Chemical characteristics of PM_(2.5) during a typical haze episode in Guangzhou

The chemical characteristics（water-soluble ions and carbonaceous species） of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between normal and haze days.The highest contributors to PM2.5 were organic carbon（OC）,nitrate,and sulfate in haze days and were OC,sulfate,and elemental carbon（EC） in normal days.The concentrations of secondary species such as,NO3^-,SO4^2-,and NH4^＋ in haze days were 6.5,3.9,and 5.3 times higher than those in normal days,respectively,while primary species（EC,Ca^2＋,K^＋） show similar increase from normal to haze days by a factor about 2.2-2.4.OC/EC ratio ranged from 2.8 to 6.2 with an average of 4.7 and the estimation on a minimum OC/EC ratio showed that SOC（secondary organic carbon） accounted more than 36.6% for the total organic carbon in haze days.The significantly increase in the secondary species（SOC,NO3^-,SO4^2-,and NH4^＋）,especially in NO3^-,caused the worst air quality in this region.Simultaneously,the result illustrated that the serious air pollution in haze episodes was strongly correlated with the meteorological conditions.During the sampling periods,air pollution and visibility had a good relationship with the air mass transport distance;the shorter air masses transport distance,the worse air quality and visibility in Guangzhou,indicating the strong domination of local sources contributing to haze formation.High concentration of the secondary aerosol in haze episodes was likely due to the higher oxidation rates of sulfur and nitrogen species.

Tectonic Evolution of the Meso-Tethys in the Western Segment of Bangonghu-Nujiang Suture Zone: Insights from Geochemistry and Geochronology of the Lagkor Tso Ophiolite

The subduction of the Bangonghu-Nujiang Meso-Tethys and the collision between the Lhasa and Qiangtang blocks were important events in the growth of the Tibetan crust. However, the timing of collision initiation and closure timing, as well as nature and structure of the Bangonghu ocean basin, are still poorly constrained. The Lagkor Tso ophiolite, located in the south of Gerze County, Tibet, is one of the most completed ophiolites preserved in the southern side of the Bangonghu- Nujiang suture zone. This study discussed the tectonic evolution of the Bangonghu-Nujiang suture zone as revealed by the Lagkor Tso ophiolite investigated by field investigations, petrology, geochemistry, geochronology and tectonic analysis methods. We present new LA-ICP-MS zircon U-Pb and 39Ar/4~Ar ages for the Lagkor Tso ophiolite, in addition to geochemical and platinum-group element （PGE） data presented for the Lagkor Tso ophiolite in Tibet. It is suggested that the ancient Lagkor Tso oceanic basin split in Middle Jurassic （161.2 ± 2.7 Ma - 165.4 ± 3.5 Ma）, and experienced a second tectonic emplacement during the Early Cretaceous （137.90 ± 6.39 Ma）. The Lagkor Tso ophiolite likely developed in an independent suture zone. The Bangonghu-Nujiang ocean subducted southwards, and the dehydration of the subducting oceanic crust materials caused partial melting of the continental mantle wedge, which formed the second-order expanding center of the obduction dish. This led to inter-arc expansion, followed by the formation of inter-arc and back-arc basins with island arc features, which are represented by ophiolites around the Shiquanhe-Lagkor Tso -Yongzhu region. The tectonic environment presently can be considered to be similar to that of the current Western Pacific, in which a large number of island arc-ocean basin systems are developed.

Geochemistry of Alkali-rich Igneous Rocks of Northern Xinjiang and Its Implications for Geodynamics

Five nearly E-W-trending alkali-rich igneous rock belts are distributed from north to south in northern Xinjiang, and they are composed mainly of riebeckite, K-feldspar granite and high-K and medium-K calc-alkaline volcanic rocks and shoshonite. They were mainly emplaced or erupted between the Carboniferous and Permian. The compositions of Sr, Nd, Pb, and O isotopes imply that their principal resource materials are derived from the upper mantle or juvenile crust, indicating obvious continental growth in the Phanerozoic. The trace element association implies that their tectonic settings are within plate and volcanic arc for alkali-rich granites, and post-collisional are, late oceanic are and continental are for alkali-rich volcanic rocks. An archipelago model was suggested for the tectonic evolution in northern Xinjiang. It can be named the central-Asia-type orogeny, which is different from the so called circum-Pacific ocean-continent-type tectonics or the Alpine-Himalayan continent-continent-collisional orogeny.

Neoproterozoic Mafic Dykes and Basalts in the Southern Margin of Tarim,Northwest China:Age,Geochemistry and Geodynamic Implications

Neoproterozoic rifting-related mafic igneous rocks are widely distributed both in the northern and southern margins of the Tarim Block,NW China.Here we report the geochronology and systematic whole-rock geochemistry of the Neoproterozoic mafic dykes and basalts along the southern margin of Tarim.Our zircon U-Pb age,in combination with stratigraphic constraint on their emplacement ages,indicates that the mafic dykes were crystallized at ca.802 Ma,and the basalt, possibly coeval with the ca.740 Ma volcanic rocks in Quruqtagh in the northern margin of Tarim. Elemental and Nd isotope geochemistry of the mafic dykes and basalts suggest that their primitive magma was derived from asthenospheric mantle（OIB-like） and lithospheric mantle respectively,with variable assimilation of crustal materials.Integrating the data supplied in the present study and that reported previously in the northern margin of Tarim,we recognize two types of mantle sources of the Neoproterozoic mafic igneous rocks in Tarim,namely the matasomatized subcontinental lithospheric mantle（SCLM） in the northern margin and the long-term enriched lithospheric mantle and asthenospheric mantle in the southern margin.A comprehensive synthesis of the Neoproterozoic igneous rocks throughout the Tarim Block led to the recognition of two major episodes of Neoproterozoic igneous activities at ca.820-800 Ma and ca.780-740 Ma,respectively.These two episodes of igneous activities were concurrent with those in many other Rodinian continents and were most likely related to mantle plume activities during the break-up of the Rodinia.

Distribution and deposition of polycyclic aromatic hydrocarbons in precipitation in Guangzhou, South China

Polycyclic aromatic hydrocarbons （PAHs） were measured in precipitation from March to August 2005 in Guangzhou, South China. Fourteen PAHs were studied, and their total concentrations varied from 616.6 to 3486.7 ng/L in dissolved phase and from 403.8 to 3125.5 ng/L in particulate phase. The estimated deposition loading of PAHs was 3568 ug/m^2 during the monitoring period. The deposition of PAHs was a potential source for Pearl River comparing with the contents of surface water. In addition, the high concentration in precipitation here implied that PAHs pollution was a potential environmental problem in Guangzhou. Most precipitation concentrations of PAHs in March （the last month in winter in Guangzhou） were higher than in the other months （in rainy season）. PAHs inclined to be adsorbed to particulate phase with the increase of molecular weight in rainwater. Combustion of fossil fuel and biomass might be the major source of PAHs, while the direct leakage or volatilization from petroleum products might be insignificant.

Sensitive High Resolution Ion Micro-Probe U-Pb Zircon Geochronology and Geochemistry of Mafic Rocks from the Pulan-Xiangquanhe Ophiolite,Tibet:Constraints on the Evolution of the Neo-tethys

The Pulan-Xiangquanhe ophiolite in the western Yarlung Tsangpo suture zone of Tibet is investigated for its geochemistry,geochronology,and tectonic implications in detail.Sensitive high resolution ion micro-probe zircon U-Pb dating reveals that diabases in the ophiolite from the three locations of Xugugab,Mapam Yum Co and La＇nga Co are dated at 122.3±2.5 Ma,118.8±1.8 Ma and 120.5±1.9 Ma,respectively.These early Cretaceous mafic rocks have Na_2O＋K_2O,rare earth element patterns,trace elemental spider diagram and other geochemical fingerprints of typical mature back-arc basin affinity.Therefore,the Pulan-Xiangquanhe ophiolite formed under a mature back-arc basin environment,which was a product of this intra-oceanic subduction system.A suprasubduction system could have existed in the southern margin of Eurasia,which involved both intra-oceanic and continent-ward subductions.Extension dominated the southern margin of the Eurasian continent during the early Cretaceous.

Geochemistry and Genesis of the Late Jurassic Granitoids at Northern Great Hinggan Range:Implications for Exploration

The Longgouhe and Ershiyizhan intrusions of the Late Jurassic, located in the Upper Heilongjiang Basin of the northern Great Hinggan Range, are closely related to porphyry Cu-Au mineralizations. In lithology the intrusions are quartz diorite, quartz monzodiorite and granodiorite of high-K caIc-alkaline series, with minor aspects of shoshonite series. Their SiO2 and A1203 contents range from 61.37% to 66.59% and 15.35% to 17.06%, respectively. The MgO content ranges from 2.02 % to 3.47 %, with Mg# indices of 44-59. The （La/Yb）N and Eu/Eu＊ values range from 16.85 to 81.73 and 0.68 to 0.93, respectively, showing strong differentiation rare earth element （REE） patterns similar to those of adakites. The rocks are enriched in Ba, Sr and light REE （LREE）, obviously depleted in Nb and Ta, slightly depleted in Rb and Ti, and poor in Yb and Y, with Yb and Y contents of 0.31-1.32 ppm and 4.32-12.07 ppm, respectively. As indicated by Sr/Y ratios of 67.74-220.60, the rocks are characterized by low-Y and high-Sr contents, which characterize the adakites in the world. Holistically, geochemical tracers suggest that the interested intrusions are adakitic rocks. Given that the Paleo- Asian Ocean and Mongol-Okhotsk Ocean were closed in the Late Paleozoic and Permian-Middle Jurassic, respectively, the interested intrusions should be formed by partial melting of delaminated crust, which had been thickened during collisional orogeny between the Siberian and Mongolian- Sinokorean continents.

Geochronology and geochemistry of Late Carboniferous dykes in the Aqishan-Yamansu belt,eastern Tianshan:Evidence for a post-collisional slab breakoff

With aim of providing constraints on the Late Paleozoic tectonic evolution of the southern Central Asian Orogenic Belt(CAOB),an integrated study was conducted on the geochronological and geochemical data for dioritic,granitic and diabase dykes from the Aqishan-Yamansu belt in the eastern Tianshan,NW China.Zircon U-Pb dating indicates that the dioritic and granitic dykes were both emplaced in the Late Carboniferous(~311 Ma and^315 Ma).The dioritic dykes show adakitic characteristics and have high Na2 O and positiveεHf(t)values(+12 to+17),which suggest an origin from partial melts of a subducted oceanic slab.The granitic dykes have high SiO2 and K2 O contents and are characterized by en riched light rare earth elements(LREE)and slightly flat heavy rare earth elements(HREE),with negative Eu and Nb-Ta-Ti anomalies.These dykes are alkali-calcic and show geochemical features of highly fractionated Itype granites.Their positiveεHf(t)values(+16 to+17)suggest that they were derived from a juvenile accreted oceanic crustal sou rce.The coeval diabase dykes have low SiO2 and K2 O contents but high TiO2,MgO and Mg#(54-59).They are enriched in LREE and show characteristics of enriched mid-ocean ridge basalts(E-MORB).The relatively high Ba/Th,slightly low Th/Ta ratios,and negative Nb-Ta anomalies imply a mantle source metasomatised by slab-derived fluids.Thus,these basic dykes were generated likely by partial melting of the upwelling asthenosphere mantle with a slight influence of slab-derived fluids.Therefore,we suggest that the formation of these Late Carboniferous dykes were triggered by a post-collisional slab breakoff and the Aqishan-Yamansu belt was a continental arc formed by southdipping subduction of the Kangguer oceanic plate.

Geochemistry,Geochronology,Sr-Nd Isotopic Compositions of Jiang Tso Ophiolite in the Middle Segment of the Bangong- Nujiang Suture Zone and Their Geological Significance

The Jiang Tso ophiolite, situated in the middle segment of the Bangong- Nujiang Suture Zone, is a part of the easternmost Qieli Lake ophiolite subzone and is close to the south of Pung Lake ophiolite. The rock association of Jiang Tso ophiolite is relatively complete and is mainly composed of metamorphic peridotite, gabbro and diabase. Comparing with N-MORB, the ophiolite is high in Mg and low in Ti, K, Na, P, and is depleted in Nb, Ta, Hf, Th and enriched in Rb, Sr and Ba. Geochemical characteristics of the Jiang Tso ophiolite indicate it is of a supra-subduction zone type formed in the spreading ridge of back arc basin. The SHRIMP U-Pb dating of zircons from the gabbro yielded a weighted average age of 188.1±4.1 Ma （MSWD=1.4）, indicating the Jiang Tso ophiolite was formed in the late stage of early Jurassic. The Sr, Nd isotopic compositions show that the Tethyan mantle domain is the depleted mantle （DM）, with enriched mantle domain II （EMII）. They have the same Sr, Nd isotopic composition with the India Ocean MORB type.

Coupled trace element and SIMS sulfur isotope geochemistry of sedimentary pyrite:Implications on pyrite growth of Caixiashan Pb-Zn deposit

Colloform pyrite with core-rim texture is commonly deposited in carbonate platforms associated with the sulfide ores such as the Caixiashan Pb-Zn deposit.However,the genesis of colloform pyrite in Pb-Zn deposits,its growth controls and their geological implication are insufficiently understood.Integration of in-situ trace element and SIMS sulfur isotopes has revealed geochemical variations among these pyrite layers.These colloform pyrite occur as residual phases of core-rim aggregates,the cores are made up of very fine-grained anhedral pyrite particles,with some rims being made up of fine-grained and poorlycrystallized pyrite,while the other rims were featured with euhedral cubic pyrite.which are cemented by fine-grained calcite and/or dolomite with minor quartz.Sulfur isotope analysis shows that some wellpreserved rims have negative δ^34 S values(-28.12‰to-0.49‰),whereas most of the cores and rims have positive δ^34 S values(>0 to+44.28‰;peak at+14.91‰).Integrating with the methane and sulfate were observed in previous fluid inclusion study,we suggest that the 34 S depleted rims were initially formed by bacteria sulfate reduction(BSR),whereas the positive δ^34 S values were resulted from the sulfate reduction driven by anaerobic methane oxidation(AOM).The well-developed authigenic pyrite and calcite may also support the reaction of AOM.Combined with petrographic observations,trace element composition of the colloform pyrite reveals the incorporation and precipitation behavior of those high abundance elements in the pyrite:Pb and Zn were present as mineral inclusion and likely precipitated before Fe,as supported by the time-resolved Pb-Zn signal spikes in most of the analyzed pyrite grains.Other metals,such as Hg,Co and Ni,may have migrated as chloride complexes and entered the pyrite lattice.Arsenic and Sb,generally influenced by complex-forming reactions rather than substitution ones,could also enter the pyrite lattice,or slightly predate the precipitation of colloform pyrite as mineral inclusions,which are controlled by their hydrolysis constant in the ore fluids.The colloform pyrite may have grown inward from the rims.The successive BSR reaction process would enrich H^32/2S in the overlying water column but reduce the metal content,the nucleation of these pyrite rims was featured by strongly negative sulfur isotopes.The following AOM process should be activated by deformation like the turbidity sediment of the mudstone as the sulfide deposition are associated with fault activities that caused the emission of methane migration upward and simultaneously replenishing the metal in the column.The higher AOM reaction rate and the higher metal supply(not only Fe.but with minor other metals such as Pb and Zn) caused by sediment movement enhanced the metal concentration within the pyrite lattice.

Geochemistry and geodynamic significance of the rare-earth mineralized Paleoproterozoic Longwangzhuang granite on the southern margin of the North China Craton

The Longwangzhuang granite pluton occurs on the southern margin of the North China Craton and consists mainly of biotite syenogranite with aegirine granite being locally distributed.The granites are characterized by high silicon and alkaline contents(SiO2=72.17%-76.82%,K2O+Na2O=8.28%-10.22%,K2O/Na2O>>1),AI(agpaitic index) =0.84-0.95,DI=95-97,ASI(aluminum saturation index)=0.96-1.13,and very high Fe* number(FeO*/(FeO*+Mg)=0.90-0.99),thus the granites are assigned to the metaluminous to weakly peraluminous,alkalic to calc-alkalic ferroan A-type granites.The granites are rich in large ion lithophile elements(LILE),especially high in REE concentrations(REE+Y=854×10-6-1572×10-6);whereas the enrichment of high strength field elements(Nb,Ta,Zr,Hf) is obviously less than that of LILEs,exhibiting mild depletions on trace element spider plots;and the rocks are significantly depleted in Ba,Sr,Ti,and Pb.The low εNd(t) values(-4.5--7.2) and high model ages(2.3-2.5 Ga) of the granites as well as the low εHf(t) values(-1.11--5.26) and high Hf model ages(THf1= 2.1-2.3 Ga,THf2=2.4-2.6 Ga) of zircons from the biotite syenogranite suggest that the granites were probably derived from an enriched mantle source.The zircons from the biotite syenogranite are mainly colorless transparent crystals exhibiting well-developed oscillatory zoning on the cathodoluminescence images with a LA-ICPMS zircon U-Pb age of 1602.1±6.6 Ma(MSWD=0.48).Petrochemical,trace elements,as well as Nd and Hf isotopic compositions of the rocks demonstrate that the granites were formed in a within-plate extensional tectonic regime possibly related to the breakup of the Columbia supercontinent.The granites were most likely formed through extreme fractional crystallization of alkali basaltic magma resulted from partial melting of the mantle,which was fertilized by recycling crustal rocks triggered by the delamination of lithospheric mantle and lower crust following the ～1.8 Ga collision and amalgamation of the North China Craton which is part of the Columbia supercontinent.However,contamination of neo-Archean to Paleoproterozoic crustal rocks during the ascent and emplacement of the magma could not be excluded.Being the youngest known anorogenic magmatism on the southern margin of the North China Craton related to Columbia breakup,it might represent the break off of the North China Craton from Columbia supercontinent at the end of Paleoproterozoic.

Geochemistry of the Eocene Felsic Porphyric Rocks and High-Mg Potassic Rocks along JARSZ:Implication for the Tectonic Evolution in Eastern Tibet

Eocene felsic porphyric rocks and the high-Mg potassic volcanic rocks（HMPR） occur along the Jinshajiang-Ailao Shan-Red River shear zone（JARSZ） in eastern Tibet.Compared with the HMPR,which are generally believed to be sourced from an enriched mantle,the felsic porphyric rocks show similar K_2O contents,enrichment in LREE and LILE,particularly radiogenic isotope（e.g.Sr and Nd） features much similar to the former,implying generation of the felsic porphyric rocks most likely related to the HMPR,although they both have clearly different major and trace element compositions. The close relationship in spatial-temporal distribution and similar Sr-Nd characteristics between the felsic porphyric rocks and HMPR in eastern Tibet indicate that both of them were possibly formed by a similar tectonic process（event）.Combining the basic dikes in southern and eastern Tibet,we suggest that the break-off of north-dipping Neo-Tethyan slab in southern Tibet during 50-40 Ma,triggered formation of high-Mg potassic magma.This led to developing felsic porphyric magma production by partial melting of underplating HMPR in the lower crust,or fractionation crystallization of the high-Mg potassic magmas.The break-off of slab in the Eocene may also have contributed to the abundant ore-forming material related to earlier subduction events,resulting in formation of the porphyric deposits along JARSZ in eastern Tibet.

Geochemistry, geochronology and mineralization of the rare-metal granites in the Daping Ta-Nb deposit, Fujian Province, South China

1 Introduction Rare-metal granites are widely distributed in South China.The Daping porphyritic granitic Ta-Nb deposit,located in the Yongding area of south Fujian province,South China,is a large rare-metal deposit recently discovered.Few studies have been made of its petrology,mineralogy,geochemistry,chronology and metallogeny.In recent years,several exploratory drillings have been done in this deposit.These drilling holes,from 380 to 600

REE Geochemistry of Fluorite from the Maoniuping REE Deposit,Sichuan Province,China:Implications for the Source of Ore-forming Fluids

Fluorite is one of the main gangue minerals in the Maoniuping REE deposit, Sichuan Province, China. Fluorite with different colors occurs not only within various orebodies, but also in wallrocks of the orefield. Based on REE geochemistry, fluorite in the orefleld can be classified as the LREE-rich, LREE-flat and LREE-depleted types. The three types of fluorite formed at different stages from the same hydrothermal fluid source, with the LREE-rich fluorite forming at the relatively early stage, the LREE-flat fluorite in the middle, and the LREE-depleted fluorite at the latest stage. Various lines of evidence demonstrate that the variation of the REE contents of fluorite shows no relation to the color. The mineralization of the Maouiuping REE deposit is associated spatially and temporally with carbonatite-syenite magmatism and the ore-forming fluids are mainly derived from carbonatite and syenite melts.

The Cenomanian-Turonian Anoxic Event in Southern Tibet: A Study of Organic Geochemistry

The Cenomanian-Turonian oceanic anoxic event (C/T OAE) is developed in southern Tibet. Organic geochemical study of the Cenomanian-Turonian sediments from the Gamba and Tingri areas shows that the mid-Cretaceous black shales in southern Tibet are enriched in organic carbon. The molecular analyses of organic matter indicate marine organic matter was derived from algae and bacteria. In the Gamba area, the organic matter is characterized by abundant tricyclic terpanes and pregane, which are predominant in 191 and 217 mass chromatograms, respectively. Pristane/phytane (Pr/Ph) ratios in the C/T OAE sediments are less than 1, demonstrating the domination of phytane. The presence of carotane can be regarded as a special biomarker indicating oxygen depletion in the C/T OAE sediments in the Tethyan Himalayas. In anoxic sediments, β-carotane and γ-carotane are very abundant. The β- and γ-carotane ratios relative to nC 17 in the Cenomanian-Turonian anoxic sediments vary from 32.28～ 42.87 and 5.10～ 11.01.

Geology and Geochemistry of the Shizitou Molybdenum Deposit, Jiangxi Province： Implications for Geodynamic Setting and Metallogenesis

The Shizitou molybdenum （Mo） deposit in Yongping, Jiangxi, is an important, recently discovered deposit in the eastern section of the Qin-Hang metallogenic belt. The Mo deposit is located in the outer contact zone behveen the porphyritic biotite granite and the Neoproterozoic migmatite, and present in the deep central part of the intrusion. Re-Os dating and S and Pb isotopic analysis have been conducted to assess the metallogenesis of the Shizitou Mo deposit. S, Pb and Re isotopes show that the ore-forming materials were derived from the porphyritic biotite granitic magma, which originated from the mixing of mantle and crust. Re-Os dating of molybdenite from the ores gives a model age from 156.9±2.2 to 158.5±2.4 Ma, with a weighted mean age of 158±1 Ma and an isochron age of 158.0±2.5 Ma. Geological and geochemical characteristics of the ore deposit and the related granitoids indicate that the Shizitou deposit is a Climax-type Mo deposit. Based on previous studies of the Qin-Hang metaliogenic belt, two metallogenic events are believed to have occurred during 172-145 Ma and 137-132 Ma. These two metallogenic periods are consistent with the timing of two metallogenic peaks during the middle to late Jurassic and the Cretaceous in South China. These events represent responses to the partial backarc extension associated with the subduction of the Izanagi plate beneath the Eurasian continent and the rapid northeastward movement of the subducting Izanagi plate.

Boron isotope geochemistry of Zigetang Co saline lake sediments,Tibetan Plateau

The origin of boron in boron-rich salt lakes in the Tibetan Plateau is highly controversial.In this study,we carried out a detailed study on boron geochemistry and isotope composition of lake sediments collected in Zigetang Co,central Tibet.Evaporites had high boron concentrations of 172.3–418.6 lg/g and δ^(11)B values of-8.2%to-3.3%,suggesting a non-marine origin for the saline lake.The boron isotopic fractionation factor,a,between evaporite and brackish water(a_(evaporite–brackish))decreased systematically with depth,from 0.9942 at the top of the drill core to 0.9893 at the bottom;the linear variation between α_(evaporite–brackish)and depth reflects boron isotopic fractionation associated with progressive crystallization.The positive correlation between δ^(11)B versus[B]and δ^(11)B versus depth in the evaporite phase reflects pH and boron speciation in the solution control on the adsorption of boron,and B(OH)_3 species incorporated preferentially into Mg(OH)_2 precipitation at high pH.

Directional Analysis of Urban Expansion Based on Sub-pixel and Regional Scale: A Case Study of Main Districts in Guangzhou, China

Multi-scale data have had a wide-ranging level of performance in the area of urban change monitoring. Herein we investigate the correlation between the impervious surface fraction(ISF) and the Defense Meteorological Satellite Program/Operational Linescan System(DMSP/OLS) nighttime stable light(NTL) data with respect to the urban expansion in the main districts of Guangzhou. Landsat 5 Thematic Mapper and Landsat 8 Operational Land Image(OLI) data from 1988 to 2015 were used to extract the ISF using the linear spectral mixture analysis model and normal difference build-up index at the sub-pixel scale. DMSP/OLS NTL data from 1992 to 2013 were calibrated to illustrate the urban nighttime light conditions at the regional scale. Urban expansion directions were identified by statistics and kernel density analysis for the ISF study area at the sub-pixel scale. In addition, the correlation between the ISF and DMSP/OLS NTL data were illustrated by linear regression analysis. Furthermore, Profile Graph in ArcGIS was employed to illustrate the urban expansion from the differences in correlation in different directions. The conclusions are as follows: 1) The impervious surface(IS)in the study area has expanded to the northeast and the east, starting with the old urban zones, and the high-density IS area has increased by321.14 km^2. 2) The linear regression analysis reveals a positive correlation between the ISF and the DMSP/OLS NTL data. The multi-scale data changes are consistent with the actual urban planning of Guangzhou. 3) The DMSP/OLS NTL data overestimate the urban extent because of its saturation and blooming effects, causing its correlation with ISF to decrease. The pattern of urban expansion influences the saturation and blooming effects of the DMSP/OLS NTL data.

The geology and geochemistry of the Shizitou molybdenum deposit, Jiangxi province, China: Implications for the geodynamic setting

1 Introduction The Qin-Hang suture zone is the most important polymetallic metallogenic zone in southern China[1-2]and has the greatest resource potential.In recent years,a group of molybdenum(Mo)deposits have been discovered in the northeastern part of the Qin-Hang belt[3].From Mar.2006to Dec.2014,the Jiangxi Copper Group Geological Exploration Engineering Co.,Ltd.conducted prospecting,

STUDY ON THE CHEMICAL CHARACTERISTICS OF POLLUTING FOG IN GUANGZHOU AREA IN SPRING

Samples of fog water collected in the area of Guangzhou during February, March and April of 2005 are used in this work to study the chemical composition of fog water in polluting fog there. Three typical episodes of polluting fog are analyzed in terms of ionic concentration and their possible sources. It is found that the concentration of various ions in fog water is much higher than those in rainwater. Fog not only blocks visual range but contains liquid particles that result in high degree of pollution and are very harmful to human health. SO4= is the anion with the highest concentration in fog water, followed by NO3-. For the cation, Ca++ and NH4+ are the highest in concentration. It is then known that rainwater is more acidic than fog water, indicating that ionic concentration of fog water is much higher than that of rainwater, but there are much more buffering materials in fog water, like NH4+ and Ca++. There is significant enrichment of Ca++, SO4=, and Mg++ in fog water. In the Guangzhou area, fog water from polluting fog is mainly influenced continental environment and human activity. The episodes of serious fog pollution during the time have immediate relationships with the presence of abundant water vapor and large amount of polluting aerosol particles.