of the Himalayan Griffons were analyzed using untargeted Liquid Chromatography Mass Spectroscopy(LC-MS)to identify metabolites.We used different culture conditions to grow Himalayan Griffons gut microbes.Inhibitory effects of gut beneficial bacteria on 5 common pathogenic bacteria were also tested using the Oxford cup method.Results:According to the results of the culture-independent method,a high abundance of four major phyla in Himalayan Griffons were identified,including Fusobacteria,Firmicutes,Bacteroidetes,and Proteobacteria.The most abundant genera were Fusobacterium,followed by Clostridium_sensu_stricto_1,Cetobacterium,Epulopiscium,and Bacteroides.The predicted primary functional categories of the Himalayan Griffons'gut microbiome were associated with carbohydrate and amino acid metabolism,replication and repair,and membrane transport.LC-MS metabolomic analysis showed a total of 154 metabolites in all the fecal samples.Cultivation yielded 184 bacterial isolates with Escherichia coli,Enterococcus faecium,Enterococcus hirae,and Paeniclostridium sordellii as most common isolates.Moreover,7 potential beneficial gut bacteria isolated showed certain inhibition to 5 common pathogenic bacteria.Conclusions:Our findings broaden and deepen the understanding of Himalayan Griffons'gut microbiome,and highlighted the importance of gut microbiome-mediated adaptation to scavenging habits.In particular,our results highlighted the protective role of gut beneficial bacteria in the Himalayan Griffons against pathogenic bacteria that appear in rotten food resources.

Shale Gas Reservoir Evaluation by Geophysical Measurements:A Case Study of the Upper Ordovician–Lower Silurian in the Fenggang Block,Northern Guizhou Province

With the aid of geophysical measurements,including seventeen two-dimensional(2 D)seismic lines and the well logging curves of well FGY1,the structure and reservoir characteristics of the Upper Ordovician–Lower Silurian strata in the Fenggang block,northern Guizhou Province,were analyzed thoroughly to identify desert areas and favorable intervals.The results show that Longmaxi-Wufeng is the most prospect-rich formation,consisting of a thick succession of overmature black shale,this formation remaining partially in the Suiyang,Fenggang and Jianchaxi synclines.The Longmaxi-Wufeng shale,especially the lower member,was deposited in a reducing low-energy environment with relatively high U content and a low Th/U value.In this shale,the organic matter type(sapropelic and humic-sapropelic),total organic carbon(TOC)content,gas content,gas adsorption capacity,vitrinite reflectance and brittle mineral content are profitable for shale gas preservation and development.The fractures of this shale were closed because of its high overburden pressure.The gas adsorption capacity of this shale increases with increasing TOC content and Ro.In the Longmaxi-Wufeng Formation at well FGY1,the most favorable intervals are in the depth ranges of 2312.4–2325.1 m and 2325.8–2331.1 m.

Helium and argon isotope geochemistry of the Tibetan Qulong porphyry Cu-Mo deposit,China

The Qulong porphyry Cu-Mo deposit,generated in the Miocene post-collisional extension environment of the Gangdese Copper(Molybdenum)Metallogenic Belt,is one of the largest porphyry Cu deposits in China.This study reports the noble gas isotopic compositions of volatiles released from fluid inclusion reserved in pyrite from the Qulong deposit.3He/4 He and 40Ar/36Ar ratios range from 0.54 to 1.015 Ra and 300-359,respectively.Concentrations of 4 He and 40Ar range from 1.77 to 2.62×10^(-8)cm^(3)STP and 1.7-34×10^(-8)cm^(3)STP,respectively.The isotopic composition of noble gases indicates that the ore-forming fluids of the Qulong Cu-Mo deposit were a mixture of fluid containing mantle component,which is exsolved from the porphyry magma,and crustal fluid characterized by atmospheric Ar and crustal radiogenic He.Theδ34S values of pyrite and molybdenite range from-0.52‰to 0.31‰,with an average of-0.12‰,indicating a magmatic origin.More mantle components were involved in the Cu-Mo deposit than in the Mo-Cu deposit in the Qulong-Jiama ore-district.

Investigation and Evaluation on Heavy Metal Content and Pesticide Residues of Three Edible Forest Products in Central Sichuan Province

Taking three mains edibles products(walnut, prickly ash and bamboo shoots) and origin soil in central area of Sichuan Province as the study objects, this research aimed at revealing the level of heavy metals and pesticide residue and comprehensive evaluation the soil heavy metal pollution in the region. The results showed that: ① Soil organic matter, total nitrogen, total phosphorus and heavy metal contents of mercury, arsenic in the south area were significant higher than that in the north area, while the heavy metal contents of lead and copper were significantly higher in the north area; ② The pollution index of six heavy metals of cadmium, mercury, arsenic, lead, chromium and copper in the producing area was less than 1.0. However, the integrated pollution index was at a warning level, and there was a potential risk of cadmium contamination; ③ The walnut samples exceeded the lead limit value over 75% in the north area and over 35% in the south area, and the same as 30% of bamboo shoot samples; ④ There was a significant negative correlation of mercury content between walnut samples and production soil, and a significant positive correlation of arsenic content between bamboo shoots and production soil. In addition, there is no significant correlation of heavy metal contents between prickly samples and production soil; ⑤ Fenthion residues were detected in walnuts, malathion samples were detected in prickly ash, and chlorothalonil, dimethoate and chlorpyrifos residues in bamboo shoots samples. None of theses pesticide residues exceeded the standard limit value. In general, the soil is in well sanitary condition and the edible forest products are not exposed to the contamination of pesticide residues in the study area. The quality and safety of the prickly ash is good while the walnut and bamboo shoots have certain risks in terms of high lead level.

Dispersal and germination of winged seeds of Brandisia hancei,a shrub in karst regions of China

Brandisia hancei(Paulowniaceae)is a widely distributed shrub in karst regions in southwestern China.Its seeds have a membranous wing,and they mature just before the rainy season begins.To assess the effect of the wing on seed dispersal and germination of B.hancei,we measured the dispersal distance at varying wind speeds and release heights,falling duration from different release heights,floating duration on still water,rates of imbibition of water,and drying and soil adherence to seeds.Germination experiments were conducted on intact and de-winged seeds immediately after harvest.The wing increased the falling duration in still air and the floating ability on water.Dispersal distance of winged and de-winged seeds did not differ at a wind speed of 2.8 m s1,but at 3.6 and 4.0 m s1 dispersal distances were greater for de-winged than for winged seeds.Seed wing had little effect of absorption and retention of water,but significantly increased soil adherence to the seeds.Mature seeds were non-dormant and germinated to over 90%with a mean germination time of about 10 days.By combining the environmental conditions in karst habitat with the seed traits of B.hancei,we conclude that dispersal and germination of winged seeds are adapted to the precipitation seasonality in heterogeneous habitats absence of soil.

Influence of nitrogen wet deposition on nitrogen output in a typical watershed in the Three Gorges Reservoir Area

In order to explore the influence of wet nitrogen(N)deposition on N output in watersheds,this study selected a typical small watershed(Chenjiagou,CJG)in the Three Gorges Reservoir(TGR)area based on one-year observation of rainfallrunoff N forms.Characteristics and sources of N output were clarified by chemical statistics and isotopic abundance,and the contribution of N deposition to the N output was quantified by the output coefficient method.The N flux of wet deposition was estimated at 18.53 kg N ha^(-1) yr^(-1),and originated mostly from agricultural activities.Watershed N was significantly accumulated from upper to lower reaches due to frequent human activities.Seasonal changes of riverine N were strongly affected by chemical fertilizer,with the highest concentration in spring and the lowest in winter.Nitrate was mainly derived from chemical fertilizer,accounting for 38.83% of all sources.N concentration in processes of different rainfall events had a hysteresis effect corresponding to the flow rate.Three rainfall events greatly changed DTN(Dissolved total N)outputs:rainstorm caused 91.26 kg DTN output,which was 11 times that of moderate rain(8.46 kg)and 4 times that of heavy rain(20.80 kg).N deposition contributed 19.89% of riverine N output in the watershed.The results can provide theoretical support for the control of N pollution in the TGR area.

Advances in the Medicinal Value of Constructed Wetland Plants for Treating Rural Domestic Sewage

Firstly,the advantages and disadvantages of constructed wetlands for treating rural domestic sewage are introduced.Secondly,the types of constructed wetland plants are introduced.Thirdly,the suitability of using medicinal wetland plants to treat rural domestic sewage is analyzed.Fourthly,the principles of selecting wetland plants with medicinal value are studied.Finally,commonly used constructed wetland plants and their medicinal value are introduced.

Application Effect of Sludge Extract in the Planting of Zinnia elegans

[Objectives] The research aimed to study the effect of sludge extract on the growth of Zinnia elegans, and evaluate its possibility of application. [Methods] Z. elegans was taken as research object, and the effect of sludge extract on the growth indicators of Z. elegans was studied. [Results] The sludge extract can obviously promote the growth of Z. elegans, and the growth indicators were significantly improved when compared with the control group. The application effect was close to that of foliar fertilizer purchased in the market. In each treatment group, the low concentration of sludge extract did not significantly promote the growth of Z. elegans, while too high concentration could inhibit its growth, and the optimal dilution ratio was 600 times. [Conclusions] Further preparation of amino acid foliar fertilizer from sludge extract and its application in planting garden plants can realize the resource utilization of sludge and has a good development and application prospect.

Chronic administration of triclosan leads to liver fibrosis through hepcidin-ferroportin axis-mediated iron overload

Triclosan(TCS)has been manufactured as an antibacterial compound for half a century.Currently,it is widely used in various personal care products;however,its potential adverse effects raise a lot of attention.Here,we create a long-term oral administration mouse model and identify the corresponding hepatotoxicity of TCS.We discover that daily intragastric administration of 10 mg/kg TCS to mice for 12 weeks results in severe hepatic fibrosis.Further study displays that hepatic iron increased 18%,23%and 29%upon oral TCS treatment for4,8 and 12 weeks,respectively.Accompanied by hepatic iron variation,splenic and duodenal iron are increased,which indicates systemic iron disorder.Not only excessive iron accumulated in the liver,abnormal hepatic malondialdehyde,prostaglandin synthase 2 and glutathione peroxidase 4 are pointed to ferroptosis.Additional study uncovers that hepcidin expression increases 7%,10%,4%in serum and 2.4-,4.8-,and 2.3-fold on transcriptional levels upon TCS exposure for 4,8 and 12 weeks,individually.Taken together,the mice in the TCS-treated group show disordered systemic iron homeostasis via the upregulated hepatic hepcidin-ferroportin axis.Meanwhile,both hepatic iron overload(systemic level)and hepatocyte ferroptosis(cellular level)are accused of TCS-induced liver fibrosis.Ferriprox■,an iron scavenger,significantly ameliorates TCS-induced liver fibrosis.In summary,this study confirms the impact of TCS on liver fibrosis;a critical signal pathway is also displayed.The significance of the current study is to prompt us to reevaluate the“pros and cons”of TCS applications.

Ultraviolet humic-like component contributes to riverine dissolved organic matter biodegradation

Biological degradation of dissolved organic matter(DOM)regulates its structure and fate in river ecosystems.Previous views suggested that labile components were dominantly consumed by microbial metabolism.Here we provide new observations that a part of recalcitrant compounds largely contribute to riverine DOM biodegradation.The excitationemission matrix fluorescent spectroscopy combined with peak picking and parallel factor analysis are used to explore component variability during DOM incubation.Humic-like and tryptophan-like DOM are the primary components of riverine DOM,with proportion contributions of 39%–82% and 16%–61% for % of the maximumfluorescence intensity,respectively.After 56 days of aerobic incubation in the dark,large amounts of tyrosine-like DOM generation are observed.Elevated temperature enhances the decomposition of ultraviolet humiclike substance and further stimulates labile DOM bio-mineralization into carbon dioxide.Meanwhile,averaged proportions of amino acid compositions(peak B and T)markedly increase(p<0.05)as the humic-like compositions(peak A,M and C)decrease after DOM incubation,suggesting incomplete degradation of refractory DOM from high-molecular to low-molecular weight compounds.The findings support the new notion of the continuous DOM biodegradation in a mode as“steps by steps”,contributing to a new understanding of carbon cycling for the UN Sustainable Development Goal.

红松种子休眠状态的变化调控种子萌发的季节性时间

种子休眠能够确保幼苗在一个季节性变化的环境中选择适宜的季节建植。红松(Pinus koraiensis)种子在秋季落下之后具有形态生理休眠。一小部分种子在落下之后的第一个春季萌发,但大部分种子在第二个春季萌发,目前尚不清楚休眠状态如何驱动这种萌发特性。在2018年10月中旬,在中国东北黑龙江省丰林国家级自然保护区的凋落物和土层之间埋藏新鲜的红松种子,并且隔一段时间取出,测定种子的野外萌发率、种胚生长情况、种子活力和室内萌发率。形态生理休眠的生理休眠部分在第一个冬季逐渐解除,但在第一个夏季被再次诱导;再次被诱导的生理休眠在第二个秋、冬季解除。形态生理休眠的形态休眠部分在第一个夏季逐渐缓慢解除,但在第二个早、中秋季迅速解除。在第二个春季,红松种子完全解除形态生理休眠。种子的生理休眠解除,但形态休眠仍然存在,导致其在第一个春季的野外萌发率非常低。种子的形态和生理休眠均解除,导致大部分种子能在第二个春季相对较低的温度(昼夜温度在10/5°C以上)下萌发。红松种子为形态生理休眠种子的休眠状态变化研究提供了示例。

A scientometric review of biochar preparation research from 2006 to 2019

Biochar is the carbon-rich product obtained from the thermochemical conversion of biomass under oxygen-limited condi-tions.Preparation methods contribute to biochar properties,which are widely concerned in the agronomic and environmental benefits of agro-ecosystems.This research aims to use bibliometrics methods to comprehensively and objectively analyze the research trends in the global biochar production field from 2006 to 2019 based on the Web of Science Core Collection database.The results showed that 1434 papers related to biochar preparation were published,which gradually increased each year.The research topics were diversified,which were mainly divided into“Environmental Sciences and Ecology,”“Engineering”and“Agriculture”.Moreover,Bioresource Technology was the most published journal contained biochar preparation.Authors from China had the most publications,followed by the US,Australia and the UK.Meanwhile,Yong Sik Ok from Korea University contributed most of the publications and had the highest H-index.Keywords analysis indicated that biochar preparation by pyrolysis was a current hotspot,of which microwave and hydrothermal were a future research trend.Besides,gasification would be used to develop new biomass energy.Biochar has the characteristics of high pH,high specific surface area,high carbon content,and rich functional groups.It is mainly used in soil improvement,water pollutant adsorption,carbon sequestration and emission reduction,and energy storage materials,etc.Furthermore,raw materials,pyrolysis temperature and pyrolysis time will also affect its characteristics and applications.It is expected that this study may provide insight into the future research interests regarding biochar preparation.

Adsorption of emerging sodium p-perfluorous nonenoxybenzene sulfonate(OBS) onto soils: Kinetics, isotherms and mechanisms

The widespread use of sodium p-perfluorous nonenoxybenzene sulfonate(OBS), a typical alternative to perfluorooctane sulfonate, has resulted in potential threats to the environment, but the adsorption behavior of OBS in soils has not yet been reported. In this study, the adsorption behaviors of OBS on five soils with different physicochemical properties were investigated. The rate of OBS adsorption was fast, and most of the OBS uptake was completed within 12 h. The good model fit of OBS adsorption to the pseudo-second-order and Elovich models indicated the occurrence of chemical adsorption. The adsorption isotherms of OBS on the soils were better described by the Freundlich model than by the Langmuir model, suggesting that the OBS adsorption sites on the soils were heterogeneous. This is possibly associated with various adsorption mechanisms including hydrophobic, π-π, hydrogen bonding, and electrostatic interactions,further confirmed by the good model fit to the D-R isotherm. Adsorption of OBS occurred on the soils, and the adsorption process was spontaneous and endothermic. In addition, the soils were more suitable for OBS adsorption at lower pH values due to the stronger electrostatic adsorption. The OBS adsorption on the soils decreased with the increase of soil depth from 0 to 30 cm. Moreover, the presence of organic matter and ammonia nitrogen in the soils was favorable for OBS adsorption, and these parameters decreased with increasing soil depth, making OBS adsorption less prominent in the deeper soil. This study indicates that OBS is easily enriched in surface soils, and that soil organic matter and ammonia nitrogen significantly affect OBS migration in soil.