Ultrasonic cavitation involves dynamic oscillation processes induced by small bubbles in a liquid under the influence of ultrasonic waves. This study focuses on the investigation of shape and diffusion instabilities o...Ultrasonic cavitation involves dynamic oscillation processes induced by small bubbles in a liquid under the influence of ultrasonic waves. This study focuses on the investigation of shape and diffusion instabilities of two bubbles formed during cavitation. The derived equations for two non-spherical gas bubbles, based on perturbation theory and the Bernoulli equation, enable the analysis of their shape instability. Numerical simulations, utilizing the modified Keller–Miksis equation,are performed to examine the shape and diffusion instabilities. Three types of shape instabilities, namely, Rayleigh–Taylor,Rebound, and parametric instabilities, are observed. The results highlight the influence of initial radius, distance, and perturbation parameter on the shape and diffusion instabilities, as evidenced by the R_0–P_a phase diagram and the variation pattern of the equilibrium curve. This research contributes to the understanding of multiple bubble instability characteristics, which has important theoretical implications for future research in the field. Specifically, it underscores the significance of initial bubble parameters, driving pressure, and relative gas concentration in determining the shape and diffusive equilibrium instabilities of non-spherical bubbles.展开更多
Metal-halide hybrid perovskite materials are excellent candidates for solar cells and photoelectric devices.In recent years,machine learning(ML)techniques have developed rapidly in many fields and provided ideas for m...Metal-halide hybrid perovskite materials are excellent candidates for solar cells and photoelectric devices.In recent years,machine learning(ML)techniques have developed rapidly in many fields and provided ideas for material discovery and design.ML can be applied to discover new materials quickly and effectively,with significant savings in resources and time compared with traditional experiments and density functional theory(DFT)calculations.In this review,we present the application of ML in per-ovskites and briefly review the recent works in the field of ML-assisted perovskite design.Firstly,the advantages of perovskites in solar cells and the merits of ML applied to perovskites are discussed.Secondly,the workflow of ML in perovskite design and some basic ML algorithms are introduced.Thirdly,the applications of ML in predicting various properties of perovskite materials and devices are reviewed.Finally,we propose some prospects for the future development of this field.The rapid devel-opment of ML technology will largely promote the process of materials science,and ML will become an increasingly popular method for predicting the target properties of materials and devices.展开更多
Integral experiments on tungsten slab samples were carried out on the D-T neutron source facility at China Institute of Atomic Energy. Leakage neutron spectra from the irradiated tungsten target were measured by the t...Integral experiments on tungsten slab samples were carried out on the D-T neutron source facility at China Institute of Atomic Energy. Leakage neutron spectra from the irradiated tungsten target were measured by the time-of-flight technique. Accuracy of the nuclear data for tungsten was examined by comparing the measured neutron spectra with the leakage neutron spectra simulated using the MCNP-4C code with evaluated nuclear data of the JEFF-3.2, FENDL-3.0 and TENDL-2014 libraries. The results show that the calculations with JEFF-3.2 agree well with the measurements in the whole energy range and all angles, whereas the spectra calculated with FENDL-3.0 and TENDL-2014 have some discrepancies with the experimental data.展开更多
The time-dependent wave packet method is used to investigate the influence of laser-fields on the vibrational population of molecules. For a two-state system in laser fields, the populations on different vibrational l...The time-dependent wave packet method is used to investigate the influence of laser-fields on the vibrational population of molecules. For a two-state system in laser fields, the populations on different vibrational levels of the upper and lower electronic states are given by wavefunctions obtained by solving the Schrbdinger equation with the split- operator method. The calculation shows that the field parameters, such as intensity, wavelength, duration, and delay time etc. can have different influences on the vibrational population. By varying the laser parameters appropriately one can control the evolution of wave packet and so the vibrational population in each state, which will benefit the light manipulation of atomic and molecular processes.展开更多
On the basis of the full velocity difference (FVD) model, an improved multiple car-following (MCF) model is proposed by taking into account multiple information inputs from preceding vehicles. The linear stability...On the basis of the full velocity difference (FVD) model, an improved multiple car-following (MCF) model is proposed by taking into account multiple information inputs from preceding vehicles. The linear stability condition of the model is obtained by using the linear stability theory. Through nonlinear analysis, a modified Korteweg-de Vries equation is constructed and solved. The traffic jam can thus be described by the klnk-antikink soliton solution for the mKdV equation. The improvement of this new model over the previous ones lies in the fact that it not only theoretically retains many strong points of the previous ones, but also performs more realistically than others in the dynamical evolution of congestion. Furthermore, numerical simulation of traffic dynamics shows that the proposed model can avoid the disadvantage of negative velocity that occurs at small sensitivity coefficients λ in the FVD model by adjusting the information on the multiple leading vehicles. No collision occurs and no unrealistic deceleration appears in the improved model.展开更多
Spin polarized injection into organic and inorganic semiconductors are studied theoretically from the spin diffusion theory and Ohm's law, and the emphases are placed on the effect of the carrier differences on the c...Spin polarized injection into organic and inorganic semiconductors are studied theoretically from the spin diffusion theory and Ohm's law, and the emphases are placed on the effect of the carrier differences on the current spin polarization. The mobility and the spin-flip time of carriers in organic and inorganic semiconductors are different. From the calculation, it is found that current spin polarization at a ferromagnetic/organic interface is higher than that at a ferromagnetic/inorganic interface because of different carriers in them. Effects of the conductivity matching, the spin dependent interracial resistances, and the bulk spin polarization of the ferromagnetic layer on the spin polarized injection are also discussed.展开更多
We report a robust method of directly stabilizing a grating feedback diode laser to an arbitrary frequency in a large range. The error signal, induced from the difference between the frequency measured by a wavelength...We report a robust method of directly stabilizing a grating feedback diode laser to an arbitrary frequency in a large range. The error signal, induced from the difference between the frequency measured by a wavelength meter and the preset target frequency, is fed back to the piezoelectric transducer module of the diode laser via a sound card in the computer. A visual Labview procedure is developed to realize a feedback system. In our experiment the frequency drift of the diode laser is reduced to 8 MHz within 25 min. The robust scheme can be adapted to realize the arbitrary frequency stabilization for many other kinds of lasers.展开更多
Lithium metal batteries(LMBs)have attracted wide attentions because of their high theoretical specific capacity and low electrochemical potential.However,the growth of lithium dendrites seriously affects the practical...Lithium metal batteries(LMBs)have attracted wide attentions because of their high theoretical specific capacity and low electrochemical potential.However,the growth of lithium dendrites seriously affects the practical application of LMBs.Thus,the lithium-philic carbonyl and carboxy dualgroup-modified covalent organic framework(COF-COOH)is designed to coat the polypropylene(PP)separator(COF-COOH@PP separator),realizing the regulation of ion transport and uniform lithium deposition.The plentiful and negative charge sites in the COF-COOH can suppress the diffusion of the freely movable lithium salt anion by the electrostatic interaction.Density functional theory(DFT)calculations demonstrate that the COF-COOH possesses the function of anchoring anion and desolvation.Consequently,the Li^(+)transference number(0.7),ion conductivity(0.64 mS cm^(-1)),and desolvating of Li^(+)are obviously improved by using the COF-COOH@PP separator.The modified Li-Li symmetric battery delivers stable cycle for more than 1000 h and lower voltage hysteresis(0.02 V).This dendrite-free deposition strategy holds great promise for practical application of Li metal anodes.展开更多
We theoretically and numerically investigate the coherence of disordered bosonic gas with effective two- and three-body interactions within a two-site Bose-Hubbard model. By properly adjusting the two- and three-body ...We theoretically and numerically investigate the coherence of disordered bosonic gas with effective two- and three-body interactions within a two-site Bose-Hubbard model. By properly adjusting the two- and three-body interactions and the disorder, the coherence of the system exhibits new and interesting phenomena, including the resonance character of coherence against the disorder in the purely two- or three-body interactions system. More interestingly, the disorder and three-body interactions together can suppress the coherence of the purely three-body interactions system, which is different from the case in which the disorder and two-body interactions together can enhance the coherence in certain values of two.body interaction. Furthermore, when two- or three- body interactions are attractive or repulsive, the phase coherence exhibits completely different phenomena. In particular, if two- or three-body interactions are attractive, the coherence of the system can be significantly enhanced in certain regions. Correspondingly, the phase coherence of the system is strongly related to the effective interaction energy. The results provide a possible way for studying the coherence of bosonic gas with multi-atoms' interactions in the presence of the disorder.展开更多
In this study,we systematically investigated the two-proton(2p)radioactivity half-lives from the excited state of nuclei near the proton drip line within the Gamowlike model(GLM)and modified Gamow-like model(MGLM).The...In this study,we systematically investigated the two-proton(2p)radioactivity half-lives from the excited state of nuclei near the proton drip line within the Gamowlike model(GLM)and modified Gamow-like model(MGLM).The calculated results were highly consistent with the theoretical values obtained using the unified fission model[Chin.Phys.C 45,124105(2021)],effective liquid drop model,and generalized liquid drop model[Acta Phys.Sin 71,062301(2022)].Furthermore,utilizing the GLM and MGLM,we predicted the 2p radioactivity halflives from the excited state for some nuclei that are not yet available experimentally.Simultaneously,by analyzing the calculated results from these theoretical models,it was found that the half-lives are strongly dependent on Qand l.展开更多
In this paper we study influences of Doppler broadening, spontaneously generated coherence, and other system parameters on propagation effect in a quasi lambda-type four-level atomic system. It is shown that when the ...In this paper we study influences of Doppler broadening, spontaneously generated coherence, and other system parameters on propagation effect in a quasi lambda-type four-level atomic system. It is shown that when the Doppler broadening is present, generally speaking, the values of gain and intensity of lasing without inversion (i.e. the probe field) in the co-propagating probe and driving fields case are much larger than those in the counter-propagating case; considerably larger gain and intensity of lasing without inversion than those without the Doppler broadening can be obtained by choosing appropriate values of the Doppler broadening width and spontaneously generated coherence strength. The gain and intensity of lasing without inversion increase with the increase of spontaneously generated coherence strength; when spontaneously generated coherence is present, much larger gain and intensity of lasing without inversion than those in the case without spontaneously generated coherence can be obtained. Choosing suitable values of the probe detuning, Rabi frequencies of the driving and pump fields at the entrance of the medium also can remarkably enhance the gain and intensity of lasing without inversion.展开更多
From experimental results of spin polarized injection and transport in organic semiconductors(OSCs),we theoretically study the current spin polarization and magnetoresistance under an electric and a magnetic field i...From experimental results of spin polarized injection and transport in organic semiconductors(OSCs),we theoretically study the current spin polarization and magnetoresistance under an electric and a magnetic field in a ferromagnetic/organic semiconductor/ferromagnetic(FM/OSC/FM) sandwich structure according to the spin drift-diffusion theory and Ohm's law.From the calculations,it is found that the interfacial current spin polarization is enhanced by several orders of magnitude through tuning the magnetic and electric fields by taking into account the specific characteristics of OSC.Furthermore,the effects of the electric and magnetic fields on the magnetoresistance are also discussed in the sandwich structure.展开更多
This paper reports that ultracold atoms are populated into different nS and nD Rydberg states (n=25-52) by two-photon excitation. The ionization spectrum of an ultracold Rydberg atom is acquired in a cesium magneto-...This paper reports that ultracold atoms are populated into different nS and nD Rydberg states (n=25-52) by two-photon excitation. The ionization spectrum of an ultracold Rydberg atom is acquired in a cesium magneto-optical trap by using the method of pulse field ionization. This denotes nS and nD states in the ionization spectrum and fits the data of energy levels of different Rydberg states to obtain quantum defects of nS and nD states.展开更多
Higher-order nonlinear Schrodinger equation with the Hirota constraint conditions is considered, and an analytic solution, which can describe the modulational instability process, is presented. Based on the solution, ...Higher-order nonlinear Schrodinger equation with the Hirota constraint conditions is considered, and an analytic solution, which can describe the modulational instability process, is presented. Based on the solution, a new pulse train without continuous wave (CW) background is generated in quadratures and the propagation of the pulse train is discussed in detail by simulating numerically. The results show that, unlike the propagation of the picosecond pulse train, under the effects of the higher-order terms, the pulse train cannot propagate along the fibre when the energy is very high; however, for some medium energy the pulse train can stably propagate. We also investigate the stability of the pulse train against violation of the Hirota conditions, and the results show that the pulse train can still propagate stably when the Hirota conditions are broken.展开更多
We analyze the distribution properties of phase and phase vortices in a speckle field generated by N-pinhole random screens, and find that the phase vortex distributions show similarity and clustering in local regions...We analyze the distribution properties of phase and phase vortices in a speckle field generated by N-pinhole random screens, and find that the phase vortex distributions show similarity and clustering in local regions. The phase patterns have a lot of sets composed of two phase vortices with opposite signs or four phase vortices which are positive and negative vortices alternately. Cases are also found where two adjacent phase vortices have the same topological charges. The density of phase vortices becomes larger with the increase of the radius of circumference and the number of pinholes on screen.Then, the relative positions of phase vortices can be adjusted by changing the radius of circumference and the number of pinholes.展开更多
The intensity distribution and phase vortices of the speckle fields generated by multi-aperture random scattering screens are simulated, and it is found that the vortices exhibit layer-like structures and the dislocat...The intensity distribution and phase vortices of the speckle fields generated by multi-aperture random scattering screens are simulated, and it is found that the vortices exhibit layer-like structures and the dislocation phenomena occur in the local phase patterns produced by the two-pinhole aperture, whose phase distributions appear as striped structures. For three- or four-pinhole aperture, there are many circular bright spots appearing in the speckle grains, and there is one vortex between the neighboring circular bright spots. The positive and negative phase vortex lattices appear in the phase distributions, and the regions circled by the isothetic phase lines form irregular quadrilaterals or hexagons. Moreover, the relative positions of the vortices or bright spots can be adjusted by changing those of the pinhole apertures.展开更多
In the present work,we extend the Coulomb and Proximity Potential Model(CPPM)to study two-proton(2p)radioactivity from excited states while the proximity potential is chosen as AW95 proposed by Aage Withner in 1995.De...In the present work,we extend the Coulomb and Proximity Potential Model(CPPM)to study two-proton(2p)radioactivity from excited states while the proximity potential is chosen as AW95 proposed by Aage Withner in 1995.Demonstration reveals that the theoretical results acquired by CPPM exhibit a high level of consistency with prior theoretical models such as the unified fission model(UFM),generalized liquid-drop model(GLDM)and effective liquid-drop model(ELDM).Furthermore,within the CPPM,we predicted the half-lives of potential 2p radioactive nuclei for which experimental data are currently unavailable.The predicted results were then assessed,compared with UFM,ELDM and GLDM models,and examined in detail.展开更多
We investigate the tunneling dynamics of a few bosons with both two-and three-body interactions in a doublewell potential. Uncorrelated tunneling of Rabi oscillation with the minimum period can happen only when the tw...We investigate the tunneling dynamics of a few bosons with both two-and three-body interactions in a doublewell potential. Uncorrelated tunneling of Rabi oscillation with the minimum period can happen only when the two-and three-body interactions satisfy a critical condition, i.e., the effective interaction energy is minimized. When the atomic interactions are slightly away from the critical condition in the weak interaction regime, the uncorrelated tunneling exhibits collapse-revival character. When the atomic interactions are strong and far away from the critical condition, the correlated tunneling with Rabi oscillation occurs. The tunneling period(the period of collapse-revival) increases(decreases) when the rate between the two-body and three-body interactions is away from the corresponding critical condition or when the number of bosons increases. Further, the tunneling properties are understood with the help of the energy spectrum of the system. Eventually, the effect of the initial configuration on the tunneling dynamics of a few bosons for both odd and even numbers of bosons is studied, which results in intriguing consequences.展开更多
The passively Q-switched and mode-locked(QML) characteristics in a diode-pumped Nd∶GdVO4 laser with Cr4+∶YAG saturable absorbers have been demonstrated. A maximum average output power of 710mW has been obtained in...The passively Q-switched and mode-locked(QML) characteristics in a diode-pumped Nd∶GdVO4 laser with Cr4+∶YAG saturable absorbers have been demonstrated. A maximum average output power of 710mW has been obtained in the QML laser. The maximum energy of a single Q-switched pulse is 52.5μJ, with the corresponding pulse width of 30ns and the peak power of 1.75kW, at the incident pump power of 7.75W. The repetition rates of the Q-switched envelope and the mode-locked laser pulse are 16.7kHz and 680MHz, respectively.展开更多
Owing to the importance of excited state dynamical relaxation, the excited state intramolecular proton transfer(ESIPT) mechanism for a novel compound containing dual hydrogen bond(abbreviated as "1-enol") is...Owing to the importance of excited state dynamical relaxation, the excited state intramolecular proton transfer(ESIPT) mechanism for a novel compound containing dual hydrogen bond(abbreviated as "1-enol") is studied in this work.Using density functional theory(DFT) and time-dependent density functional theory(TDDFT) method, the experimental electronic spectra can be reproduced for 1-enol compound. We first verify the formation of dual intramolecular hydrogen bonds, and then confirm that the dual hydrogen bond should be strengthened in the first excited state. The photo-excitation process is analyzed by using frontier molecular orbital(HOMO and LUMO) for 1-enol compound. The obvious intramolecular charge transfer(ICT) provides the driving force to effectively facilitate the ESIPT process in the S1 state. Exploration of the constructed S0-state and S1-state potential energy surface(PES) reveals that only the excited state intramolecular single proton transfer occurs for 1-enol system, which makes up for the deficiencies in previous experiment.展开更多
基金Project supported by the Scientific Research Project of Higher Education in the Inner Mongolia Autonomous Region (Grant No.NJZY23100)。
文摘Ultrasonic cavitation involves dynamic oscillation processes induced by small bubbles in a liquid under the influence of ultrasonic waves. This study focuses on the investigation of shape and diffusion instabilities of two bubbles formed during cavitation. The derived equations for two non-spherical gas bubbles, based on perturbation theory and the Bernoulli equation, enable the analysis of their shape instability. Numerical simulations, utilizing the modified Keller–Miksis equation,are performed to examine the shape and diffusion instabilities. Three types of shape instabilities, namely, Rayleigh–Taylor,Rebound, and parametric instabilities, are observed. The results highlight the influence of initial radius, distance, and perturbation parameter on the shape and diffusion instabilities, as evidenced by the R_0–P_a phase diagram and the variation pattern of the equilibrium curve. This research contributes to the understanding of multiple bubble instability characteristics, which has important theoretical implications for future research in the field. Specifically, it underscores the significance of initial bubble parameters, driving pressure, and relative gas concentration in determining the shape and diffusive equilibrium instabilities of non-spherical bubbles.
基金funded by the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No.XDA17040506)the National Natural Science Foundation of China(62005148/12004235)+2 种基金The Open Competition Mechanism to Select The Best Candidates Project in Jinzhong Science and Technology Bureau (J202101)the DNL Cooperation Fund CAS(DNL180311)the 111 Project (B14041)
文摘Metal-halide hybrid perovskite materials are excellent candidates for solar cells and photoelectric devices.In recent years,machine learning(ML)techniques have developed rapidly in many fields and provided ideas for material discovery and design.ML can be applied to discover new materials quickly and effectively,with significant savings in resources and time compared with traditional experiments and density functional theory(DFT)calculations.In this review,we present the application of ML in per-ovskites and briefly review the recent works in the field of ML-assisted perovskite design.Firstly,the advantages of perovskites in solar cells and the merits of ML applied to perovskites are discussed.Secondly,the workflow of ML in perovskite design and some basic ML algorithms are introduced.Thirdly,the applications of ML in predicting various properties of perovskite materials and devices are reviewed.Finally,we propose some prospects for the future development of this field.The rapid devel-opment of ML technology will largely promote the process of materials science,and ML will become an increasingly popular method for predicting the target properties of materials and devices.
基金supported by the National Natural Science Foundation of China(No.11605097,91426301,and 11605257)Doctoral Scientific Research Foundation of Inner Mongolia University for the Nationalities(No.BS365)the‘‘ADS project 302’’of the Chinese Academy of Sciences(No.XDA03030200)
文摘Integral experiments on tungsten slab samples were carried out on the D-T neutron source facility at China Institute of Atomic Energy. Leakage neutron spectra from the irradiated tungsten target were measured by the time-of-flight technique. Accuracy of the nuclear data for tungsten was examined by comparing the measured neutron spectra with the leakage neutron spectra simulated using the MCNP-4C code with evaluated nuclear data of the JEFF-3.2, FENDL-3.0 and TENDL-2014 libraries. The results show that the calculations with JEFF-3.2 agree well with the measurements in the whole energy range and all angles, whereas the spectra calculated with FENDL-3.0 and TENDL-2014 have some discrepancies with the experimental data.
基金Project supported by the Natural Science Foundation of Shandong Province of China (Grant No. Y2006A23)the National Basic Research Program of China (Grant No. 2006CB806000)the Open Fund of the State Key Laboratory of High Field Laser Physics (Shanghai Institute of Optics and Fine Mechanics)
文摘The time-dependent wave packet method is used to investigate the influence of laser-fields on the vibrational population of molecules. For a two-state system in laser fields, the populations on different vibrational levels of the upper and lower electronic states are given by wavefunctions obtained by solving the Schrbdinger equation with the split- operator method. The calculation shows that the field parameters, such as intensity, wavelength, duration, and delay time etc. can have different influences on the vibrational population. By varying the laser parameters appropriately one can control the evolution of wave packet and so the vibrational population in each state, which will benefit the light manipulation of atomic and molecular processes.
基金Project supported by the National High Tech Research and Development Program of China (Grant No 511-0910-1031)the National "10th Five-year" Science and Technique Important Program of China (Grant No 2002BA404A07)
文摘On the basis of the full velocity difference (FVD) model, an improved multiple car-following (MCF) model is proposed by taking into account multiple information inputs from preceding vehicles. The linear stability condition of the model is obtained by using the linear stability theory. Through nonlinear analysis, a modified Korteweg-de Vries equation is constructed and solved. The traffic jam can thus be described by the klnk-antikink soliton solution for the mKdV equation. The improvement of this new model over the previous ones lies in the fact that it not only theoretically retains many strong points of the previous ones, but also performs more realistically than others in the dynamical evolution of congestion. Furthermore, numerical simulation of traffic dynamics shows that the proposed model can avoid the disadvantage of negative velocity that occurs at small sensitivity coefficients λ in the FVD model by adjusting the information on the multiple leading vehicles. No collision occurs and no unrealistic deceleration appears in the improved model.
基金Supported by the National Natural Science Foundation of China under Grant No 10747143, and the Shandong Distinguished Middle-Aged and Young Scientist Encourage and Reward Foundation (2007BS01017).
文摘Spin polarized injection into organic and inorganic semiconductors are studied theoretically from the spin diffusion theory and Ohm's law, and the emphases are placed on the effect of the carrier differences on the current spin polarization. The mobility and the spin-flip time of carriers in organic and inorganic semiconductors are different. From the calculation, it is found that current spin polarization at a ferromagnetic/organic interface is higher than that at a ferromagnetic/inorganic interface because of different carriers in them. Effects of the conductivity matching, the spin dependent interracial resistances, and the bulk spin polarization of the ferromagnetic layer on the spin polarized injection are also discussed.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB921603)the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China(Grant No.IRT13076)+4 种基金the Major Research Plan of the National Natural Science Foundation of China(Grant No.91436108)the National Natural Science Foundation of China(Grant Nos.61378014,61308023,61378015,and 11434007)the Fund for Fostering Talents in Basic Science of the National Natural Science Foundation of China(Grant No.J1103210)the New Teacher Fund of the Ministry of Education of China(Grant No.20131401120012)the Natural Science Foundation for Young Scientists of Shanxi Province,China(Grant No.2013021005-1)
文摘We report a robust method of directly stabilizing a grating feedback diode laser to an arbitrary frequency in a large range. The error signal, induced from the difference between the frequency measured by a wavelength meter and the preset target frequency, is fed back to the piezoelectric transducer module of the diode laser via a sound card in the computer. A visual Labview procedure is developed to realize a feedback system. In our experiment the frequency drift of the diode laser is reduced to 8 MHz within 25 min. The robust scheme can be adapted to realize the arbitrary frequency stabilization for many other kinds of lasers.
基金financial support provided by the National Natural Science Foundation of China(52064049)the Key National Natural Science Foundation of Yunnan Province(2018FA028 and 2019FY003023)+2 种基金International Joint Research Center for Advanced Energy Materials of Yunnan Province(202003AE140001)Key Laboratory of Solid State Ions for Green Energy of Yunnan University(2019)the Analysis and Measurements Center of Yunnan University for the sample testing service.
文摘Lithium metal batteries(LMBs)have attracted wide attentions because of their high theoretical specific capacity and low electrochemical potential.However,the growth of lithium dendrites seriously affects the practical application of LMBs.Thus,the lithium-philic carbonyl and carboxy dualgroup-modified covalent organic framework(COF-COOH)is designed to coat the polypropylene(PP)separator(COF-COOH@PP separator),realizing the regulation of ion transport and uniform lithium deposition.The plentiful and negative charge sites in the COF-COOH can suppress the diffusion of the freely movable lithium salt anion by the electrostatic interaction.Density functional theory(DFT)calculations demonstrate that the COF-COOH possesses the function of anchoring anion and desolvation.Consequently,the Li^(+)transference number(0.7),ion conductivity(0.64 mS cm^(-1)),and desolvating of Li^(+)are obviously improved by using the COF-COOH@PP separator.The modified Li-Li symmetric battery delivers stable cycle for more than 1000 h and lower voltage hysteresis(0.02 V).This dendrite-free deposition strategy holds great promise for practical application of Li metal anodes.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11475027,11274255 and 11305132the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grand No 20136203110001+1 种基金the Natural Science Foundation of Gansu Province under Grant No 1506RJYA131the Creation of Science and Technology of Northwest Normal University under Grant Nos NWNU-KJCXGC-03-48 and NWNU-LKQN-12-12
文摘We theoretically and numerically investigate the coherence of disordered bosonic gas with effective two- and three-body interactions within a two-site Bose-Hubbard model. By properly adjusting the two- and three-body interactions and the disorder, the coherence of the system exhibits new and interesting phenomena, including the resonance character of coherence against the disorder in the purely two- or three-body interactions system. More interestingly, the disorder and three-body interactions together can suppress the coherence of the purely three-body interactions system, which is different from the case in which the disorder and two-body interactions together can enhance the coherence in certain values of two.body interaction. Furthermore, when two- or three- body interactions are attractive or repulsive, the phase coherence exhibits completely different phenomena. In particular, if two- or three-body interactions are attractive, the coherence of the system can be significantly enhanced in certain regions. Correspondingly, the phase coherence of the system is strongly related to the effective interaction energy. The results provide a possible way for studying the coherence of bosonic gas with multi-atoms' interactions in the presence of the disorder.
基金supported by the National Natural Science Foundation of China(Nos.12175100 and 11975132)the Construct Program of the Key Discipline in Hunan Province+3 种基金the Research Foundation of the Education Bureau of Hunan Province,China(No.18A237)the Natural Science Foundation of Hunan Province,China(No.2018JJ2321)the Innovation Group of Nuclear and Particle Physics in USCthe Opening Project of the Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment,University of South China(No.2019KFZ10)。
文摘In this study,we systematically investigated the two-proton(2p)radioactivity half-lives from the excited state of nuclei near the proton drip line within the Gamowlike model(GLM)and modified Gamow-like model(MGLM).The calculated results were highly consistent with the theoretical values obtained using the unified fission model[Chin.Phys.C 45,124105(2021)],effective liquid drop model,and generalized liquid drop model[Acta Phys.Sin 71,062301(2022)].Furthermore,utilizing the GLM and MGLM,we predicted the 2p radioactivity halflives from the excited state for some nuclei that are not yet available experimentally.Simultaneously,by analyzing the calculated results from these theoretical models,it was found that the half-lives are strongly dependent on Qand l.
基金supported by the National Natural Science Foundation of China (Grant No.10875072)
文摘In this paper we study influences of Doppler broadening, spontaneously generated coherence, and other system parameters on propagation effect in a quasi lambda-type four-level atomic system. It is shown that when the Doppler broadening is present, generally speaking, the values of gain and intensity of lasing without inversion (i.e. the probe field) in the co-propagating probe and driving fields case are much larger than those in the counter-propagating case; considerably larger gain and intensity of lasing without inversion than those without the Doppler broadening can be obtained by choosing appropriate values of the Doppler broadening width and spontaneously generated coherence strength. The gain and intensity of lasing without inversion increase with the increase of spontaneously generated coherence strength; when spontaneously generated coherence is present, much larger gain and intensity of lasing without inversion than those in the case without spontaneously generated coherence can be obtained. Choosing suitable values of the probe detuning, Rabi frequencies of the driving and pump fields at the entrance of the medium also can remarkably enhance the gain and intensity of lasing without inversion.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10904083 and 10904084) the Shandong Provincial Distinguished Middle-Aged and Young Scientist Encourage and Reward Foundation,China (Grant No. BS2009CL008) the Science and Technology Foundation for Institution of Higher Education of Shandong Province,China (Grant No. J09LA03)
文摘From experimental results of spin polarized injection and transport in organic semiconductors(OSCs),we theoretically study the current spin polarization and magnetoresistance under an electric and a magnetic field in a ferromagnetic/organic semiconductor/ferromagnetic(FM/OSC/FM) sandwich structure according to the spin drift-diffusion theory and Ohm's law.From the calculations,it is found that the interfacial current spin polarization is enhanced by several orders of magnitude through tuning the magnetic and electric fields by taking into account the specific characteristics of OSC.Furthermore,the effects of the electric and magnetic fields on the magnetoresistance are also discussed in the sandwich structure.
基金supported by the 973 Program of China(Grant No 2006CB921603)the National Natural Science Foundation of China (Grant Nos 10574084,60678003 and 60778008)+1 种基金the Special Foundation for State Major Basic Research Program of China(Grant No 2005CCA06300)the Scholarship Foundation of Shanxi Province,China
文摘This paper reports that ultracold atoms are populated into different nS and nD Rydberg states (n=25-52) by two-photon excitation. The ionization spectrum of an ultracold Rydberg atom is acquired in a cesium magneto-optical trap by using the method of pulse field ionization. This denotes nS and nD states in the ionization spectrum and fits the data of energy levels of different Rydberg states to obtain quantum defects of nS and nD states.
基金Project supported by the National Natural Science Foundation of China (Grant No 60477026).
文摘Higher-order nonlinear Schrodinger equation with the Hirota constraint conditions is considered, and an analytic solution, which can describe the modulational instability process, is presented. Based on the solution, a new pulse train without continuous wave (CW) background is generated in quadratures and the propagation of the pulse train is discussed in detail by simulating numerically. The results show that, unlike the propagation of the picosecond pulse train, under the effects of the higher-order terms, the pulse train cannot propagate along the fibre when the energy is very high; however, for some medium energy the pulse train can stably propagate. We also investigate the stability of the pulse train against violation of the Hirota conditions, and the results show that the pulse train can still propagate stably when the Hirota conditions are broken.
基金Project supported by the National Natural Science Foundation of China(Grant No.11404179)
文摘We analyze the distribution properties of phase and phase vortices in a speckle field generated by N-pinhole random screens, and find that the phase vortex distributions show similarity and clustering in local regions. The phase patterns have a lot of sets composed of two phase vortices with opposite signs or four phase vortices which are positive and negative vortices alternately. Cases are also found where two adjacent phase vortices have the same topological charges. The density of phase vortices becomes larger with the increase of the radius of circumference and the number of pinholes on screen.Then, the relative positions of phase vortices can be adjusted by changing the radius of circumference and the number of pinholes.
基金Supported by the National Natural Science Foundation of China under Grant Nos 10974122 and 10874105, the Shandong Distinguished Middle-Aged and Young Scientist Encourage and Reward Foundation under Grant No 2007BS04031.
文摘The intensity distribution and phase vortices of the speckle fields generated by multi-aperture random scattering screens are simulated, and it is found that the vortices exhibit layer-like structures and the dislocation phenomena occur in the local phase patterns produced by the two-pinhole aperture, whose phase distributions appear as striped structures. For three- or four-pinhole aperture, there are many circular bright spots appearing in the speckle grains, and there is one vortex between the neighboring circular bright spots. The positive and negative phase vortex lattices appear in the phase distributions, and the regions circled by the isothetic phase lines form irregular quadrilaterals or hexagons. Moreover, the relative positions of the vortices or bright spots can be adjusted by changing those of the pinhole apertures.
基金supported by the National Natural Science Foundation of China(Nos.12175100 and 11975132)the Construct Program of the Key Discipline in Hunan Province,the Research Foundation of Education Bureau of Hunan Province,China(No.18A237)+1 种基金the Natural Science Foundation of Hunan Province,China(No.2018JJ2321)the Innovation Group of Nuclear and Particle Physics in USC,the Opening Project of Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment,University of South China(No.2019KFZ10).
文摘In the present work,we extend the Coulomb and Proximity Potential Model(CPPM)to study two-proton(2p)radioactivity from excited states while the proximity potential is chosen as AW95 proposed by Aage Withner in 1995.Demonstration reveals that the theoretical results acquired by CPPM exhibit a high level of consistency with prior theoretical models such as the unified fission model(UFM),generalized liquid-drop model(GLDM)and effective liquid-drop model(ELDM).Furthermore,within the CPPM,we predicted the half-lives of potential 2p radioactive nuclei for which experimental data are currently unavailable.The predicted results were then assessed,compared with UFM,ELDM and GLDM models,and examined in detail.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11475027,11764039,11274255,and 11305132)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20136203110001)Scientific Research Project of Gansu Higher Education,China(Grant No.2016A-005)
文摘We investigate the tunneling dynamics of a few bosons with both two-and three-body interactions in a doublewell potential. Uncorrelated tunneling of Rabi oscillation with the minimum period can happen only when the two-and three-body interactions satisfy a critical condition, i.e., the effective interaction energy is minimized. When the atomic interactions are slightly away from the critical condition in the weak interaction regime, the uncorrelated tunneling exhibits collapse-revival character. When the atomic interactions are strong and far away from the critical condition, the correlated tunneling with Rabi oscillation occurs. The tunneling period(the period of collapse-revival) increases(decreases) when the rate between the two-body and three-body interactions is away from the corresponding critical condition or when the number of bosons increases. Further, the tunneling properties are understood with the help of the energy spectrum of the system. Eventually, the effect of the initial configuration on the tunneling dynamics of a few bosons for both odd and even numbers of bosons is studied, which results in intriguing consequences.
文摘The passively Q-switched and mode-locked(QML) characteristics in a diode-pumped Nd∶GdVO4 laser with Cr4+∶YAG saturable absorbers have been demonstrated. A maximum average output power of 710mW has been obtained in the QML laser. The maximum energy of a single Q-switched pulse is 52.5μJ, with the corresponding pulse width of 30ns and the peak power of 1.75kW, at the incident pump power of 7.75W. The repetition rates of the Q-switched envelope and the mode-locked laser pulse are 16.7kHz and 680MHz, respectively.
基金Project supported by the National Natural Science Foundation of China(Grant No.11404112)the Funding Scheme for Young Teachers in Colleges and Universities in Henan Province,China(Grant No.2017GGJS077)the Key Scientific Research Project of Colleges and Universities of Henan Province,China(Grant No.18A140023)
文摘Owing to the importance of excited state dynamical relaxation, the excited state intramolecular proton transfer(ESIPT) mechanism for a novel compound containing dual hydrogen bond(abbreviated as "1-enol") is studied in this work.Using density functional theory(DFT) and time-dependent density functional theory(TDDFT) method, the experimental electronic spectra can be reproduced for 1-enol compound. We first verify the formation of dual intramolecular hydrogen bonds, and then confirm that the dual hydrogen bond should be strengthened in the first excited state. The photo-excitation process is analyzed by using frontier molecular orbital(HOMO and LUMO) for 1-enol compound. The obvious intramolecular charge transfer(ICT) provides the driving force to effectively facilitate the ESIPT process in the S1 state. Exploration of the constructed S0-state and S1-state potential energy surface(PES) reveals that only the excited state intramolecular single proton transfer occurs for 1-enol system, which makes up for the deficiencies in previous experiment.