Research on the Performance of Titanium Gypsum Concrete Based on Calcium-Silicon-Sulfur Ratio

Based on the high sulfur content in titanium gypsum,the concept of the calcium-silicon-sulfur(Ca/Si/S)ratio was proposed.The Ca/Si/S ratio of concrete was adjusted by changing the titanium gypsum,fly ash,and cement con-tent.The effects of different Ca/Si/S ratios on the mechanical properties,hydration products,and concrete micro-structure were investigated by nuclear magnetic resonance,uniaxial compression,and scanning electron microscopy.The result shows:(1)The compressive strength of concrete mixed with titanium gypsum increases first and then decreases with the Ca/Si/S ratio decrease.When the Ca/Si/S ratio is 1:0.85:0.10,the strength reaches the peak and is lower than the blank group.(2)The microstructure indicates the addition of titanium gypsum can effectively stimulate the activity of fly ash.Still,too much or too little titanium gypsum will hamper concrete strength development.(3)Titanium gypsum concrete’s nuclear magnetic resonance T2 spectrum has two characteristic peaks.With the Ca/Si/S ratio decreasing,the micropores in the concrete expand towards the macropores.The compressive strength is negatively correlated with the proportion of macropores and is positively correlated with the proportion of no-capillary pores.

Pore Structure Characteristics of Baking-Free Slag-Sludge Bricks and Its Correlations to Mechanical Properties

In order to explore the relationship between the macroscopic properties and pore structure characteristics of baking-free slag-sludge bricks,the compressive strength and water absorption rate using aluminum industrial slag and sludge of different substitution rates were tested.Optical instruments and image analysis software were used to measure the parameters of the pore structure.Specifically,a fractal model was built based on the fractal theory,in which the fractal dimension was used as the characteristic index of the pore structure to analyze the correlation and interaction mechanism between the fractal dimension and the macroscopic mechanical properties.Based on this study,conclusions were drawn as follows:(1)The plane pore structure of baking-free bricks shows good fractal characteristics.With the increase of the aluminum industrial slag content,the fractal dimension becomes smaller and the pore structure develops well;with the increase of the sludge content,the fractal dimension becomes larger and the pore structure becomes worse;(2)As the fractal dimension of the plane pore structure increases,the compressive strength of baking-free bricks falls,and the porosity and water absorption rise;(3)The optimum content of baking-free slag-sludge bricks is aluminum industrial slag 30%and sludge 10%.After 7 days of curing,baking-free bricks boast higher performance,and fully meet the performance requirements of solid concrete bricks(MU40),which can reduce time costs,and enhance enterprise revenue.

Effects of Recycled Aggregate Content on Pervious Concrete Performance

A recycled aggregate(RA)was prepared by crushing and sieving demolished discarded concrete pavements and was subsequently tested and analyzed to determine its various physical properties.On this basis,pervious concrete(PC)mix proportions were designed.Coarse RA particles with sizes of 5–10 and 10–20 mm were selected.Concrete specimens were prepared with a water–cement ratio of 0.3,an aggregate–cement ratio of 4.5,the substitute rates of RA with 0,25%,50%,75%and a single-/double-gap-graded RA mix(mass ratio of particles with sizes of 5–10 mm to particles with sizes of 10–20 mm:1:1,1:2,2:1,2:3 and 3:2).Various properties of the RA-containing PC(RPC)were determined by analyzing the compressive strength,splitting tensile strength,effective porosity,permeation coefficient and impact and abrasion resistance of the specimens.The results showed the following:The density of the RPC decreased with an increasing RA replacement ratio.The density of the RPC prepared with a double-gapgraded RA mix was lower than that prepared with a single-gap-graded RA(particle size:10–20 mm)mix.The permeation coefficient of the RPC increased with increasing porosity.The splitting tensile strength of the RPC was positively correlated with its compressive strength.The compressive strength of the RPC decreased with increasing porosity.The regression analysis showed that the impact and abrasion resistance of the RPC increased with increasing compressive strength.In addition,all of the RPC specimens met the strength and permeation requirements.This study can provide theoretical support for the application of RPC.

Study on Mechanical Properties and Action Mechanism of Leather Industrial Sludge Aggregate Baking-Free Bricks

Taking an industrial sludge and its preparation of sludge wrap shell aggregates(WSAs)instead of sand to prepare baking-free brick as the research object,the development law of mechanical properties and the influence mechanism of macro and micro characteristic parameters of the bricks under different sludge and WSAs replacement rates were studied through the macroscopic mechanical properties test,with the help of nuclear magnetic resonance(NMR),transmission electron microscopy-energy spectrum and other testing technology and pores and cracks analysis system(PCAS)software.The results showed that the compressive strength of each sample decreased with the increase of sludge content.When the sludge content was less than 30%,it was mainly affected by the water-binder ratio.When the sludge content was more than 30%,it was mainly affected by the sludge content.At the age of 7 days,with the increase in replacement rate of WSAs,the compressive strength of the S10 and S30 groups was higher than that of the control group.The compressive strength of the S50 experimental group was 30.38 MPa,and the loss of compressive strength was slight compared with the control group.The water absorption rate of the 28 days S100 experimental group increased by 10.71%compared with the control group.When the content of WSAs was less than 50%,the holes above 0.1μm in the brick can be reduced and transformed into smaller holes,with a decreasing trend of the plane porosity of the brick.The microscopic results of the baking-free brick showed that the three-phase system of WSAs-interface transition area-mortar was poorly bonded and delaminated compared with the gravel aggregate-interface transition area-mortar system,and damage was more likely to occur in the WSAs and interface transition area.The above results show that it is feasible to use sludge and WSAs instead of sand for the preparation of baking-free bricks.This technology not only solves the problem of sludge disposal,but also protects the over-exploitation of mineral resources,and the technology has a broad application prospect and market value.