The first humans （hominids） appeared at about the same geological time in three independent areas： in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around ...The first humans （hominids） appeared at about the same geological time in three independent areas： in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around the world descended from hominids that emerged in these three foci then resided elsewhere. The number of people emerged 2-3 million years ago now about 7.0 billion people. They inhabit the planet and the master space. Kazakh steppe, located in the middle of the Eurasian continent, has always had a positive impact on neighboring countries. According to historical geological data obtained in the south near the ridge Karatau, the first people emerged on the territory of Kazakhstan were found about 2 million years ago. Such a conclusion was made on the basis of residual cultural pebble tools of hominids, founded by scientists. As a result of geological survey work carried out in the 1960＇s there were found some primitive people, starting with the era of＂Arystandy culture＂ and including the Late Paleolithic era in the area of ridges Big and Small Karatau. There had been found the fossil remains of large mammals hunted by hominids around the sites of ancient people. Thanks for these residues the corresponding time of residence of primitive people can be judged from the animal world of the Kazakh steppe.展开更多
The thermodynamic equilibria and kinetic aspect of gold dissolution in iodine-iodide leaching were studied with emphasis on the effects of pH value and temperature on the system.The results of thermodynamic analysis o...The thermodynamic equilibria and kinetic aspect of gold dissolution in iodine-iodide leaching were studied with emphasis on the effects of pH value and temperature on the system.The results of thermodynamic analysis of iodine in aqueous solution were given and numerous forms of iodine exist mainly in the acid region of pH values.An increase of the potential of the system results in an increase of iodine speciation.The oxidizing potential of the system will increase by the addition of element iodine.The IO^(3-)anions are stable in the potential range from-2.0 to-0.75 V and at pH value greater than 12.1.An increase of the temperature shifts boundaries of existence of various iodine species in the acid region of pH values.Some of them become unstable.The determined values of the diffusion coefficients and the thickness of the diffusion boundary layer,as well as the solvent concentration on the disc surface(14 mg/L) indicate that the process proceeds in the external diffusion region.Thus,while choosing the conditions of leaching from gold-containing materials of different origins of iodide solvents,it is necessary to carry out the process within the acidic region of pH values,where I^-,I_3^- and IO_4^- ions are capable to form complex compounds with metals.展开更多
In work was researched the composition and structure of high-alloyed aluminum cast iron ЧЮ22Ш. Crystalization of cast iron ЧЮ22Ш (ЧЮ22Ш standard cast iron) was researched by phase transformation, leaking upon...In work was researched the composition and structure of high-alloyed aluminum cast iron ЧЮ22Ш. Crystalization of cast iron ЧЮ22Ш (ЧЮ22Ш standard cast iron) was researched by phase transformation, leaking upon its harden and cooling –down. High-alloyed materials are widely applied as the heat-resistant materials. Overall content of that reaches 30-50% and more. Previous performed researches allowed to optimize the content high-alloyed aluminum cast iron ЧЮ22Ш, to research its structure, casting and operational characteristics, to develop technological mode of melting, casting and thermal / heat treatment casts, to held its industrial examination and to determine perspective direction of its application. However, in present time ability of the aluminum cast iron ЧЮ22Ш is being used not sufficiently.展开更多
The object of research is the wax as a waste product of bees in the steppe and mountain areas of Almaty region of Kazakhstan. Purpose: To study the structure parameters and the homologous phase composition, morphology...The object of research is the wax as a waste product of bees in the steppe and mountain areas of Almaty region of Kazakhstan. Purpose: To study the structure parameters and the homologous phase composition, morphology waxes of alpine and mountain areas of Kazakhstan and the establishment temperature-dependent patterns of their atomic-crystalline state. Methods: Radiography, gas chromatography, scanning electron microscopy and chemical methods of separation of multicomponent systems. The results were obtained in the atomic crystal and molecular structures of beeswax depending on the districts collecting materials. The technique of obtaining radiographs after dissolving beeswax in benzene, hexane and xylene was used. Submitted thermo-radiographic study samples were obtained. Batch analysis thermo-radiographs waxes after treatment with benzene, hexane and xylene showed that their structure is essentially different from the source and closer to the spectra of the crystallized wax melted and due to annihilation of stacking faults waxes native atoms after their dissolution in hexane, benzene and xylene and subsequent their recrystallization. The results obtained allow expanding the amount of information on the physico-chemical processes and structural transformations in beeswax as a composite of different genesis biomaterial. Scope: Beekeeping, plant, structural and analytical chemistry, biotechnology and biocomposites.展开更多
This paper presents the results of the search of biologically active uranium compounds such as amino acids. We first received and examined X-ray and IR （infrared radiation） spectroscopy of uranium complexes with α-...This paper presents the results of the search of biologically active uranium compounds such as amino acids. We first received and examined X-ray and IR （infrared radiation） spectroscopy of uranium complexes with α- and β-amino acids in aqueous and organic solution. We proposed a method for direct synthesis of complex organic compounds of uranium chloride UO2Cl2 with α- andβ-amino acids for the synthesis of drugs for the treatment of cancer.展开更多
The surface properties of water soluble copolymers vinyl ethers of monoethanolamine and ethylene glycol with sodium 2-acrylamido-2-methyl-propanesulfonate were investigated by studying adsorption at the aqueous soluti...The surface properties of water soluble copolymers vinyl ethers of monoethanolamine and ethylene glycol with sodium 2-acrylamido-2-methyl-propanesulfonate were investigated by studying adsorption at the aqueous solution – air interface. It is found that copolymers have considerably higher surface activity in comparison with poly- sodium 2-acrylamido-2-methyl-propanesulfonate.展开更多
This paper proposes the method of producing graphene sheets and carbon nanotubes with reactive magnetron sputtering in vapour by sublimation aromatic hydrocarbons (naphthalene) with a structure of the benzene rings in...This paper proposes the method of producing graphene sheets and carbon nanotubes with reactive magnetron sputtering in vapour by sublimation aromatic hydrocarbons (naphthalene) with a structure of the benzene rings in a more natural formation of graphene structures. The carbon grid of molecular structure of aromatic hydrocarbons coincides with the graphene of carbon grid. The article shows the method of obtaining carbon nanostructures. The graphene of peaks was observed with the vibrational mode (2D-zone) at a frequency of ~2728 sm-1 using the method of Raman spectroscopy. Results from studies using atomic force microscopy confirm the formation of graphene sheets and the carbon nanotubes.展开更多
The availability of polymetallic ores is getting leaner in grade and is larger but inferior in volumes than in the past, making the extraction of copper, nickel and other non-ferrous metals metallurgically more diffic...The availability of polymetallic ores is getting leaner in grade and is larger but inferior in volumes than in the past, making the extraction of copper, nickel and other non-ferrous metals metallurgically more difficult to produce. The standard technologies, including enrichment and concentration, do not provide methods for obtaining monometallic concentrates and high extraction of metals into the commercial product. Pyrometallurgical processing of large volumes of poor raw materials is not economical and is complicated from the technological point of view. Conditions of chemical enrichment of poor natural materials have been studied with the use of technology of salt exchange leaching. The main impurity in sulfide ores of nonferrous metals is iron present in the forms of pyrite and pyrrhotite and the properties of chemical enrichment for nickel in pyrite concentrates has been investigated in this work. On the basis of thermodynamic analysis carried out with the use of Potential-pH Pourbaix’s Diagrams, it has been established that, with the use of nickel salt, it is possible to leach iron sulfides from ores. Based on the study of the mechanism and kinetics of the process of dissolution of iron sulfides with nickel salts, it was established that during the dissolution, the chemical composition and thermodynamic characteristics of the dissolved iron sulfides change—the residues from leaching are enriched with iron sulfides that are rich in sulfur and also result with elemental sulfur formation. Enrichment of leaching residues with sulfide iron with increased sulfur content and formation on the surface of nickel sulfide leads to increase of diffusional resistances and the process is limited by the velocity of mass transfer. To increase the velocity of the process and completeness of the reaction, it is necessary to activate the process, in particular, by grinding the solid phase.展开更多
Method and mechanism for the formation of sulfur compounds during the process of sulfur electrochemical dissolution has been studied, including a technique for the production of composite sulfur-graphite electrode. Al...Method and mechanism for the formation of sulfur compounds during the process of sulfur electrochemical dissolution has been studied, including a technique for the production of composite sulfur-graphite electrode. Along with these, a 3D design is presented in the unit that was used to perform electrolytic reduction, using composite sulfur-graphite electrode. For the first time, a study was carried out for the simultaneous reactions of electroreduction and electrooxidation of sulfur at the sulfur-graphite electrode in sulfurous environment in the same electrolytic bath, with separate electrode spaces. Influences of current density, acid concentration and electrolyte temperature were studied, and it was demonstrated that sulfur is reduced in cathode chamber with formation of hydrogen sulfide gas, and is oxidized in the anode chamber with formation of sulfite and sulfate ions. It has been shown that the methods we propose can be used to produce important sulfur compounds through electrochemical dissolution of specially designed sulfur-graphite electrode.展开更多
Sorption characteristics of ion exchange resins 001 × 7, 005 × 8, D72 regarding rare earth metals （REM） during extraction from barren solution of uranium sorption in dynamic conditions were investigated. I...Sorption characteristics of ion exchange resins 001 × 7, 005 × 8, D72 regarding rare earth metals （REM） during extraction from barren solution of uranium sorption in dynamic conditions were investigated. It was identified that D72 resin capacity on analyzed REM was 2.46 mg.cm-3 after passing 220 BV （bed volume） of initial solution with 95 % recovery of element of REM with the lowest affinity. Researches on REM desorption in dynamic conditions from investigated ion exchange resins by solution of 1.7 mol.L-1 HNO3 and 8.0 mol.L-1 NHnNO3 with 0.2 mol.L-1 HNO3 passing were carded out. It was identified that using desorption solution based on ammonium nitrate allows to achieve acceptable recovery degree of REM from the resin. The possibility of organization of a circulating desorption solution system increases the perspectives of nitrate ammonium solution usage.展开更多
文摘The first humans （hominids） appeared at about the same geological time in three independent areas： in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around the world descended from hominids that emerged in these three foci then resided elsewhere. The number of people emerged 2-3 million years ago now about 7.0 billion people. They inhabit the planet and the master space. Kazakh steppe, located in the middle of the Eurasian continent, has always had a positive impact on neighboring countries. According to historical geological data obtained in the south near the ridge Karatau, the first people emerged on the territory of Kazakhstan were found about 2 million years ago. Such a conclusion was made on the basis of residual cultural pebble tools of hominids, founded by scientists. As a result of geological survey work carried out in the 1960＇s there were found some primitive people, starting with the era of＂Arystandy culture＂ and including the Late Paleolithic era in the area of ridges Big and Small Karatau. There had been found the fossil remains of large mammals hunted by hominids around the sites of ancient people. Thanks for these residues the corresponding time of residence of primitive people can be judged from the animal world of the Kazakh steppe.
文摘The thermodynamic equilibria and kinetic aspect of gold dissolution in iodine-iodide leaching were studied with emphasis on the effects of pH value and temperature on the system.The results of thermodynamic analysis of iodine in aqueous solution were given and numerous forms of iodine exist mainly in the acid region of pH values.An increase of the potential of the system results in an increase of iodine speciation.The oxidizing potential of the system will increase by the addition of element iodine.The IO^(3-)anions are stable in the potential range from-2.0 to-0.75 V and at pH value greater than 12.1.An increase of the temperature shifts boundaries of existence of various iodine species in the acid region of pH values.Some of them become unstable.The determined values of the diffusion coefficients and the thickness of the diffusion boundary layer,as well as the solvent concentration on the disc surface(14 mg/L) indicate that the process proceeds in the external diffusion region.Thus,while choosing the conditions of leaching from gold-containing materials of different origins of iodide solvents,it is necessary to carry out the process within the acidic region of pH values,where I^-,I_3^- and IO_4^- ions are capable to form complex compounds with metals.
文摘In work was researched the composition and structure of high-alloyed aluminum cast iron ЧЮ22Ш. Crystalization of cast iron ЧЮ22Ш (ЧЮ22Ш standard cast iron) was researched by phase transformation, leaking upon its harden and cooling –down. High-alloyed materials are widely applied as the heat-resistant materials. Overall content of that reaches 30-50% and more. Previous performed researches allowed to optimize the content high-alloyed aluminum cast iron ЧЮ22Ш, to research its structure, casting and operational characteristics, to develop technological mode of melting, casting and thermal / heat treatment casts, to held its industrial examination and to determine perspective direction of its application. However, in present time ability of the aluminum cast iron ЧЮ22Ш is being used not sufficiently.
文摘The object of research is the wax as a waste product of bees in the steppe and mountain areas of Almaty region of Kazakhstan. Purpose: To study the structure parameters and the homologous phase composition, morphology waxes of alpine and mountain areas of Kazakhstan and the establishment temperature-dependent patterns of their atomic-crystalline state. Methods: Radiography, gas chromatography, scanning electron microscopy and chemical methods of separation of multicomponent systems. The results were obtained in the atomic crystal and molecular structures of beeswax depending on the districts collecting materials. The technique of obtaining radiographs after dissolving beeswax in benzene, hexane and xylene was used. Submitted thermo-radiographic study samples were obtained. Batch analysis thermo-radiographs waxes after treatment with benzene, hexane and xylene showed that their structure is essentially different from the source and closer to the spectra of the crystallized wax melted and due to annihilation of stacking faults waxes native atoms after their dissolution in hexane, benzene and xylene and subsequent their recrystallization. The results obtained allow expanding the amount of information on the physico-chemical processes and structural transformations in beeswax as a composite of different genesis biomaterial. Scope: Beekeeping, plant, structural and analytical chemistry, biotechnology and biocomposites.
文摘This paper presents the results of the search of biologically active uranium compounds such as amino acids. We first received and examined X-ray and IR （infrared radiation） spectroscopy of uranium complexes with α- and β-amino acids in aqueous and organic solution. We proposed a method for direct synthesis of complex organic compounds of uranium chloride UO2Cl2 with α- andβ-amino acids for the synthesis of drugs for the treatment of cancer.
文摘The surface properties of water soluble copolymers vinyl ethers of monoethanolamine and ethylene glycol with sodium 2-acrylamido-2-methyl-propanesulfonate were investigated by studying adsorption at the aqueous solution – air interface. It is found that copolymers have considerably higher surface activity in comparison with poly- sodium 2-acrylamido-2-methyl-propanesulfonate.
文摘This paper proposes the method of producing graphene sheets and carbon nanotubes with reactive magnetron sputtering in vapour by sublimation aromatic hydrocarbons (naphthalene) with a structure of the benzene rings in a more natural formation of graphene structures. The carbon grid of molecular structure of aromatic hydrocarbons coincides with the graphene of carbon grid. The article shows the method of obtaining carbon nanostructures. The graphene of peaks was observed with the vibrational mode (2D-zone) at a frequency of ~2728 sm-1 using the method of Raman spectroscopy. Results from studies using atomic force microscopy confirm the formation of graphene sheets and the carbon nanotubes.
文摘The availability of polymetallic ores is getting leaner in grade and is larger but inferior in volumes than in the past, making the extraction of copper, nickel and other non-ferrous metals metallurgically more difficult to produce. The standard technologies, including enrichment and concentration, do not provide methods for obtaining monometallic concentrates and high extraction of metals into the commercial product. Pyrometallurgical processing of large volumes of poor raw materials is not economical and is complicated from the technological point of view. Conditions of chemical enrichment of poor natural materials have been studied with the use of technology of salt exchange leaching. The main impurity in sulfide ores of nonferrous metals is iron present in the forms of pyrite and pyrrhotite and the properties of chemical enrichment for nickel in pyrite concentrates has been investigated in this work. On the basis of thermodynamic analysis carried out with the use of Potential-pH Pourbaix’s Diagrams, it has been established that, with the use of nickel salt, it is possible to leach iron sulfides from ores. Based on the study of the mechanism and kinetics of the process of dissolution of iron sulfides with nickel salts, it was established that during the dissolution, the chemical composition and thermodynamic characteristics of the dissolved iron sulfides change—the residues from leaching are enriched with iron sulfides that are rich in sulfur and also result with elemental sulfur formation. Enrichment of leaching residues with sulfide iron with increased sulfur content and formation on the surface of nickel sulfide leads to increase of diffusional resistances and the process is limited by the velocity of mass transfer. To increase the velocity of the process and completeness of the reaction, it is necessary to activate the process, in particular, by grinding the solid phase.
文摘Method and mechanism for the formation of sulfur compounds during the process of sulfur electrochemical dissolution has been studied, including a technique for the production of composite sulfur-graphite electrode. Along with these, a 3D design is presented in the unit that was used to perform electrolytic reduction, using composite sulfur-graphite electrode. For the first time, a study was carried out for the simultaneous reactions of electroreduction and electrooxidation of sulfur at the sulfur-graphite electrode in sulfurous environment in the same electrolytic bath, with separate electrode spaces. Influences of current density, acid concentration and electrolyte temperature were studied, and it was demonstrated that sulfur is reduced in cathode chamber with formation of hydrogen sulfide gas, and is oxidized in the anode chamber with formation of sulfite and sulfate ions. It has been shown that the methods we propose can be used to produce important sulfur compounds through electrochemical dissolution of specially designed sulfur-graphite electrode.
基金financially supported by LLP ‘‘Institute of High Technologies’’(No.RMK-D-018)
文摘Sorption characteristics of ion exchange resins 001 × 7, 005 × 8, D72 regarding rare earth metals （REM） during extraction from barren solution of uranium sorption in dynamic conditions were investigated. It was identified that D72 resin capacity on analyzed REM was 2.46 mg.cm-3 after passing 220 BV （bed volume） of initial solution with 95 % recovery of element of REM with the lowest affinity. Researches on REM desorption in dynamic conditions from investigated ion exchange resins by solution of 1.7 mol.L-1 HNO3 and 8.0 mol.L-1 NHnNO3 with 0.2 mol.L-1 HNO3 passing were carded out. It was identified that using desorption solution based on ammonium nitrate allows to achieve acceptable recovery degree of REM from the resin. The possibility of organization of a circulating desorption solution system increases the perspectives of nitrate ammonium solution usage.
