Artificial Intelligence & Machine Learning in the Earth Sciences

1 Introduction In the same way mathematics is regarded by many mathematicians as the study of patterns in numbers(Hardy,1940),the earth sciences can be thought of usefully as the study of patterns in the physical,chemical and biotic constituents of the Earth in both time and space.The documentation,definition and,ultimately。

Characterization and spatial analysis of coseismic landslides triggered by the Luding Ms 6.8 earthquake in the Xianshuihe fault zone, Southwest China

On September 5, 2022, a magnitude Ms 6.8 earthquake occurred along the Moxi fault in the southern part of the Xianshuihe fault zone located in the southeastern margin of the Tibetan Plateau,resulting in severe damage and substantial economic loss. In this study, we established a coseismic landslide database triggered by Luding Ms 6.8 earthquake, which includes 4794 landslides with a total area of 46.79 km^(2). The coseismic landslides primarily consisted of medium and small-sized landslides, characterized by shallow surface sliding. Some exhibited characteristics of high-position initiation resulted in the obstruction or partial obstruction of rivers, leading to the formation of dammed lakes. Our research found that the coseismic landslides were predominantly observed on slopes ranging from 30° to 50°, occurring at between 1000 m and 2500 m, with slope aspects varying from 90° to 180°. Landslides were also highly developed in granitic bodies that had experienced structural fracturing and strong-tomoderate weathering. Coseismic landslides concentrated within a 6 km range on both sides of the Xianshuihe and Daduhe fault zones. The area and number of coseismic landslides exhibited a negative correlation with the distance to fault lines, road networks, and river systems, as they were influenced by fault activity, road excavation, and river erosion. The coseismic landslides were mainly distributed in the southeastern region of the epicenter, exhibiting relatively concentrated patterns within the IX-degree zones such as Moxi Town, Wandong River basin, Detuo Town to Wanggangping Township. Our research findings provide important data on the coseismic landslides triggered by the Luding Ms 6.8 earthquake and reveal the spatial distribution patterns of these landslides. These findings can serve as important references for risk mitigation, reconstruction planning, and regional earthquake disaster research in the earthquake-affected area.

Changes in Sediment Sources in the Southern Muddy Area of Weihai,China,Since the Late Pleistocene:A Record from Rare Earth Elements

The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea interactions since the late Pleistocene.This study investigates the evolution of sediment sources and their responses to environmental changes since the late Pleistocene,using core WHZK01 collected from the nearshore muddy area in southern Weihai for rare earth element(REE)analysis.In doing so,this work highlights the changing patterns of material sources and the primary control factors.The results reveal that the sedimentary deposits in core WHZK01 exhibit distinct terrestrial characteristics.Discriminant function analysis(F_(D))and source discrimination dia-grams both suggest that the primary sources of these deposits are the Yellow River and adjacent small and medium-sized rivers,although the sources vary among different sedimentary units.Furthermore,the DU3 layer(17.82-25.10 m)displays typical riverine sedimentation,dominated by terrestrial detrital input,primarily from the local rivers,namely the Huanglei and Muzhu Rivers.The material in the DU2 layer(14.91-17.82 m)is mainly influenced by a mixture of the Qinglong and Yellow Rivers.The DU1 layer(0-14.91 m)is influenced by sea-level changes during the Holocene,with the Yellow River being the primary source,although there is also some input from local rivers.The changes in sea level during the Holocene and the input of Yellow River material carried by the coastal currents of the Yellow Sea are identified as the main controlling factors for the changes in material sources in the study area since the late Pleistocene,with small and mediumsized rivers also exerting some influence on the material sources.The above mentioned findings not only contribute to a better understanding of the source-sink systems of the Yellow River and adjacent small and mediumsized rivers but also deepen our understanding of the late Quaternary land-sea interactions in the Shandong Peninsula.

Stress triggering effect on the 2022 Honghe M_(S)5.0 earthquake with historical strong earthquakes

The 2022 Honghe M_(S)5.0 seismic event is intriguing due to its occurrence in the south of the Red River Fault,an area historically lacking seismic activities greater than M_(S)5.0.To elucidate the seismogenic mechanism and scrutinize stress-triggered interactions,we calculated co-seismic and post-seismic Coulomb stress alterations induced by nine historical seismic events(M≥6.0).The analysis reveals that these substantial seismic events provoked co-seismic stress augmentations of 1.409 bar and postseismic stress increments of 0.159 bar.Noteworthy seismic events,such as the 1833 Songming,1877Shiping,1913 Eshan,and 1970 Tonghai earthquakes,catalyzed the occurrence of the Honghe earthquake.Areas of heightened future seismic risk include the southern region of the Red River Fault and the eastern segments of the Shiping-Jianshui and Qujiang faults.Additionally,we assessed the correlation between the spatial distribution of aftershocks and the Coulomb stress shift triggered by the mainshock,taking into account the influence of calculation parameter settings.

The Collaboratory for the Study of Earthquake Predictability in China:Experiment Design and Preliminary Results of CSEP2.0

Since the inaugural international collaboration under the framework of the Collaboratory for the Study of Earthquake Predictability(CSEP)in 2007,numerous forecast models have been developed and operated for earthquake forecasting experiments across CSEP testing centers(Schorlemmer et al.,2018).Over more than a decade,efforts to compare forecasts with observed earthquakes using numerous statistical test methods and insights into earthquake predictability,which have become a highlight of the CSEP platform.

Lithospheric strength of the Anatolian plateau and implications for strong earthquake activity in Turkey

On February 6, 2023, the doublet earthquake including two main shocks with magnitudes M_(W)7.8 and M_(W)7.5, occurred near the western side of the East Anatolian Fault at the southeast boundary of the Anatolian Plateau in Turkey. Based on the WGM2012 Bouguer gravity anomaly data and the Etopo1topography data, this study first introduced a joint inversion of admittance and coherence functions and used the Bayesian optimal parameter estimation method to obtain the effective elastic thickness Teand loading ratio F of the lithosphere for various tectonic units in the Anatolian Plateau. Secondly, we discussed the characteristics and influencing factors of the lithospheric mechanical strength and analyzed its relationship with seismic activity. The lithospheric mechanical strength of the Anatolian Plateau showed clear lateral heterogeneity and a "weak-strong-weak" spatial pattern from east to west,reflecting various tectonic processes. At last, the strong seismic activity was found where the lithospheric strength was low in the Anatolian Plate. We also incorporated GPS strain rate and other results to investigate the tectonic background and primary causes of the M_(W)7.8 and M_(W)7.5 doublet earthquakes in Turkey. The results have a good insight into urban safety design in the Turkish region, including postdisaster rehabilitation, earthquake hazard assessment, and loss reduction.

Seismogenic model of the 2023 M_(W)5.5 Pingyuan earthquake in North China Plain and its tectonic implications

The 6 August 2023 M_(W)5.5 Pingyuan earthquake is the largest earthquake in the central North China Plain(NCP)over the past two decades.Due to the thick sedimentary cover,no corresponding active faults have been reported yet in the epicenter area.Thus,this earthquake presents a unique opportunity to delve into the buried active faults beneath the NCP.By integrating strong ground motion records,high-precision aftershock sequence relocation,and focal mechanism solutions,we gain insights into the seismotectonics of the Pingyuan earthquake.The aftershocks are clustered at depths ranging from 15 to 20 km and delineate a NE-SW trend,consistent with the distribution of ground motion records.A NE-SW nodal plane(226°)of the focal mechanism solutions is also derived from regional waveform inversion,suggesting that the mainshock was dominated by strike-slip motion with minor normal faulting component.Integrating regional geological data,we propose that an unrecognized fault between the NE-SW trending Gaotang and Lingxian-Yangxin faults is the seismogenic fault of this event.Based on the S-wave velocity structure beneath the NCP,this fault probably extends into the lower crust with a high angle.Considering the tectonic regime and stress state,we speculate that the interplay of shear strain between the Amurian and South China blocks and the hot upwelling magma from the subducted paleo Pacific flat slab significantly contributed to the generation of the Pingyuan earthquake.

Below-Moho Earthquakes of Tibet,Himalaya,the Indian Foreland,and Worldwide:How,Where and Why?

We seek to understand lithospheric rheology by mapping continental earthquake depths relative to Moho depth,across the entire India/Asia convergent orogen,and eventually worldwide.Such mapping has particular value in geothermometry,and potentially in identifying regions of delamination.How:We are extending our Sn/Lg method beyond amplitude ratios of regional seismic phases measured on arrays(array Sn/Lg method,Wang and Klemperer,2021)to include frequency proxies for earthquake depth relative to Moho(Wang&Klemperer,2024a,b;Harris et al.,2024).

Ecological environmental quality evaluation and driving factor analysis of the Lijiang River Basin,based on Google Earth Engine

For regional ecological management,it is important to evaluate the quality of ecosystems and analyze the underlying causes of ecological changes.Using the Google Earth Engine(GEE)platform,the remote sensing ecological index(RSEI)was calculated for the Lijiang River Basin in Guangxi Zhuang Autonomous Region for 1991,2001,2011,and 2021.Spatial autocorrelation analysis was employed to investigate spatiotemporal variations in the ecological environmental quality of the Lijiang River Basin.Furthermore,geographic detectors were used to quantitatively analyze influencing factors and their interaction effects on ecological environmental quality.The results verified that:1)From 1991 to 2021,the ecological environmental quality of the Lijiang River Basin demonstrated significant improvement.The area with good and excellent ecological environmental quality in proportion increased by 19.69%(3406.57 km^(2)),while the area with fair and poor ecological environmental quality in proportion decreased by 10.76%(1860.36 km^(2)).2)Spatially,the ecological environmental quality of the Lijiang River Basin exhibited a pattern of low quality in the central region and high quality in the periphery.Specifically,poor ecological environmental quality characterized the Guilin urban area,Pingle County,and Lingchuan County.3)From 1991 to 2021,a significant positive spatial correlation was observed in ecological environmental quality of the Lijiang River Basin.Areas with high-high agglomeration were predominantly forests and grasslands,indicating good ecological environmental quality,whereas areas with low-low agglomeration were dominated by cultivated land and construction land,indicating poor ecological environmental quality.4)Annual average precipitation and temperature exerted the most significant influence on the ecological environmental quality of the basin,and their interactions with other factors had the great influence.This study aimed to enhance understanding of the evolution of the ecological environment in the Lijiang River Basin of Guangxi Zhuang Autonomous Region and provide scientific guidance for decision-making and management related to ecology in the region.

Geological risk assessment of traffic engineering construction among 7.0-8.5 magnitude earthquake areas:Practice from the Sichuan-Tibet transport corridor in the eastern Tibetan Plateau

At least 13 active fault zones have developed in the Ya'an-Linzhi section of the Sichuan-Tibet transport corridor,and there have been undergone 17 MS≥7.0 earthquakes,the largest earthquake is 1950 Chayu MS 8.5 earthquake,which has very strong seismic activity.Therefore,carrying out engineering construction in the Sichuan-Tibet transport corridor is a huge challenge for geological technological personnel.To determining the spatial geometric distribution,activity of active faults and geological safety risk in the Sichuan-Tibet transport corridor.Based on remote sensing images,ground surveys,and chronological tests,as well as the deep geophysical and current GPS data,we investigated the geometry,segmentation,and paleoearthquake history of five major active fault zones in the Ya'an-Linzhi section of the Sichuan-Tibet transport corridor,namely the Xianshuihe,Litang,Batang,Jiali-Chayu and Lulang-Yigong.The five major fault zones are all Holocene active faults,which contain strike-slip components as well as thrust or normal fault components,and contain multiple branch faults.The Selaha-Kangding segment of the Xianshuihe fault zone,the Maoyaba and Litang segment of the Litang fault zone,the middle segment(Yigong-Tongmai-Bomi)of Jiali-Chayu fault zone and Lulang-Yigong fault zone have the risk of experiencing strong earthquakes in the future,with a high possibility of the occurrence of MS≥7.0 earthquakes.The Jinsha River and the Palong-Zangbu River,which is a high-risk area for geological hazard chain risk in the Ya'an-Linzhi section of the Sichuan-Tibet transport corridor.Construction and safe operation Ya'an-Linzhi section of the Sichuan-Tibet transport corridor,need strengthen analysis the current crustal deformation,stress distribution and fault activity patterns,clarify active faults relationship with large earthquakes,and determine the potential maximum magnitude,epicenters,and risk range.This study provides basic data for understanding the activity,seismicity,and tectonic deformation patterns of the regional faults in the Sichuan-Tibet transport corridor.

Overview of the virtual special issue on the 2023 Kahramanmaraş,Türkiye earthquake doublet

On 6 February 2023,a calamitous earthquake with a magnitude of 7.8 struck close to the city of Kahraman-maraş,sending tremors through southeastern Türkiye and northern Syria.This earthquake(Event 1),which initiated at 04:17:34 AM local time(or 01:17:34 UTC according to the United States Geological Survey,USGS),persisted for approximately 90 seconds,carving a trail of destruction along roughly 380 kilometers of the Earth’s surface(e.g.,Ren CM et al.,2024).This initial earthquake was succeeded by a second significant tremor,Event 2,with a magnitude of 7.6,occurring nine hours later at 10:24:48 UTC(according to the USGS).Event 2 propagated along a different fault line,approximately 100 kilometers north of the epicenter of Event 1,generating surface ruptures extending close to 200 kilometers.The twin seismic shocks of the 2023 Kahramanmaraşearthquake wrought extensive havoc,devastating densely inhabited regions spanning several large cities in southeastern Türkiye and northwestern Syria,including but not limited to Kahramanmaraş,Adıyaman,Şanlıurfa,Antakya,Gaziantep,Malatya,İskenderun,and Adana.The tragic aftermath of these events includes a death toll of some 60,000 and over 120,000 injuries across the two nations.

Evolution and spatiotemporal analysis of earthquake public opinion based on social media data

As critical conduits for the dissemination of online public opinion,social media platforms offer a timely and effective means for managing emergencies during major disasters,such as earthquakes.This study focuses on the analysis of online public opinions following the Maduo M7.4 earthquake in Qinghai Province and the Yangbi M6.4 earthquake in Yunnan Province.By collecting,cleaning,and organizing post-earthquake Sina Weibo(short for Weibo)data,we employed the Latent Dirichlet Allocation(LDA)model to extract information pertinent to public opinion on these earthquakes.This analysis included a comparison of the nature and temporal evolution of online public opinions related to both events.An emotion analysis,utilizing an emotion dictionary,categorized the emotional content of post-earthquake Weibo posts,facilitating a comparative study of the characteristics and temporal trends of online public emotions following the earthquakes.The findings were visualized using Geographic Information System(GIS)techniques.The analysis revealed certain commonalities in online public opinion following both earthquakes.Notably,the peak of online engagement occurred within the first 24 hours post-earthquake,with a rapid decline observed between 24 to 48 hours thereafter.The variation in popularity of online public opinion was linked to aftershock occurrences.Adjusted for population factors,online engagement in areas surrounding the earthquake sites and in Sichuan Province was significantly high.Initially dominated by feelings of“fear”and“surprise”,the public sentiment shifted towards a more positive outlook with the onset of rescue operations.However,distinctions in the online public response to each earthquake were also noted.Following the Yangbi earthquake,Yunnan Province reported the highest number of Weibo posts nationwide;in contrast,Qinghai Province ranked third post-Maduo earthquake,attributable to its smaller population size and extensive damage to communication infrastructure.This research offers a methodological approach for the analysis of online public opinion related to earthquakes,providing insights for the enhancement of post-disaster emergency management and public mental health support.

Physical and Thermo-Mechanical Properties of Composite Materials Based on Raw Earth and Crushed Palm Leaf Fibers (Borassus aethiopum)

The objective of this study is to seek solutions to reduce the impact of buildings on climate change and to promote the use of local bio-sourced or geo-sourced materials for sustainable construction. Different samples of raw earth from 3 sites were taken in the commune of Mlomp. Geotechnical tests showed that the raw earth samples from sites 2 and 3 have more clay fraction while site 1 contains more sand. The fact of integrating fibers from crushed palm leaves (Borassus aethiopum) (2%, 4% and 6%) into the 3 raw earth samples reduced the mechanical resistance to compression and traction of the 3 raw earths. The experimental results of thermal tests on samples of earth mixtures with crushed Palma leaf fibers show a decrease in thermal conductivity as well as thermal effusivity as the percentages increase (2%, 4% and 6%) of fibers in raw earth for the 3 sites. This shows that this renewable composite material can help improve the thermal insulation of building envelopes.

Rare earth element geochemistry of Post-to Neo-archean shales from Singhbhum mobile belt, Eastern India: implications for tectonic setting and paleo-oxidation conditions

In the present study, trace element(including rare earth element) chemical data has been interpreted with the aim to decipher the tectonic setting and paleo-redox conditions of the Post- to Neo-archean shales from the Singhbhum Mobile Belt, eastern India. The data show moderate enrichment of compatible elements [such as Cu(avg. 59.28 ppm), Ni(avg. 59.49 ppm), V(avg.234.24 ppm) and Cr(avg. 181.23 ppm)] relative to the Post-Archean Australian Shale. Their chondrite normalized light rare earth elements are moderately fractionated [(La/Sm)Nranges from 2.21 to 5.78], whereas heavy rare earth elements show a nearly flat pattern [(Gd/Lu)Nranges from0.74 to 1.68]; this indicates that the rare earth element(REE) concentrations, rather than being severely affected by the diagenesis and weathering processes, decreased gradually from Gd to Lu. The Post-Archean Australian Shale normalized multi-element diagram shows the slight enrichment of Cr, V, Zr, Y, U and Sc, whereas Sr, Pb, Hf and Th are depleted. The notable negative anomaly of Sr indicates the least accumulation of plagioclase, which is also supported by the negative Eu-anomaly in these rocks.The La–Th–Sc and Th–Zr–Sc tectonic setting diagrams indicate their continental arc setting. The geochemical parameters, such as U/Th, V/Cr, Ni/Co, and Cu/Zn, indicate that these shales were deposited under oxic to anoxic environmental conditions.

Soft-sediment Deformation Structures Related to Earthquake from the Devonian of the Eastern North Qilian Mts.and Its Tectonic Significance

Devonian in the North Qilian orogenic belt and Hexi Corridor developed terrestrial molasse of later stage of foreland basin caused by collision between the North China plate and Qaidam microplate. The foreland basin triggered a intense earthquake, and formed seismites and earthquake-related soft-sediment deformation. The soft-sediment deformation structures of Devonian in the eastern North Qilian Mts. consist of seismo-cracks, sandstone dykes, syn-depositional faults, microfoids （micro-corrugated lamination）, fluidized veins, load casts, flame structures, pillow structures and brecciation. The seismo-cracks, syn-depositional faults and microfolds are cracks, faults and folds formed directly by oscillation of earthquake. The seismic dykes formed by sediment instilling into seismic cracks. Fluidized veins were made by instilling into the seismo-fissures of the fluidized sands. The load casts, flame structures and pillow structures were formed by sinking and instilling caused from oscillation of earthquake along the face between sandy and muddy beds. The brecciation resulted from the oscillation of earthquake and cracking of sedimentary layers. The seismites and soft-sediment deformations in Devonian triggered the earthquake related to tectonic activities during the orogeny and uplift of North Qilian Mts.

Rock Damage Structure of the South Longmen-Shan Fault in the 2008 M8 Wenchuan Earthquake Viewed with Fault-Zone Trapped Waves and Scientific Drilling

This article is to review results from scientific drilling and fault-zone trapped waves （FZTWs） at the south Longman-Shan fault （LSF） zone that ruptured in the 2008 May 12 M8 Wenchuan earthquake in Sichuan,China.Immediately after the mainshock,two Wenchuan Fault Scientific Drilling （WFSD） boreholes were drilled at WFSD-1 and WFSD-2 sites approximately 400 m and 1 km west of the surface rupture along the Yinxiu-Beichuan fault （YBF）,the middle fault strand of the south LSF zone.Two boreholes met the principal slip of Wenchuan earthquake along the YBF at depths of 589-m and 1230-m,respectively.The slip is accompanied with a 100-200-m-wide zone consisting of fault gouge,breccia,cataclasite and fractures.Close to WFSD-1 site,the nearly-vertical slip of ～4.3-m with a 190-m wide zone of highly fractured rocks restricted to the hanging wall of the YBF was found at the ground surface after the Wenchuan earthquake.A dense linear seismic array was deployed across the surface rupture at this venue to record FZTWs generated by aftershocks.Observations and 3-D finite-difference simulations of FZTWs recorded at this cross-fault array and network stations close to the YBF show a distinct low-velocity zone composed by severely damaged rocks along the south LSF at seismogenic depths.The zone is several hundred meters wide along the principal slip,within which seismic velocities are reduced by ～30-55％ from wall-rock velocities and with the maximum velocity reduction in the ～200-m-wide rupture core zone at shallow depth.The FZTW-inferred geometry and physical properties of the south LSF rupture zone at shallow depth are in general consistent with the results from petrological and structural analyses of cores and well log at WFSD boreholes.We interpret this remarkable low-velocity zone as being a break-down zone during dynamic rupture in the 2008 M8 earthquake.We examined the FZTWS generated by similar earthquakes before and after the 2008 mainshock and observed that seismic velocities within fault core zone was reduced by ～10％ due to severe damage of fault rocks during the M8 mainshock.Scientific drilling and locations of aftershocks generating prominent FZTWs also indicate rupture bifurcation along the YBF and the Anxian-Guangxian fault （AGF）,two strands of the south LSF at shallow depth.A combination of seismic,petrologic and geologic study at the south LSF leads to further understand the relationship between the fault-zone structure and rupture dynamics,and the amplification of ground shaking strength along the low-velocity fault zone due to its waveguide effect.

Geochemistry and multivariate statistical evaluation of major oxides, trace and rare earth elements in coal occurrences and deposits around Kogi east, Northern Anambra Basin, Nigeria

The Cretaceous Mamu Formation coal samples located within the Northern Anambra Basin were collected, analysed and interpreted using multivariate statistical approach to determine the major, trace and rare elements association with a view to determine the source of the terrestrial rocks, palaeoweathering/climatic conditions and tectonic setting. The dominant oxides such as SiO2, A12O3, Fe2O3, TiO2 and CaO were identified in the coal to suggest terrigenous origin. The ratio of SiO2/Al2O3 of 4.8 suggests that the coal was formed from low land peat associated with freshwater continental marine or blackish water with low salinity as indicated by Sr/Ba and CaO + MgO/K2O + Na2。ratios. The major oxides also revealed stable condition of deposition, low degree of tectonic setting but constant subsidence in the basin. The condition of deposition was acidic in nature as indicated by TiO2/Zr plot. Based on the abundance of Zr, Zn, Ba, Ni, Co, Sr, V, and Y, moderate salinity, sub-oxic to oxic bottom water condition was prevalent and also indication of marine influence. Based on the ratios of La/Yb;La/Sm and Gd/Yb, LREE has higher enrichment than HREE. Humid climatic conditions were observed at the coal formation stage while weak laterization to kaolinization was also evidence.

Earth observation big data for climate change research

Earth observation technology has provided highly useful information in global climate change research over the past few decades and greatly promoted its development,especially through providing biological,physical,and chemical parameters on a global scale.Earth observation data has the 4V features(volume,variety,veracity,and velocity) of big data that are suitable for climate change research.Moreover,the large amount of data available from scientific satellites plays an important role.This study reviews the advances of climate change studies based on Earth observation big data and provides examples of case studies that utilize Earth observation big data in climate change research,such as synchronous satelliteeaerialeground observation experiments,which provide extremely large and abundant datasets; Earth observational sensitive factors(e.g.,glaciers,lakes,vegetation,radiation,and urbanization); and global environmental change information and simulation systems.With the era of global environment change dawning,Earth observation big data will underpin the Future Earth program with a huge volume of various types of data and will play an important role in academia and decisionmaking.Inevitably,Earth observation big data will encounter opportunities and challenges brought about by global climate change.

Geochemistry of rare earth elements in groundwater from deep seated limestone aquifer in Renlou Coal Mine,Anhui Province,China

Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It can be concluded that the groundwater is warm （34.0-37.2 ℃） C1-Ca, Na type water with circum-neutral pH （7.35-8.28） and high total dissolved solids （TDS, 1 746-2 849 mg/L）. The groundwater exhibits heavy REEs enrichment relative to light REEs compared with Post Archean Average Shale （PAAS）, as well as their aquifer rocks （limestone）. The enrichment of REEs is considered to be controlled by terrigeneous materials （e.g. zircon） in aquifer rocks, whereas the fractionation of REEs is controlled by marine derived materials （e.g. calcite）, to a less extent, terrigeneous materials and inorganic complexation. The Ce anomalies normalized to PAAS and aquifer rocks are weak, which probably reflects the signature of the aquifer rock rather than redox conditions or pH. The similarities of REE patterns between groundwater and aquifer rocks imply that aquifer rocks play important roles in controlling the REE characteristics of groundwater, and then provide a probability for discrimination of groundwater sources by using REEs.

Shear velocity structure of crust and uppermost mantle in China from surface wave tomography using ambient noise and earthquake data

We present a 3D model of shear velocity of crust and upper mantle in China and surrounding regions from surface wave tomography. We combine dispersion measurements from ambient noise correlation and traditional earthquake data. The stations include the China National Seismic Network, global networks, and all the available PASSCAL stations in the region over the years. The combined data sets provide excellent data coverage of the region for surface wave measurements from 8 to 120 s, which are used to invert for 3D shear wave velocity structure of the crust and upper mantle down to about 150 kin. We also derive new models of the study region for crustal thickness and averaged S velocities for upper, mid, and lower crust and the uppermost mantle. The models provide a fundamental data set for understanding continental dynamics and evolution. The tomography results reveal significant features of crust and upper mantle structure, including major basins, Moho depth variation, mantle velocity contrast between eastern and western North China Craton, widespread low-velocity zone in mid- crust in much of the Tibetan Plateau, and clear velocity contrasts of the mantle lithosphere between north and southern Tibet with significant E-W variations. The low velocity structure in the upper mantle under north and eastern TP correlates with surface geological boundaries. A patch of high velocity anomaly is found under the eastern part of the TP, which may indicate intact mantle lithosphere. Mantle lithosphere change from the western to The Tanlu Fault appears boundary. shows striking systematic eastern North China Craton. to be a major lithosphere