Over the years,zinc-ion batteries(ZIBs)have attracted attention as a promising next-generation energy storage technology because of their excellent safety,long cycling performance,eco-friendliness,and high-power densi...Over the years,zinc-ion batteries(ZIBs)have attracted attention as a promising next-generation energy storage technology because of their excellent safety,long cycling performance,eco-friendliness,and high-power density.However,issues,such as the corrosion and dissolution of the Zn anode,limited wet-tability,and lack of sufficient nucleation sites for Zn plating,have limited their practical application.The introduction of a protective layer comprising of tellurium(Te)nanobelts onto the surface of Zn anode has emerged as a promising approach to overcome these limitations and improve the electrochemical behav-ior by enhancing the safety and wettability of ZIBs,as well as providing numerous nucleation sites for Zn plating.In the presence of a Te-based protective layer,the energy power density of the surface-engineered Zn anode improved significantly(ranging from 310 to 144 W h kg^(-1),over a power density range of 270 to 1,800 W kg^(-1)),and the lifespan capability was extended.These results demonstrate that the proposed strategy of employing Te nanobelts as a protective layer holds great promise for enhancing the energy storage performance of zIBs,making them even more attractive as a viable energy storage solution forthefuture.展开更多
The discovery of efficient,selective,and stable electrocatalysts can be a key point to produce the largescale chemical fuels via electrochemical CO_(2) reduction(ECR).In this study,an earth-abundant and nontoxic ZnO-b...The discovery of efficient,selective,and stable electrocatalysts can be a key point to produce the largescale chemical fuels via electrochemical CO_(2) reduction(ECR).In this study,an earth-abundant and nontoxic ZnO-based electrocatalyst was developed for use in gas-diffusion electrodes(GDE),and the effect of nitrogen(N)doping on the ECR activity of ZnO electrocatalysts was investigated.Initially,a ZnO nanosheet was prepared via the hydrothermal method,and nitridation was performed at different times to control the N-doping content.With an increase in the N-doping content,the morphological properties of the nanosheet changed significantly,namely,the 2D nanosheets transformed into irregularly shaped nanoparticles.Furthermore,the ECR performance of Zn O electrocatalysts with different N-doping content was assessed in 1.0 M KHCO_(3) electrolyte using a gas-diffusion electrode-based ECR cell.While the ECR activity increased after a small amount of N doping,it decreased for higher N doping content.Among them,the N:ZnO-1 h electrocatalysts showed the best CO selectivity,with a faradaic efficiency(FE_(CO))of 92.7%at-0.73 V vs.reversible hydrogen electrode(RHE),which was greater than that of an undoped Zn O electrocatalyst(FE_(CO)of 63.4%at-0.78 V_(RHE)).Also,the N:ZnO-1 h electrocatalyst exhibited outstanding durability for 16 h,with a partial current density of-92.1 mA cm^(-2).This improvement of N:ZnO-1 h electrocatalyst can be explained by density functional theory calculations,demonstrating that this improvement of N:ZnO-1 h electrocatalyst comes from(ⅰ)the optimized active sites lowering the free energy barrier for the rate-determining step(RDS),and(ⅱ)the modification of electronic structure enhancing the electron transfer rate by N doping.展开更多
As lead halide perovskite(LHP)semiconductors have shown tremendous promise in many application fields,and particularly made strong impact in the solar photovoltaic area,low dimensional quantum dot forms of these perov...As lead halide perovskite(LHP)semiconductors have shown tremendous promise in many application fields,and particularly made strong impact in the solar photovoltaic area,low dimensional quantum dot forms of these perovskites are showing the potential to make distinct marks in the fields of electronics,optoelectronics and photonics.The so-called perovskite quantum dots(PQDs)not only possess the most important features of LHP materials,i.e.,the unusual high defect tolerance,but also demonstrate clear quantum size effects,along with exhibiting desirable optoelectronic properties such as near perfect photoluminescent quantum yield,multiple exciton generation and slow hot-carrier cooling.Here,we review the advantageous properties of these nanoscale perovskites and survey the prospects for diverse applications which include lightemitting devices,solar cells,photocatalysts,lasers,detectors and memristors,emphasizing the distinct superiorities as well as the challenges.展开更多
Bio-cement and bio-concrete are innovative solutions for sustainable construction, aiming to reduce environmental impact while maintaining the durability and versatility of building materials. Bio-cement is an eco-fri...Bio-cement and bio-concrete are innovative solutions for sustainable construction, aiming to reduce environmental impact while maintaining the durability and versatility of building materials. Bio-cement is an eco-friendly alternative to traditional cement, produced through Microbially Induced Calcium Carbonate Precipitation (MICP), which mimics natural biomineralization processes. This method reduces CO2 emissions and enhances the strength and durability of construction materials. Bio-concrete incorporates bio-cement into concrete, creating a self-healing material. When cracks form in bio-concrete, dormant bacteria within the material become active in the presence of water, producing limestone to fill the cracks, extending the material’s lifespan and reducing the need for repairs. The environmental impact of traditional cement production is significant, with cement generation accounting for up to 8% of global carbon emissions. Creative solutions are needed to develop more sustainable construction materials, with some efforts using modern innovations to make concrete ultra-durable and others turning to science to create affordable bio-cement. The research demonstrates the potential of bio-cement to revolutionize sustainable building practices by offering a low-energy, low-emission alternative to traditional cement while also addressing environmental concerns. The findings suggest promising applications in various construction scenarios, including earthquake-prone areas, by enhancing material durability and longevity through self-repair mechanisms.展开更多
Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the c...Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical performance.In this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle effect.OM-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain catenation.The OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g^(-1) after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g^(-1) even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g^(-1)).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.展开更多
In this paper,the installation of energy storage systems(EES)and their role in grid peak load shaving in two echelons,their distribution and generation are investigated.First,the optimal placement and capacity of the ...In this paper,the installation of energy storage systems(EES)and their role in grid peak load shaving in two echelons,their distribution and generation are investigated.First,the optimal placement and capacity of the energy storage is taken into consideration,then,the charge-discharge strategy for this equipment is determined.Here,Genetic Algorithm(GA)and Particle Swarm Optimization(PSO)are used to calculate the minimum and maximum load in the network with the presence of energy storage systems.The energy storage systems were utilized in a distribution system with the aid of a peak load shaving approach.Ultimately,the battery charge-discharge is managed at any time during the day,considering the load consumption at each hour.The results depict that the load curve reached a constant state by managing charge-discharge with no significant changes.This shows the significance of such matters in terms of economy and technicality.展开更多
Implementing machine learning algorithms in the non-conducive environment of the vehicular network requires some adaptations due to the high computational complexity of these algorithms.K-clustering algorithms are sim...Implementing machine learning algorithms in the non-conducive environment of the vehicular network requires some adaptations due to the high computational complexity of these algorithms.K-clustering algorithms are simplistic,with fast performance and relative accuracy.However,their implementation depends on the initial selection of clusters number(K),the initial clusters’centers,and the clustering metric.This paper investigated using Scott’s histogram formula to estimate the K number and the Link Expiration Time(LET)as a clustering metric.Realistic traffic flows were considered for three maps,namely Highway,Traffic Light junction,and Roundabout junction,to study the effect of road layout on estimating the K number.A fast version of the PAM algorithm was used for clustering with a modification to reduce time complexity.The Affinity propagation algorithm sets the baseline for the estimated K number,and the Medoid Silhouette method is used to quantify the clustering.OMNET++,Veins,and SUMO were used to simulate the traffic,while the related algorithms were implemented in Python.The Scott’s formula estimation of the K number only matched the baseline when the road layout was simple.Moreover,the clustering algorithm required one iteration on average to converge when used with LET.展开更多
In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional t...In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.展开更多
Owing to the persisting hype in pushing toward global carbon neutrality,the study scope of atmospheric science is rapidly expanding.Among numerous trending topics,energy meteorology has been attracting the most attent...Owing to the persisting hype in pushing toward global carbon neutrality,the study scope of atmospheric science is rapidly expanding.Among numerous trending topics,energy meteorology has been attracting the most attention hitherto.One essential skill of solar energy meteorologists is solar power curve modeling,which seeks to map irradiance and auxiliary weather variables to solar power,by statistical and/or physical means.In this regard,this tutorial review aims to deliver a complete overview of those fundamental scientific and engineering principles pertaining to the solar power curve.Solar power curves can be modeled in two primary ways,one of regression and the other of model chain.Both classes of modeling approaches,alongside their hybridization and probabilistic extensions,which allow accuracy improvement and uncertainty quantification,are scrutinized and contrasted thoroughly in this review.展开更多
Layered-type transition metal(TM)oxides are considered as one of the most promising cathodes for K-ion batteries because of the large theoretical gravimetric capacity by low molar mass.However,they suffer from severe ...Layered-type transition metal(TM)oxides are considered as one of the most promising cathodes for K-ion batteries because of the large theoretical gravimetric capacity by low molar mass.However,they suffer from severe structural change by de/intercalation and diffusion of K^(+)ions with large ionic size,which results in not only much lower reversible capacity than the theoretical capacity but also poor power capability.Thus,it is important to enhance the structural stability of the layered-type TM oxides for outstanding electrochemical behaviors under the K-ion battery system.Herein,it is investigated that the substitution of the appropriate Ti^(4+)contents enables a highly enlarged reversible capacity of P3-type KxCrO_(2) using combined studies of first-principles calculation and various experiments.Whereas the pristine P3-type KxCrO_(2) just exhibits the reversible capacity of∼120 mAh g^(−1) in the voltage range of 1.5-4.0 V(vs.K^(+)/K),the∼0.61 mol K^(+)corresponding to∼150 mAh g^(−1) can be reversible de/intercalated at the structure of P3-type K0.71[Cr_(0.75)Ti_(0.25)]O_(2) under the same conditions.Furthermore,even at the high current density of 788 mA g^(−1),the specific capacity of P3-type K0.71[Cr_(0.75)Ti_(0.25)]O_(2) is∼120 mAh g^(−1),which is∼81 times larger than that of the pristine P3-type KxCrO_(2).It is believed that this research can provide an effective strategy to improve the electrochemical performances of the cathode materials suffered by severe structural change that occurred during charge/discharge under not only K-ion battery system but also other rechargeable battery systems.展开更多
This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1...This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1.00 m in width.The related reflector is made of lined sheets of aluminum,and the tubes are made of stainless steel used for the absorption of heat.They have an outer diameter of 0.051 m and a wall thickness of 0.002 m.Water,used as a heat transfer fluid(HTF),flows through the absorber tube at a mass flow rate of 0.7 kg/s.The dimensions of cylindrical turbulators are 0.04 m in length and 0.047 m in diameter.Simulations are performed using the ANSYS Fluent 2020 R2 software.The PTC performance is evaluated by comparing the experimental and numerical outcomes,namely,the outlet temperature,useful heat,and thermal efficiency for a modified tube(MT)(tube with novel cylindrical turbulators)and a plain tube(PT)(tube without novel cylindrical turbulators).According to the results,the experimental outlet temperatures recorded 63.2°C and 50.5°C for the MT and PT,respectively.The heat gain reaches 1137.5 Win the MT and 685.8 Win the PT.Compared to the PT collector,the PTC exhibited a(1.64 times)higher efficiency.展开更多
Small coin cell batteries are predominantly used for testing lithium-ion batteries(LIBs)in academia because they require small amounts of material and are easy to assemble.However,insufficient attention is given to di...Small coin cell batteries are predominantly used for testing lithium-ion batteries(LIBs)in academia because they require small amounts of material and are easy to assemble.However,insufficient attention is given to difference in cell performance that arises from the differences in format between coin cells used by academic researchers and pouch or cylindrical cells which are used in industry.In this article,we compare coin cells and pouch cells of different size with exactly the same electrode materials,electrolyte,and electrochemical conditions.We show the battery impedance changes substantially depending on the cell format using techniques including Electrochemical Impedance Spectroscopy(EIS)and Galvanostatic Intermittent Titration Technique(GITT).Using full cell NCA-graphite LIBs,we demonstrate that this difference in impedance has important knock-on effects on the battery rate performance due to ohmic polarization and the battery life time due to Li metal plating on the anode.We hope this work will help researchers getting a better idea of how small coin cell formats impact the cell performance and help predicting improvements that can be achieved by implementing larger cell formats.展开更多
The increase in oil prices and greenhouse gas emissions has led to the search for substitutes for fossil fuels. In Cameroon, the abundance of lignocellulosic resources is inherent to agricultural activity. Production ...The increase in oil prices and greenhouse gas emissions has led to the search for substitutes for fossil fuels. In Cameroon, the abundance of lignocellulosic resources is inherent to agricultural activity. Production of bioethanol remains a challenge given the crystallinity of cellulose and the presence of the complex. The pretreatment aimed to solubilize the lignin fraction and to make cellulose more accessible to the hydrolytic enzymes, was done using the organosolv process. A mathematical modeling was performed to point out the effect of the temperature on the kinetics of the release of the reducing sugars during the pretreatment. Two mathematical model was used, SAEMAN’s model and Response surface methodology. The first show that the kinetic parameters of the hydrolysis of the cellulose and reducing sugar are: 0.05089 min<sup>-1</sup>, 5358.1461 J·mol<sup>-1</sup>, 1383.03691 min<sup>-1</sup>, 51577.6100 J·mol<sup>-1</sup> respectively. The second model was used. Temperature is the factor having the most positive influence whereas, ethanol concentration is not an essential factor. To release the maximum, an organosolv pre-treatment of this sub-strate should be carried out at 209.08°C for 47.60 min with an ethanol-water ratio of 24.02%. Organosolv pre-treatment is an effective process for delignification of the lignocellulosic structure.展开更多
The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips an...The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips and husks are materials which can have good thermal conductivity and therefore the combination of these precursors could make it possible to obtain panels with good insulating properties. With regard to environmental and climatic constraints, the composite panels formulated at various rates were tested and the physico-mechanical and thermal properties showed that it was essential to add a crosslinker in order to increase certain solicitation. an incorporation rate of 12% to 30% made it possible to obtain panels with low thermal conductivity, a low surface water absorption capacity and which gives the composite good thermal insulation and will find many applications in the construction and real estate sector. Finally, new solutions to improve the fire reaction of the insulation panels are tested which allows to identify suitable solutions for the developed composites. In view of the flame tests, the panels obtained are good and can effectively combat fire safety in public buildings.展开更多
Preparation of hierarchically porous, heteroatom-rich nanostructured carbons through green and scalable routes plays a key role for practical energy storage applications. In this work, naturally abundant lignocellulos...Preparation of hierarchically porous, heteroatom-rich nanostructured carbons through green and scalable routes plays a key role for practical energy storage applications. In this work, naturally abundant lignocellulosic agricultural waste with high initial oxygen content, hazelnut shells, were hydrothermally carbonized and converted into nanostructured ‘hydrochar’. Environmentally benign ceramic/magnesium oxide(Mg O) templating was used to introduce porosity into the hydrochar. Electrochemical performance of the resulting material(HM700) was investigated in aqueous solutions of 1 M H;SO;, 6 M KOH and1 M Na;SO;, using a three-electrode cell. HM700 achieved a high specific capacitance of 323.2 F/g in 1 M H;SO;(at 1 A/g,-0.3 to 0.9 V vs. Ag/Ag Cl) due to the contributions of oxygen heteroatoms(13.5 wt%)to the total capacitance by pseudo-capacitive effect. Moreover, a maximum energy density of 11.1 Wh/kg and a maximum power density of 3686.2 W/kg were attained for the symmetric supercapacitor employing HM700 as electrode material(1 M Na;SO;, E = 2 V), making the device promising for green supercapacitor applications.展开更多
Lithium/Sodium-ion batteries(LIB/SIB)have attracted enormous attention as a promising electrochemical energy storage system due to their high energy density and long cycle life.One of the major hurdles is the initial ...Lithium/Sodium-ion batteries(LIB/SIB)have attracted enormous attention as a promising electrochemical energy storage system due to their high energy density and long cycle life.One of the major hurdles is the initial irreversible capacity loss during the first few cycles owing to forming the solid electrolyte interphase layer(SEI).This process consumes a profusion of lithium/sodium,which reduces the overall energy density and cycle life.Thus,a suitable approach to compensate for the irreversible capacity loss must be developed to improve the energy density and cycle life.Pre-lithiation/sodiation is a widely accepted process to compensate for the irreversible capacity loss during the initial cycles.Various strategies such as physical,chemical,and electrochemical pre-lithiation/sodiation have been explored;however,these approaches add an extra step to the current manufacturing process.Alternative to these strategies,pre-lithiation/sodiation additives have attracted enormous attention due to their easy adaptability and compatibility with the current battery manufacturing process.In this review,we consolidate recent developments and emphasize the importance of using pre-lithiation/sodiation additives(anode and cathode)to overcome the irreversible capacity loss during the initial cycles in lithium/sodium-ion batteries.This review also addresses the technical and scientific challenges of using pre-lithiation/sodiation additives and offers the insights to boost the energy density and cycle life with their possible commercial exploration.The most important prerequisites for designing effective pre-lithiation/sodiation additives have been explored and the future directions have been discussed.展开更多
Aqueous foam is broadly applicable to enhanced oil recovery(EOR).The rheology of foam as a function of foam quality,gas and liquid velocities,and surfactant concentration constitute the foundation of its application.T...Aqueous foam is broadly applicable to enhanced oil recovery(EOR).The rheology of foam as a function of foam quality,gas and liquid velocities,and surfactant concentration constitute the foundation of its application.The great variations of the above factors can affect the effectiveness of N2 foam in EOR continuously in complex formations,which is rarely involved in previous relevant studies.This paper presents an experimental study of foam flow in porous media by injecting pre-generated N2 foam into a sand pack under the conditions of considering a wide range of gas and liquid velocities and surfactant concentrations.The results show that in a wide range of gas and liquid velocities,the pressure gradient contours are L-shaped near the coordinate axes,but V-shaped in other regions.And the surfactant concentration is a strong factor influencing the trend of pressure gradient contours.Foam flow resistance is very sensitive to the surfactant concentration in both the high-and low-foam quality regime,especially when the surfactant concentration is less than CMC.The foam quality is an important variable to the flow resistance obtained.There exists a transition point from low-to high-quality regime in a particular flow system,where has the maximum flow resistance,the corresponding foam quality is called transition foam quality,which increases as the surfactant concentration increases.The results can add to our knowledge base of foam rheology in porous media,and can provide a strong basis for the field application of foams.展开更多
In this paper, neutronic analysis in a laser fusion inertial confinement fusion fission energy (LIFE) engine fuelled plutonium and minor actinides using a MCNP codes was investigated. LIFE engine fuel zone contained...In this paper, neutronic analysis in a laser fusion inertial confinement fusion fission energy (LIFE) engine fuelled plutonium and minor actinides using a MCNP codes was investigated. LIFE engine fuel zone contained 10 vol% TRISO particles and 90 vol% natural lithium coolant mixture. TRISO fuel compositions have Mod①: reactor grade plutonium (RG-Pu), Mod②: weapon grade plutonium (WG-Pu) and Mod③: minor actinides (MAs). Tritium breeding ratios (TBR) were computed as 1.52, 1.62 and 1.46 for Mod(D, Mod② and Mod③, respectively. The operation period was computed as ~21 years when the reference TBR 〉 1.05 for a self- sustained reactor for all investigated cases. Blanket energy multiplication values (M) were calculated as 4.18, 4.95 and 3.75 for Mod①, Mod② and Mod③, respectively. The bumup (BU) values were obtained as ~1230, ~1550 and ~1060 GWd tM-1, respectively. As a result, the higher BU were provided with using TRISO particles for all cases in LIFE engine.展开更多
Residual oil zones(ROZs)have large potential for CO_(2)enhanced oil recovery(EOR)and geologic storage.During CO_(2)injection,the migration of CO_(2)in ROZs controls the performance of both EOR and storage.However,it h...Residual oil zones(ROZs)have large potential for CO_(2)enhanced oil recovery(EOR)and geologic storage.During CO_(2)injection,the migration of CO_(2)in ROZs controls the performance of both EOR and storage.However,it has not been clearly visualized and understood that how geological heterogeneity factors control the transport of CO_(2)in ROZs.In this study,the oil recovery performance and geologic storage potential during continuous CO_(2)injection in a representative ROZ are studied based on geostatistical modelling and high-fidelity three-phase flow simulation.We examined the influence of autocorrelation length of permeability,global heterogeneity(DykstraeParsons coefficient),and permeability anisotropy on cumulative oil recovery and CO_(2)retention fraction.Simulation results indicate that,as the permeability autocorrelation length increases,the cumulative oil recovery and CO_(2)storage efficiency decrease.This results from the accelerated migration of CO_(2)along high permeability zones(i.e.,gas channeling).The increase in global heterogeneity and permeability anisotropies can lead to low oil recovery and poor CO_(2)sequestration performance,depending on the degree of CO_(2)channeling.The net utilization ratio of CO_(2)(CO_(2)retained/oil produced)unfavorably increases with both autocorrelation length and Dykstra eParsons coefficient,but decreases with the increase in kv/kh.Such a decrease is attributed to enlarged swept volume induced by gravity override.The study provides important implications for fieldscale CO_(2)EOR and storage applications in ROZs.展开更多
Uttarakhand state comes under special category state where approximately 69.45% population lived in rural area under the population density with varied range of 37 to 607 persons per sq.km. Although Uttarakhand is hav...Uttarakhand state comes under special category state where approximately 69.45% population lived in rural area under the population density with varied range of 37 to 607 persons per sq.km. Although Uttarakhand is having per capita consumption of 1112.29 kWh which is higher than national average per capita consumption of 779 kWh as till date, but remote communities, villages are not able to access clean, cheep and good quality of energy due to uneven terrain, lack of proper transmission & distribution lines [1]. 100% villages are electrified under the RGGVY scheme as per the Ministry of Power Government of India, but due to poor loading of transformer, lack of grid infrastructure and natural calamities, remote house owners are not able to get good quality of power thus affect the livelihood and source of income generation in various means [2]. As Uttarakhand state having future plans to be make state energy sufficient and energy access to all by year 2016-2017, so major ground level initiative have been taken by Government of Uttarakhand. The government of Uttarakhand has incorporated innovative business model to provide good quality of power with non-conventional energy source. Under the initiative invlovement of local people and village level, panchayats have ownership and responsibility to operate these clean energy business model to improve livelihood in remote hilly places of Uttarakhand. Under this analysis, five different type of community models are categorized as Community 1, Community 2, Community 3, Standalone 1 & Standalone 2 for rural &remote communities based on number of unclustered households with the distance covered between 200 m to 20 km, and electrical loads i.e. lighting, fan, mobile chargers, television along with time of day energy consumption patterns. These community models are for remote hilly location where grid integration and distribution lines are not feasible to built due to hilly terrain, low soil strength and huge expenses for expanding power cables for supplying good quality power. The preliminary studies and simulations has been done in HOMER tool by considering the various composite source of power, i.e. Solar PV with battery bank, Solar PV with battery Bank & Generator, and Solar PV along with DG. These three hybrid source of power generation with Solar PV as base source under five different community models, the techno-commercial feasibility has been analyzed in terms of load sharing proposition with Solar PV and battery, DG, Energy production through PV, load consumption per year, Excess and unmet energy monitoring, battery sizing to meet the load during nights, DG operation when the solar energy not available due to weather condition and non availability of sunshine in night. Financial feasibility has been examined in terms of levelized cost of energy, cost summary and O&M cost per year of three integrated sources of energy generation with Solar PV under each community model. Solar PV power plant , which is the best renewable source of energy to cater energy access issue in remote hilly places. The Uttarakhand receives good amout of daily average radiation level of 5.14 - 5.50 kWh/m2/day. Financial feasible community models for different hilly region based on their energy consumption need to be implemented with the help of local community by providing ownership to local people, panchayat, for it not only caters energy access issue but also provides clean, cheep, uninterruptable energy and improves livelihood standard to locals by engaging them into operation maintenance and tariff or rent collection. The study shows that Solar PV power plant with battery bank is the optimal solution considering life cycle cost of hybrid system. It is feasible due to low operation and maintenance cost, price declination of battery and Solar PV module, battery prices at time of replacement.展开更多
基金supported by the Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korea government(MOTIE)(RS-2023-00303581,Multiscale Simulation-Driven Development of Cost-Effective and Stable Aqueous Zn Ion Battery with Energy Density of 110 Wh/L for Energy Storage Systems:A Korea-USA Collaboration)。
文摘Over the years,zinc-ion batteries(ZIBs)have attracted attention as a promising next-generation energy storage technology because of their excellent safety,long cycling performance,eco-friendliness,and high-power density.However,issues,such as the corrosion and dissolution of the Zn anode,limited wet-tability,and lack of sufficient nucleation sites for Zn plating,have limited their practical application.The introduction of a protective layer comprising of tellurium(Te)nanobelts onto the surface of Zn anode has emerged as a promising approach to overcome these limitations and improve the electrochemical behav-ior by enhancing the safety and wettability of ZIBs,as well as providing numerous nucleation sites for Zn plating.In the presence of a Te-based protective layer,the energy power density of the surface-engineered Zn anode improved significantly(ranging from 310 to 144 W h kg^(-1),over a power density range of 270 to 1,800 W kg^(-1)),and the lifespan capability was extended.These results demonstrate that the proposed strategy of employing Te nanobelts as a protective layer holds great promise for enhancing the energy storage performance of zIBs,making them even more attractive as a viable energy storage solution forthefuture.
基金supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) (Grant Nos.2018R1A6A1A03024334,2019R1A2C1007637,2021M3I3A1082880,2021R1I1A1A01044174)the Basic Science Research Capacity Enhancement Project through Korea Basic Science Institute (Grant No.2019R1A6C1010024)。
文摘The discovery of efficient,selective,and stable electrocatalysts can be a key point to produce the largescale chemical fuels via electrochemical CO_(2) reduction(ECR).In this study,an earth-abundant and nontoxic ZnO-based electrocatalyst was developed for use in gas-diffusion electrodes(GDE),and the effect of nitrogen(N)doping on the ECR activity of ZnO electrocatalysts was investigated.Initially,a ZnO nanosheet was prepared via the hydrothermal method,and nitridation was performed at different times to control the N-doping content.With an increase in the N-doping content,the morphological properties of the nanosheet changed significantly,namely,the 2D nanosheets transformed into irregularly shaped nanoparticles.Furthermore,the ECR performance of Zn O electrocatalysts with different N-doping content was assessed in 1.0 M KHCO_(3) electrolyte using a gas-diffusion electrode-based ECR cell.While the ECR activity increased after a small amount of N doping,it decreased for higher N doping content.Among them,the N:ZnO-1 h electrocatalysts showed the best CO selectivity,with a faradaic efficiency(FE_(CO))of 92.7%at-0.73 V vs.reversible hydrogen electrode(RHE),which was greater than that of an undoped Zn O electrocatalyst(FE_(CO)of 63.4%at-0.78 V_(RHE)).Also,the N:ZnO-1 h electrocatalyst exhibited outstanding durability for 16 h,with a partial current density of-92.1 mA cm^(-2).This improvement of N:ZnO-1 h electrocatalyst can be explained by density functional theory calculations,demonstrating that this improvement of N:ZnO-1 h electrocatalyst comes from(ⅰ)the optimized active sites lowering the free energy barrier for the rate-determining step(RDS),and(ⅱ)the modification of electronic structure enhancing the electron transfer rate by N doping.
基金supported by the National Natural Science Foundation of China(Grant No.52102266,12204167)the China Postdoctoral Science Foundation(2020M680861)+4 种基金the support from the Department of Science and Technology-Science and Engineering Research Board(DST-SERB),Government of India(project no.SRG/2020/000258)CSIR-Indian Institute of Chemical Technology,Hyderabadsupported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.2022R1A5A1032539,2022R1C1C1008282)Industrial Strategic Technology Development Program-Alchemist Project(1415180859,Chiral perovskite LED smart contact lens based hyper vision metaverse)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)Korea Evaluation Institute of Industrial Technology(KEIT,Korea).
文摘As lead halide perovskite(LHP)semiconductors have shown tremendous promise in many application fields,and particularly made strong impact in the solar photovoltaic area,low dimensional quantum dot forms of these perovskites are showing the potential to make distinct marks in the fields of electronics,optoelectronics and photonics.The so-called perovskite quantum dots(PQDs)not only possess the most important features of LHP materials,i.e.,the unusual high defect tolerance,but also demonstrate clear quantum size effects,along with exhibiting desirable optoelectronic properties such as near perfect photoluminescent quantum yield,multiple exciton generation and slow hot-carrier cooling.Here,we review the advantageous properties of these nanoscale perovskites and survey the prospects for diverse applications which include lightemitting devices,solar cells,photocatalysts,lasers,detectors and memristors,emphasizing the distinct superiorities as well as the challenges.
文摘Bio-cement and bio-concrete are innovative solutions for sustainable construction, aiming to reduce environmental impact while maintaining the durability and versatility of building materials. Bio-cement is an eco-friendly alternative to traditional cement, produced through Microbially Induced Calcium Carbonate Precipitation (MICP), which mimics natural biomineralization processes. This method reduces CO2 emissions and enhances the strength and durability of construction materials. Bio-concrete incorporates bio-cement into concrete, creating a self-healing material. When cracks form in bio-concrete, dormant bacteria within the material become active in the presence of water, producing limestone to fill the cracks, extending the material’s lifespan and reducing the need for repairs. The environmental impact of traditional cement production is significant, with cement generation accounting for up to 8% of global carbon emissions. Creative solutions are needed to develop more sustainable construction materials, with some efforts using modern innovations to make concrete ultra-durable and others turning to science to create affordable bio-cement. The research demonstrates the potential of bio-cement to revolutionize sustainable building practices by offering a low-energy, low-emission alternative to traditional cement while also addressing environmental concerns. The findings suggest promising applications in various construction scenarios, including earthquake-prone areas, by enhancing material durability and longevity through self-repair mechanisms.
基金Ministry of Trade,Industry and Energy,Grant/Award Number:20010095Korea Evaluation Institute of Industrial Technology,Grant/Award Number:20012341。
文摘Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical performance.In this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle effect.OM-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain catenation.The OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g^(-1) after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g^(-1) even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g^(-1)).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.
基金supported in part by an International Research Partnership“Electrical Engineering-Thai French Research Center(EE-TFRC)”under the project framework of the Lorraine Universitéd’Excellence(LUE)in cooperation between Universitéde Lorraine and King Mongkut’s University of Technology North Bangkok and in part by the National Research Council of Thailand(NRCT)under Senior Research Scholar Program under Grant No.N42A640328.
文摘In this paper,the installation of energy storage systems(EES)and their role in grid peak load shaving in two echelons,their distribution and generation are investigated.First,the optimal placement and capacity of the energy storage is taken into consideration,then,the charge-discharge strategy for this equipment is determined.Here,Genetic Algorithm(GA)and Particle Swarm Optimization(PSO)are used to calculate the minimum and maximum load in the network with the presence of energy storage systems.The energy storage systems were utilized in a distribution system with the aid of a peak load shaving approach.Ultimately,the battery charge-discharge is managed at any time during the day,considering the load consumption at each hour.The results depict that the load curve reached a constant state by managing charge-discharge with no significant changes.This shows the significance of such matters in terms of economy and technicality.
文摘Implementing machine learning algorithms in the non-conducive environment of the vehicular network requires some adaptations due to the high computational complexity of these algorithms.K-clustering algorithms are simplistic,with fast performance and relative accuracy.However,their implementation depends on the initial selection of clusters number(K),the initial clusters’centers,and the clustering metric.This paper investigated using Scott’s histogram formula to estimate the K number and the Link Expiration Time(LET)as a clustering metric.Realistic traffic flows were considered for three maps,namely Highway,Traffic Light junction,and Roundabout junction,to study the effect of road layout on estimating the K number.A fast version of the PAM algorithm was used for clustering with a modification to reduce time complexity.The Affinity propagation algorithm sets the baseline for the estimated K number,and the Medoid Silhouette method is used to quantify the clustering.OMNET++,Veins,and SUMO were used to simulate the traffic,while the related algorithms were implemented in Python.The Scott’s formula estimation of the K number only matched the baseline when the road layout was simple.Moreover,the clustering algorithm required one iteration on average to converge when used with LET.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(NRF-2022R1C1C1011058)。
文摘In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.
基金supported by the National Natural Science Foundation of China(project no.42375192),and the China Meteorological Administration Climate Change Special Program(CMA-CCSPproject no.QBZ202315)+2 种基金supported by the National Natural Science Foundation of China(project no.42030608)supported by the National Research,Development and Innovation Fund,project no.OTKA-FK 142702by the Hungarian Academy of Sciences through the Sustainable Development and Technologies National Programme(FFT NP FTA)and the János Bolyai Research Scholarship.
文摘Owing to the persisting hype in pushing toward global carbon neutrality,the study scope of atmospheric science is rapidly expanding.Among numerous trending topics,energy meteorology has been attracting the most attention hitherto.One essential skill of solar energy meteorologists is solar power curve modeling,which seeks to map irradiance and auxiliary weather variables to solar power,by statistical and/or physical means.In this regard,this tutorial review aims to deliver a complete overview of those fundamental scientific and engineering principles pertaining to the solar power curve.Solar power curves can be modeled in two primary ways,one of regression and the other of model chain.Both classes of modeling approaches,alongside their hybridization and probabilistic extensions,which allow accuracy improvement and uncertainty quantification,are scrutinized and contrasted thoroughly in this review.
基金Korea Institute of Materials Science,Grant/Award Number:PNK9370National Research Foundation of Korea,Grant/Award Numbers:NRF-2021R1A2C1014280,NRF-2022R1C1C1011058,NRF-2022M3H446401037201Korea Institute of Science and Technology,Grant/Award Number:2E32581-23-092。
文摘Layered-type transition metal(TM)oxides are considered as one of the most promising cathodes for K-ion batteries because of the large theoretical gravimetric capacity by low molar mass.However,they suffer from severe structural change by de/intercalation and diffusion of K^(+)ions with large ionic size,which results in not only much lower reversible capacity than the theoretical capacity but also poor power capability.Thus,it is important to enhance the structural stability of the layered-type TM oxides for outstanding electrochemical behaviors under the K-ion battery system.Herein,it is investigated that the substitution of the appropriate Ti^(4+)contents enables a highly enlarged reversible capacity of P3-type KxCrO_(2) using combined studies of first-principles calculation and various experiments.Whereas the pristine P3-type KxCrO_(2) just exhibits the reversible capacity of∼120 mAh g^(−1) in the voltage range of 1.5-4.0 V(vs.K^(+)/K),the∼0.61 mol K^(+)corresponding to∼150 mAh g^(−1) can be reversible de/intercalated at the structure of P3-type K0.71[Cr_(0.75)Ti_(0.25)]O_(2) under the same conditions.Furthermore,even at the high current density of 788 mA g^(−1),the specific capacity of P3-type K0.71[Cr_(0.75)Ti_(0.25)]O_(2) is∼120 mAh g^(−1),which is∼81 times larger than that of the pristine P3-type KxCrO_(2).It is believed that this research can provide an effective strategy to improve the electrochemical performances of the cathode materials suffered by severe structural change that occurred during charge/discharge under not only K-ion battery system but also other rechargeable battery systems.
文摘This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1.00 m in width.The related reflector is made of lined sheets of aluminum,and the tubes are made of stainless steel used for the absorption of heat.They have an outer diameter of 0.051 m and a wall thickness of 0.002 m.Water,used as a heat transfer fluid(HTF),flows through the absorber tube at a mass flow rate of 0.7 kg/s.The dimensions of cylindrical turbulators are 0.04 m in length and 0.047 m in diameter.Simulations are performed using the ANSYS Fluent 2020 R2 software.The PTC performance is evaluated by comparing the experimental and numerical outcomes,namely,the outlet temperature,useful heat,and thermal efficiency for a modified tube(MT)(tube with novel cylindrical turbulators)and a plain tube(PT)(tube without novel cylindrical turbulators).According to the results,the experimental outlet temperatures recorded 63.2°C and 50.5°C for the MT and PT,respectively.The heat gain reaches 1137.5 Win the MT and 685.8 Win the PT.Compared to the PT collector,the PTC exhibited a(1.64 times)higher efficiency.
基金funding from the ERC(Consolidator Grant MIGHTY,866005)the Innovate UK(UKRI:104174)Faraday Institution-Future CAT(FIRG017)and Degradation(FIRG001)
文摘Small coin cell batteries are predominantly used for testing lithium-ion batteries(LIBs)in academia because they require small amounts of material and are easy to assemble.However,insufficient attention is given to difference in cell performance that arises from the differences in format between coin cells used by academic researchers and pouch or cylindrical cells which are used in industry.In this article,we compare coin cells and pouch cells of different size with exactly the same electrode materials,electrolyte,and electrochemical conditions.We show the battery impedance changes substantially depending on the cell format using techniques including Electrochemical Impedance Spectroscopy(EIS)and Galvanostatic Intermittent Titration Technique(GITT).Using full cell NCA-graphite LIBs,we demonstrate that this difference in impedance has important knock-on effects on the battery rate performance due to ohmic polarization and the battery life time due to Li metal plating on the anode.We hope this work will help researchers getting a better idea of how small coin cell formats impact the cell performance and help predicting improvements that can be achieved by implementing larger cell formats.
文摘The increase in oil prices and greenhouse gas emissions has led to the search for substitutes for fossil fuels. In Cameroon, the abundance of lignocellulosic resources is inherent to agricultural activity. Production of bioethanol remains a challenge given the crystallinity of cellulose and the presence of the complex. The pretreatment aimed to solubilize the lignin fraction and to make cellulose more accessible to the hydrolytic enzymes, was done using the organosolv process. A mathematical modeling was performed to point out the effect of the temperature on the kinetics of the release of the reducing sugars during the pretreatment. Two mathematical model was used, SAEMAN’s model and Response surface methodology. The first show that the kinetic parameters of the hydrolysis of the cellulose and reducing sugar are: 0.05089 min<sup>-1</sup>, 5358.1461 J·mol<sup>-1</sup>, 1383.03691 min<sup>-1</sup>, 51577.6100 J·mol<sup>-1</sup> respectively. The second model was used. Temperature is the factor having the most positive influence whereas, ethanol concentration is not an essential factor. To release the maximum, an organosolv pre-treatment of this sub-strate should be carried out at 209.08°C for 47.60 min with an ethanol-water ratio of 24.02%. Organosolv pre-treatment is an effective process for delignification of the lignocellulosic structure.
文摘The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips and husks are materials which can have good thermal conductivity and therefore the combination of these precursors could make it possible to obtain panels with good insulating properties. With regard to environmental and climatic constraints, the composite panels formulated at various rates were tested and the physico-mechanical and thermal properties showed that it was essential to add a crosslinker in order to increase certain solicitation. an incorporation rate of 12% to 30% made it possible to obtain panels with low thermal conductivity, a low surface water absorption capacity and which gives the composite good thermal insulation and will find many applications in the construction and real estate sector. Finally, new solutions to improve the fire reaction of the insulation panels are tested which allows to identify suitable solutions for the developed composites. In view of the flame tests, the panels obtained are good and can effectively combat fire safety in public buildings.
基金supported by the Scientific and Technological Research Council of Turkey(TüBTAK)under Grant 112T570
文摘Preparation of hierarchically porous, heteroatom-rich nanostructured carbons through green and scalable routes plays a key role for practical energy storage applications. In this work, naturally abundant lignocellulosic agricultural waste with high initial oxygen content, hazelnut shells, were hydrothermally carbonized and converted into nanostructured ‘hydrochar’. Environmentally benign ceramic/magnesium oxide(Mg O) templating was used to introduce porosity into the hydrochar. Electrochemical performance of the resulting material(HM700) was investigated in aqueous solutions of 1 M H;SO;, 6 M KOH and1 M Na;SO;, using a three-electrode cell. HM700 achieved a high specific capacitance of 323.2 F/g in 1 M H;SO;(at 1 A/g,-0.3 to 0.9 V vs. Ag/Ag Cl) due to the contributions of oxygen heteroatoms(13.5 wt%)to the total capacitance by pseudo-capacitive effect. Moreover, a maximum energy density of 11.1 Wh/kg and a maximum power density of 3686.2 W/kg were attained for the symmetric supercapacitor employing HM700 as electrode material(1 M Na;SO;, E = 2 V), making the device promising for green supercapacitor applications.
基金the support of the Deputyship for Research and Innovation-Ministry of Education,Kingdom of Saudi Arabia,for this research through a grant(NU/IFC/INT/01/002)under the Institutional Funding Committee at Najran University,Kingdom of Saudi Arabiathe support from the National Research Foundation of Korea(NRF)funded by the Brain Pool program(2021H1D3A2A02039346)。
文摘Lithium/Sodium-ion batteries(LIB/SIB)have attracted enormous attention as a promising electrochemical energy storage system due to their high energy density and long cycle life.One of the major hurdles is the initial irreversible capacity loss during the first few cycles owing to forming the solid electrolyte interphase layer(SEI).This process consumes a profusion of lithium/sodium,which reduces the overall energy density and cycle life.Thus,a suitable approach to compensate for the irreversible capacity loss must be developed to improve the energy density and cycle life.Pre-lithiation/sodiation is a widely accepted process to compensate for the irreversible capacity loss during the initial cycles.Various strategies such as physical,chemical,and electrochemical pre-lithiation/sodiation have been explored;however,these approaches add an extra step to the current manufacturing process.Alternative to these strategies,pre-lithiation/sodiation additives have attracted enormous attention due to their easy adaptability and compatibility with the current battery manufacturing process.In this review,we consolidate recent developments and emphasize the importance of using pre-lithiation/sodiation additives(anode and cathode)to overcome the irreversible capacity loss during the initial cycles in lithium/sodium-ion batteries.This review also addresses the technical and scientific challenges of using pre-lithiation/sodiation additives and offers the insights to boost the energy density and cycle life with their possible commercial exploration.The most important prerequisites for designing effective pre-lithiation/sodiation additives have been explored and the future directions have been discussed.
基金financially supported by National Natural Science Foundation of China(No.U20B6003).
文摘Aqueous foam is broadly applicable to enhanced oil recovery(EOR).The rheology of foam as a function of foam quality,gas and liquid velocities,and surfactant concentration constitute the foundation of its application.The great variations of the above factors can affect the effectiveness of N2 foam in EOR continuously in complex formations,which is rarely involved in previous relevant studies.This paper presents an experimental study of foam flow in porous media by injecting pre-generated N2 foam into a sand pack under the conditions of considering a wide range of gas and liquid velocities and surfactant concentrations.The results show that in a wide range of gas and liquid velocities,the pressure gradient contours are L-shaped near the coordinate axes,but V-shaped in other regions.And the surfactant concentration is a strong factor influencing the trend of pressure gradient contours.Foam flow resistance is very sensitive to the surfactant concentration in both the high-and low-foam quality regime,especially when the surfactant concentration is less than CMC.The foam quality is an important variable to the flow resistance obtained.There exists a transition point from low-to high-quality regime in a particular flow system,where has the maximum flow resistance,the corresponding foam quality is called transition foam quality,which increases as the surfactant concentration increases.The results can add to our knowledge base of foam rheology in porous media,and can provide a strong basis for the field application of foams.
文摘In this paper, neutronic analysis in a laser fusion inertial confinement fusion fission energy (LIFE) engine fuelled plutonium and minor actinides using a MCNP codes was investigated. LIFE engine fuel zone contained 10 vol% TRISO particles and 90 vol% natural lithium coolant mixture. TRISO fuel compositions have Mod①: reactor grade plutonium (RG-Pu), Mod②: weapon grade plutonium (WG-Pu) and Mod③: minor actinides (MAs). Tritium breeding ratios (TBR) were computed as 1.52, 1.62 and 1.46 for Mod(D, Mod② and Mod③, respectively. The operation period was computed as ~21 years when the reference TBR 〉 1.05 for a self- sustained reactor for all investigated cases. Blanket energy multiplication values (M) were calculated as 4.18, 4.95 and 3.75 for Mod①, Mod② and Mod③, respectively. The bumup (BU) values were obtained as ~1230, ~1550 and ~1060 GWd tM-1, respectively. As a result, the higher BU were provided with using TRISO particles for all cases in LIFE engine.
基金the support from Science&Technology Department of Sichuan Province(Grant Nos.2021ZYCD004,2022YFSY0008,2022NSFSC1023)National Natural Science Foundation of China(Grant Nos.42102300,52204033)the Engineering Research Center of Geothermal Resources Development Technology and Equipment,Ministry of Education,Jilin University(Grant No.22003).
文摘Residual oil zones(ROZs)have large potential for CO_(2)enhanced oil recovery(EOR)and geologic storage.During CO_(2)injection,the migration of CO_(2)in ROZs controls the performance of both EOR and storage.However,it has not been clearly visualized and understood that how geological heterogeneity factors control the transport of CO_(2)in ROZs.In this study,the oil recovery performance and geologic storage potential during continuous CO_(2)injection in a representative ROZ are studied based on geostatistical modelling and high-fidelity three-phase flow simulation.We examined the influence of autocorrelation length of permeability,global heterogeneity(DykstraeParsons coefficient),and permeability anisotropy on cumulative oil recovery and CO_(2)retention fraction.Simulation results indicate that,as the permeability autocorrelation length increases,the cumulative oil recovery and CO_(2)storage efficiency decrease.This results from the accelerated migration of CO_(2)along high permeability zones(i.e.,gas channeling).The increase in global heterogeneity and permeability anisotropies can lead to low oil recovery and poor CO_(2)sequestration performance,depending on the degree of CO_(2)channeling.The net utilization ratio of CO_(2)(CO_(2)retained/oil produced)unfavorably increases with both autocorrelation length and Dykstra eParsons coefficient,but decreases with the increase in kv/kh.Such a decrease is attributed to enlarged swept volume induced by gravity override.The study provides important implications for fieldscale CO_(2)EOR and storage applications in ROZs.
文摘Uttarakhand state comes under special category state where approximately 69.45% population lived in rural area under the population density with varied range of 37 to 607 persons per sq.km. Although Uttarakhand is having per capita consumption of 1112.29 kWh which is higher than national average per capita consumption of 779 kWh as till date, but remote communities, villages are not able to access clean, cheep and good quality of energy due to uneven terrain, lack of proper transmission & distribution lines [1]. 100% villages are electrified under the RGGVY scheme as per the Ministry of Power Government of India, but due to poor loading of transformer, lack of grid infrastructure and natural calamities, remote house owners are not able to get good quality of power thus affect the livelihood and source of income generation in various means [2]. As Uttarakhand state having future plans to be make state energy sufficient and energy access to all by year 2016-2017, so major ground level initiative have been taken by Government of Uttarakhand. The government of Uttarakhand has incorporated innovative business model to provide good quality of power with non-conventional energy source. Under the initiative invlovement of local people and village level, panchayats have ownership and responsibility to operate these clean energy business model to improve livelihood in remote hilly places of Uttarakhand. Under this analysis, five different type of community models are categorized as Community 1, Community 2, Community 3, Standalone 1 & Standalone 2 for rural &remote communities based on number of unclustered households with the distance covered between 200 m to 20 km, and electrical loads i.e. lighting, fan, mobile chargers, television along with time of day energy consumption patterns. These community models are for remote hilly location where grid integration and distribution lines are not feasible to built due to hilly terrain, low soil strength and huge expenses for expanding power cables for supplying good quality power. The preliminary studies and simulations has been done in HOMER tool by considering the various composite source of power, i.e. Solar PV with battery bank, Solar PV with battery Bank & Generator, and Solar PV along with DG. These three hybrid source of power generation with Solar PV as base source under five different community models, the techno-commercial feasibility has been analyzed in terms of load sharing proposition with Solar PV and battery, DG, Energy production through PV, load consumption per year, Excess and unmet energy monitoring, battery sizing to meet the load during nights, DG operation when the solar energy not available due to weather condition and non availability of sunshine in night. Financial feasibility has been examined in terms of levelized cost of energy, cost summary and O&M cost per year of three integrated sources of energy generation with Solar PV under each community model. Solar PV power plant , which is the best renewable source of energy to cater energy access issue in remote hilly places. The Uttarakhand receives good amout of daily average radiation level of 5.14 - 5.50 kWh/m2/day. Financial feasible community models for different hilly region based on their energy consumption need to be implemented with the help of local community by providing ownership to local people, panchayat, for it not only caters energy access issue but also provides clean, cheep, uninterruptable energy and improves livelihood standard to locals by engaging them into operation maintenance and tariff or rent collection. The study shows that Solar PV power plant with battery bank is the optimal solution considering life cycle cost of hybrid system. It is feasible due to low operation and maintenance cost, price declination of battery and Solar PV module, battery prices at time of replacement.