Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysi...Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that： （1） up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; （2） high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; （3） in gas reservoirs of such abiotic methane （〉80%） and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; （4） a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.展开更多
Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks incl...Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks include rhyolite, andesite, Wachyte, basalt and tuff. Facies of the volcanic rocks can be classified into 5 categories and 15 special types. Porosity and permeability of the volcanic reservoirs arc facies-controlled, Commercial reservoirs were commonly found among the following volcanic subfacics： volcanic neck （Ⅰ1）, underground-explosive breccia （Ⅰ3）, pyroclastic-bcaring lava flow （Ⅱ3）, upper effusivc （Ⅲ3） and inner extrusive ones （ Ⅳ1）. The best volcanic reservoirs arc generally evolved in the interbedded explosive and effusivc volcanics. Rhyolites show in general better reservoir features than other types of rocks do.展开更多
文摘Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that： （1） up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; （2） high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; （3） in gas reservoirs of such abiotic methane （〉80%） and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; （4） a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.
文摘Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks include rhyolite, andesite, Wachyte, basalt and tuff. Facies of the volcanic rocks can be classified into 5 categories and 15 special types. Porosity and permeability of the volcanic reservoirs arc facies-controlled, Commercial reservoirs were commonly found among the following volcanic subfacics： volcanic neck （Ⅰ1）, underground-explosive breccia （Ⅰ3）, pyroclastic-bcaring lava flow （Ⅱ3）, upper effusivc （Ⅲ3） and inner extrusive ones （ Ⅳ1）. The best volcanic reservoirs arc generally evolved in the interbedded explosive and effusivc volcanics. Rhyolites show in general better reservoir features than other types of rocks do.
