Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace ...Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming fluids.Three different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide veins.The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage.Compared with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i ratios.These features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition.Sch B shows dark(Sch B-I)and light(Sch B-II)domains under CL imaging.From Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually enriched.Sch C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde stage.The Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity.The extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit.展开更多
Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysi...Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that: (1) up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; (2) high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; (3) in gas reservoirs of such abiotic methane (〉80%) and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; (4) a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.展开更多
The zircon SHRIMP dating age for the Shangyou granites is 464±11 Ma. The geological feature of the pluton is consistent with the isotopic age, which shows that it is a product of Caledonian orogenesis. The Shangy...The zircon SHRIMP dating age for the Shangyou granites is 464±11 Ma. The geological feature of the pluton is consistent with the isotopic age, which shows that it is a product of Caledonian orogenesis. The Shangyou granites are regarded as peraluminous crust-derived granites to possess the typical geochemical characteristics of calc-alkaline rocks on the active continental margin with enriched Si, K, Al (A/CNK -- 1.11 on average), HREE, Rb, U, Th and heavily depleted V, Cr, Co, Ni, as well as Ti-Y, Nb-Ta, Zr, Sr, P and Ba, to be commonly corundum normative (av C -- 1.44). The Shangyou granites with higher 87Sr/86Sr ratios (0.707126-0.712186), ENd(t) values (-7.29 to -10.22) and (tDM) values (1.52-1.63 Ga), which are considered to result from partial melting of continental crust metamorphic sedimentary rocks with relatively low of crust maturation degree corresponding to the Middle Proterozoic, to have some possible contributions of mantle-derived components. The Shangyou granites are regarded as post-collision granites, which were formed in a transitional tectonic setting from compression to extension in the Middle Ordovician period after the Yangtze plate was subducted beneath the Cathaysian plate. The Ar-Ar total ages of K-feldspar and biotite are 292.1 Ma and 295.5 Ma respectively, which have recorded information of a late-stage thermal alteration event.展开更多
Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite,muscovite and K-feldspar,giving a petrogenetic age of 167 Ma.Owing to the closu...Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite,muscovite and K-feldspar,giving a petrogenetic age of 167 Ma.Owing to the closure systems in different minerals,the cooling history of the pluton can be determined with an age-temperature diagram.The late hydrothermal event has been recognized,which is related probably with mineralization.In terms of the comparative geochronological and petrologic records,it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics.And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny.The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.展开更多
Fractal geometry is increasingly becoming a useful tool for modeling and quantifying the complex patterns of natural phenomena. The Earth's topography is one of these phenomena that have fractal characteristics. T...Fractal geometry is increasingly becoming a useful tool for modeling and quantifying the complex patterns of natural phenomena. The Earth's topography is one of these phenomena that have fractal characteristics. This paper investigates the relative sensitivity of topography to active tectonics using ASTER Global Digital Elevation Model. The covering divider method was used for direct extraction of surface fractal dimension(D surf) to estimate the roughness-surface of topography with aid of geographic information system(GIS)techniques. This evaluation let us highlight the role of the geomorphic and tectonic processes on the spatial variability of fractal properties of natural landforms.Geomorphic zones can be delineated using fractal dimension mapping in which variability of surface fractal dimension reflects the roughness of the landform surface and is a measure of topography texture. Obtained results showed this method can be a quick and easy way to assess the distribution of land surface deformation in different tectonic settings. The loose alluvial deposits and irregularities derived by tectonic activity have high fractal dimensions whereas the competent formations and higher wavelength folded surfaces have lower fractal dimensions.According to the obtained results, the Kazerun Fault Zone has a crucial role in the separation of the Zagros Mountain Ranges into the different lithological,geomorphological and structural zones.展开更多
The energy radiated as seismic waves strongly depends on the fault rupture process associated with rupture speed and dynamic frictional mechanisms involved in the fault slip motion. Following McGarr and Fletcher appro...The energy radiated as seismic waves strongly depends on the fault rupture process associated with rupture speed and dynamic frictional mechanisms involved in the fault slip motion. Following McGarr and Fletcher approach, we derived a physics-based relationship of the weighted average fault slip velocity vs apparent stress, rupture speed and static stress drop based on a dynamic circular fault model. The resultant function can be approximately used to bound near-fault ground motion and seismic energy associated with near-fault coseismic deformation. Fault frictional overshoot and under- shoot mechanisms governed by a simple slip-weakening constitutive relation are included in our consideration by using dy- namic rupture models named as M- and D-models and proposed by Madariaga (1976) and Boatwright. We applied the above function to the 2008 great Wenchuan earthquake and the 1999 Jiji (Chi-Chi) earthquake to infer the near-fault ground motion called slip weighted average particle velocity and obtained that such model-dependent prediction of weighted average ground velocities is consistent to the results derived from the near-fault strong motion observations. Moreover, we compared our re- sults with the results by McGarr and Fletcher approach, and we found that the values of the weighted average particle veloci- ties we obtained for these two earthquakes are generally smaller and closer to the values by direct integration of strong mo- tion recordings of the near-fault particle velocity waveform data. In other words, if this result comes to be true, it would be a straightforward way used to constrain the near-fault ground motion or to estimate source parameters such as rupture speed, static and dynamic stress drops.展开更多
Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distribut...Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distributed at the edge of faults,in poor sand bodies,and in insufficiently injected and produced areas.Therefore,the edge of faults is a major target for remaining oil enrichment and potential tapping.Based on the dynamic change of production from development wells determined by the injection-recovery relationship at the edge of faults,we analyzed the control of structural features of faults on remaining oil enrichment at the edge.Our results show that the macroscopic structural features and their geometric relationship with sand bodies controlled remaining oil enrichment zones like the edges of NNE-striking faults,the footwalls of antithetic faults,the hard linkage segments(two faults had linked together with each other to form a bigger through-going fault),the tips of faults,and the oblique anticlines of soft linkages.Fault edges formed two types of forward microamplitude structures:(1) the tilted uplift of footwalls controlled by inverse fault sections and(2) the hanging-wall horizontal anticlines controlled by synthetic fault points.The remaining oil distribution was controlled by microamplitude structures.Consequently,such zones as the tilted uplift of the footwall of the NNW-striking antithetic faults with a fault throw larger than 40 m,the hard linkage segments,the tips of faults,and the oblique anticlines of soft linkage were favorable for tapping the remaining oil potential.Multi-target directional drilling was used for remaining oil development at fault edges.Reasonable fault spacing was determined on the basis of fault combinations and width of the shattered zone.Well core and log data revealed that the width of the shattered zone on the side of the fault core was less than 15 m in general;therefore,the distance from a fault to the development target should be larger than 15 m.Vertically segmented growth faults should take the separation of the lateral overlap of faults into account.Therefore,the safe distance of remaining oil well deployment at the fault edge should be larger than the sum of the width of shattered zone in faults and the separation of growth faults by vertical segmentation.展开更多
Jurassic and Triassic coals and organic matter-rich shales of the Tabas Basin, Iran, were investigated with respect to their thermal maturation and petrographic composition. The Triassic coals of the Parvadeh coal fie...Jurassic and Triassic coals and organic matter-rich shales of the Tabas Basin, Iran, were investigated with respect to their thermal maturation and petrographic composition. The Triassic coals of the Parvadeh coal field range in vitrinite reflectance between 1.17% and 1.37% and the Jurassic coals of the Mazino coal field between 2.08% and 2.29% VRr. Maceral analysis revealed a predominance of vitrinite in all samples, with slightly higher percentages of inertinite in the Jurassic samples. Rock-Eval analyses confirm the presence of type III kerogen in the Triassic coals, while the Jurassic coals contain strongly carbonized residual kerogen. The range of sulfur contents for coals from the Parvadeh coal field (0.37% to 4.64%) and Mazino coal field (0.45% to 2.92%) is related to the effect of marine water in peat. The studied samples are characterized by the predominance of short- over long-chained n-alkanes. The relatively high Pr/Ph ratios indicate predominance of terrestrial organic matter whereas Pr/n-C17 and Ph/n-C18 ratios prove oxic conditions during deposition. In addition, the DBT/Phen ratio shows that these coals formed in fluvial/deltaic environments. Molecular geochemical parameters such as carbon preference index (CPI, 0.99-1.04), methyl phenanthrene index (MPI, 1.20-1.60), methyl naphthalene ratio (MNR, 1.61-3.45), and ethyl naphthalene ratio (ENR, 4-6.78) confirm the high maturity of the samples. Burial and thermal history reconstruction indicates necessity of an erosional thickness of about 4000 m in the Parvadeh area. Towards the Mazino area, a higher basal heat flow up to 80 mW m^-2 is assumed for the Paleogene leading to higher maturities.展开更多
The faults and fractures are known as two of the most important parameters in earthquake occurrence.During the construction in urban areas, faults and fractures may be covered in depth and thus are not visible at the ...The faults and fractures are known as two of the most important parameters in earthquake occurrence.During the construction in urban areas, faults and fractures may be covered in depth and thus are not visible at the ground surface. In this context, non-invasive geophysical prospecting methods(microtremor and geoelectrical methods) and borehole data were used to detect subsurface geological structures(hidden faults) in a suburb of Shiraz in Iran. The horizontal to vertical spectral ratio(HVSR) method was used to obtain the dynamic parameters(predominant frequency and resonance amplitude) of the soil, to detect hidden faults. The results show that the abrupt changes in the sediment thickness and predominant frequencies at a specific direction(NW-SE) can be related to the displacement of a nearly vertical fault with NW-SE trend. In addition, the electrical resistivity method using continuous resistivity profiling(CRP) and Schlumberger arrays was employed to detect a hidden fault and the results were compared with previous data. The obtained results of both arrays illustrate the presence of a nearly vertical fault with NW-SE trend in the region. Comparison of all results shows that the detected faults by both methods are consistent with each other. Therefore, it can be conclusive that combination of the two methods is a useful and reliable approach to study and detect hidden faults.展开更多
The aim of this work is to establish volcanic seismic reflection configuration models in the rift basins of Northeast China from a new perspective,the volcanostratigraphic structure.Accordingly,the volcanostratigraphi...The aim of this work is to establish volcanic seismic reflection configuration models in the rift basins of Northeast China from a new perspective,the volcanostratigraphic structure.Accordingly,the volcanostratigraphic structure of an outcrop near the Hailaier Rift Basin was analyzed to understand the characteristics and causal factors of physical boundaries.Further,3D seismic reflection data and analysis of deep boreholes in the Songliao Rift Basin were used to establish the relationship between volcanic seismic reflection configurations and volcanostratigraphic structures.These studies suggested that in volcanic successions,physical boundaries coincide with volcanic boundaries,and their distributions are controlled by the stacking patterns of volcanic units.Therefore,volcanic seismic reflection configurations can be interpreted in terms of the stacking patterns of volcanic units.These are also referred to as general bedding patterns in volcanostratigraphy.Furthermore,four typical seismic reflection configurations were identified,namely,the chaotic,the parallel continuous,the hummocky,the multi-mound superimposed and the composite.The corresponding interpretation models comprised single massive unit,vertical,intersectional,lateral multi-mound,and composite stacking patterns.The hummocky and composite reflection configurations with intersectional and composite stacking patterns are the most favorable for the exploration of volcanic reservoirs in rift basins.展开更多
In this paper, remote sensing techniques,as well as field studies, have been used to investigate the geomorphological processes and landscape evolution along the Saravan Fault, SE Iran to highlight how topographic fea...In this paper, remote sensing techniques,as well as field studies, have been used to investigate the geomorphological processes and landscape evolution along the Saravan Fault, SE Iran to highlight how topographic features were influenced by active tectonics. Quantitative geomorphic analysis was carried out using mountain-front sinuosity(Smf),valley floor width-valley height ratio(Vf), drainage basin asymmetry factor(Af), Hypsometric integral(Hi), drainage basin shape index(Bs), mean axial slope of channel(MASC), standard deviation of topography(STD) and index of active tectonic(Iat).Remote sensing techniques, as well as field studies revealed that the Saravan Fault have three parts trending N-S, NW-SE, and E-W. Obtained results show that basins with high Iat index are located at where the strike of the Saravan Faults changes and where several strike-slip faults are crossed the Saravan fault.展开更多
Although the urban heat island(UHI) is a well-documented phenomenon, relatively little information in the literature is available about its impact on summer extreme heat event(EHE). As UHI is characterized by increase...Although the urban heat island(UHI) is a well-documented phenomenon, relatively little information in the literature is available about its impact on summer extreme heat event(EHE). As UHI is characterized by increased temperature, it can potentially increase the magnitude and duration of EHEs within cities. Based on daily maximum temperature records from 62 observation stations in Zhejiang province from the period 1971-2011 and satellite-measured nighttime light imagery from the Defense Meteorological Satellite Program(DMSP) Operational Linescan System(OLS) during 1992-2010, we analyzed the long-term change of summer EHEs and its association with the rapid urbanization process. The results could be concluded as follows:(1) Zhejiang has experienced rapid urbanization and dramatic growth in urban areas in the past two decades, especially after 2000.(2) The summer mean maximum temperature and the 95 th percentile of summer daily maximum temperature in most of its stations have increased, with the most significant increase occurring in the highly urbanized areas including the city belt around Hangzhou Bay, Taizhou-Wenzhou and Jinghua-Yiwu city belts.(3) The hot days and hot-day degrees, defined by both daily 95 th percentile and the threshold of 35℃, show that the UHI effect causes additional hot days and heat stress in urban stations compared to rural stations.The results in this study suggest that the UHI effect should be determined and incorporated in preparing high temperature forecasts in cities.展开更多
The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich...The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich wetlands in China,was selected as a case study for researching the changes that the urban wetlands have undergone and their impact on the urban thermal environment.Land surface temperature(LST) was acquired from the thermal infrared data of Landsat 5 Thematic Mapper(TM) images in 1990,1995,2000,2006,and 2010,using the single-channel method.The results are as follows:1) considering the changes in land use,the urban wetlands located to the west of Hangzhou have decreased significantly during 1990–2010 because of rapid urbanization.In the Xixi Wetland,the change in land use was relatively small and most of the water body and vegetation were preserved.However,to the east of the Xixi Wetland,large areas of water body and vegetation have been replaced by built-up land as a result of the urbanization process;2) considering the change in LST,it was found from land surface temperature retrieval that the changing spatial pattern of the thermal field was highly correlated with land use changes.Low temperature regions of the eastern Xixi Wetland were gradually eroded by high temperature regions,and the centroid of the heat island in East Xixi was found to be constantly shifting westward.In addition,the difference in LST between the Xixi Wetland and East Xixi has increased;3) considering the impact factors for this area,land use structure and patch shape were found to have a significant impact on LST,shown by the results of multiple linear stepwise regressions.Increasing the size of the wetlands in urban planning is considered to be the most effective measure in alleviating the urban heat island effect.Moreover,reducing the spatial complexity of landscape patches also contributes to the alleviation of the urban heat island effect.展开更多
Based on seismic and drilling data,the reactivation mechanism of the pre-existing basement F4 strike-slip faultin Nanpu sag and its controlling effect on hydrocarbon accumulation difference are systematically studied....Based on seismic and drilling data,the reactivation mechanism of the pre-existing basement F4 strike-slip faultin Nanpu sag and its controlling effect on hydrocarbon accumulation difference are systematically studied.By defining fault activation stages,back-stripping fault throw and physical modeling,it is found that the Nanpu No.4 structural zone formed by the Cenozoic reactivity of the F4 fault grew from south to north,with strike-slip deformation dominated in the south and extensional deformation dominated in the north.Faults in the No.4 structural zone and those in the adjacent No.2 and No.3 structural zones were different fault systems,which grew separately,contacted and connected,and finally interwove under the action of unified stress field.By constructing the identification chart of deformation mechanisms of reactivation of pre-existing faults,it is concluded that during the sedimentary period of the Paleogene Shahejie Formation,F4 fault was reactivated by strike-slip faulting,and during the sedimentary period of Paleogene Dongying Formation and Neogene Guantao-Minghuazhen formations,it was reactivated by oblique extension.The controlling effects of Cenozoic reactivation of F4 fault on hydrocarbon accumulation include:(1)As the oil-source fault,it controlled the vertical cross-layer migration of oil and gas.(2)It gave rise to strike-slip transfer zone to control the distribution of sand bodies.(3)It grew upward and interacted with faults in the neighboring area,controlling the formation of two types of traps,and was favorable for oil and gas accumulation.展开更多
The Oligocene–Miocene carbonate record of the Zagros Mountains, known as the Asmari Formation, constitutes an important hydrocarbon reservoir in southern Iran. This marine carbonate succession, which developed under ...The Oligocene–Miocene carbonate record of the Zagros Mountains, known as the Asmari Formation, constitutes an important hydrocarbon reservoir in southern Iran. This marine carbonate succession, which developed under tropical conditions, is explored in terms of larger foraminiferal biostratigraphy, facies analysis and sequence stratigraphy in a new section at Papoon cropping out in the western Fars sub-basin, in the south-east of the Zagros belt. Facies analysis shows evidence of re-working and transport of skeletal components throughout the depositional system, interpreted here as a carbonate ramp. The foraminifera-based biozones identified include the Globigerina–Turborotalia cerroazulensis–Hantkenina Zone and Nummulites vascus–Nummulites fichteli Zone, both of Rupelian age, the Archaias asmaricus–Archaias hensoni–Miogypsinoides complanatus Zone of Chattian age and the ‘Indeterminate’ Zone of Aquitanian age. The vertical sedimentary evolution of the formation exhibits a progressive shallowing of the facies belts and thus the succession is interpreted as a high-rank low-order regressive systems tract. This long-lasting Rupelian–Aquitanian regressive event is in accordance with accepted global long-term eustatic curves. Accordingly, long-term eustatic trends would have been a factor controlling accommodation during the deposition of the Asmari Formation studied in the western Fars sub-basin.展开更多
Sixteen physicochemical parameters including four major and ten trace metals were analyzed for seven top soil and six top stream sediment samples collected around the vicinity of cement factory in Mekelle, Ethiopia. W...Sixteen physicochemical parameters including four major and ten trace metals were analyzed for seven top soil and six top stream sediment samples collected around the vicinity of cement factory in Mekelle, Ethiopia. Water and aqua regia extraction techniques were deployed to determine the water soluble and near total concentration of the metals in the samples. Water extraction results verified the magnitude of loading of the metals from anthropogenic sources. The mean values of the water soluble metals are found to exceed the reference values except for Ca and Zn in both lithogenic media indicating the severity of pollution. Spatial distribution of the metals suggested that cement factory dust and traffic emissions represent the most important pollutant sources for the investigated area.? The mean proportion of the major and trace metals in the water soluble phase of soil can be put on a descending order as: Mg (57.76%) > Fe > Ca > K > Na > Mn (3.77%) and Mo (53.17%) > Cu > Co > As > Ni > Zn > Pb > Cr (5.02%) respectively. The order of major metals is almost reverse in the case of the stream sediment with slight difference in the order of the trace metals. Factor analysis has revealed that the first factor represents the contribution of metals (Mn, Cr, As, Co, Zn, Na, K, Cu, Pb and Ni) from local anthropogenic activities, whereas the second factor represents the contribution of metals (Na, Fe, Cu, Pb, Ni, Ca, As, Co, Zn and Mo) from both lithogenic and anthropogenic origins. Third factor consists of Ca, Mo, Mg, and Fe from geogenic source of the local geology. It is spatially evident that the cement dust emission has an impact on the soil’s Cr, Co, Mo and Ni content which drastically decreases downstream. The spatial pattern of Cu, Pb, As, Zn and Co shows significant association with the cement dust and loadings from the traffic movement on the road.展开更多
In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-...In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-1,3,5-triazine by photo-Fenton process is more rapid and more effective than Fenton and UV/H2O2 processes. The effects of certain experimental parameters on kinetics and efficiency of the degradation of 2-chloro-4,6,-diamino-1,3,5-triazine by photo-Fenton process, have been evaluated. Under optimal conditions, photo-Fenton process achieved more than 90% of chloride release and about 30% of nitrate formation. The results of total organic carbon (TOC) and total Kjeldahl nitrogen (TKN) analyses have shown that no carbon dioxide and ammonia are formed during photo-Fenton treatment of aqueous solutions containing 40 mg/L triazine. These results indicate that only substituent groups of triazine ring are released;however, nitrogen atoms of triazine ring remain unaffected. A simple mechanism of degradation of 2-chloro-4,6-diamino-1,3,5-triazine has been proposed. The degradation starts by a rapid release of chlorine atoms as chloride ions to form 2-hydroxy-4,6-diamino-1,3,5-triazine. The amino groups of 2-hydroxy-4,6-diamino-1,3,5-triazine undergo are oxidized into nitro groups by hydroxyl radicals to form 2-hydroxy-4,6-dinitro-1,3,5-triazine which undergoes a slow release of nitro groups and their substitution with hydroxyl groups to form cyanuric acid and nitrate ions. The degradation of cyanuric acid by photo-Fenton process has also been investigated. The results of TOC and TKN analyzes show that no carbon dioxide is formed during the treatment.展开更多
It is known that the Amazon region plays an important role in the global energy, hydrological cycle and carbon balance. This region has been suffering from the course of the past 40 years intense land use and land cov...It is known that the Amazon region plays an important role in the global energy, hydrological cycle and carbon balance. This region has been suffering from the course of the past 40 years intense land use and land cover changes. With this in mind, this study has examined possible associations between change in spatial and temporal rainfall variability and land cover change in the Amazon, using the PRECIS regional modelling system. It has been found that the impacts of land cover change by forest removal are more intense in the so-called “Arc of deforestation” over central and southern Amazonia. However, the relative impact of the simulated rainfall changes seems to be more important in the JJA dry season. In addition, the simulations under the deforestation scenarios also show the occurrence of extreme rainfall events as well as more frequent dry periods. Therefore, the results found show to be potentially important in the modulation of regional climate variations which have several environmental and socio-economic impacts.展开更多
基金jointly supported by the National Key Research and Development Program of China(Grant No.2022YFC2905001)the Basic Research Fund of the Chinese Academy of Geological Sciences(Grant No.JKYZD202316)+2 种基金the National Natural Science Foundation of China(Grant Nos.42272093,42230813,42002097)the Research Project of the Shengyuan Mining Co.,Ltd.,Tibet(Grant No.XZSYKYJT-JSFW2019-001)the China Scholarship Council project and the Geological Survey project(Grant Nos.DD20230054,DD20221684,DD20221690,DD20230031,DD20230049,DD20230338)。
文摘Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming fluids.Three different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide veins.The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage.Compared with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i ratios.These features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition.Sch B shows dark(Sch B-I)and light(Sch B-II)domains under CL imaging.From Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually enriched.Sch C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde stage.The Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity.The extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit.
文摘Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that: (1) up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; (2) high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; (3) in gas reservoirs of such abiotic methane (〉80%) and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; (4) a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.
文摘The zircon SHRIMP dating age for the Shangyou granites is 464±11 Ma. The geological feature of the pluton is consistent with the isotopic age, which shows that it is a product of Caledonian orogenesis. The Shangyou granites are regarded as peraluminous crust-derived granites to possess the typical geochemical characteristics of calc-alkaline rocks on the active continental margin with enriched Si, K, Al (A/CNK -- 1.11 on average), HREE, Rb, U, Th and heavily depleted V, Cr, Co, Ni, as well as Ti-Y, Nb-Ta, Zr, Sr, P and Ba, to be commonly corundum normative (av C -- 1.44). The Shangyou granites with higher 87Sr/86Sr ratios (0.707126-0.712186), ENd(t) values (-7.29 to -10.22) and (tDM) values (1.52-1.63 Ga), which are considered to result from partial melting of continental crust metamorphic sedimentary rocks with relatively low of crust maturation degree corresponding to the Middle Proterozoic, to have some possible contributions of mantle-derived components. The Shangyou granites are regarded as post-collision granites, which were formed in a transitional tectonic setting from compression to extension in the Middle Ordovician period after the Yangtze plate was subducted beneath the Cathaysian plate. The Ar-Ar total ages of K-feldspar and biotite are 292.1 Ma and 295.5 Ma respectively, which have recorded information of a late-stage thermal alteration event.
文摘Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite,muscovite and K-feldspar,giving a petrogenetic age of 167 Ma.Owing to the closure systems in different minerals,the cooling history of the pluton can be determined with an age-temperature diagram.The late hydrothermal event has been recognized,which is related probably with mineralization.In terms of the comparative geochronological and petrologic records,it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics.And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny.The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.
基金the Research Council of Shiraz University which has supported the project
文摘Fractal geometry is increasingly becoming a useful tool for modeling and quantifying the complex patterns of natural phenomena. The Earth's topography is one of these phenomena that have fractal characteristics. This paper investigates the relative sensitivity of topography to active tectonics using ASTER Global Digital Elevation Model. The covering divider method was used for direct extraction of surface fractal dimension(D surf) to estimate the roughness-surface of topography with aid of geographic information system(GIS)techniques. This evaluation let us highlight the role of the geomorphic and tectonic processes on the spatial variability of fractal properties of natural landforms.Geomorphic zones can be delineated using fractal dimension mapping in which variability of surface fractal dimension reflects the roughness of the landform surface and is a measure of topography texture. Obtained results showed this method can be a quick and easy way to assess the distribution of land surface deformation in different tectonic settings. The loose alluvial deposits and irregularities derived by tectonic activity have high fractal dimensions whereas the competent formations and higher wavelength folded surfaces have lower fractal dimensions.According to the obtained results, the Kazerun Fault Zone has a crucial role in the separation of the Zagros Mountain Ranges into the different lithological,geomorphological and structural zones.
基金supported by the Knowledge Innovation Program of Chinese Academy of Sciences (KZCX2-YW-Q08-2)One-Hundred-Individual Program of Chinese Academy of Sciences
文摘The energy radiated as seismic waves strongly depends on the fault rupture process associated with rupture speed and dynamic frictional mechanisms involved in the fault slip motion. Following McGarr and Fletcher approach, we derived a physics-based relationship of the weighted average fault slip velocity vs apparent stress, rupture speed and static stress drop based on a dynamic circular fault model. The resultant function can be approximately used to bound near-fault ground motion and seismic energy associated with near-fault coseismic deformation. Fault frictional overshoot and under- shoot mechanisms governed by a simple slip-weakening constitutive relation are included in our consideration by using dy- namic rupture models named as M- and D-models and proposed by Madariaga (1976) and Boatwright. We applied the above function to the 2008 great Wenchuan earthquake and the 1999 Jiji (Chi-Chi) earthquake to infer the near-fault ground motion called slip weighted average particle velocity and obtained that such model-dependent prediction of weighted average ground velocities is consistent to the results derived from the near-fault strong motion observations. Moreover, we compared our re- sults with the results by McGarr and Fletcher approach, and we found that the values of the weighted average particle veloci- ties we obtained for these two earthquakes are generally smaller and closer to the values by direct integration of strong mo- tion recordings of the near-fault particle velocity waveform data. In other words, if this result comes to be true, it would be a straightforward way used to constrain the near-fault ground motion or to estimate source parameters such as rupture speed, static and dynamic stress drops.
基金financial support from the Natural Science Foundation of China (Grant No. 41272151, 41472126)the Natural Science Foundation for Distinguished Young Scholars of Heilongjiang Province, China (Grant No. JC201304)+1 种基金the Joint Funds of the National Natural Science Foundation of China (Grant No. U1562214)the Program for Huabei Oilfield (Grant No. HBYT-CY5-2015-JS-127)
文摘Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distributed at the edge of faults,in poor sand bodies,and in insufficiently injected and produced areas.Therefore,the edge of faults is a major target for remaining oil enrichment and potential tapping.Based on the dynamic change of production from development wells determined by the injection-recovery relationship at the edge of faults,we analyzed the control of structural features of faults on remaining oil enrichment at the edge.Our results show that the macroscopic structural features and their geometric relationship with sand bodies controlled remaining oil enrichment zones like the edges of NNE-striking faults,the footwalls of antithetic faults,the hard linkage segments(two faults had linked together with each other to form a bigger through-going fault),the tips of faults,and the oblique anticlines of soft linkages.Fault edges formed two types of forward microamplitude structures:(1) the tilted uplift of footwalls controlled by inverse fault sections and(2) the hanging-wall horizontal anticlines controlled by synthetic fault points.The remaining oil distribution was controlled by microamplitude structures.Consequently,such zones as the tilted uplift of the footwall of the NNW-striking antithetic faults with a fault throw larger than 40 m,the hard linkage segments,the tips of faults,and the oblique anticlines of soft linkage were favorable for tapping the remaining oil potential.Multi-target directional drilling was used for remaining oil development at fault edges.Reasonable fault spacing was determined on the basis of fault combinations and width of the shattered zone.Well core and log data revealed that the width of the shattered zone on the side of the fault core was less than 15 m in general;therefore,the distance from a fault to the development target should be larger than 15 m.Vertically segmented growth faults should take the separation of the lateral overlap of faults into account.Therefore,the safe distance of remaining oil well deployment at the fault edge should be larger than the sum of the width of shattered zone in faults and the separation of growth faults by vertical segmentation.
文摘Jurassic and Triassic coals and organic matter-rich shales of the Tabas Basin, Iran, were investigated with respect to their thermal maturation and petrographic composition. The Triassic coals of the Parvadeh coal field range in vitrinite reflectance between 1.17% and 1.37% and the Jurassic coals of the Mazino coal field between 2.08% and 2.29% VRr. Maceral analysis revealed a predominance of vitrinite in all samples, with slightly higher percentages of inertinite in the Jurassic samples. Rock-Eval analyses confirm the presence of type III kerogen in the Triassic coals, while the Jurassic coals contain strongly carbonized residual kerogen. The range of sulfur contents for coals from the Parvadeh coal field (0.37% to 4.64%) and Mazino coal field (0.45% to 2.92%) is related to the effect of marine water in peat. The studied samples are characterized by the predominance of short- over long-chained n-alkanes. The relatively high Pr/Ph ratios indicate predominance of terrestrial organic matter whereas Pr/n-C17 and Ph/n-C18 ratios prove oxic conditions during deposition. In addition, the DBT/Phen ratio shows that these coals formed in fluvial/deltaic environments. Molecular geochemical parameters such as carbon preference index (CPI, 0.99-1.04), methyl phenanthrene index (MPI, 1.20-1.60), methyl naphthalene ratio (MNR, 1.61-3.45), and ethyl naphthalene ratio (ENR, 4-6.78) confirm the high maturity of the samples. Burial and thermal history reconstruction indicates necessity of an erosional thickness of about 4000 m in the Parvadeh area. Towards the Mazino area, a higher basal heat flow up to 80 mW m^-2 is assumed for the Paleogene leading to higher maturities.
基金supported by the Center of Excellence for Environmental Geohazards and the Research Council of Shiraz University
文摘The faults and fractures are known as two of the most important parameters in earthquake occurrence.During the construction in urban areas, faults and fractures may be covered in depth and thus are not visible at the ground surface. In this context, non-invasive geophysical prospecting methods(microtremor and geoelectrical methods) and borehole data were used to detect subsurface geological structures(hidden faults) in a suburb of Shiraz in Iran. The horizontal to vertical spectral ratio(HVSR) method was used to obtain the dynamic parameters(predominant frequency and resonance amplitude) of the soil, to detect hidden faults. The results show that the abrupt changes in the sediment thickness and predominant frequencies at a specific direction(NW-SE) can be related to the displacement of a nearly vertical fault with NW-SE trend. In addition, the electrical resistivity method using continuous resistivity profiling(CRP) and Schlumberger arrays was employed to detect a hidden fault and the results were compared with previous data. The obtained results of both arrays illustrate the presence of a nearly vertical fault with NW-SE trend in the region. Comparison of all results shows that the detected faults by both methods are consistent with each other. Therefore, it can be conclusive that combination of the two methods is a useful and reliable approach to study and detect hidden faults.
基金Projects(41472304,41430322) supported by the National Natural Science Foundation of ChinaProject(2012CB822002) supported by National Major State Basic Research Program of China
文摘The aim of this work is to establish volcanic seismic reflection configuration models in the rift basins of Northeast China from a new perspective,the volcanostratigraphic structure.Accordingly,the volcanostratigraphic structure of an outcrop near the Hailaier Rift Basin was analyzed to understand the characteristics and causal factors of physical boundaries.Further,3D seismic reflection data and analysis of deep boreholes in the Songliao Rift Basin were used to establish the relationship between volcanic seismic reflection configurations and volcanostratigraphic structures.These studies suggested that in volcanic successions,physical boundaries coincide with volcanic boundaries,and their distributions are controlled by the stacking patterns of volcanic units.Therefore,volcanic seismic reflection configurations can be interpreted in terms of the stacking patterns of volcanic units.These are also referred to as general bedding patterns in volcanostratigraphy.Furthermore,four typical seismic reflection configurations were identified,namely,the chaotic,the parallel continuous,the hummocky,the multi-mound superimposed and the composite.The corresponding interpretation models comprised single massive unit,vertical,intersectional,lateral multi-mound,and composite stacking patterns.The hummocky and composite reflection configurations with intersectional and composite stacking patterns are the most favorable for the exploration of volcanic reservoirs in rift basins.
基金the Research Council of University of Sistan and Baluchestan which has supported the project
文摘In this paper, remote sensing techniques,as well as field studies, have been used to investigate the geomorphological processes and landscape evolution along the Saravan Fault, SE Iran to highlight how topographic features were influenced by active tectonics. Quantitative geomorphic analysis was carried out using mountain-front sinuosity(Smf),valley floor width-valley height ratio(Vf), drainage basin asymmetry factor(Af), Hypsometric integral(Hi), drainage basin shape index(Bs), mean axial slope of channel(MASC), standard deviation of topography(STD) and index of active tectonic(Iat).Remote sensing techniques, as well as field studies revealed that the Saravan Fault have three parts trending N-S, NW-SE, and E-W. Obtained results show that basins with high Iat index are located at where the strike of the Saravan Faults changes and where several strike-slip faults are crossed the Saravan fault.
基金National Science Foundation of China(41371068)"Strategic Priority Research Program(B)" of the Chinese Academy of Sciences(XDB05020403)
文摘Although the urban heat island(UHI) is a well-documented phenomenon, relatively little information in the literature is available about its impact on summer extreme heat event(EHE). As UHI is characterized by increased temperature, it can potentially increase the magnitude and duration of EHEs within cities. Based on daily maximum temperature records from 62 observation stations in Zhejiang province from the period 1971-2011 and satellite-measured nighttime light imagery from the Defense Meteorological Satellite Program(DMSP) Operational Linescan System(OLS) during 1992-2010, we analyzed the long-term change of summer EHEs and its association with the rapid urbanization process. The results could be concluded as follows:(1) Zhejiang has experienced rapid urbanization and dramatic growth in urban areas in the past two decades, especially after 2000.(2) The summer mean maximum temperature and the 95 th percentile of summer daily maximum temperature in most of its stations have increased, with the most significant increase occurring in the highly urbanized areas including the city belt around Hangzhou Bay, Taizhou-Wenzhou and Jinghua-Yiwu city belts.(3) The hot days and hot-day degrees, defined by both daily 95 th percentile and the threshold of 35℃, show that the UHI effect causes additional hot days and heat stress in urban stations compared to rural stations.The results in this study suggest that the UHI effect should be determined and incorporated in preparing high temperature forecasts in cities.
基金Under the auspices of National Natural Science Foundation of China(No.41101039,41371068)
文摘The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich wetlands in China,was selected as a case study for researching the changes that the urban wetlands have undergone and their impact on the urban thermal environment.Land surface temperature(LST) was acquired from the thermal infrared data of Landsat 5 Thematic Mapper(TM) images in 1990,1995,2000,2006,and 2010,using the single-channel method.The results are as follows:1) considering the changes in land use,the urban wetlands located to the west of Hangzhou have decreased significantly during 1990–2010 because of rapid urbanization.In the Xixi Wetland,the change in land use was relatively small and most of the water body and vegetation were preserved.However,to the east of the Xixi Wetland,large areas of water body and vegetation have been replaced by built-up land as a result of the urbanization process;2) considering the change in LST,it was found from land surface temperature retrieval that the changing spatial pattern of the thermal field was highly correlated with land use changes.Low temperature regions of the eastern Xixi Wetland were gradually eroded by high temperature regions,and the centroid of the heat island in East Xixi was found to be constantly shifting westward.In addition,the difference in LST between the Xixi Wetland and East Xixi has increased;3) considering the impact factors for this area,land use structure and patch shape were found to have a significant impact on LST,shown by the results of multiple linear stepwise regressions.Increasing the size of the wetlands in urban planning is considered to be the most effective measure in alleviating the urban heat island effect.Moreover,reducing the spatial complexity of landscape patches also contributes to the alleviation of the urban heat island effect.
基金Supported by the Heilongjiang Outstanding Young Talents Support Project(140119002)Research Project of PetroChina Science and Technology Innovation Fund(2020D-5007-0108)PetroChina"14th Five-Year Plan"Science and Technology Project(2021DJ0701).
文摘Based on seismic and drilling data,the reactivation mechanism of the pre-existing basement F4 strike-slip faultin Nanpu sag and its controlling effect on hydrocarbon accumulation difference are systematically studied.By defining fault activation stages,back-stripping fault throw and physical modeling,it is found that the Nanpu No.4 structural zone formed by the Cenozoic reactivity of the F4 fault grew from south to north,with strike-slip deformation dominated in the south and extensional deformation dominated in the north.Faults in the No.4 structural zone and those in the adjacent No.2 and No.3 structural zones were different fault systems,which grew separately,contacted and connected,and finally interwove under the action of unified stress field.By constructing the identification chart of deformation mechanisms of reactivation of pre-existing faults,it is concluded that during the sedimentary period of the Paleogene Shahejie Formation,F4 fault was reactivated by strike-slip faulting,and during the sedimentary period of Paleogene Dongying Formation and Neogene Guantao-Minghuazhen formations,it was reactivated by oblique extension.The controlling effects of Cenozoic reactivation of F4 fault on hydrocarbon accumulation include:(1)As the oil-source fault,it controlled the vertical cross-layer migration of oil and gas.(2)It gave rise to strike-slip transfer zone to control the distribution of sand bodies.(3)It grew upward and interacted with faults in the neighboring area,controlling the formation of two types of traps,and was favorable for oil and gas accumulation.
基金supported by the I + D + i research project CGL201560805-P (BIOGEOEVENTS)the Grup de Recerca Reconegut per la Generalitat de Catalunya 2017 SGR 824 "Geologia Sedimentària"
文摘The Oligocene–Miocene carbonate record of the Zagros Mountains, known as the Asmari Formation, constitutes an important hydrocarbon reservoir in southern Iran. This marine carbonate succession, which developed under tropical conditions, is explored in terms of larger foraminiferal biostratigraphy, facies analysis and sequence stratigraphy in a new section at Papoon cropping out in the western Fars sub-basin, in the south-east of the Zagros belt. Facies analysis shows evidence of re-working and transport of skeletal components throughout the depositional system, interpreted here as a carbonate ramp. The foraminifera-based biozones identified include the Globigerina–Turborotalia cerroazulensis–Hantkenina Zone and Nummulites vascus–Nummulites fichteli Zone, both of Rupelian age, the Archaias asmaricus–Archaias hensoni–Miogypsinoides complanatus Zone of Chattian age and the ‘Indeterminate’ Zone of Aquitanian age. The vertical sedimentary evolution of the formation exhibits a progressive shallowing of the facies belts and thus the succession is interpreted as a high-rank low-order regressive systems tract. This long-lasting Rupelian–Aquitanian regressive event is in accordance with accepted global long-term eustatic curves. Accordingly, long-term eustatic trends would have been a factor controlling accommodation during the deposition of the Asmari Formation studied in the western Fars sub-basin.
文摘Sixteen physicochemical parameters including four major and ten trace metals were analyzed for seven top soil and six top stream sediment samples collected around the vicinity of cement factory in Mekelle, Ethiopia. Water and aqua regia extraction techniques were deployed to determine the water soluble and near total concentration of the metals in the samples. Water extraction results verified the magnitude of loading of the metals from anthropogenic sources. The mean values of the water soluble metals are found to exceed the reference values except for Ca and Zn in both lithogenic media indicating the severity of pollution. Spatial distribution of the metals suggested that cement factory dust and traffic emissions represent the most important pollutant sources for the investigated area.? The mean proportion of the major and trace metals in the water soluble phase of soil can be put on a descending order as: Mg (57.76%) > Fe > Ca > K > Na > Mn (3.77%) and Mo (53.17%) > Cu > Co > As > Ni > Zn > Pb > Cr (5.02%) respectively. The order of major metals is almost reverse in the case of the stream sediment with slight difference in the order of the trace metals. Factor analysis has revealed that the first factor represents the contribution of metals (Mn, Cr, As, Co, Zn, Na, K, Cu, Pb and Ni) from local anthropogenic activities, whereas the second factor represents the contribution of metals (Na, Fe, Cu, Pb, Ni, Ca, As, Co, Zn and Mo) from both lithogenic and anthropogenic origins. Third factor consists of Ca, Mo, Mg, and Fe from geogenic source of the local geology. It is spatially evident that the cement dust emission has an impact on the soil’s Cr, Co, Mo and Ni content which drastically decreases downstream. The spatial pattern of Cu, Pb, As, Zn and Co shows significant association with the cement dust and loadings from the traffic movement on the road.
文摘In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-1,3,5-triazine by photo-Fenton process is more rapid and more effective than Fenton and UV/H2O2 processes. The effects of certain experimental parameters on kinetics and efficiency of the degradation of 2-chloro-4,6,-diamino-1,3,5-triazine by photo-Fenton process, have been evaluated. Under optimal conditions, photo-Fenton process achieved more than 90% of chloride release and about 30% of nitrate formation. The results of total organic carbon (TOC) and total Kjeldahl nitrogen (TKN) analyses have shown that no carbon dioxide and ammonia are formed during photo-Fenton treatment of aqueous solutions containing 40 mg/L triazine. These results indicate that only substituent groups of triazine ring are released;however, nitrogen atoms of triazine ring remain unaffected. A simple mechanism of degradation of 2-chloro-4,6-diamino-1,3,5-triazine has been proposed. The degradation starts by a rapid release of chlorine atoms as chloride ions to form 2-hydroxy-4,6-diamino-1,3,5-triazine. The amino groups of 2-hydroxy-4,6-diamino-1,3,5-triazine undergo are oxidized into nitro groups by hydroxyl radicals to form 2-hydroxy-4,6-dinitro-1,3,5-triazine which undergoes a slow release of nitro groups and their substitution with hydroxyl groups to form cyanuric acid and nitrate ions. The degradation of cyanuric acid by photo-Fenton process has also been investigated. The results of TOC and TKN analyzes show that no carbon dioxide is formed during the treatment.
文摘It is known that the Amazon region plays an important role in the global energy, hydrological cycle and carbon balance. This region has been suffering from the course of the past 40 years intense land use and land cover changes. With this in mind, this study has examined possible associations between change in spatial and temporal rainfall variability and land cover change in the Amazon, using the PRECIS regional modelling system. It has been found that the impacts of land cover change by forest removal are more intense in the so-called “Arc of deforestation” over central and southern Amazonia. However, the relative impact of the simulated rainfall changes seems to be more important in the JJA dry season. In addition, the simulations under the deforestation scenarios also show the occurrence of extreme rainfall events as well as more frequent dry periods. Therefore, the results found show to be potentially important in the modulation of regional climate variations which have several environmental and socio-economic impacts.