CLUE-S模型及其在奈曼旗土地利用时空动态变化模拟中的应用

在对目前常用的土地利用变化模型进行调研的基础上,认为CLUE-S模型是众多模型中适用于区域土地利用变化研究的一种较好的模型;它是根据系统论的观点,在深刻理解土地利用系统内土地利用变化特征(包括关联性、竞争性、稳定性以及等级性等)的基础上构建而成,具有同步模拟不同土地利用变化的能力。论文以奈曼旗为例,根据1985年的空间图形数据,结合道路、居民点、城镇、水域的分布、以及地形和土壤等驱动因素,对其2000年的土地利用变化格局进行模拟;并用2000年的土地利用现状图对模拟结果进行检验。结果显示,在基本单元(500m×500m栅格)的水平上,模拟的正确率为85%,Kappa指数值是0.80。说明CLUE-S模型具有成功模拟区域土地利用时空动态变化的能力,是值得向国内同行推荐的一种较好的LUCC模型。

气候变化对小兴安岭森林影响的模拟研究(英文)

中国东北小兴安岭的温带针阔混交林是中国重要的商品木材资源。本文应用森林林窗模型 NEWCOP来模拟森林的生长和更新。研究表明 ,该模型可以再现森林的树种组成动态和森林的分布 ,故可以用来模拟气候变化对森林的可能影响。通过模拟在 GISS 2× CO2 和 GFDL 2× CO2 气候变化情景下的小兴安岭现有森林的动态发现 :在未来 10 0 a现存森林可能有一个快速衰退过程 ,随后可恢复为落叶阔叶树 (如蒙古栎 )为主要树种的森林 。

Phytoremediation for phenanthrene and pyrene contaminated soils

Phytoremediation of soil contaminated with phenanthrene and pyrene was investigated using twelve plant species. Plant uptake and accumulation of these chemicals were evaluated. At the end of the experiment(45 d), the remaining respective concentrations of soil phenanthrene and pyrene in spiked vegetated soils, with initial phenanthrene of 133 3 mg/kg and pyrene of 171 5 mg/kg, were 8 71—16 4 and 44 9—65 0 mg/kg, generally 4 7%—49 4% and 7 1%—35 9% lower than their concentrations in the non vegetated soils. The loss of phenanthrene and pyrene in vegetated spiked soils were 88 2%—93 0% and 62 3%—73 8% of the added amounts of these contaminants, respectively. Although plant uptake and accumulation of these compounds were evident, and root concentrations and RCFs(root concentration factors; defined as the ratio of PAH concentrations in roots and in the soils on a dry weight basis) of these compounds significantly positively correlated to root lipid contents, plant uptake and accumulation only accounted for less than 0 01% and 0 23% of the enhanced loss of these chemicals in vegetated versus non vegetated soils. In contrast, plant promoted microbial biodegradation was the dominant mechanism of the phytoremediation for soil phenanthrene and pyrene contamination. Results from this study suggested a feasibility of the establishment of phytoremediation for soil PAH contamination.

Characterization of fine organic particulate matter from Chinese cooking

PM 2.5 samples were collected by a three-stage cascade impactor at two kinds of Chinese restaurants to characterize fine organic particulate matter from Chinese cooking sources. Major individual organic compounds have been quantified by GC/MS, including series of alkanes, n-alkanoic acids, n-alkanals, alkan-2-ones and PAHs. Alkanes and ketones make up a significant fraction of particle-phase organic compounds, ranging from C 11 to C 26, and C 9 to C 19, respectively. In addition, other organic compound classes have been identified, such as alkanols, esters, furans, lactones, amides, and nitriles. The mass concentrations of fine particles, alkanes, n-alkanoic acids and PAHs in air emitted from the Uigur style cooking are hundreds times higher than ambient PM 2.5in Beijing.

Application of the HY-1 satellite to sea ice monitoring and forecasting

The HY-1A satellite is the first oceanic satellite of China. During the winter of 2002-2003, the data of the HY-1A were applied to the sea ice monitoring and forecasting for the Bohai Sea of China for the first time. The sea ice retrieval system of the HY-1 A has been constructed. It receives 1B data from the satellite, outputs sea ice images and provides digital products of ice concentration, ice thickness and ice edge, which can be used as important information for sea ice monitoring and the initial fields of the numeric sea ice forecast and as one of the reference data for the sea ice forecasting verification. The sea ice retrieval system of the satellite is described, including its processes, methods and parameters. The retrieving results and their application to the sea ice monitoring and forecasting for the Bohai Sea are also discussed.

Photoassisted fenton oxidation of refractory organics in UASB-pretreated leachate

Nearly 91% of organic pollutants in Hong Kong leachate could be effectively removed by the UASB(upflow anaerobic sludge blanket) process followed by the fenton coagulation. The COD (chemical oxygen demand) of leachate was lowered from an average of 5620 mg/L to 1910 mg/L after the UASB treatment at 37℃, and was further lowered to 513 mg/L after fenton coagulation. The remaining refractory residues could be further removed by photochemical oxidation with the addition of H 2O 2. The BOD/COD ratio was greatly increased from 0.062 to 0.142, indicating the biodegradability of organic residues was improved. The photochemical oxidation for the fenton\|coagulation supernatant was most effective at pH 3\_4, with the addition of 800 mg/L of H 2O 2, and UV radiation time of 30 minutes. The final effluent contained only 148 mg/L of COD, 21 mg/L of BOD(biochemical oxygen demand) and 56 mg/L of TOC (total organic carbon).

Treatment and utilization of septic tank effluent using vertical-flow constructed wetlands and vegetable hydroponics

Vertical flow constructed wetlands is a typical ecological sanitation system for sewage treatment. The removal rates for COD, BOD 5, SS, TN, and TP were 60%, 80%, 74%, 49% and 79%, respectively, when septic tank effluent was treated by vertical flow filter. So the concentration of COD and BOD\-5 in the treated effluent could meet the quality standard for irrigation water. After that the treated effluent was used for hydroponic cultivation of water spinach and romaine lettuce, the removal efficiencies of the whole system for COD, BOD\-5, SS, TN and TP were 71 4%, 97 5%, 96 9%, 86 3%, and 87 4%, respectively. And it could meet the integrated wastewater discharge standard for secondary biological treatment plant. It was found that using treated effluent for hydroponic cultivation of vegetables could reduce the nitrate content in vegetables. The removal rates for total bacteria and coliform index by using vertical flow bed system with cinder substrate were 80%—90% and 85%—96%, respectively.

POC fluxes from euphotic zone estimated from ^(234)Th deficiency in winter in the northwestern North Pacific Ocean

Dissolved and particulate 234 Th, particulate organic carbon(PON), nitrogen, and chlorophyll-a concentrations in the upper 200 m of water columns from seven stations in the northwestern North Pacific Ocean were determined in the winter of 1997.The dissolved, particulate, and total 234 Th activities (dissolved plus particulate)show a pronounced deficiency with respect to its parent 238 U in the euphotic zone whereas the total 234 Th shows a near-equilibrium at the depth greater than 100 m.The 234 Th data are used to derive the mean residence time, export fluxes of 234 Th, and fluxes of particulate organic carbon and nitrogen out of the euphotic zone. In the Subarctic Current area, the residence time of dissolved 234 Th with respect to its removal onto particles is 40 ~50 d while the residence time of dissolved 234Th in the subtropical area is about 20 d due to the Kuroshio's influence.The particulate organic carbon(POC)and particulate organic nitroge(PON)fluxes in winter range over 3.8～8.2 and 0.50～0.98 mmol/(m2 ·d), respectively, and are higher in the west region than in the east, and higher in the south than in the north. The co-influence of Kuroshio-Oyashio Currents with supply of nutrient substances from the coastal area and the light condition are two factors determining the horizontal distribution of POC fluxes in winter.The depth distribution of the chlorophyll-a as well as the consistence of the ratio of POC to PON with the Redfield ratio suggest that phytoplankton is the main contributor to the export of POC in this area in winter.The POC fluxes in the northwestern North Pacific Ocean in winter are comparable to some areas in the world oceans in spring and summer seasons.

Subjective annoyance caused by indoor low-level and low frequency noise and control method

The influence of low_level noise has not been widely noticed. This paper discovered that low_level and low frequency noise(A_weighted equivalent level L eq <45 dB) causes higher probability of subjective annoyance. The fuzzy mathematic principle was applied to deal with the threshold level of subjective annoyance from noise in this study; there is preferable relationship between the indoor noise and noise annoyance at low frequency noise level. Study indicated at the same centered noise level, the change of annoyance probability is mainly caused by the change of the frequency spectrum characteristic of the indoor noise. Under low noise level environment, without change of the medium_low frequency noise, the slight increase of medium_high frequency noise level with the help of noise sheltering effect can significantly reduce the noise annoyance. This discovery brings a new resolution on how to improve the environmental quality of working or living places. A noise control model is given in this study according to the acoustic analysis.

Effect of Land Use History on Methane Emission and Methanogenic Flora in Flooded Soils

The characteristics of methane emission were compared among six types of upland and paddy soils developed from different parent materials with distinct physics and chemical properties after planting rice. The fluxes of methane emission in submerged soils from the upland were obviously lower than those from the paddy rice field. The flux of methane emission in the paddy soil developed from fluvo-aquic soil was the largest among all the types of soils. Planting of rice was helpful to emission of methane in soils. The amounts of various groups of methanogenic flora were conformed with the deferences among the fluxes of methane emission in various types of soils. Methane formation was observed in each type Of air-dried soils stored for a long time after addition of water and incubation at 35℃.

Rapid degradation of bensulfuron-methyl upon repeated application in paddy soils

Rapid degradation of bensulfuron-methyl upon repeated application in paddy soils was studied. The results showed that the DT _ 50 of bensulfuron-methyl was reduced from 16 d to 9 d in soil with one-year bensulfuron-methyl application. Rapid bensulfuron-methyl degradation was happened to previously untreated soil by addition 5% rapid bensulfuron-methyl adapted soil and was inhibited following pre-treatment with broad-spectrum antibiotic chloramphenicol. In bensulfuron-methyl adapted soil mineralisation of 14 C labeled bensulfuron-methyl to 14 CO_2 occurred at a faster rate than with previously untreated soil. It was concluded that rapid bensulfuron-methyl degradation upon repeated application is probably linked to the adaptation of soil bacteria which can utilize bensulfuron-methyl as a source of carbon and energy.

Leaf litter ecological fate in the Schelde Estuary in Belgium

Two dominant species of Willow( Salix triandra )and Reed (Phragmites australis) along the Schelde Estuary(in Belgium)were selected in this research. The pigments of higher plant was used as biomarkers, the decomposition process of the two species were studied after they fall into the Schelde Estuary. After statistical analysis(Spearman rank order correlation, P <0 05), the results has shown the decomposition dynamics pattern of the pigments, and the willow showed different pattern in comparing with the reed, e.g. Chlorophyll a decomposition dynamics for willow is: y 1=12196 x 2 - 175895 x +1E+06+ k , R 2=0 5706 while for reed is: y 2=-37878 x 2+229782 x +734282+ k , R 2=0 9065 The precise time of the leaf litter spent in the water was also calculated as were less than 24 days, 24-37 days, longer than 37 days(willow)and less than 24 days, longer than 24 days(reed), the leaf litter fate of the two dominant species in the Schelde Estuary was also compared.

EVALUATION OF ECOLOGICAL SERVICES OF JILIN PROVINCE, NORTHEAST CHINA

The main purpose of this study is to give evaluation of ecological services of Jilin Province, Northeast China. To take this value into decision-making and GDP accounting system is considered to be one of the economic solutions for ecological problems. The evaluation is based on the methods proposed by COSTANZA et al., and some modifications about unit value of forest and cropland system were made according to the real characters of ecosystem, climate, natural conditions etc., in Jilin Province. Total value of ecosystem services is about 554.404x10(9) yuan(RMB)/a, which is about 4.9 times of GDP of the corresponding period. The results of this study could be used as a fundamental work for the construction of ecological province, which was carried out from 2001, and could provide ecological information for decision-making. Furthermore, the necessities for the further studies on the evaluation of ecological services and natural capital were discussed.

Sorption of BTEX mixtures to organobenonites

Organobentonites synthesized by replacing the metal ions in bentonite with cetyltrimethylammonium(CTMA) or tetramethylammonium cation(TMA) were investigated for their behaviors to sorb benzene, toluene, p-xylene from water. The results served to distinguish the sorption mechanisms(adsorption or partition) of the two types of organobentonites. Bentonites modified with short-chain alkyl functional groups(e.g., TMA) sorb organic contaminants primarily by an adsorption process, in which the sorbed amount decreases with increasing steric hindrance of the organic compound and the process exhibits a competitive effect because of steric hindrance in multi-solute systems. In contrast, the sorption of contaminants to organobentonites modified with long-chain alkyl groups(e.g., CTMA) occurs by partition process without exhibiting a competitive effect, and the additional organic compounds may induce a cosorptive effect. In the latter case, the measured distribution coefficients of organic compounds between organobentonites and water(logK d) are positively correlated with the octanol-water partition coefficients of the compounds(logK ow ) and the sorption process exhibits no competitive effect in multi-solute systems.

PAHs pollution from traffic sources in air of Hangzhou, China: Trend and influencing factors

PAHs pollution in air of arterial roads was investigated from October 1998 to October 2001 in Hangzhou, China. The results showed that Σ10 PAHs was 13—36 μg/m3, among which, BaP, a strong carcinogenic kind ranged from 0.034 μg/m3 to 0.12 μg/m3. PAHs pollutions in four seasons were winter>autumn>spring-summer. The annual averages of ΣPAHs concentration were 25 μg/m3 for 1999, 28 μg/m3 for 2000, and 29 μg/m3 for 2001, respectively. Leaded gasoline was banned in December 1998 in Hangzhou, thus comparative measurements with PAHs in leaded and lead-free gasoline powered motor exhausts made it certain that the use of lead-free gasoline leaded to a heavier PAHs pollution in roadside air from December, 1998, in China, and ΣPAHs in air samples after the lead-banning were more than twice of that in samples before the action. For the large contribution of vehicle discharge to air pollution in roadside, further research was performed to suggest the factors influencing PAHs distribution in vehicle exhaust in order to control air pollution effectively. Compared to gasoline engines, emissions from diesel engines were less toxic, although they might produce more PAHs. Of the same vehicular and oil type, automobiles of longer mileages produced more toxic PAHs. PAHs distributions in the vehicular exhausts were related to the oil type. Large difference was found in the abundance of 3-, 5- and 6-ring PAHs between exhausts from gasoline and diesel oil engines. Diesel oil engines produced relative lighter PAHs such as NAPH, ACEN, FLUOR, while gasoline engines emitted heavier kinds such as BkF, IN and BP. The automobile produced more PAHs with the increase of mileage especially FLUR, PY, BaP, BP. Some significant ratios for traffic source in Hangzhou such as PHEN/AN, FLUR/PY, IN/BP were 0.50—4.3, 0.58—7.4, 0.51—1.5, respectively. A source fingerprint for vehicle exhausts of a mixture of vehicle and oil types in the city district for light-duty vehicle was the abundance of BaA, followed by NAPH, BP, IN. 4-ring PAHs such as FLUR, PY, BaA and CHRY were the most predominant kinds followed by 6-ring PAHs(BP, IN).

Biological Characteristies of Methane Emission of Oryzasativa，Panicumcrus－galliand Cyperusdif for misGrown on PaddySoil

Biological characteristics of methane emission were compared among Oryza sativa, Panicum crus-galli andCyperus difformis grown on paddy soil. The order of the amounts of methane emitted was P. crus-galli > O. sativa >C. difformis, with the former two 11 and 8 times as much as that of the latter, respectively. And it was just opposite tothat of the methane-forming activities of roots of the three plants. The diurnal changes of methane emission of thethree plants were relatively consistent with valleys during 11:00-14:00 and midnight and peaks during 8:00-11: 00,14:00- 20:00 and about 5:00 early morning. The methanogenic activites in rhizospheric soils were higher than those innonrhizospheric soils with P. crus-galli and O. sativa, but not with C. difformis. The pathways of methane release ofP. crus-galli and O . sativa were probably through the top gaps near the junctions of nodal plate and leaf sheath, how-ever in C. difformistopgaps from which methane could escape into atmosphere were not found.

Preparation, Characterization and Catalytic Properties of S_2O_8^(2-)/ZrO_2 Supported by Tungsten Carbide

A WC-supported S_2O 2-_8/ZrO_2(PSZ) catalyst was prepared and characterized by means of XRD, BET, FTIR and XPS. The isomerization of n-pentane over the catalyst was investigated as well. The results show that the skeletal isomerization and the crack of n-pentane proceed simultaneously on WC-supported S_2O 2-_8/ZrO_2 catalyst. The addition of tungsten carbide showed a significant enhancement in the activity and stability of the catalyst for n-pentane isomerization. The catalyst showed evidently a better activity than S_2O 2-_8/ZrO_2 supported by Pt and WO_3. The results can be interpreted by the existence of the tungsten oxycarbide compound(WC_xO_y) with carbidic, oxide and acidic sites.

Pilot regulation of MnP-SA for treating PTA wastewater

In the pilot study of treating the purified terephthalic acid(PTA) wastewater with the functional Strain Fhhh in the carrier activated sludge process(CASP), the ratio of COD∶TN∶TP and the concentrations of Cu, Mn, Se and Zn were controlled to improve the manganese peroxidase(MnP) levels for increasing the treatment efficiency. When the ratio of COD∶TN∶TP was 100∶0.36∶0.15 and the concentrations of Cu, Mn, Se and Zn were 0.54, 5.07, 0.00 and 0.08 mg/L, the MnP specific activity(MnP-SA) reached 689 U/L, and the sludge loading rate to COD(SLRC) was 1.09 d -1, which was 4—7 fold of that in other processes reported. The data indicated that improving MnP level could enhance the degradability of Fhhh. And the potentials of Fhhh and CASP will be also discussed in this paper.

Predication of Fhhh potential in PTA wastewater treatment

Ebis is the intelligent environmental biotechnological informatics software developed for judging the effectiveness of the microorganism strain in the industrial wastewater treatment system(IWTS) at the optimal status. The parameter, as the objective function for the judgment, is the minimum reactor volume( V _ min ) calculated by Ebis for microorganism required in wastewater treatment. The rationality and the universality of Ebis were demonstrated in the domestic sewage treatment system(DSTS) with the data published in USA and China at first,then Fhhh strain's potential for treating the purified terephthalic acid(PTA) was proved. It suggests that Ebis would be useful and universal for predicating the technique effectiveness in both DSTS and IWTS.

Effects of pesticides on soil biochemical characteristics of a paddy soil

The impact of triazophos, bensulfuron-methyl, chlobenthiazone on soil biochemical characteristics in a paddy soil under controlled moisture(flooded soil) and temperature(25℃) condition was studied. The electron transport system(ETS)/dehydrogenase activity displayed a negative correlation with triazophos, bensulfuron-methyl, chlobenthiazone concentrations, and the activity decreased as the concentration of the pesticides increased. The higher doses, 5 and 10 field rates, of triazophos, bensulfuron-methyl, chlobenthiazone significantly inhibited ETS activity, while lower rates failed to produce any significant reducing effect against the control. The relative toxicity of triazophos, bensulfuron-methyl, chlobenthiazone in decreasing the ETS activity was in the order: triazophos > chlobenthiazone > bensulfuron-methyl, irrespective of the rates of application. Triazophos, bensulfuron-methyl, chlobenthiazone caused an improvement in the soil phenol content and it increased with increasing concentration of triazophos, bensulfuron-methyl, chlobenthiazone. Triazophos, bensulfuron-methyl, chlobenthiazone incorporation did not produce any significant change in soil protein content. The response of biomass phospholipid content was nearly similar to ETS activity. The phospholipid content was decreased with the addition of triazophos, bensulfuron-methyl, chlobenthiazone in the order of triazophos > chlobenthiazone > bensulfuron-methyl; and the toxicity of applied amount was in the order: 10 FR(field rate) > 5 FR > 1 0 FR > 0 5 FR > control.